#------------------------------------------------------------------------------
#$Date: 2020-02-04 22:31:26 +0200 (Tue, 04 Feb 2020) $
#$Revision: 247707 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/30/7703008.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7703008
loop_
_publ_author_name
'Xu, Hui'
'Liu, Xing-Man'
'Su, Tan'
'Chen, Wei-Chao'
'Su, Zhong-Min'
_publ_section_title
;
 Two Ni/Co-substituted sandwich-type germanomolybdates based on an
 unprecedented trivacant polyanion
 [α-GeMo₁₀O₃₆]⁸.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              977
_journal_page_last               982
_journal_paper_doi               10.1039/c9dt04433g
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety
'Co4 Ge2 H4 Mo20 O74, C12 H36 Co3 N24 O6, 11(H2 O)'
_chemical_formula_sum            'C12 H62 Co7 Ge2 Mo20 N24 O91'
_chemical_formula_weight         4475.39
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_date             2019-10-21
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2019-10-28 deposited with the CCDC.	2019-12-17 downloaded from the CCDC.
;
_cell_angle_alpha                110.550(4)
_cell_angle_beta                 98.559(4)
_cell_angle_gamma                112.651(4)
_cell_formula_units_Z            1
_cell_length_a                   13.9114(12)
_cell_length_b                   14.1874(12)
_cell_length_c                   14.6356(13)
_cell_measurement_reflns_used    9922
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      66.767
_cell_measurement_theta_min      3.414
_cell_volume                     2357.5(4)
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_collection       'APEX3 Ver. 2016.5-0 (Bruker-AXS, 2016)'
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      173.0
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'Bruker APEX II'
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0455
_diffrn_reflns_av_unetI/netI     0.0418
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            31585
_diffrn_reflns_point_group_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        66.853
_diffrn_reflns_theta_max         66.853
_diffrn_reflns_theta_min         3.415
_exptl_absorpt_coefficient_mu    32.285
_exptl_absorpt_correction_T_max  0.002
_exptl_absorpt_correction_T_min  0.001
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 (Krause et al., 2015) was used for absorption correction.
;
_exptl_crystal_colour            'orange yellow'
_exptl_crystal_colour_primary    'orange yellow'
_exptl_crystal_density_diffrn    3.152
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2123
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.2
_refine_diff_density_max         0.770
_refine_diff_density_min         -1.077
_refine_diff_density_rms         0.196
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     732
_refine_ls_number_reflns         8291
_refine_ls_number_restraints     18
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0405
_refine_ls_R_factor_gt           0.0310
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0253P)²+9.8766P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0675
_refine_ls_wR_factor_ref         0.0716
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7085
_reflns_number_total             8380
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9dt04433g2.cif
_cod_data_source_block           1_CCDC1
_cod_depositor_comments
'Adding full bibliography for 7703007--7703008.cif.'
_cod_database_code               7703008
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H,H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(O10W) \\sim Ueq, Uanis(N4) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.01
Uanis(O36) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
3. Others
 Sof(O7WA)=Sof(H7WC)=Sof(H7WD)=1-FVAR(1)
 Sof(O7W)=Sof(H7WA)=Sof(H7WB)=FVAR(1)
 Sof(O9WA)=Sof(H9WC)=Sof(H9WD)=1-FVAR(2)
 Sof(O9W)=Sof(H9WA)=Sof(H9WB)=FVAR(2)
 Fixed Sof: O10W(0.5) H10A(0.5) H10B(0.5)
4.a Riding coordinates:
 O1W(H1WA,H1WB), O5W(H5WA,H5WB), O6W(H6WA,H6WB), O7W(H7WA,H7WB), O7WA(H7WC,
 H7WD), O8W(H8WA,H8WB), O9W(H9WA,H9WB), O9WA(H9WC,H9WD), O10W(H10A,H10B)
4.b Rotating group:
 O2W(H2WA,H2WB), O3W(H3WA,H3WB), O4W(H4WA,H4WB)
4.c Aromatic/amide H refined with riding coordinates:
 C3(H3), C5(H5), C1(H1), C2(H2), C4(H4), C6(H6)
4.d X=CH2 refined with riding coordinates:
 N4(H4A,H4B), N8(H8A,H8B), N12(H12A,H12B)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Mo1 Mo 0.31728(4) -0.80508(4) 0.14492(3) 0.00870(10) Uani 1 1 d . . . . .
Mo2 Mo 0.59903(4) -0.66650(4) 0.48872(3) 0.00956(10) Uani 1 1 d . . . . .
Mo3 Mo 0.50012(4) -0.70500(3) 0.03584(3) 0.00806(10) Uani 1 1 d . . . . .
Mo4 Mo 0.77857(4) -0.70247(4) 0.10975(3) 0.00866(10) Uani 1 1 d . . . . .
Mo5 Mo 0.54345(4) -0.55191(4) 0.30476(3) 0.00941(10) Uani 1 1 d . . . . .
Mo6 Mo 0.82448(4) -0.79990(4) 0.27989(3) 0.00961(10) Uani 1 1 d . . . . .
Mo7 Mo 0.81704(4) -0.54993(4) 0.37680(3) 0.00976(10) Uani 1 1 d . . . . .
Mo8 Mo 0.61202(4) -0.91502(4) 0.38839(3) 0.00975(10) Uani 1 1 d . . . . .
Mo9 Mo 0.37302(4) -0.91801(4) 0.32603(3) 0.00950(10) Uani 1 1 d . . . . .
Mo10 Mo 0.73318(4) -0.48204(4) 0.19860(4) 0.01219(11) Uani 1 1 d . . . . .
Ge1 Ge 0.56582(5) -0.81233(5) 0.20750(5) 0.00577(13) Uani 1 1 d . . . . .
Co1 Co 0.43426(8) -1.09448(7) 0.12609(7) 0.0102(2) Uani 1 1 d . . . . .
Co2 Co 0.61620(7) -0.99871(7) 0.03170(7) 0.00890(19) Uani 1 1 d . . . . .
O1 O 0.4722(3) -0.8483(3) -0.0416(3) 0.0136(9) Uani 1 1 d . . . . .
O1W O 0.3523(4) -1.2438(3) 0.1377(3) 0.0214(10) Uani 1 1 d . . . . .
H1WA H 0.367261 -1.229705 0.201338 0.032 Uiso 1 1 d R . . . .
H1WB H 0.293311 -1.299835 0.097678 0.032 Uiso 1 1 d R . . . .
O2 O 0.6565(3) -0.6638(3) 0.0925(3) 0.0120(8) Uani 1 1 d . . . . .
