#------------------------------------------------------------------------------
#$Date: 2020-05-05 16:29:40 +0300 (Tue, 05 May 2020) $
#$Revision: 251663 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/39/7703913.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7703913
loop_
_publ_author_name
'Fortuño, Consuelo'
'Martín, Antonio'
'Mastrorilli, Piero'
'Latronico, Mario'
'Petrelli, Valentina'
'Todisco, Stefano'
_publ_section_title
;
 Stable mixed-valence diphenylphosphanido bridged
 platinum(ii)-platinum(iv) complexes.
;
_journal_issue                   15
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4935
_journal_page_last               4955
_journal_paper_doi               10.1039/d0dt00712a
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C52 H34 F10 N2 P2 Pt2 S2, 2(C H2 Cl2)'
_chemical_formula_sum            'C54 H38 Cl4 F10 N2 P2 Pt2 S2'
_chemical_formula_weight         1562.90
_chemical_name_common            'CFT 128.1 CH2Cl2/hex'
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2020-02-06 deposited with the CCDC.	2020-03-23 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 97.5230(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.9852(9)
_cell_length_b                   24.082(2)
_cell_length_c                   20.5966(17)
_cell_measurement_reflns_used    9807
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      30.8847
_cell_measurement_theta_min      2.5217
_cell_volume                     5401.8(8)
_computing_cell_refinement       'SAINT V8.38A (Bruker AXS Inc., 2017)'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'SAINT V8.38A (Bruker AXS Inc., 2017)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.3333
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.923
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0228
_diffrn_reflns_av_unetI/netI     0.0264
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.923
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -34
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            50792
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.923
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         31.096
_diffrn_reflns_theta_min         1.307
_exptl_absorpt_coefficient_mu    5.583
_exptl_absorpt_correction_T_max  0.4335
_exptl_absorpt_correction_T_min  0.3531
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 - Bruker AXS area detector scaling and absorption correction
;
_exptl_crystal_colour            'clear colourless'
_exptl_crystal_density_diffrn    1.922
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             3008
_exptl_crystal_size_max          0.340
_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.180
_refine_diff_density_max         1.338
_refine_diff_density_min         -1.453
_refine_diff_density_rms         0.113
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     715
_refine_ls_number_reflns         16002
_refine_ls_number_restraints     18
_refine_ls_restrained_S_all      1.007
_refine_ls_R_factor_all          0.0298
_refine_ls_R_factor_gt           0.0232
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0214P)²+9.8809P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0505
_refine_ls_wR_factor_ref         0.0525
_reflns_Friedel_coverage         0.000
_reflns_number_gt                14119
_reflns_number_total             16002
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0dt00712a2.cif
_cod_data_source_block           4_AMT1181
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-Scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7703910--7703914.cif.
;
_cod_original_cell_volume        5401.9(8)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7703913
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.253
_shelx_estimated_absorpt_t_max   0.433
_shelxl_version_number           2013-4
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.72778(2) 0.39792(2) 0.80468(2) 0.01126(2) Uani 1 1 d . . . . .
Pt2 Pt 0.62999(2) 0.52142(2) 0.71832(2) 0.00983(2) Uani 1 1 d . . . . .
P1 P 0.81144(6) 0.47196(3) 0.75327(3) 0.01132(12) Uani 1 1 d . . . . .
P2 P 0.57396(6) 0.46353(3) 0.79988(3) 0.01167(12) Uani 1 1 d . . . . .
S1 S 0.65552(6) 0.60258(3) 0.78850(3) 0.01489(12) Uani 1 1 d . . . . .
S2 S 0.43709(6) 0.57411(3) 0.70176(3) 0.01589(12) Uani 1 1 d . . . . .
F1 F 0.75296(15) 0.30736(7) 0.69382(9) 0.0241(4) Uani 1 1 d . . . . .
F2 F 0.91802(19) 0.23047(8) 0.67740(11) 0.0380(5) Uani 1 1 d . . . . .
