#------------------------------------------------------------------------------
#$Date: 2020-03-05 02:08:00 +0200 (Thu, 05 Mar 2020) $
#$Revision: 248942 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/30/7703049.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7703049
loop_
_publ_author_name
'Chupina, Anastasia V.'
'Shayapov, Vladimir'
'Novikov, Alexander S.'
'Volchek, Victoria V.'
'Benassi, Enrico'
'Abramov, Pavel A.'
'Sokolov, Maxim N.'
_publ_section_title
;
 [{AgL}₂Mo₈O₂₆]ⁿ⁻ complexes: a
 combined experimental and theoretical study.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1522
_journal_page_last               1530
_journal_paper_doi               10.1039/c9dt04043a
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C52 H70 Ag2 Mo6 N8 O25 P2'
_chemical_formula_weight         2060.48
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2019-10-15 deposited with the CCDC.	2019-12-26 downloaded from the CCDC.
;
_cell_angle_alpha                94.658(3)
_cell_angle_beta                 90.989(3)
_cell_angle_gamma                95.871(3)
_cell_formula_units_Z            1
_cell_length_a                   11.3665(4)
_cell_length_b                   12.0432(4)
_cell_length_c                   12.7074(4)
_cell_measurement_reflns_used    7726
_cell_measurement_temperature    130(2)
_cell_measurement_theta_max      29.4100
_cell_measurement_theta_min      3.6700
_cell_volume                     1724.09(10)
_computing_cell_refinement       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_molecular_graphics    'ShelXle (Hübschle, 2011)'
_computing_publication_material  'CIFTAB-2014 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      130(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.6168
_diffrn_detector_type            AtlasS2
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.828
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'New Xcalibur, AtlasS2'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0184
_diffrn_reflns_av_unetI/netI     0.0346
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.828
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            13177
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.828
_diffrn_reflns_theta_full        25.500
_diffrn_reflns_theta_max         29.429
_diffrn_reflns_theta_min         3.515
_diffrn_source                   'sealed X-ray tube'
_exptl_absorpt_coefficient_mu    1.737
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.92163
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.41 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.985
_exptl_crystal_description       block
_exptl_crystal_F_000             1014
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.120
_refine_diff_density_max         0.822
_refine_diff_density_min         -0.568
_refine_diff_density_rms         0.088
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     431
_refine_ls_number_reflns         7909
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.0285
_refine_ls_R_factor_gt           0.0237
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0215P)²+0.4633P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0541
_refine_ls_wR_factor_ref         0.0562
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7078
_reflns_number_total             7909
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c9dt04043a2.cif
_cod_data_source_block           12
_cod_depositor_comments
'Adding full bibliography for 7703041--7703051.cif.'
_cod_database_code               7703049
_shelx_shelxl_version_number     2017/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.701
_shelx_estimated_absorpt_t_max   0.819
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
C1 C 0.6748(2) 0.0125(2) 0.78495(16) 0.0144(5) Uani 1 1 d . . .
C2 C 0.7142(2) 0.0858(2) 0.87125(17) 0.0187(5) Uani 1 1 d . . .
H2 H 0.701205 0.162577 0.872767 0.022 Uiso 1 1 calc R U .
C3 C 0.7728(2) 0.0466(2) 0.95551(18) 0.0239(6) Uani 1 1 d . . .
H3 H 0.801122 0.096916 1.013992 0.029 Uiso 1 1 calc R U .
C4 C 0.7897(2) -0.0647(2) 0.95437(19) 0.0256(6) Uani 1 1 d . . .
H4 H 0.829119 -0.091074 1.012472 0.031 Uiso 1 1 calc R U .
C5 C 0.7496(2) -0.1391(2) 0.8690(2) 0.0271(6) Uani 1 1 d . . .
H5 H 0.761271 -0.216173 0.868692 0.033 Uiso 1 1 calc R U .
C6 C 0.6924(2) -0.1000(2) 0.78415(18) 0.0210(5) Uani 1 1 d . . .
H6 H 0.665210 -0.150378 0.725319 0.025 Uiso 1 1 calc R U .
C7 C 0.7159(2) 0.1424(2) 0.60438(17) 0.0147(5) Uani 1 1 d . . .
C8 C 0.8237(2) 0.1844(2) 0.65053(19) 0.0230(6) Uani 1 1 d . . .
H8 H 0.845773 0.163868 0.718161 0.028 Uiso 1 1 calc R U .
C9 C 0.8996(2) 0.2568(2) 0.59748(19) 0.0261(6) Uani 1 1 d . . .
H9 H 0.973991 0.286932 0.628221 0.031 Uiso 1 1 calc R U .
