#------------------------------------------------------------------------------
#$Date: 2019-10-15 03:57:51 +0300 (Tue, 15 Oct 2019) $
#$Revision: 219347 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/13/7701372.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7701372
loop_
_publ_author_name
'Gupta, Arvind Kumar Kumar'
'Orthaber, Andreas'
_publ_section_title
;
 Facile synthesis of silver alkynide cluster and coordination polymers
 using picolinic acid as co-ligand
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/C9DT03697K
_journal_year                    2019
_chemical_formula_moiety         '2(C58 H96 Ag6.5 N2 O4 Si4), Cl O4'
_chemical_formula_sum            'C116 H192 Ag13 Cl N4 O12 Si8'
_chemical_formula_weight         3497.20
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_audit_creation_date             2019-08-15
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2019-10-10 deposited with the CCDC.    2019-10-14 downloaded from the CCDC.
;
_cell_angle_alpha                91.328(7)
_cell_angle_beta                 94.827(7)
_cell_angle_gamma                117.772(7)
_cell_formula_units_Z            2
_cell_length_a                   16.217(4)
_cell_length_b                   16.611(4)
_cell_length_c                   29.328(6)
_cell_measurement_reflns_used    9656
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      26.95
_cell_measurement_theta_min      2.52
_cell_volume                     6948(3)
_computing_cell_refinement       'Bruker APEX2'
_computing_data_collection       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'XT (Sheldrick, 2015)'
_diffrn_ambient_temperature      150.15
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0691
_diffrn_reflns_av_unetI/netI     0.0337
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            285113
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        24.999
_diffrn_reflns_theta_max         24.999
_diffrn_reflns_theta_min         0.698
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.927
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6559
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.672
_exptl_crystal_description       plate
_exptl_crystal_F_000             3504
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.06
_refine_diff_density_max         3.482
_refine_diff_density_min         -3.609
_refine_diff_density_rms         0.256
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.133
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1445
_refine_ls_number_reflns         24428
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.133
_refine_ls_R_factor_all          0.1048
_refine_ls_R_factor_gt           0.0864
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0835P)²+238.8645P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2332
_refine_ls_wR_factor_ref         0.2530
_reflns_Friedel_coverage         0.000
_reflns_number_gt                19963
_reflns_number_total             24428
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9dt03697k2.cif
_cod_data_source_block           ag_ag_501_0m_a
_cod_database_code               7701372
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.893
_shelx_estimated_absorpt_t_min   0.723
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Others
 Fixed Sof: Ag4(0.5)
3.a Ternary CH refined with riding coordinates:
 C3(H3), C6(H6), C9(H9), C17(H17), C20(H20), C25(H25), C28(H28), C31(H31),
 C36(H36), C39(H39), C42(H42), C61(H61), C64(H64), C67(H67), C72(H72), C75(H75),
  C78(H78), C83(H83), C86(H86), C89(H89), C106(H106), C110(H110), C113(H113),
 C116(H116)
3.b Aromatic/amide H refined with riding coordinates:
 C47(H47), C50(H50), C51(H51), C54(H54), C57(H57), C58(H58), C94(H94),
 C97(H97), C98(H98), C101(H101), C104(H104), C105(H105)
3.c Idealised Me refined as rotating group:
 C4(H4A,H4B,H4C), C7(H7A,H7B,H7C), C8(H8A,H8B,H8C), C10(H10A,H10B,H10C),
 C11(H11A,H11B,H11C), C15(H15A,H15B,H15C), C16(H16A,H16B,H16C), C18(H18A,H18B,
 H18C), C19(H19A,H19B,H19C), C21(H21A,H21B,H21C), C22(H22A,H22B,H22C), C26(H26A,
 H26B,H26C), C27(H27A,H27B,H27C), C29(H29A,H29B,H29C), C30(H30A,H30B,H30C),
 C32(H32A,H32B,H32C), C33(H33A,H33B,H33C), C37(H37A,H37B,H37C), C38(H38A,H38B,
 H38C), C40(H40A,H40B,H40C), C41(H41A,H41B,H41C), C43(H43A,H43B,H43C), C44(H44A,
 H44B,H44C), C49(H49A,H49B,H49C), C56(H56A,H56B,H56C), C62(H62A,H62B,H62C),
 C63(H63A,H63B,H63C), C65(H65A,H65B,H65C), C66(H66A,H66B,H66C), C68(H68A,H68B,
 H68C), C69(H69A,H69B,H69C), C73(H73A,H73B,H73C), C74(H74A,H74B,H74C), C76(H76A,
 H76B,H76C), C77(H77A,H77B,H77C), C79(H79A,H79B,H79C), C80(H80A,H80B,H80C),
 C84(H84A,H84B,H84C), C85(H85A,H85B,H85C), C87(H87A,H87B,H87C), C88(H88A,H88B,
 H88C), C90(H90A,H90B,H90C), C91(H91A,H91B,H91C), C96(H96A,H96B,H96C),
 C103(H10G,H10H,H10I), C107(H10D,H10E,H10F), C111(H11D,H11E,H11F), C112(H11G,
 H11H,H11I), C114(H11J,H11K,H11L), C115(H11M,H11N,H11O), C117(H11P,H11Q,H11R),
 C118(H11S,H11T,H11U)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Ag1 Ag 0.99935(9) 0.89320(8) -0.14590(4) 0.0419(3) Uani 1 1 d . . .
Ag2 Ag 0.88922(7) 1.00476(6) -0.12806(3) 0.0308(2) Uani 1 1 d . . .
Ag3 Ag 0.84954(13) 0.85648(14) -0.06392(5) 0.0769(6) Uani 1 1 d . . .
Ag4 Ag 1.00536(18) 1.02983(16) 0.00386(8) 0.0406(6) Uani 0.5 1 d . . .
Ag6 Ag 0.87917(9) 0.95651(8) 0.07270(4) 0.0437(3) Uani 1 1 d . . .
Ag5 Ag 0.92647(11) 1.11585(12) -0.04021(4) 0.0817(6) Uani 1 1 d . . .
Ag7 Ag 0.91604(8) 0.81321(8) 0.11885(4) 0.0396(3) Uani 1 1 d . . .
Ag8 Ag 0.39483(8) 0.86969(8) 0.35829(4) 0.0374(3) Uani 1 1 d . . .
Ag9 Ag 0.500000 1.000000 0.500000 0.0415(4) Uani 1 2 d S T P
Ag10 Ag 0.30052(8) 0.89731(7) 0.52402(3) 0.0354(3) Uani 1 1 d . . .
Ag11 Ag 0.40083(7) 0.86214(7) 0.62520(3) 0.0322(2) Uani 1 1 d . . .
Ag12 Ag 0.38196(6) 1.02693(6) 0.61180(3) 0.0243(2) Uani 1 1 d . . .
Ag13 Ag 0.58666(7) 0.96605(7) 0.58316(3) 0.0306(2) Uani 1 1 d . . .
Ag14 Ag 0.51149(8) 1.17223(8) 0.54577(4) 0.0387(3) Uani 1 1 d . . .
C1 C 0.8442(10) 0.8663(9) -0.1420(4) 0.032(3) Uani 1 1 d . . .
C2 C 0.8104(10) 0.7863(10) -0.1527(5) 0.035(3) Uani 1 1 d . . .
C3 C 0.7728(14) 0.6562(13) -0.2344(6) 0.070(6) Uani 1 1 d . . .
H3 H 0.733904 0.591367 -0.246808 0.084 Uiso 1 1 calc R . .
C4 C 0.8777(15) 0.676(2) -0.2315(9) 0.117(13) Uani 1 1 d . . .
H4A H 0.883958 0.635584 -0.253977 0.176 Uiso 1 1 calc GR . .
H4B H 0.897683 0.666625 -0.200622 0.176 Uiso 1 1 calc GR . .
H4C H 0.917014 0.739937 -0.238209 0.176 Uiso 1 1 calc GR . .
C6 C 0.6141(12) 0.6399(13) -0.1802(8) 0.065(6) Uani 1 1 d . . .
H6 H 0.611389 0.686913 -0.200086 0.078 Uiso 1 1 calc R . .
C7 C 0.580(2) 0.652(3) -0.1373(13) 0.19(2) Uani 1 1 d . . .
H7A H 0.520988 0.654617 -0.144099 0.279 Uiso 1 1 calc GR . .
H7B H 0.626464 0.708120 -0.120157 0.279 Uiso 1 1 calc GR . .
H7C H 0.568327 0.599709 -0.118769 0.279 Uiso 1 1 calc GR . .
C8 C 0.5463(15) 0.5480(16) -0.2054(10) 0.097(9) Uani 1 1 d . . .
H8A H 0.530943 0.499697 -0.184041 0.146 Uiso 1 1 calc GR . .
H8B H 0.575559 0.535865 -0.230751 0.146 Uiso 1 1 calc GR . .
H8C H 0.488800 0.549328 -0.217529 0.146 Uiso 1 1 calc GR . .
C9 C 0.7575(17) 0.5886(12) -0.1316(9) 0.080(7) Uani 1 1 d . . .
H9 H 0.715147 0.582651 -0.107516 0.096 Uiso 1 1 calc R . .
C10 C 0.8496(17) 0.6210(13) -0.1072(7) 0.079(7) Uani 1 1 d . . .
H10A H 0.844950 0.587075 -0.079814 0.118 Uiso 1 1 calc GR . .
H10B H 0.875915 0.686103 -0.098073 0.118 Uiso 1 1 calc GR . .
H10C H 0.890417 0.611867 -0.127204 0.118 Uiso 1 1 calc GR . .
C11 C 0.719(2) 0.4895(15) -0.1549(12) 0.146(17) Uani 1 1 d . . .
H11A H 0.763369 0.488929 -0.175447 0.219 Uiso 1 1 calc GR . .
H11B H 0.658216 0.471257 -0.172510 0.219 Uiso 1 1 calc GR . .
H11C H 0.711581 0.446708 -0.131161 0.219 Uiso 1 1 calc GR . .
C12 C 0.9210(10) 1.1404(10) -0.1163(5) 0.033(3) Uani 1 1 d . . .
C13 C 0.9353(10) 1.2185(9) -0.1121(5) 0.033(3) Uani 1 1 d . . .
C15 C 1.0319(13) 1.5047(10) -0.0635(5) 0.049(4) Uani 1 1 d . . .
H15A H 0.972854 1.488133 -0.050376 0.074 Uiso 1 1 calc GR . .
H15B H 1.031288 1.532303 -0.092594 0.074 Uiso 1 1 calc GR . .
H15C H 1.084394 1.548489 -0.042065 0.074 Uiso 1 1 calc GR . .
C16 C 1.0532(13) 1.3819(12) -0.0269(5) 0.050(4) Uani 1 1 d . . .
H16A H 1.108350 1.428436 -0.007828 0.075 Uiso 1 1 calc GR . .
H16B H 1.060958 1.327383 -0.031981 0.075 Uiso 1 1 calc GR . .
H16C H 0.997117 1.366005 -0.011222 0.075 Uiso 1 1 calc GR . .
C17 C 0.8268(12) 1.3241(10) -0.1020(5) 0.045(4) Uani 1 1 d . . .
H17 H 0.830604 1.385494 -0.105290 0.054 Uiso 1 1 calc R . .
C18 C 0.7484(13) 1.2580(13) -0.1379(7) 0.064(5) Uani 1 1 d . . .
H18A H 0.740570 1.196264 -0.134962 0.096 Uiso 1 1 calc GR . .
H18B H 0.764848 1.276898 -0.168658 0.096 Uiso 1 1 calc GR . .
H18C H 0.689711 1.258679 -0.132919 0.096 Uiso 1 1 calc GR . .
C19 C 0.8049(14) 1.2994(14) -0.0533(6) 0.060(5) Uani 1 1 d . . .
H19A H 0.745858 1.299190 -0.048101 0.090 Uiso 1 1 calc GR . .
H19B H 0.855626 1.344436 -0.031507 0.090 Uiso 1 1 calc GR . .
H19C H 0.799050 1.238766 -0.048865 0.090 Uiso 1 1 calc GR . .
C20 C 0.9660(12) 1.3658(10) -0.1752(5) 0.042(4) Uani 1 1 d . . .
H20 H 0.917145 1.313097 -0.195519 0.050 Uiso 1 1 calc R . .
C21 C 1.0597(13) 1.3760(13) -0.1860(5) 0.055(5) Uani 1 1 d . . .
