#------------------------------------------------------------------------------
#$Date: 2020-03-05 02:11:42 +0200 (Thu, 05 Mar 2020) $
#$Revision: 248956 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/32/7703253.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7703253
loop_
_publ_author_name
'Wang, Ning'
'Zhang, Junying'
'Xu, Xing-Dong'
'Feng, Shengyu'
_publ_section_title
;
 Turn-on fluorescence in a pyridine-decorated tetraphenylethylene: the
 cooperative effect of coordination-driven rigidification and silver ion
 induced aggregation.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1883
_journal_page_last               1890
_journal_paper_doi               10.1039/c9dt03985f
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         '0.5(C108 H80 Ag8 F24 N8 O32 S8), 2(H2 O)'
_chemical_formula_sum            'C54 H44 Ag4 F12 N4 O18 S4'
_chemical_formula_weight         1824.65
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-I 2ya'
_space_group_name_H-M_alt        'I 1 2/a 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_audit_creation_date             2019-04-09
_audit_creation_method
;
Olex2 1.2
(compiled 2018.04.26 svn.r3504 for OlexSys, GUI svn.r5492)
;
_audit_update_record
;
2019-09-17 deposited with the CCDC.	2020-01-10 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 95.672(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.1288(3)
_cell_length_b                   14.0651(3)
_cell_length_c                   29.2057(4)
_cell_measurement_reflns_used    11303
_cell_measurement_temperature    173.00(2)
_cell_measurement_theta_max      76.3230
_cell_measurement_theta_min      3.0070
_cell_volume                     6184.2(2)
_computing_cell_refinement       'CrysAlisPro 1.171.40.25a (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.40.25a (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.40.25a (Rigaku OD, 2018)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      173.00(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -51.00  -3.00   1.00    0.15    --  -48.45 115.00  10.00   48
  2  ω    -84.00 -44.00   1.00    0.15    --  -48.45-168.00 137.00   40
  3  ω     65.00 120.00   1.00    0.15    --   48.45 168.00 155.00   55
  4  ω     28.00  87.00   1.00    0.15    --   48.45-115.00 -78.00   59
  5  ω   -118.00 -85.00   1.00    0.60    --  -86.25-115.00 -78.00   33
  6  ω     99.00 168.00   1.00    0.60    --  106.49 115.00  10.00   69
  7  ω     76.00 112.00   1.00    0.60    --  106.49-115.00 -78.00   36
  8  ω     63.00 147.00   1.00    0.60    --  106.49-168.00 137.00   84
  9  ω     87.00 112.00   1.00    0.60    --  106.49 168.00 155.00   25
 10  ω   -120.00 -26.00   1.00    0.15    --  -48.45 -77.00 -60.00   94
 11  ω   -159.00 -80.00   1.00    0.60    --  -86.25 -94.00 -60.00   79
 12  ω    103.00 178.00   1.00    0.60    --  106.49  15.00-180.00   75
 13  ω     50.00 107.00   1.00    0.60    --  106.49 -94.00 120.00   57
 14  ω     35.00 108.00   1.00    0.60    --  106.49 -45.00-120.00   73
 15  ω     39.00 119.00   1.00    0.60    --  106.49 -45.00  60.00   80
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_measurement_specimen_support 'Mitegen 50um'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0095507000
_diffrn_orient_matrix_UB_12      -0.0895125000
_diffrn_orient_matrix_UB_13      -0.0305251000
_diffrn_orient_matrix_UB_21      -0.0416907000
_diffrn_orient_matrix_UB_22      0.0603894000
_diffrn_orient_matrix_UB_23      -0.0405228000
_diffrn_orient_matrix_UB_31      0.0929253000
_diffrn_orient_matrix_UB_32      0.0180919000
_diffrn_orient_matrix_UB_33      -0.0155125000
_diffrn_radiation_collimation    0.3
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0468
_diffrn_reflns_av_unetI/netI     0.0421
_diffrn_reflns_Laue_measured_fraction_full 0.976
_diffrn_reflns_Laue_measured_fraction_max 0.988
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            18776
_diffrn_reflns_point_group_measured_fraction_full 0.976
_diffrn_reflns_point_group_measured_fraction_max 0.988
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         67.076
_diffrn_reflns_theta_min         3.041
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_current           24.0
_diffrn_source_power             1.2
_diffrn_source_target            Mo
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_diffrn_source_voltage           50.0
_exptl_absorpt_coefficient_mu    12.270
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.37290
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.25a (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear light yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.960
_exptl_crystal_description       block
_exptl_crystal_F_000             3600
_exptl_crystal_size_max          0.04
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.441
_refine_diff_density_min         -1.025
_refine_diff_density_rms         0.106
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     439
_refine_ls_number_reflns         5457
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.038
_refine_ls_R_factor_all          0.0437
_refine_ls_R_factor_gt           0.0367
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0455P)²+26.5270P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0903
_refine_ls_wR_factor_ref         0.0985
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4855
_reflns_number_total             5457
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9dt03985f2.cif
_cod_data_source_block           190404a
_cod_depositor_comments
'Adding full bibliography for 7703251--7703253.cif.'