C10 C 0.8649(2) 0.2842(2) 0.49908(19) 0.0227(6) Uani 1 1 d . . .
H10 H 0.914113 0.335175 0.461601 0.027 Uiso 1 1 calc R U .
C11 C 0.7573(2) 0.2362(2) 0.45606(18) 0.0199(5) Uani 1 1 d . . .
H11 H 0.734942 0.253278 0.387285 0.024 Uiso 1 1 calc R U .
C12 C 0.5066(2) 0.1627(2) 0.72018(16) 0.0149(5) Uani 1 1 d . . .
C13 C 0.5464(2) 0.2760(2) 0.73634(18) 0.0200(5) Uani 1 1 d . . .
H13 H 0.625873 0.301257 0.721483 0.024 Uiso 1 1 calc R U .
C14 C 0.4707(2) 0.3519(2) 0.77397(19) 0.0240(6) Uani 1 1 d . . .
H14 H 0.498208 0.429306 0.784122 0.029 Uiso 1 1 calc R U .
C15 C 0.3551(2) 0.3160(2) 0.79698(19) 0.0235(6) Uani 1 1 d . . .
H15 H 0.303467 0.368402 0.823277 0.028 Uiso 1 1 calc R U .
C16 C 0.3152(2) 0.2036(2) 0.7815(2) 0.0253(6) Uani 1 1 d . . .
H16 H 0.236132 0.178455 0.797557 0.030 Uiso 1 1 calc R U .
C17 C 0.3907(2) 0.1270(2) 0.74236(18) 0.0206(5) Uani 1 1 d . . .
H17 H 0.362585 0.049871 0.730814 0.025 Uiso 1 1 calc R U .
C18 C 0.2143(3) 0.4216(3) 0.5655(2) 0.0390(8) Uani 1 1 d . . .
H18A H 0.193141 0.358421 0.607859 0.059 Uiso 1 1 calc R U .
H18B H 0.146242 0.433360 0.520857 0.059 Uiso 1 1 calc R U .
H18C H 0.236982 0.489341 0.612421 0.059 Uiso 1 1 calc R U .
C19 C 0.3530(4) 0.4802(3) 0.4279(3) 0.0622(12) Uani 1 1 d . . .
H19A H 0.427209 0.460995 0.396578 0.093 Uiso 1 1 calc R U .
H19B H 0.366047 0.554235 0.466907 0.093 Uiso 1 1 calc R U .
H19C H 0.292982 0.481528 0.371823 0.093 Uiso 1 1 calc R U .
C20 C 0.3584(2) 0.3012(2) 0.49936(19) 0.0225(6) Uani 1 1 d . . .
H20 H 0.325983 0.248869 0.545854 0.027 Uiso 1 1 calc R U .
C21 C 0.5855(2) 0.1562(2) 0.1588(2) 0.0241(6) Uani 1 1 d . . .
H21 H 0.581927 0.095291 0.106034 0.029 Uiso 1 1 calc R U .
C22 C 0.5517(3) 0.3479(2) 0.2065(2) 0.0285(6) Uani 1 1 d . . .
H22A H 0.580316 0.329064 0.275311 0.043 Uiso 1 1 calc R U .
H22B H 0.470978 0.369180 0.212748 0.043 Uiso 1 1 calc R U .
H22C H 0.603547 0.410615 0.182813 0.043 Uiso 1 1 calc R U .
C23 C 0.5121(3) 0.2667(3) 0.0235(2) 0.0412(8) Uani 1 1 d . . .
H23A H 0.509206 0.195301 -0.019805 0.062 Uiso 1 1 calc R U .
H23B H 0.567320 0.322580 -0.006992 0.062 Uiso 1 1 calc R U .
H23C H 0.433055 0.292441 0.025249 0.062 Uiso 1 1 calc R U .
C24 C 0.0696(3) 0.1696(3) 0.3548(2) 0.0404(8) Uani 1 1 d . . .
H24 H 0.100726 0.226914 0.312824 0.048 Uiso 1 1 calc R U .
C25 C -0.0744(3) 0.0101(3) 0.3719(3) 0.0517(10) Uani 1 1 d . . .
H25A H -0.042385 -0.060609 0.350639 0.078 Uiso 1 1 calc R U .
H25B H -0.159940 0.002026 0.357093 0.078 Uiso 1 1 calc R U .
H25C H -0.059095 0.029325 0.447613 0.078 Uiso 1 1 calc DR U .
C26 C -0.0627(3) 0.1011(3) 0.2068(2) 0.0418(8) Uani 1 1 d . . .