H21A H 1.068152 1.390646 -0.218012 0.083 Uiso 1 1 calc GR . .
H21B H 1.061806 1.318710 -0.181304 0.083 Uiso 1 1 calc GR . .
H21C H 1.109929 1.425165 -0.165733 0.083 Uiso 1 1 calc GR . .
C22 C 0.9547(18) 1.4504(14) -0.1879(7) 0.071(6) Uani 1 1 d . . .
H22A H 0.999396 1.503464 -0.167755 0.107 Uiso 1 1 calc GR . .
H22B H 0.890685 1.438813 -0.184115 0.107 Uiso 1 1 calc GR . .
H22C H 0.966747 1.462347 -0.219866 0.107 Uiso 1 1 calc GR . .
C23 C 0.8594(11) 0.9692(11) -0.0058(4) 0.039(3) Uani 1 1 d . . .
C24 C 0.7811(12) 0.9470(11) 0.0053(5) 0.046(4) Uani 1 1 d . . .
C25 C 0.6111(14) 0.9353(14) -0.0440(6) 0.059(5) Uani 1 1 d . . .
H25 H 0.546808 0.926952 -0.040601 0.071 Uiso 1 1 calc R . .
C26 C 0.6676(17) 1.0337(16) -0.0611(8) 0.093(8) Uani 1 1 d . . .
H26A H 0.684027 1.079389 -0.035603 0.139 Uiso 1 1 calc GR . .
H26B H 0.628910 1.043138 -0.085754 0.139 Uiso 1 1 calc GR . .
H26C H 0.724973 1.039643 -0.072755 0.139 Uiso 1 1 calc GR . .
C27 C 0.597(2) 0.853(2) -0.0755(9) 0.116(11) Uani 1 1 d . . .
H27A H 0.609638 0.871798 -0.106649 0.174 Uiso 1 1 calc GR . .
H27B H 0.532729 0.804014 -0.075954 0.174 Uiso 1 1 calc GR . .
H27C H 0.640815 0.830621 -0.063757 0.174 Uiso 1 1 calc GR . .
C28 C 0.5927(11) 0.8058(10) 0.0357(6) 0.049(4) Uani 1 1 d . . .
H28 H 0.586552 0.761401 0.010325 0.059 Uiso 1 1 calc R . .
C29 C 0.4915(14) 0.7878(15) 0.0425(10) 0.084(7) Uani 1 1 d . . .
H29A H 0.451510 0.722360 0.044889 0.126 Uiso 1 1 calc GR . .
H29B H 0.466376 0.807994 0.016170 0.126 Uiso 1 1 calc GR . .
H29C H 0.492884 0.821567 0.070595 0.126 Uiso 1 1 calc GR . .
C30 C 0.6361(13) 0.7846(12) 0.0774(8) 0.066(5) Uani 1 1 d . . .
H30A H 0.633775 0.819303 0.104330 0.098 Uiso 1 1 calc GR . .
H30B H 0.701505 0.801276 0.073738 0.098 Uiso 1 1 calc GR . .
H30C H 0.601541 0.719156 0.081701 0.098 Uiso 1 1 calc GR . .
C31 C 0.6763(15) 1.0206(14) 0.0582(6) 0.062(5) Uani 1 1 d . . .
H31 H 0.729817 1.077064 0.048860 0.074 Uiso 1 1 calc R . .
C32 C 0.5980(17) 1.0391(19) 0.0556(8) 0.085(7) Uani 1 1 d . . .
H32A H 0.543853 0.987360 0.066104 0.127 Uiso 1 1 calc GR . .
H32B H 0.582573 1.048331 0.023736 0.127 Uiso 1 1 calc GR . .
H32C H 0.614181 1.094203 0.075047 0.127 Uiso 1 1 calc GR . .
C33 C 0.7057(14) 1.0108(14) 0.1077(7) 0.068(5) Uani 1 1 d . . .
H33A H 0.734034 1.070384 0.124974 0.101 Uiso 1 1 calc GR . .
H33B H 0.751417 0.987685 0.108213 0.101 Uiso 1 1 calc GR . .
H33C H 0.650528 0.967978 0.121845 0.101 Uiso 1 1 calc GR . .
C34 C 0.9009(11) 0.9440(9) 0.1427(4) 0.037(3) Uani 1 1 d . . .
C35 C 0.8938(9) 0.9230(9) 0.1826(4) 0.031(3) Uani 1 1 d . . .
C36 C 0.9929(10) 0.9286(11) 0.2752(5) 0.043(4) Uani 1 1 d . . .
H36 H 0.983774 0.921342 0.308399 0.051 Uiso 1 1 calc R . .
C37 C 1.0614(12) 1.0275(12) 0.2703(6) 0.053(4) Uani 1 1 d . . .
H37A H 1.122795 1.041637 0.286084 0.079 Uiso 1 1 calc GR . .
H37B H 1.038609 1.066796 0.283950 0.079 Uiso 1 1 calc GR . .
H37C H 1.067170 1.038128 0.237718 0.079 Uiso 1 1 calc GR . .
C38 C 1.0317(13) 0.8635(14) 0.2600(6) 0.058(5) Uani 1 1 d . . .
H38A H 1.048991 0.874731 0.228668 0.087 Uiso 1 1 calc GR . .
H38B H 0.983503 0.800078 0.260993 0.087 Uiso 1 1 calc GR . .
H38C H 1.087124 0.874819 0.280812 0.087 Uiso 1 1 calc GR . .
C39 C 0.8174(12) 0.9626(11) 0.2667(5) 0.044(4) Uani 1 1 d . . .
H39 H 0.748588 0.924373 0.257785 0.053 Uiso 1 1 calc R . .
C40 C 0.8426(12) 1.0516(11) 0.2461(5) 0.046(4) Uani 1 1 d . . .
H40A H 0.816087 1.084607 0.262543 0.068 Uiso 1 1 calc GR . .
H40B H 0.817357 1.040312 0.213735 0.068 Uiso 1 1 calc GR . .
H40C H 0.911006 1.088204 0.248621 0.068 Uiso 1 1 calc GR . .
C41 C 0.8294(16) 0.9707(13) 0.3197(6) 0.063(5) Uani 1 1 d . . .
H41A H 0.896243 1.002563 0.330760 0.095 Uiso 1 1 calc GR . .
H41B H 0.800589 0.909623 0.331068 0.095 Uiso 1 1 calc GR . .
H41C H 0.798818 1.005135 0.330759 0.095 Uiso 1 1 calc GR . .
C42 C 0.7950(11) 0.7674(10) 0.2418(5) 0.040(3) Uani 1 1 d . . .
H42 H 0.830179 0.736909 0.229844 0.048 Uiso 1 1 calc R . .
C43 C 0.7713(13) 0.7343(11) 0.2889(6) 0.054(4) Uani 1 1 d . . .
H43A H 0.739984 0.765406 0.302779 0.081 Uiso 1 1 calc GR . .
H43B H 0.829056 0.747613 0.308344 0.081 Uiso 1 1 calc GR . .
H43C H 0.729596 0.668316 0.286254 0.081 Uiso 1 1 calc GR . .
C44 C 0.7056(11) 0.7373(12) 0.2080(6) 0.056(5) Uani 1 1 d . . .
H44A H 0.669271 0.670565 0.205705 0.084 Uiso 1 1 calc GR . .
H44B H 0.723319 0.758551 0.177715 0.084 Uiso 1 1 calc GR . .
H44C H 0.667441 0.763573 0.219217 0.084 Uiso 1 1 calc GR . .
C45 C 0.8143(11) 0.7400(11) 0.0159(5) 0.040(3) Uani 1 1 d . . .
C46 C 0.7617(11) 0.6657(10) 0.0460(5) 0.042(4) Uani 1 1 d . . .
C47 C 0.6895(14) 0.5859(12) 0.0253(6) 0.063(5) Uani 1 1 d . . .
H47 H 0.675030 0.579738 -0.007028 0.076 Uiso 1 1 calc R . .
C48 C 0.6377(15) 0.5143(14) 0.0514(8) 0.075(6) Uani 1 1 d . . .
C49 C 0.559(2) 0.4258(18) 0.0310(10) 0.129(13) Uani 1 1 d . . .
H49A H 0.504156 0.433793 0.021887 0.194 Uiso 1 1 calc GR . .
H49B H 0.543869 0.379945 0.053724 0.194 Uiso 1 1 calc GR . .
H49C H 0.578286 0.405517 0.004027 0.194 Uiso 1 1 calc GR . .
C50 C 0.6649(13) 0.5275(12) 0.0984(7) 0.062(5) Uani 1 1 d . . .
H50 H 0.631719 0.480467 0.117768 0.075 Uiso 1 1 calc R . .
C51 C 0.7388(12) 0.6075(10) 0.1170(6) 0.047(4) Uani 1 1 d . . .
H51 H 0.756441 0.614653 0.149148 0.056 Uiso 1 1 calc R . .
C52 C 0.9369(10) 1.1800(10) 0.0580(5) 0.035(3) Uani 1 1 d . . .
C53 C 0.9067(11) 1.2157(8) 0.0976(5) 0.036(3) Uani 1 1 d . . .
C54 C 0.8538(13) 1.2610(12) 0.0882(7) 0.057(5) Uani 1 1 d . . .
H54 H 0.840007 1.271355 0.057465 0.069 Uiso 1 1 calc R . .
C55 C 0.8214(14) 1.2907(11) 0.1238(8) 0.063(6) Uani 1 1 d . . .
C56 C 0.761(2) 1.3374(16) 0.1143(10) 0.097(9) Uani 1 1 d . . .
H56A H 0.792640 1.388088 0.094952 0.146 Uiso 1 1 calc GR . .
H56B H 0.752116 1.360875 0.143352 0.146 Uiso 1 1 calc GR . .
H56C H 0.700363 1.293493 0.098458 0.146 Uiso 1 1 calc GR . .
C57 C 0.8454(13) 1.2777(11) 0.1673(8) 0.062(5) Uani 1 1 d . . .
H57 H 0.826970 1.299893 0.192567 0.075 Uiso 1 1 calc R . .
C58 C 0.8974(13) 1.2311(11) 0.1743(6) 0.050(4) Uani 1 1 d . . .
H58 H 0.912403 1.220941 0.204908 0.060 Uiso 1 1 calc R . .
C59 C 0.6047(8) 0.9597(9) 0.5061(4) 0.022(2) Uani 1 1 d . . .
C60 C 0.6568(9) 0.9278(8) 0.5212(4) 0.026(3) Uani 1 1 d . . .
C61 C 0.6779(13) 0.7799(12) 0.5698(7) 0.058(5) Uani 1 1 d . . .
H61 H 0.622877 0.737992 0.547808 0.070 Uiso 1 1 calc R . .
C62 C 0.738(2) 0.729(2) 0.5785(12) 0.130(14) Uani 1 1 d . . .
H62A H 0.794317 0.767040 0.599651 0.196 Uiso 1 1 calc GR . .
H62B H 0.757312 0.716661 0.549368 0.196 Uiso 1 1 calc GR . .
H62C H 0.701042 0.670998 0.591984 0.196 Uiso 1 1 calc GR . .
C63 C 0.6389(14) 0.7877(14) 0.6113(7) 0.067(5) Uani 1 1 d . . .
H63A H 0.615386 0.729932 0.626087 0.100 Uiso 1 1 calc GR . .
H63B H 0.587239 0.801802 0.603629 0.100 Uiso 1 1 calc GR . .
H63C H 0.687629 0.836631 0.632285 0.100 Uiso 1 1 calc GR . .
C64 C 0.7773(10) 0.8549(9) 0.4832(5) 0.033(3) Uani 1 1 d . . .
H64 H 0.822920 0.831767 0.492115 0.040 Uiso 1 1 calc R . .
C65 C 0.8285(17) 0.9385(14) 0.4560(7) 0.070(6) Uani 1 1 d . . .
H65A H 0.853579 0.921747 0.430237 0.105 Uiso 1 1 calc GR . .
H65B H 0.880163 0.986815 0.476060 0.105 Uiso 1 1 calc GR . .
H65C H 0.784686 0.960301 0.444317 0.105 Uiso 1 1 calc GR . .
C66 C 0.6954(15) 0.7786(13) 0.4547(7) 0.065(5) Uani 1 1 d . . .
H66A H 0.642349 0.791812 0.451962 0.097 Uiso 1 1 calc GR . .
H66B H 0.677471 0.721291 0.469480 0.097 Uiso 1 1 calc GR . .
