#------------------------------------------------------------------------------
#$Date: 2020-07-06 05:54:46 +0300 (Mon, 06 Jul 2020) $
#$Revision: 253861 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/43/7704373.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7704373
loop_
_publ_author_name
'Han, Li-Jing'
'Wu, Xiu-Xin'
'Ma, Zheng-Gen'
'Li, Yi'
'Wei, Qiao-Hua'
_publ_section_title
;
 Novel luminescent homo/heterometallic platinum(ii) alkynyl complexes
 based on Y-shaped pyridyl diphosphines.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              8347
_journal_page_last               8353
_journal_paper_doi               10.1039/d0dt01173h
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C179 H140 Ag4 Cl2 N2 P4 Pt4'
_chemical_formula_weight         3725.55
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2020-03-13 deposited with the CCDC.	2020-05-08 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 91.31(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   18.249(4)
_cell_length_b                   14.605(3)
_cell_length_c                   27.333(6)
_cell_measurement_reflns_used    4412
_cell_measurement_temperature    77(2)
_cell_measurement_theta_max      26.1
_cell_measurement_theta_min      2.6
_cell_volume                     7283(3)
_computing_cell_refinement
'HKL2000 Scalepack (Otwinowski & Minor, 1997)'
_computing_data_collection       'MarCCD 165 detector'
_computing_data_reduction
'HKL2000 Scalepack (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'shelxs-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      77(2)
_diffrn_measured_fraction_theta_full 0.962
_diffrn_measured_fraction_theta_max 0.962
_diffrn_measurement_device       'MarCCD 165 detector'
_diffrn_measurement_method       oscillation
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.72000
_diffrn_reflns_av_R_equivalents  0.0567
_diffrn_reflns_av_sigmaI/netI    0.0517
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            33807
_diffrn_reflns_theta_full        29.36
_diffrn_reflns_theta_max         29.36
_diffrn_reflns_theta_min         1.81
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    4.488
_exptl_absorpt_correction_T_max  0.6624
_exptl_absorpt_correction_T_min  0.4672
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'HKL2000 Scalepack (Otwinowski & Minor, 1997)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.699
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3644
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.728
_refine_diff_density_min         -4.426
_refine_diff_density_rms         0.466
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.143
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     894
_refine_ls_number_reflns         18533
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.143
_refine_ls_R_factor_all          0.0494
_refine_ls_R_factor_gt           0.0484
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0896P)²+14.5992P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1449
_refine_ls_wR_factor_ref         0.1451
_reflns_number_gt                18442
_reflns_number_total             18533
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            d0dt01173h2.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7704372--7704375.cif.
;
_cod_original_sg_symbol_H-M      'P2(1)/c  '
_cod_database_code               7704373
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.770797(18) 0.94793(4) 0.139200(12) 0.03990(11) Uani 1 1 d . . .
Ag2 Ag 0.756102(16) 0.83260(2) 0.255841(12) 0.02455(8) Uani 1 1 d . . .
Pt1 Pt 0.629299(7) 0.886348(10) 0.189191(5) 0.01845(6) Uani 1 1 d . . .
Pt2 Pt 0.857355(7) 0.989835(10) 0.231391(5) 0.01697(6) Uani 1 1 d . . .
P1 P 0.82581(5) 1.08063(7) 0.29604(3) 0.01723(18) Uani 1 1 d . . .
P2 P 0.56116(5) 1.01272(7) 0.20934(4) 0.01801(18) Uani 1 1 d . . .
C1 C 0.6976(2) 0.7808(3) 0.17740(15) 0.0217(7) Uani 1 1 d . . .
C2 C 0.7468(2) 0.7249(3) 0.17463(15) 0.0240(8) Uani 1 1 d . . .
C3 C 0.8017(2) 0.6558(3) 0.16941(15) 0.0230(8) Uani 1 1 d . . .
C4 C 0.8219(3) 0.6251(4) 0.12341(18) 0.0371(11) Uani 1 1 d . . .
H4 H 0.8004 0.6522 0.0949 0.044 Uiso 1 1 calc R . .
C5 C 0.8375(2) 0.6180(3) 0.21034(16) 0.0246(8) Uani 1 1 d . . .
H5 H 0.8264 0.6396 0.2421 0.029 Uiso 1 1 calc R . .
C6 C 0.8728(3) 0.5559(5) 0.11855(18) 0.0436(14) Uani 1 1 d . . .
H6 H 0.8851 0.5357 0.0867 0.052 Uiso 1 1 calc R . .
C7 C 0.8891(2) 0.5492(3) 0.20492(16) 0.0251(8) Uani 1 1 d . . .
H7 H 0.9131 0.5248 0.2332 0.030 Uiso 1 1 calc R . .
C8 C 0.9066(3) 0.5150(3) 0.15931(19) 0.0302(9) Uani 1 1 d . . .
C9 C 0.9582(3) 0.4348(4) 0.1540(2) 0.0411(12) Uani 1 1 d . . .
H9A H 0.9933 0.4340 0.1816 0.062 Uiso 1 1 d R . .
H9B H 0.9847 0.4409 0.1234 0.062 Uiso 1 1 d R . .
H9C H 0.9300 0.3777 0.1535 0.062 Uiso 1 1 d R . .
C11 C 0.8841(2) 0.9197(3) 0.17063(15) 0.0212(7) Uani 1 1 d . . .
C12 C 0.8969(2) 0.8803(3) 0.13250(16) 0.0243(8) Uani 1 1 d . . .
C13 C 0.9213(2) 0.8322(3) 0.08980(15) 0.0256(8) Uani 1 1 d . . .
C14 C 0.8736(3) 0.8084(4) 0.05153(17) 0.0330(10) Uani 1 1 d . . .
H14 H 0.8228 0.8217 0.0536 0.040 Uiso 1 1 calc R . .
C15 C 0.9962(3) 0.8111(4) 0.08576(16) 0.0300(9) Uani 1 1 d . . .
H15 H 1.0295 0.8252 0.1119 0.036 Uiso 1 1 calc R . .
C16 C 0.9001(3) 0.7649(4) 0.01001(19) 0.0408(12) Uani 1 1 d . . .
H16 H 0.8667 0.7476 -0.0155 0.049 Uiso 1 1 calc R . .
C17 C 1.0216(3) 0.7696(4) 0.04363(17) 0.0351(10) Uani 1 1 d . . .
H17 H 1.0724 0.7569 0.0411 0.042 Uiso 1 1 calc R . .
C18 C 0.9741(3) 0.7464(4) 0.00503(19) 0.0394(12) Uani 1 1 d . . .
C19 C 1.0033(4) 0.7020(5) -0.0407(2) 0.0489(15) Uani 1 1 d . . .
H19A H 1.0491 0.7322 -0.0498 0.073 Uiso 1 1 d R . .
H19B H 0.9671 0.7083 -0.0676 0.073 Uiso 1 1 d R . .
H19C H 1.0128 0.6370 -0.0345 0.073 Uiso 1 1 d R . .
C21 C 0.6488(2) 0.9310(3) 0.12114(15) 0.0214(7) Uani 1 1 d . . .
C22 C 0.6698(2) 0.9582(3) 0.08154(15) 0.0226(7) Uani 1 1 d . . .
C23 C 0.6779(3) 0.9902(3) 0.03205(16) 0.0236(8) Uani 1 1 d . . .
C24 C 0.6161(3) 1.0047(4) 0.00250(19) 0.0355(11) Uani 1 1 d . . .
H24 H 0.5688 0.9932 0.0150 0.043 Uiso 1 1 calc R . .
C25 C 0.7462(3) 1.0076(3) 0.01288(19) 0.0320(10) Uani 1 1 d . . .
H25 H 0.7894 0.9977 0.0323 0.038 Uiso 1 1 calc R . .
C26 C 0.6229(4) 1.0358(5) -0.0447(2) 0.0475(14) Uani 1 1 d . . .
H26 H 0.5800 1.0450 -0.0644 0.057 Uiso 1 1 calc R . .
C27 C 0.7514(3) 1.0398(4) -0.03507(19) 0.0386(11) Uani 1 1 d . . .
H27 H 0.7984 1.0523 -0.0478 0.046 Uiso 1 1 calc R . .
C28 C 0.6906(4) 1.0538(4) -0.06404(18) 0.0398(12) Uani 1 1 d . . .
