#------------------------------------------------------------------------------
#$Date: 2020-07-06 06:14:56 +0300 (Mon, 06 Jul 2020) $
#$Revision: 253922 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/41/7704197.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7704197
loop_
_publ_author_name
'Yabune, Natsuki'
'Nakajima, Hiroshi'
'Nishioka, Takanori'
_publ_section_title
;
 Metal-metal bond formation of triplatinum cores with a silver(i) ion
 affording a heptanuclear cluster bearing four Pt-Ag bonds.
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7680
_journal_page_last               7683
_journal_paper_doi               10.1039/d0dt01227k
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C28 H36 Cl F3 N12 O3 Pt3 S3'
_chemical_formula_sum            'C28 H36 Cl F3 N12 O3 Pt3 S3'
_chemical_formula_weight         1362.57
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2020-04-02 deposited with the CCDC.	2020-04-27 downloaded from the CCDC.
;
_cell_angle_alpha                90.0000
_cell_angle_beta                 113.9235(16)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            16
_cell_length_a                   38.466(7)
_cell_length_b                   18.519(3)
_cell_length_c                   28.967(5)
_cell_measurement_reflns_used    21109
_cell_measurement_temperature    193
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      3.01
_cell_volume                     18862(6)
_computing_cell_refinement       CrystalClear
_computing_data_collection       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'CrystalStructure 4.3'
_computing_publication_material  'CrystalStructure 4.3 (Rigaku, 2019)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    SIR97
_diffrn_ambient_temperature      193
_diffrn_detector_area_resol_mean 14.222
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Rigaku Saturn724'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0401
_diffrn_reflns_Laue_measured_fraction_full 0.000
_diffrn_reflns_Laue_measured_fraction_max 0.000
_diffrn_reflns_limit_h_max       49
_diffrn_reflns_limit_h_min       -49
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            95400
_diffrn_reflns_point_group_measured_fraction_full 0.000
_diffrn_reflns_point_group_measured_fraction_max 0.000
_diffrn_reflns_theta_full        27.450
_diffrn_reflns_theta_max         27.450
_diffrn_reflns_theta_min         3.009
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    9.084
_exptl_absorpt_correction_T_max  0.438
_exptl_absorpt_correction_T_min  0.350
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.919
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             10208.00
_exptl_crystal_size_max          0.126
_exptl_crystal_size_mid          0.096
_exptl_crystal_size_min          0.091
_refine_diff_density_max         2.94
_refine_diff_density_min         -2.41
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.095
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     974
_refine_ls_number_reflns         21456
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0699
_refine_ls_R_factor_gt           0.0651
_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0911P)²+434.3782P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1769
_refine_ls_wR_factor_ref         0.1813
_reflns_number_gt                19778
_reflns_number_total             21456
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            d0dt01227k2.cif
_cod_data_source_block           Pt3C1-Me
_cod_depositor_comments
'Adding full bibliography for 7704196--7704197.cif.'
_cod_database_code               7704197
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.240920(11) 1.01613(2) 0.099127(15) 0.03892(10) Uani 1 1 d . . .
Pt2 Pt 0.296359(14) 0.96497(2) 0.058709(19) 0.04870(12) Uani 1 1 d . . .
Pt3 Pt 0.209013(13) 0.89645(2) 0.013275(16) 0.04284(11) Uani 1 1 d . . .
Pt4 Pt 0.061625(11) 0.90836(2) 0.132825(15) 0.03862(10) Uani 1 1 d . . .
Pt5 Pt 0.138051(11) 0.87073(2) 0.139275(14) 0.03784(10) Uani 1 1 d . . .
Pt6 Pt 0.093577(10) 0.99395(2) 0.057157(14) 0.03542(10) Uani 1 1 d . . .
Cl1 Cl 0.0217(4) 0.7409(8) -0.0986(6) 0.140(6) Uani 0.50 1 d P . .
Cl2 Cl 0.0152(3) 0.7957(18) -0.1627(12) 0.38(3) Uani 0.50 1 d P . .
Cl3 Cl 0.0000 0.6004(6) 0.2500 0.131(8) Uani 0.50 2 d SP . .
Cl4 Cl 0.0000 0.6736(12) 0.2500 0.135(6) Uani 0.50 2 d SP . .
Cl5 Cl 0.3677(8) 1.0709(13) -0.1179(9) 0.280(17) Uani 0.50 1 d P . .
S1 S 0.23430(9) 1.01239(15) 0.01398(11) 0.0456(6) Uani 1 1 d . . .
S2 S 0.26036(8) 0.89632(14) 0.09278(10) 0.0420(5) Uani 1 1 d . . .
S3 S 0.11372(7) 0.98616(14) 0.14523(9) 0.0367(5) Uani 1 1 d . . .
S4 S 0.07937(7) 0.87232(14) 0.06663(9) 0.0398(5) Uani 1 1 d . . .
S5 S 0.16526(12) 1.1640(2) -0.10621(15) 0.0688(9) Uani 1 1 d . . .
S6 S 0.17559(9) 1.19614(19) 0.26755(13) 0.0565(8) Uani 1 1 d . . .
F1 F 0.1233(4) 1.2095(8) -0.1928(5) 0.152(6) Uani 1 1 d . . .
F2 F 0.1493(4) 1.2937(7) -0.1357(5) 0.132(5) Uani 1 1 d . . .
F3 F 0.1025(4) 1.2321(10) -0.1340(8) 0.173(7) Uani 1 1 d . . .
F4 F 0.1149(3) 1.2197(7) 0.2829(5) 0.107(4) Uani 1 1 d . . .
F5 F 0.1416(4) 1.3161(6) 0.2731(5) 0.110(4) Uani 1 1 d . . .
F6 F 0.1115(5) 1.2469(9) 0.2110(4) 0.162(7) Uani 1 1 d . . .
O1 O 0.1428(3) 1.1010(5) -0.1204(4) 0.071(3) Uani 1 1 d . . .
O2 O 0.1959(3) 1.1659(7) -0.1202(5) 0.093(4) Uani 1 1 d . . .
O3 O 0.1725(3) 1.1901(6) -0.0576(4) 0.071(3) Uani 1 1 d . . .
O4 O 0.1633(3) 1.1221(6) 0.2548(5) 0.075(3) Uani 1 1 d . . .
O5 O 0.1993(3) 1.2022(8) 0.3220(4) 0.086(4) Uani 1 1 d . . .
O6 O 0.1933(7) 1.2215(11) 0.2375(7) 0.177(10) Uani 1 1 d . . .
N1 N 0.2070(2) 1.1411(5) 0.1292(3) 0.0406(19) Uani 1 1 d . . .
N2 N 0.2364(3) 1.1798(5) 0.0852(4) 0.045(2) Uani 1 1 d . . .
N3 N 0.2259(3) 1.0483(5) 0.1895(3) 0.0425(19) Uani 1 1 d . . .
N4 N 0.2779(3) 0.9897(6) 0.2136(4) 0.054(2) Uani 1 1 d . . .
N5 N 0.3571(4) 1.0663(7) 0.0659(6) 0.076(4) Uani 1 1 d . . .
N6 N 0.3186(5) 1.0631(7) -0.0116(7) 0.085(4) Uani 1 1 d . . .
N7 N 0.3774(3) 0.9708(7) 0.1270(6) 0.075(4) Uani 1 1 d . . .
N8 N 0.3613(3) 0.8605(6) 0.1200(5) 0.060(3) Uani 1 1 d . . .
N9 N 0.1316(3) 0.8766(6) -0.0653(4) 0.059(3) Uani 1 1 d . . .
N10 N 0.1657(4) 0.9218(6) -0.1011(4) 0.061(3) Uani 1 1 d . . .
N11 N 0.1489(3) 0.7892(6) -0.0016(4) 0.054(2) Uani 1 1 d . . .
N12 N 0.2016(3) 0.7325(5) 0.0331(4) 0.050(2) Uani 1 1 d . . .
N13 N 0.0501(3) 0.8816(7) 0.2252(4) 0.057(3) Uani 1 1 d . . .
N14 N 0.0568(3) 0.9950(6) 0.2213(4) 0.054(3) Uani 1 1 d . . .
N15 N 0.0183(3) 0.7967(6) 0.1605(4) 0.057(3) Uani 1 1 d . . .
N16 N -0.0086(3) 0.8118(6) 0.0803(4) 0.054(2) Uani 1 1 d . . .
N17 N 0.2179(2) 0.8452(6) 0.2105(4) 0.050(2) Uani 1 1 d . . .
N18 N 0.1875(3) 0.8928(6) 0.2517(3) 0.051(2) Uani 1 1 d . . .
N19 N 0.1942(3) 0.7559(6) 0.1490(4) 0.051(2) Uani 1 1 d . . .
N20 N 0.1389(3) 0.7063(6) 0.1223(4) 0.053(2) Uani 1 1 d . . .
N21 N 0.1258(3) 1.1162(5) 0.0216(3) 0.0407(19) Uani 1 1 d . . .
N22 N 0.1046(2) 1.1592(5) 0.0729(3) 0.0414(19) Uani 1 1 d . . .
N23 N 0.0966(2) 1.0278(5) -0.0407(3) 0.0399(19) Uani 1 1 d . . .
N24 N 0.0433(2) 0.9767(5) -0.0564(3) 0.0401(19) Uani 1 1 d . . .
C1 C 0.2252(3) 1.1203(6) 0.1013(4) 0.042(2) Uani 1 1 d . . .
C2 C 0.2060(3) 1.2160(6) 0.1313(5) 0.048(3) Uani 1 1 d . . .
H2 H 0.1949 1.2446 0.1489 0.058 Uiso 1 1 calc R . .
C3 C 0.2237(4) 1.2391(7) 0.1039(5) 0.061(3) Uani 1 1 d . . .