H66C H 0.713071 0.772965 0.424111 0.097 Uiso 1 1 calc GR . .
C67 C 0.8437(13) 0.9817(13) 0.5724(6) 0.052(4) Uani 1 1 d . . .
H67 H 0.864471 1.032613 0.551409 0.062 Uiso 1 1 calc R . .
C68 C 0.9281(16) 0.969(2) 0.5832(11) 0.118(13) Uani 1 1 d . . .
H68A H 0.977225 1.023080 0.601178 0.177 Uiso 1 1 calc GR . .
H68B H 0.951037 0.960179 0.554597 0.177 Uiso 1 1 calc GR . .
H68C H 0.911641 0.915279 0.600943 0.177 Uiso 1 1 calc GR . .
C69 C 0.8234(12) 1.0205(10) 0.6149(5) 0.045(4) Uani 1 1 d . . .
H69A H 0.813218 0.978804 0.639458 0.068 Uiso 1 1 calc GR . .
H69B H 0.767127 1.027603 0.607790 0.068 Uiso 1 1 calc GR . .
H69C H 0.876792 1.080019 0.624987 0.068 Uiso 1 1 calc GR . .
C70 C 0.5554(9) 0.9754(10) 0.6503(5) 0.032(3) Uani 1 1 d . . .
C71 C 0.5388(9) 0.9693(9) 0.6901(4) 0.029(3) Uani 1 1 d . . .
C72 C 0.6449(12) 0.9740(13) 0.7796(5) 0.054(4) Uani 1 1 d . . .
H72 H 0.642487 0.972511 0.813531 0.065 Uiso 1 1 calc R . .
C73 C 0.6578(16) 0.8893(15) 0.7623(8) 0.074(6) Uani 1 1 d . . .
H73A H 0.660124 0.888998 0.728998 0.111 Uiso 1 1 calc GR . .
H73B H 0.604998 0.832503 0.769786 0.111 Uiso 1 1 calc GR . .
H73C H 0.716410 0.894253 0.777440 0.111 Uiso 1 1 calc GR . .
C74 C 0.7250(12) 1.0621(15) 0.7705(6) 0.064(5) Uani 1 1 d . . .
H74A H 0.779876 1.074082 0.791874 0.097 Uiso 1 1 calc GR . .
H74B H 0.708492 1.111346 0.774703 0.097 Uiso 1 1 calc GR . .
H74C H 0.739439 1.059011 0.738934 0.097 Uiso 1 1 calc GR . .
C75 C 0.4318(11) 0.8437(10) 0.7609(5) 0.041(4) Uani 1 1 d . . .
H75 H 0.446057 0.799660 0.743777 0.049 Uiso 1 1 calc R . .
C76 C 0.4293(15) 0.8187(14) 0.8108(6) 0.071(6) Uani 1 1 d . . .
H76A H 0.412252 0.857868 0.828966 0.107 Uiso 1 1 calc GR . .
H76B H 0.491232 0.827476 0.823076 0.107 Uiso 1 1 calc GR . .
H76C H 0.382794 0.754751 0.812270 0.107 Uiso 1 1 calc GR . .
C77 C 0.3354(11) 0.8262(10) 0.7402(5) 0.048(4) Uani 1 1 d . . .
H77A H 0.292070 0.760667 0.738785 0.072 Uiso 1 1 calc GR . .
H77B H 0.339355 0.847534 0.709213 0.072 Uiso 1 1 calc GR . .
H77C H 0.312498 0.859065 0.759350 0.072 Uiso 1 1 calc GR . .
C78 C 0.5133(12) 1.0597(10) 0.7736(5) 0.048(4) Uani 1 1 d . . .
H78 H 0.571951 1.114869 0.767561 0.058 Uiso 1 1 calc R . .
C79 C 0.4340(14) 1.0711(12) 0.7485(7) 0.058(5) Uani 1 1 d . . .
H79A H 0.375435 1.013786 0.747560 0.087 Uiso 1 1 calc GR . .
H79B H 0.448141 1.087075 0.717089 0.087 Uiso 1 1 calc GR . .
H79C H 0.427235 1.119713 0.764537 0.087 Uiso 1 1 calc GR . .
C80 C 0.5105(16) 1.0661(14) 0.8250(6) 0.067(5) Uani 1 1 d . . .
H80A H 0.518717 1.126438 0.834762 0.100 Uiso 1 1 calc GR . .
H80B H 0.561060 1.056960 0.840642 0.100 Uiso 1 1 calc GR . .
H80C H 0.449966 1.019023 0.832918 0.100 Uiso 1 1 calc GR . .
C81 C 0.4810(9) 1.1627(9) 0.6217(4) 0.029(3) Uani 1 1 d . . .
C82 C 0.5395(9) 1.2440(8) 0.6277(5) 0.029(3) Uani 1 1 d . . .
C83 C 0.7283(9) 1.4124(9) 0.6359(5) 0.036(3) Uani 1 1 d . . .
H83 H 0.751703 1.374099 0.652799 0.043 Uiso 1 1 calc R . .
C84 C 0.7473(11) 1.4059(11) 0.5871(5) 0.043(4) Uani 1 1 d . . .
H84A H 0.730465 1.446072 0.569125 0.065 Uiso 1 1 calc GR . .
H84B H 0.709849 1.342809 0.574136 0.065 Uiso 1 1 calc GR . .
H84C H 0.814025 1.424502 0.586156 0.065 Uiso 1 1 calc GR . .
C85 C 0.7893(13) 1.5111(12) 0.6581(8) 0.078(7) Uani 1 1 d . . .
H85A H 0.855044 1.524269 0.662744 0.117 Uiso 1 1 calc GR . .
H85B H 0.767920 1.516674 0.687718 0.117 Uiso 1 1 calc GR . .
H85C H 0.783297 1.554516 0.637773 0.117 Uiso 1 1 calc GR . .
C86 C 0.5369(11) 1.4241(9) 0.6198(6) 0.042(4) Uani 1 1 d . . .
H86 H 0.469004 1.381814 0.621504 0.051 Uiso 1 1 calc R . .
C87 C 0.5480(14) 1.4374(11) 0.5687(6) 0.057(5) Uani 1 1 d . . .
H87A H 0.508022 1.463083 0.556188 0.086 Uiso 1 1 calc GR . .
H87B H 0.529379 1.378471 0.552315 0.086 Uiso 1 1 calc GR . .
H87C H 0.613548 1.479280 0.564989 0.086 Uiso 1 1 calc GR . .
C88 C 0.5576(15) 1.5142(11) 0.6459(7) 0.060(5) Uani 1 1 d . . .
H88A H 0.623936 1.558196 0.645836 0.091 Uiso 1 1 calc GR . .
H88B H 0.543035 1.502728 0.677663 0.091 Uiso 1 1 calc GR . .
H88C H 0.518790 1.538995 0.630972 0.091 Uiso 1 1 calc GR . .
C89 C 0.5952(10) 1.3677(9) 0.7114(5) 0.038(3) Uani 1 1 d . . .
H89 H 0.625432 1.433233 0.723046 0.045 Uiso 1 1 calc R . .
C90 C 0.4923(11) 1.3254(10) 0.7218(6) 0.047(4) Uani 1 1 d . . .
H90A H 0.459189 1.261302 0.710085 0.071 Uiso 1 1 calc GR . .
H90B H 0.462250 1.358693 0.706921 0.071 Uiso 1 1 calc GR . .
H90C H 0.490156 1.329450 0.755034 0.071 Uiso 1 1 calc GR . .
C91 C 0.6496(14) 1.3252(12) 0.7370(5) 0.055(5) Uani 1 1 d . . .
H91A H 0.639851 1.324217 0.769548 0.083 Uiso 1 1 calc GR . .
H91B H 0.716500 1.361386 0.733780 0.083 Uiso 1 1 calc GR . .
H91C H 0.627240 1.262709 0.724068 0.083 Uiso 1 1 calc GR . .
C92 C 0.2435(11) 0.8117(9) 0.4317(5) 0.035(3) Uani 1 1 d . . .
C93 C 0.1887(9) 0.7687(8) 0.3852(4) 0.026(3) Uani 1 1 d . . .
C94 C 0.0912(11) 0.7166(10) 0.3827(5) 0.042(4) Uani 1 1 d . . .
H94 H 0.060413 0.707920 0.409694 0.050 Uiso 1 1 calc R . .
C95 C 0.0396(11) 0.6773(10) 0.3404(5) 0.041(3) Uani 1 1 d . . .
C96 C -0.0644(12) 0.6187(13) 0.3363(7) 0.064(5) Uani 1 1 d . . .
H96A H -0.083867 0.598167 0.366533 0.096 Uiso 1 1 calc GR . .
H96B H -0.082142 0.565520 0.315015 0.096 Uiso 1 1 calc GR . .
H96C H -0.095320 0.653799 0.324794 0.096 Uiso 1 1 calc GR . .
C97 C 0.0885(12) 0.6923(12) 0.3022(5) 0.047(4) Uani 1 1 d . . .
H97 H 0.056219 0.665223 0.272927 0.056 Uiso 1 1 calc R . .
C98 C 0.1826(10) 0.7457(10) 0.3070(5) 0.040(3) Uani 1 1 d . . .
H98 H 0.214345 0.757619 0.280257 0.048 Uiso 1 1 calc R . .
C99 C 0.5871(9) 1.2533(9) 0.4607(5) 0.031(3) Uani 1 1 d . . .
C100 C 0.6185(9) 1.3195(9) 0.4234(4) 0.030(3) Uani 1 1 d . . .
C101 C 0.6393(10) 1.4073(9) 0.4322(5) 0.034(3) Uani 1 1 d . . .
H101 H 0.632417 1.426980 0.461638 0.041 Uiso 1 1 calc R . .
C102 C 0.6708(11) 1.4698(9) 0.3984(5) 0.037(3) Uani 1 1 d . . .
C103 C 0.7006(13) 1.5702(10) 0.4082(6) 0.052(4) Uani 1 1 d . . .
H10G H 0.672328 1.577918 0.435135 0.078 Uiso 1 1 calc GR . .
H10H H 0.679604 1.593216 0.381647 0.078 Uiso 1 1 calc GR . .
H10I H 0.769005 1.604185 0.414230 0.078 Uiso 1 1 calc GR . .
C104 C 0.6787(11) 1.4376(9) 0.3565(5) 0.041(4) Uani 1 1 d . . .
H104 H 0.701732 1.477784 0.332808 0.049 Uiso 1 1 calc R . .
C105 C 0.6528(11) 1.3453(9) 0.3490(5) 0.037(3) Uani 1 1 d . . .
H105 H 0.654503 1.322629 0.319243 0.044 Uiso 1 1 calc R . .
C106 C 1.0430(12) 1.4183(10) -0.0720(5) 0.040(3) Uani 1 1 d . . .
H106 H 1.102537 1.436984 -0.086278 0.048 Uiso 1 1 calc R . .
C107 C 0.752(2) 0.7114(17) -0.2657(8) 0.117(12) Uani 1 1 d . . .
H10D H 0.796996 0.775881 -0.257922 0.176 Uiso 1 1 calc GR . .
H10E H 0.688507 0.701813 -0.263408 0.176 Uiso 1 1 calc GR . .
H10F H 0.757697 0.694305 -0.297079 0.176 Uiso 1 1 calc GR . .
C108 C 0.2759(9) 0.8934(8) 0.6015(4) 0.025(3) Uani 1 1 d . . .
C109 C 0.2066(9) 0.8205(9) 0.5890(4) 0.028(3) Uani 1 1 d . . .
C110 C 0.0194(10) 0.7162(10) 0.5290(5) 0.038(3) Uani 1 1 d . . .
H110 H 0.042160 0.701005 0.501079 0.045 Uiso 1 1 calc R . .
C111 C -0.0837(11) 0.6430(12) 0.5287(6) 0.051(4) Uani 1 1 d . . .
H11D H -0.111832 0.658916 0.553378 0.077 Uiso 1 1 calc GR . .
H11E H -0.086592 0.583584 0.533380 0.077 Uiso 1 1 calc GR . .
H11F H -0.118331 0.640032 0.499104 0.077 Uiso 1 1 calc GR . .
C112 C 0.0276(13) 0.8121(11) 0.5233(7) 0.056(5) Uani 1 1 d . . .
H11G H -0.010999 0.810430 0.495388 0.084 Uiso 1 1 calc GR . .
H11H H 0.093187 0.856216 0.521034 0.084 Uiso 1 1 calc GR . .