_cod_database_code               7703253
_shelxl_version_number           2013-4
_chemical_oxdiff_formula         AgCNO
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.791
_shelx_estimated_absorpt_t_min   0.640
_reflns_odcompleteness_completeness 98.87
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H,H) groups
2.a Free rotating group:
 O8(H8A,H8B)
2.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C8(H8), C12(H12), C14(H14), C16(H16), C17(H17),
 C19(H19), C20(H20), C21(H21), C22(H22), C23(H23), C26(H26)
2.c Idealised Me refined as rotating group:
 C24(H24A,H24B,H24C), C25(H25A,H25B,H25C)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.833
_oxdiff_exptl_absorpt_empirical_full_min 0.704
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Ag1 Ag 0.63761(2) 0.73331(2) 0.29377(2) 0.03491(11) Uani 1 1 d . . .
Ag2 Ag 0.50355(2) 0.57324(2) 0.43204(2) 0.03945(11) Uani 1 1 d . . .
S1 S 0.46918(7) 0.64790(8) 0.53387(3) 0.0334(2) Uani 1 1 d . . .
S2 S 0.38835(7) 0.72915(8) 0.34670(3) 0.0346(2) Uani 1 1 d . . .
F1 F 0.3858(2) 0.9028(2) 0.37773(11) 0.0619(8) Uani 1 1 d . . .
F2 F 0.3543(2) 0.7852(3) 0.51787(12) 0.0670(9) Uani 1 1 d . . .
F3 F 0.4587(2) 0.8045(3) 0.42375(12) 0.0760(10) Uani 1 1 d . . .
F4 F 0.3174(3) 0.8042(3) 0.41648(12) 0.0757(10) Uani 1 1 d . . .
F5 F 0.4085(3) 0.7736(3) 0.58782(12) 0.0808(12) Uani 1 1 d . . .
F6 F 0.3113(3) 0.6735(3) 0.55967(15) 0.0827(12) Uani 1 1 d . . .
O1 O 0.4261(2) 0.5929(2) 0.49608(10) 0.0410(7) Uani 1 1 d . . .
O2 O 0.6235(2) 0.8442(2) 0.21298(10) 0.0411(7) Uani 1 1 d . . .
O3 O 0.5711(2) 0.6157(2) 0.21841(10) 0.0423(7) Uani 1 1 d . . .
O4 O 0.3965(2) 0.6380(2) 0.37030(11) 0.0414(7) Uani 1 1 d . . .
O5 O 0.5364(2) 0.7114(3) 0.52125(14) 0.0559(9) Uani 1 1 d . . .
O6 O 0.4659(2) 0.7561(3) 0.32490(13) 0.0544(9) Uani 1 1 d . . .
O7 O 0.3046(2) 0.7448(3) 0.31979(11) 0.0469(8) Uani 1 1 d . . .
O9 O 0.4918(3) 0.5924(3) 0.57509(12) 0.0582(10) Uani 1 1 d . . .
N1 N 0.6649(2) 0.8854(2) 0.28566(11) 0.0308(7) Uani 1 1 d . . .
