#------------------------------------------------------------------------------
#$Date: 2020-07-06 06:14:56 +0300 (Mon, 06 Jul 2020) $
#$Revision: 253922 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/41/7704196.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7704196
loop_
_publ_author_name
'Yabune, Natsuki'
'Nakajima, Hiroshi'
'Nishioka, Takanori'
_publ_section_title
;
 Metal-metal bond formation of triplatinum cores with a silver(i) ion
 affording a heptanuclear cluster bearing four Pt-Ag bonds.
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7680
_journal_page_last               7683
_journal_paper_doi               10.1039/d0dt01227k
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C57 H72 Ag F21 N24 O9 P2 Pt6 S7'
_chemical_formula_sum            'C57 H72 Ag F21 N24 O9 P2 Pt6 S7'
_chemical_formula_weight         3201.09
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2020-04-02 deposited with the CCDC.	2020-04-27 downloaded from the CCDC.
;
_cell_angle_alpha                90.0000
_cell_angle_beta                 108.832(2)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   22.410(3)
_cell_length_b                   22.131(3)
_cell_length_c                   18.447(3)
_cell_measurement_reflns_used    14981
_cell_measurement_temperature    193
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      3.02
_cell_volume                     8659(2)
_computing_cell_refinement       CrystalClear
_computing_data_collection       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'CrystalStructure 4.3'
_computing_publication_material  'CrystalStructure 4.3 (Rigaku, 2019)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    SIR97
_diffrn_ambient_temperature      193
_diffrn_detector_area_resol_mean 14.222
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Rigaku Saturn724'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0261
_diffrn_reflns_Laue_measured_fraction_full 0.000
_diffrn_reflns_Laue_measured_fraction_max 0.000
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            35559
_diffrn_reflns_point_group_measured_fraction_full 0.000
_diffrn_reflns_point_group_measured_fraction_max 0.000
_diffrn_reflns_theta_full        27.490
_diffrn_reflns_theta_max         27.490
_diffrn_reflns_theta_min         3.025
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    10.153
_exptl_absorpt_correction_T_max  0.544
_exptl_absorpt_correction_T_min  0.403
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.455
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             6000.00
_exptl_crystal_size_max          0.090
_exptl_crystal_size_mid          0.060
_exptl_crystal_size_min          0.060
_refine_diff_density_max         3.64
_refine_diff_density_min         -1.55
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     578
_refine_ls_number_reflns         9844
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0421
_refine_ls_R_factor_gt           0.0377
_refine_ls_shift/su_max          0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0496P)²+61.6139P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0922
_refine_ls_wR_factor_ref         0.0952
_reflns_number_gt                8789
_reflns_number_total             9844
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            d0dt01227k2.cif
_cod_data_source_block           IrPtPt
_cod_depositor_comments
'Adding full bibliography for 7704196--7704197.cif.'
_cod_database_code               7704196
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.385786(11) 0.751507(10) 0.145944(13) 0.03042(7) Uani 1 1 d . . .
Pt2 Pt 0.402533(10) 0.649332(10) 0.281060(12) 0.02902(7) Uani 1 1 d . . .
Pt3 Pt 0.275879(11) 0.697919(11) 0.214240(14) 0.03536(7) Uani 1 1 d . . .
Ag1 Ag 0.5000 0.70976(3) 0.2500 0.03302(14) Uani 1 2 d S . .
S1 S 0.37133(8) 0.75313(7) 0.26700(9) 0.0332(3) Uani 1 1 d . . .
S2 S 0.34190(7) 0.65536(7) 0.14967(9) 0.0327(3) Uani 1 1 d . . .
S3 S 0.08219(18) 0.59793(14) 0.4559(2) 0.0941(10) Uani 1 1 d . . .
S4 S -0.0128(4) 0.8098(2) 0.2573(5) 0.0696(17) Uani 0.50 1 d P . .
P1 P 0.32233(16) 0.50263(15) 0.4315(2) 0.1023(12) Uani 1 1 d . . .
F1 F 0.3071(6) 0.5631(4) 0.4830(7) 0.178(4) Uani 1 1 d . . .
F2 F 0.3285(5) 0.4438(4) 0.3899(6) 0.152(4) Uani 1 1 d . . .
F3 F 0.2482(5) 0.4964(6) 0.4118(9) 0.235(7) Uani 1 1 d . . .
F4 F 0.3950(4) 0.5125(4) 0.4600(8) 0.173(5) Uani 1 1 d . . .
F5 F 0.3193(7) 0.4655(5) 0.5092(6) 0.214(6) Uani 1 1 d . . .
F6 F 0.3227(6) 0.5483(5) 0.3705(7) 0.196(6) Uani 1 1 d . . .
F7 F 0.1350(6) 0.5947(7) 0.5924(5) 0.214(6) Uani 1 1 d . . .
F8 F 0.1927(5) 0.6231(6) 0.5203(7) 0.186(5) Uani 1 1 d . . .
F9 F 0.1707(5) 0.5319(6) 0.5281(7) 0.182(5) Uani 1 1 d . . .
F10 F 0.0507(10) 0.7226(11) 0.2235(13) 0.159(7) Uiso 0.50 1 d P . .
F11 F 0.0311(8) 0.7148(8) 0.3266(11) 0.122(5) Uiso 0.50 1 d P . .
F12 F -0.0426(12) 0.6960(12) 0.2261(18) 0.190(10) Uiso 0.50 1 d P . .
O1 O 0.0711(5) 0.6580(4) 0.4634(6) 0.128(4) Uani 1 1 d . . .
O2 O 0.0964(4) 0.5834(4) 0.3895(5) 0.102(3) Uani 1 1 d . . .
O3 O 0.0403(5) 0.5577(6) 0.4738(6) 0.142(4) Uani 1 1 d . . .
O4 O -0.0596(7) 0.8096(6) 0.2905(7) 0.074(4) Uani 0.50 1 d P . .
O5 O 0.0393(5) 0.8360(5) 0.3136(5) 0.125(3) Uani 1 1 d . . .
N1 N 0.4694(3) 0.8469(3) 0.1157(3) 0.0434(14) Uani 1 1 d . . .
N2 N 0.4090(3) 0.8892(3) 0.1710(4) 0.0494(15) Uani 1 1 d . . .
N3 N 0.4432(3) 0.7698(3) 0.0227(3) 0.0416(13) Uani 1 1 d . . .
N4 N 0.3574(3) 0.7219(3) -0.0261(3) 0.0389(12) Uani 1 1 d . . .
N5 N 0.4989(3) 0.6136(3) 0.4271(3) 0.0473(15) Uani 1 1 d . . .
N6 N 0.4284(3) 0.6677(3) 0.4531(3) 0.0462(14) Uani 1 1 d . . .