C29 C 0.6989(6) 1.0872(5) -0.1164(2) 0.065(2) Uani 1 1 d . . .
H29A H 0.6949 1.1541 -0.1173 0.097 Uiso 1 1 d R . .
H29B H 0.6603 1.0603 -0.1373 0.097 Uiso 1 1 d R . .
H29C H 0.7470 1.0687 -0.1283 0.097 Uiso 1 1 d R . .
C31 C 0.8742(2) 0.8778(3) 0.27274(14) 0.0198(7) Uani 1 1 d . . .
C32 C 0.8804(2) 0.8091(3) 0.29815(16) 0.0241(8) Uani 1 1 d . . .
C33 C 0.8982(2) 0.7345(3) 0.33045(16) 0.0245(8) Uani 1 1 d . . .
C34 C 0.8467(3) 0.7019(4) 0.3632(2) 0.0344(10) Uani 1 1 d . . .
H34 H 0.7984 0.7260 0.3622 0.041 Uiso 1 1 calc R . .
C35 C 0.9683(3) 0.6956(3) 0.33100(17) 0.0294(9) Uani 1 1 d . . .
H35 H 1.0036 0.7152 0.3082 0.035 Uiso 1 1 calc R . .
C36 C 0.8653(3) 0.6349(4) 0.3970(2) 0.0412(12) Uani 1 1 d . . .
H36 H 0.8294 0.6137 0.4190 0.049 Uiso 1 1 calc R . .
C37 C 0.9861(3) 0.6282(4) 0.3650(2) 0.0362(11) Uani 1 1 d . . .
H37 H 1.0336 0.6017 0.3650 0.043 Uiso 1 1 calc R . .
C38 C 0.9358(3) 0.5980(4) 0.3995(2) 0.0431(13) Uani 1 1 d . . .
C39 C 0.9593(4) 0.5333(6) 0.4397(3) 0.066(2) Uani 1 1 d . . .
H39A H 0.9490 0.5607 0.4715 0.099 Uiso 1 1 d R . .
H39B H 1.0120 0.5213 0.4376 0.099 Uiso 1 1 d R . .
H39C H 0.9322 0.4756 0.4361 0.099 Uiso 1 1 d R . .
C41 C 0.8323(2) 1.0960(3) 0.18800(14) 0.0203(7) Uani 1 1 d . . .
C42 C 0.8121(2) 1.1567(3) 0.16074(15) 0.0242(8) Uani 1 1 d . . .
C43 C 0.7891(2) 1.2310(3) 0.12944(16) 0.0256(8) Uani 1 1 d . . .
C44 C 0.7711(4) 1.3153(4) 0.1497(2) 0.0397(12) Uani 1 1 d . . .
H44 H 0.7738 1.3239 0.1841 0.048 Uiso 1 1 calc R . .
C45 C 0.7843(4) 1.2207(4) 0.0789(2) 0.0414(12) Uani 1 1 d . . .
H45 H 0.7967 1.1637 0.0646 0.050 Uiso 1 1 calc R . .
C46 C 0.7489(5) 1.3869(4) 0.1191(3) 0.0561(19) Uani 1 1 d . . .
H46 H 0.7370 1.4444 0.1330 0.067 Uiso 1 1 calc R . .
C47 C 0.7615(4) 1.2928(4) 0.0492(2) 0.0438(13) Uani 1 1 d . . .
H47 H 0.7582 1.2840 0.0148 0.053 Uiso 1 1 calc R . .
C48 C 0.7438(4) 1.3757(4) 0.0682(2) 0.0451(14) Uani 1 1 d . . .
C49 C 0.7202(6) 1.4531(5) 0.0353(3) 0.068(2) Uani 1 1 d . . .
H49A H 0.7587 1.4998 0.0349 0.103 Uiso 1 1 d R . .
H49B H 0.6750 1.4802 0.0475 0.103 Uiso 1 1 d R . .
H49C H 0.7114 1.4298 0.0021 0.103 Uiso 1 1 d R . .
C51 C 0.6244(2) 0.8436(3) 0.25926(15) 0.0222(7) Uani 1 1 d . . .
C52 C 0.6318(2) 0.8233(3) 0.30216(16) 0.0241(8) Uani 1 1 d . . .
C53 C 0.6367(2) 0.8090(3) 0.35415(15) 0.0233(8) Uani 1 1 d . . .
C54 C 0.6255(3) 0.8824(3) 0.38650(18) 0.0285(9) Uani 1 1 d . . .
H54 H 0.6118 0.9407 0.3738 0.034 Uiso 1 1 calc R . .
C55 C 0.6560(3) 0.7242(3) 0.37432(16) 0.0266(8) Uani 1 1 d . . .
H55 H 0.6627 0.6730 0.3534 0.032 Uiso 1 1 calc R . .
C56 C 0.6342(3) 0.8709(3) 0.43637(17) 0.0293(9) Uani 1 1 d . . .
H56 H 0.6249 0.9209 0.4576 0.035 Uiso 1 1 calc R . .
C57 C 0.6657(3) 0.7139(3) 0.42454(16) 0.0276(8) Uani 1 1 d . . .
H57 H 0.6790 0.6557 0.4375 0.033 Uiso 1 1 calc R . .
C58 C 0.6563(2) 0.7873(3) 0.45615(16) 0.0263(8) Uani 1 1 d . . .
C59 C 0.6703(3) 0.7773(4) 0.51042(17) 0.0341(10) Uani 1 1 d . . .
H59A H 0.6641 0.7131 0.5198 0.051 Uiso 1 1 d R . .
H59B H 0.6354 0.8154 0.5281 0.051 Uiso 1 1 d R . .
H59C H 0.7204 0.7970 0.5186 0.051 Uiso 1 1 d R . .
C01 C 0.4318(6) -0.0026(8) 0.3911(5) 0.042(3) Uani 0.50 1 d P . .
H01A H 0.4704 -0.0183 0.3677 0.050 Uiso 0.50 1 calc PR . .
H01B H 0.3996 -0.0568 0.3943 0.050 Uiso 0.50 1 calc PR . .
C101 C 0.8464(2) 1.0409(3) 0.35811(14) 0.0206(7) Uani 1 1 d . . .
C102 C 0.8077(2) 0.9649(3) 0.37510(16) 0.0261(8) Uani 1 1 d . . .
H102 H 0.7718 0.9363 0.3546 0.031 Uiso 1 1 calc R . .
C103 C 0.8217(3) 0.9314(4) 0.42172(17) 0.0315(9) Uani 1 1 d . . .
H103 H 0.7952 0.8800 0.4331 0.038 Uiso 1 1 calc R . .
C104 C 0.8736(3) 0.9721(4) 0.45176(18) 0.0407(12) Uani 1 1 d . . .
H104 H 0.8827 0.9489 0.4838 0.049 Uiso 1 1 calc R . .
C105 C 0.9124(4) 1.0466(4) 0.4355(2) 0.0475(15) Uani 1 1 d . . .
H105 H 0.9487 1.0740 0.4562 0.057 Uiso 1 1 calc R . .
C106 C 0.8986(3) 1.0820(4) 0.38844(18) 0.0350(10) Uani 1 1 d . . .
H106 H 0.9249 1.1339 0.3774 0.042 Uiso 1 1 calc R . .
C111 C 0.8672(2) 1.1931(3) 0.29383(14) 0.0200(7) Uani 1 1 d . . .
C112 C 0.9431(2) 1.1958(3) 0.28794(15) 0.0234(8) Uani 1 1 d . . .
H112 H 0.9696 1.1404 0.2844 0.028 Uiso 1 1 calc R . .
C113 C 0.9797(2) 1.2790(3) 0.28728(16) 0.0269(8) Uani 1 1 d . . .
H113 H 1.0314 1.2805 0.2838 0.032 Uiso 1 1 calc R . .
C114 C 0.9406(2) 1.3599(3) 0.29174(16) 0.0270(8) Uani 1 1 d . . .
H114 H 0.9656 1.4169 0.2915 0.032 Uiso 1 1 calc R . .
C115 C 0.8653(3) 1.3581(3) 0.29654(18) 0.0295(9) Uani 1 1 d . . .
H115 H 0.8387 1.4137 0.2991 0.035 Uiso 1 1 calc R . .