O3 O 0.5719(3) -0.5379(3) 0.1692(3) 0.0131(8) Uani 1 1 d . . . . .
O4 O 0.6834(3) -0.8467(3) 0.0171(3) 0.0117(8) Uani 1 1 d . . . . .
O5 O 0.3950(3) -0.6278(3) 0.2402(3) 0.0136(9) Uani 1 1 d . . . . .
O6 O 0.4554(3) -0.7598(3) 0.4602(3) 0.0134(8) Uani 1 1 d . . . . .
O7 O 0.8986(3) -0.6236(3) 0.3720(3) 0.0141(9) Uani 1 1 d . . . . .
O8 O 0.6897(3) -0.5388(3) 0.3126(3) 0.0134(9) Uani 1 1 d . . . . .
O9 O 0.5116(3) -0.9489(3) 0.1038(3) 0.0079(8) Uani 1 1 d . . . . .
O10 O 0.6541(3) -0.7584(3) 0.5098(3) 0.0112(8) Uani 1 1 d . . . . .
O11 O 0.8383(3) -0.5348(3) 0.2378(3) 0.0135(9) Uani 1 1 d . . . . .
O12 O 0.9401(3) -0.8067(4) 0.3200(3) 0.0214(10) Uani 1 1 d . . . . .
O13 O 0.3638(3) -0.7320(3) 0.0462(3) 0.0132(8) Uani 1 1 d . . . . .
O14 O 0.5462(3) -0.8207(3) 0.3203(3) 0.0084(8) Uani 1 1 d . . . . .
O15 O 0.7411(3) -0.9304(3) 0.1681(3) 0.0147(9) Uani 1 1 d . . . . .
O16 O 0.3465(3) -1.0261(3) 0.2061(3) 0.0142(9) Uani 1 1 d . . . . .
O17 O 0.4985(3) -0.7389(3) 0.1792(3) 0.0077(8) Uani 1 1 d . . . . .
O18 O 0.3026(3) -0.9328(3) 0.0533(3) 0.0137(9) Uani 1 1 d . . . . .
O19 O 0.7518(3) -0.8267(3) 0.3717(3) 0.0135(8) Uani 1 1 d . . . . .
O20 O 0.8765(3) -0.7280(3) 0.1813(3) 0.0136(9) Uani 1 1 d . . . . .
O21 O 0.5505(3) -0.5949(3) 0.4070(3) 0.0157(9) Uani 1 1 d . . . . .
O22 O 0.5582(3) -1.0276(3) 0.2640(3) 0.0157(9) Uani 1 1 d . . . . .
O23 O 0.7413(3) -0.5919(3) 0.4580(3) 0.0141(9) Uani 1 1 d . . . . .
O24 O 0.3337(3) -0.8280(3) 0.2615(3) 0.0137(8) Uani 1 1 d . . . . .
O25 O 0.2577(3) -0.9698(4) 0.3570(3) 0.0205(10) Uani 1 1 d . . . . .
O26 O 0.5065(4) -0.6457(3) -0.0466(3) 0.0210(10) Uani 1 1 d . . . . .
O27 O 0.4668(3) -0.9519(3) 0.4034(3) 0.0120(8) Uani 1 1 d . . . . .
O28 O 0.8470(3) -0.6464(3) 0.0393(3) 0.0214(10) Uani 1 1 d . . . . .
O29 O 0.6370(3) -0.5673(3) 0.6106(3) 0.0178(9) Uani 1 1 d . . . . .
O30 O 0.1879(3) -0.8179(4) 0.1165(3) 0.0211(10) Uani 1 1 d . . . . .
O31 O 0.7879(4) -0.3460(3) 0.2924(3) 0.0211(10) Uani 1 1 d . . . . .
O32 O 0.5732(4) -0.4140(3) 0.3651(3) 0.0196(10) Uani 1 1 d . . . . .
O33 O 0.6594(3) -0.9632(3) 0.4657(3) 0.0172(9) Uani 1 1 d . . . . .
O34 O 0.7545(4) -0.4611(4) 0.0920(4) 0.0279(11) Uani 1 1 d . . . . .
O35 O 0.9107(3) -0.4113(3) 0.4535(3) 0.0200(10) Uani 1 1 d . . . . .
O36 O 0.7084(3) -0.7369(3) 0.2345(3) 0.0070(8) Uani 1 1 d . U . . .
Co3 Co 1.05557(8) 0.10760(8) 0.78985(7) 0.0164(2) Uani 1 1 d . . . . .
Co4 Co 1.000000 0.000000 0.500000 0.0107(3) Uani 1 2 d S T P . .
O2W O 0.9339(5) 0.1017(5) 0.8638(4) 0.0418(14) Uani 1 1 d . . . . .
H2WA H 0.878900 0.097557 0.826443 0.063 Uiso 1 1 d GR . . . .
H2WB H 0.964740 0.136486 0.930293 0.063 Uiso 1 1 d GR . . . .
O3W O 1.1158(4) 0.0393(4) 0.8799(4) 0.0328(12) Uani 1 1 d . . . . .
H3WA H 1.145516 0.088748 0.945505 0.049 Uiso 1 1 d GR . . . .
H3WB H 1.171319 0.029951 0.864836 0.049 Uiso 1 1 d GR . . . .
O4W O 1.1640(5) 0.2630(4) 0.9196(4) 0.0446(15) Uani 1 1 d . . . . .
H4WA H 1.135403 0.309110 0.933261 0.067 Uiso 1 1 d GR . . . .
H4WB H 1.221734 0.299542 0.905730 0.067 Uiso 1 1 d GR . . . .
N3 N 0.8197(4) -0.2348(4) 0.6063(4) 0.0135(11) Uani 1 1 d . . . . .
N10 N 0.9704(4) 0.1330(4) 0.5956(4) 0.0162(11) Uani 1 1 d . . . . .
N5 N 0.8436(4) -0.0764(4) 0.3878(4) 0.0150(11) Uani 1 1 d . . . . .
N2 N 0.9258(4) -0.1024(4) 0.5737(4) 0.0133(10) Uani 1 1 d . . . . .
N9 N 0.9892(4) 0.1729(4) 0.7006(4) 0.0168(11) Uani 1 1 d . . . . .
N7 N 0.6669(4) -0.1799(4) 0.3171(4) 0.0198(12) Uani 1 1 d . . . . .
N6 N 0.8184(4) -0.1231(4) 0.2810(4) 0.0174(11) Uani 1 1 d . . . . .
N1 N 0.9460(4) -0.0580(4) 0.6788(4) 0.0111(10) Uani 1 1 d . . . . .