N7 N 0.4789(3) 0.5380(3) 0.3314(4) 0.0463(15) Uani 1 1 d . . .
N8 N 0.3901(3) 0.5119(3) 0.2523(4) 0.0477(14) Uani 1 1 d . . .
N9 N 0.2016(3) 0.6988(3) 0.3209(4) 0.0614(19) Uani 1 1 d . . .
N10 N 0.2230(3) 0.7903(3) 0.3039(5) 0.0619(19) Uani 1 1 d . . .
N11 N 0.1747(3) 0.6193(3) 0.2302(5) 0.064(2) Uani 1 1 d . . .
N12 N 0.1722(3) 0.6131(3) 0.1123(5) 0.0583(18) Uani 1 1 d . . .
C1 C 0.4234(3) 0.8350(3) 0.1478(4) 0.0409(15) Uani 1 1 d . . .
C2 C 0.4813(4) 0.9074(4) 0.1165(5) 0.060(2) Uani 1 1 d . . .
H2 H 0.5105 0.9267 0.0965 0.072 Uiso 1 1 calc R . .
C3 C 0.4436(5) 0.9345(4) 0.1511(5) 0.066(2) Uani 1 1 d . . .
H3 H 0.4413 0.9765 0.1600 0.080 Uiso 1 1 calc R . .
C4 C 0.3606(5) 0.9012(4) 0.2055(5) 0.066(2) Uani 1 1 d . . .
H4A H 0.3742 0.8857 0.2581 0.079 Uiso 1 1 calc R . .
H4B H 0.3214 0.8811 0.1757 0.079 Uiso 1 1 calc R . .
H4C H 0.3535 0.9449 0.2062 0.079 Uiso 1 1 calc R . .
C5 C 0.4948(3) 0.8012(3) 0.0791(4) 0.0406(15) Uani 1 1 d . . .
H5A H 0.5199 0.7721 0.1178 0.049 Uiso 1 1 calc R . .
H5B H 0.5229 0.8199 0.0535 0.049 Uiso 1 1 calc R . .
C6 C 0.3954(3) 0.7440(3) 0.0403(4) 0.0358(14) Uani 1 1 d . . .
C7 C 0.4355(4) 0.7638(4) -0.0545(4) 0.0472(17) Uani 1 1 d . . .
H7 H 0.4630 0.7783 -0.0803 0.057 Uiso 1 1 calc R . .
C8 C 0.3821(4) 0.7338(4) -0.0852(4) 0.0471(17) Uani 1 1 d . . .
H8 H 0.3641 0.7226 -0.1374 0.057 Uiso 1 1 calc R . .
C9 C 0.2967(4) 0.6917(3) -0.0399(4) 0.0483(17) Uani 1 1 d . . .
H9A H 0.2831 0.6963 0.0053 0.058 Uiso 1 1 calc R . .
H9B H 0.3010 0.6487 -0.0497 0.058 Uiso 1 1 calc R . .
H9C H 0.2653 0.7100 -0.0844 0.058 Uiso 1 1 calc R . .
C10 C 0.4465(3) 0.6468(3) 0.3944(4) 0.0372(14) Uani 1 1 d . . .
C11 C 0.5148(4) 0.6123(4) 0.5061(4) 0.056(2) Uani 1 1 d . . .
H11 H 0.5490 0.5913 0.5413 0.068 Uiso 1 1 calc R . .
C12 C 0.4728(5) 0.6461(4) 0.5218(4) 0.069(3) Uani 1 1 d . . .
H12 H 0.4720 0.6549 0.5719 0.083 Uiso 1 1 calc R . .
C13 C 0.3723(4) 0.7020(4) 0.4469(5) 0.057(2) Uani 1 1 d . . .
H13A H 0.3450 0.6786 0.4686 0.068 Uiso 1 1 calc R . .
H13B H 0.3497 0.7107 0.3929 0.068 Uiso 1 1 calc R . .
H13C H 0.3840 0.7401 0.4751 0.068 Uiso 1 1 calc R . .
C14 C 0.5272(3) 0.5770(4) 0.3823(5) 0.054(2) Uani 1 1 d . . .
H14A H 0.5613 0.5520 0.4166 0.065 Uiso 1 1 calc R . .
H14B H 0.5456 0.6033 0.3517 0.065 Uiso 1 1 calc R . .
C15 C 0.4242(3) 0.5606(3) 0.2847(4) 0.0383(14) Uani 1 1 d . . .
C16 C 0.4778(5) 0.4756(4) 0.3273(5) 0.058(2) Uani 1 1 d . . .
H16 H 0.5108 0.4492 0.3546 0.070 Uiso 1 1 calc R . .
C17 C 0.4245(5) 0.4600(4) 0.2805(5) 0.061(2) Uani 1 1 d . . .
H17 H 0.4107 0.4197 0.2673 0.073 Uiso 1 1 calc R . .
C18 C 0.3249(5) 0.5116(4) 0.2005(6) 0.072(3) Uani 1 1 d . . .
H18A H 0.3228 0.5322 0.1527 0.086 Uiso 1 1 calc R . .
H18B H 0.2979 0.5326 0.2249 0.086 Uiso 1 1 calc R . .
H18C H 0.3105 0.4698 0.1894 0.086 Uiso 1 1 calc R . .
C19 C 0.2307(3) 0.7333(4) 0.2821(4) 0.0491(18) Uani 1 1 d . . .
C20 C 0.1774(5) 0.7314(6) 0.3666(7) 0.089(3) Uani 1 1 d . . .
H20 H 0.1550 0.7166 0.3987 0.106 Uiso 1 1 calc R . .
C21 C 0.1917(6) 0.7894(6) 0.3571(7) 0.092(4) Uani 1 1 d . . .
H21 H 0.1819 0.8235 0.3824 0.110 Uiso 1 1 calc R . .
C22 C 0.2408(5) 0.8451(4) 0.2715(7) 0.081(3) Uani 1 1 d . . .
H22A H 0.2478 0.8353 0.2231 0.097 Uiso 1 1 calc R . .
H22B H 0.2796 0.8618 0.3076 0.097 Uiso 1 1 calc R . .
H22C H 0.2069 0.8750 0.2622 0.097 Uiso 1 1 calc R . .
C23 C 0.1975(5) 0.6331(4) 0.3109(6) 0.073(3) Uani 1 1 d . . .
H23A H 0.2396 0.6148 0.3347 0.087 Uiso 1 1 calc R . .
H23B H 0.1684 0.6162 0.3363 0.087 Uiso 1 1 calc R . .
C24 C 0.2036(3) 0.6398(3) 0.1789(5) 0.0485(18) Uani 1 1 d . . .
C25 C 0.1257(5) 0.5803(5) 0.1930(9) 0.090(4) Uani 1 1 d . . .
