#------------------------------------------------------------------------------
#$Date: 2020-03-05 02:08:00 +0200 (Thu, 05 Mar 2020) $
#$Revision: 248942 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/30/7703048.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7703048
loop_
_publ_author_name
'Chupina, Anastasia V.'
'Shayapov, Vladimir'
'Novikov, Alexander S.'
'Volchek, Victoria V.'
'Benassi, Enrico'
'Abramov, Pavel A.'
'Sokolov, Maxim N.'
_publ_section_title
;
 [{AgL}₂Mo₈O₂₆]ⁿ⁻ complexes: a
 combined experimental and theoretical study.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1522
_journal_page_last               1530
_journal_paper_doi               10.1039/c9dt04043a
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C48 H94 Ag2 I2 Mo8 N6 O28'
_chemical_formula_weight         2440.35
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2019-10-15 deposited with the CCDC.	2019-12-26 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 116.353(7)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   13.8249(8)
_cell_length_b                   19.4381(7)
_cell_length_c                   15.3544(9)
_cell_measurement_reflns_used    8922
_cell_measurement_temperature    130(2)
_cell_measurement_theta_max      29.2940
_cell_measurement_theta_min      2.6300
_cell_volume                     3697.4(4)
_computing_cell_refinement       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_molecular_graphics    'ShelXle (Hübschle, 2011)'
_computing_publication_material  'CIFTAB-2014 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      130(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.6168
_diffrn_detector_type            AtlasS2
_diffrn_measured_fraction_theta_full 0.969
_diffrn_measured_fraction_theta_max 0.834
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'New Xcalibur, AtlasS2'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0298
_diffrn_reflns_av_unetI/netI     0.0399
_diffrn_reflns_Laue_measured_fraction_full 0.969
_diffrn_reflns_Laue_measured_fraction_max 0.834
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            22107
_diffrn_reflns_point_group_measured_fraction_full 0.969
_diffrn_reflns_point_group_measured_fraction_max 0.834
_diffrn_reflns_theta_full        25.500
_diffrn_reflns_theta_max         29.479
_diffrn_reflns_theta_min         1.949
_diffrn_source                   'sealed X-ray tube'
_exptl_absorpt_coefficient_mu    2.738
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.73665
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.41 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.192
_exptl_crystal_description       plate
_exptl_crystal_F_000             2368
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.050
_refine_diff_density_max         2.943
_refine_diff_density_min         -2.192
_refine_diff_density_rms         0.156
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     424
_refine_ls_number_reflns         8581
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0459
_refine_ls_R_factor_gt           0.0357
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0453P)²+9.2040P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0912
_refine_ls_wR_factor_ref         0.0967
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7258
_reflns_number_total             8581
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c9dt04043a2.cif
_cod_data_source_block           7
_cod_depositor_comments
'Adding full bibliography for 7703041--7703051.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7703048
_shelx_shelxl_version_number     2017/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.548
_shelx_estimated_absorpt_t_max   0.875
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
C1 C 0.7241(4) 0.6694(2) 0.8751(4) 0.0284(11) Uani 1 1 d . .
H1A H 0.660950 0.666235 0.815002 0.034 Uiso 1 1 calc R U
C2 C 0.7195(4) 0.7075(3) 0.9494(4) 0.0310(12) Uani 1 1 d . .
H2A H 0.654916 0.730362 0.940031 0.037 Uiso 1 1 calc R U
C3 C 0.8102(4) 0.7115(3) 1.0370(4) 0.0289(11) Uani 1 1 d . .
H3A H 0.809751 0.738109 1.088731 0.035 Uiso 1 1 calc R U
C4 C 0.9007(4) 0.6766(2) 1.0486(3) 0.0204(9) Uani 1 1 d . .
C5 C 0.9001(4) 0.6405(2) 0.9698(3) 0.0219(10) Uani 1 1 d . .
H5A H 0.964027 0.617514 0.977307 0.026 Uiso 1 1 calc R U
C6 C 1.0581(4) 0.6069(3) 0.7809(5) 0.0397(14) Uani 1 1 d . .
H6A H 1.071997 0.653838 0.773626 0.048 Uiso 1 1 calc R U
C7 C 1.0487(5) 0.4904(3) 0.7248(5) 0.0493(17) Uani 1 1 d . .