C116 C 0.8285(2) 1.2743(3) 0.29758(17) 0.0258(8) Uani 1 1 d . . .
H116 H 0.7768 1.2730 0.3009 0.031 Uiso 1 1 calc R . .
C121 C 0.5542(2) 1.1038(3) 0.16440(15) 0.0209(7) Uani 1 1 d . . .
C122 C 0.5768(5) 1.1920(5) 0.1747(2) 0.063(2) Uani 1 1 d . . .
H122 H 0.5992 1.2055 0.2056 0.075 Uiso 1 1 calc R . .
C123 C 0.5670(5) 1.2620(5) 0.1401(3) 0.072(3) Uani 1 1 d . . .
H123 H 0.5798 1.3234 0.1480 0.086 Uiso 1 1 calc R . .
C124 C 0.5383(3) 1.2404(4) 0.09423(18) 0.0369(11) Uani 1 1 d . . .
H124 H 0.5346 1.2865 0.0698 0.044 Uiso 1 1 calc R . .
C125 C 0.5155(3) 1.1542(4) 0.08391(18) 0.0389(12) Uani 1 1 d . . .
H125 H 0.4942 1.1406 0.0527 0.047 Uiso 1 1 calc R . .
C126 C 0.5232(3) 1.0855(4) 0.11904(19) 0.0404(12) Uani 1 1 d . . .
H126 H 0.5069 1.0252 0.1116 0.049 Uiso 1 1 calc R . .
C131 C 0.4666(2) 0.9954(3) 0.22720(15) 0.0195(7) Uani 1 1 d . . .
C132 C 0.4193(2) 1.0705(3) 0.23013(15) 0.0230(8) Uani 1 1 d . . .
H132 H 0.4367 1.1301 0.2228 0.028 Uiso 1 1 calc R . .
C133 C 0.3470(2) 1.0583(3) 0.24368(17) 0.0269(8) Uani 1 1 d . . .
H133 H 0.3152 1.1096 0.2459 0.032 Uiso 1 1 calc R . .
C134 C 0.3212(2) 0.9710(4) 0.25392(17) 0.0292(9) Uani 1 1 d . . .
H134 H 0.2718 0.9625 0.2633 0.035 Uiso 1 1 calc R . .
C135 C 0.3677(3) 0.8959(3) 0.2503(2) 0.0315(10) Uani 1 1 d . . .
H135 H 0.3501 0.8361 0.2570 0.038 Uiso 1 1 calc R . .
C136 C 0.4409(2) 0.9088(3) 0.23682(17) 0.0263(8) Uani 1 1 d . . .
H136 H 0.4727 0.8576 0.2343 0.032 Uiso 1 1 calc R . .
C201 C 0.6841(2) 1.0647(3) 0.25968(14) 0.0196(7) Uani 1 1 d . . .
H201 H 0.7069 1.0396 0.2318 0.023 Uiso 1 1 calc R . .
C202 C 0.7272(2) 1.0981(3) 0.29805(14) 0.0184(7) Uani 1 1 d . . .
C203 C 0.6073(2) 1.0672(3) 0.26136(14) 0.0195(7) Uani 1 1 d . . .
C204 C 0.6934(2) 1.1383(3) 0.33832(14) 0.0194(7) Uani 1 1 d . . .
H204 H 0.7227 1.1615 0.3647 0.023 Uiso 1 1 calc R . .
C205 C 0.5746(2) 1.1078(3) 0.30114(15) 0.0212(7) Uani 1 1 d . . .
H205 H 0.5226 1.1110 0.3023 0.025 Uiso 1 1 calc R . .
C206 C 0.6176(2) 1.1446(3) 0.34001(13) 0.0197(7) Uani 1 1 d . . .
C207 C 0.5830(2) 1.1894(3) 0.38238(14) 0.0246(8) Uani 1 1 d . . .
C208 C 0.5178(2) 1.2375(4) 0.37802(16) 0.0288(9) Uani 1 1 d . . .
H208 H 0.4935 1.2428 0.3470 0.035 Uiso 1 1 calc R . .
C209 C 0.6157(3) 1.1852(5) 0.42902(16) 0.0372(12) Uani 1 1 d . . .
H209 H 0.6602 1.1523 0.4342 0.045 Uiso 1 1 calc R . .
C210 C 0.4879(3) 1.2778(4) 0.41901(18) 0.0371(11) Uani 1 1 d . . .
H210 H 0.4430 1.3100 0.4151 0.045 Uiso 1 1 calc R . .
C211 C 0.5829(3) 1.2291(6) 0.46756(18) 0.0513(18) Uani 1 1 d . . .
H211 H 0.6072 1.2276 0.4987 0.062 Uiso 1 1 calc R . .
Cl1 Cl 0.47370(15) 0.0217(2) 0.44925(13) 0.0487(7) Uani 0.50 1 d P . .
Cl2 Cl 0.38080(13) 0.08704(17) 0.36789(9) 0.0331(4) Uani 0.50 1 d P . .
N1 N 0.5190(3) 1.2736(4) 0.46371(16) 0.0463(13) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C11 Ag1 C21 160.43(16) . . ?
C11 Ag1 C22 160.53(14) . . ?
C21 Ag1 C22 30.13(15) . . ?
C11 Ag1 C12 28.93(14) . . ?
C21 Ag1 C12 146.22(15) . . ?
C22 Ag1 C12 131.79(14) . . ?
C11 Ag1 Pt2 42.22(10) . . ?
C21 Ag1 Pt2 133.98(10) . . ?
C22 Ag1 Pt2 156.61(10) . . ?
C12 Ag1 Pt2 71.15(10) . . ?
C11 Ag1 Pt1 123.16(11) . . ?
C21 Ag1 Pt1 40.68(10) . . ?
C22 Ag1 Pt1 70.80(11) . . ?
C12 Ag1 Pt1 134.00(11) . . ?
Pt2 Ag1 Pt1 96.73(2) . . ?
C31 Ag2 C51 155.00(14) . . ?
C31 Ag2 C1 130.07(14) . . ?
C51 Ag2 C1 69.26(14) . . ?
C31 Ag2 C32 28.72(15) . . ?
C51 Ag2 C32 150.39(14) . . ?
C1 Ag2 C32 135.23(14) . . ?
C31 Ag2 C52 137.44(14) . . ?
C51 Ag2 C52 27.47(14) . . ?
C1 Ag2 C52 92.38(13) . . ?
C32 Ag2 C52 122.98(14) . . ?
C31 Ag2 Pt1 138.76(10) . . ?
C51 Ag2 Pt1 41.83(10) . . ?
C1 Ag2 Pt1 41.53(9) . . ?
C32 Ag2 Pt1 166.62(10) . . ?
C52 Ag2 Pt1 69.24(10) . . ?
C31 Ag2 Pt2 41.48(10) . . ?
C51 Ag2 Pt2 124.81(11) . . ?
C1 Ag2 Pt2 106.95(10) . . ?
C32 Ag2 Pt2 70.19(10) . . ?
C52 Ag2 Pt2 133.08(10) . . ?
Pt1 Ag2 Pt2 97.629(16) . . ?
C21 Pt1 C1 88.68(17) . . ?
C21 Pt1 C51 172.27(16) . . ?
C1 Pt1 C51 87.48(17) . . ?
C21 Pt1 P2 93.97(12) . . ?
C1 Pt1 P2 173.32(12) . . ?
C51 Pt1 P2 89.15(13) . . ?
C21 Pt1 Ag2 119.59(12) . . ?
C1 Pt1 Ag2 55.10(11) . . ?
C51 Pt1 Ag2 52.87(12) . . ?
P2 Pt1 Ag2 118.42(3) . . ?
C21 Pt1 Ag1 47.76(12) . . ?
C1 Pt1 Ag1 67.93(12) . . ?
C51 Pt1 Ag1 124.51(12) . . ?
P2 Pt1 Ag1 109.57(3) . . ?
Ag2 Pt1 Ag1 72.833(17) . . ?
C41 Pt2 C31 174.84(16) . . ?
C41 Pt2 C11 87.81(16) . . ?
C31 Pt2 C11 90.75(16) . . ?
C41 Pt2 P1 87.17(11) . . ?
C31 Pt2 P1 94.31(12) . . ?
C11 Pt2 P1 174.94(12) . . ?