H26A H -0.018411 0.162400 0.173329 0.063 Uiso 1 1 calc R U .
H26B H -0.146670 0.113125 0.208140 0.063 Uiso 1 1 calc R U .
H26C H -0.053436 0.029834 0.166399 0.063 Uiso 1 1 calc R U .
N1 N 0.55188(19) 0.25169(19) 0.13045(15) 0.0231(5) Uani 1 1 d . . .
N2 N 0.68301(17) 0.16670(17) 0.50707(14) 0.0153(4) Uani 1 1 d . . .
N3 N -0.0181(2) 0.0983(2) 0.31299(17) 0.0309(6) Uani 1 1 d . . .
N4 N 0.3127(2) 0.39748(19) 0.49939(17) 0.0269(5) Uani 1 1 d . . .
O1 O 1.07158(15) 0.41890(14) 0.81451(12) 0.0183(4) Uani 1 1 d . . .
O2 O 1.15595(18) 0.63191(16) 0.75297(13) 0.0294(4) Uani 1 1 d . . .
O3 O 1.22161(15) 0.54741(15) 0.94514(13) 0.0206(4) Uani 1 1 d . . .
O4 O 0.92494(15) 0.57721(15) 0.82456(12) 0.0211(4) Uani 1 1 d . . .
O5 O 1.000000 0.500000 1.000000 0.0122(5) Uani 1 2 d S . P
O6 O 1.07547(15) 0.70475(14) 0.95460(12) 0.0193(4) Uani 1 1 d . . .
O7 O 0.99209(16) 0.80715(15) 1.14390(13) 0.0218(4) Uani 1 1 d . . .
O8 O 0.85032(15) 0.65593(14) 1.00706(12) 0.0188(4) Uani 1 1 d . . .
O9 O 0.85206(15) 0.36748(15) 0.86915(12) 0.0202(4) Uani 1 1 d . . .
O10 O 0.68420(16) 0.52270(17) 0.86574(14) 0.0309(5) Uani 1 1 d . . .
O11 O 0.44003(18) 0.27408(16) 0.44345(14) 0.0295(4) Uani 1 1 d . . .
O12 O 0.62078(16) 0.13967(15) 0.24694(13) 0.0249(4) Uani 1 1 d . . .
O13 O 0.1145(2) 0.1683(2) 0.44335(18) 0.0602(7) Uani 1 1 d . . .
Mo1 Mo 1.09099(2) 0.57585(2) 0.85701(2) 0.01957(6) Uani 1 1 d . . .
Mo2 Mo 0.99247(2) 0.67863(2) 1.08117(2) 0.01510(5) Uani 1 1 d . . .
Mo3 Mo 0.81697(2) 0.50804(2) 0.92027(2) 0.01841(6) Uani 1 1 d . . .
Ag1 Ag 0.51078(2) 0.09444(2) 0.42835(2) 0.01622(5) Uani 1 1 d . . .
P1 P 0.60090(5) 0.05718(5) 0.66994(4) 0.01287(12) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 C6 119.7(2) . .
C2 C1 P1 122.84(18) . .
C6 C1 P1 117.45(17) . .
C1 C2 C3 119.9(2) . .
C1 C2 H2 120.1 . .
C3 C2 H2 120.1 . .
C4 C3 C2 120.2(2) . .
C4 C3 H3 119.9 . .
C2 C3 H3 119.9 . .
C3 C4 C5 120.6(2) . .
C3 C4 H4 119.7 . .
C5 C4 H4 119.7 . .
C4 C5 C6 119.4(2) . .
C4 C5 H5 120.3 . .
C6 C5 H5 120.3 . .
C1 C6 C5 120.3(2) . .
C1 C6 H6 119.9 . .
C5 C6 H6 119.9 . .
N2 C7 C8 122.0(2) . .
N2 C7 P1 113.54(17) . .
C8 C7 P1 124.34(18) . .
C7 C8 C9 119.5(2) . .
C7 C8 H8 120.3 . .
C9 C8 H8 120.3 . .
C10 C9 C8 118.7(2) . .
C10 C9 H9 120.7 . .
C8 C9 H9 120.7 . .
C9 C10 C11 118.8(2) . .
C9 C10 H10 120.6 . .
C11 C10 H10 120.6 . .
N2 C11 C10 122.9(2) . .
N2 C11 H11 118.5 . .
C10 C11 H11 118.5 . .
C17 C12 C13 119.3(2) . .
C17 C12 P1 117.87(19) . .
C13 C12 P1 122.83(19) . .
C14 C13 C12 120.2(2) . .
C14 C13 H13 119.9 . .