H25 H 0.0991 0.5595 0.2156 0.108 Uiso 1 1 calc R . .
C26 C 0.1231(5) 0.5776(5) 0.1195(9) 0.087(4) Uani 1 1 d . . .
H26 H 0.0933 0.5556 0.0798 0.104 Uiso 1 1 calc R . .
C27 C 0.1854(4) 0.6207(4) 0.0417(5) 0.064(2) Uani 1 1 d . . .
H27A H 0.2225 0.5967 0.0431 0.077 Uiso 1 1 calc R . .
H27B H 0.1936 0.6635 0.0349 0.077 Uiso 1 1 calc R . .
H27C H 0.1490 0.6072 -0.0010 0.077 Uiso 1 1 calc R . .
C28 C 0.1363(9) 0.5872(7) 0.5187(7) 0.111(5) Uani 1 1 d . . .
C29 C 0.0000 0.7437(14) 0.2500 0.152(10) Uiso 1 2 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
F F 0.0171 0.0103
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
O O 0.0106 0.0060
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
S S 0.1246 0.1234
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Ag Ag -0.8971 1.1015
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
P P 0.1023 0.0942
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Pt Pt -1.7033 8.3905
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pt1 C6 85.4(3) . . ?
C1 Pt1 S2 177.26(19) . . ?
C6 Pt1 S2 97.37(19) . . ?
C1 Pt1 S1 98.82(19) . . ?
C6 Pt1 S1 175.81(19) . . ?
S2 Pt1 S1 78.45(5) . . ?
C1 Pt1 Ag1 90.36(19) . . ?
C6 Pt1 Ag1 105.78(18) . . ?
S2 Pt1 Ag1 88.85(4) . . ?
S1 Pt1 Ag1 74.44(4) . . ?
C10 Pt2 C15 84.6(3) . . ?
C10 Pt2 S2 174.6(2) . . ?
C15 Pt2 S2 98.1(2) . . ?
C10 Pt2 S1 99.66(19) . . ?
C15 Pt2 S1 175.6(2) . . ?
S2 Pt2 S1 77.51(5) . . ?
C10 Pt2 Ag1 94.22(19) . . ?
C15 Pt2 Ag1 106.18(18) . . ?
S2 Pt2 Ag1 89.51(4) . . ?
S1 Pt2 Ag1 74.73(4) . . ?
C10 Pt2 Pt3 122.42(19) . . ?
C15 Pt2 Pt3 124.4(2) . . ?
S2 Pt2 Pt3 52.20(4) . . ?
S1 Pt2 Pt3 52.27(4) . . ?
Ag1 Pt2 Pt3 117.362(16) . . ?
C24 Pt3 C19 86.3(3) . . ?
C24 Pt3 S2 98.7(2) . . ?
C19 Pt3 S2 172.0(2) . . ?
C24 Pt3 S1 170.6(2) . . ?
C19 Pt3 S1 96.5(2) . . ?
S2 Pt3 S1 77.61(5) . . ?
C24 Pt3 Pt2 118.40(19) . . ?
C19 Pt3 Pt2 120.0(2) . . ?
S2 Pt3 Pt2 52.07(4) . . ?
S1 Pt3 Pt2 52.56(4) . . ?
Pt2 Ag1 Pt2 122.36(3) . 2_655 ?
Pt2 Ag1 Pt1 72.283(12) . . ?
Pt2 Ag1 Pt1 128.381(12) 2_655 . ?
Pt2 Ag1 Pt1 128.381(11) . 2_655 ?
Pt2 Ag1 Pt1 72.282(11) 2_655 2_655 ?
Pt1 Ag1 Pt1 141.66(3) . 2_655 ?
Pt1 S1 Pt3 89.14(5) . . ?
Pt1 S1 Pt2 87.90(5) . . ?
Pt3 S1 Pt2 75.17(5) . . ?
Pt1 S2 Pt2 88.50(5) . . ?
Pt1 S2 Pt3 89.43(5) . . ?
Pt2 S2 Pt3 75.73(5) . . ?
O1 S3 O2 114.3(6) . . ?
O1 S3 C28 102.6(8) . . ?
O2 S3 C28 107.7(7) . . ?
O1 S3 O3 115.8(7) . . ?
O2 S3 O3 114.6(6) . . ?
C28 S3 O3 99.5(8) . . ?
S4 S4 O4 176(2) 2 . ?
S4 S4 O5 78.0(13) 2 2 ?
O4 S4 O5 105.5(9) . 2 ?
S4 S4 O5 72.6(14) 2 . ?
O4 S4 O5 104.0(9) . . ?
O5 S4 O5 121.7(9) 2 . ?
S4 S4 C29 76.4(3) 2 . ?
O4 S4 C29 103.4(7) . . ?
O5 S4 C29 111.1(7) 2 . ?
O5 S4 C29 109.2(7) . . ?
S4 S4 O4 2.5(13) 2 2 ?
O4 S4 O4 178.7(7) . 2 ?
O5 S4 O4 75.8(7) 2 2 ?
O5 S4 O4 74.9(6) . 2 ?
C29 S4 O4 76.3(5) . 2 ?
F6 P1 F2 99.9(7) . . ?
F6 P1 F4 84.3(7) . . ?
F2 P1 F4 91.9(6) . . ?
F6 P1 F3 98.3(8) . . ?
F2 P1 F3 94.0(7) . . ?
F4 P1 F3 173.0(8) . . ?
F6 P1 F5 167.5(7) . . ?
F2 P1 F5 92.7(6) . . ?
F4 P1 F5 96.1(7) . . ?
F3 P1 F5 79.9(8) . . ?
F6 P1 F1 86.6(6) . . ?
F2 P1 F1 171.4(5) . . ?
F4 P1 F1 94.4(6) . . ?
F3 P1 F1 79.4(7) . . ?
F5 P1 F1 80.8(6) . . ?
F12 F10 C29 63.5(19) 2 . ?
F12 F10 F11 88(2) 2 2 ?
C29 F10 F11 54.4(10) . 2 ?
F12 F11 C29 61.8(17) 2 . ?
F12 F11 F10 94(2) 2 2 ?
C29 F11 F10 51.8(10) . 2 ?
F11 F12 F10 128(3) 2 2 ?
F11 F12 C29 71.2(18) 2 . ?
F10 F12 C29 68.4(19) 2 . ?
S4 O4 S4 1.3(7) . 2 ?
S4 O5 S4 29.4(4) 2 . ?
C2 N1 C1 110.8(7) . . ?
C2 N1 C5 126.3(6) . . ?
C1 N1 C5 122.5(6) . . ?
C1 N2 C3 110.3(7) . . ?
C1 N2 C4 126.3(6) . . ?
C3 N2 C4 123.2(7) . . ?
C6 N3 C7 111.3(6) . . ?