H11I H 0.005847 0.830324 0.549936 0.084 Uiso 1 1 calc GR . .
C113 C 0.1317(9) 0.6203(9) 0.5673(5) 0.035(3) Uani 1 1 d . . .
H113 H 0.183122 0.629735 0.591599 0.042 Uiso 1 1 calc R . .
C114 C 0.0504(12) 0.5227(10) 0.5711(7) 0.053(4) Uani 1 1 d . . .
H11J H -0.005133 0.514053 0.551161 0.080 Uiso 1 1 calc GR . .
H11K H 0.035582 0.514968 0.602916 0.080 Uiso 1 1 calc GR . .
H11L H 0.069531 0.477452 0.561541 0.080 Uiso 1 1 calc GR . .
C115 C 0.1712(10) 0.6274(9) 0.5214(5) 0.039(3) Uani 1 1 d . . .
H11M H 0.197648 0.585318 0.519121 0.058 Uiso 1 1 calc GR . .
H11N H 0.220327 0.689961 0.519071 0.058 Uiso 1 1 calc GR . .
H11O H 0.120878 0.611516 0.496434 0.058 Uiso 1 1 calc GR . .
C116 C 0.0399(11) 0.6937(11) 0.6340(5) 0.050(4) Uani 1 1 d . . .
H116 H -0.019027 0.634246 0.628893 0.060 Uiso 1 1 calc R . .
C117 C 0.0103(15) 0.7660(15) 0.6451(7) 0.075(6) Uani 1 1 d . . .
H11P H -0.004654 0.762780 0.676905 0.113 Uiso 1 1 calc GR . .
H11Q H -0.045064 0.755210 0.624398 0.113 Uiso 1 1 calc GR . .
H11R H 0.061693 0.826592 0.641126 0.113 Uiso 1 1 calc GR . .
C118 C 0.1011(15) 0.6827(16) 0.6735(6) 0.080(7) Uani 1 1 d . . .
H11S H 0.149977 0.742949 0.686074 0.120 Uiso 1 1 calc GR . .
H11T H 0.130321 0.647199 0.662167 0.120 Uiso 1 1 calc GR . .
H11U H 0.062152 0.650788 0.697653 0.120 Uiso 1 1 calc GR . .
Cl1C Cl 0.7162(4) 0.4488(3) 0.23204(14) 0.0590(12) Uani 1 1 d . . .
N1 N 0.7876(8) 0.6766(8) 0.0908(4) 0.035(3) Uani 1 1 d . . .
N2 N 0.9280(9) 1.1995(8) 0.1400(4) 0.042(3) Uani 1 1 d . . .
N3 N 0.2335(8) 0.7827(8) 0.3476(4) 0.034(3) Uani 1 1 d . . .
N4 N 0.6255(7) 1.2875(7) 0.3823(4) 0.028(2) Uani 1 1 d . . .
O5 O 0.8895(7) 0.8083(7) 0.0333(3) 0.043(2) Uani 1 1 d . . .
O6 O 0.7789(9) 0.7333(8) -0.0244(4) 0.058(3) Uani 1 1 d . . .
O7 O 0.9088(9) 1.1922(9) 0.0185(4) 0.054(3) Uani 1 1 d . . .
O8 O 0.9877(7) 1.1431(7) 0.0657(3) 0.037(2) Uani 1 1 d . . .
O9 O 0.3311(7) 0.8464(6) 0.4344(3) 0.038(2) Uani 1 1 d . . .
O10 O 0.1974(7) 0.8142(7) 0.4619(3) 0.043(3) Uani 1 1 d . . .
O11 O 0.5637(8) 1.2796(7) 0.4949(3) 0.043(2) Uani 1 1 d . . .
O12 O 0.5876(6) 1.1787(6) 0.4549(3) 0.030(2) Uani 1 1 d . . .
O1C O 0.7839(15) 0.4238(16) 0.2467(9) 0.133(8) Uani 1 1 d . . .
O2C O 0.6285(11) 0.3870(10) 0.2465(5) 0.082(4) Uani 1 1 d . . .
O3C O 0.7447(14) 0.5364(10) 0.2506(8) 0.111(7) Uani 1 1 d . . .
O4C O 0.7042(18) 0.4474(14) 0.1849(6) 0.138(9) Uani 1 1 d . . .
Si1 Si 0.7395(3) 0.6636(2) -0.17489(13) 0.0335(8) Uani 1 1 d . . .
Si2 Si 0.9436(3) 1.3348(2) -0.11427(13) 0.0325(8) Uani 1 1 d . . .
Si3 Si 0.6598(3) 0.9243(3) 0.01443(15) 0.0428(10) Uani 1 1 d . . .
Si4 Si 0.8744(3) 0.8944(3) 0.24264(12) 0.0294(8) Uani 1 1 d . . .
Si5 Si 0.7427(3) 0.8858(3) 0.53856(13) 0.0298(8) Uani 1 1 d . . .
Si6 Si 0.5283(3) 0.9597(3) 0.75247(12) 0.0309(8) Uani 1 1 d . . .
Si7 Si 0.6028(3) 1.3665(2) 0.64760(13) 0.0298(8) Uani 1 1 d . . .
Si8 Si 0.0966(2) 0.7115(2) 0.57952(12) 0.0274(7) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ag6 Ag1 Ag2 73.58(4) 2_775 .
C1 Ag1 Ag2 40.9(3) . .
C1 Ag1 Ag6 106.6(3) . 2_775
C1 Ag1 C34 108.1(5) . 2_775
C1 Ag1 O8 91.3(4) . 2_775
C34 Ag1 Ag2 67.5(4) 2_775 .
C34 Ag1 Ag6 43.2(3) 2_775 2_775
C34 Ag1 O8 103.1(4) 2_775 2_775
N2 Ag1 Ag2 165.3(3) 2_775 .
N2 Ag1 Ag6 100.4(3) 2_775 2_775
N2 Ag1 C1 133.5(4) 2_775 .
N2 Ag1 C34 117.5(5) 2_775 2_775
N2 Ag1 O8 70.5(4) 2_775 2_775
O8 Ag1 Ag2 95.1(2) 2_775 .
O8 Ag1 Ag6 59.9(2) 2_775 2_775
Ag1 Ag2 Ag7 88.56(5) . 2_775
Ag3 Ag2 Ag1 67.34(4) . .
Ag3 Ag2 Ag7 121.99(6) . 2_775
Ag5 Ag2 Ag1 121.37(6) . .
Ag5 Ag2 Ag3 81.82(6) . .
Ag5 Ag2 Ag7 66.85(4) . 2_775
C1 Ag2 Ag1 47.8(4) . .
C1 Ag2 Ag3 50.0(3) . .
C1 Ag2 Ag5 131.7(3) . .
C1 Ag2 Ag7 136.3(4) . 2_775
C12 Ag2 Ag1 137.3(4) . .
C12 Ag2 Ag3 131.3(4) . .
C12 Ag2 Ag5 49.7(4) . .
C12 Ag2 Ag7 48.8(4) . 2_775
C12 Ag2 C1 174.5(6) . .
Ag2 Ag3 Ag4 81.09(7) . .
Ag4 Ag3 Ag2 91.11(8) 2_775 .
Ag4 Ag3 Ag4 14.18(9) 2_775 .
C1 Ag3 Ag2 43.9(3) . .
C1 Ag3 Ag4 124.2(4) . 2_775
C1 Ag3 Ag4 119.7(3) . .
C1 Ag3 C23 127.5(5) . .
C23 Ag3 Ag2 84.7(3) . .
C23 Ag3 Ag4 50.1(4) . 2_775
C23 Ag3 Ag4 39.5(4) . .
O6 Ag3 Ag2 164.0(3) . .
O6 Ag3 Ag4 102.4(3) . 2_775
O6 Ag3 Ag4 110.6(3) . .
O6 Ag3 C1 128.8(4) . .
O6 Ag3 C23 97.4(4) . .
Ag3 Ag4 Ag3 165.81(9) 2_775 .
Ag3 Ag4 Ag6 95.44(9) 2_775 2_775
Ag3 Ag4 Ag6 94.15(8) 2_775 .
Ag3 Ag4 Ag5 81.68(8) 2_775 2_775
Ag4 Ag4 Ag3 121.4(3) 2_775 2_775
Ag4 Ag4 Ag3 44.4(3) 2_775 .
Ag4 Ag4 Ag6 73.6(3) 2_775 2_775
Ag4 Ag4 Ag6 88.0(3) 2_775 .
Ag4 Ag4 Ag5 40.7(3) 2_775 2_775
Ag4 Ag4 Ag5 125.8(3) 2_775 .
Ag4 Ag4 C23 71.6(5) 2_775 2_775
Ag4 Ag4 C23 83.0(5) 2_775 .
Ag6 Ag4 Ag3 86.03(7) . .
Ag6 Ag4 Ag3 80.87(6) 2_775 .
Ag6 Ag4 Ag6 161.66(9) . 2_775
Ag6 Ag4 Ag5 83.93(7) 2_775 2_775
Ag6 Ag4 Ag5 82.04(7) . 2_775
Ag5 Ag4 Ag3 84.31(7) 2_775 .
Ag5 Ag4 Ag3 82.33(8) . .
Ag5 Ag4 Ag3 111.57(10) . 2_775
Ag5 Ag4 Ag6 91.74(8) . 2_775
Ag5 Ag4 Ag6 99.22(9) . .
Ag5 Ag4 Ag5 166.45(9) . 2_775
C23 Ag4 Ag3 140.5(4) . 2_775
C23 Ag4 Ag3 109.2(4) 2_775 .
C23 Ag4 Ag3 48.1(4) . .
C23 Ag4 Ag3 59.2(4) 2_775 2_775
C23 Ag4 Ag6 53.1(4) . .
C23 Ag4 Ag6 124.0(4) 2_775 .
C23 Ag4 Ag6 50.5(3) 2_775 2_775
C23 Ag4 Ag6 122.5(4) . 2_775
C23 Ag4 Ag5 61.3(4) . .
C23 Ag4 Ag5 48.5(4) 2_775 2_775
C23 Ag4 Ag5 110.5(4) . 2_775
C23 Ag4 Ag5 135.3(4) 2_775 .
C23 Ag4 C23 154.6(2) . 2_775
Ag1 Ag6 Ag7 94.13(5) 2_775 .
Ag4 Ag6 Ag1 94.88(6) . 2_775
Ag4 Ag6 Ag1 108.00(7) 2_775 2_775
Ag4 Ag6 Ag4 18.34(9) . 2_775
Ag4 Ag6 Ag7 108.48(7) . .
Ag4 Ag6 Ag7 94.28(6) 2_775 .
C23 Ag6 Ag1 127.7(4) . 2_775
C23 Ag6 Ag4 46.4(4) . 2_775
C23 Ag6 Ag4 45.9(4) . .
C23 Ag6 Ag7 126.6(4) . .
C23 Ag6 C24 30.0(5) . .
C24 Ag6 Ag1 134.2(4) . 2_775
C24 Ag6 Ag4 75.8(4) . 2_775
C24 Ag6 Ag4 75.5(4) . .
C24 Ag6 Ag7 131.5(4) . .
C34 Ag6 Ag1 52.5(4) . 2_775
C34 Ag6 Ag4 131.5(4) . 2_775
C34 Ag6 Ag4 132.5(4) . .
C34 Ag6 Ag7 51.8(4) . .
C34 Ag6 C23 177.9(6) . .
C34 Ag6 C24 151.8(6) . .
Ag2 Ag5 Ag4 81.03(7) . 2_775
Ag4 Ag5 Ag2 93.34(8) . .
Ag4 Ag5 Ag4 13.55(9) . 2_775
C12 Ag5 Ag2 44.0(4) . .
C12 Ag5 Ag4 128.5(4) . .
C12 Ag5 Ag4 119.8(4) . 2_775
C12 Ag5 C23 127.3(5) . .
C23 Ag5 Ag2 84.9(3) . .
C23 Ag5 Ag4 48.5(4) . .
C23 Ag5 Ag4 42.0(4) . 2_775
O7 Ag5 Ag2 161.8(3) . .
O7 Ag5 Ag4 110.9(3) . 2_775
O7 Ag5 Ag4 100.2(3) . .
O7 Ag5 C12 128.8(5) . .
O7 Ag5 C23 95.0(5) . .
Ag6 Ag7 Ag2 73.51(4) . 2_775
C12 Ag7 Ag2 40.8(3) 2_775 2_775
C12 Ag7 Ag6 106.3(3) 2_775 .