H7A H 1.065897 0.465930 0.677557 0.074 Uiso 1 1 calc R U
H7B H 1.091742 0.471351 0.789775 0.074 Uiso 1 1 calc R U
H7C H 0.971808 0.484986 0.707172 0.074 Uiso 1 1 calc R U
C8 C 1.0976(5) 0.5850(4) 0.6464(5) 0.0466(15) Uani 1 1 d . .
H8A H 1.106497 0.544722 0.612136 0.070 Uiso 1 1 calc R U
H8B H 1.038230 0.613469 0.600823 0.070 Uiso 1 1 calc R U
H8C H 1.164481 0.611904 0.673272 0.070 Uiso 1 1 calc R U
C9 C 0.6522(4) 0.2550(2) 0.2753(3) 0.0225(10) Uani 1 1 d . .
H9A H 0.727137 0.254222 0.282860 0.027 Uiso 1 1 calc R U
H9B H 0.607249 0.227914 0.216523 0.027 Uiso 1 1 calc R U
C10 C 0.6127(4) 0.3286(2) 0.2585(4) 0.0243(10) Uani 1 1 d . .
H10A H 0.657376 0.356618 0.316395 0.029 Uiso 1 1 calc R U
H10B H 0.537149 0.330232 0.249352 0.029 Uiso 1 1 calc R U
C11 C 0.6184(4) 0.3591(3) 0.1692(4) 0.0275(11) Uani 1 1 d . .
H11A H 0.694352 0.358973 0.179503 0.033 Uiso 1 1 calc R U
H11B H 0.576002 0.330018 0.111916 0.033 Uiso 1 1 calc R U
C12 C 0.5751(5) 0.4322(3) 0.1491(5) 0.0396(14) Uani 1 1 d . .
H12A H 0.580157 0.449932 0.091473 0.059 Uiso 1 1 calc R U
H12B H 0.499526 0.432440 0.137608 0.059 Uiso 1 1 calc R U
H12C H 0.617823 0.461382 0.205166 0.059 Uiso 1 1 calc R U
C13 C 0.7213(4) 0.2577(3) 0.4559(3) 0.0295(12) Uani 1 1 d . .
H13A H 0.708180 0.238747 0.509521 0.035 Uiso 1 1 calc R U
H13B H 0.699603 0.306751 0.448009 0.035 Uiso 1 1 calc R U
C14 C 0.8450(5) 0.2534(3) 0.4853(4) 0.0400(14) Uani 1 1 d . .
H14A H 0.870857 0.206210 0.508162 0.048 Uiso 1 1 calc R U
H14B H 0.856961 0.262461 0.427313 0.048 Uiso 1 1 calc R U
C15 C 0.9088(5) 0.3033(4) 0.5629(5) 0.0466(16) Uani 1 1 d . .
H15A H 0.886317 0.350511 0.537816 0.056 Uiso 1 1 calc R U
H15B H 0.891696 0.296603 0.618446 0.056 Uiso 1 1 calc R U
C16 C 1.0269(5) 0.2972(3) 0.5981(5) 0.0459(16) Uani 1 1 d . .
H16A H 1.063538 0.331556 0.648907 0.069 Uiso 1 1 calc R U
H16B H 1.050339 0.251034 0.624698 0.069 Uiso 1 1 calc R U
H16C H 1.044954 0.305011 0.543965 0.069 Uiso 1 1 calc R U
C17 C 0.6922(4) 0.1469(2) 0.3647(3) 0.0209(9) Uani 1 1 d . .
H17A H 0.767524 0.149688 0.373620 0.025 Uiso 1 1 calc R U
H17B H 0.648549 0.125218 0.300707 0.025 Uiso 1 1 calc R U
C18 C 0.6895(4) 0.1006(2) 0.4433(4) 0.0234(10) Uani 1 1 d . .
H18A H 0.723924 0.124576 0.506735 0.028 Uiso 1 1 calc R U
H18B H 0.613587 0.090841 0.428845 0.028 Uiso 1 1 calc R U
C19 C 0.7482(4) 0.0336(2) 0.4494(4) 0.0282(11) Uani 1 1 d . .
H19A H 0.825389 0.043043 0.468763 0.034 Uiso 1 1 calc R U
H19B H 0.717287 0.011245 0.384697 0.034 Uiso 1 1 calc R U
C20 C 0.7379(5) -0.0145(3) 0.5228(4) 0.0321(12) Uani 1 1 d . .