F3 F 1.10982(19) 0.21015(9) 0.77239(13) 0.0484(6) Uani 1 1 d . . . . .
F4 F 1.13468(19) 0.27228(9) 0.88413(12) 0.0457(6) Uani 1 1 d . . . . .
F5 F 0.97473(17) 0.35284(8) 0.90051(9) 0.0302(4) Uani 1 1 d . . . . .
F6 F 0.73320(17) 0.37287(7) 0.95877(8) 0.0251(4) Uani 1 1 d . . . . .
F7 F 0.6113(2) 0.29986(9) 1.02448(9) 0.0364(5) Uani 1 1 d . . . . .
F8 F 0.4515(2) 0.22664(8) 0.95923(11) 0.0396(5) Uani 1 1 d . . . . .
F9 F 0.40977(19) 0.22936(8) 0.82552(11) 0.0374(5) Uani 1 1 d . . . . .
F10 F 0.52847(17) 0.30223(7) 0.75900(8) 0.0262(4) Uani 1 1 d . . . . .
N1 N 0.68991(19) 0.56631(9) 0.63743(10) 0.0123(4) Uani 1 1 d . . . . .
N2 N 0.4485(2) 0.66146(10) 0.78396(12) 0.0210(5) Uani 1 1 d . . . . .
C1 C 0.8578(2) 0.33665(11) 0.79670(14) 0.0178(5) Uani 1 1 d . . . . .
C2 C 0.8483(3) 0.30216(11) 0.74247(16) 0.0212(6) Uani 1 1 d . . . . .
C3 C 0.9318(3) 0.26074(12) 0.73281(18) 0.0270(7) Uani 1 1 d . . . . .
C4 C 1.0291(3) 0.25061(13) 0.7806(2) 0.0333(8) Uani 1 1 d . . . . .
C5 C 1.0400(3) 0.28198(13) 0.83649(19) 0.0317(8) Uani 1 1 d . . . . .
C6 C 0.9557(3) 0.32375(12) 0.84354(16) 0.0241(6) Uani 1 1 d . . . . .
C7 C 0.6374(2) 0.34096(11) 0.85547(13) 0.0146(5) Uani 1 1 d . . . . .
C8 C 0.6538(3) 0.33783(11) 0.92325(13) 0.0175(5) Uani 1 1 d . . . . .
C9 C 0.5923(3) 0.30049(12) 0.95854(15) 0.0234(6) Uani 1 1 d . . . . .
C10 C 0.5106(3) 0.26350(12) 0.92575(17) 0.0263(7) Uani 1 1 d . . . . .
C11 C 0.4904(3) 0.26500(12) 0.85832(16) 0.0242(6) Uani 1 1 d . . . . .
C12 C 0.5536(3) 0.30294(11) 0.82516(14) 0.0184(5) Uani 1 1 d . . . . .
C13 C 0.6003(2) 0.46137(11) 0.64629(12) 0.0123(5) Uani 1 1 d . . . . .
C14 C 0.5628(2) 0.40666(11) 0.64919(13) 0.0154(5) Uani 1 1 d . . . . .
H14 H 0.5443 0.3920 0.6896 0.019 Uiso 1 1 calc R U . . .
C15 C 0.5515(3) 0.37233(12) 0.59316(15) 0.0198(6) Uani 1 1 d . . . . .
H15 H 0.5243 0.3351 0.5964 0.024 Uiso 1 1 calc R U . . .
C16 C 0.5790(3) 0.39180(12) 0.53415(14) 0.0204(6) Uani 1 1 d . . . . .
H16 H 0.5698 0.3682 0.4969 0.024 Uiso 1 1 calc R U . . .
C17 C 0.6208(2) 0.44645(12) 0.52881(13) 0.0168(5) Uani 1 1 d . . . . .
C18 C 0.6542(3) 0.46905(13) 0.46932(13) 0.0202(6) Uani 1 1 d . . . . .
H18 H 0.6469 0.4464 0.4313 0.024 Uiso 1 1 calc R U . . .