C12 C13 H13 119.9 . .
C13 C14 C15 120.5(3) . .
C13 C14 H14 119.8 . .
C15 C14 H14 119.8 . .
C16 C15 C14 119.6(2) . .
C16 C15 H15 120.2 . .
C14 C15 H15 120.2 . .
C15 C16 C17 120.1(3) . .
C15 C16 H16 119.9 . .
C17 C16 H16 119.9 . .
C12 C17 C16 120.3(2) . .
C12 C17 H17 119.8 . .
C16 C17 H17 119.8 . .
N4 C18 H18A 109.5 . .
N4 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
N4 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
N4 C19 H19A 109.5 . .
N4 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
N4 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
O11 C20 N4 124.8(2) . .
O11 C20 H20 117.6 . .
N4 C20 H20 117.6 . .
O12 C21 N1 125.6(2) . .
O12 C21 H21 117.2 . .
N1 C21 H21 117.2 . .
N1 C22 H22A 109.5 . .
N1 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
N1 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
N1 C23 H23A 109.5 . .
N1 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
N1 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
O13 C24 N3 125.7(3) . .
O13 C24 H24 117.2 . .
N3 C24 H24 117.2 . .
N3 C25 H25A 109.5 . .
N3 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
N3 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
N3 C26 H26A 109.5 . .
N3 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
N3 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C21 N1 C22 120.8(2) . .
C21 N1 C23 123.1(2) . .
C22 N1 C23 116.1(2) . .
C11 N2 C7 118.1(2) . .
C11 N2 Ag1 119.38(15) . .
C7 N2 Ag1 122.54(16) . .
C24 N3 C26 122.9(3) . .
C24 N3 C25 121.5(3) . .
C26 N3 C25 115.6(3) . .
C20 N4 C19 121.4(2) . .
C20 N4 C18 121.4(2) . .
C19 N4 C18 117.1(2) . .
Mo1 O1 Mo2 116.31(7) . 2_767
Mo1 O3 Mo3 116.52(8) . 2_767
Mo3 O4 Mo1 116.38(8) . .
Mo1 O5 Mo1 180.0 2_767 .
Mo1 O5 Mo3 89.954(8) 2_767 2_767
Mo1 O5 Mo3 90.045(9) . 2_767
Mo1 O5 Mo3 90.046(8) 2_767 .
Mo1 O5 Mo3 89.954(9) . .
Mo3 O5 Mo3 180.0 2_767 .
Mo1 O5 Mo2 90.029(8) 2_767 .
Mo1 O5 Mo2 89.972(8) . .
Mo3 O5 Mo2 90.045(8) 2_767 .
Mo3 O5 Mo2 89.954(8) . .
Mo1 O5 Mo2 89.971(8) 2_767 2_767
Mo1 O5 Mo2 90.028(8) . 2_767
Mo3 O5 Mo2 89.955(8) 2_767 2_767
Mo3 O5 Mo2 90.046(8) . 2_767
Mo2 O5 Mo2 179.999(12) . 2_767
Mo2 O6 Mo1 116.92(9) . .
Mo2 O8 Mo3 116.16(8) . .
Mo3 O9 Mo2 116.11(8) . 2_767
C20 O11 Ag1 125.55(18) . .
O2 Mo1 O1 103.28(8) . .
O2 Mo1 O3 103.82(9) . .
O1 Mo1 O3 87.36(7) . .
O2 Mo1 O4 102.88(8) . .
O1 Mo1 O4 87.48(7) . .
O3 Mo1 O4 153.28(7) . .
O2 Mo1 O6 103.32(8) . .
O1 Mo1 O6 153.40(7) . .
O3 Mo1 O6 86.62(7) . .
O4 Mo1 O6 86.36(7) . .
O2 Mo1 O5 179.37(7) . .
O1 Mo1 O5 77.08(5) . .
O3 Mo1 O5 76.69(5) . .
O4 Mo1 O5 76.61(5) . .
O6 Mo1 O5 76.32(5) . .
O7 Mo2 O8 104.07(8) . .
O7 Mo2 O6 104.03(8) . .
O8 Mo2 O6 90.95(7) . .
O7 Mo2 O1 102.78(8) . 2_767
O8 Mo2 O1 90.01(7) . 2_767
O6 Mo2 O1 152.07(7) . 2_767
O7 Mo2 O9 102.13(8) . 2_767
O8 Mo2 O9 153.78(7) . 2_767
O6 Mo2 O9 83.67(7) . 2_767
O1 Mo2 O9 83.23(7) 2_767 2_767
O7 Mo2 O5 177.35(6) . .