H3 H 0.2273 1.2883 0.0977 0.073 Uiso 1 1 calc R . .
C4 C 0.2577(4) 1.1833(7) 0.0526(5) 0.058(3) Uani 1 1 d . . .
H4A H 0.2403 1.1746 0.0174 0.070 Uiso 1 1 calc R . .
H4B H 0.2777 1.1465 0.0633 0.070 Uiso 1 1 calc R . .
H4C H 0.2693 1.2312 0.0555 0.070 Uiso 1 1 calc R . .
C5 C 0.1938(3) 1.0895(7) 0.1559(4) 0.048(3) Uani 1 1 d . . .
H5A H 0.1816 1.1151 0.1754 0.057 Uiso 1 1 calc R . .
H5B H 0.1747 1.0569 0.1316 0.057 Uiso 1 1 calc R . .
C6 C 0.2491(3) 1.0141(6) 0.1727(4) 0.045(2) Uani 1 1 d . . .
C7 C 0.2401(4) 1.0459(7) 0.2419(4) 0.057(3) Uani 1 1 d . . .
H7 H 0.2292 1.0668 0.2629 0.068 Uiso 1 1 calc R . .
C8 C 0.2726(5) 1.0076(8) 0.2565(5) 0.067(4) Uani 1 1 d . . .
H8 H 0.2888 0.9951 0.2902 0.080 Uiso 1 1 calc R . .
C9 C 0.3112(4) 0.9506(10) 0.2148(5) 0.074(4) Uani 1 1 d . . .
H9A H 0.3342 0.9783 0.2342 0.089 Uiso 1 1 calc R . .
H9B H 0.3091 0.9438 0.1802 0.089 Uiso 1 1 calc R . .
H9C H 0.3126 0.9033 0.2307 0.089 Uiso 1 1 calc R . .
C10 C 0.3250(5) 1.0354(8) 0.0355(7) 0.070(4) Uani 1 1 d . . .
C11 C 0.3469(7) 1.1108(11) -0.0077(11) 0.104(7) Uani 1 1 d . . .
H11 H 0.3487 1.1384 -0.0342 0.125 Uiso 1 1 calc R . .
C12 C 0.3708(6) 1.1107(10) 0.0395(11) 0.101(7) Uani 1 1 d . . .
H12 H 0.3939 1.1371 0.0533 0.122 Uiso 1 1 calc R . .
C13 C 0.2874(7) 1.0444(11) -0.0595(8) 0.103(7) Uani 1 1 d . . .
H13A H 0.2972 1.0383 -0.0856 0.124 Uiso 1 1 calc R . .
H13B H 0.2684 1.0832 -0.0695 0.124 Uiso 1 1 calc R . .
H13C H 0.2755 0.9993 -0.0556 0.124 Uiso 1 1 calc R . .
C14 C 0.3742(5) 1.0508(8) 0.1193(8) 0.082(5) Uani 1 1 d . . .
H14A H 0.3585 1.0715 0.1359 0.098 Uiso 1 1 calc R . .
H14B H 0.3998 1.0731 0.1347 0.098 Uiso 1 1 calc R . .
C15 C 0.3473(4) 0.9271(7) 0.1032(6) 0.061(3) Uani 1 1 d . . .
C16 C 0.4085(4) 0.9307(11) 0.1544(8) 0.094(6) Uani 1 1 d . . .
H16 H 0.4335 0.9488 0.1723 0.113 Uiso 1 1 calc R . .
C17 C 0.3983(4) 0.8634(9) 0.1518(7) 0.079(5) Uani 1 1 d . . .
H17 H 0.4139 0.8239 0.1690 0.095 Uiso 1 1 calc R . .
C18 C 0.3389(4) 0.7945(7) 0.1035(6) 0.063(3) Uani 1 1 d . . .
H18A H 0.3205 0.7999 0.0684 0.075 Uiso 1 1 calc R . .
H18B H 0.3252 0.7854 0.1251 0.075 Uiso 1 1 calc R . .
H18C H 0.3558 0.7538 0.1060 0.075 Uiso 1 1 calc R . .
C19 C 0.1863(4) 0.7991(7) 0.0166(4) 0.049(3) Uani 1 1 d . . .
C20 C 0.1399(4) 0.7152(8) 0.0018(5) 0.061(3) Uani 1 1 d . . .
H20 H 0.1153 0.6944 -0.0085 0.073 Uiso 1 1 calc R . .
C21 C 0.1724(4) 0.6823(7) 0.0219(5) 0.057(3) Uani 1 1 d . . .
H21 H 0.1758 0.6319 0.0281 0.068 Uiso 1 1 calc R . .
C22 C 0.2421(4) 0.7144(7) 0.0555(5) 0.054(3) Uani 1 1 d . . .
H22A H 0.2570 0.7574 0.0560 0.065 Uiso 1 1 calc R . .
H22B H 0.2472 0.6765 0.0354 0.065 Uiso 1 1 calc R . .
H22C H 0.2491 0.6970 0.0901 0.065 Uiso 1 1 calc R . .
C23 C 0.1223(4) 0.8470(8) -0.0264(6) 0.062(3) Uani 1 1 d . . .
H23A H 0.0960 0.8279 -0.0410 0.074 Uiso 1 1 calc R . .
H23B H 0.1239 0.8850 -0.0016 0.074 Uiso 1 1 calc R . .
C24 C 0.1662(4) 0.9027(6) -0.0555(5) 0.051(3) Uani 1 1 d . . .
C25 C 0.1092(5) 0.8798(8) -0.1181(6) 0.080(5) Uani 1 1 d . . .
H25 H 0.0836 0.8638 -0.1352 0.096 Uiso 1 1 calc R . .
C26 C 0.1311(5) 0.9097(9) -0.1392(5) 0.073(4) Uani 1 1 d . . .
H26 H 0.1238 0.9203 -0.1740 0.088 Uiso 1 1 calc R . .
C27 C 0.1967(5) 0.9529(9) -0.1109(6) 0.072(4) Uani 1 1 d . . .
H27A H 0.2210 0.9406 -0.0831 0.087 Uiso 1 1 calc R . .
H27B H 0.1939 1.0055 -0.1135 0.087 Uiso 1 1 calc R . .
H27C H 0.1963 0.9335 -0.1426 0.087 Uiso 1 1 calc R . .
C28 C 0.0551(3) 0.9326(7) 0.1964(4) 0.047(3) Uani 1 1 d . . .
C29 C 0.0481(4) 0.9126(10) 0.2685(5) 0.071(4) Uani 1 1 d . . .
H29 H 0.0439 0.8878 0.2945 0.085 Uiso 1 1 calc R . .
C30 C 0.0531(4) 0.9798(11) 0.2660(5) 0.073(5) Uani 1 1 d . . .
H30 H 0.0541 1.0144 0.2907 0.088 Uiso 1 1 calc R . .
C31 C 0.0641(4) 1.0676(8) 0.2062(5) 0.066(4) Uani 1 1 d . . .
H31A H 0.0478 1.0755 0.1704 0.079 Uiso 1 1 calc R . .
H31B H 0.0908 1.0714 0.2114 0.079 Uiso 1 1 calc R . .
H31C H 0.0584 1.1041 0.2267 0.079 Uiso 1 1 calc R . .
C32 C 0.0464(4) 0.8068(9) 0.2104(5) 0.066(4) Uani 1 1 d . . .
H32A H 0.0712 0.7889 0.2123 0.079 Uiso 1 1 calc R . .
H32B H 0.0394 0.7782 0.2343 0.079 Uiso 1 1 calc R . .
C33 C 0.0209(3) 0.8342(7) 0.1214(5) 0.050(3) Uani 1 1 d . . .
C34 C -0.0127(5) 0.7524(10) 0.1442(6) 0.083(5) Uani 1 1 d . . .
H34 H -0.0209 0.7219 0.1642 0.100 Uiso 1 1 calc R . .
C35 C -0.0290(5) 0.7607(11) 0.0945(7) 0.089(6) Uani 1 1 d . . .
H35 H -0.0510 0.7359 0.0721 0.107 Uiso 1 1 calc R . .
C36 C -0.0182(4) 0.8354(8) 0.0294(5) 0.061(3) Uani 1 1 d . . .
H36A H -0.0132 0.7963 0.0101 0.073 Uiso 1 1 calc R . .
H36B H -0.0028 0.8776 0.0296 0.073 Uiso 1 1 calc R . .
H36C H -0.0452 0.8483 0.0137 0.073 Uiso 1 1 calc R . .
C37 C 0.1835(3) 0.8741(6) 0.2053(4) 0.043(2) Uani 1 1 d . . .
C38 C 0.2421(4) 0.8448(8) 0.2621(5) 0.061(3) Uani 1 1 d . . .
H38 H 0.2673 0.8264 0.2765 0.073 Uiso 1 1 calc R . .
C39 C 0.2235(4) 0.8748(8) 0.2877(5) 0.063(3) Uani 1 1 d . . .
H39 H 0.2330 0.8823 0.3231 0.075 Uiso 1 1 calc R . .
C40 C 0.1590(4) 0.9283(8) 0.2641(5) 0.062(3) Uani 1 1 d . . .
H40A H 0.1342 0.9057 0.2454 0.074 Uiso 1 1 calc R . .
H40B H 0.1577 0.9795 0.2550 0.074 Uiso 1 1 calc R . .
H40C H 0.1657 0.9239 0.3005 0.074 Uiso 1 1 calc R . .
C41 C 0.2233(3) 0.8100(8) 0.1700(5) 0.055(3) Uani 1 1 d . . .
H41A H 0.2487 0.7873 0.1826 0.067 Uiso 1 1 calc R . .