C6 N3 C5 122.8(6) . . ?
C7 N3 C5 125.9(6) . . ?
C6 N4 C8 110.5(6) . . ?
C6 N4 C9 127.3(6) . . ?
C8 N4 C9 122.1(6) . . ?
C10 N5 C11 112.0(7) . . ?
C10 N5 C14 121.9(6) . . ?
C11 N5 C14 125.5(7) . . ?
C10 N6 C12 107.2(7) . . ?
C10 N6 C13 126.6(6) . . ?
C12 N6 C13 126.1(7) . . ?
C15 N7 C16 109.9(7) . . ?
C15 N7 C14 121.5(6) . . ?
C16 N7 C14 128.3(7) . . ?
C15 N8 C17 109.3(7) . . ?
C15 N8 C18 126.7(6) . . ?
C17 N8 C18 123.8(7) . . ?
C19 N9 C20 112.9(9) . . ?
C19 N9 C23 121.1(7) . . ?
C20 N9 C23 126.0(8) . . ?
C19 N10 C21 110.0(9) . . ?
C19 N10 C22 125.1(7) . . ?
C21 N10 C22 124.7(9) . . ?
C24 N11 C25 109.6(9) . . ?
C24 N11 C23 123.2(7) . . ?
C25 N11 C23 126.9(9) . . ?
C24 N12 C26 111.0(9) . . ?
C24 N12 C27 125.4(7) . . ?
C26 N12 C27 123.6(9) . . ?
N2 C1 N1 104.9(6) . . ?
N2 C1 Pt1 132.6(5) . . ?
N1 C1 Pt1 122.3(5) . . ?
C3 C2 N1 106.9(7) . . ?
C3 C2 H2 126.6 . . ?
N1 C2 H2 126.6 . . ?
C2 C3 N2 107.0(8) . . ?
C2 C3 H3 126.5 . . ?
N2 C3 H3 126.5 . . ?
N2 C4 H4A 109.5 . . ?
N2 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
N2 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
N1 C5 N3 109.1(5) . . ?
N1 C5 H5A 109.9 . . ?
N3 C5 H5A 109.9 . . ?
N1 C5 H5B 109.9 . . ?
N3 C5 H5B 109.9 . . ?
H5A C5 H5B 108.3 . . ?
N4 C6 N3 104.8(6) . . ?
N4 C6 Pt1 132.4(5) . . ?
N3 C6 Pt1 122.4(5) . . ?
C8 C7 N3 106.5(6) . . ?
C8 C7 H7 126.7 . . ?
N3 C7 H7 126.7 . . ?
C7 C8 N4 106.9(6) . . ?
C7 C8 H8 126.5 . . ?
N4 C8 H8 126.5 . . ?
N4 C9 H9A 109.5 . . ?
N4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
N4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
N5 C10 N6 105.6(6) . . ?
N5 C10 Pt2 123.0(5) . . ?
N6 C10 Pt2 130.6(5) . . ?
C12 C11 N5 105.1(7) . . ?
C12 C11 H11 127.4 . . ?
N5 C11 H11 127.4 . . ?
C11 C12 N6 110.0(8) . . ?
C11 C12 H12 125.0 . . ?
N6 C12 H12 125.0 . . ?
N6 C13 H13A 109.5 . . ?
N6 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
N6 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
N5 C14 N7 109.2(6) . . ?
N5 C14 H14A 109.8 . . ?
N7 C14 H14A 109.8 . . ?
N5 C14 H14B 109.8 . . ?
N7 C14 H14B 109.8 . . ?
H14A C14 H14B 108.3 . . ?
N8 C15 N7 104.8(6) . . ?
N8 C15 Pt2 132.0(5) . . ?
N7 C15 Pt2 122.9(5) . . ?
C17 C16 N7 107.7(7) . . ?
C17 C16 H16 126.1 . . ?
N7 C16 H16 126.1 . . ?
C16 C17 N8 108.3(8) . . ?
C16 C17 H17 125.8 . . ?
N8 C17 H17 125.8 . . ?
N8 C18 H18A 109.5 . . ?
N8 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
N8 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N9 C19 N10 103.9(7) . . ?
N9 C19 Pt3 122.5(6) . . ?
N10 C19 Pt3 133.5(6) . . ?
N9 C20 C21 105.5(9) . . ?
N9 C20 H20 127.2 . . ?
C21 C20 H20 127.2 . . ?
C20 C21 N10 107.6(10) . . ?
C20 C21 H21 126.2 . . ?
N10 C21 H21 126.2 . . ?
N10 C22 H22A 109.5 . . ?
N10 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
N10 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
N11 C23 N9 109.1(7) . . ?
N11 C23 H23A 109.9 . . ?
N9 C23 H23A 109.9 . . ?
N11 C23 H23B 109.9 . . ?
N9 C23 H23B 109.9 . . ?
H23A C23 H23B 108.3 . . ?
N12 C24 N11 104.9(7) . . ?
N12 C24 Pt3 135.4(6) . . ?
N11 C24 Pt3 119.7(6) . . ?
C26 C25 N11 107.3(9) . . ?
C26 C25 H25 126.4 . . ?
N11 C25 H25 126.4 . . ?
C25 C26 N12 107.1(10) . . ?
C25 C26 H26 126.5 . . ?
N12 C26 H26 126.5 . . ?
N12 C27 H27A 109.5 . . ?
N12 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
N12 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
F7 C28 S3 120.4(15) . . ?
F7 C28 F9 99.5(13) . . ?
S3 C28 F9 122.4(11) . . ?
F7 C28 F8 101.8(12) . . ?
S3 C28 F8 115.5(10) . . ?
F9 C28 F8 91.9(14) . . ?
F12 C29 F12 82(3) . 2 ?
F12 C29 F10 100(2) . . ?
F12 C29 F10 48.1(14) 2 . ?
F12 C29 F10 48.1(14) . 2 ?
F12 C29 F10 100(2) 2 2 ?
F10 C29 F10 142(3) . 2 ?
F12 C29 F11 92(2) . . ?
F12 C29 F11 47.0(14) 2 . ?
F10 C29 F11 90.2(14) . . ?
F10 C29 F11 73.8(13) 2 . ?
F12 C29 F11 47.0(14) . 2 ?
F12 C29 F11 92(2) 2 2 ?
F10 C29 F11 73.8(13) . 2 ?
F10 C29 F11 90.2(14) 2 2 ?
F11 C29 F11 129(3) . 2 ?
F12 C29 S4 129.3(13) . . ?
F12 C29 S4 146.9(15) 2 . ?
F10 C29 S4 122.4(18) . . ?
F10 C29 S4 95.2(13) 2 . ?
F11 C29 S4 112.0(13) . . ?
F11 C29 S4 117.1(13) 2 . ?