N11 N 0.9288(4) 0.2708(4) 0.6471(5) 0.0238(13) Uani 1 1 d . . . . .
N4 N 0.7386(5) -0.3413(4) 0.5920(5) 0.0332(15) Uani 1 1 d . U . . .
H4A H 0.703303 -0.398532 0.529539 0.040 Uiso 1 1 calc R . . . .
H4B H 0.723406 -0.350410 0.645508 0.040 Uiso 1 1 calc R . . . .
N8 N 0.5539(4) -0.2379(5) 0.3054(5) 0.0309(14) Uani 1 1 d . . . . .
H8A H 0.504657 -0.283204 0.243252 0.037 Uiso 1 1 calc R . . . .
H8B H 0.532773 -0.228497 0.360298 0.037 Uiso 1 1 calc R . . . .
N12 N 0.8964(5) 0.3543(5) 0.6506(6) 0.0360(16) Uani 1 1 d . . . . .
H12A H 0.897291 0.400978 0.709630 0.043 Uiso 1 1 calc R . . . .
H12B H 0.875315 0.359720 0.593752 0.043 Uiso 1 1 calc R . . . .
C3 C 0.7508(5) -0.1115(5) 0.4060(5) 0.0211(14) Uani 1 1 d . . . . .
H3 H 0.743631 -0.091580 0.472835 0.025 Uiso 1 1 calc R . . . .
C5 C 0.9624(5) 0.2546(5) 0.7284(5) 0.0231(15) Uani 1 1 d . . . . .
H5 H 0.966076 0.296790 0.796727 0.028 Uiso 1 1 calc R . . . .
C1 C 0.8816(5) -0.1403(5) 0.6960(5) 0.0149(13) Uani 1 1 d . . . . .
H1 H 0.878896 -0.134261 0.762207 0.018 Uiso 1 1 calc R . . . .
C2 C 0.8499(5) -0.2105(5) 0.5315(5) 0.0168(13) Uani 1 1 d . . . . .
H2 H 0.821556 -0.262323 0.460130 0.020 Uiso 1 1 calc R . . . .
C4 C 0.7115(5) -0.1853(5) 0.2417(5) 0.0256(15) Uani 1 1 d . . . . .
H4 H 0.671075 -0.228341 0.169940 0.031 Uiso 1 1 calc R . . . .
C6 C 0.9351(5) 0.1937(5) 0.5651(5) 0.0194(14) Uani 1 1 d . . . . .
H6 H 0.916819 0.184973 0.496383 0.023 Uiso 1 1 calc R . . . .
O5W O 0.6493(6) 0.1912(5) 0.6740(4) 0.065(2) Uani 1 1 d . . . . .
H5WA H 0.682024 0.229114 0.646781 0.098 Uiso 1 1 d R . . . .
H5WB H 0.651454 0.132054 0.626611 0.098 Uiso 1 1 d R . . . .
O6W O 0.3673(6) -0.4801(6) 0.1405(6) 0.073(2) Uani 1 1 d . . . . .
H6WA H 0.304172 -0.493280 0.146505 0.110 Uiso 1 1 d R . . . .
H6WB H 0.381262 -0.514600 0.172925 0.110 Uiso 1 1 d R . . . .
O7W O 0.9681(9) 0.1407(11) 1.0617(8) 0.032(4) Uani 0.49(2) 1 d . . . A 1
H7WA H 0.942130 0.087424 1.068030 0.048 Uiso 0.49(2) 1 d R . . A 1
H7WB H 1.036360 0.177854 1.093300 0.048 Uiso 0.49(2) 1 d R . . A 1
O7WA O 1.0190(14) 0.239(2) 1.0695(10) 0.083(9) Uani 0.51(2) 1 d . . . A 2
H7WC H 0.973795 0.227842 1.102516 0.124 Uiso 0.51(2) 1 d R . . A 2
H7WD H 1.076045 0.232352 1.095906 0.124 Uiso 0.51(2) 1 d R . . A 2
O8W O 0.8854(6) -0.4156(8) 0.6916(9) 0.136(5) Uani 1 1 d . . . . .
H8WA H 0.953918 -0.392089 0.700869 0.204 Uiso 1 1 d R . . . .
H8WB H 0.849628 -0.464029 0.626559 0.204 Uiso 1 1 d R . . . .
O9W O 0.828(3) 0.478(2) 0.832(3) 0.089(10) Uani 0.48(7) 1 d . . . B 1
H9WA H 0.872783 0.549844 0.851899 0.133 Uiso 0.48(7) 1 d R . . B 1
H9WB H 0.852613 0.463724 0.881129 0.133 Uiso 0.48(7) 1 d R . . B 1
O9WA O 0.843(4) 0.543(10) 0.862(6) 0.26(3) Uani 0.52(7) 1 d . . . B 2
H9WC H 0.877567 0.504091 0.866159 0.396 Uiso 0.52(7) 1 d R . . B 2
H9WD H 0.863127 0.567881 0.818319 0.396 Uiso 0.52(7) 1 d R . . B 2
O10W O 0.9964(17) 0.4413(15) 0.9490(14) 0.125(7) Uani 0.5 1 d . U . C -1
H10A H 0.937376 0.437445 0.914319 0.187 Uiso 0.5 1 d R . . C -1
H10B H 0.980296 0.429065 1.000369 0.187 Uiso 0.5 1 d R . . C -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co -2.3653 3.6143 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge -1.0885 0.8855 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -0.0483 2.7339 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Mo1 O17 72.01(13) . .
O13 Mo1 O5 75.58(15) . .
O13 Mo1 O17 72.22(14) . .
O18 Mo1 O5 156.28(16) . .
O18 Mo1 O13 88.23(16) . .
O18 Mo1 O17 86.72(16) . .
O18 Mo1 O24 100.39(18) . .
O24 Mo1 O5 89.21(16) . .
O24 Mo1 O13 157.31(16) . .
O24 Mo1 O17 87.24(16) . .
O30 Mo1 O5 94.26(18) . .
O30 Mo1 O13 94.41(19) . .
O30 Mo1 O17 162.61(17) . .
O30 Mo1 O18 104.32(19) . .
O30 Mo1 O24 103.57(19) . .
O6 Mo2 O10 97.94(17) . .
O6 Mo2 O14 75.48(14) . .
O6 Mo2 O21 87.83(17) . .
O6 Mo2 O23 157.01(17) . .
O10 Mo2 O14 73.90(15) . .
O10 Mo2 O21 154.64(16) . .
O10 Mo2 O23 85.16(16) . .