H41B H 0.2216 0.8457 0.1437 0.067 Uiso 1 1 calc R . .
C42 C 0.1566(3) 0.7709(7) 0.1331(4) 0.047(2) Uani 1 1 d . . .
C43 C 0.1999(4) 0.6818(8) 0.1496(5) 0.066(4) Uani 1 1 d . . .
H43 H 0.2236 0.6575 0.1599 0.079 Uiso 1 1 calc R . .
C44 C 0.1651(5) 0.6514(8) 0.1324(6) 0.067(4) Uani 1 1 d . . .
H44 H 0.1596 0.6012 0.1281 0.081 Uiso 1 1 calc R . .
C45 C 0.0974(4) 0.6942(8) 0.1034(6) 0.071(4) Uani 1 1 d . . .
H45A H 0.0846 0.7198 0.0713 0.085 Uiso 1 1 calc R . .
H45B H 0.0882 0.7124 0.1281 0.085 Uiso 1 1 calc R . .
H45C H 0.0921 0.6424 0.0982 0.085 Uiso 1 1 calc R . .
C46 C 0.1096(3) 1.0963(6) 0.0530(4) 0.039(2) Uani 1 1 d . . .
C47 C 0.1302(3) 1.1901(6) 0.0207(4) 0.049(3) Uani 1 1 d . . .
H47 H 0.1406 1.2164 0.0011 0.059 Uiso 1 1 calc R . .
C48 C 0.1167(3) 1.2174(6) 0.0533(4) 0.049(3) Uani 1 1 d . . .
H48 H 0.1158 1.2669 0.0613 0.058 Uiso 1 1 calc R . .
C49 C 0.0857(4) 1.1674(7) 0.1073(5) 0.055(3) Uani 1 1 d . . .
H49A H 0.0990 1.1384 0.1377 0.066 Uiso 1 1 calc R . .
H49B H 0.0593 1.1511 0.0905 0.066 Uiso 1 1 calc R . .
H49C H 0.0862 1.2183 0.1167 0.066 Uiso 1 1 calc R . .
C50 C 0.1333(3) 1.0629(6) -0.0107(4) 0.044(2) Uani 1 1 d . . .
H50A H 0.1521 1.0268 0.0102 0.053 Uiso 1 1 calc R . .
H50B H 0.1435 1.0869 -0.0331 0.053 Uiso 1 1 calc R . .
C51 C 0.0760(3) 0.9950(6) -0.0193(3) 0.036(2) Uani 1 1 d . . .
C52 C 0.0770(4) 1.0317(7) -0.0929(4) 0.049(3) Uani 1 1 d . . .
H52 H 0.0853 1.0534 -0.1164 0.059 Uiso 1 1 calc R . .
C53 C 0.0435(3) 0.9979(7) -0.1028(4) 0.049(3) Uani 1 1 d . . .
H53 H 0.0238 0.9899 -0.1353 0.058 Uiso 1 1 calc R . .
C54 C 0.0106(3) 0.9429(7) -0.0524(5) 0.050(3) Uani 1 1 d . . .
H54A H 0.0158 0.9352 -0.0167 0.060 Uiso 1 1 calc R . .
H54B H 0.0056 0.8964 -0.0700 0.060 Uiso 1 1 calc R . .
H54C H -0.0116 0.9744 -0.0678 0.060 Uiso 1 1 calc R . .
C55 C 0.1368(6) 1.2185(13) -0.1387(9) 0.112(9) Uani 1 1 d . . .
C56 C 0.1342(4) 1.2423(12) 0.2598(6) 0.086(6) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
F F 0.0171 0.0103
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
O O 0.0106 0.0060
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Pt Pt -1.7033 8.3905
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
S S 0.1246 0.1234
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Cl Cl 0.1484 0.1585
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 Pt1 C1 84.6(4) . . ?
C6 Pt1 S2 98.3(3) . . ?
C1 Pt1 S2 176.7(3) . . ?
C6 Pt1 S1 176.3(3) . . ?
C1 Pt1 S1 98.7(3) . . ?
S2 Pt1 S1 78.27(9) . . ?
C6 Pt1 Pt2 125.4(3) . . ?
C1 Pt1 Pt2 125.8(3) . . ?
S2 Pt1 Pt2 51.13(7) . . ?
S1 Pt1 Pt2 51.24(7) . . ?
C6 Pt1 Pt3 131.0(3) . . ?
C1 Pt1 Pt3 131.3(3) . . ?
S2 Pt1 Pt3 47.30(7) . . ?
S1 Pt1 Pt3 47.42(7) . . ?
Pt2 Pt1 Pt3 65.247(18) . . ?
C15 Pt2 C10 85.0(6) . . ?
C15 Pt2 S2 97.5(4) . . ?
C10 Pt2 S2 171.3(5) . . ?
C15 Pt2 S1 173.5(4) . . ?
C10 Pt2 S1 98.4(5) . . ?
S2 Pt2 S1 78.33(10) . . ?
C15 Pt2 Pt1 122.3(4) . . ?
C10 Pt2 Pt1 120.5(4) . . ?
S2 Pt2 Pt1 51.21(7) . . ?
S1 Pt2 Pt1 51.26(7) . . ?
C24 Pt3 C19 84.4(5) . . ?
C24 Pt3 S2 176.4(4) . . ?
C19 Pt3 S2 99.2(3) . . ?
C24 Pt3 S1 97.2(4) . . ?
C19 Pt3 S1 176.0(3) . . ?
S2 Pt3 S1 79.18(10) . . ?
C24 Pt3 Pt1 129.5(3) . . ?
C19 Pt3 Pt1 128.3(3) . . ?
S2 Pt3 Pt1 47.93(7) . . ?
S1 Pt3 Pt1 48.00(7) . . ?
C28 Pt4 C33 85.6(5) . . ?
C28 Pt4 S3 97.9(3) . . ?
C33 Pt4 S3 174.1(4) . . ?
C28 Pt4 S4 170.6(3) . . ?
C33 Pt4 S4 97.8(4) . . ?
S3 Pt4 S4 77.97(9) . . ?
C28 Pt4 Pt5 119.1(3) . . ?
C33 Pt4 Pt5 122.7(4) . . ?
S3 Pt4 Pt5 51.39(7) . . ?
S4 Pt4 Pt5 51.72(6) . . ?
C37 Pt5 C42 84.8(5) . . ?
C37 Pt5 S3 96.9(3) . . ?
C42 Pt5 S3 177.7(3) . . ?
C37 Pt5 S4 172.6(3) . . ?
C42 Pt5 S4 100.1(3) . . ?
S3 Pt5 S4 78.01(9) . . ?
C37 Pt5 Pt4 121.0(3) . . ?
C42 Pt5 Pt4 126.1(3) . . ?
S3 Pt5 Pt4 51.59(6) . . ?
S4 Pt5 Pt4 51.58(7) . . ?
C37 Pt5 Pt6 132.5(3) . . ?
C42 Pt5 Pt6 133.0(3) . . ?
S3 Pt5 Pt6 46.43(6) . . ?
S4 Pt5 Pt6 46.63(6) . . ?
Pt4 Pt5 Pt6 64.624(14) . . ?
C46 Pt6 C51 84.3(4) . . ?
C46 Pt6 S3 98.6(3) . . ?
C51 Pt6 S3 177.0(3) . . ?
C46 Pt6 S4 175.8(3) . . ?
C51 Pt6 S4 98.4(3) . . ?
S3 Pt6 S4 78.77(9) . . ?
C46 Pt6 Pt5 128.6(3) . . ?
C51 Pt6 Pt5 130.5(3) . . ?
S3 Pt6 Pt5 46.87(7) . . ?
S4 Pt6 Pt5 47.19(6) . . ?
Pt3 S1 Pt2 89.30(10) . . ?
Pt3 S1 Pt1 84.58(9) . . ?
Pt2 S1 Pt1 77.49(9) . . ?
Pt3 S2 Pt2 89.55(9) . . ?
Pt3 S2 Pt1 84.77(9) . . ?
Pt2 S2 Pt1 77.66(8) . . ?
Pt6 S3 Pt5 86.70(9) . . ?
Pt6 S3 Pt4 89.22(8) . . ?
Pt5 S3 Pt4 77.02(8) . . ?
Pt6 S4 Pt4 88.95(9) . . ?
Pt6 S4 Pt5 86.18(9) . . ?
Pt4 S4 Pt5 76.71(8) . . ?
O2 S5 O3 115.8(7) . . ?
O2 S5 O1 115.3(7) . . ?
O3 S5 O1 115.1(7) . . ?
O2 S5 C55 106.8(11) . . ?
O3 S5 C55 101.1(9) . . ?
O1 S5 C55 99.7(8) . . ?
O6 S6 O4 110.7(8) . . ?
O6 S6 O5 113.5(10) . . ?
O4 S6 O5 110.0(8) . . ?
O6 S6 C56 114.1(13) . . ?
O4 S6 C56 104.1(8) . . ?
O5 S6 C56 103.8(7) . . ?
C1 N1 C2 110.3(10) . . ?
C1 N1 C5 121.5(9) . . ?
C2 N1 C5 128.0(10) . . ?
C1 N2 C3 107.6(11) . . ?
C1 N2 C4 126.8(10) . . ?
C3 N2 C4 125.6(11) . . ?
C6 N3 C7 110.9(10) . . ?
C6 N3 C5 121.3(9) . . ?
C7 N3 C5 127.3(10) . . ?
C6 N4 C8 110.2(11) . . ?
C6 N4 C9 126.5(11) . . ?
C8 N4 C9 123.3(11) . . ?
C10 N5 C12 110.9(17) . . ?
C10 N5 C14 121.7(13) . . ?
C12 N5 C14 127.4(17) . . ?