C12 Ag7 C34 108.1(5) 2_775 .
C12 Ag7 O5 91.5(4) 2_775 .
C34 Ag7 Ag2 67.7(4) . 2_775
C34 Ag7 Ag6 43.2(3) . .
C34 Ag7 O5 102.5(4) . .
N1 Ag7 Ag2 162.8(3) . 2_775
N1 Ag7 Ag6 103.7(3) . .
N1 Ag7 C12 128.7(5) . 2_775
N1 Ag7 C34 122.2(5) . .
N1 Ag7 O5 69.7(4) . .
O5 Ag7 Ag2 95.1(2) . 2_775
O5 Ag7 Ag6 59.3(2) . .
Ag12 Ag8 Ag14 58.18(3) 2_676 2_676
Ag13 Ag8 Ag12 79.73(4) 2_676 2_676
Ag13 Ag8 Ag14 83.75(4) 2_676 2_676
C70 Ag8 Ag12 73.8(3) 2_676 2_676
C70 Ag8 Ag13 43.0(3) 2_676 2_676
C70 Ag8 Ag14 114.0(3) 2_676 2_676
C70 Ag8 C81 113.1(5) 2_676 2_676
C70 Ag8 C82 141.1(4) 2_676 2_676
C70 Ag8 O9 103.0(4) 2_676 .
C81 Ag8 Ag12 39.7(3) 2_676 2_676
C81 Ag8 Ag13 111.7(3) 2_676 2_676
C81 Ag8 Ag14 44.1(3) 2_676 2_676
C81 Ag8 C82 28.4(4) 2_676 2_676
C81 Ag8 O9 97.4(4) 2_676 .
C82 Ag8 Ag12 68.1(3) 2_676 2_676
C82 Ag8 Ag13 132.1(3) 2_676 2_676
C82 Ag8 Ag14 49.5(3) 2_676 2_676
N3 Ag8 Ag12 170.5(3) . 2_676
N3 Ag8 Ag13 100.3(3) . 2_676
N3 Ag8 Ag14 112.3(3) . 2_676
N3 Ag8 C70 112.8(4) . 2_676
N3 Ag8 C81 134.1(4) . 2_676
N3 Ag8 C82 106.0(4) . 2_676
N3 Ag8 O9 70.5(4) . .
O9 Ag8 Ag12 101.8(2) . 2_676
O9 Ag8 Ag13 60.3(2) . 2_676
O9 Ag8 Ag14 53.6(2) . 2_676
O9 Ag8 C82 92.1(4) . 2_676
Ag10 Ag9 Ag10 180.0 2_676 .
Ag10 Ag9 Ag14 91.76(3) 2_676 .
Ag10 Ag9 Ag14 88.24(3) . .
Ag10 Ag9 Ag14 88.24(3) 2_676 2_676
Ag10 Ag9 Ag14 91.76(3) . 2_676
Ag13 Ag9 Ag10 84.05(3) . 2_676
Ag13 Ag9 Ag10 95.95(3) 2_676 2_676
Ag13 Ag9 Ag10 95.95(3) . .
Ag13 Ag9 Ag10 84.05(3) 2_676 .
Ag13 Ag9 Ag13 180.0 . 2_676
Ag13 Ag9 Ag14 91.57(3) 2_676 2_676
Ag13 Ag9 Ag14 91.57(3) . .
Ag13 Ag9 Ag14 88.43(3) 2_676 .
Ag13 Ag9 Ag14 88.43(3) . 2_676
Ag14 Ag9 Ag14 180.0 . 2_676
C59 Ag9 Ag10 51.8(3) . 2_676
C59 Ag9 Ag10 128.2(3) 2_676 2_676
C59 Ag9 Ag10 128.2(3) . .
C59 Ag9 Ag10 51.8(3) 2_676 .
C59 Ag9 Ag13 128.1(3) 2_676 .
C59 Ag9 Ag13 128.1(3) . 2_676
C59 Ag9 Ag13 51.9(3) 2_676 2_676
C59 Ag9 Ag13 51.9(3) . .
C59 Ag9 Ag14 126.0(3) 2_676 2_676
C59 Ag9 Ag14 54.0(3) . 2_676
C59 Ag9 Ag14 126.0(3) . .
C59 Ag9 Ag14 54.0(3) 2_676 .
C59 Ag9 C59 180.0 2_676 .
Ag9 Ag10 Ag12 82.95(3) . .
C59 Ag10 Ag9 43.5(3) 2_676 .
C59 Ag10 Ag12 78.0(3) 2_676 .
C59 Ag10 C109 145.1(4) 2_676 .
C108 Ag10 Ag9 118.0(3) . .
C108 Ag10 Ag12 42.1(3) . .
C108 Ag10 C59 119.3(4) . 2_676
C108 Ag10 C109 28.9(4) . .
C109 Ag10 Ag9 142.0(3) . .
C109 Ag10 Ag12 70.8(3) . .
O10 Ag10 Ag9 112.2(3) . .
O10 Ag10 Ag12 159.2(3) . .
O10 Ag10 C59 102.8(4) . 2_676
O10 Ag10 C108 129.0(4) . .
O10 Ag10 C109 101.0(4) . .
Ag12 Ag11 Ag13 84.57(4) . .
C70 Ag11 Ag12 79.7(3) . .
C70 Ag11 Ag13 42.8(3) . .
C70 Ag11 C71 26.9(4) . .
C70 Ag11 C108 124.2(4) . .
C70 Ag11 O12 102.9(4) . 2_676
C71 Ag11 Ag12 83.7(3) . .
C71 Ag11 Ag13 69.5(3) . .
C108 Ag11 Ag12 44.6(3) . .
C108 Ag11 Ag13 118.2(3) . .
C108 Ag11 C71 121.6(4) . .
C108 Ag11 O12 91.5(4) . 2_676
N4 Ag11 Ag12 161.3(3) 2_676 .
N4 Ag11 Ag13 102.3(3) 2_676 .
N4 Ag11 C70 117.2(4) 2_676 .
N4 Ag11 C71 115.0(4) 2_676 .
N4 Ag11 C108 118.4(4) 2_676 .
N4 Ag11 O12 69.8(3) 2_676 2_676
O12 Ag11 Ag12 99.8(2) 2_676 .
O12 Ag11 Ag13 60.2(2) 2_676 .
O12 Ag11 C71 128.8(4) 2_676 .
Ag10 Ag12 Ag8 120.24(4) . 2_676
Ag10 Ag12 Ag14 84.79(4) . .
Ag11 Ag12 Ag8 83.79(4) . 2_676
Ag11 Ag12 Ag10 70.14(4) . .
Ag11 Ag12 Ag14 119.24(4) . .
Ag14 Ag12 Ag8 62.45(3) . 2_676
C81 Ag12 Ag8 46.5(4) . 2_676
C81 Ag12 Ag10 131.2(4) . .
C81 Ag12 Ag11 130.3(4) . .
C81 Ag12 Ag14 46.5(3) . .
C81 Ag12 C108 176.2(5) . .
C108 Ag12 Ag8 137.2(3) . 2_676
C108 Ag12 Ag10 49.2(3) . .
C108 Ag12 Ag11 53.4(3) . .
C108 Ag12 Ag14 133.9(3) . .
Ag8 Ag13 Ag11 84.09(4) 2_676 .
Ag9 Ag13 Ag8 96.21(4) . 2_676
Ag9 Ag13 Ag11 94.29(4) . .
C59 Ag13 Ag8 127.1(3) . 2_676
C59 Ag13 Ag9 45.5(3) . .
C59 Ag13 Ag11 125.2(3) . .
C59 Ag13 C60 30.3(4) . .
C60 Ag13 Ag8 141.3(3) . 2_676
C60 Ag13 Ag9 75.6(3) . .
C60 Ag13 Ag11 133.6(3) . .
C70 Ag13 Ag8 49.5(4) . 2_676
C70 Ag13 Ag9 126.9(4) . .
C70 Ag13 Ag11 50.2(4) . .
C70 Ag13 C59 172.3(5) . .
C70 Ag13 C60 157.2(5) . .
Ag9 Ag14 Ag8 88.43(4) . 2_676
Ag9 Ag14 Ag12 80.93(4) . .
Ag12 Ag14 Ag8 59.37(3) . 2_676
C59 Ag14 Ag8 118.3(3) 2_676 2_676
C59 Ag14 Ag9 42.9(3) 2_676 .
C59 Ag14 Ag12 74.7(3) 2_676 .
C59 Ag14 C82 141.8(4) 2_676 .
C81 Ag14 Ag8 44.9(3) . 2_676
C81 Ag14 Ag9 115.1(3) . .
C81 Ag14 Ag12 40.3(3) . .
C81 Ag14 C59 114.2(4) . 2_676
C81 Ag14 C82 28.7(4) . .
C82 Ag14 Ag8 50.1(3) . 2_676
C82 Ag14 Ag9 137.1(3) . .
C82 Ag14 Ag12 69.0(3) . .
O11 Ag14 Ag8 135.0(3) . 2_676
O11 Ag14 Ag9 106.5(3) . .
O11 Ag14 Ag12 162.7(3) . .
O11 Ag14 C59 99.8(4) . 2_676
O11 Ag14 C81 138.0(4) . .
O11 Ag14 C82 111.3(4) . .
Ag2 C1 Ag1 91.3(5) . .
Ag2 C1 Ag3 86.1(5) . .
Ag3 C1 Ag1 94.8(5) . .
C2 C1 Ag1 94.1(11) . .
C2 C1 Ag2 173.2(13) . .
C2 C1 Ag3 97.6(10) . .
C1 C2 Si1 169.6(13) . .
C4 C3 H3 106.8 . .
C4 C3 Si1 109.9(15) . .
C107 C3 H3 106.8 . .
C107 C3 C4 113(2) . .
C107 C3 Si1 113.6(18) . .
Si1 C3 H3 106.8 . .
C3 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
C3 C4 H4C 109.5 . .
H4A C4 H4B 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C7 C6 H6 105.6 . .
C7 C6 C8 110(2) . .
C7 C6 Si1 115.1(19) . .
C8 C6 H6 105.6 . .
C8 C6 Si1 113.8(13) . .
Si1 C6 H6 105.6 . .
C6 C7 H7A 109.5 . .
C6 C7 H7B 109.5 . .
C6 C7 H7C 109.5 . .
H7A C7 H7B 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C6 C8 H8A 109.5 . .
C6 C8 H8B 109.5 . .
C6 C8 H8C 109.5 . .
H8A C8 H8B 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C10 C9 H9 105.6 . .
C10 C9 C11 111.8(19) . .
C10 C9 Si1 118.2(16) . .
C11 C9 H9 105.6 . .
C11 C9 Si1 109.0(16) . .
Si1 C9 H9 105.6 . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10B 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C9 C11 H11A 109.5 . .
C9 C11 H11B 109.5 . .
C9 C11 H11C 109.5 . .
H11A C11 H11B 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
Ag2 C12 Ag5 86.3(5) . .
Ag2 C12 Ag7 90.5(5) . 2_775
Ag5 C12 Ag7 93.3(5) . 2_775
C13 C12 Ag2 175.5(13) . .
C13 C12 Ag5 97.4(10) . .
C13 C12 Ag7 92.0(10) . 2_775
C12 C13 Si2 170.6(13) . .
H15A C15 H15B 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C106 C15 H15A 109.5 . .
C106 C15 H15B 109.5 . .
C106 C15 H15C 109.5 . .
H16A C16 H16B 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C106 C16 H16A 109.5 . .
C106 C16 H16B 109.5 . .
C106 C16 H16C 109.5 . .
C18 C17 H17 106.9 . .
C18 C17 Si2 110.8(12) . .
C19 C17 H17 106.9 . .
C19 C17 C18 112.1(15) . .
C19 C17 Si2 112.9(12) . .
Si2 C17 H17 106.9 . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18B 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C17 C19 H19A 109.5 . .
C17 C19 H19B 109.5 . .
C17 C19 H19C 109.5 . .
H19A C19 H19B 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C21 C20 H20 106.5 . .
C21 C20 C22 111.3(15) . .
C21 C20 Si2 111.8(10) . .
C22 C20 H20 106.5 . .
C22 C20 Si2 113.7(12) . .
Si2 C20 H20 106.5 . .
C20 C21 H21A 109.5 . .
C20 C21 H21B 109.5 . .
C20 C21 H21C 109.5 . .