H20A H 0.776239 -0.057497 0.525814 0.048 Uiso 1 1 calc R U
H20B H 0.769448 0.007416 0.586973 0.048 Uiso 1 1 calc R U
H20C H 0.661514 -0.024332 0.503037 0.048 Uiso 1 1 calc R U
C21 C 0.5365(4) 0.2178(2) 0.3540(3) 0.0214(10) Uani 1 1 d . .
H21A H 0.538798 0.195103 0.412682 0.026 Uiso 1 1 calc R U
H21B H 0.511965 0.265688 0.353409 0.026 Uiso 1 1 calc R U
C22 C 0.4536(4) 0.1810(3) 0.2652(4) 0.0291(11) Uani 1 1 d . .
H22A H 0.479118 0.133747 0.263138 0.035 Uiso 1 1 calc R U
H22B H 0.446501 0.205412 0.206010 0.035 Uiso 1 1 calc R U
C23 C 0.3439(4) 0.1776(3) 0.2651(4) 0.0312(12) Uani 1 1 d . .
H23A H 0.322943 0.224502 0.275142 0.037 Uiso 1 1 calc R U
H23B H 0.290092 0.161631 0.200414 0.037 Uiso 1 1 calc R U
C24 C 0.3398(6) 0.1310(3) 0.3410(5) 0.0512(17) Uani 1 1 d . .
H24A H 0.266821 0.131444 0.336492 0.077 Uiso 1 1 calc R U
H24B H 0.358490 0.084071 0.330749 0.077 Uiso 1 1 calc R U
H24C H 0.391389 0.147032 0.405586 0.077 Uiso 1 1 calc R U
N1 N 0.8126(3) 0.6373(2) 0.8840(3) 0.0210(8) Uani 1 1 d . .
N2 N 0.6506(3) 0.21953(19) 0.3627(3) 0.0189(8) Uani 1 1 d . .
N3 N 1.0735(3) 0.5625(2) 0.7244(3) 0.0318(10) Uani 1 1 d . .
O1 O 0.7293(2) 0.34154(15) 0.6329(2) 0.0196(7) Uani 1 1 d . .
O2 O 0.7649(2) 0.45413(15) 0.5375(2) 0.0176(6) Uani 1 1 d . .
O3 O 0.8331(3) 0.55696(18) 0.4430(3) 0.0264(7) Uani 1 1 d . .
O4 O 0.5555(2) 0.42256(14) 0.6238(2) 0.0137(6) Uani 1 1 d . .
O5 O 0.3831(2) 0.49502(15) 0.6258(2) 0.0157(6) Uani 1 1 d . .
O6 O 0.4446(2) 0.60026(14) 0.5391(2) 0.0140(6) Uani 1 1 d . .
O7 O 0.5862(2) 0.54880(15) 0.7233(2) 0.0165(6) Uani 1 1 d . .
O8 O 0.4994(2) 0.71465(15) 0.4556(2) 0.0187(6) Uani 1 1 d . .
O9 O 0.6025(2) 0.52622(14) 0.5432(2) 0.0123(6) Uani 1 1 d . .
O10 O 0.6469(2) 0.66358(15) 0.6270(2) 0.0189(6) Uani 1 1 d . .
O11 O 0.6582(2) 0.62725(15) 0.4562(2) 0.0163(6) Uani 1 1 d . .
O12 O 0.7705(2) 0.46557(15) 0.7200(2) 0.0190(6) Uani 1 1 d . .
O13 O 0.8343(2) 0.58214(16) 0.6167(2) 0.0221(7) Uani 1 1 d . .
O14 O 1.0267(3) 0.5931(2) 0.8436(3) 0.0496(11) Uani 1 1 d . .
Mo1 Mo 0.69385(3) 0.42571(2) 0.61125(3) 0.01309(9) Uani 1 1 d . .
Mo2 Mo 0.50058(3) 0.51613(2) 0.61422(2) 0.01168(8) Uani 1 1 d . .
Mo3 Mo 0.56141(3) 0.64030(2) 0.51064(3) 0.01331(9) Uani 1 1 d . .
Mo4 Mo 0.75535(3) 0.55025(2) 0.50182(3) 0.01616(9) Uani 1 1 d . .
Ag1 Ag 0.81255(3) 0.58458(2) 0.75691(3) 0.02948(10) Uani 1 1 d . .