C11 N6 C10 109.7(19) . . ?
C11 N6 C13 123.4(17) . . ?
C10 N6 C13 126.8(14) . . ?
C15 N7 C16 110.0(14) . . ?
C15 N7 C14 121.1(12) . . ?
C16 N7 C14 128.8(14) . . ?
C17 N8 C15 111.3(13) . . ?
C17 N8 C18 125.2(11) . . ?
C15 N8 C18 123.4(12) . . ?
C24 N9 C25 109.5(14) . . ?
C24 N9 C23 121.3(11) . . ?
C25 N9 C23 129.1(14) . . ?
C24 N10 C26 111.7(13) . . ?
C24 N10 C27 127.1(12) . . ?
C26 N10 C27 121.2(13) . . ?
C19 N11 C20 111.1(11) . . ?
C19 N11 C23 121.7(11) . . ?
C20 N11 C23 126.9(11) . . ?
C19 N12 C21 109.3(11) . . ?
C19 N12 C22 126.3(11) . . ?
C21 N12 C22 124.2(10) . . ?
C28 N13 C29 110.2(12) . . ?
C28 N13 C32 121.4(11) . . ?
C29 N13 C32 128.4(12) . . ?
C28 N14 C30 109.0(13) . . ?
C28 N14 C31 126.4(10) . . ?
C30 N14 C31 124.4(12) . . ?
C34 N15 C33 111.3(12) . . ?
C34 N15 C32 128.9(12) . . ?
C33 N15 C32 119.7(10) . . ?
C33 N16 C35 108.9(11) . . ?
C33 N16 C36 126.6(11) . . ?
C35 N16 C36 124.6(11) . . ?
C37 N17 C38 108.1(11) . . ?
C37 N17 C41 122.6(9) . . ?
C38 N17 C41 128.3(11) . . ?
C37 N18 C39 111.2(11) . . ?
C37 N18 C40 125.6(10) . . ?
C39 N18 C40 123.2(11) . . ?
C42 N19 C43 110.4(12) . . ?
C42 N19 C41 122.6(10) . . ?
C43 N19 C41 126.2(11) . . ?
C42 N20 C44 110.5(12) . . ?
C42 N20 C45 126.0(11) . . ?
C44 N20 C45 123.5(12) . . ?
C46 N21 C47 112.3(10) . . ?
C46 N21 C50 120.7(9) . . ?
C47 N21 C50 126.7(9) . . ?
C46 N22 C48 111.5(10) . . ?
C46 N22 C49 125.4(10) . . ?
C48 N22 C49 122.9(10) . . ?
C51 N23 C52 111.5(9) . . ?
C51 N23 C50 122.2(9) . . ?
C52 N23 C50 125.8(10) . . ?
C51 N24 C53 109.5(9) . . ?
C51 N24 C54 127.9(9) . . ?
C53 N24 C54 122.6(9) . . ?
N1 C1 N2 107.3(10) . . ?
N1 C1 Pt1 122.2(8) . . ?
N2 C1 Pt1 129.2(9) . . ?
C3 C2 N1 105.7(11) . . ?
C3 C2 H2 127.2 . . ?
N1 C2 H2 127.2 . . ?
C2 C3 N2 109.1(11) . . ?
C2 C3 H3 125.5 . . ?
N2 C3 H3 125.5 . . ?
N2 C4 H4A 109.5 . . ?
N2 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
N2 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
N3 C5 N1 108.7(9) . . ?
N3 C5 H5A 109.9 . . ?
N1 C5 H5A 109.9 . . ?
N3 C5 H5B 109.9 . . ?
N1 C5 H5B 109.9 . . ?
H5A C5 H5B 108.3 . . ?
N4 C6 N3 105.9(10) . . ?
N4 C6 Pt1 131.4(9) . . ?
N3 C6 Pt1 122.2(8) . . ?
C8 C7 N3 105.4(11) . . ?
C8 C7 H7 127.3 . . ?
N3 C7 H7 127.3 . . ?
C7 C8 N4 107.5(11) . . ?
C7 C8 H8 126.2 . . ?
N4 C8 H8 126.2 . . ?
N4 C9 H9A 109.5 . . ?
N4 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
N4 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
N5 C10 N6 104.1(14) . . ?
N5 C10 Pt2 123.7(12) . . ?
N6 C10 Pt2 132.3(14) . . ?
C12 C11 N6 106.7(18) . . ?
C12 C11 H11 126.7 . . ?
N6 C11 H11 126.7 . . ?
C11 C12 N5 108.6(18) . . ?
C11 C12 H12 125.7 . . ?
N5 C12 H12 125.7 . . ?
N6 C13 H13A 109.5 . . ?
N6 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
N6 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
N5 C14 N7 109.2(14) . . ?
N5 C14 H14A 109.8 . . ?
N7 C14 H14A 109.8 . . ?
N5 C14 H14B 109.8 . . ?
N7 C14 H14B 109.8 . . ?
H14A C14 H14B 108.3 . . ?
N7 C15 N8 103.3(12) . . ?
N7 C15 Pt2 122.4(10) . . ?
N8 C15 Pt2 134.2(11) . . ?
C17 C16 N7 108.4(15) . . ?
C17 C16 H16 125.8 . . ?
N7 C16 H16 125.8 . . ?
C16 C17 N8 106.8(14) . . ?
C16 C17 H17 126.6 . . ?
N8 C17 H17 126.6 . . ?
N8 C18 H18A 109.5 . . ?
N8 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
N8 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N11 C19 N12 104.9(11) . . ?
N11 C19 Pt3 121.5(9) . . ?
N12 C19 Pt3 133.5(9) . . ?
C21 C20 N11 105.4(12) . . ?
C21 C20 H20 127.3 . . ?
N11 C20 H20 127.3 . . ?
C20 C21 N12 109.2(12) . . ?
C20 C21 H21 125.4 . . ?
N12 C21 H21 125.4 . . ?
N12 C22 H22A 109.5 . . ?
N12 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
N12 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
N9 C23 N11 108.9(11) . . ?
N9 C23 H23A 109.9 . . ?
N11 C23 H23A 109.9 . . ?
N9 C23 H23B 109.9 . . ?
N11 C23 H23B 109.9 . . ?
H23A C23 H23B 108.3 . . ?
N9 C24 N10 105.5(11) . . ?
N9 C24 Pt3 122.4(10) . . ?
N10 C24 Pt3 131.4(10) . . ?
C26 C25 N9 106.7(14) . . ?
C26 C25 H25 126.6 . . ?
N9 C25 H25 126.6 . . ?
C25 C26 N10 106.6(13) . . ?
C25 C26 H26 126.7 . . ?
N10 C26 H26 126.7 . . ?
N10 C27 H27A 109.5 . . ?
N10 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
N10 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
N13 C28 N14 105.1(11) . . ?
N13 C28 Pt4 121.5(9) . . ?
N14 C28 Pt4 133.3(9) . . ?
C30 C29 N13 106.5(13) . . ?
C30 C29 H29 126.8 . . ?
N13 C29 H29 126.8 . . ?
C29 C30 N14 109.2(14) . . ?
C29 C30 H30 125.4 . . ?
N14 C30 H30 125.4 . . ?
N14 C31 H31A 109.5 . . ?
N14 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
N14 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
N15 C32 N13 111.8(12) . . ?
N15 C32 H32A 109.3 . . ?
N13 C32 H32A 109.3 . . ?
N15 C32 H32B 109.3 . . ?
N13 C32 H32B 109.3 . . ?
H32A C32 H32B 107.9 . . ?
N16 C33 N15 105.3(10) . . ?
N16 C33 Pt4 133.0(9) . . ?
N15 C33 Pt4 121.7(9) . . ?
C35 C34 N15 105.6(14) . . ?
C35 C34 H34 127.2 . . ?
N15 C34 H34 127.2 . . ?
C34 C35 N16 108.9(13) . . ?
C34 C35 H35 125.5 . . ?
N16 C35 H35 125.5 . . ?
N16 C36 H36A 109.5 . . ?
N16 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
N16 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
N18 C37 N17 106.1(9) . . ?
N18 C37 Pt5 131.9(9) . . ?
N17 C37 Pt5 121.4(8) . . ?
C39 C38 N17 108.4(11) . . ?
C39 C38 H38 125.8 . . ?
N17 C38 H38 125.8 . . ?
C38 C39 N18 106.1(12) . . ?
C38 C39 H39 126.9 . . ?
N18 C39 H39 126.9 . . ?
N18 C40 H40A 109.5 . . ?
N18 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
N18 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
N17 C41 N19 108.6(9) . . ?
N17 C41 H41A 110.0 . . ?
N19 C41 H41A 110.0 . . ?
N17 C41 H41B 110.0 . . ?
N19 C41 H41B 110.0 . . ?
H41A C41 H41B 108.4 . . ?
N20 C42 N19 105.4(10) . . ?
N20 C42 Pt5 132.2(9) . . ?
N19 C42 Pt5 121.6(9) . . ?
C44 C43 N19 106.2(12) . . ?
C44 C43 H43 126.9 . . ?
N19 C43 H43 126.9 . . ?
C43 C44 N20 107.5(13) . . ?
C43 C44 H44 126.3 . . ?
N20 C44 H44 126.3 . . ?
N20 C45 H45A 109.5 . . ?
N20 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
N20 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
N21 C46 N22 103.7(9) . . ?
N21 C46 Pt6 122.4(8) . . ?
N22 C46 Pt6 133.5(8) . . ?
C48 C47 N21 105.9(10) . . ?
C48 C47 H47 127.1 . . ?
N21 C47 H47 127.1 . . ?
C47 C48 N22 106.6(10) . . ?
C47 C48 H48 126.7 . . ?
N22 C48 H48 126.7 . . ?