C41 Pt2 Ag1 63.37(12) . . ?
C31 Pt2 Ag1 112.13(12) . . ?
C11 Pt2 Ag1 48.71(11) . . ?
P1 Pt2 Ag1 128.85(3) . . ?
C41 Pt2 Ag2 125.88(12) . . ?
C31 Pt2 Ag2 49.08(11) . . ?
C11 Pt2 Ag2 87.56(12) . . ?
P1 Pt2 Ag2 95.92(3) . . ?
Ag1 Pt2 Ag2 73.702(17) . . ?
C111 P1 C202 106.71(18) . . ?
C111 P1 C101 104.03(19) . . ?
C202 P1 C101 101.49(18) . . ?
C111 P1 Pt2 112.74(13) . . ?
C202 P1 Pt2 111.74(13) . . ?
C101 P1 Pt2 118.88(14) . . ?
C121 P2 C203 103.46(19) . . ?
C121 P2 C131 103.41(18) . . ?
C203 P2 C131 106.02(18) . . ?
C121 P2 Pt1 117.15(14) . . ?
C203 P2 Pt1 107.14(13) . . ?
C131 P2 Pt1 118.25(14) . . ?
C2 C1 Pt1 169.8(4) . . ?
C2 C1 Ag2 87.4(3) . . ?
Pt1 C1 Ag2 83.37(14) . . ?
C1 C2 C3 176.4(5) . . ?
C4 C3 C5 117.9(4) . . ?
C4 C3 C2 121.2(4) . . ?
C5 C3 C2 121.0(4) . . ?
C6 C4 C3 121.0(4) . . ?
C6 C4 H4 119.5 . . ?
C3 C4 H4 119.5 . . ?
C7 C5 C3 120.5(4) . . ?
C7 C5 H5 119.8 . . ?
C3 C5 H5 119.8 . . ?
C4 C6 C8 121.5(5) . . ?
C4 C6 H6 119.3 . . ?
C8 C6 H6 119.3 . . ?
C8 C7 C5 121.8(4) . . ?
C8 C7 H7 119.1 . . ?
C5 C7 H7 119.1 . . ?
C7 C8 C6 117.2(4) . . ?
C7 C8 C9 121.5(4) . . ?
C6 C8 C9 121.3(5) . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C12 C11 Pt2 176.0(4) . . ?
C12 C11 Ag1 87.2(3) . . ?
Pt2 C11 Ag1 89.06(15) . . ?
C11 C12 C13 172.7(5) . . ?
C11 C12 Ag1 63.8(3) . . ?
C13 C12 Ag1 123.4(3) . . ?
C14 C13 C15 118.6(4) . . ?
C14 C13 C12 122.1(4) . . ?
C15 C13 C12 119.3(4) . . ?
C13 C14 C16 120.1(5) . . ?
C13 C14 H14 119.9 . . ?
C16 C14 H14 119.9 . . ?
C17 C15 C13 120.2(4) . . ?
C17 C15 H15 119.9 . . ?
C13 C15 H15 119.9 . . ?
C18 C16 C14 121.7(5) . . ?
C18 C16 H16 119.1 . . ?
C14 C16 H16 119.1 . . ?
C15 C17 C18 121.4(5) . . ?
C15 C17 H17 119.3 . . ?
C18 C17 H17 119.3 . . ?
C16 C18 C17 117.9(5) . . ?
C16 C18 C19 121.8(5) . . ?
C17 C18 C19 120.3(5) . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C22 C21 Pt1 171.9(4) . . ?
C22 C21 Ag1 80.3(3) . . ?
Pt1 C21 Ag1 91.57(16) . . ?
C21 C22 C23 167.6(4) . . ?
C21 C22 Ag1 69.6(3) . . ?
C23 C22 Ag1 122.8(3) . . ?
C25 C23 C24 118.5(4) . . ?
C25 C23 C22 121.8(4) . . ?
C24 C23 C22 119.7(4) . . ?
C26 C24 C23 120.5(5) . . ?
C26 C24 H24 119.8 . . ?
C23 C24 H24 119.8 . . ?
C23 C25 C27 119.8(5) . . ?
C23 C25 H25 120.1 . . ?
C27 C25 H25 120.1 . . ?
C24 C26 C28 121.5(5) . . ?
C24 C26 H26 119.3 . . ?
C28 C26 H26 119.3 . . ?
C28 C27 C25 121.5(5) . . ?
C28 C27 H27 119.3 . . ?
C25 C27 H27 119.3 . . ?
C27 C28 C26 118.3(5) . . ?
C27 C28 C29 119.7(6) . . ?
C26 C28 C29 122.0(6) . . ?
C28 C29 H29A 109.5 . . ?
C28 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C28 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C32 C31 Pt2 176.5(4) . . ?
C32 C31 Ag2 87.2(3) . . ?
Pt2 C31 Ag2 89.45(14) . . ?
C31 C32 C33 171.1(4) . . ?
C31 C32 Ag2 64.0(3) . . ?
C33 C32 Ag2 124.7(3) . . ?
C34 C33 C35 118.9(4) . . ?
C34 C33 C32 120.5(4) . . ?
C35 C33 C32 120.6(4) . . ?
C36 C34 C33 120.8(4) . . ?
C36 C34 H34 119.6 . . ?
C33 C34 H34 119.6 . . ?
C37 C35 C33 119.6(4) . . ?
C37 C35 H35 120.2 . . ?
C33 C35 H35 120.2 . . ?
C34 C36 C38 121.2(5) . . ?
C34 C36 H36 119.4 . . ?
C38 C36 H36 119.4 . . ?
C35 C37 C38 121.8(5) . . ?
C35 C37 H37 119.1 . . ?
C38 C37 H37 119.1 . . ?
C36 C38 C37 117.6(5) . . ?
C36 C38 C39 121.7(5) . . ?
C37 C38 C39 120.5(5) . . ?
C38 C39 H39A 109.5 . . ?
C38 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
C38 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C42 C41 Pt2 174.9(4) . . ?
C41 C42 C43 178.2(5) . . ?
C45 C43 C44 118.7(4) . . ?
C45 C43 C42 121.4(4) . . ?
C44 C43 C42 119.9(4) . . ?
C43 C44 C46 119.6(5) . . ?
C43 C44 H44 120.2 . . ?
C46 C44 H44 120.2 . . ?
C47 C45 C43 120.7(5) . . ?
C47 C45 H45 119.6 . . ?
C43 C45 H45 119.6 . . ?
C44 C46 C48 121.3(6) . . ?
C44 C46 H46 119.3 . . ?
C48 C46 H46 119.3 . . ?
C48 C47 C45 121.5(5) . . ?
C48 C47 H47 119.3 . . ?
C45 C47 H47 119.3 . . ?
C47 C48 C46 118.2(5) . . ?
C47 C48 C49 120.6(6) . . ?
C46 C48 C49 121.2(6) . . ?
C48 C49 H49A 109.5 . . ?
C48 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C48 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C52 C51 Pt1 170.3(4) . . ?
C52 C51 Ag2 86.1(3) . . ?
Pt1 C51 Ag2 85.30(15) . . ?
C51 C52 C53 173.5(5) . . ?
C51 C52 Ag2 66.4(3) . . ?
C53 C52 Ag2 116.7(3) . . ?
C55 C53 C54 117.8(4) . . ?
C55 C53 C52 121.8(4) . . ?
C54 C53 C52 120.3(4) . . ?
C56 C54 C53 120.9(4) . . ?
C56 C54 H54 119.6 . . ?
C53 C54 H54 119.6 . . ?
C57 C55 C53 120.8(4) . . ?
C57 C55 H55 119.6 . . ?
C53 C55 H55 119.6 . . ?
C54 C56 C58 121.1(4) . . ?
C54 C56 H56 119.5 . . ?
C58 C56 H56 119.5 . . ?
C55 C57 C58 121.1(4) . . ?
C55 C57 H57 119.5 . . ?
C58 C57 H57 119.5 . . ?
C57 C58 C56 118.3(4) . . ?
C57 C58 C59 121.1(4) . . ?
C56 C58 C59 120.6(4) . . ?
C58 C59 H59A 109.5 . . ?
C58 C59 H59B 109.5 . . ?
H59A C59 H59B 109.5 . . ?
C58 C59 H59C 109.5 . . ?