I1 I 1.03987(3) 0.67385(2) 1.18085(2) 0.03139(10) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C2 123.0(5) . .
N1 C1 H1A 118.5 . .
C2 C1 H1A 118.5 . .
C3 C2 C1 118.8(5) . .
C3 C2 H2A 120.6 . .
C1 C2 H2A 120.6 . .
C4 C3 C2 119.0(5) . .
C4 C3 H3A 120.5 . .
C2 C3 H3A 120.5 . .
C3 C4 C5 119.0(4) . .
C3 C4 I1 122.4(4) . .
C5 C4 I1 118.6(3) . .
N1 C5 C4 122.1(4) . .
N1 C5 H5A 118.9 . .
C4 C5 H5A 118.9 . .
O14 C6 N3 125.9(6) . .
O14 C6 H6A 117.0 . .
N3 C6 H6A 117.0 . .
N3 C7 H7A 109.5 . .
N3 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
N3 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
N3 C8 H8A 109.5 . .
N3 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
N3 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C10 C9 N2 115.7(4) . .
C10 C9 H9A 108.3 . .
N2 C9 H9A 108.3 . .
C10 C9 H9B 108.3 . .
N2 C9 H9B 108.3 . .
H9A C9 H9B 107.4 . .
C9 C10 C11 111.2(4) . .
C9 C10 H10A 109.4 . .
C11 C10 H10A 109.4 . .
C9 C10 H10B 109.4 . .
C11 C10 H10B 109.4 . .
H10A C10 H10B 108.0 . .
C12 C11 C10 111.9(4) . .
C12 C11 H11A 109.2 . .
C10 C11 H11A 109.2 . .
C12 C11 H11B 109.2 . .
C10 C11 H11B 109.2 . .
H11A C11 H11B 107.9 . .
C11 C12 H12A 109.5 . .
C11 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C11 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
N2 C13 C14 114.1(4) . .
N2 C13 H13A 108.7 . .
C14 C13 H13A 108.7 . .
N2 C13 H13B 108.7 . .
C14 C13 H13B 108.7 . .
H13A C13 H13B 107.6 . .
C15 C14 C13 112.3(5) . .
C15 C14 H14A 109.2 . .
C13 C14 H14A 109.2 . .
C15 C14 H14B 109.2 . .
C13 C14 H14B 109.2 . .
H14A C14 H14B 107.9 . .
C16 C15 C14 114.0(5) . .
C16 C15 H15A 108.8 . .
C14 C15 H15A 108.8 . .
C16 C15 H15B 108.8 . .
C14 C15 H15B 108.8 . .
H15A C15 H15B 107.7 . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
N2 C17 C18 115.0(4) . .
N2 C17 H17A 108.5 . .
C18 C17 H17A 108.5 . .
N2 C17 H17B 108.5 . .
C18 C17 H17B 108.5 . .
H17A C17 H17B 107.5 . .
C19 C18 C17 110.9(4) . .
C19 C18 H18A 109.5 . .
C17 C18 H18A 109.5 . .
C19 C18 H18B 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 108.0 . .
C18 C19 C20 110.5(4) . .
C18 C19 H19A 109.5 . .
C20 C19 H19A 109.5 . .
C18 C19 H19B 109.5 . .
C20 C19 H19B 109.5 . .
H19A C19 H19B 108.1 . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C22 C21 N2 115.4(4) . .
C22 C21 H21A 108.4 . .
N2 C21 H21A 108.4 . .
C22 C21 H21B 108.4 . .
N2 C21 H21B 108.4 . .
H21A C21 H21B 107.5 . .
C21 C22 C23 112.2(4) . .
C21 C22 H22A 109.2 . .
C23 C22 H22A 109.2 . .
C21 C22 H22B 109.2 . .
C23 C22 H22B 109.2 . .
H22A C22 H22B 107.9 . .
C24 C23 C22 114.2(5) . .
C24 C23 H23A 108.7 . .
C22 C23 H23A 108.7 . .
C24 C23 H23B 108.7 . .
C22 C23 H23B 108.7 . .
H23A C23 H23B 107.6 . .
C23 C24 H24A 109.5 . .
C23 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C1 N1 C5 118.0(4) . .
C1 N1 Ag1 119.3(3) . .
C5 N1 Ag1 122.6(3) . .
C9 N2 C17 106.6(3) . .
C9 N2 C13 110.7(4) . .
C17 N2 C13 110.8(4) . .