F12 C29 S4 146.9(15) . 2 ?
F12 C29 S4 129.3(13) 2 2 ?
F10 C29 S4 95.2(13) . 2 ?
F10 C29 S4 122.4(18) 2 2 ?
F11 C29 S4 117.1(13) . 2 ?
F11 C29 S4 112.0(13) 2 2 ?
S4 C29 S4 27.2(7) . 2 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1 2.027(7) . ?
Pt1 C6 2.035(6) . ?
Pt1 S2 2.3543(16) . ?
Pt1 S1 2.3579(16) . ?
Pt1 Ag1 2.8139(4) . ?
Pt2 C10 2.004(6) . ?
Pt2 C15 2.019(7) . ?
Pt2 S2 2.3690(15) . ?
Pt2 S1 2.3908(15) . ?
Pt2 Ag1 2.7741(5) . ?
Pt2 Pt3 2.9109(5) . ?
Pt3 C24 2.004(8) . ?
Pt3 C19 2.007(8) . ?
Pt3 S2 2.3733(16) . ?
Pt3 S1 2.3816(17) . ?
Ag1 Pt2 2.7742(5) 2_655 ?
Ag1 Pt1 2.8139(4) 2_655 ?
S3 O1 1.368(9) . ?
S3 O2 1.399(7) . ?
S3 C28 1.400(18) . ?
S3 O3 1.408(8) . ?
S4 S4 0.708(10) 2 ?
S4 O4 1.374(13) . ?
S4 O5 1.378(11) 2 ?
S4 O5 1.412(13) . ?
S4 C29 1.50(3) . ?
S4 O4 2.081(14) 2 ?
P1 F6 1.515(9) . ?
P1 F2 1.540(10) . ?
P1 F4 1.557(9) . ?
P1 F3 1.588(12) . ?
P1 F5 1.673(11) . ?
P1 F1 1.738(11) . ?
F7 C28 1.379(14) . ?
F8 C28 1.487(17) . ?
F9 C28 1.428(18) . ?
F10 F12 1.16(3) 2 ?
F10 C29 1.45(2) . ?
F10 F11 1.77(3) 2 ?
F11 F12 1.16(3) 2 ?
F11 C29 1.50(2) . ?
F11 F10 1.77(3) 2 ?
F12 F11 1.16(3) 2 ?
F12 F10 1.16(3) 2 ?
F12 C29 1.40(3) . ?
O4 S4 2.081(14) 2 ?
O5 S4 1.378(11) 2 ?
N1 C2 1.364(10) . ?
N1 C1 1.370(9) . ?
N1 C5 1.433(9) . ?
N2 C1 1.347(9) . ?
N2 C3 1.387(10) . ?
N2 C4 1.448(10) . ?
N3 C6 1.342(9) . ?
N3 C7 1.385(9) . ?
N3 C5 1.458(9) . ?
N4 C6 1.339(8) . ?
N4 C8 1.398(9) . ?
N4 C9 1.462(9) . ?
N5 C10 1.351(9) . ?
N5 C11 1.384(10) . ?
N5 C14 1.441(10) . ?
N6 C10 1.354(9) . ?
N6 C12 1.418(10) . ?
N6 C13 1.443(10) . ?
N7 C15 1.346(9) . ?
N7 C16 1.382(10) . ?
N7 C14 1.464(11) . ?
N8 C15 1.344(9) . ?
N8 C17 1.389(10) . ?
N8 C18 1.465(11) . ?
N9 C19 1.348(10) . ?
N9 C20 1.349(13) . ?
N9 C23 1.465(12) . ?
N10 C19 1.350(10) . ?
N10 C21 1.378(12) . ?
N10 C22 1.464(12) . ?
N11 C24 1.384(10) . ?
N11 C25 1.392(13) . ?
N11 C23 1.442(13) . ?
N12 C24 1.341(11) . ?
N12 C26 1.394(12) . ?
N12 C27 1.435(12) . ?
C2 C3 1.352(13) . ?
C2 H2 0.9500 . ?
C3 H3 0.9500 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C7 C8 1.323(11) . ?
C7 H7 0.9500 . ?
C8 H8 0.9500 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C11 C12 1.307(14) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C16 C17 1.274(13) . ?
C16 H16 0.9500 . ?
C17 H17 0.9500 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C20 C21 1.349(17) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C25 C26 1.339(17) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C29 F12 1.40(3) 2 ?
C29 F10 1.45(2) 2 ?
C29 F11 1.50(2) 2 ?
C29 S4 1.50(3) 2 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C10 Pt2 Pt3 C24 -100.9(4) . . . . ?
C15 Pt2 Pt3 C24 6.6(4) . . . . ?
S2 Pt2 Pt3 C24 78.3(3) . . . . ?
S1 Pt2 Pt3 C24 -177.0(3) . . . . ?
Ag1 Pt2 Pt3 C24 143.8(3) . . . . ?
C10 Pt2 Pt3 C19 2.3(4) . . . . ?
C15 Pt2 Pt3 C19 109.7(4) . . . . ?
S2 Pt2 Pt3 C19 -178.6(3) . . . . ?
S1 Pt2 Pt3 C19 -73.9(3) . . . . ?
Ag1 Pt2 Pt3 C19 -113.0(3) . . . . ?
C10 Pt2 Pt3 S2 -179.2(2) . . . . ?
C15 Pt2 Pt3 S2 -71.7(2) . . . . ?
S1 Pt2 Pt3 S2 104.72(7) . . . . ?
Ag1 Pt2 Pt3 S2 65.56(5) . . . . ?
C10 Pt2 Pt3 S1 76.1(2) . . . . ?
C15 Pt2 Pt3 S1 -176.4(2) . . . . ?
S2 Pt2 Pt3 S1 -104.72(7) . . . . ?
Ag1 Pt2 Pt3 S1 -39.16(5) . . . . ?
C10 Pt2 Ag1 Pt2 90.53(19) . . . 2_655 ?
C15 Pt2 Ag1 Pt2 4.9(2) . . . 2_655 ?
S2 Pt2 Ag1 Pt2 -93.42(4) . . . 2_655 ?
S1 Pt2 Ag1 Pt2 -170.60(4) . . . 2_655 ?
Pt3 Pt2 Ag1 Pt2 -139.419(13) . . . 2_655 ?
C10 Pt2 Ag1 Pt1 -144.78(19) . . . . ?
C15 Pt2 Ag1 Pt1 129.6(2) . . . . ?
S2 Pt2 Ag1 Pt1 31.28(4) . . . . ?
S1 Pt2 Ag1 Pt1 -45.91(4) . . . . ?
Pt3 Pt2 Ag1 Pt1 -14.723(15) . . . . ?
C10 Pt2 Ag1 Pt1 -1.9(2) . . . 2_655 ?