H59A C59 H59C 109.5 . . ?
H59B C59 H59C 109.5 . . ?
Cl2 C01 Cl1 113.2(6) . . ?
Cl2 C01 H01A 108.9 . . ?
Cl1 C01 H01A 108.9 . . ?
Cl2 C01 H01B 108.9 . . ?
Cl1 C01 H01B 108.9 . . ?
H01A C01 H01B 107.7 . . ?
C106 C101 C102 119.3(4) . . ?
C106 C101 P1 122.9(3) . . ?
C102 C101 P1 117.8(3) . . ?
C103 C102 C101 120.1(4) . . ?
C103 C102 H102 119.9 . . ?
C101 C102 H102 119.9 . . ?
C104 C103 C102 120.5(5) . . ?
C104 C103 H103 119.8 . . ?
C102 C103 H103 119.8 . . ?
C103 C104 C105 120.1(5) . . ?
C103 C104 H104 119.9 . . ?
C105 C104 H104 119.9 . . ?
C104 C105 C106 120.2(5) . . ?
C104 C105 H105 119.9 . . ?
C106 C105 H105 119.9 . . ?
C101 C106 C105 119.7(5) . . ?
C101 C106 H106 120.1 . . ?
C105 C106 H106 120.1 . . ?
C116 C111 C112 119.5(4) . . ?
C116 C111 P1 124.1(3) . . ?
C112 C111 P1 116.4(3) . . ?
C113 C112 C111 120.4(4) . . ?
C113 C112 H112 119.8 . . ?
C111 C112 H112 119.8 . . ?
C112 C113 C114 119.7(4) . . ?
C112 C113 H113 120.2 . . ?
C114 C113 H113 120.2 . . ?
C115 C114 C113 120.4(4) . . ?
C115 C114 H114 119.8 . . ?
C113 C114 H114 119.8 . . ?
C114 C115 C116 119.8(4) . . ?
C114 C115 H115 120.1 . . ?
C116 C115 H115 120.1 . . ?
C111 C116 C115 120.1(4) . . ?
C111 C116 H116 119.9 . . ?
C115 C116 H116 119.9 . . ?
C126 C121 C122 118.7(4) . . ?
C126 C121 P2 119.2(4) . . ?
C122 C121 P2 122.0(3) . . ?
C121 C122 C123 120.6(6) . . ?
C121 C122 H122 119.7 . . ?
C123 C122 H122 119.7 . . ?
C124 C123 C122 119.0(7) . . ?
C124 C123 H123 120.5 . . ?
C122 C123 H123 120.5 . . ?
C125 C124 C123 120.6(5) . . ?
C125 C124 H124 119.7 . . ?
C123 C124 H124 119.7 . . ?
C124 C125 C126 120.0(5) . . ?
C124 C125 H125 120.0 . . ?
C126 C125 H125 120.0 . . ?
C121 C126 C125 120.9(5) . . ?
C121 C126 H126 119.6 . . ?
C125 C126 H126 119.6 . . ?
C136 C131 C132 119.8(4) . . ?
C136 C131 P2 120.5(3) . . ?
C132 C131 P2 119.7(3) . . ?
C133 C132 C131 120.4(4) . . ?
C133 C132 H132 119.8 . . ?
C131 C132 H132 119.8 . . ?
C132 C133 C134 119.9(4) . . ?
C132 C133 H133 120.0 . . ?
C134 C133 H133 120.0 . . ?
C133 C134 C135 119.9(4) . . ?
C133 C134 H134 120.1 . . ?
C135 C134 H134 120.1 . . ?
C134 C135 C136 119.9(4) . . ?
C134 C135 H135 120.0 . . ?
C136 C135 H135 120.0 . . ?
C131 C136 C135 120.1(4) . . ?
C131 C136 H136 119.9 . . ?
C135 C136 H136 119.9 . . ?
C202 C201 C203 121.1(3) . . ?
C202 C201 H201 119.5 . . ?
C203 C201 H201 119.5 . . ?
C201 C202 C204 119.3(3) . . ?
C201 C202 P1 118.2(3) . . ?
C204 C202 P1 122.3(3) . . ?
C205 C203 C201 119.0(4) . . ?
C205 C203 P2 126.9(3) . . ?
C201 C203 P2 114.1(3) . . ?
C206 C204 C202 120.6(4) . . ?
C206 C204 H204 119.7 . . ?
C202 C204 H204 119.7 . . ?
C203 C205 C206 120.7(4) . . ?
C203 C205 H205 119.7 . . ?
C206 C205 H205 119.7 . . ?
C204 C206 C205 119.2(3) . . ?
C204 C206 C207 119.8(4) . . ?
C205 C206 C207 121.0(3) . . ?
C208 C207 C209 116.7(4) . . ?
C208 C207 C206 122.5(4) . . ?
C209 C207 C206 120.8(4) . . ?
C207 C208 C210 119.9(4) . . ?
C207 C208 H208 120.1 . . ?
C210 C208 H208 120.1 . . ?
C211 C209 C207 119.4(5) . . ?
C211 C209 H209 120.3 . . ?
C207 C209 H209 120.3 . . ?
N1 C210 C208 123.6(5) . . ?
N1 C210 H210 118.2 . . ?
C208 C210 H210 118.2 . . ?
N1 C211 C209 124.0(5) . . ?
N1 C211 H211 118.0 . . ?
C209 C211 H211 118.0 . . ?
C210 N1 C211 116.4(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C11 2.259(4) . ?
Ag1 C21 2.283(4) . ?
Ag1 C22 2.402(4) . ?
Ag1 C12 2.514(4) . ?
Ag1 Pt2 3.0062(9) . ?
Ag1 Pt1 3.0831(9) . ?
Ag2 C31 2.291(4) . ?
Ag2 C51 2.413(4) . ?
Ag2 C1 2.490(4) . ?
Ag2 C32 2.545(4) . ?
Ag2 C52 2.626(4) . ?
Ag2 Pt1 3.0161(9) . ?
Ag2 Pt2 3.0317(6) . ?
Pt1 C21 2.010(4) . ?
Pt1 C1 2.013(4) . ?
Pt1 C51 2.018(4) . ?
Pt1 P2 2.2994(11) . ?
Pt2 C41 1.999(4) . ?
Pt2 C31 2.008(4) . ?
Pt2 C11 2.021(4) . ?
Pt2 P1 2.2933(10) . ?
P1 C111 1.810(4) . ?
P1 C202 1.820(4) . ?
P1 C101 1.824(4) . ?
P2 C121 1.813(4) . ?
P2 C203 1.819(4) . ?
P2 C131 1.822(4) . ?
C1 C2 1.217(6) . ?
C2 C3 1.431(6) . ?
C3 C4 1.393(6) . ?
C3 C5 1.396(6) . ?
C4 C6 1.381(7) . ?
C4 H4 0.9500 . ?
C5 C7 1.388(6) . ?
C5 H5 0.9500 . ?
C6 C8 1.395(7) . ?
C6 H6 0.9500 . ?
C7 C8 1.387(7) . ?
C7 H7 0.9500 . ?
C8 C9 1.512(7) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C11 C12 1.218(6) . ?
C12 C13 1.442(6) . ?
C13 C14 1.390(6) . ?
C13 C15 1.408(6) . ?
C14 C16 1.397(7) . ?
C14 H14 0.9500 . ?
C15 C17 1.390(6) . ?
C15 H15 0.9500 . ?
C16 C18 1.386(8) . ?
C16 H16 0.9500 . ?
C17 C18 1.392(7) . ?
C17 H17 0.9500 . ?
C18 C19 1.517(7) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C21 C22 1.223(6) . ?
C22 C23 1.442(6) . ?
C23 C25 1.387(7) . ?
C23 C24 1.389(6) . ?
C24 C26 1.376(7) . ?
C24 H24 0.9500 . ?
C25 C27 1.398(7) . ?
C25 H25 0.9500 . ?
C26 C28 1.380(9) . ?
C26 H26 0.9500 . ?
C27 C28 1.365(9) . ?
C27 H27 0.9500 . ?
C28 C29 1.524(8) . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C31 C32 1.225(6) . ?
C32 C33 1.435(6) . ?
C33 C34 1.396(6) . ?
C33 C35 1.400(6) . ?
C34 C36 1.383(7) . ?