C19 C 0.6959(2) 0.52190(13) 0.46554(13) 0.0193(5) Uani 1 1 d . . . . .
H19 H 0.7161 0.5356 0.4250 0.023 Uiso 1 1 calc R U . . .
C20 C 0.7099(2) 0.55710(12) 0.52219(12) 0.0157(5) Uani 1 1 d . . . . .
C21 C 0.7536(3) 0.61179(12) 0.52224(14) 0.0191(5) Uani 1 1 d . . . . .
H21 H 0.7756 0.6278 0.4833 0.023 Uiso 1 1 calc R U . . .
C22 C 0.7642(3) 0.64201(12) 0.57935(14) 0.0197(5) Uani 1 1 d . . . . .
H22 H 0.7938 0.6791 0.5800 0.024 Uiso 1 1 calc R U . . .
C23 C 0.7314(2) 0.61807(11) 0.63635(13) 0.0154(5) Uani 1 1 d . . . . .
H23 H 0.7390 0.6394 0.6755 0.019 Uiso 1 1 calc R U . . .
C24 C 0.6780(2) 0.53549(11) 0.58129(12) 0.0120(5) Uani 1 1 d . . . . .
C25 C 0.6311(2) 0.48065(11) 0.58548(12) 0.0135(5) Uani 1 1 d . . . . .
C26 C 0.5055(2) 0.61913(11) 0.76073(13) 0.0157(5) Uani 1 1 d . . . . .
C27 C 0.5126(3) 0.69703(12) 0.83490(15) 0.0275(7) Uani 1 1 d . . . . .
H27A H 0.5522 0.6739 0.8708 0.041 Uiso 1 1 calc R U . . .
H27B H 0.4536 0.7221 0.8516 0.041 Uiso 1 1 calc R U . . .
H27C H 0.5750 0.7189 0.8165 0.041 Uiso 1 1 calc R U . . .
C28 C 0.3209(3) 0.67400(15) 0.7613(2) 0.0356(8) Uani 1 1 d . . . . .
H28A H 0.2858 0.6445 0.7318 0.053 Uiso 1 1 calc R U . . .
H28B H 0.3155 0.7095 0.7379 0.053 Uiso 1 1 calc R U . . .
H28C H 0.2750 0.6764 0.7989 0.053 Uiso 1 1 calc R U . . .
C29 C 0.8963(2) 0.46476(11) 0.68309(13) 0.0139(5) Uani 1 1 d . . . . .
C30 C 0.8783(2) 0.41696(12) 0.64477(14) 0.0180(5) Uani 1 1 d . . . . .
H30 H 0.8290 0.3877 0.6579 0.022 Uiso 1 1 calc R U . . .
C31 C 0.9319(3) 0.41177(14) 0.58738(14) 0.0233(6) Uani 1 1 d . . . . .
H31 H 0.9199 0.3788 0.5620 0.028 Uiso 1 1 calc R U . . .
C32 C 1.0024(3) 0.45438(14) 0.56740(14) 0.0242(6) Uani 1 1 d . . . . .
H32 H 1.0376 0.4511 0.5278 0.029 Uiso 1 1 calc R U . . .
C33 C 1.0215(3) 0.50199(13) 0.60531(15) 0.0237(6) Uani 1 1 d . . . . .
H33 H 1.0705 0.5312 0.5918 0.028 Uiso 1 1 calc R U . . .
C34 C 0.9696(3) 0.50717(12) 0.66278(14) 0.0186(5) Uani 1 1 d . . . . .
H34 H 0.9839 0.5398 0.6886 0.022 Uiso 1 1 calc R U . . .
C35 C 0.9112(2) 0.51383(11) 0.81219(13) 0.0150(5) Uani 1 1 d . . . . .
C36 C 0.9362(3) 0.57011(12) 0.80324(15) 0.0201(6) Uani 1 1 d . . . . .
H36 H 0.8991 0.5887 0.7650 0.024 Uiso 1 1 calc R U . . .
C37 C 1.0145(3) 0.59892(13) 0.84953(17) 0.0280(7) Uani 1 1 d . . . . .