H21A C21 H21B 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C20 C22 H22A 109.5 . .
C20 C22 H22B 109.5 . .
C20 C22 H22C 109.5 . .
H22A C22 H22B 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
Ag4 C23 Ag3 70.8(5) 2_775 .
Ag4 C23 Ag3 92.4(6) . .
Ag4 C23 Ag4 25.4(2) . 2_775
Ag4 C23 Ag6 81.0(5) . .
Ag4 C23 Ag6 83.1(5) 2_775 .
Ag4 C23 Ag5 89.5(5) 2_775 .
Ag4 C23 Ag5 70.2(4) . .
Ag6 C23 Ag3 123.7(7) . .
Ag6 C23 Ag5 122.7(6) . .
Ag5 C23 Ag3 106.4(5) . .
C24 C23 Ag3 109.0(12) . .
C24 C23 Ag4 156.3(13) . 2_775
C24 C23 Ag4 155.7(12) . .
C24 C23 Ag6 77.7(9) . .
C24 C23 Ag5 112.5(12) . .
C23 C24 Ag6 72.3(10) . .
C23 C24 Si3 170.6(14) . .
Si3 C24 Ag6 115.6(7) . .
C26 C25 H25 106.0 . .
C26 C25 Si3 112.4(14) . .
C27 C25 H25 106.0 . .
C27 C25 C26 118(2) . .
C27 C25 Si3 107.7(15) . .
Si3 C25 H25 106.0 . .
C25 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
H26A C26 H26B 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C25 C27 H27A 109.5 . .
C25 C27 H27B 109.5 . .
C25 C27 H27C 109.5 . .
H27A C27 H27B 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
C29 C28 H28 106.6 . .
C29 C28 Si3 108.9(12) . .
C30 C28 H28 106.6 . .
C30 C28 C29 110.4(17) . .
C30 C28 Si3 117.1(12) . .
Si3 C28 H28 106.6 . .
C28 C29 H29A 109.5 . .
C28 C29 H29B 109.5 . .
C28 C29 H29C 109.5 . .
H29A C29 H29B 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C28 C30 H30A 109.5 . .
C28 C30 H30B 109.5 . .
C28 C30 H30C 109.5 . .
H30A C30 H30B 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C32 C31 H31 105.4 . .
C32 C31 C33 110.9(17) . .
C32 C31 Si3 113.2(15) . .
C33 C31 H31 105.4 . .
C33 C31 Si3 115.4(13) . .
Si3 C31 H31 105.4 . .
C31 C32 H32A 109.5 . .
C31 C32 H32B 109.5 . .
C31 C32 H32C 109.5 . .
H32A C32 H32B 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
C31 C33 H33A 109.5 . .
C31 C33 H33B 109.5 . .
C31 C33 H33C 109.5 . .
H33A C33 H33B 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
Ag6 C34 Ag1 84.3(5) . 2_775
Ag6 C34 Ag7 85.0(5) . .
Ag7 C34 Ag1 134.9(7) . 2_775
C35 C34 Ag1 106.4(10) . 2_775
C35 C34 Ag6 166.3(13) . .
C35 C34 Ag7 92.8(10) . .
C34 C35 Si4 174.7(13) . .
C37 C36 H36 107.5 . .
C37 C36 C38 111.7(14) . .
C37 C36 Si4 111.9(11) . .
C38 C36 H36 107.5 . .
C38 C36 Si4 110.4(11) . .
Si4 C36 H36 107.5 . .
C36 C37 H37A 109.5 . .
C36 C37 H37B 109.5 . .
C36 C37 H37C 109.5 . .
H37A C37 H37B 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
C36 C38 H38A 109.5 . .
C36 C38 H38B 109.5 . .
C36 C38 H38C 109.5 . .
H38A C38 H38B 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
C40 C39 H39 105.3 . .
C40 C39 C41 113.3(14) . .
C40 C39 Si4 115.0(11) . .
C41 C39 H39 105.3 . .
C41 C39 Si4 111.6(11) . .
Si4 C39 H39 105.3 . .
C39 C40 H40A 109.5 . .
C39 C40 H40B 109.5 . .
C39 C40 H40C 109.5 . .
H40A C40 H40B 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
C39 C41 H41A 109.5 . .
C39 C41 H41B 109.5 . .
C39 C41 H41C 109.5 . .
H41A C41 H41B 109.5 . .
H41A C41 H41C 109.5 . .
H41B C41 H41C 109.5 . .
C43 C42 H42 106.8 . .
C43 C42 C44 111.5(13) . .
C43 C42 Si4 113.3(11) . .
C44 C42 H42 106.8 . .
C44 C42 Si4 111.3(11) . .
Si4 C42 H42 106.8 . .
C42 C43 H43A 109.5 . .
C42 C43 H43B 109.5 . .
C42 C43 H43C 109.5 . .
H43A C43 H43B 109.5 . .
H43A C43 H43C 109.5 . .
H43B C43 H43C 109.5 . .
C42 C44 H44A 109.5 . .
C42 C44 H44B 109.5 . .
C42 C44 H44C 109.5 . .
H44A C44 H44B 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
O5 C45 C46 118.4(13) . .
O6 C45 C46 117.6(14) . .
O6 C45 O5 123.9(14) . .
C47 C46 C45 117.7(15) . .
N1 C46 C45 119.9(13) . .
N1 C46 C47 122.3(15) . .
C46 C47 H47 119.7 . .
C46 C47 C48 120.5(18) . .
C48 C47 H47 119.7 . .
C47 C48 C49 123(2) . .
C47 C48 C50 116.4(18) . .
C50 C48 C49 121(2) . .
C48 C49 H49A 109.5 . .
C48 C49 H49B 109.5 . .
C48 C49 H49C 109.5 . .
H49A C49 H49B 109.5 . .
H49A C49 H49C 109.5 . .
H49B C49 H49C 109.5 . .
C48 C50 H50 119.7 . .
C51 C50 C48 120.7(17) . .
C51 C50 H50 119.7 . .
C50 C51 H51 119.2 . .
N1 C51 C50 121.7(16) . .
N1 C51 H51 119.2 . .
O7 C52 C53 115.6(13) . .
O8 C52 C53 119.6(13) . .
O8 C52 O7 124.8(13) . .
C54 C53 C52 118.8(14) . .
N2 C53 C52 118.8(13) . .
N2 C53 C54 122.4(14) . .
C53 C54 H54 120.0 . .
C55 C54 C53 120.0(18) . .
C55 C54 H54 120.0 . .
C54 C55 C56 121(2) . .
C57 C55 C54 118.3(18) . .
C57 C55 C56 120.8(18) . .
C55 C56 H56A 109.5 . .
C55 C56 H56B 109.5 . .
C55 C56 H56C 109.5 . .
H56A C56 H56B 109.5 . .
H56A C56 H56C 109.5 . .
H56B C56 H56C 109.5 . .
C55 C57 H57 120.6 . .
C55 C57 C58 118.8(16) . .
C58 C57 H57 120.6 . .
C57 C58 H58 118.1 . .
N2 C58 C57 123.8(17) . .
N2 C58 H58 118.1 . .
Ag9 C59 Ag10 84.7(4) . 2_676
Ag9 C59 Ag13 82.6(4) . .
Ag9 C59 Ag14 83.1(4) . 2_676
Ag10 C59 Ag14 120.4(4) 2_676 2_676
Ag13 C59 Ag10 115.6(5) . 2_676
Ag13 C59 Ag14 120.1(5) . 2_676
C60 C59 Ag9 162.1(10) . .
C60 C59 Ag10 108.4(9) . 2_676
C60 C59 Ag13 80.8(7) . .
C60 C59 Ag14 99.7(9) . 2_676
C59 C60 Ag13 69.0(7) . .
C59 C60 Si5 173.7(11) . .
Si5 C60 Ag13 116.4(6) . .
C62 C61 H61 105.4 . .
C62 C61 Si5 110.9(13) . .
C63 C61 H61 105.4 . .
C63 C61 C62 110.2(18) . .
C63 C61 Si5 118.5(14) . .
Si5 C61 H61 105.4 . .
C61 C62 H62A 109.5 . .
C61 C62 H62B 109.5 . .
C61 C62 H62C 109.5 . .
H62A C62 H62B 109.5 . .
H62A C62 H62C 109.5 . .
H62B C62 H62C 109.5 . .
C61 C63 H63A 109.5 . .
C61 C63 H63B 109.5 . .
C61 C63 H63C 109.5 . .
H63A C63 H63B 109.5 . .
H63A C63 H63C 109.5 . .
H63B C63 H63C 109.5 . .
C65 C64 H64 106.7 . .
C65 C64 Si5 111.8(10) . .
C66 C64 H64 106.7 . .
C66 C64 C65 112.3(15) . .
C66 C64 Si5 112.2(11) . .
Si5 C64 H64 106.7 . .
C64 C65 H65A 109.5 . .
C64 C65 H65B 109.5 . .
C64 C65 H65C 109.5 . .
H65A C65 H65B 109.5 . .
H65A C65 H65C 109.5 . .
H65B C65 H65C 109.5 . .
C64 C66 H66A 109.5 . .
C64 C66 H66B 109.5 . .
C64 C66 H66C 109.5 . .
H66A C66 H66B 109.5 . .
H66A C66 H66C 109.5 . .
H66B C66 H66C 109.5 . .
C68 C67 H67 104.2 . .
C68 C67 C69 109.8(16) . .
C68 C67 Si5 115.8(14) . .
C69 C67 H67 104.2 . .
C69 C67 Si5 116.9(13) . .
Si5 C67 H67 104.2 . .
C67 C68 H68A 109.5 . .
C67 C68 H68B 109.5 . .
C67 C68 H68C 109.5 . .
H68A C68 H68B 109.5 . .
H68A C68 H68C 109.5 . .
H68B C68 H68C 109.5 . .
C67 C69 H69A 109.5 . .
C67 C69 H69B 109.5 . .
C67 C69 H69C 109.5 . .
H69A C69 H69B 109.5 . .
H69A C69 H69C 109.5 . .
H69B C69 H69C 109.5 . .
Ag8 C70 Ag11 122.1(6) 2_676 .
Ag13 C70 Ag8 87.5(5) . 2_676
Ag13 C70 Ag11 87.0(5) . .
C71 C70 Ag8 101.5(10) . 2_676
C71 C70 Ag11 91.3(10) . .
C71 C70 Ag13 170.3(12) . .
C70 C71 Ag11 61.8(9) . .
C70 C71 Si6 172.4(12) . .
Si6 C71 Ag11 123.3(6) . .
C73 C72 H72 107.8 . .
C73 C72 Si6 108.8(12) . .
C74 C72 H72 107.8 . .
C74 C72 C73 111.6(16) . .
C74 C72 Si6 112.8(13) . .
Si6 C72 H72 107.8 . .
C72 C73 H73A 109.5 . .
C72 C73 H73B 109.5 . .
C72 C73 H73C 109.5 . .
H73A C73 H73B 109.5 . .
H73A C73 H73C 109.5 . .
H73B C73 H73C 109.5 . .
C72 C74 H74A 109.5 . .
C72 C74 H74B 109.5 . .
C72 C74 H74C 109.5 . .
H74A C74 H74B 109.5 . .
H74A C74 H74C 109.5 . .
H74B C74 H74C 109.5 . .
C76 C75 H75 105.8 . .
C76 C75 Si6 113.6(12) . .
C77 C75 H75 105.8 . .
C77 C75 C76 110.5(14) . .
C77 C75 Si6 114.3(10) . .
Si6 C75 H75 105.8 . .
C75 C76 H76A 109.5 . .
C75 C76 H76B 109.5 . .
C75 C76 H76C 109.5 . .
H76A C76 H76B 109.5 . .
H76A C76 H76C 109.5 . .
H76B C76 H76C 109.5 . .
C75 C77 H77A 109.5 . .
C75 C77 H77B 109.5 . .
C75 C77 H77C 109.5 . .
H77A C77 H77B 109.5 . .
H77A C77 H77C 109.5 . .
H77B C77 H77C 109.5 . .
C79 C78 H78 105.1 . .
C79 C78 Si6 116.2(11) . .
C80 C78 H78 105.1 . .
C80 C78 C79 110.6(15) . .
C80 C78 Si6 113.6(13) . .
Si6 C78 H78 105.1 . .
C78 C79 H79A 109.5 . .
C78 C79 H79B 109.5 . .
C78 C79 H79C 109.5 . .
H79A C79 H79B 109.5 . .