C34 H34 0.9500 . ?
C35 C37 1.388(7) . ?
C35 H35 0.9500 . ?
C36 C38 1.394(8) . ?
C36 H36 0.9500 . ?
C37 C38 1.402(7) . ?
C37 H37 0.9500 . ?
C38 C39 1.504(8) . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C41 C42 1.211(6) . ?
C42 C43 1.438(6) . ?
C43 C45 1.390(7) . ?
C43 C44 1.391(7) . ?
C44 C46 1.393(8) . ?
C44 H44 0.9500 . ?
C45 C47 1.388(8) . ?
C45 H45 0.9500 . ?
C46 C48 1.400(9) . ?
C46 H46 0.9500 . ?
C47 C48 1.360(9) . ?
C47 H47 0.9500 . ?
C48 C49 1.501(8) . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C51 C52 1.214(6) . ?
C52 C53 1.437(6) . ?
C53 C55 1.398(6) . ?
C53 C54 1.408(6) . ?
C54 C56 1.379(7) . ?
C54 H54 0.9500 . ?
C55 C57 1.388(6) . ?
C55 H55 0.9500 . ?
C56 C58 1.392(7) . ?
C56 H56 0.9500 . ?
C57 C58 1.391(7) . ?
C57 H57 0.9500 . ?
C58 C59 1.506(6) . ?
C59 H59A 0.9800 . ?
C59 H59B 0.9800 . ?
C59 H59C 0.9800 . ?
C01 Cl2 1.719(13) . ?
C01 Cl1 1.784(14) . ?
C01 H01A 0.9900 . ?
C01 H01B 0.9900 . ?
C101 C106 1.385(6) . ?
C101 C102 1.400(6) . ?
C102 C103 1.383(6) . ?
C102 H102 0.9500 . ?
C103 C104 1.375(7) . ?
C103 H103 0.9500 . ?
C104 C105 1.377(8) . ?
C104 H104 0.9500 . ?
C105 C106 1.404(7) . ?
C105 H105 0.9500 . ?
C106 H106 0.9500 . ?
C111 C116 1.386(6) . ?
C111 C112 1.397(5) . ?
C112 C113 1.387(6) . ?
C112 H112 0.9500 . ?
C113 C114 1.388(7) . ?
C113 H113 0.9500 . ?
C114 C115 1.384(6) . ?
C114 H114 0.9500 . ?
C115 C116 1.396(6) . ?
C115 H115 0.9500 . ?
C116 H116 0.9500 . ?
C121 C126 1.377(6) . ?
C121 C122 1.380(7) . ?
C122 C123 1.402(8) . ?
C122 H122 0.9500 . ?
C123 C124 1.384(9) . ?
C123 H123 0.9500 . ?
C124 C125 1.353(9) . ?
C124 H124 0.9500 . ?
C125 C126 1.394(7) . ?
C125 H125 0.9500 . ?
C126 H126 0.9500 . ?
C131 C136 1.376(6) . ?
C131 C132 1.400(6) . ?
C132 C133 1.390(5) . ?
C132 H132 0.9500 . ?
C133 C134 1.391(7) . ?
C133 H133 0.9500 . ?
C134 C135 1.391(7) . ?
C134 H134 0.9500 . ?
C135 C136 1.407(6) . ?
C135 H135 0.9500 . ?
C136 H136 0.9500 . ?
C201 C202 1.385(5) . ?
C201 C203 1.403(5) . ?
C201 H201 0.9500 . ?
C202 C204 1.402(5) . ?
C203 C205 1.387(5) . ?
C204 C206 1.388(5) . ?
C204 H204 0.9500 . ?
C205 C206 1.413(6) . ?
C205 H205 0.9500 . ?
C206 C207 1.483(5) . ?
C207 C208 1.385(6) . ?
C207 C209 1.396(6) . ?
C208 C210 1.388(6) . ?
C208 H208 0.9500 . ?
C209 C211 1.382(7) . ?
C209 H209 0.9500 . ?
C210 N1 1.336(7) . ?
C210 H210 0.9500 . ?
C211 N1 1.338(7) . ?
C211 H211 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C31 Ag2 Pt1 C21 36.0(2) . . . . ?
C51 Ag2 Pt1 C21 177.9(2) . . . . ?
C1 Ag2 Pt1 C21 -64.6(2) . . . . ?
C32 Ag2 Pt1 C21 18.5(5) . . . . ?
C52 Ag2 Pt1 C21 175.70(17) . . . . ?
Pt2 Ag2 Pt1 C21 42.37(14) . . . . ?
C31 Ag2 Pt1 C1 100.6(2) . . . . ?
C51 Ag2 Pt1 C1 -117.4(2) . . . . ?
C32 Ag2 Pt1 C1 83.1(5) . . . . ?
C52 Ag2 Pt1 C1 -119.67(18) . . . . ?
Pt2 Ag2 Pt1 C1 107.00(15) . . . . ?
C31 Ag2 Pt1 C51 -141.9(2) . . . . ?
C1 Ag2 Pt1 C51 117.4(2) . . . . ?
C32 Ag2 Pt1 C51 -159.5(5) . . . . ?
C52 Ag2 Pt1 C51 -2.23(19) . . . . ?
Pt2 Ag2 Pt1 C51 -135.56(16) . . . . ?
C31 Ag2 Pt1 P2 -77.43(16) . . . . ?
C51 Ag2 Pt1 P2 64.49(16) . . . . ?
C1 Ag2 Pt1 P2 -178.07(15) . . . . ?
C32 Ag2 Pt1 P2 -95.0(4) . . . . ?
C52 Ag2 Pt1 P2 62.26(11) . . . . ?
Pt2 Ag2 Pt1 P2 -71.08(4) . . . . ?
C31 Ag2 Pt1 Ag1 25.96(15) . . . . ?
C51 Ag2 Pt1 Ag1 167.87(16) . . . . ?
C1 Ag2 Pt1 Ag1 -74.69(15) . . . . ?
C32 Ag2 Pt1 Ag1 8.4(4) . . . . ?
C52 Ag2 Pt1 Ag1 165.64(10) . . . . ?
Pt2 Ag2 Pt1 Ag1 32.308(12) . . . . ?
C11 Ag1 Pt1 C21 -165.1(2) . . . . ?
C22 Ag1 Pt1 C21 -0.34(19) . . . . ?
C12 Ag1 Pt1 C21 -130.5(2) . . . . ?
Pt2 Ag1 Pt1 C21 159.30(16) . . . . ?
C11 Ag1 Pt1 C1 -55.60(18) . . . . ?
C21 Ag1 Pt1 C1 109.5(2) . . . . ?
C22 Ag1 Pt1 C1 109.21(16) . . . . ?
C12 Ag1 Pt1 C1 -20.93(19) . . . . ?
Pt2 Ag1 Pt1 C1 -91.15(12) . . . . ?
C11 Ag1 Pt1 C51 14.7(2) . . . . ?
C21 Ag1 Pt1 C51 179.9(2) . . . . ?
C22 Ag1 Pt1 C51 179.55(19) . . . . ?
C12 Ag1 Pt1 C51 49.4(2) . . . . ?
Pt2 Ag1 Pt1 C51 -20.81(15) . . . . ?
C11 Ag1 Pt1 P2 117.76(13) . . . . ?
C21 Ag1 Pt1 P2 -77.09(16) . . . . ?
C22 Ag1 Pt1 P2 -77.43(11) . . . . ?
C12 Ag1 Pt1 P2 152.44(14) . . . . ?
Pt2 Ag1 Pt1 P2 82.21(3) . . . . ?
C11 Ag1 Pt1 Ag2 3.01(13) . . . . ?
C21 Ag1 Pt1 Ag2 168.16(16) . . . . ?
C22 Ag1 Pt1 Ag2 167.82(11) . . . . ?
C12 Ag1 Pt1 Ag2 37.68(14) . . . . ?
Pt2 Ag1 Pt1 Ag2 -32.544(16) . . . . ?
C11 Ag1 Pt2 C41 112.5(2) . . . . ?
C21 Ag1 Pt2 C41 -95.19(19) . . . . ?
C22 Ag1 Pt2 C41 -58.0(3) . . . . ?
C12 Ag1 Pt2 C41 111.80(16) . . . . ?
Pt1 Ag1 Pt2 C41 -113.87(12) . . . . ?