N22 C49 H49A 109.5 . . ?
N22 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
N22 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
N21 C50 N23 106.4(8) . . ?
N21 C50 H50A 110.5 . . ?
N23 C50 H50A 110.5 . . ?
N21 C50 H50B 110.5 . . ?
N23 C50 H50B 110.5 . . ?
H50A C50 H50B 108.6 . . ?
N24 C51 N23 106.6(8) . . ?
N24 C51 Pt6 131.9(8) . . ?
N23 C51 Pt6 120.8(7) . . ?
C53 C52 N23 104.8(10) . . ?
C53 C52 H52 127.6 . . ?
N23 C52 H52 127.6 . . ?
C52 C53 N24 107.5(9) . . ?
C52 C53 H53 126.3 . . ?
N24 C53 H53 126.3 . . ?
N24 C54 H54A 109.5 . . ?
N24 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
N24 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
F3 C55 F1 100.8(18) . . ?
F3 C55 F2 97.2(17) . . ?
F1 C55 F2 98(2) . . ?
F3 C55 S5 122(2) . . ?
F1 C55 S5 116.7(15) . . ?
F2 C55 S5 117.5(13) . . ?
F4 C56 F6 108.3(15) . . ?
F4 C56 F5 105.9(13) . . ?
F6 C56 F5 101.6(18) . . ?
F4 C56 S6 118.3(17) . . ?
F6 C56 S6 109.9(12) . . ?
F5 C56 S6 111.5(11) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C6 2.025(11) . ?
Pt1 C1 2.030(11) . ?
Pt1 S2 2.372(3) . ?
Pt1 S1 2.376(3) . ?
Pt1 Pt2 2.9733(7) . ?
Pt1 Pt3 3.1824(7) . ?
Pt2 C15 1.986(14) . ?
Pt2 C10 1.992(15) . ?
Pt2 S2 2.370(3) . ?
Pt2 S1 2.375(3) . ?
Pt3 C24 2.009(12) . ?
Pt3 C19 2.023(13) . ?
Pt3 S2 2.349(3) . ?
Pt3 S1 2.354(3) . ?
Pt4 C28 2.007(12) . ?
Pt4 C33 2.009(11) . ?
Pt4 S3 2.374(3) . ?
Pt4 S4 2.377(3) . ?
Pt4 Pt5 2.9525(7) . ?
Pt5 C37 2.002(10) . ?
Pt5 C42 2.016(12) . ?
Pt5 S3 2.368(3) . ?
Pt5 S4 2.381(3) . ?
Pt5 Pt6 3.2390(6) . ?
Pt6 C46 2.011(11) . ?
Pt6 C51 2.036(9) . ?
Pt6 S3 2.351(2) . ?
Pt6 S4 2.360(3) . ?
Cl1 Cl2 2.04(5) . ?
Cl3 Cl4 1.36(2) . ?
S5 O2 1.392(11) . ?
S5 O3 1.406(10) . ?
S5 O1 1.411(10) . ?
S5 C55 1.51(3) . ?
S6 O6 1.387(12) . ?
S6 O4 1.448(10) . ?
S6 O5 1.471(11) . ?
S6 C56 1.741(18) . ?
F1 C55 1.45(3) . ?
F2 C55 1.46(2) . ?
F3 C55 1.40(2) . ?
F4 C56 1.26(2) . ?
F5 C56 1.42(2) . ?
F6 C56 1.33(2) . ?
N1 C1 1.323(14) . ?
N1 C2 1.391(14) . ?
N1 C5 1.445(15) . ?
N2 C1 1.333(14) . ?
N2 C3 1.396(16) . ?
N2 C4 1.485(16) . ?
N3 C6 1.338(15) . ?
N3 C7 1.388(14) . ?
N3 C5 1.442(15) . ?
N4 C6 1.331(15) . ?
N4 C8 1.378(17) . ?
N4 C9 1.461(16) . ?
N5 C10 1.32(2) . ?
N5 C12 1.37(2) . ?
N5 C14 1.44(2) . ?
N6 C11 1.37(2) . ?
N6 C10 1.38(2) . ?
N6 C13 1.46(3) . ?
N7 C15 1.349(19) . ?
N7 C16 1.36(2) . ?
N7 C14 1.497(19) . ?
N8 C17 1.347(19) . ?
N8 C15 1.355(16) . ?
N8 C18 1.460(18) . ?
N9 C24 1.333(17) . ?
N9 C25 1.419(18) . ?
N9 C23 1.423(19) . ?
N10 C24 1.360(17) . ?
N10 C26 1.360(19) . ?
N10 C27 1.45(2) . ?
N11 C19 1.329(16) . ?
N11 C20 1.425(18) . ?
N11 C23 1.454(17) . ?
N12 C19 1.366(15) . ?
N12 C21 1.390(17) . ?
N12 C22 1.464(16) . ?
N13 C28 1.325(16) . ?
N13 C29 1.410(17) . ?
N13 C32 1.440(19) . ?
N14 C28 1.349(15) . ?
N14 C30 1.387(17) . ?
N14 C31 1.476(19) . ?
N15 C34 1.365(17) . ?
N15 C33 1.365(16) . ?
N15 C32 1.422(17) . ?
N16 C33 1.334(15) . ?
N16 C35 1.394(18) . ?
N16 C36 1.435(17) . ?
N17 C37 1.377(14) . ?
N17 C38 1.404(15) . ?
N17 C41 1.428(17) . ?
N18 C37 1.336(15) . ?
N18 C39 1.397(15) . ?
N18 C40 1.443(17) . ?
N19 C42 1.357(15) . ?
N19 C43 1.388(17) . ?
N19 C41 1.440(17) . ?
N20 C42 1.347(16) . ?
N20 C44 1.376(17) . ?
N20 C45 1.479(18) . ?
N21 C46 1.345(14) . ?
N21 C47 1.381(14) . ?
N21 C50 1.468(14) . ?
N22 C46 1.347(13) . ?
N22 C48 1.385(15) . ?
N22 C49 1.460(15) . ?
N23 C51 1.335(13) . ?
N23 C52 1.391(13) . ?
N23 C50 1.475(13) . ?
N24 C51 1.324(13) . ?
N24 C53 1.404(14) . ?
N24 C54 1.451(14) . ?
C2 C3 1.308(19) . ?
C2 H2 0.9500 . ?
C3 H3 0.9500 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C7 C8 1.35(2) . ?
C7 H7 0.9500 . ?
C8 H8 0.9500 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C11 C12 1.30(3) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C16 C17 1.30(2) . ?
C16 H16 0.9500 . ?
C17 H17 0.9500 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C20 C21 1.297(19) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C25 C26 1.35(3) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C29 C30 1.27(2) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C34 C35 1.33(2) . ?
C34 H34 0.9500 . ?
C35 H35 0.9500 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C38 C39 1.34(2) . ?
C38 H38 0.9500 . ?
C39 H39 0.9500 . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C41 H41A 0.9900 . ?
C41 H41B 0.9900 . ?
C43 C44 1.35(2) . ?
C43 H43 0.9500 . ?
C44 H44 0.9500 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C47 C48 1.345(17) . ?
C47 H47 0.9500 . ?
C48 H48 0.9500 . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C50 H50A 0.9900 . ?
C50 H50B 0.9900 . ?
C52 C53 1.354(17) . ?
C52 H52 0.9500 . ?
C53 H53 0.9500 . ?
C54 H54A 0.9800 . ?
C54 H54B 0.9800 . ?
C54 H54C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 Pt1 Pt2 C15 -2.1(6) . . . . ?
C1 Pt1 Pt2 C15 109.7(6) . . . . ?
S2 Pt1 Pt2 C15 -72.0(5) . . . . ?
S1 Pt1 Pt2 C15 179.8(5) . . . . ?
Pt3 Pt1 Pt2 C15 -126.0(5) . . . . ?
C6 Pt1 Pt2 C10 -106.8(7) . . . . ?
C1 Pt1 Pt2 C10 5.0(7) . . . . ?
S2 Pt1 Pt2 C10 -176.7(6) . . . . ?
S1 Pt1 Pt2 C10 75.2(6) . . . . ?
Pt3 Pt1 Pt2 C10 129.3(6) . . . . ?
C6 Pt1 Pt2 S2 69.9(4) . . . . ?
C1 Pt1 Pt2 S2 -178.4(4) . . . . ?
S1 Pt1 Pt2 S2 -108.19(13) . . . . ?
Pt3 Pt1 Pt2 S2 -54.02(9) . . . . ?
C6 Pt1 Pt2 S1 178.1(4) . . . . ?
C1 Pt1 Pt2 S1 -70.2(4) . . . . ?
S2 Pt1 Pt2 S1 108.19(13) . . . . ?
Pt3 Pt1 Pt2 S1 54.18(9) . . . . ?
C6 Pt1 Pt3 C24 126.0(7) . . . . ?
C1 Pt1 Pt3 C24 -0.7(7) . . . . ?
S2 Pt1 Pt3 C24 -176.6(5) . . . . ?
S1 Pt1 Pt3 C24 -58.4(5) . . . . ?
Pt2 Pt1 Pt3 C24 -117.6(5) . . . . ?
C6 Pt1 Pt3 C19 6.6(6) . . . . ?
C1 Pt1 Pt3 C19 -120.2(6) . . . . ?
S2 Pt1 Pt3 C19 63.9(4) . . . . ?
S1 Pt1 Pt3 C19 -177.9(4) . . . . ?
Pt2 Pt1 Pt3 C19 122.9(4) . . . . ?
C6 Pt1 Pt3 S2 -57.3(5) . . . . ?
C1 Pt1 Pt3 S2 175.9(4) . . . . ?
S1 Pt1 Pt3 S2 118.19(13) . . . . ?