H79A C79 H79C 109.5 . .
H79B C79 H79C 109.5 . .
C78 C80 H80A 109.5 . .
C78 C80 H80B 109.5 . .
C78 C80 H80C 109.5 . .
H80A C80 H80B 109.5 . .
H80A C80 H80C 109.5 . .
H80B C80 H80C 109.5 . .
Ag12 C81 Ag8 93.8(5) . 2_676
Ag12 C81 Ag14 93.2(5) . .
Ag14 C81 Ag8 91.0(4) . 2_676
C82 C81 Ag8 86.7(9) . 2_676
C82 C81 Ag12 179.4(12) . .
C82 C81 Ag14 86.9(9) . .
Ag14 C82 Ag8 80.4(3) . 2_676
C81 C82 Ag8 64.8(8) . 2_676
C81 C82 Ag14 64.4(8) . .
C81 C82 Si7 163.4(11) . .
Si7 C82 Ag8 124.2(7) . 2_676
Si7 C82 Ag14 128.2(6) . .
C84 C83 H83 105.4 . .
C84 C83 C85 110.8(13) . .
C84 C83 Si7 117.6(11) . .
C85 C83 H83 105.4 . .
C85 C83 Si7 111.1(10) . .
Si7 C83 H83 105.4 . .
C83 C84 H84A 109.5 . .
C83 C84 H84B 109.5 . .
C83 C84 H84C 109.5 . .
H84A C84 H84B 109.5 . .
H84A C84 H84C 109.5 . .
H84B C84 H84C 109.5 . .
C83 C85 H85A 109.5 . .
C83 C85 H85B 109.5 . .
C83 C85 H85C 109.5 . .
H85A C85 H85B 109.5 . .
H85A C85 H85C 109.5 . .
H85B C85 H85C 109.5 . .
C87 C86 H86 105.9 . .
C87 C86 C88 110.8(13) . .
C87 C86 Si7 114.2(11) . .
C88 C86 H86 105.9 . .
C88 C86 Si7 113.2(12) . .
Si7 C86 H86 105.9 . .
C86 C87 H87A 109.5 . .
C86 C87 H87B 109.5 . .
C86 C87 H87C 109.5 . .
H87A C87 H87B 109.5 . .
H87A C87 H87C 109.5 . .
H87B C87 H87C 109.5 . .
C86 C88 H88A 109.5 . .
C86 C88 H88B 109.5 . .
C86 C88 H88C 109.5 . .
H88A C88 H88B 109.5 . .
H88A C88 H88C 109.5 . .
H88B C88 H88C 109.5 . .
C90 C89 H89 106.5 . .
C90 C89 Si7 110.9(10) . .
C91 C89 H89 106.5 . .
C91 C89 C90 112.7(13) . .
C91 C89 Si7 113.1(10) . .
Si7 C89 H89 106.5 . .
C89 C90 H90A 109.5 . .
C89 C90 H90B 109.5 . .
C89 C90 H90C 109.5 . .
H90A C90 H90B 109.5 . .
H90A C90 H90C 109.5 . .
H90B C90 H90C 109.5 . .
C89 C91 H91A 109.5 . .
C89 C91 H91B 109.5 . .
C89 C91 H91C 109.5 . .
H91A C91 H91B 109.5 . .
H91A C91 H91C 109.5 . .
H91B C91 H91C 109.5 . .
O9 C92 C93 117.6(12) . .
O10 C92 C93 115.8(13) . .
O10 C92 O9 126.4(14) . .
C94 C93 C92 118.7(12) . .
N3 C93 C92 120.0(12) . .
N3 C93 C94 121.3(12) . .
C93 C94 H94 120.2 . .
C95 C94 C93 119.7(14) . .
C95 C94 H94 120.2 . .
C94 C95 C96 121.6(15) . .
C97 C95 C94 117.5(15) . .
C97 C95 C96 120.9(15) . .
C95 C96 H96A 109.5 . .
C95 C96 H96B 109.5 . .
C95 C96 H96C 109.5 . .
H96A C96 H96B 109.5 . .
H96A C96 H96C 109.5 . .
H96B C96 H96C 109.5 . .
C95 C97 H97 120.2 . .
C98 C97 C95 119.5(15) . .
C98 C97 H97 120.2 . .
C97 C98 H98 118.2 . .
N3 C98 C97 123.6(14) . .
N3 C98 H98 118.2 . .
O11 C99 C100 115.6(12) . .
O11 C99 O12 126.0(13) . .
O12 C99 C100 118.5(12) . .
C101 C100 C99 120.1(12) . .
N4 C100 C99 117.5(12) . .
N4 C100 C101 122.4(13) . .
C100 C101 H101 119.6 . .
C100 C101 C102 120.7(13) . .
C102 C101 H101 119.6 . .
C101 C102 C103 121.9(14) . .
C104 C102 C101 117.2(13) . .
C104 C102 C103 120.9(13) . .
C102 C103 H10G 109.5 . .
C102 C103 H10H 109.5 . .
C102 C103 H10I 109.5 . .
H10G C103 H10H 109.5 . .
H10G C103 H10I 109.5 . .
H10H C103 H10I 109.5 . .
C102 C104 H104 120.3 . .
C102 C104 C105 119.4(13) . .
C105 C104 H104 120.3 . .
C104 C105 H105 118.9 . .
N4 C105 C104 122.1(13) . .
N4 C105 H105 118.9 . .
C15 C106 H106 107.6 . .
C15 C106 Si2 109.7(11) . .
C16 C106 C15 109.0(12) . .
C16 C106 H106 107.6 . .
C16 C106 Si2 115.1(11) . .
Si2 C106 H106 107.6 . .
C3 C107 H10D 109.5 . .
C3 C107 H10E 109.5 . .
C3 C107 H10F 109.5 . .
H10D C107 H10E 109.5 . .
H10D C107 H10F 109.5 . .
H10E C107 H10F 109.5 . .
Ag10 C108 Ag11 94.5(4) . .
Ag12 C108 Ag10 88.7(4) . .
Ag12 C108 Ag11 82.0(4) . .
C109 C108 Ag10 84.0(9) . .
C109 C108 Ag11 107.8(9) . .
C109 C108 Ag12 168.2(11) . .
C108 C109 Ag10 67.0(8) . .
C108 C109 Si8 170.8(11) . .
Si8 C109 Ag10 122.0(6) . .
C111 C110 H110 106.1 . .
C111 C110 C112 111.3(13) . .
C111 C110 Si8 112.6(11) . .
C112 C110 H110 106.1 . .
C112 C110 Si8 113.9(11) . .
Si8 C110 H110 106.1 . .
C110 C111 H11D 109.5 . .
C110 C111 H11E 109.5 . .
C110 C111 H11F 109.5 . .
H11D C111 H11E 109.5 . .
H11D C111 H11F 109.5 . .
H11E C111 H11F 109.5 . .
C110 C112 H11G 109.5 . .
C110 C112 H11H 109.5 . .
C110 C112 H11I 109.5 . .
H11G C112 H11H 109.5 . .
H11G C112 H11I 109.5 . .
H11H C112 H11I 109.5 . .
C114 C113 H113 106.8 . .
C114 C113 Si8 112.3(10) . .
C115 C113 H113 106.8 . .
C115 C113 C114 110.6(12) . .
C115 C113 Si8 113.0(10) . .
Si8 C113 H113 106.8 . .
C113 C114 H11J 109.5 . .
C113 C114 H11K 109.5 . .
C113 C114 H11L 109.5 . .
H11J C114 H11K 109.5 . .
H11J C114 H11L 109.5 . .
H11K C114 H11L 109.5 . .
C113 C115 H11M 109.5 . .
C113 C115 H11N 109.5 . .
C113 C115 H11O 109.5 . .
H11M C115 H11N 109.5 . .
H11M C115 H11O 109.5 . .
H11N C115 H11O 109.5 . .
C117 C116 H116 106.4 . .
C117 C116 C118 113.4(16) . .
C117 C116 Si8 112.7(13) . .
C118 C116 H116 106.4 . .
C118 C116 Si8 110.9(12) . .
Si8 C116 H116 106.4 . .
C116 C117 H11P 109.5 . .
C116 C117 H11Q 109.5 . .
C116 C117 H11R 109.5 . .
H11P C117 H11Q 109.5 . .
H11P C117 H11R 109.5 . .
H11Q C117 H11R 109.5 . .
C116 C118 H11S 109.5 . .
C116 C118 H11T 109.5 . .
C116 C118 H11U 109.5 . .
H11S C118 H11T 109.5 . .
H11S C118 H11U 109.5 . .
H11T C118 H11U 109.5 . .
O1C Cl1C O2C 110.1(11) . .
O1C Cl1C O3C 108.1(15) . .
O3C Cl1C O2C 110.5(11) . .
O4C Cl1C O1C 111.6(16) . .
O4C Cl1C O2C 107.4(12) . .
O4C Cl1C O3C 109.2(13) . .
C46 N1 Ag7 117.4(9) . .
C46 N1 C51 118.4(13) . .
C51 N1 Ag7 124.2(10) . .
C53 N2 Ag1 115.8(9) . 2_775
C53 N2 C58 116.5(14) . .
C58 N2 Ag1 127.3(12) . 2_775
C93 N3 Ag8 116.5(9) . .
C93 N3 C98 118.4(12) . .
C98 N3 Ag8 125.1(10) . .
C100 N4 Ag11 117.9(9) . 2_676
C100 N4 C105 118.1(12) . .
C105 N4 Ag11 123.9(9) . 2_676
C45 O5 Ag7 113.7(9) . .
C45 O6 Ag3 115.5(11) . .
C52 O7 Ag5 116.2(10) . .
C52 O8 Ag1 113.8(8) . 2_775
C92 O9 Ag8 113.8(9) . .
C92 O10 Ag10 107.3(10) . .
C99 O11 Ag14 111.9(9) . .
C99 O12 Ag11 114.5(8) . 2_676
C2 Si1 C3 106.2(7) . .
C2 Si1 C9 109.1(7) . .
C3 Si1 C9 117.2(11) . .
C6 Si1 C2 105.9(7) . .
C6 Si1 C3 108.1(10) . .
C6 Si1 C9 109.7(11) . .
C13 Si2 C17 107.5(7) . .
C13 Si2 C20 104.7(6) . .
C13 Si2 C106 110.2(7) . .
C17 Si2 C20 110.4(7) . .
C17 Si2 C106 112.3(7) . .
C106 Si2 C20 111.3(7) . .
C24 Si3 C25 102.7(8) . .
C24 Si3 C28 109.7(8) . .
C24 Si3 C31 105.0(8) . .
C25 Si3 C28 113.0(9) . .
C25 Si3 C31 112.3(9) . .
C28 Si3 C31 113.2(8) . .
C35 Si4 C36 107.3(7) . .
C35 Si4 C39 107.6(7) . .
C35 Si4 C42 107.4(6) . .
C36 Si4 C39 111.0(7) . .
C42 Si4 C36 111.6(7) . .
C42 Si4 C39 111.6(7) . .
C60 Si5 C61 106.5(7) . .
C60 Si5 C64 106.0(6) . .
C61 Si5 C64 109.7(8) . .
C67 Si5 C60 106.5(7) . .
C67 Si5 C61 115.9(9) . .
C67 Si5 C64 111.5(7) . .
C71 Si6 C72 106.0(7) . .
C71 Si6 C75 108.2(7) . .
C71 Si6 C78 106.7(7) . .
C75 Si6 C72 110.7(8) . .
C75 Si6 C78 116.4(7) . .
C78 Si6 C72 108.3(8) . .
C82 Si7 C83 108.1(6) . .
C82 Si7 C86 107.9(7) . .
C82 Si7 C89 104.4(6) . .
C83 Si7 C86 116.2(7) . .
C83 Si7 C89 110.0(7) . .
C89 Si7 C86 109.5(7) . .
C109 Si8 C110 110.1(6) . .
C109 Si8 C113 106.4(6) . .
C109 Si8 C116 106.7(6) . .
C110 Si8 C113 110.1(7) . .
C116 Si8 C110 112.2(7) . .
C116 Si8 C113 111.0(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 Ag2 3.1771(16) .
Ag1 Ag6 3.0297(17) 2_775
Ag1 C1 2.355(15) .
Ag1 C34 2.414(14) 2_775
Ag1 N2 2.335(13) 2_775
Ag1 O8 2.457(9) 2_775
Ag2 Ag3 2.9934(18) .
Ag2 Ag5 2.9811(18) .