O8 Mo2 O5 78.47(5) . .
O6 Mo2 O5 76.53(5) . .
O1 Mo2 O5 76.33(5) 2_767 .
O9 Mo2 O5 75.32(5) 2_767 .
O10 Mo3 O9 105.25(8) . .
O10 Mo3 O4 102.68(9) . .
O9 Mo3 O4 90.86(8) . .
O10 Mo3 O3 103.55(9) . 2_767
O9 Mo3 O3 90.34(7) . 2_767
O4 Mo3 O3 152.43(7) . 2_767
O10 Mo3 O8 100.82(8) . .
O9 Mo3 O8 153.93(7) . .
O4 Mo3 O8 83.51(7) . .
O3 Mo3 O8 83.40(7) 2_767 .
O10 Mo3 O5 176.21(7) . .
O9 Mo3 O5 78.53(5) . .
O4 Mo3 O5 76.73(5) . .
O3 Mo3 O5 76.54(5) 2_767 .
O8 Mo3 O5 75.41(5) . .
N2 Ag1 P1 148.81(5) . 2_656
N2 Ag1 O11 90.46(7) . .
P1 Ag1 O11 119.86(5) 2_656 .
N2 Ag1 Ag1 91.37(5) . 2_656
P1 Ag1 Ag1 74.401(16) 2_656 2_656
O11 Ag1 Ag1 131.56(4) . 2_656
C1 P1 C12 106.13(10) . .
C1 P1 C7 105.08(11) . .
C12 P1 C7 101.74(11) . .
C1 P1 Ag1 111.96(8) . 2_656
C12 P1 Ag1 111.39(8) . 2_656
C7 P1 Ag1 119.33(8) . 2_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.388(3) .
C1 C6 1.389(3) .
C1 P1 1.819(2) .
C2 C3 1.391(3) .
C2 H2 0.9500 .
C3 C4 1.372(4) .
C3 H3 0.9500 .
C4 C5 1.389(4) .
C4 H4 0.9500 .
C5 C6 1.389(3) .
C5 H5 0.9500 .
C6 H6 0.9500 .
C7 N2 1.349(3) .
C7 C8 1.379(3) .
C7 P1 1.833(2) .
C8 C9 1.386(4) .
C8 H8 0.9500 .
C9 C10 1.380(3) .
C9 H9 0.9500 .
C10 C11 1.382(4) .
C10 H10 0.9500 .
C11 N2 1.340(3) .
C11 H11 0.9500 .
C12 C17 1.384(3) .
C12 C13 1.391(3) .
C12 P1 1.828(2) .
C13 C14 1.382(3) .
C13 H13 0.9500 .
C14 C15 1.385(4) .
C14 H14 0.9500 .
C15 C16 1.380(4) .
C15 H15 0.9500 .
C16 C17 1.391(3) .
C16 H16 0.9500 .
C17 H17 0.9500 .
C18 N4 1.449(3) .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 N4 1.448(4) .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 O11 1.233(3) .
C20 N4 1.318(3) .
C20 H20 0.9500 .
C21 O12 1.222(3) .
C21 N1 1.323(3) .
C21 H21 0.9500 .
C22 N1 1.447(3) .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 N1 1.456(3) .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 O13 1.229(4) .
C24 N3 1.322(4) .
C24 H24 0.9500 .
C25 N3 1.451(4) .
C25 H25A 0.9800 .
C25 H25B 0.9800 .
C25 H25C 0.9800 .
C26 N3 1.438(3) .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
N2 Ag1 2.243(2) .
O1 Mo1 1.9126(17) .
O1 Mo2 1.9438(16) 2_767
O2 Mo1 1.6809(17) .
O3 Mo1 1.9195(17) .
O3 Mo3 1.9274(16) 2_767
O4 Mo3 1.9199(17) .
O4 Mo1 1.9270(17) .
O5 Mo1 2.3123(2) 2_767
O5 Mo1 2.3124(2) .
O5 Mo3 2.3126(2) 2_767
O5 Mo3 2.3126(2) .
O5 Mo2 2.3193(2) .
O5 Mo2 2.3193(2) 2_767
O6 Mo2 1.9105(16) .
O6 Mo1 1.9313(16) .
O7 Mo2 1.6830(17) .
O8 Mo2 1.8405(16) .
O8 Mo3 2.0151(17) .
O9 Mo3 1.8479(17) .
O9 Mo2 2.0122(16) 2_767
O10 Mo3 1.6814(17) .
O11 Ag1 2.3786(18) .
Ag1 P1 2.3678(6) 2_656
Ag1 Ag1 3.0207(4) 2_656