Pt2 Pt1 Pt3 S2 59.02(9) . . . . ?
C6 Pt1 Pt3 S1 -175.5(5) . . . . ?
C1 Pt1 Pt3 S1 57.7(4) . . . . ?
S2 Pt1 Pt3 S1 -118.19(13) . . . . ?
Pt2 Pt1 Pt3 S1 -59.17(10) . . . . ?
C28 Pt4 Pt5 C37 -3.2(5) . . . . ?
C33 Pt4 Pt5 C37 -107.9(6) . . . . ?
S3 Pt4 Pt5 C37 72.7(4) . . . . ?
S4 Pt4 Pt5 C37 179.6(4) . . . . ?
C28 Pt4 Pt5 C42 104.8(6) . . . . ?
C33 Pt4 Pt5 C42 0.1(6) . . . . ?
S3 Pt4 Pt5 C42 -179.3(4) . . . . ?
S4 Pt4 Pt5 C42 -72.4(4) . . . . ?
C28 Pt4 Pt5 S3 -75.9(4) . . . . ?
C33 Pt4 Pt5 S3 179.4(4) . . . . ?
S4 Pt4 Pt5 S3 106.89(11) . . . . ?
C28 Pt4 Pt5 S4 177.2(4) . . . . ?
C33 Pt4 Pt5 S4 72.5(4) . . . . ?
S3 Pt4 Pt5 S4 -106.89(11) . . . . ?
C28 Pt4 Pt5 Pt6 -129.2(4) . . . . ?
C33 Pt4 Pt5 Pt6 126.1(4) . . . . ?
S3 Pt4 Pt5 Pt6 -53.32(7) . . . . ?
S4 Pt4 Pt5 Pt6 53.57(8) . . . . ?
C37 Pt5 Pt6 C46 11.1(6) . . . . ?
C42 Pt5 Pt6 C46 -122.3(6) . . . . ?
S3 Pt5 Pt6 C46 60.8(4) . . . . ?
S4 Pt5 Pt6 C46 -179.0(4) . . . . ?
Pt4 Pt5 Pt6 C46 120.9(4) . . . . ?
C37 Pt5 Pt6 C51 132.1(6) . . . . ?
C42 Pt5 Pt6 C51 -1.3(6) . . . . ?
S3 Pt5 Pt6 C51 -178.2(4) . . . . ?
S4 Pt5 Pt6 C51 -58.0(4) . . . . ?
Pt4 Pt5 Pt6 C51 -118.1(4) . . . . ?
C37 Pt5 Pt6 S3 -49.6(5) . . . . ?
C42 Pt5 Pt6 S3 176.9(5) . . . . ?
S4 Pt5 Pt6 S3 120.26(12) . . . . ?
Pt4 Pt5 Pt6 S3 60.14(8) . . . . ?
C37 Pt5 Pt6 S4 -169.9(5) . . . . ?
C42 Pt5 Pt6 S4 56.6(5) . . . . ?
S3 Pt5 Pt6 S4 -120.26(12) . . . . ?
Pt4 Pt5 Pt6 S4 -60.12(9) . . . . ?
C24 Pt3 S1 Pt2 -144.0(4) . . . . ?
C19 Pt3 S1 Pt2 102(5) . . . . ?
S2 Pt3 S1 Pt2 35.73(9) . . . . ?
Pt1 Pt3 S1 Pt2 77.50(9) . . . . ?
C24 Pt3 S1 Pt1 138.5(4) . . . . ?
C19 Pt3 S1 Pt1 24(5) . . . . ?
S2 Pt3 S1 Pt1 -41.77(9) . . . . ?
C15 Pt2 S1 Pt3 -86(4) . . . . ?
C10 Pt2 S1 Pt3 152.7(5) . . . . ?
S2 Pt2 S1 Pt3 -35.48(9) . . . . ?
Pt1 Pt2 S1 Pt3 -84.60(8) . . . . ?
C15 Pt2 S1 Pt1 -1(4) . . . . ?
C10 Pt2 S1 Pt1 -122.7(5) . . . . ?
S2 Pt2 S1 Pt1 49.12(8) . . . . ?
C6 Pt1 S1 Pt3 66(6) . . . . ?
C1 Pt1 S1 Pt3 -140.0(3) . . . . ?
S2 Pt1 S1 Pt3 41.42(9) . . . . ?
Pt2 Pt1 S1 Pt3 90.48(8) . . . . ?
C6 Pt1 S1 Pt2 -25(6) . . . . ?
C1 Pt1 S1 Pt2 129.5(3) . . . . ?
S2 Pt1 S1 Pt2 -49.07(8) . . . . ?
Pt3 Pt1 S1 Pt2 -90.48(8) . . . . ?
C24 Pt3 S2 Pt2 -31(6) . . . . ?
C19 Pt3 S2 Pt2 147.9(3) . . . . ?
S1 Pt3 S2 Pt2 -35.82(9) . . . . ?
Pt1 Pt3 S2 Pt2 -77.65(8) . . . . ?
C24 Pt3 S2 Pt1 46(6) . . . . ?
C19 Pt3 S2 Pt1 -134.5(3) . . . . ?
S1 Pt3 S2 Pt1 41.83(9) . . . . ?
C15 Pt2 S2 Pt3 -149.4(4) . . . . ?
C10 Pt2 S2 Pt3 104(3) . . . . ?
S1 Pt2 S2 Pt3 35.58(9) . . . . ?
Pt1 Pt2 S2 Pt3 84.75(8) . . . . ?
C15 Pt2 S2 Pt1 125.8(4) . . . . ?
C10 Pt2 S2 Pt1 19(3) . . . . ?
S1 Pt2 S2 Pt1 -49.17(9) . . . . ?
C6 Pt1 S2 Pt3 140.0(3) . . . . ?
C1 Pt1 S2 Pt3 -67(5) . . . . ?
S1 Pt1 S2 Pt3 -41.52(9) . . . . ?
Pt2 Pt1 S2 Pt3 -90.69(8) . . . . ?
C6 Pt1 S2 Pt2 -129.3(3) . . . . ?
C1 Pt1 S2 Pt2 23(5) . . . . ?
S1 Pt1 S2 Pt2 49.17(9) . . . . ?
Pt3 Pt1 S2 Pt2 90.69(8) . . . . ?
C46 Pt6 S3 Pt5 -136.4(3) . . . . ?
C51 Pt6 S3 Pt5 27(6) . . . . ?
S4 Pt6 S3 Pt5 40.24(8) . . . . ?
C46 Pt6 S3 Pt4 146.5(3) . . . . ?
C51 Pt6 S3 Pt4 -50(6) . . . . ?
S4 Pt6 S3 Pt4 -36.80(9) . . . . ?
Pt5 Pt6 S3 Pt4 -77.04(8) . . . . ?
C37 Pt5 S3 Pt6 145.6(3) . . . . ?
C42 Pt5 S3 Pt6 -76(8) . . . . ?
S4 Pt5 S3 Pt6 -39.93(8) . . . . ?
Pt4 Pt5 S3 Pt6 -89.96(7) . . . . ?
C37 Pt5 S3 Pt4 -124.5(3) . . . . ?
C42 Pt5 S3 Pt4 14(8) . . . . ?
S4 Pt5 S3 Pt4 50.03(8) . . . . ?
Pt6 Pt5 S3 Pt4 89.96(7) . . . . ?
C28 Pt4 S3 Pt6 -152.0(4) . . . . ?
C33 Pt4 S3 Pt6 82(3) . . . . ?
S4 Pt4 S3 Pt6 36.62(8) . . . . ?
Pt5 Pt4 S3 Pt6 86.79(8) . . . . ?
C28 Pt4 S3 Pt5 121.2(4) . . . . ?
C33 Pt4 S3 Pt5 -5(3) . . . . ?
S4 Pt4 S3 Pt5 -50.17(8) . . . . ?
C46 Pt6 S4 Pt4 88(4) . . . . ?
C51 Pt6 S4 Pt4 -143.9(3) . . . . ?
S3 Pt6 S4 Pt4 36.76(8) . . . . ?
Pt5 Pt6 S4 Pt4 76.75(7) . . . . ?
C46 Pt6 S4 Pt5 11(4) . . . . ?
C51 Pt6 S4 Pt5 139.3(3) . . . . ?
S3 Pt6 S4 Pt5 -39.99(8) . . . . ?
C28 Pt4 S4 Pt6 -101(2) . . . . ?
C33 Pt4 S4 Pt6 147.8(4) . . . . ?
S3 Pt4 S4 Pt6 -36.46(8) . . . . ?
Pt5 Pt4 S4 Pt6 -86.32(8) . . . . ?
C28 Pt4 S4 Pt5 -15(2) . . . . ?
C33 Pt4 S4 Pt5 -125.9(4) . . . . ?
S3 Pt4 S4 Pt5 49.86(8) . . . . ?
C37 Pt5 S4 Pt6 87(2) . . . . ?
C42 Pt5 S4 Pt6 -141.6(3) . . . . ?
S3 Pt5 S4 Pt6 39.78(8) . . . . ?
Pt4 Pt5 S4 Pt6 89.82(8) . . . . ?
C37 Pt5 S4 Pt4 -3(2) . . . . ?
C42 Pt5 S4 Pt4 128.5(3) . . . . ?
S3 Pt5 S4 Pt4 -50.04(8) . . . . ?
Pt6 Pt5 S4 Pt4 -89.82(8) . . . . ?
C2 N1 C1 N2 0.2(12) . . . . ?
C5 N1 C1 N2 -174.9(9) . . . . ?
C2 N1 C1 Pt1 168.8(7) . . . . ?
C5 N1 C1 Pt1 -6.3(14) . . . . ?
C3 N2 C1 N1 -0.8(12) . . . . ?