O21 Mo2 O14 83.83(14) . .
O21 Mo2 O23 80.39(16) . .
O23 Mo2 O14 83.64(14) . .
O29 Mo2 O6 103.61(18) . .
O29 Mo2 O10 101.13(19) . .
O29 Mo2 O14 174.65(17) . .
O29 Mo2 O21 101.45(18) . .
O29 Mo2 O23 98.06(18) . .
O1 Mo3 O2 89.05(16) . .
O1 Mo3 O3 159.38(17) . .
O1 Mo3 O13 99.75(17) . .
O1 Mo3 O17 90.78(15) . .
O2 Mo3 O3 74.97(15) . .
O2 Mo3 O17 79.29(14) . .
O3 Mo3 O17 73.72(13) . .
O13 Mo3 O2 152.87(17) . .
O13 Mo3 O3 89.48(16) . .
O13 Mo3 O17 75.01(15) . .
O26 Mo3 O1 104.60(19) . .
O26 Mo3 O2 101.34(19) . .
O26 Mo3 O3 91.48(17) . .
O26 Mo3 O13 101.1(2) . .
O26 Mo3 O17 164.60(16) . .
O2 Mo4 O11 74.52(15) . .
O2 Mo4 O36 79.36(15) . .
O4 Mo4 O2 88.39(16) . .
O4 Mo4 O11 158.26(16) . .
O4 Mo4 O20 99.42(17) . .
O4 Mo4 O36 89.44(15) . .
O11 Mo4 O36 74.49(13) . .
O20 Mo4 O2 153.21(16) . .
O20 Mo4 O11 90.65(16) . .
O20 Mo4 O36 75.16(15) . .
O28 Mo4 O2 99.52(19) . .
O28 Mo4 O4 103.44(19) . .
O28 Mo4 O11 92.74(17) . .
O28 Mo4 O20 103.44(19) . .
O28 Mo4 O36 167.06(17) . .
O3 Mo5 O17 72.71(13) . .
O5 Mo5 O3 91.09(17) . .
O5 Mo5 O8 150.56(16) . .
O5 Mo5 O17 72.84(14) . .
O8 Mo5 O3 74.07(16) . .
O8 Mo5 O17 78.44(14) . .
O21 Mo5 O3 156.75(16) . .
O21 Mo5 O5 99.94(18) . .
O21 Mo5 O8 86.72(17) . .
O21 Mo5 O17 90.96(15) . .
O32 Mo5 O3 92.52(18) . .
O32 Mo5 O5 104.31(19) . .
O32 Mo5 O8 101.67(18) . .
O32 Mo5 O17 164.72(18) . .
O32 Mo5 O21 104.32(19) . .
O7 Mo6 O20 75.37(15) . .
O7 Mo6 O36 71.87(14) . .
O12 Mo6 O7 93.05(18) . .
O12 Mo6 O15 104.17(19) . .
O12 Mo6 O19 103.2(2) . .
O12 Mo6 O20 95.91(19) . .
O12 Mo6 O36 162.14(17) . .
O15 Mo6 O7 156.73(17) . .
O15 Mo6 O19 100.07(18) . .
O15 Mo6 O20 87.22(17) . .
O15 Mo6 O36 88.17(16) . .
O19 Mo6 O7 90.88(16) . .
O19 Mo6 O20 157.03(16) . .
O19 Mo6 O36 86.92(15) . .
O20 Mo6 O36 71.47(14) . .
O7 Mo7 O8 150.36(16) . .
O7 Mo7 O11 91.68(17) . .
O7 Mo7 O36 73.09(15) . .
O8 Mo7 O11 73.15(15) . .
O8 Mo7 O36 78.06(14) . .
O11 Mo7 O36 72.72(13) . .
O23 Mo7 O7 100.80(18) . .
O23 Mo7 O8 86.47(17) . .
O23 Mo7 O11 156.25(16) . .
O23 Mo7 O36 91.53(15) . .
O35 Mo7 O7 103.38(19) . .
O35 Mo7 O8 102.53(18) . .
O35 Mo7 O11 92.24(18) . .
O35 Mo7 O23 104.24(19) . .
O35 Mo7 O36 164.23(17) . .
O10 Mo8 O14 72.68(14) . .
O19 Mo8 O10 83.62(15) . .
O19 Mo8 O14 85.07(15) . .
O22 Mo8 O10 160.91(17) . .
O22 Mo8 O14 88.24(16) . .
O22 Mo8 O19 94.85(17) . .
O22 Mo8 O27 93.00(17) . .
O27 Mo8 O10 82.05(15) . .
O27 Mo8 O14 73.93(14) . .
O27 Mo8 O19 157.32(15) . .
O33 Mo8 O10 94.26(18) . .
O33 Mo8 O14 165.92(16) . .
O33 Mo8 O19 98.96(18) . .
O33 Mo8 O22 104.75(19) . .
O33 Mo8 O27 99.55(18) . .
O6 Mo9 O14 72.92(13) . .
O16 Mo9 O6 160.08(16) . .
O16 Mo9 O14 87.28(16) . .
O16 Mo9 O24 92.54(17) . .
O16 Mo9 O27 95.40(17) . .
O24 Mo9 O6 83.52(16) . .
O24 Mo9 O14 84.33(15) . .
O25 Mo9 O6 95.56(18) . .
O25 Mo9 O14 167.90(17) . .
O25 Mo9 O16 104.34(19) . .
O25 Mo9 O24 98.27(19) . .
O25 Mo9 O27 100.78(19) . .
O27 Mo9 O6 81.62(16) . .
O27 Mo9 O14 74.35(14) . .
O27 Mo9 O24 156.82(16) . .
O3 Mo10 O2 74.74(14) . .
O3 Mo10 O8 72.96(16) . .
O8 Mo10 O2 85.21(14) . .
O11 Mo10 O2 74.38(15) . .
O11 Mo10 O3 135.39(16) . .
O11 Mo10 O8 73.11(15) . .
O31 Mo10 O2 172.81(18) . .
O31 Mo10 O3 102.80(18) . .
O31 Mo10 O8 87.61(17) . .
O31 Mo10 O11 103.82(19) . .
O31 Mo10 O34 102.1(2) . .
O34 Mo10 O2 85.03(17) . .
O34 Mo10 O3 103.0(2) . .
O34 Mo10 O8 170.13(17) . .
O34 Mo10 O11 105.6(2) . .
O14 Ge1 O9 111.45(17) . .
O14 Ge1 O17 106.91(17) . .
O14 Ge1 O36 106.85(17) . .
O17 Ge1 O9 110.16(17) . .