H37 H 1.0314 0.6370 0.8427 0.034 Uiso 1 1 calc R U . . .
C38 C 1.0685(3) 0.57241(15) 0.90588(17) 0.0323(7) Uani 1 1 d . . . . .
H38 H 1.1219 0.5923 0.9377 0.039 Uiso 1 1 calc R U . . .
C39 C 1.0442(3) 0.51687(14) 0.91548(16) 0.0288(7) Uani 1 1 d . . . . .
H39 H 1.0809 0.4986 0.9540 0.035 Uiso 1 1 calc R U . . .
C40 C 0.9665(3) 0.48773(12) 0.86904(14) 0.0205(6) Uani 1 1 d . . . . .
H40 H 0.9507 0.4495 0.8760 0.025 Uiso 1 1 calc R U . . .
C41 C 0.5614(2) 0.50452(11) 0.87282(13) 0.0154(5) Uani 1 1 d . . . . .
C42 C 0.4544(3) 0.53494(12) 0.87821(14) 0.0190(5) Uani 1 1 d . . . . .
H42 H 0.3849 0.5310 0.8459 0.023 Uiso 1 1 calc R U . . .
C43 C 0.4494(3) 0.57065(13) 0.93026(15) 0.0252(6) Uani 1 1 d . . . . .
H43 H 0.3766 0.5911 0.9337 0.030 Uiso 1 1 calc R U . . .
C44 C 0.5503(3) 0.57655(14) 0.97736(15) 0.0315(7) Uani 1 1 d . . . . .
H44 H 0.5476 0.6020 1.0123 0.038 Uiso 1 1 calc R U . . .
C45 C 0.6551(3) 0.54558(14) 0.97389(15) 0.0300(7) Uani 1 1 d . . . . .
H45 H 0.7232 0.5492 1.0071 0.036 Uiso 1 1 calc R U . . .
C46 C 0.6614(3) 0.50918(12) 0.92195(13) 0.0207(6) Uani 1 1 d . . . . .
H46 H 0.7332 0.4876 0.9199 0.025 Uiso 1 1 calc R U . . .
C47 C 0.4173(2) 0.43675(11) 0.78316(13) 0.0144(5) Uani 1 1 d . . . . .
C48 C 0.3416(2) 0.44177(12) 0.72359(13) 0.0173(5) Uani 1 1 d . . . . .
H48 H 0.3711 0.4603 0.6880 0.021 Uiso 1 1 calc R U . . .
C49 C 0.2237(3) 0.42001(13) 0.71577(15) 0.0226(6) Uani 1 1 d . . . . .
H49 H 0.1735 0.4231 0.6747 0.027 Uiso 1 1 calc R U . . .
C50 C 0.1786(3) 0.39370(14) 0.76786(16) 0.0271(7) Uani 1 1 d . . . . .
H50 H 0.0976 0.3791 0.7626 0.033 Uiso 1 1 calc R U . . .
C51 C 0.2527(3) 0.38894(14) 0.82751(16) 0.0256(6) Uani 1 1 d . . . . .
H51 H 0.2220 0.3714 0.8634 0.031 Uiso 1 1 calc R U . . .
C52 C 0.3711(3) 0.40961(12) 0.83494(14) 0.0190(5) Uani 1 1 d . . . . .
H52 H 0.4218 0.4054 0.8757 0.023 Uiso 1 1 calc R U . . .