C15 Pt2 Ag1 Pt1 -87.5(2) . . . 2_655 ?
S2 Pt2 Ag1 Pt1 174.16(4) . . . 2_655 ?
S1 Pt2 Ag1 Pt1 96.98(5) . . . 2_655 ?
Pt3 Pt2 Ag1 Pt1 128.16(2) . . . 2_655 ?
C1 Pt1 Ag1 Pt2 145.9(2) . . . . ?
C6 Pt1 Ag1 Pt2 -128.8(2) . . . . ?
S2 Pt1 Ag1 Pt2 -31.50(4) . . . . ?
S1 Pt1 Ag1 Pt2 46.82(4) . . . . ?
C1 Pt1 Ag1 Pt2 -96.5(2) . . . 2_655 ?
C6 Pt1 Ag1 Pt2 -11.2(2) . . . 2_655 ?
S2 Pt1 Ag1 Pt2 86.13(5) . . . 2_655 ?
S1 Pt1 Ag1 Pt2 164.45(5) . . . 2_655 ?
C1 Pt1 Ag1 Pt1 15.6(2) . . . 2_655 ?
C6 Pt1 Ag1 Pt1 100.9(2) . . . 2_655 ?
S2 Pt1 Ag1 Pt1 -161.81(4) . . . 2_655 ?
S1 Pt1 Ag1 Pt1 -83.48(4) . . . 2_655 ?
C1 Pt1 S1 Pt3 143.1(2) . . . . ?
C6 Pt1 S1 Pt3 -35(2) . . . . ?
S2 Pt1 S1 Pt3 -36.91(5) . . . . ?
Ag1 Pt1 S1 Pt3 -128.95(5) . . . . ?
C1 Pt1 S1 Pt2 -141.7(2) . . . . ?
C6 Pt1 S1 Pt2 40(2) . . . . ?
S2 Pt1 S1 Pt2 38.28(5) . . . . ?
Ag1 Pt1 S1 Pt2 -53.76(4) . . . . ?
C24 Pt3 S1 Pt1 104.5(15) . . . . ?
C19 Pt3 S1 Pt1 -148.8(2) . . . . ?
S2 Pt3 S1 Pt1 36.70(5) . . . . ?
Pt2 Pt3 S1 Pt1 88.05(5) . . . . ?
C24 Pt3 S1 Pt2 16.4(15) . . . . ?
C19 Pt3 S1 Pt2 123.1(2) . . . . ?
S2 Pt3 S1 Pt2 -51.36(4) . . . . ?
C10 Pt2 S1 Pt1 146.56(19) . . . . ?
C15 Pt2 S1 Pt1 -48(2) . . . . ?
S2 Pt2 S1 Pt1 -38.16(5) . . . . ?
Ag1 Pt2 S1 Pt1 54.78(3) . . . . ?
Pt3 Pt2 S1 Pt1 -89.67(5) . . . . ?
C10 Pt2 S1 Pt3 -123.77(19) . . . . ?
C15 Pt2 S1 Pt3 42(2) . . . . ?
S2 Pt2 S1 Pt3 51.51(5) . . . . ?
Ag1 Pt2 S1 Pt3 144.45(4) . . . . ?
C1 Pt1 S2 Pt2 -38(4) . . . . ?
C6 Pt1 S2 Pt2 141.44(18) . . . . ?
S1 Pt1 S2 Pt2 -38.68(5) . . . . ?
Ag1 Pt1 S2 Pt2 35.67(4) . . . . ?
C1 Pt1 S2 Pt3 38(4) . . . . ?
C6 Pt1 S2 Pt3 -142.82(18) . . . . ?
S1 Pt1 S2 Pt3 37.06(5) . . . . ?
Ag1 Pt1 S2 Pt3 111.41(4) . . . . ?
C10 Pt2 S2 Pt1 97(2) . . . . ?
C15 Pt2 S2 Pt1 -142.52(18) . . . . ?
S1 Pt2 S2 Pt1 38.21(5) . . . . ?
Ag1 Pt2 S2 Pt1 -36.25(4) . . . . ?
Pt3 Pt2 S2 Pt1 89.79(5) . . . . ?
C10 Pt2 S2 Pt3 7(2) . . . . ?
C15 Pt2 S2 Pt3 127.68(18) . . . . ?
S1 Pt2 S2 Pt3 -51.58(5) . . . . ?
Ag1 Pt2 S2 Pt3 -126.04(3) . . . . ?
C24 Pt3 S2 Pt1 152.0(2) . . . . ?
C19 Pt3 S2 Pt1 -79.8(17) . . . . ?
S1 Pt3 S2 Pt1 -36.76(5) . . . . ?
Pt2 Pt3 S2 Pt1 -88.59(5) . . . . ?
C24 Pt3 S2 Pt2 -119.4(2) . . . . ?
C19 Pt3 S2 Pt2 8.8(17) . . . . ?
S1 Pt3 S2 Pt2 51.83(5) . . . . ?
O5 S4 O4 S4 -157(10) 2 . . 2 ?
O5 S4 O4 S4 -28(9) . . . 2 ?
C29 S4 O4 S4 86(9) . . . 2 ?
O4 S4 O4 S4 11(36) 2 . . 2 ?
O4 S4 O5 S4 178.2(10) . . . 2 ?
O5 S4 O5 S4 -63.3(9) 2 . . 2 ?
C29 S4 O5 S4 68.3(7) . . . 2 ?
O4 S4 O5 S4 -1.0(7) 2 . . 2 ?
C3 N2 C1 N1 2.2(8) . . . . ?
C4 N2 C1 N1 177.0(7) . . . . ?
C3 N2 C1 Pt1 -172.1(6) . . . . ?
C4 N2 C1 Pt1 2.7(12) . . . . ?
C2 N1 C1 N2 -2.2(8) . . . . ?
C5 N1 C1 N2 -175.7(6) . . . . ?
C2 N1 C1 Pt1 172.8(5) . . . . ?
C5 N1 C1 Pt1 -0.7(9) . . . . ?
C6 Pt1 C1 N2 137.6(7) . . . . ?
S2 Pt1 C1 N2 -43(5) . . . . ?
S1 Pt1 C1 N2 -42.3(7) . . . . ?
Ag1 Pt1 C1 N2 -116.6(7) . . . . ?
C6 Pt1 C1 N1 -35.9(5) . . . . ?
S2 Pt1 C1 N1 143(4) . . . . ?
S1 Pt1 C1 N1 144.2(5) . . . . ?
Ag1 Pt1 C1 N1 69.9(5) . . . . ?
C1 N1 C2 C3 1.4(9) . . . . ?
C5 N1 C2 C3 174.6(7) . . . . ?
N1 C2 C3 N2 0.0(10) . . . . ?