C11 Ag1 Pt2 C31 -70.2(2) . . . . ?
C21 Ag1 Pt2 C31 82.04(19) . . . . ?
C22 Ag1 Pt2 C31 119.2(3) . . . . ?
C12 Ag1 Pt2 C31 -70.97(16) . . . . ?
Pt1 Ag1 Pt2 C31 63.36(12) . . . . ?
C21 Ag1 Pt2 C11 152.3(2) . . . . ?
C22 Ag1 Pt2 C11 -170.5(3) . . . . ?
C12 Ag1 Pt2 C11 -0.74(19) . . . . ?
Pt1 Ag1 Pt2 C11 133.59(16) . . . . ?
C11 Ag1 Pt2 P1 174.20(16) . . . . ?
C21 Ag1 Pt2 P1 -33.54(16) . . . . ?
C22 Ag1 Pt2 P1 3.6(3) . . . . ?
C12 Ag1 Pt2 P1 173.46(11) . . . . ?
Pt1 Ag1 Pt2 P1 -52.21(4) . . . . ?
C11 Ag1 Pt2 Ag2 -101.40(16) . . . . ?
C21 Ag1 Pt2 Ag2 50.86(15) . . . . ?
C22 Ag1 Pt2 Ag2 88.1(3) . . . . ?
C12 Ag1 Pt2 Ag2 -102.14(11) . . . . ?
Pt1 Ag1 Pt2 Ag2 32.191(13) . . . . ?
C31 Ag2 Pt2 C41 178.6(2) . . . . ?
C51 Ag2 Pt2 C41 -29.71(18) . . . . ?
C1 Ag2 Pt2 C41 46.47(17) . . . . ?
C32 Ag2 Pt2 C41 179.24(17) . . . . ?
C52 Ag2 Pt2 C41 -63.68(19) . . . . ?
Pt1 Ag2 Pt2 C41 4.96(14) . . . . ?
C51 Ag2 Pt2 C31 151.66(19) . . . . ?
C1 Ag2 Pt2 C31 -132.17(18) . . . . ?
C32 Ag2 Pt2 C31 0.60(19) . . . . ?
C52 Ag2 Pt2 C31 117.7(2) . . . . ?
Pt1 Ag2 Pt2 C31 -173.68(15) . . . . ?
C31 Ag2 Pt2 C11 93.11(19) . . . . ?
C51 Ag2 Pt2 C11 -115.23(17) . . . . ?
C1 Ag2 Pt2 C11 -39.06(15) . . . . ?
C32 Ag2 Pt2 C11 93.71(15) . . . . ?
C52 Ag2 Pt2 C11 -149.20(17) . . . . ?
Pt1 Ag2 Pt2 C11 -80.57(11) . . . . ?
C31 Ag2 Pt2 P1 -90.58(15) . . . . ?
C51 Ag2 Pt2 P1 61.07(12) . . . . ?
C1 Ag2 Pt2 P1 137.25(10) . . . . ?
C32 Ag2 Pt2 P1 -89.98(11) . . . . ?
C52 Ag2 Pt2 P1 27.11(13) . . . . ?
Pt1 Ag2 Pt2 P1 95.74(3) . . . . ?
C31 Ag2 Pt2 Ag1 140.61(15) . . . . ?
C51 Ag2 Pt2 Ag1 -67.73(12) . . . . ?
C1 Ag2 Pt2 Ag1 8.44(10) . . . . ?
C32 Ag2 Pt2 Ag1 141.21(11) . . . . ?
C52 Ag2 Pt2 Ag1 -101.70(13) . . . . ?
Pt1 Ag2 Pt2 Ag1 -33.070(17) . . . . ?
C41 Pt2 P1 C111 -48.14(18) . . . . ?
C31 Pt2 P1 C111 136.82(18) . . . . ?
C11 Pt2 P1 C111 -40.7(13) . . . . ?
Ag1 Pt2 P1 C111 -100.11(14) . . . . ?
Ag2 Pt2 P1 C111 -173.92(14) . . . . ?
C41 Pt2 P1 C202 72.05(18) . . . . ?
C31 Pt2 P1 C202 -103.00(18) . . . . ?
C11 Pt2 P1 C202 79.5(13) . . . . ?
Ag1 Pt2 P1 C202 20.08(15) . . . . ?
Ag2 Pt2 P1 C202 -53.73(14) . . . . ?
C41 Pt2 P1 C101 -170.25(19) . . . . ?
C31 Pt2 P1 C101 14.70(19) . . . . ?
C11 Pt2 P1 C101 -162.8(13) . . . . ?
Ag1 Pt2 P1 C101 137.78(15) . . . . ?
Ag2 Pt2 P1 C101 63.97(15) . . . . ?
C21 Pt1 P2 C121 -4.13(19) . . . . ?
C1 Pt1 P2 C121 109.1(11) . . . . ?
C51 Pt1 P2 C121 168.79(19) . . . . ?
Ag2 Pt1 P2 C121 122.77(15) . . . . ?
Ag1 Pt1 P2 C121 42.20(15) . . . . ?
C21 Pt1 P2 C203 -119.72(18) . . . . ?
C1 Pt1 P2 C203 -6.5(11) . . . . ?
C51 Pt1 P2 C203 53.20(18) . . . . ?
Ag2 Pt1 P2 C203 7.18(14) . . . . ?
Ag1 Pt1 P2 C203 -73.39(14) . . . . ?
C21 Pt1 P2 C131 120.71(19) . . . . ?
C1 Pt1 P2 C131 -126.1(11) . . . . ?
C51 Pt1 P2 C131 -66.37(19) . . . . ?
Ag2 Pt1 P2 C131 -112.39(15) . . . . ?
Ag1 Pt1 P2 C131 167.04(15) . . . . ?
C21 Pt1 C1 C2 102(2) . . . . ?
C51 Pt1 C1 C2 -71(2) . . . . ?
P2 Pt1 C1 C2 -12(3) . . . . ?
Ag2 Pt1 C1 C2 -26(2) . . . . ?
Ag1 Pt1 C1 C2 58(2) . . . . ?
C21 Pt1 C1 Ag2 128.20(15) . . . . ?
C51 Pt1 C1 Ag2 -45.09(14) . . . . ?
P2 Pt1 C1 Ag2 14.7(11) . . . . ?
Ag1 Pt1 C1 Ag2 83.94(9) . . . . ?
C31 Ag2 C1 C2 53.3(4) . . . . ?
C51 Ag2 C1 C2 -145.3(3) . . . . ?
C32 Ag2 C1 C2 14.5(4) . . . . ?
C52 Ag2 C1 C2 -130.1(3) . . . . ?
Pt1 Ag2 C1 C2 175.5(4) . . . . ?
Pt2 Ag2 C1 C2 93.2(3) . . . . ?
C31 Ag2 C1 Pt1 -122.15(16) . . . . ?
C51 Ag2 C1 Pt1 39.27(14) . . . . ?
C32 Ag2 C1 Pt1 -160.96(15) . . . . ?
C52 Ag2 C1 Pt1 54.41(15) . . . . ?
Pt2 Ag2 C1 Pt1 -82.25(12) . . . . ?
Pt1 C1 C2 C3 -177(100) . . . . ?
Ag2 C1 C2 C3 157(8) . . . . ?
C1 C2 C3 C4 51(8) . . . . ?
C1 C2 C3 C5 -130(8) . . . . ?
C5 C3 C4 C6 3.5(8) . . . . ?
C2 C3 C4 C6 -177.4(6) . . . . ?
C4 C3 C5 C7 -2.8(7) . . . . ?
C2 C3 C5 C7 178.1(4) . . . . ?
C3 C4 C6 C8 -0.8(10) . . . . ?
C3 C5 C7 C8 -0.6(7) . . . . ?
C5 C7 C8 C6 3.2(8) . . . . ?
C5 C7 C8 C9 -174.9(5) . . . . ?
C4 C6 C8 C7 -2.5(9) . . . . ?
C4 C6 C8 C9 175.6(6) . . . . ?
C41 Pt2 C11 C12 -34(6) . . . . ?
C31 Pt2 C11 C12 141(6) . . . . ?
P1 Pt2 C11 C12 -42(7) . . . . ?
Ag1 Pt2 C11 C12 21(6) . . . . ?