C53 C 0.8064(6) 0.2003(3) 0.9181(4) 0.063(2) Uani 0.7 1 d . . P A 1
H53A H 0.7889 0.2299 0.8848 0.076 Uiso 0.7 1 calc R U P A 1
H53B H 0.7278 0.1818 0.9234 0.076 Uiso 0.7 1 calc R U P A 1
Cl1 Cl 0.8666(4) 0.22947(14) 0.99099(19) 0.1282(15) Uani 0.7 1 d . U P A 1
Cl2 Cl 0.9066(2) 0.15199(11) 0.89094(16) 0.0738(9) Uani 0.7 1 d . . P A 1
C53' C 0.8910(18) 0.2260(8) 0.9511(9) 0.056(4) Uani 0.3 1 d . U P B 2
H53C H 0.8474 0.2551 0.9232 0.067 Uiso 0.3 1 calc R U P B 2
H53D H 0.9801 0.2337 0.9541 0.067 Uiso 0.3 1 calc R U P B 2
Cl1' Cl 0.8475(4) 0.2302(2) 1.0283(2) 0.0515(11) Uani 0.3 1 d . . P B 2
Cl2' Cl 0.8616(11) 0.1632(4) 0.9145(4) 0.117(3) Uani 0.3 1 d . U P B 2
C54 C 1.1631(5) 0.2262(2) 0.6018(3) 0.0685(15) Uani 1 1 d . . . . .
H54A H 1.1907 0.1955 0.6321 0.082 Uiso 1 1 calc R U . . .
H54B H 1.0737 0.2219 0.5883 0.082 Uiso 1 1 calc R U . . .
Cl3 Cl 1.19111(15) 0.28937(6) 0.64212(9) 0.0845(5) Uani 1 1 d . . . . .
Cl4 Cl 1.2386(2) 0.22216(10) 0.53369(8) 0.1172(8) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C7 Pt1 C1 87.08(10) . . ?
C7 Pt1 P2 94.54(7) . . ?
C1 Pt1 P2 172.72(8) . . ?
C7 Pt1 P1 171.56(7) . . ?
C1 Pt1 P1 101.07(7) . . ?
P2 Pt1 P1 77.65(2) . . ?
C13 Pt2 N1 80.32(9) . . ?
C13 Pt2 P2 93.85(7) . . ?
N1 Pt2 P2 173.13(6) . . ?
C13 Pt2 P1 85.01(7) . . ?
N1 Pt2 P1 99.08(6) . . ?
P2 Pt2 P1 76.66(2) . . ?
C13 Pt2 S1 170.66(7) . . ?
N1 Pt2 S1 91.91(6) . . ?
P2 Pt2 S1 94.21(2) . . ?
P1 Pt2 S1 101.45(2) . . ?
C13 Pt2 S2 102.11(7) . . ?
N1 Pt2 S2 88.79(6) . . ?
P2 Pt2 S2 96.02(2) . . ?
P1 Pt2 S2 170.23(2) . . ?
S1 Pt2 S2 72.34(2) . . ?
C29 P1 C35 104.70(12) . . ?
C29 P1 Pt1 124.10(9) . . ?
C35 P1 Pt1 111.06(9) . . ?
C29 P1 Pt2 107.78(8) . . ?
C35 P1 Pt2 109.51(9) . . ?
Pt1 P1 Pt2 99.10(2) . . ?
C41 P2 C47 100.11(12) . . ?
C41 P2 Pt1 118.11(9) . . ?
C47 P2 Pt1 115.65(9) . . ?
C41 P2 Pt2 109.10(9) . . ?
C47 P2 Pt2 114.01(9) . . ?
Pt1 P2 Pt2 100.36(3) . . ?
C26 S1 Pt2 87.56(9) . . ?
C26 S2 Pt2 86.47(9) . . ?
C23 N1 C24 119.4(2) . . ?
C23 N1 Pt2 128.48(18) . . ?
C24 N1 Pt2 112.08(17) . . ?
C26 N2 C28 122.0(3) . . ?
C26 N2 C27 120.4(3) . . ?
C28 N2 C27 117.6(2) . . ?
C6 C1 C2 113.4(3) . . ?
C6 C1 Pt1 125.8(2) . . ?
C2 C1 Pt1 120.7(2) . . ?
F1 C2 C1 120.6(2) . . ?
F1 C2 C3 114.9(3) . . ?
C1 C2 C3 124.5(3) . . ?
F2 C3 C4 120.1(3) . . ?
F2 C3 C2 120.5(3) . . ?
C4 C3 C2 119.4(3) . . ?
F3 C4 C5 121.4(3) . . ?