C4 N2 C1 N1 -179.8(10) . . . . ?
C3 N2 C1 Pt1 -168.4(8) . . . . ?
C4 N2 C1 Pt1 12.7(16) . . . . ?
C6 Pt1 C1 N1 -34.7(9) . . . . ?
S2 Pt1 C1 N1 173(5) . . . . ?
S1 Pt1 C1 N1 146.9(8) . . . . ?
Pt2 Pt1 C1 N1 -165.1(7) . . . . ?
Pt3 Pt1 C1 N1 107.9(8) . . . . ?
C6 Pt1 C1 N2 131.3(10) . . . . ?
S2 Pt1 C1 N2 -22(6) . . . . ?
S1 Pt1 C1 N2 -47.1(10) . . . . ?
Pt2 Pt1 C1 N2 0.8(11) . . . . ?
Pt3 Pt1 C1 N2 -86.2(10) . . . . ?
C1 N1 C2 C3 0.5(13) . . . . ?
C5 N1 C2 C3 175.2(11) . . . . ?
N1 C2 C3 N2 -1.0(13) . . . . ?
C1 N2 C3 C2 1.2(13) . . . . ?
C4 N2 C3 C2 -179.8(11) . . . . ?
C6 N3 C5 N1 -53.6(14) . . . . ?
C7 N3 C5 N1 117.1(12) . . . . ?
C1 N1 C5 N3 57.8(13) . . . . ?
C2 N1 C5 N3 -116.3(11) . . . . ?
C8 N4 C6 N3 1.0(15) . . . . ?
C9 N4 C6 N3 -178.1(13) . . . . ?
C8 N4 C6 Pt1 173.1(10) . . . . ?
C9 N4 C6 Pt1 -6(2) . . . . ?
C7 N3 C6 N4 0.1(14) . . . . ?
C5 N3 C6 N4 172.2(10) . . . . ?
C7 N3 C6 Pt1 -172.8(9) . . . . ?
C5 N3 C6 Pt1 -0.7(15) . . . . ?
C1 Pt1 C6 N4 -132.8(12) . . . . ?
S2 Pt1 C6 N4 45.7(12) . . . . ?
S1 Pt1 C6 N4 22(6) . . . . ?
Pt2 Pt1 C6 N4 -2.0(14) . . . . ?
Pt3 Pt1 C6 N4 84.4(12) . . . . ?
C1 Pt1 C6 N3 38.1(10) . . . . ?
S2 Pt1 C6 N3 -143.4(9) . . . . ?
S1 Pt1 C6 N3 -167(5) . . . . ?
Pt2 Pt1 C6 N3 168.9(7) . . . . ?
Pt3 Pt1 C6 N3 -104.7(9) . . . . ?
C6 N3 C7 C8 -1.2(15) . . . . ?
C5 N3 C7 C8 -172.7(12) . . . . ?
N3 C7 C8 N4 1.8(16) . . . . ?
C6 N4 C8 C7 -1.8(17) . . . . ?
C9 N4 C8 C7 177.3(14) . . . . ?
C12 N5 C10 N6 -0.8(19) . . . . ?
C14 N5 C10 N6 -179.2(14) . . . . ?
C12 N5 C10 Pt2 178.6(13) . . . . ?
C14 N5 C10 Pt2 0(2) . . . . ?
C11 N6 C10 N5 -0.9(19) . . . . ?
C13 N6 C10 N5 177.4(17) . . . . ?
C11 N6 C10 Pt2 179.8(13) . . . . ?
C13 N6 C10 Pt2 -2(3) . . . . ?
C15 Pt2 C10 N5 -39.3(13) . . . . ?
S2 Pt2 C10 N5 68(4) . . . . ?
S1 Pt2 C10 N5 135.2(12) . . . . ?
Pt1 Pt2 C10 N5 85.5(13) . . . . ?
C15 Pt2 C10 N6 139.9(15) . . . . ?
S2 Pt2 C10 N6 -113(3) . . . . ?
S1 Pt2 C10 N6 -45.6(15) . . . . ?
Pt1 Pt2 C10 N6 -95.3(15) . . . . ?
C10 N6 C11 C12 2(2) . . . . ?
C13 N6 C11 C12 -176.0(19) . . . . ?
N6 C11 C12 N5 -3(3) . . . . ?
C10 N5 C12 C11 2(2) . . . . ?
C14 N5 C12 C11 -179.3(18) . . . . ?
C10 N5 C14 N7 51(2) . . . . ?
C12 N5 C14 N7 -127.2(18) . . . . ?
C15 N7 C14 N5 -50(2) . . . . ?
C16 N7 C14 N5 127(2) . . . . ?
C16 N7 C15 N8 3.7(19) . . . . ?
C14 N7 C15 N8 -179.4(14) . . . . ?
C16 N7 C15 Pt2 -179.5(13) . . . . ?
C14 N7 C15 Pt2 -3(2) . . . . ?
C17 N8 C15 N7 -1.2(17) . . . . ?
C18 N8 C15 N7 -178.7(13) . . . . ?
C17 N8 C15 Pt2 -177.4(13) . . . . ?
C18 N8 C15 Pt2 5(2) . . . . ?
C10 Pt2 C15 N7 39.3(13) . . . . ?
S2 Pt2 C15 N7 -132.3(12) . . . . ?
S1 Pt2 C15 N7 -83(4) . . . . ?
Pt1 Pt2 C15 N7 -83.9(13) . . . . ?
C10 Pt2 C15 N8 -145.1(16) . . . . ?
S2 Pt2 C15 N8 43.3(15) . . . . ?
S1 Pt2 C15 N8 93(4) . . . . ?
Pt1 Pt2 C15 N8 91.7(15) . . . . ?
C15 N7 C16 C17 -5(2) . . . . ?
C14 N7 C16 C17 178.4(18) . . . . ?
N7 C16 C17 N8 4(2) . . . . ?
C15 N8 C17 C16 -2(2) . . . . ?
C18 N8 C17 C16 175.7(16) . . . . ?
C20 N11 C19 N12 -1.7(13) . . . . ?
C23 N11 C19 N12 -175.2(11) . . . . ?
C20 N11 C19 Pt3 175.7(8) . . . . ?
C23 N11 C19 Pt3 2.1(16) . . . . ?
C21 N12 C19 N11 2.9(13) . . . . ?
C22 N12 C19 N11 178.6(10) . . . . ?
C21 N12 C19 Pt3 -174.0(9) . . . . ?
C22 N12 C19 Pt3 1.7(18) . . . . ?
C24 Pt3 C19 N11 -39.4(10) . . . . ?
S2 Pt3 C19 N11 140.6(9) . . . . ?
S1 Pt3 C19 N11 75(5) . . . . ?
Pt1 Pt3 C19 N11 98.1(9) . . . . ?
C24 Pt3 C19 N12 137.1(12) . . . . ?
S2 Pt3 C19 N12 -42.9(11) . . . . ?
S1 Pt3 C19 N12 -108(5) . . . . ?
Pt1 Pt3 C19 N12 -85.4(11) . . . . ?
C19 N11 C20 C21 -0.2(15) . . . . ?
C23 N11 C20 C21 172.9(12) . . . . ?
N11 C20 C21 N12 2.1(15) . . . . ?
C19 N12 C21 C20 -3.2(15) . . . . ?
C22 N12 C21 C20 -179.0(11) . . . . ?
C24 N9 C23 N11 -56.3(15) . . . . ?
C25 N9 C23 N11 119.1(13) . . . . ?
C19 N11 C23 N9 52.7(15) . . . . ?
C20 N11 C23 N9 -119.8(13) . . . . ?
C25 N9 C24 N10 -0.1(13) . . . . ?
C23 N9 C24 N10 176.1(11) . . . . ?
C25 N9 C24 Pt3 -171.9(8) . . . . ?
C23 N9 C24 Pt3 4.2(16) . . . . ?
C26 N10 C24 N9 1.4(15) . . . . ?
C27 N10 C24 N9 -179.8(12) . . . . ?
C26 N10 C24 Pt3 172.2(10) . . . . ?
C27 N10 C24 Pt3 -9(2) . . . . ?
C19 Pt3 C24 N9 36.8(10) . . . . ?
S2 Pt3 C24 N9 -144(5) . . . . ?
S1 Pt3 C24 N9 -139.6(9) . . . . ?
Pt1 Pt3 C24 N9 -99.9(10) . . . . ?
C19 Pt3 C24 N10 -132.8(12) . . . . ?
S2 Pt3 C24 N10 46(6) . . . . ?
S1 Pt3 C24 N10 50.9(11) . . . . ?
Pt1 Pt3 C24 N10 90.5(11) . . . . ?
C24 N9 C25 C26 -1.2(15) . . . . ?
C23 N9 C25 C26 -177.0(13) . . . . ?
N9 C25 C26 N10 2.0(16) . . . . ?
C24 N10 C26 C25 -2.1(17) . . . . ?
C27 N10 C26 C25 178.9(13) . . . . ?
C29 N13 C28 N14 0.8(14) . . . . ?
C32 N13 C28 N14 179.2(11) . . . . ?
C29 N13 C28 Pt4 177.2(9) . . . . ?
C32 N13 C28 Pt4 -4.5(16) . . . . ?
C30 N14 C28 N13 0.6(13) . . . . ?
C31 N14 C28 N13 176.7(12) . . . . ?
C30 N14 C28 Pt4 -175.1(10) . . . . ?
C31 N14 C28 Pt4 1.0(19) . . . . ?
C33 Pt4 C28 N13 40.4(10) . . . . ?
S3 Pt4 C28 N13 -134.8(9) . . . . ?
S4 Pt4 C28 N13 -71(2) . . . . ?