C1 N2 C3 C2 -1.4(10) . . . . ?
C4 N2 C3 C2 -176.4(8) . . . . ?
C2 N1 C5 N3 -120.7(8) . . . . ?
C1 N1 C5 N3 51.7(8) . . . . ?
C6 N3 C5 N1 -54.5(8) . . . . ?
C7 N3 C5 N1 123.6(7) . . . . ?
C8 N4 C6 N3 0.3(7) . . . . ?
C9 N4 C6 N3 -176.8(6) . . . . ?
C8 N4 C6 Pt1 172.5(5) . . . . ?
C9 N4 C6 Pt1 -4.6(10) . . . . ?
C7 N3 C6 N4 -0.2(7) . . . . ?
C5 N3 C6 N4 178.2(6) . . . . ?
C7 N3 C6 Pt1 -173.4(5) . . . . ?
C5 N3 C6 Pt1 5.0(9) . . . . ?
C1 Pt1 C6 N4 -137.3(6) . . . . ?
S2 Pt1 C6 N4 42.7(6) . . . . ?
S1 Pt1 C6 N4 41(3) . . . . ?
Ag1 Pt1 C6 N4 133.6(6) . . . . ?
C1 Pt1 C6 N3 33.7(5) . . . . ?
S2 Pt1 C6 N3 -146.2(5) . . . . ?
S1 Pt1 C6 N3 -148(2) . . . . ?
Ag1 Pt1 C6 N3 -55.3(5) . . . . ?
C6 N3 C7 C8 0.0(8) . . . . ?
C5 N3 C7 C8 -178.3(6) . . . . ?
N3 C7 C8 N4 0.2(8) . . . . ?
C6 N4 C8 C7 -0.3(8) . . . . ?
C9 N4 C8 C7 177.0(6) . . . . ?
C11 N5 C10 N6 0.3(8) . . . . ?
C14 N5 C10 N6 171.3(6) . . . . ?
C11 N5 C10 Pt2 -171.1(5) . . . . ?
C14 N5 C10 Pt2 -0.1(9) . . . . ?
C12 N6 C10 N5 0.8(7) . . . . ?
C13 N6 C10 N5 -175.3(7) . . . . ?
C12 N6 C10 Pt2 171.3(5) . . . . ?
C13 N6 C10 Pt2 -4.9(11) . . . . ?
C15 Pt2 C10 N5 37.9(6) . . . . ?
S2 Pt2 C10 N5 158.6(16) . . . . ?
S1 Pt2 C10 N5 -143.2(5) . . . . ?
Ag1 Pt2 C10 N5 -68.0(5) . . . . ?
Pt3 Pt2 C10 N5 165.6(5) . . . . ?
C15 Pt2 C10 N6 -131.2(7) . . . . ?
S2 Pt2 C10 N6 -10(3) . . . . ?
S1 Pt2 C10 N6 47.8(6) . . . . ?
Ag1 Pt2 C10 N6 123.0(6) . . . . ?
Pt3 Pt2 C10 N6 -3.4(7) . . . . ?
C10 N5 C11 C12 -1.4(9) . . . . ?
C14 N5 C11 C12 -172.1(7) . . . . ?
N5 C11 C12 N6 1.9(9) . . . . ?
C10 N6 C12 C11 -1.8(9) . . . . ?
C13 N6 C12 C11 174.4(8) . . . . ?
C10 N5 C14 N7 -51.9(8) . . . . ?
C11 N5 C14 N7 117.8(7) . . . . ?
C15 N7 C14 N5 52.4(8) . . . . ?
C16 N7 C14 N5 -121.3(7) . . . . ?
C17 N8 C15 N7 0.6(8) . . . . ?
C18 N8 C15 N7 175.5(7) . . . . ?
C17 N8 C15 Pt2 -172.4(6) . . . . ?
C18 N8 C15 Pt2 2.5(11) . . . . ?
C16 N7 C15 N8 -0.1(7) . . . . ?
C14 N7 C15 N8 -174.9(6) . . . . ?
C16 N7 C15 Pt2 173.7(5) . . . . ?
C14 N7 C15 Pt2 -1.1(8) . . . . ?
C10 Pt2 C15 N8 134.8(7) . . . . ?
S2 Pt2 C15 N8 -40.5(6) . . . . ?
S1 Pt2 C15 N8 -31(3) . . . . ?
Ag1 Pt2 C15 N8 -132.3(6) . . . . ?
Pt3 Pt2 C15 N8 8.8(7) . . . . ?
C10 Pt2 C15 N7 -37.1(5) . . . . ?
S2 Pt2 C15 N7 147.6(5) . . . . ?
S1 Pt2 C15 N7 157(2) . . . . ?
Ag1 Pt2 C15 N7 55.8(5) . . . . ?
Pt3 Pt2 C15 N7 -163.1(4) . . . . ?
C15 N7 C16 C17 -0.5(9) . . . . ?
C14 N7 C16 C17 173.8(7) . . . . ?
N7 C16 C17 N8 0.8(9) . . . . ?
C15 N8 C17 C16 -0.9(9) . . . . ?
C18 N8 C17 C16 -176.0(8) . . . . ?
C20 N9 C19 N10 -1.2(10) . . . . ?
C23 N9 C19 N10 178.0(8) . . . . ?
C20 N9 C19 Pt3 176.3(7) . . . . ?
C23 N9 C19 Pt3 -4.6(11) . . . . ?
C21 N10 C19 N9 2.1(10) . . . . ?
C22 N10 C19 N9 -173.4(9) . . . . ?
C21 N10 C19 Pt3 -175.0(8) . . . . ?
C22 N10 C19 Pt3 9.6(14) . . . . ?
C24 Pt3 C19 N9 41.1(7) . . . . ?
S2 Pt3 C19 N9 -87.8(19) . . . . ?
S1 Pt3 C19 N9 -129.9(6) . . . . ?
Pt2 Pt3 C19 N9 -79.7(7) . . . . ?
C24 Pt3 C19 N10 -142.3(8) . . . . ?
S2 Pt3 C19 N10 88.8(19) . . . . ?
S1 Pt3 C19 N10 46.7(8) . . . . ?
Pt2 Pt3 C19 N10 96.8(8) . . . . ?
C19 N9 C20 C21 -0.2(13) . . . . ?
C23 N9 C20 C21 -179.3(10) . . . . ?
N9 C20 C21 N10 1.5(13) . . . . ?
C19 N10 C21 C20 -2.3(13) . . . . ?
C22 N10 C21 C20 173.2(10) . . . . ?
C24 N11 C23 N9 55.9(10) . . . . ?
C25 N11 C23 N9 -130.3(9) . . . . ?
C19 N9 C23 N11 -49.5(11) . . . . ?
C20 N9 C23 N11 129.5(10) . . . . ?