N2 N 0.6222(2) 0.5773(2) 0.29039(11) 0.0304(7) Uani 1 1 d . . .
C1 C 0.7430(3) 0.8395(3) 0.45572(13) 0.0313(8) Uani 1 1 d . . .
C2 C 0.7500 0.7865(4) 0.5000 0.0319(12) Uani 1 2 d S T P
C3 C 0.6216(2) 0.6300(3) 0.38636(12) 0.0275(8) Uani 1 1 d . . .
H3 H 0.5729 0.6551 0.3671 0.033 Uiso 1 1 calc R . .
C4 C 0.7628(3) 0.5551(3) 0.44351(14) 0.0327(9) Uani 1 1 d . . .
H4 H 0.8102 0.5284 0.4631 0.039 Uiso 1 1 calc R . .
C5 C 0.7389(3) 0.5139(3) 0.40053(13) 0.0302(8) Uani 1 1 d . . .
H5 H 0.7692 0.4589 0.3915 0.036 Uiso 1 1 calc R . .
C6 C 0.7185(2) 0.6342(3) 0.45806(12) 0.0296(8) Uani 1 1 d . . .
C7 C 0.6705(3) 0.5532(3) 0.37077(13) 0.0285(8) Uani 1 1 d . . .
C8 C 0.6439(2) 0.6691(3) 0.42942(13) 0.0283(8) Uani 1 1 d . . .
H8 H 0.6092 0.7194 0.4399 0.034 Uiso 1 1 calc R . .
C9 C 0.6472(3) 0.9158(3) 0.24228(14) 0.0331(9) Uani 1 1 d . . .
C10 C 0.5926(3) 0.5445(3) 0.24868(13) 0.0320(9) Uani 1 1 d . . .
C11 C 0.7500 0.6888(4) 0.5000 0.0290(12) Uani 1 2 d S T P
C12 C 0.7697(2) 0.8405(3) 0.37522(14) 0.0321(9) Uani 1 1 d . . .
H12 H 0.7987 0.8145 0.3507 0.039 Uiso 1 1 calc R . .
C13 C 0.6454(2) 0.5136(3) 0.32440(13) 0.0284(8) Uani 1 1 d . . .
C14 C 0.6428(3) 0.4174(3) 0.31613(15) 0.0367(9) Uani 1 1 d . . .
H14 H 0.6620 0.3737 0.3399 0.044 Uiso 1 1 calc R . .
C15 C 0.7089(3) 0.9138(3) 0.36670(14) 0.0324(9) Uani 1 1 d . . .
C16 C 0.7882(3) 0.8050(3) 0.41931(14) 0.0340(9) Uani 1 1 d . . .
H16 H 0.8319 0.7568 0.4250 0.041 Uiso 1 1 calc R . .
C17 C 0.6534(3) 1.0113(3) 0.23002(15) 0.0393(10) Uani 1 1 d . . .
H17 H 0.6410 1.0309 0.1989 0.047 Uiso 1 1 calc R . .
C18 C 0.6882(3) 0.9501(3) 0.31931(14) 0.0315(8) Uani 1 1 d . . .
C19 C 0.6877(3) 0.9174(3) 0.44770(14) 0.0386(10) Uani 1 1 d . . .
H19 H 0.6609 0.9453 0.4725 0.046 Uiso 1 1 calc R . .
C20 C 0.6709(3) 0.9554(3) 0.40356(15) 0.0396(10) Uani 1 1 d . . .
H20 H 0.6337 1.0096 0.3986 0.048 Uiso 1 1 calc R . .
C21 C 0.6119(3) 0.3850(3) 0.27260(15) 0.0412(10) Uani 1 1 d . . .
H21 H 0.6087 0.3186 0.2666 0.049 Uiso 1 1 calc R . .
C22 C 0.6948(3) 1.0459(3) 0.30903(15) 0.0373(9) Uani 1 1 d . . .
H22 H 0.7109 1.0906 0.3328 0.045 Uiso 1 1 calc R . .
C23 C 0.6778(3) 1.0759(3) 0.26392(16) 0.0402(10) Uani 1 1 d . . .