F3 C4 C3 120.1(3) . . ?
C5 C4 C3 118.5(3) . . ?
F4 C5 C4 119.2(3) . . ?
F4 C5 C6 120.6(3) . . ?
C4 C5 C6 120.1(3) . . ?
F5 C6 C1 120.3(3) . . ?
F5 C6 C5 115.7(3) . . ?
C1 C6 C5 124.0(3) . . ?
C8 C7 C12 114.1(2) . . ?
C8 C7 Pt1 122.7(2) . . ?
C12 C7 Pt1 123.2(2) . . ?
F6 C8 C7 119.9(2) . . ?
F6 C8 C9 116.3(2) . . ?
C7 C8 C9 123.7(3) . . ?
F7 C9 C10 119.5(3) . . ?
F7 C9 C8 120.9(3) . . ?
C10 C9 C8 119.6(3) . . ?
F8 C10 C9 120.2(3) . . ?
F8 C10 C11 120.7(3) . . ?
C9 C10 C11 119.1(3) . . ?
F9 C11 C10 119.8(3) . . ?
F9 C11 C12 120.8(3) . . ?
C10 C11 C12 119.4(3) . . ?
F10 C12 C11 116.1(3) . . ?
F10 C12 C7 119.8(2) . . ?
C11 C12 C7 124.1(3) . . ?
C14 C13 C25 117.2(2) . . ?
C14 C13 Pt2 130.9(2) . . ?
C25 C13 Pt2 111.81(18) . . ?
C13 C14 C15 121.1(3) . . ?
C16 C15 C14 121.2(3) . . ?
C15 C16 C17 120.1(3) . . ?
C16 C17 C25 118.1(3) . . ?
C16 C17 C18 123.1(3) . . ?
C25 C17 C18 118.7(3) . . ?
C19 C18 C17 122.1(3) . . ?
C18 C19 C20 120.5(3) . . ?
C21 C20 C24 118.1(2) . . ?
C21 C20 C19 123.8(3) . . ?
C24 C20 C19 118.2(3) . . ?
C22 C21 C20 119.2(3) . . ?
C21 C22 C23 119.9(3) . . ?
N1 C23 C22 121.9(3) . . ?
N1 C24 C20 121.5(2) . . ?
N1 C24 C25 116.6(2) . . ?
C20 C24 C25 121.8(2) . . ?
C13 C25 C17 122.2(2) . . ?
C13 C25 C24 119.2(2) . . ?
C17 C25 C24 118.6(2) . . ?
N2 C26 S1 122.6(2) . . ?
N2 C26 S2 123.8(2) . . ?
S1 C26 S2 113.51(15) . . ?
C30 C29 C34 118.6(3) . . ?
C30 C29 P1 118.4(2) . . ?
C34 C29 P1 122.7(2) . . ?
C31 C30 C29 120.6(3) . . ?
C32 C31 C30 120.1(3) . . ?
C31 C32 C33 119.7(3) . . ?
C34 C33 C32 120.4(3) . . ?
C33 C34 C29 120.5(3) . . ?
C40 C35 C36 118.4(3) . . ?
C40 C35 P1 117.7(2) . . ?
C36 C35 P1 123.9(2) . . ?
C37 C36 C35 120.6(3) . . ?
C36 C37 C38 120.3(3) . . ?
C39 C38 C37 119.7(3) . . ?
C38 C39 C40 120.2(3) . . ?
C39 C40 C35 120.8(3) . . ?
C46 C41 C42 119.2(3) . . ?
C46 C41 P2 120.3(2) . . ?
C42 C41 P2 120.3(2) . . ?
C43 C42 C41 120.4(3) . . ?
C42 C43 C44 119.9(3) . . ?
C43 C44 C45 120.4(3) . . ?
C44 C45 C46 120.4(3) . . ?
C45 C46 C41 119.6(3) . . ?
C48 C47 C52 118.5(2) . . ?
C48 C47 P2 125.0(2) . . ?
C52 C47 P2 116.5(2) . . ?