O36 Ge1 O9 109.85(16) . .
O36 Ge1 O17 111.56(17) . .
O1W Co1 O1 95.03(16) . 2_635
O1W Co1 O4 93.24(16) . 2_635
O1W Co1 O9 176.20(17) . .
O1W Co1 O16 89.91(16) . .
O1W Co1 O22 90.87(17) . .
O4 Co1 O1 87.51(15) 2_635 2_635
O9 Co1 O1 83.60(15) . 2_635
O9 Co1 O4 83.17(15) . 2_635
O16 Co1 O1 174.94(16) . 2_635
O16 Co1 O4 91.12(15) . 2_635
O16 Co1 O9 91.40(15) . .
O22 Co1 O1 90.61(16) . 2_635
O22 Co1 O4 175.61(16) . 2_635
O22 Co1 O9 92.69(15) . .
O22 Co1 O16 90.41(16) . .
O1 Co2 O9 91.54(15) 2_635 2_635
O4 Co2 O1 172.16(16) . 2_635
O4 Co2 O9 90.55(14) . .
O4 Co2 O9 82.72(15) . 2_635
O9 Co2 O1 83.32(15) . 2_635
O9 Co2 O9 81.63(15) . 2_635
O15 Co2 O1 93.17(16) . 2_635
O15 Co2 O4 92.20(16) . .
O15 Co2 O9 173.71(15) . 2_635
O15 Co2 O9 94.77(15) . .
O18 Co2 O1 91.70(15) 2_635 2_635
O18 Co2 O4 93.82(15) 2_635 .
O18 Co2 O9 92.07(15) 2_635 2_635
O18 Co2 O9 171.83(16) 2_635 .
O18 Co2 O15 91.96(16) 2_635 .
Mo3 O1 Co1 129.0(2) . 2_635
Mo3 O1 Co2 130.9(2) . 2_635
Co2 O1 Co1 96.06(15) 2_635 2_635
Co1 O1W H1WA 109.4 . .
Co1 O1W H1WB 127.5 . .
H1WA O1W H1WB 116.7 . .
Mo3 O2 Mo4 152.5(2) . .
Mo3 O2 Mo10 103.53(16) . .
Mo4 O2 Mo10 103.78(17) . .
Mo5 O3 Mo3 111.95(16) . .
Mo10 O3 Mo3 103.18(16) . .
Mo10 O3 Mo5 104.42(18) . .
Mo4 O4 Co1 128.5(2) . 2_635
Mo4 O4 Co2 131.8(2) . .
Co2 O4 Co1 97.01(15) . 2_635
Mo5 O5 Mo1 119.19(18) . .
Mo2 O6 Mo9 119.48(19) . .
Mo7 O7 Mo6 119.80(19) . .
Mo5 O8 Mo7 149.5(2) . .
Mo5 O8 Mo10 104.93(18) . .
Mo7 O8 Mo10 105.53(17) . .
Ge1 O9 Co1 119.72(19) . .
Ge1 O9 Co2 120.23(19) . .
Ge1 O9 Co2 120.11(18) . 2_635
Co1 O9 Co2 96.48(15) . 2_635
Co1 O9 Co2 96.58(14) . .
Co2 O9 Co2 98.37(15) . 2_635
Mo2 O10 Mo8 120.1(2) . .
Mo7 O11 Mo4 110.70(16) . .
Mo10 O11 Mo4 104.17(17) . .
Mo10 O11 Mo7 104.70(17) . .
Mo3 O13 Mo1 115.7(2) . .
Mo8 O14 Mo2 92.52(13) . .
Mo8 O14 Mo9 91.77(13) . .
Mo9 O14 Mo2 91.65(12) . .
Ge1 O14 Mo2 128.41(18) . .
Ge1 O14 Mo8 121.44(18) . .
Ge1 O14 Mo9 121.51(19) . .
Mo6 O15 Co2 139.9(2) . .
Mo9 O16 Co1 137.9(2) . .
Mo1 O17 Mo3 94.16(14) . .
Mo1 O17 Mo5 94.07(12) . .
Mo3 O17 Mo5 99.03(13) . .
Ge1 O17 Mo1 122.31(18) . .
Ge1 O17 Mo3 120.51(17) . .
Ge1 O17 Mo5 120.42(18) . .
Mo1 O18 Co2 142.9(2) . 2_635
Mo6 O19 Mo8 146.4(2) . .
Mo4 O20 Mo6 116.53(18) . .
Mo5 O21 Mo2 154.9(2) . .
Mo8 O22 Co1 138.5(2) . .
Mo7 O23 Mo2 153.5(2) . .
Mo1 O24 Mo9 144.8(2) . .
Mo9 O27 Mo8 117.28(19) . .
Mo4 O36 Mo7 98.98(13) . .
Mo6 O36 Mo4 94.28(13) . .
Mo6 O36 Mo7 93.10(13) . .
Ge1 O36 Mo4 120.69(18) . .
Ge1 O36 Mo6 122.36(18) . .
Ge1 O36 Mo7 120.84(17) . .
O2W Co3 O3W 88.9(2) . .
O2W Co3 N9 89.1(2) . .
O2W Co3 N6 177.0(2) . 2_756
O3W Co3 N6 92.5(2) . 2_756
O4W Co3 O2W 86.7(2) . .
O4W Co3 O3W 82.6(2) . .
O4W Co3 N9 98.2(2) . .
O4W Co3 N6 90.8(2) . 2_756
N9 Co3 O3W 177.8(2) . .
N9 Co3 N6 89.6(2) . 2_756
N1 Co3 O2W 88.5(2) . .
N1 Co3 O3W 88.97(19) . .
N1 Co3 O4W 170.4(2) . .
N1 Co3 N9 90.05(19) . .
N1 Co3 N6 94.23(19) . 2_756
N10 Co4 N10 180.0 2_756 .
N10 Co4 N2 89.93(18) . 2_756
N10 Co4 N2 90.07(18) 2_756 2_756
N10 Co4 N2 89.93(18) 2_756 .
N10 Co4 N2 90.07(18) . .
N5 Co4 N10 89.18(18) . 2_756
N5 Co4 N10 90.82(18) . .
N5 Co4 N10 89.18(18) 2_756 .
N5 Co4 N10 90.82(18) 2_756 2_756
N5 Co4 N5 180.0 2_756 .
N5 Co4 N2 90.87(19) 2_756 .
N5 Co4 N2 90.87(19) . 2_756
N5 Co4 N2 89.13(19) . .
N5 Co4 N2 89.13(19) 2_756 2_756
N2 Co4 N2 180.0 2_756 .