C9 N2 C21 110.7(3) . .
C17 N2 C21 110.4(3) . .
C13 N2 C21 107.6(4) . .
C6 N3 C7 122.0(6) . .
C6 N3 C8 121.1(5) . .
C7 N3 C8 116.0(5) . .
Mo1 O2 Mo4 117.76(15) . .
Mo2 O4 Mo1 108.66(13) . .
Mo2 O4 Mo3 109.20(12) . 3_666
Mo1 O4 Mo3 104.31(12) . 3_666
Mo2 O5 Mo4 118.39(15) . 3_666
Mo2 O6 Mo3 107.86(13) . .
Mo2 O6 Mo1 110.07(13) . 3_666
Mo3 O6 Mo1 104.89(12) . 3_666
Mo2 O9 Mo3 92.55(10) . .
Mo2 O9 Mo1 92.49(10) . .
Mo3 O9 Mo1 162.06(14) . .
Mo2 O9 Mo2 104.90(11) . 3_666
Mo3 O9 Mo2 97.87(10) . 3_666
Mo1 O9 Mo2 97.44(10) . 3_666
Mo2 O9 Mo4 165.15(14) . .
Mo3 O9 Mo4 85.38(9) . .
Mo1 O9 Mo4 85.35(9) . .
Mo2 O9 Mo4 89.95(9) 3_666 .
Mo3 O11 Mo4 117.49(15) . .
Mo1 O12 Ag1 130.38(16) . .
Mo4 O13 Ag1 132.62(17) . .
O1 Mo1 O12 104.15(15) . .
O1 Mo1 O2 102.65(14) . .
O12 Mo1 O2 101.04(14) . .
O1 Mo1 O4 98.97(13) . .
O12 Mo1 O4 97.10(13) . .
O2 Mo1 O4 147.27(12) . .
O1 Mo1 O6 91.40(13) . 3_666
O12 Mo1 O6 162.31(12) . 3_666
O2 Mo1 O6 83.36(12) . 3_666
O4 Mo1 O6 71.77(11) . 3_666
O1 Mo1 O9 162.99(13) . .
O12 Mo1 O9 92.07(12) . .
O2 Mo1 O9 78.81(12) . .
O4 Mo1 O9 73.51(11) . .
O6 Mo1 O9 71.83(10) 3_666 .
O1 Mo1 Mo2 133.88(11) . .
O12 Mo1 Mo2 84.13(10) . .
O2 Mo1 Mo2 120.47(9) . .
O4 Mo1 Mo2 35.10(8) . .
O6 Mo1 Mo2 78.96(7) 3_666 .
O9 Mo1 Mo2 41.66(7) . .
O7 Mo2 O5 105.07(14) . .
O7 Mo2 O4 101.39(13) . .
O5 Mo2 O4 96.94(13) . .
O7 Mo2 O6 101.00(13) . .
O5 Mo2 O6 96.50(13) . .
O4 Mo2 O6 149.82(12) . .
O7 Mo2 O9 98.10(13) . .
O5 Mo2 O9 156.83(12) . .
O4 Mo2 O9 78.56(11) . .
O6 Mo2 O9 78.48(11) . .
O7 Mo2 O9 173.18(13) . 3_666
O5 Mo2 O9 81.74(12) . 3_666
O4 Mo2 O9 77.80(11) . 3_666
O6 Mo2 O9 77.57(11) . 3_666
O9 Mo2 O9 75.10(11) . 3_666
O7 Mo2 Mo3 89.20(10) . .
O5 Mo2 Mo3 133.16(9) . .
O4 Mo2 Mo3 124.13(9) . .
O6 Mo2 Mo3 36.66(9) . .
O9 Mo2 Mo3 45.57(7) . .
O9 Mo2 Mo3 85.75(7) 3_666 .
O7 Mo2 Mo1 89.91(10) . .
O5 Mo2 Mo1 133.18(9) . .
O4 Mo2 Mo1 36.25(9) . .
O6 Mo2 Mo1 124.31(9) . .
O9 Mo2 Mo1 45.85(7) . .
O9 Mo2 Mo1 85.52(7) 3_666 .
Mo3 Mo2 Mo1 90.108(13) . .
O8 Mo3 O10 104.88(15) . .
O8 Mo3 O11 101.21(14) . .
O10 Mo3 O11 101.65(14) . .
O8 Mo3 O6 99.25(13) . .