Pt5 Pt4 C28 N13 -84.9(9) . . . . ?
C33 Pt4 C28 N14 -144.4(12) . . . . ?
S3 Pt4 C28 N14 40.4(11) . . . . ?
S4 Pt4 C28 N14 104(2) . . . . ?
Pt5 Pt4 C28 N14 90.3(12) . . . . ?
C28 N13 C29 C30 -2.0(17) . . . . ?
C32 N13 C29 C30 179.8(14) . . . . ?
N13 C29 C30 N14 2.3(18) . . . . ?
C28 N14 C30 C29 -2.0(17) . . . . ?
C31 N14 C30 C29 -178.1(14) . . . . ?
C34 N15 C32 N13 -125.1(17) . . . . ?
C33 N15 C32 N13 55.3(17) . . . . ?
C28 N13 C32 N15 -51.4(17) . . . . ?
C29 N13 C32 N15 126.7(14) . . . . ?
C35 N16 C33 N15 0.1(16) . . . . ?
C36 N16 C33 N15 -179.7(13) . . . . ?
C35 N16 C33 Pt4 -177.3(13) . . . . ?
C36 N16 C33 Pt4 3(2) . . . . ?
C34 N15 C33 N16 -1.1(17) . . . . ?
C32 N15 C33 N16 178.5(13) . . . . ?
C34 N15 C33 Pt4 176.6(12) . . . . ?
C32 N15 C33 Pt4 -3.8(18) . . . . ?
C28 Pt4 C33 N16 140.8(14) . . . . ?
S3 Pt4 C33 N16 -93(4) . . . . ?
S4 Pt4 C33 N16 -48.1(13) . . . . ?
Pt5 Pt4 C33 N16 -97.2(13) . . . . ?
C28 Pt4 C33 N15 -36.2(11) . . . . ?
S3 Pt4 C33 N15 90(4) . . . . ?
S4 Pt4 C33 N15 134.9(10) . . . . ?
Pt5 Pt4 C33 N15 85.8(11) . . . . ?
C33 N15 C34 C35 2(2) . . . . ?
C32 N15 C34 C35 -177.9(17) . . . . ?
N15 C34 C35 N16 -2(2) . . . . ?
C33 N16 C35 C34 1(2) . . . . ?
C36 N16 C35 C34 -179.2(16) . . . . ?
C39 N18 C37 N17 -1.6(14) . . . . ?
C40 N18 C37 N17 177.1(12) . . . . ?
C39 N18 C37 Pt5 169.7(10) . . . . ?
C40 N18 C37 Pt5 -11.6(19) . . . . ?
C38 N17 C37 N18 2.2(13) . . . . ?
C41 N17 C37 N18 171.3(11) . . . . ?
C38 N17 C37 Pt5 -170.3(8) . . . . ?
C41 N17 C37 Pt5 -1.1(15) . . . . ?
C42 Pt5 C37 N18 -131.0(12) . . . . ?
S3 Pt5 C37 N18 47.4(11) . . . . ?
S4 Pt5 C37 N18 1(3) . . . . ?
Pt4 Pt5 C37 N18 -1.5(13) . . . . ?
Pt6 Pt5 C37 N18 81.2(12) . . . . ?
C42 Pt5 C37 N17 39.2(9) . . . . ?
S3 Pt5 C37 N17 -142.4(9) . . . . ?
S4 Pt5 C37 N17 171.3(18) . . . . ?
Pt4 Pt5 C37 N17 168.7(7) . . . . ?
Pt6 Pt5 C37 N17 -108.6(9) . . . . ?
C37 N17 C38 C39 -2.0(15) . . . . ?
C41 N17 C38 C39 -170.3(13) . . . . ?
N17 C38 C39 N18 1.0(16) . . . . ?
C37 N18 C39 C38 0.4(16) . . . . ?
C40 N18 C39 C38 -178.4(13) . . . . ?
C37 N17 C41 N19 -51.8(15) . . . . ?
C38 N17 C41 N19 115.0(13) . . . . ?
C42 N19 C41 N17 53.5(14) . . . . ?
C43 N19 C41 N17 -115.4(13) . . . . ?
C44 N20 C42 N19 1.4(13) . . . . ?
C45 N20 C42 N19 -179.9(12) . . . . ?
C44 N20 C42 Pt5 -167.8(10) . . . . ?
C45 N20 C42 Pt5 10.9(19) . . . . ?
C43 N19 C42 N20 -1.9(13) . . . . ?
C41 N19 C42 N20 -172.2(10) . . . . ?
C43 N19 C42 Pt5 168.8(8) . . . . ?
C41 N19 C42 Pt5 -1.6(15) . . . . ?
C37 Pt5 C42 N20 129.8(11) . . . . ?
S3 Pt5 C42 N20 -8(8) . . . . ?
S4 Pt5 C42 N20 -44.6(11) . . . . ?
Pt4 Pt5 C42 N20 4.7(13) . . . . ?
Pt6 Pt5 C42 N20 -82.7(11) . . . . ?
C37 Pt5 C42 N19 -37.9(9) . . . . ?
S3 Pt5 C42 N19 -176(100) . . . . ?
S4 Pt5 C42 N19 147.7(8) . . . . ?
Pt4 Pt5 C42 N19 -163.0(7) . . . . ?
Pt6 Pt5 C42 N19 109.6(8) . . . . ?
C42 N19 C43 C44 1.6(15) . . . . ?
C41 N19 C43 C44 171.6(12) . . . . ?
N19 C43 C44 N20 -0.7(16) . . . . ?
C42 N20 C44 C43 -0.4(16) . . . . ?
C45 N20 C44 C43 -179.2(13) . . . . ?
C47 N21 C46 N22 -1.4(11) . . . . ?
C50 N21 C46 N22 -175.4(9) . . . . ?
C47 N21 C46 Pt6 172.7(7) . . . . ?
C50 N21 C46 Pt6 -1.3(13) . . . . ?
C48 N22 C46 N21 1.3(11) . . . . ?
C49 N22 C46 N21 176.1(10) . . . . ?
C48 N22 C46 Pt6 -171.8(8) . . . . ?
C49 N22 C46 Pt6 3.0(16) . . . . ?
C51 Pt6 C46 N21 -40.1(8) . . . . ?
S3 Pt6 C46 N21 139.1(8) . . . . ?
S4 Pt6 C46 N21 89(4) . . . . ?
Pt5 Pt6 C46 N21 99.0(8) . . . . ?
C51 Pt6 C46 N22 132.0(10) . . . . ?
S3 Pt6 C46 N22 -48.8(10) . . . . ?
S4 Pt6 C46 N22 -99(4) . . . . ?
Pt5 Pt6 C46 N22 -88.9(10) . . . . ?
C46 N21 C47 C48 0.9(13) . . . . ?
C50 N21 C47 C48 174.5(10) . . . . ?
N21 C47 C48 N22 -0.1(12) . . . . ?
C46 N22 C48 C47 -0.8(12) . . . . ?
C49 N22 C48 C47 -175.7(10) . . . . ?
C46 N21 C50 N23 55.9(12) . . . . ?
C47 N21 C50 N23 -117.2(11) . . . . ?
C51 N23 C50 N21 -56.4(13) . . . . ?
C52 N23 C50 N21 115.4(11) . . . . ?
C53 N24 C51 N23 0.7(12) . . . . ?
C54 N24 C51 N23 -176.7(10) . . . . ?
C53 N24 C51 Pt6 171.0(9) . . . . ?
C54 N24 C51 Pt6 -6.4(17) . . . . ?
C52 N23 C51 N24 0.6(12) . . . . ?
C50 N23 C51 N24 173.4(9) . . . . ?
C52 N23 C51 Pt6 -171.0(8) . . . . ?
C50 N23 C51 Pt6 1.8(14) . . . . ?
C46 Pt6 C51 N24 -129.7(11) . . . . ?
S3 Pt6 C51 N24 67(6) . . . . ?
S4 Pt6 C51 N24 53.7(10) . . . . ?
Pt5 Pt6 C51 N24 92.6(10) . . . . ?
C46 Pt6 C51 N23 39.5(8) . . . . ?
S3 Pt6 C51 N23 -124(5) . . . . ?
S4 Pt6 C51 N23 -137.2(8) . . . . ?
Pt5 Pt6 C51 N23 -98.2(8) . . . . ?
C51 N23 C52 C53 -1.6(13) . . . . ?
C50 N23 C52 C53 -174.1(10) . . . . ?
N23 C52 C53 N24 1.9(13) . . . . ?
C51 N24 C53 C52 -1.7(14) . . . . ?
C54 N24 C53 C52 175.8(11) . . . . ?
O2 S5 C55 F3 -178.7(14) . . . . ?
O3 S5 C55 F3 -57.2(16) . . . . ?
O1 S5 C55 F3 61.0(16) . . . . ?
O2 S5 C55 F1 56.9(16) . . . . ?
O3 S5 C55 F1 178.4(14) . . . . ?
O1 S5 C55 F1 -63.4(16) . . . . ?
O2 S5 C55 F2 -59.0(17) . . . . ?
O3 S5 C55 F2 62.5(17) . . . . ?
O1 S5 C55 F2 -179.3(15) . . . . ?
O6 S6 C56 F4 175.1(13) . . . . ?
O4 S6 C56 F4 54.3(14) . . . . ?
O5 S6 C56 F4 -60.9(15) . . . . ?
O6 S6 C56 F6 50.0(18) . . . . ?
O4 S6 C56 F6 -70.8(17) . . . . ?
O5 S6 C56 F6 174.1(15) . . . . ?
O6 S6 C56 F5 -61.8(14) . . . . ?
O4 S6 C56 F5 177.4(12) . . . . ?
O5 S6 C56 F5 62.2(15) . . . . ?