Co3 O2W H2WA 110.8 . .
Co3 O2W H2WB 110.2 . .
H2WA O2W H2WB 130.6 . .
Co3 O3W H3WA 110.7 . .
Co3 O3W H3WB 111.2 . .
H3WA O3W H3WB 102.8 . .
Co3 O4W H4WA 111.1 . .
Co3 O4W H4WB 109.7 . .
H4WA O4W H4WB 102.9 . .
C1 N3 N4 127.3(5) . .
C2 N3 N4 125.5(5) . .
C2 N3 C1 107.2(5) . .
N9 N10 Co4 126.3(4) . .
C6 N10 Co4 125.8(4) . .
C6 N10 N9 107.9(5) . .
N6 N5 Co4 127.1(4) . .
C3 N5 Co4 124.0(4) . .
C3 N5 N6 107.1(5) . .
N1 N2 Co4 122.7(3) . .
C2 N2 Co4 129.2(4) . .
C2 N2 N1 107.8(5) . .
N10 N9 Co3 122.7(4) . .
C5 N9 Co3 130.7(4) . .
C5 N9 N10 106.5(5) . .
C3 N7 N8 126.7(6) . .
C4 N7 N8 127.0(6) . .
C4 N7 C3 106.3(5) . .
N5 N6 Co3 121.8(4) . 2_756
C4 N6 Co3 131.2(5) . 2_756
C4 N6 N5 106.4(5) . .
N2 N1 Co3 127.5(3) . .
C1 N1 Co3 125.9(4) . .
C1 N1 N2 106.6(5) . .
C5 N11 N12 125.3(6) . .
C5 N11 C6 106.1(5) . .
C6 N11 N12 128.6(6) . .
N3 N4 H4A 120.0 . .
N3 N4 H4B 120.0 . .
H4A N4 H4B 120.0 . .
N7 N8 H8A 120.0 . .
N7 N8 H8B 120.0 . .
H8A N8 H8B 120.0 . .
N11 N12 H12A 120.0 . .
N11 N12 H12B 120.0 . .
H12A N12 H12B 120.0 . .
N5 C3 N7 110.0(6) . .
N5 C3 H3 125.0 . .
N7 C3 H3 125.0 . .
N9 C5 N11 110.6(6) . .
N9 C5 H5 124.7 . .
N11 C5 H5 124.7 . .
N3 C1 H1 125.1 . .
N1 C1 N3 109.9(5) . .
N1 C1 H1 125.1 . .
N3 C2 H2 125.8 . .
N2 C2 N3 108.4(5) . .
N2 C2 H2 125.8 . .
N7 C4 H4 124.9 . .
N6 C4 N7 110.2(6) . .
N6 C4 H4 124.9 . .
N10 C6 N11 108.9(6) . .
N10 C6 H6 125.5 . .
N11 C6 H6 125.5 . .
H5WA O5W H5WB 86.7 . .
H6WA O6W H6WB 96.7 . .
H7WA O7W H7WB 111.7 . .
H7WC O7WA H7WD 109.6 . .
H8WA O8W H8WB 107.8 . .
H9WA O9W H9WB 104.5 . .
H9WC O9WA H9WD 104.5 . .
H10A O10W H10B 104.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Mo1 O5 2.106(4) .
Mo1 O13 2.096(4) .
Mo1 O17 2.226(4) .
Mo1 O18 1.746(4) .
Mo1 O24 1.844(4) .
Mo1 O30 1.709(4) .
Mo2 O6 1.802(4) .
Mo2 O10 1.834(4) .
Mo2 O14 2.416(4) .
Mo2 O21 2.015(4) .
Mo2 O23 2.055(4) .
Mo2 O29 1.681(4) .
Mo3 O1 1.793(4) .
Mo3 O2 1.976(4) .
Mo3 O3 2.185(4) .
Mo3 O13 1.826(4) .
Mo3 O17 2.313(4) .
Mo3 O26 1.691(4) .
Mo4 O2 1.984(4) .
Mo4 O4 1.791(4) .
Mo4 O11 2.178(4) .
Mo4 O20 1.818(4) .
Mo4 O28 1.700(4) .
Mo4 O36 2.305(4) .
Mo5 O3 2.141(4) .
Mo5 O5 1.819(4) .
Mo5 O8 1.952(4) .
Mo5 O17 2.401(3) .
Mo5 O21 1.806(4) .
Mo5 O32 1.683(4) .
Mo6 O7 2.090(4) .
Mo6 O12 1.680(4) .
Mo6 O15 1.762(4) .
Mo6 O19 1.854(4) .
Mo6 O20 2.103(4) .
Mo6 O36 2.249(4) .
Mo7 O7 1.808(4) .
Mo7 O8 1.968(4) .
Mo7 O11 2.170(4) .
Mo7 O23 1.807(4) .
Mo7 O35 1.693(4) .
Mo7 O36 2.399(3) .
Mo8 O10 2.087(4) .
Mo8 O14 2.287(4) .
Mo8 O19 1.973(4) .
Mo8 O22 1.749(4) .
Mo8 O27 1.950(4) .
Mo8 O33 1.687(4) .
Mo9 O6 2.112(4) .
Mo9 O14 2.301(4) .
Mo9 O16 1.747(4) .
Mo9 O24 2.013(4) .
Mo9 O25 1.692(4) .
Mo9 O27 1.907(4) .
Mo10 O2 2.186(4) .
Mo10 O3 1.987(4) .
Mo10 O8 2.160(4) .
Mo10 O11 1.981(4) .
Mo10 O31 1.699(4) .
Mo10 O34 1.733(5) .
Ge1 O9 1.759(3) .
Ge1 O14 1.750(4) .
Ge1 O17 1.753(4) .
Ge1 O36 1.753(3) .
Co1 O1 2.114(4) 2_635
Co1 O1W 2.066(4) .
Co1 O4 2.113(4) 2_635
Co1 O9 2.097(4) .
Co1 O16 2.084(4) .
Co1 O22 2.075(4) .
Co2 O1 2.112(4) 2_635
Co2 O4 2.098(4) .
Co2 O9 2.131(4) 2_635
Co2 O9 2.111(4) .
Co2 O15 2.063(4) .
Co2 O18 2.046(4) 2_635
O1W H1WA 0.8543 .
O1W H1WB 0.8222 .
Co3 O2W 2.132(5) .
Co3 O3W 2.137(5) .
Co3 O4W 2.095(5) .
Co3 N9 2.136(5) .
Co3 N6 2.145(5) 2_756
Co3 N1 2.076(5) .