H23 H 0.6830 1.1413 0.2565 0.048 Uiso 1 1 calc R . .
C24 C 0.5343(3) 0.5905(4) 0.17327(15) 0.0450(11) Uani 1 1 d . . .
H24A H 0.5158 0.6481 0.1561 0.068 Uiso 1 1 calc GR . .
H24B H 0.4827 0.5491 0.1753 0.068 Uiso 1 1 calc GR . .
H24C H 0.5790 0.5568 0.1574 0.068 Uiso 1 1 calc GR . .
C25 C 0.5931(3) 0.8689(4) 0.16644(14) 0.0439(11) Uani 1 1 d . . .
H25A H 0.5701 0.8120 0.1499 0.066 Uiso 1 1 calc GR . .
H25B H 0.6426 0.8951 0.1512 0.066 Uiso 1 1 calc GR . .
H25C H 0.5458 0.9166 0.1664 0.066 Uiso 1 1 calc GR . .
C26 C 0.5859(3) 0.4483(3) 0.23817(14) 0.0373(9) Uani 1 1 d . . .
H26 H 0.5641 0.4272 0.2083 0.045 Uiso 1 1 calc R . .
C27 C 0.3876(3) 0.8145(3) 0.39354(16) 0.0430(11) Uani 1 1 d . . .
C28 C 0.3808(4) 0.7245(4) 0.55073(17) 0.0488(12) Uani 1 1 d . . .
O8 O 0.4683(2) 1.0380(2) 0.45466(11) 0.0433(7) Uani 1 1 d . . .
H8A H 0.4202 1.0123 0.4632 0.065 Uiso 1 1 d G . .
H8B H 0.5011 1.0586 0.4788 0.065 Uiso 1 1 d G . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N2 169.59(12) . .
O1 Ag2 O4 101.38(11) . .
O1 Ag2 O9 102.24(13) . 5_666
O1 Ag2 C3 148.04(12) . .
O1 Ag2 C8 117.04(12) . .
O4 Ag2 C8 105.86(11) . .
O9 Ag2 O4 108.95(12) 5_666 .
O9 Ag2 C3 104.16(14) 5_666 .
O9 Ag2 C8 119.78(14) 5_666 .
C3 Ag2 O4 86.76(11) . .
C3 Ag2 C8 32.18(12) . .
O1 S1 C28 103.6(2) . .
O5 S1 O1 114.5(2) . .
O5 S1 O9 115.8(2) . .
O5 S1 C28 105.1(2) . .
O9 S1 O1 113.4(2) . .
O9 S1 C28 102.3(2) . .
O4 S2 C27 103.4(2) . .
O6 S2 O4 114.0(2) . .
O6 S2 O7 115.4(2) . .
O6 S2 C27 103.0(2) . .
O7 S2 O4 115.0(2) . .
O7 S2 C27 103.8(2) . .
S1 O1 Ag2 116.92(17) . .
C9 O2 C25 117.5(4) . .
C10 O3 C24 117.8(4) . .
S2 O4 Ag2 133.48(19) . .
S1 O9 Ag2 118.0(2) . 5_666
C9 N1 Ag1 113.0(3) . .
C9 N1 C18 118.9(4) . .
C18 N1 Ag1 127.7(3) . .
C10 N2 Ag1 114.1(3) . .
C10 N2 C13 118.5(4) . .
C13 N2 Ag1 127.2(3) . .
C16 C1 C2 119.1(4) . .
C19 C1 C2 122.2(4) . .
C19 C1 C16 118.4(4) . .
C1 C2 C1 119.9(5) . 2_656
C11 C2 C1 120.1(3) . 2_656
C11 C2 C1 120.1(3) . .
C7 C3 Ag2 111.0(3) . .
C8 C3 Ag2 76.2(2) . .
C8 C3 C7 120.6(3) . .
C6 C4 C5 121.2(4) . .
C4 C5 C7 120.3(4) . .
C4 C6 C8 118.4(4) . .
C4 C6 C11 122.9(3) . .
C8 C6 C11 118.6(4) . .
C3 C7 C13 119.2(3) . .