O10 Mo3 O6 97.17(13) . .
O11 Mo3 O6 147.46(12) . .
O8 Mo3 O9 162.35(13) . .
O10 Mo3 O9 92.23(12) . .
O11 Mo3 O9 79.06(11) . .
O6 Mo3 O9 73.89(11) . .
O8 Mo3 O4 90.38(12) . 3_666
O10 Mo3 O4 162.42(12) . 3_666
O11 Mo3 O4 83.45(12) . 3_666
O6 Mo3 O4 71.35(11) . 3_666
O9 Mo3 O4 72.06(10) . 3_666
O8 Mo3 Mo2 134.56(11) . .
O10 Mo3 Mo2 83.82(10) . .
O11 Mo3 Mo2 120.94(9) . .
O6 Mo3 Mo2 35.48(8) . .
O9 Mo3 Mo2 41.88(7) . .
O4 Mo3 Mo2 79.20(7) 3_666 .
O3 Mo4 O13 104.78(16) . .
O3 Mo4 O11 104.61(15) . .
O13 Mo4 O11 96.64(14) . .
O3 Mo4 O2 104.27(15) . .
O13 Mo4 O2 97.18(14) . .
O11 Mo4 O2 143.46(12) . .
O3 Mo4 O5 93.58(14) . 3_666
O13 Mo4 O5 161.64(14) . 3_666
O11 Mo4 O5 78.37(12) . 3_666
O2 Mo4 O5 77.93(12) . 3_666
O3 Mo4 O9 163.51(14) . .
O13 Mo4 O9 91.71(13) . .
O11 Mo4 O9 72.94(11) . .
O2 Mo4 O9 72.98(11) . .
O5 Mo4 O9 69.92(10) 3_666 .
N1 Ag1 O13 152.72(13) . .
N1 Ag1 O12 124.32(13) . .
O13 Ag1 O12 82.96(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.326(6) .
C1 C2 1.384(7) .
C1 H1A 0.9500 .
C2 C3 1.375(7) .
C2 H2A 0.9500 .
C3 C4 1.364(7) .
C3 H3A 0.9500 .
C4 C5 1.396(6) .
C4 I1 2.087(5) .
C5 N1 1.337(6) .
C5 H5A 0.9500 .
C6 O14 1.247(8) .
C6 N3 1.306(8) .
C6 H6A 0.9500 .
C7 N3 1.443(7) .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 N3 1.447(8) .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 C10 1.513(7) .
C9 N2 1.518(6) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 C11 1.528(7) .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
C11 C12 1.519(7) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C13 N2 1.521(6) .
C13 C14 1.565(8) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 C15 1.486(8) .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C15 C16 1.479(8) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 N2 1.520(6) .
C17 C18 1.519(6) .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C18 C19 1.516(7) .
C18 H18A 0.9900 .
C18 H18B 0.9900 .
C19 C20 1.518(7) .
C19 H19A 0.9900 .
C19 H19B 0.9900 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 C22 1.515(7) .
C21 N2 1.523(6) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 C23 1.517(7) .
C22 H22A 0.9900 .
C22 H22B 0.9900 .
C23 C24 1.497(8) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
N1 Ag1 2.204(4) .
O1 Mo1 1.698(3) .
O2 Mo1 1.882(3) .
O2 Mo4 1.935(3) .
O3 Mo4 1.689(3) .
O4 Mo2 1.951(3) .
O4 Mo1 2.007(3) .
O4 Mo3 2.325(3) 3_666
O5 Mo2 1.759(3) .
O5 Mo4 2.224(3) 3_666
O6 Mo2 1.952(3) .
O6 Mo3 2.008(3) .
O6 Mo1 2.307(3) 3_666
O7 Mo2 1.688(3) .
O8 Mo3 1.702(3) .
O9 Mo2 2.139(3) .
O9 Mo3 2.289(3) .
O9 Mo1 2.309(3) .
O9 Mo2 2.343(3) 3_666
O9 Mo4 2.506(3) .
O10 Mo3 1.708(3) .
O11 Mo3 1.884(3) .
O11 Mo4 1.923(3) .
O12 Mo1 1.715(3) .
O12 Ag1 2.391(3) .
O13 Mo4 1.726(3) .
O13 Ag1 2.302(3) .
Mo1 Mo2 3.2154(5) .
Mo2 Mo3 3.2015(5) .