Co4 N10 2.146(5) 2_756
Co4 N10 2.146(5) .
Co4 N5 2.116(5) .
Co4 N5 2.116(5) 2_756
Co4 N2 2.148(5) 2_756
Co4 N2 2.148(5) .
O2W H2WA 0.8403 .
O2W H2WB 0.8658 .
O3W H3WA 0.8778 .
O3W H3WB 0.8786 .
O4W H4WA 0.8707 .
O4W H4WB 0.8702 .
N3 N4 1.412(7) .
N3 C1 1.342(7) .
N3 C2 1.336(8) .
N10 N9 1.380(7) .
N10 C6 1.310(8) .
N5 N6 1.391(7) .
N5 C3 1.299(8) .
N2 N1 1.377(7) .
N2 C2 1.321(8) .
N9 C5 1.302(8) .
N7 N8 1.416(7) .
N7 C3 1.337(8) .
N7 C4 1.337(9) .
N6 C4 1.304(8) .
N1 C1 1.303(7) .
N11 N12 1.409(7) .
N11 C5 1.340(9) .
N11 C6 1.352(8) .
N4 H4A 0.8800 .
N4 H4B 0.8800 .
N8 H8A 0.8800 .
N8 H8B 0.8800 .
N12 H12A 0.8800 .
N12 H12B 0.8800 .
C3 H3 0.9500 .
C5 H5 0.9500 .
C1 H1 0.9500 .
C2 H2 0.9500 .
C4 H4 0.9500 .
C6 H6 0.9500 .
O5W H5WA 0.8198 .
O5W H5WB 0.8961 .
O6W H6WA 0.8499 .
O6W H6WB 0.8427 .
O7W H7WA 0.7481 .
O7W H7WB 0.8397 .
O7WA H7WC 0.8502 .
O7WA H7WD 0.8853 .
O8W H8WA 0.8502 .
O8W H8WB 0.8731 .
O9W H9WA 0.8701 .
O9W H9WB 0.8701 .
O9WA H9WC 0.8697 .
O9WA H9WD 0.8700 .
O10W H10A 0.8699 .
O10W H10B 0.8701 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
O1W H1WA O5W 0.85 1.79 2.595(7) 156.6 2_646 yes
O2W H2WB O7W 0.87 1.90 2.680(12) 149.8 . yes
O2W H2WB O7WA 0.87 1.86 2.703(16) 164.5 . yes
O5W H5WA O10 0.82 2.07 2.741(7) 139.3 1_565 yes
O6W H6WA O9W 0.85 1.99 2.82(3) 163.7 2_656 yes
O6W H6WA O9WA 0.85 1.85 2.70(5) 170.4 2_656 yes
O7W H7WA O3W 0.75 2.12 2.855(15) 167.7 2_757 yes
O7W H7WB O30 0.84 2.06 2.808(11) 148.5 1_666 yes
O7WA H7WC O20 0.85 2.04 2.822(13) 152.6 1_566 yes
O7WA H7WD O30 0.89 1.97 2.833(13) 164.2 1_666 yes
O9WA H9WD O8W 0.87 2.00 2.85(4) 165.4 1_565 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Mo3 O13 Mo1 73.8(2) . .
O2 Mo3 O1 Co1 -42.2(3) . 2_635
O2 Mo3 O1 Co2 109.8(3) . 2_635
O2 Mo3 O13 Mo1 -33.5(4) . .
O2 Mo4 O4 Co1 45.1(2) . 2_635
O2 Mo4 O4 Co2 -111.9(3) . .
O2 Mo4 O20 Mo6 32.2(5) . .
O3 Mo3 O1 Co1 -80.9(5) . 2_635
O3 Mo3 O1 Co2 71.1(6) . 2_635
O3 Mo3 O13 Mo1 -87.7(2) . .
O3 Mo5 O5 Mo1 83.3(2) . .
O3 Mo5 O21 Mo2 4.6(9) . .
O4 Mo4 O20 Mo6 -73.2(2) . .
O5 Mo1 O18 Co2 7.4(7) . 2_635
O5 Mo1 O24 Mo9 -138.3(4) . .
O5 Mo5 O21 Mo2 121.8(5) . .
O6 Mo2 O10 Mo8 64.5(2) . .
O6 Mo9 O16 Co1 37.1(7) . .
O7 Mo6 O15 Co2 -16.5(7) . .
O7 Mo6 O19 Mo8 136.5(4) . .
O7 Mo7 O23 Mo2 -120.9(5) . .
O8 Mo5 O5 Mo1 25.0(5) . .
O8 Mo5 O21 Mo2 -29.3(5) . .
O8 Mo7 O7 Mo6 -26.5(5) . .
O8 Mo7 O23 Mo2 30.1(5) . .
O9 Ge1 O14 Mo2 -179.4(2) . .
O9 Ge1 O14 Mo8 57.2(2) . .
O9 Ge1 O14 Mo9 -57.5(2) . .
O9 Ge1 O17 Mo1 59.4(2) . .
O9 Ge1 O17 Mo3 -58.8(2) . .
O9 Ge1 O17 Mo5 177.33(18) . .
O9 Ge1 O36 Mo4 58.9(2) . .
O9 Ge1 O36 Mo6 -59.8(2) . .
O9 Ge1 O36 Mo7 -176.69(18) . .
O10 Mo2 O6 Mo9 -64.9(2) . .
O10 Mo8 O22 Co1 -25.3(7) . .
O11 Mo4 O4 Co1 82.8(5) . 2_635
O11 Mo4 O4 Co2 -74.2(5) . .
O11 Mo4 O20 Mo6 87.5(2) . .
O11 Mo7 O7 Mo6 -84.2(2) . .
O11 Mo7 O23 Mo2 -0.5(8) . .
O12 Mo6 O15 Co2 -153.0(3) . .
O12 Mo6 O19 Mo8 -130.1(4) . .
O13 Mo1 O18 Co2 53.8(4) . 2_635
O13 Mo1 O24 Mo9 -91.0(5) . .
O13 Mo3 O1 Co1 163.6(3) . 2_635
O13 Mo3 O1 Co2 -44.4(3) . 2_635
O14 Mo2 O6 Mo9 6.09(19) . .
O14 Mo2 O10 Mo8 -7.85(18) . .
O14 Mo8 O22 Co1 -24.9(3) . .
O14 Mo9 O16 Co1 30.8(3) . .
O14 Ge1 O9 Co1 0.5(3) . .
O14 Ge1 O9 Co2 119.3(2) . 2_635
O14 Ge1 O9 Co2 -118.5(2) . .