C5 C7 C3 118.8(3) . .
C5 C7 C13 121.9(4) . .
C3 C8 Ag2 71.7(2) . .
C3 C8 C6 120.3(4) . .
C6 C8 Ag2 114.8(3) . .
O2 C9 C17 125.2(4) . .
N1 C9 O2 112.2(4) . .
N1 C9 C17 122.5(4) . .
O3 C10 C26 124.7(4) . .
N2 C10 O3 112.1(4) . .
N2 C10 C26 123.2(4) . .
C2 C11 C6 121.2(3) . 2_656
C2 C11 C6 121.2(3) . .
C6 C11 C6 117.7(5) 2_656 .
C16 C12 C15 120.3(4) . .
N2 C13 C7 116.4(4) . .
N2 C13 C14 121.4(4) . .
C14 C13 C7 122.1(4) . .
C13 C14 C21 119.1(4) . .
C12 C15 C18 120.0(4) . .
C12 C15 C20 119.3(4) . .
C20 C15 C18 120.7(4) . .
C12 C16 C1 120.7(4) . .
C23 C17 C9 118.3(4) . .
N1 C18 C15 117.4(4) . .
N1 C18 C22 120.9(4) . .
C22 C18 C15 121.7(4) . .
C1 C19 C20 120.7(4) . .
C19 C20 C15 120.0(4) . .
C26 C21 C14 120.3(4) . .
C23 C22 C18 119.5(4) . .
C17 C23 C22 119.9(4) . .
C21 C26 C10 117.5(4) . .
F1 C27 S2 111.0(3) . .
F1 C27 F3 108.5(4) . .
F3 C27 S2 111.4(4) . .
F4 C27 S2 112.0(3) . .
F4 C27 F1 106.9(4) . .
F4 C27 F3 106.9(4) . .
F2 C28 S1 111.4(3) . .
F2 C28 F5 108.0(5) . .
F2 C28 F6 107.8(5) . .
F5 C28 S1 110.5(4) . .
F5 C28 F6 108.5(4) . .
F6 C28 S1 110.7(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.196(3) .
Ag1 N2 2.208(3) .
Ag2 O1 2.320(3) .
Ag2 O4 2.475(3) .
Ag2 O9 2.341(4) 5_666
Ag2 C3 2.465(4) .
Ag2 C8 2.522(4) .
S1 O1 1.449(3) .
S1 O5 1.428(4) .
S1 O9 1.447(4) .
S1 C28 1.822(5) .
S2 O4 1.455(3) .
S2 O6 1.439(4) .
S2 O7 1.440(3) .
S2 C27 1.821(5) .
F1 C27 1.324(6) .
F2 C28 1.317(6) .
F3 C27 1.329(5) .
F4 C27 1.318(6) .
F5 C28 1.318(7) .
F6 C28 1.319(7) .
O2 C9 1.347(5) .
O2 C25 1.434(5) .
O3 C10 1.354(5) .
O3 C24 1.425(5) .
O9 Ag2 2.341(4) 5_666
N1 C9 1.338(5) .
N1 C18 1.360(6) .
N2 C10 1.338(5) .
N2 C13 1.358(5) .
C1 C2 1.487(5) .
C1 C16 1.406(6) .
C1 C19 1.385(6) .
C2 C1 1.487(5) 2_656
C2 C11 1.374(9) .
C3 C7 1.410(6) .
C3 C8 1.383(5) .
C4 C5 1.397(6) .
C4 C6 1.388(6) .
C5 C7 1.397(6) .
C6 C8 1.424(5) .
C6 C11 1.484(5) .
C7 C13 1.479(5) .
C9 C17 1.396(6) .
C10 C26 1.389(6) .
C11 C6 1.484(5) 2_656
C12 C15 1.388(6) .
C12 C16 1.384(6) .
C13 C14 1.374(6) .
C14 C21 1.388(6) .
C15 C18 1.480(6) .
C15 C20 1.398(6) .
C17 C23 1.367(7) .
C18 C22 1.386(6) .
C19 C20 1.395(6) .
C21 C26 1.371(7) .
C22 C23 1.383(6) .