C49 C48 C47 120.6(3) . . ?
C48 C49 C50 120.2(3) . . ?
C51 C50 C49 119.6(3) . . ?
C52 C51 C50 120.2(3) . . ?
C51 C52 C47 120.9(3) . . ?
Cl1 C53 Cl2 111.6(4) . . ?
Cl2' C53' Cl1' 113.7(10) . . ?
Cl4 C54 Cl3 111.4(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C7 2.057(3) . ?
Pt1 C1 2.075(3) . ?
Pt1 P2 2.3060(7) . ?
Pt1 P1 2.3237(7) . ?
Pt2 C13 2.067(3) . ?
Pt2 N1 2.160(2) . ?
Pt2 P2 2.3271(7) . ?
Pt2 P1 2.3526(7) . ?
Pt2 S1 2.4253(7) . ?
Pt2 S2 2.4550(7) . ?
P1 C29 1.828(3) . ?
P1 C35 1.828(3) . ?
P2 C41 1.818(3) . ?
P2 C47 1.828(3) . ?
S1 C26 1.719(3) . ?
S2 C26 1.725(3) . ?
F1 C2 1.358(3) . ?
F2 C3 1.346(4) . ?
F3 C4 1.343(3) . ?
F4 C5 1.354(4) . ?
F5 C6 1.359(4) . ?
F6 C8 1.357(3) . ?
F7 C9 1.347(3) . ?
F8 C10 1.342(3) . ?
F9 C11 1.349(3) . ?
F10 C12 1.355(3) . ?
N1 C23 1.328(3) . ?
N1 C24 1.366(3) . ?
N2 C26 1.319(3) . ?
N2 C28 1.450(4) . ?
N2 C27 1.462(4) . ?
C1 C6 1.382(4) . ?
C1 C2 1.385(4) . ?
C2 C3 1.387(4) . ?
C3 C4 1.377(5) . ?
C4 C5 1.368(5) . ?
C5 C6 1.388(4) . ?
C7 C8 1.386(4) . ?
C7 C12 1.388(4) . ?
C8 C9 1.387(4) . ?
C9 C10 1.377(5) . ?
C10 C11 1.378(5) . ?
C11 C12 1.381(4) . ?
C13 C14 1.384(4) . ?
C13 C25 1.418(4) . ?
C14 C15 1.412(4) . ?
C15 C16 1.373(4) . ?
C16 C17 1.403(4) . ?
C17 C25 1.421(4) . ?
C17 C18 1.432(4) . ?
C18 C19 1.359(4) . ?
C19 C20 1.434(4) . ?
C20 C21 1.402(4) . ?
C20 C24 1.410(4) . ?
C21 C22 1.375(4) . ?
C22 C23 1.397(4) . ?
C24 C25 1.424(4) . ?
C29 C30 1.395(4) . ?
C29 C34 1.398(4) . ?
C30 C31 1.394(4) . ?
C31 C32 1.380(5) . ?
C32 C33 1.388(5) . ?
C33 C34 1.385(4) . ?
C35 C40 1.396(4) . ?
C35 C36 1.400(4) . ?
C36 C37 1.384(4) . ?
C37 C38 1.388(5) . ?
C38 C39 1.383(5) . ?
C39 C40 1.386(4) . ?
C41 C46 1.397(4) . ?
C41 C42 1.401(4) . ?
C42 C43 1.381(4) . ?
C43 C44 1.382(5) . ?
C44 C45 1.381(5) . ?
C45 C46 1.392(4) . ?
C47 C48 1.394(4) . ?
C47 C52 1.401(4) . ?
C48 C49 1.387(4) . ?
C49 C50 1.392(4) . ?
C50 C51 1.387(4) . ?
C51 C52 1.382(4) . ?
C53 Cl1 1.710(9) . ?
C53 Cl2 1.743(8) . ?
C53' Cl2' 1.70(2) . ?
C53' Cl1' 1.722(16) . ?
C54 Cl4 1.723(5) . ?
C54 Cl3 1.741(6) . ?