O14 Ge1 O17 Mo1 -61.9(2) . .
O14 Ge1 O17 Mo3 179.96(18) . .
O14 Ge1 O17 Mo5 56.1(2) . .
O14 Ge1 O36 Mo4 179.88(18) . .
O14 Ge1 O36 Mo6 61.3(2) . .
O14 Ge1 O36 Mo7 -55.7(2) . .
O15 Mo6 O19 Mo8 -22.8(4) . .
O17 Mo1 O18 Co2 -18.5(4) . 2_635
O17 Mo1 O24 Mo9 -66.3(4) . .
O17 Mo3 O1 Co1 -121.4(3) . 2_635
O17 Mo3 O1 Co2 30.5(3) . 2_635
O17 Mo3 O13 Mo1 -14.37(17) . .
O17 Mo5 O5 Mo1 11.82(18) . .
O17 Mo5 O21 Mo2 49.0(5) . .
O17 Ge1 O9 Co1 -118.0(2) . .
O17 Ge1 O9 Co2 123.0(2) . .
O17 Ge1 O9 Co2 0.8(3) . 2_635
O17 Ge1 O14 Mo2 -59.0(3) . .
O17 Ge1 O14 Mo8 177.59(18) . .
O17 Ge1 O14 Mo9 62.9(2) . .
O17 Ge1 O36 Mo4 -63.6(2) . .
O17 Ge1 O36 Mo6 177.79(18) . .
O17 Ge1 O36 Mo7 60.9(2) . .
O18 Mo1 O24 Mo9 19.9(4) . .
O19 Mo6 O15 Co2 100.4(3) . .
O19 Mo8 O22 Co1 -109.8(3) . .
O20 Mo4 O4 Co1 -160.7(2) . 2_635
O20 Mo4 O4 Co2 42.4(3) . .
O20 Mo6 O15 Co2 -57.6(3) . .
O20 Mo6 O19 Mo8 84.2(5) . .
O21 Mo2 O6 Mo9 90.3(2) . .
O21 Mo2 O10 Mo8 -37.3(5) . .
O21 Mo5 O5 Mo1 -76.1(2) . .
O23 Mo2 O6 Mo9 31.4(5) . .
O23 Mo2 O10 Mo8 -92.6(2) . .
O23 Mo7 O7 Mo6 75.5(2) . .
O24 Mo1 O18 Co2 -105.1(4) . 2_635
O24 Mo9 O16 Co1 115.0(3) . .
O25 Mo9 O16 Co1 -145.8(3) . .
O26 Mo3 O1 Co1 59.3(3) . 2_635
O26 Mo3 O1 Co2 -148.7(3) . 2_635
O26 Mo3 O13 Mo1 -179.1(2) . .
O27 Mo8 O22 Co1 48.9(3) . .
O27 Mo9 O16 Co1 -43.2(3) . .
O28 Mo4 O4 Co1 -54.3(3) . 2_635
O28 Mo4 O4 Co2 148.7(3) . .
O28 Mo4 O20 Mo6 -179.5(2) . .
O29 Mo2 O6 Mo9 -168.5(2) . .
O29 Mo2 O10 Mo8 170.1(2) . .
O30 Mo1 O18 Co2 147.8(4) . 2_635
O30 Mo1 O24 Mo9 127.5(4) . .
O32 Mo5 O5 Mo1 176.2(2) . .
O32 Mo5 O21 Mo2 -130.6(5) . .
O33 Mo8 O22 Co1 149.6(3) . .
O35 Mo7 O7 Mo6 -176.9(2) . .
O35 Mo7 O23 Mo2 132.1(5) . .
O36 Mo4 O4 Co1 124.5(2) . 2_635
O36 Mo4 O4 Co2 -32.5(3) . .
O36 Mo4 O20 Mo6 13.73(17) . .
O36 Mo6 O15 Co2 13.9(3) . .
O36 Mo6 O19 Mo8 64.7(4) . .
O36 Mo7 O7 Mo6 -12.79(19) . .
O36 Mo7 O23 Mo2 -47.9(5) . .
O36 Ge1 O9 Co1 118.8(2) . .
O36 Ge1 O9 Co2 -122.5(2) . 2_635
O36 Ge1 O9 Co2 -0.3(3) . .
O36 Ge1 O14 Mo2 60.5(3) . .
O36 Ge1 O14 Mo8 -62.9(2) . .
O36 Ge1 O14 Mo9 -177.52(18) . .
O36 Ge1 O17 Mo1 -178.35(18) . .
O36 Ge1 O17 Mo3 63.5(2) . .
O36 Ge1 O17 Mo5 -60.4(2) . .
Co3 N9 C5 N11 176.9(4) . .
Co3 N6 C4 N7 171.0(4) 2_756 .
Co3 N1 C1 N3 178.3(4) . .
Co4 N10 N9 Co3 0.7(6) . .
Co4 N10 N9 C5 178.8(4) . .
Co4 N10 C6 N11 -178.6(4) . .
Co4 N5 N6 Co3 -7.3(6) . 2_756
Co4 N5 N6 C4 164.1(4) . .
Co4 N5 C3 N7 -164.8(4) . .
Co4 N2 N1 Co3 -4.6(6) . .
Co4 N2 N1 C1 174.8(4) . .
Co4 N2 C2 N3 -173.1(4) . .
N10 N9 C5 N11 -1.0(7) . .
N5 N6 C4 N7 0.8(7) . .
N2 N1 C1 N3 -1.2(6) . .
N9 N10 C6 N11 -1.0(7) . .
N6 N5 C3 N7 1.0(7) . .
N1 N2 C2 N3 1.5(6) . .
N4 N3 C1 N1 -178.8(5) . .
N4 N3 C2 N2 178.7(5) . .
N8 N7 C3 N5 177.7(5) . .
N8 N7 C4 N6 -178.4(6) . .
N12 N11 C5 N9 -178.4(6) . .
N12 N11 C6 N10 179.1(6) . .
C3 N5 N6 Co3 -172.4(4) . 2_756
C3 N5 N6 C4 -1.1(7) . .
C3 N7 C4 N6 -0.2(7) . .
C5 N11 C6 N10 0.4(7) . .
C1 N3 C2 N2 -2.2(7) . .
C2 N3 C1 N1 2.1(7) . .
C2 N2 N1 Co3 -179.6(4) . .
C2 N2 N1 C1 -0.2(6) . .
C4 N7 C3 N5 -0.5(7) . .
C6 N10 N9 Co3 -176.9(4) . .
C6 N10 N9 C5 1.2(6) . .
C6 N11 C5 N9 0.4(7) . .