C26 N12 C24 N11 1.7(9) . . . . ?
C27 N12 C24 N11 -180.0(7) . . . . ?
C26 N12 C24 Pt3 -177.7(7) . . . . ?
C27 N12 C24 Pt3 0.6(12) . . . . ?
C25 N11 C24 N12 -0.2(9) . . . . ?
C23 N11 C24 N12 174.5(7) . . . . ?
C25 N11 C24 Pt3 179.3(6) . . . . ?
C23 N11 C24 Pt3 -6.0(10) . . . . ?
C19 Pt3 C24 N12 144.1(8) . . . . ?
S2 Pt3 C24 N12 -42.2(8) . . . . ?
S1 Pt3 C24 N12 -108.4(15) . . . . ?
Pt2 Pt3 C24 N12 -93.6(7) . . . . ?
C19 Pt3 C24 N11 -35.2(6) . . . . ?
S2 Pt3 C24 N11 138.5(5) . . . . ?
S1 Pt3 C24 N11 72.3(17) . . . . ?
Pt2 Pt3 C24 N11 87.1(6) . . . . ?
C24 N11 C25 C26 -1.4(11) . . . . ?
C23 N11 C25 C26 -175.9(9) . . . . ?
N11 C25 C26 N12 2.3(12) . . . . ?
C24 N12 C26 C25 -2.6(12) . . . . ?
C27 N12 C26 C25 179.1(9) . . . . ?
O1 S3 C28 F7 62.4(14) . . . . ?
O2 S3 C28 F7 -176.6(11) . . . . ?
O3 S3 C28 F7 -56.9(14) . . . . ?
O1 S3 C28 F9 -170.7(11) . . . . ?
O2 S3 C28 F9 -49.7(13) . . . . ?
O3 S3 C28 F9 70.0(13) . . . . ?
O1 S3 C28 F8 -60.4(13) . . . . ?
O2 S3 C28 F8 60.5(12) . . . . ?
O3 S3 C28 F8 -179.7(11) . . . . ?
F11 F12 C29 F12 -101(2) 2 . . 2 ?
F10 F12 C29 F12 112(3) 2 . . 2 ?
F11 F12 C29 F10 -56(2) 2 . . . ?
F10 F12 C29 F10 156.6(19) 2 . . . ?
F11 F12 C29 F10 147(3) 2 . . 2 ?
F11 F12 C29 F11 -146.7(17) 2 . . . ?
F10 F12 C29 F11 66.0(19) 2 . . . ?
F10 F12 C29 F11 -147(3) 2 . . 2 ?
F11 F12 C29 S4 92(2) 2 . . . ?
F10 F12 C29 S4 -55(2) 2 . . . ?
F11 F12 C29 S4 60(3) 2 . . 2 ?
F10 F12 C29 S4 -87(3) 2 . . 2 ?
F12 F10 C29 F12 -69(3) 2 . . . ?
F11 F10 C29 F12 39.2(13) 2 . . . ?
F11 F10 C29 F12 108(2) 2 . . 2 ?
F12 F10 C29 F10 -39.8(17) 2 . . 2 ?
F11 F10 C29 F10 68.2(11) 2 . . 2 ?
F12 F10 C29 F11 23(2) 2 . . . ?
F11 F10 C29 F11 131(2) 2 . . . ?
F12 F10 C29 F11 -108(2) 2 . . 2 ?
F12 F10 C29 S4 139.7(17) 2 . . . ?
F11 F10 C29 S4 -112.2(12) 2 . . . ?
F12 F10 C29 S4 140.5(18) 2 . . 2 ?
F11 F10 C29 S4 -111.4(12) 2 . . 2 ?
F12 F11 C29 F12 77(3) 2 . . . ?
F10 F11 C29 F12 -45.1(12) 2 . . . ?
F10 F11 C29 F12 -122(3) 2 . . 2 ?
F12 F11 C29 F10 -24(2) 2 . . . ?
F10 F11 C29 F10 -145(3) 2 . . . ?
F12 F11 C29 F10 122(3) 2 . . 2 ?
F12 F11 C29 F11 45.3(17) 2 . . 2 ?
F10 F11 C29 F11 -76.4(14) 2 . . 2 ?
F12 F11 C29 S4 -149.2(18) 2 . . . ?
F10 F11 C29 S4 89.1(12) 2 . . . ?
F12 F11 C29 S4 -119.7(17) 2 . . 2 ?
F10 F11 C29 S4 118.6(17) 2 . . 2 ?
S4 S4 C29 F12 -141(2) 2 . . . ?
O4 S4 C29 F12 43(2) . . . . ?
O5 S4 C29 F12 -69.7(19) 2 . . . ?
O5 S4 C29 F12 153.3(18) . . . . ?
O4 S4 C29 F12 -138.3(18) 2 . . . ?
S4 S4 C29 F12 63(3) 2 . . 2 ?
O4 S4 C29 F12 -113(3) . . . 2 ?
O5 S4 C29 F12 135(3) 2 . . 2 ?
O5 S4 C29 F12 -2(3) . . . 2 ?
O4 S4 C29 F12 66(3) 2 . . 2 ?
S4 S4 C29 F10 2(2) 2 . . . ?
O4 S4 C29 F10 -174.5(13) . . . . ?
O5 S4 C29 F10 72.8(13) 2 . . . ?
O5 S4 C29 F10 -64.2(12) . . . . ?
O4 S4 C29 F10 4.2(12) 2 . . . ?
S4 S4 C29 F10 -178.6(17) 2 . . 2 ?
O4 S4 C29 F10 5.3(12) . . . 2 ?
O5 S4 C29 F10 -107.4(11) 2 . . 2 ?
O5 S4 C29 F10 115.6(10) . . . 2 ?
O4 S4 C29 F10 -176.0(10) 2 . . 2 ?
S4 S4 C29 F11 106.8(16) 2 . . . ?
O4 S4 C29 F11 -69.4(12) . . . . ?
O5 S4 C29 F11 177.9(10) 2 . . . ?
O5 S4 C29 F11 40.9(10) . . . . ?
O4 S4 C29 F11 109.3(9) 2 . . . ?
S4 S4 C29 F11 -85.7(18) 2 . . 2 ?
O4 S4 C29 F11 98.1(12) . . . 2 ?
O5 S4 C29 F11 -14.6(12) 2 . . 2 ?
O5 S4 C29 F11 -151.5(10) . . . 2 ?
O4 S4 C29 F11 -83.2(10) 2 . . 2 ?
O4 S4 C29 S4 -176(2) . . . 2 ?
O5 S4 C29 S4 71.1(13) 2 . . 2 ?
O5 S4 C29 S4 -65.8(14) . . . 2 ?
O4 S4 C29 S4 2.5(13) 2 . . 2 ?