Ag2 Ag7 3.1795(16) 2_775
Ag2 C1 2.081(13) .
Ag2 C12 2.076(14) .
Ag3 Ag4 2.686(3) 2_775
Ag3 Ag4 3.277(3) .
Ag3 C1 2.297(13) .
Ag3 C23 2.443(15) .
Ag3 O6 2.235(12) .
Ag4 Ag4 0.941(5) 2_775
Ag4 Ag6 2.989(3) 2_775
Ag4 Ag6 2.870(3) .
Ag4 Ag5 3.260(3) 2_775
Ag4 Ag5 2.619(3) .
Ag4 C23 2.181(16) 2_775
Ag4 C23 2.085(16) .
Ag6 Ag7 3.0322(17) .
Ag6 C23 2.325(13) .
Ag6 C24 2.384(16) .
Ag6 C34 2.084(13) .
Ag5 C12 2.279(14) .
Ag5 C23 2.443(15) .
Ag5 O7 2.231(12) .
Ag7 C12 2.392(14) 2_775
Ag7 C34 2.392(14) .
Ag7 N1 2.321(11) .
Ag7 O5 2.504(10) .
Ag8 Ag12 3.2287(16) 2_676
Ag8 Ag13 3.0687(15) 2_676
Ag8 Ag14 3.3267(17) 2_676
Ag8 C70 2.337(14) 2_676
Ag8 C81 2.348(13) 2_676
Ag8 C82 2.590(13) 2_676
Ag8 N3 2.314(12) .
Ag8 O9 2.501(10) .
Ag9 Ag10 3.0279(13) .
Ag9 Ag10 3.0278(13) 2_676
Ag9 Ag13 2.9099(11) 2_676
Ag9 Ag13 2.9099(11) .
Ag9 Ag14 3.0505(13) 2_676
Ag9 Ag14 3.0505(13) .
Ag9 C59 2.092(11) 2_676
Ag9 C59 2.092(11) .
Ag10 Ag12 3.0870(14) .
Ag10 C59 2.389(13) 2_676
Ag10 C108 2.336(12) .
Ag10 C109 2.524(13) .
Ag10 O10 2.290(10) .
Ag11 Ag12 2.9243(15) .
Ag11 Ag13 3.0755(15) .
Ag11 C70 2.366(14) .
Ag11 C71 2.684(13) .
Ag11 C108 2.371(13) .
Ag11 N4 2.319(11) 2_676
Ag11 O12 2.477(9) 2_676
Ag12 Ag14 3.1881(15) .
Ag12 C81 2.065(13) .
Ag12 C108 2.072(12) .
Ag13 C59 2.309(10) .
Ag13 C60 2.442(11) .
Ag13 C70 2.094(13) .
Ag14 C59 2.487(12) 2_676
Ag14 C81 2.316(13) .
Ag14 C82 2.564(13) .
Ag14 O11 2.247(10) .
C1 C2 1.200(19) .
C2 Si1 1.878(15) .
C3 H3 1.0000 .
C3 C4 1.57(3) .
C3 C107 1.44(3) .
C3 Si1 1.886(17) .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C6 H6 1.0000 .
C6 C7 1.47(3) .
C6 C8 1.53(3) .
C6 Si1 1.874(18) .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 H9 1.0000 .
C9 C10 1.44(3) .
C9 C11 1.58(3) .
C9 Si1 1.90(2) .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 C13 1.209(19) .
C13 Si2 1.875(14) .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C15 C106 1.55(2) .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C16 C106 1.50(2) .
C17 H17 1.0000 .
C17 C18 1.53(2) .
C17 C19 1.52(2) .
C17 Si2 1.886(17) .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 H20 1.0000 .
C20 C21 1.51(2) .
C20 C22 1.55(2) .
C20 Si2 1.888(15) .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 C24 1.22(2) .
C24 Si3 1.868(18) .
C25 H25 1.0000 .
C25 C26 1.58(3) .
C25 C27 1.55(3) .
C25 Si3 1.873(17) .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
C28 H28 1.0000 .
C28 C29 1.56(3) .
C28 C30 1.49(3) .
C28 Si3 1.904(16) .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
C31 H31 1.0000 .
C31 C32 1.44(3) .
C31 C33 1.53(3) .
C31 Si3 1.929(19) .
C32 H32A 0.9800 .
C32 H32B 0.9800 .
C32 H32C 0.9800 .
C33 H33A 0.9800 .
C33 H33B 0.9800 .
C33 H33C 0.9800 .
C34 C35 1.230(19) .
C35 Si4 1.848(14) .
C36 H36 1.0000 .
C36 C37 1.51(2) .
C36 C38 1.56(2) .
C36 Si4 1.890(15) .
C37 H37A 0.9800 .
C37 H37B 0.9800 .
C37 H37C 0.9800 .
C38 H38A 0.9800 .
C38 H38B 0.9800 .
C38 H38C 0.9800 .
C39 H39 1.0000 .
C39 C40 1.50(2) .
C39 C41 1.54(2) .
C39 Si4 1.920(15) .
C40 H40A 0.9800 .
C40 H40B 0.9800 .
C40 H40C 0.9800 .
C41 H41A 0.9800 .
C41 H41B 0.9800 .
C41 H41C 0.9800 .
C42 H42 1.0000 .
C42 C43 1.51(2) .
C42 C44 1.55(2) .
C42 Si4 1.890(15) .
C43 H43A 0.9800 .
C43 H43B 0.9800 .
C43 H43C 0.9800 .
C44 H44A 0.9800 .
C44 H44B 0.9800 .
C44 H44C 0.9800 .
C45 C46 1.49(2) .
C45 O5 1.269(18) .
C45 O6 1.248(18) .
C46 C47 1.38(2) .
C46 N1 1.326(19) .
C47 H47 0.9500 .
C47 C48 1.39(3) .
C48 C49 1.49(3) .
C48 C50 1.39(3) .
C49 H49A 0.9800 .
C49 H49B 0.9800 .
C49 H49C 0.9800 .
C50 H50 0.9500 .
C50 C51 1.37(2) .
C51 H51 0.9500 .
C51 N1 1.354(18) .
C52 C53 1.507(19) .
C52 O7 1.263(18) .
C52 O8 1.246(17) .
C53 C54 1.40(2) .
C53 N2 1.33(2) .
C54 H54 0.9500 .
C54 C55 1.39(2) .
C55 C56 1.52(3) .
C55 C57 1.35(3) .
C56 H56A 0.9800 .
C56 H56B 0.9800 .
C56 H56C 0.9800 .
C57 H57 0.9500 .
C57 C58 1.39(3) .
C58 H58 0.9500 .
C58 N2 1.356(19) .
C59 C60 1.246(17) .
C60 Si5 1.868(13) .
C61 H61 1.0000 .
C61 C62 1.58(3) .
C61 C63 1.45(3) .
C61 Si5 1.885(16) .
C62 H62A 0.9800 .
C62 H62B 0.9800 .
C62 H62C 0.9800 .
C63 H63A 0.9800 .
C63 H63B 0.9800 .
C63 H63C 0.9800 .
C64 H64 1.0000 .
C64 C65 1.53(2) .
C64 C66 1.51(2) .
C64 Si5 1.896(14) .
C65 H65A 0.9800 .
C65 H65B 0.9800 .
C65 H65C 0.9800 .
C66 H66A 0.9800 .
C66 H66B 0.9800 .
C66 H66C 0.9800 .
C67 H67 1.0000 .
C67 C68 1.49(3) .
C67 C69 1.52(2) .
C67 Si5 1.851(18) .
C68 H68A 0.9800 .
C68 H68B 0.9800 .
C68 H68C 0.9800 .
C69 H69A 0.9800 .
C69 H69B 0.9800 .
C69 H69C 0.9800 .
C70 C71 1.215(18) .
C71 Si6 1.856(13) .
C72 H72 1.0000 .
C72 C73 1.60(3) .
C72 C74 1.48(3) .
C72 Si6 1.893(16) .
C73 H73A 0.9800 .
C73 H73B 0.9800 .
C73 H73C 0.9800 .
C74 H74A 0.9800 .
C74 H74B 0.9800 .
C74 H74C 0.9800 .
C75 H75 1.0000 .
C75 C76 1.53(2) .
C75 C77 1.52(2) .
C75 Si6 1.869(14) .
C76 H76A 0.9800 .
C76 H76B 0.9800 .
C76 H76C 0.9800 .
C77 H77A 0.9800 .
C77 H77B 0.9800 .
C77 H77C 0.9800 .
C78 H78 1.0000 .
C78 C79 1.52(3) .
C78 C80 1.51(2) .
C78 Si6 1.885(17) .
C79 H79A 0.9800 .
C79 H79B 0.9800 .
C79 H79C 0.9800 .
C80 H80A 0.9800 .
C80 H80B 0.9800 .
C80 H80C 0.9800 .
C81 C82 1.234(18) .
C82 Si7 1.852(12) .
C83 H83 1.0000 .
C83 C84 1.50(2) .
C83 C85 1.56(2) .
C83 Si7 1.877(13) .
C84 H84A 0.9800 .
C84 H84B 0.9800 .
C84 H84C 0.9800 .
C85 H85A 0.9800 .
C85 H85B 0.9800 .
C85 H85C 0.9800 .
C86 H86 1.0000 .
C86 C87 1.53(2) .
C86 C88 1.54(2) .
C86 Si7 1.889(17) .
C87 H87A 0.9800 .
C87 H87B 0.9800 .
C87 H87C 0.9800 .
C88 H88A 0.9800 .
C88 H88B 0.9800 .
C88 H88C 0.9800 .
C89 H89 1.0000 .
C89 C90 1.54(2) .
C89 C91 1.53(2) .
C89 Si7 1.886(14) .
C90 H90A 0.9800 .
C90 H90B 0.9800 .
C90 H90C 0.9800 .
C91 H91A 0.9800 .
C91 H91B 0.9800 .
C91 H91C 0.9800 .
C92 C93 1.523(19) .
C92 O9 1.255(17) .
C92 O10 1.218(17) .
C93 C94 1.40(2) .
C93 N3 1.334(17) .
C94 H94 0.9500 .
C94 C95 1.39(2) .
C95 C96 1.50(2) .
C95 C97 1.39(2) .
C96 H96A 0.9800 .
C96 H96B 0.9800 .
C96 H96C 0.9800 .
C97 H97 0.9500 .
C97 C98 1.35(2) .
C98 H98 0.9500 .
C98 N3 1.343(18) .
C99 C100 1.516(19) .
C99 O11 1.241(17) .
C99 O12 1.250(16) .
C100 C101 1.348(19) .
C100 N4 1.339(17) .
C101 H101 0.9500 .
C101 C102 1.399(19) .
C102 C103 1.517(19) .
C102 C104 1.37(2) .
C103 H10G 0.9800 .
C103 H10H 0.9800 .
C103 H10I 0.9800 .
C104 H104 0.9500 .
C104 C105 1.39(2) .
C105 H105 0.9500 .
C105 N4 1.339(17) .
C106 H106 1.0000 .
C106 Si2 1.887(16) .
C107 H10D 0.9800 .
C107 H10E 0.9800 .
C107 H10F 0.9800 .
C108 C109 1.227(18) .
C109 Si8 1.849(13) .
C110 H110 1.0000 .
C110 C111 1.54(2) .
C110 C112 1.55(2) .
C110 Si8 1.885(15) .
C111 H11D 0.9800 .
C111 H11E 0.9800 .
C111 H11F 0.9800 .
C112 H11G 0.9800 .
C112 H11H 0.9800 .
C112 H11I 0.9800 .
C113 H113 1.0000 .
C113 C114 1.556(19) .
C113 C115 1.52(2) .
C113 Si8 1.887(14) .
C114 H11J 0.9800 .
C114 H11K 0.9800 .
C114 H11L 0.9800 .
C115 H11M 0.9800 .
C115 H11N 0.9800 .
C115 H11O 0.9800 .
C116 H116 1.0000 .
C116 C117 1.52(3) .
C116 C118 1.53(3) .
C116 Si8 1.872(15) .
C117 H11P 0.9800 .
C117 H11Q 0.9800 .
C117 H11R 0.9800 .
C118 H11S 0.9800 .
C118 H11T 0.9800 .
C118 H11U 0.9800 .
Cl1C O1C 1.384(18) .
Cl1C O2C 1.421(15) .
Cl1C O3C 1.386(15) .
Cl1C O4C 1.379(17) .