Ag2 Pt2 C11 C12 92(6) . . . . ?
C41 Pt2 C11 Ag1 -55.72(16) . . . . ?
C31 Pt2 C11 Ag1 119.33(15) . . . . ?
P1 Pt2 C11 Ag1 -63.1(14) . . . . ?
Ag2 Pt2 C11 Ag1 70.34(11) . . . . ?
C21 Ag1 C11 C12 92.3(5) . . . . ?
C22 Ag1 C11 C12 -9.8(6) . . . . ?
Pt2 Ag1 C11 C12 -178.6(4) . . . . ?
Pt1 Ag1 C11 C12 122.2(3) . . . . ?
C21 Ag1 C11 Pt2 -89.1(4) . . . . ?
C22 Ag1 C11 Pt2 168.7(4) . . . . ?
C12 Ag1 C11 Pt2 178.6(4) . . . . ?
Pt1 Ag1 C11 Pt2 -59.23(17) . . . . ?
Pt2 C11 C12 C13 154(4) . . . . ?
Ag1 C11 C12 C13 176(4) . . . . ?
Pt2 C11 C12 Ag1 -21(6) . . . . ?
C21 Ag1 C12 C11 -143.0(3) . . . . ?
C22 Ag1 C12 C11 175.6(3) . . . . ?
Pt2 Ag1 C12 C11 1.0(3) . . . . ?
Pt1 Ag1 C12 C11 -79.9(3) . . . . ?
C11 Ag1 C12 C13 -179.4(6) . . . . ?
C21 Ag1 C12 C13 37.6(5) . . . . ?
C22 Ag1 C12 C13 -3.7(5) . . . . ?
Pt2 Ag1 C12 C13 -178.3(4) . . . . ?
Pt1 Ag1 C12 C13 100.7(4) . . . . ?
C11 C12 C13 C14 175(4) . . . . ?
Ag1 C12 C13 C14 -9.2(6) . . . . ?
C11 C12 C13 C15 -7(4) . . . . ?
Ag1 C12 C13 C15 168.7(3) . . . . ?
C15 C13 C14 C16 -0.4(8) . . . . ?
C12 C13 C14 C16 177.5(5) . . . . ?
C14 C13 C15 C17 1.8(8) . . . . ?
C12 C13 C15 C17 -176.2(5) . . . . ?
C13 C14 C16 C18 -1.6(9) . . . . ?
C13 C15 C17 C18 -1.3(8) . . . . ?
C14 C16 C18 C17 2.1(9) . . . . ?
C14 C16 C18 C19 -177.9(6) . . . . ?
C15 C17 C18 C16 -0.7(9) . . . . ?
C15 C17 C18 C19 179.4(6) . . . . ?
C1 Pt1 C21 C22 -56(3) . . . . ?
C51 Pt1 C21 C22 4(3) . . . . ?
P2 Pt1 C21 C22 117(3) . . . . ?
Ag2 Pt1 C21 C22 -9(3) . . . . ?
Ag1 Pt1 C21 C22 4(3) . . . . ?
C1 Pt1 C21 Ag1 -60.87(16) . . . . ?
C51 Pt1 C21 Ag1 -0.7(13) . . . . ?
P2 Pt1 C21 Ag1 112.98(11) . . . . ?
Ag2 Pt1 C21 Ag1 -13.03(17) . . . . ?
C11 Ag1 C21 C22 -139.5(4) . . . . ?
C12 Ag1 C21 C22 -79.1(4) . . . . ?
Pt2 Ag1 C21 C22 151.4(2) . . . . ?
Pt1 Ag1 C21 C22 -179.4(4) . . . . ?
C11 Ag1 C21 Pt1 39.8(5) . . . . ?
C22 Ag1 C21 Pt1 179.4(4) . . . . ?
C12 Ag1 C21 Pt1 100.2(3) . . . . ?
Pt2 Ag1 C21 Pt1 -29.2(2) . . . . ?
Pt1 C21 C22 C23 -179(100) . . . . ?
Ag1 C21 C22 C23 -175(2) . . . . ?
Pt1 C21 C22 Ag1 -5(3) . . . . ?
C11 Ag1 C22 C21 139.3(4) . . . . ?
C12 Ag1 C22 C21 132.9(3) . . . . ?
Pt2 Ag1 C22 C21 -60.1(4) . . . . ?
Pt1 Ag1 C22 C21 0.4(2) . . . . ?
C11 Ag1 C22 C23 -42.0(6) . . . . ?
C21 Ag1 C22 C23 178.7(5) . . . . ?
C12 Ag1 C22 C23 -48.4(4) . . . . ?
Pt2 Ag1 C22 C23 118.6(3) . . . . ?
Pt1 Ag1 C22 C23 179.1(4) . . . . ?
C21 C22 C23 C25 -178.5(19) . . . . ?
Ag1 C22 C23 C25 7.2(6) . . . . ?
C21 C22 C23 C24 2(2) . . . . ?
Ag1 C22 C23 C24 -172.3(4) . . . . ?
C25 C23 C24 C26 0.0(8) . . . . ?
C22 C23 C24 C26 179.6(5) . . . . ?
C24 C23 C25 C27 0.5(7) . . . . ?
C22 C23 C25 C27 -179.0(4) . . . . ?
C23 C24 C26 C28 -0.4(10) . . . . ?
C23 C25 C27 C28 -0.7(8) . . . . ?
C25 C27 C28 C26 0.4(9) . . . . ?
C25 C27 C28 C29 -178.8(6) . . . . ?
C24 C26 C28 C27 0.1(10) . . . . ?
C24 C26 C28 C29 179.3(6) . . . . ?
C41 Pt2 C31 C32 -32(7) . . . . ?
C11 Pt2 C31 C32 -106(6) . . . . ?
P1 Pt2 C31 C32 74(6) . . . . ?
Ag1 Pt2 C31 C32 -61(6) . . . . ?
Ag2 Pt2 C31 C32 -20(6) . . . . ?
C41 Pt2 C31 Ag2 -12.4(18) . . . . ?
C11 Pt2 C31 Ag2 -86.12(15) . . . . ?
P1 Pt2 C31 Ag2 94.10(10) . . . . ?
Ag1 Pt2 C31 Ag2 -41.11(14) . . . . ?
C51 Ag2 C31 C32 111.5(4) . . . . ?
C1 Ag2 C31 C32 -113.3(3) . . . . ?
C52 Ag2 C31 C32 71.8(3) . . . . ?
Pt1 Ag2 C31 C32 -171.7(2) . . . . ?
Pt2 Ag2 C31 C32 178.8(4) . . . . ?
C51 Ag2 C31 Pt2 -67.3(4) . . . . ?
C1 Ag2 C31 Pt2 67.9(2) . . . . ?
C32 Ag2 C31 Pt2 -178.8(4) . . . . ?
C52 Ag2 C31 Pt2 -107.0(2) . . . . ?
Pt1 Ag2 C31 Pt2 9.5(2) . . . . ?
Pt2 C31 C32 C33 -151(4) . . . . ?
Ag2 C31 C32 C33 -170(3) . . . . ?
Pt2 C31 C32 Ag2 20(6) . . . . ?
C51 Ag2 C32 C31 -127.3(3) . . . . ?
C1 Ag2 C32 C31 93.6(3) . . . . ?
C52 Ag2 C32 C31 -130.0(3) . . . . ?
Pt1 Ag2 C32 C31 24.4(6) . . . . ?
Pt2 Ag2 C32 C31 -0.8(3) . . . . ?
C31 Ag2 C32 C33 178.2(6) . . . . ?
C51 Ag2 C32 C33 50.9(5) . . . . ?
C1 Ag2 C32 C33 -88.2(4) . . . . ?
C52 Ag2 C32 C33 48.2(4) . . . . ?
Pt1 Ag2 C32 C33 -157.4(3) . . . . ?
Pt2 Ag2 C32 C33 177.4(4) . . . . ?
C31 C32 C33 C34 131(3) . . . . ?
Ag2 C32 C33 C34 -38.2(6) . . . . ?
C31 C32 C33 C35 -46(3) . . . . ?
Ag2 C32 C33 C35 144.3(4) . . . . ?
C35 C33 C34 C36 2.7(8) . . . . ?
C32 C33 C34 C36 -175.0(5) . . . . ?
C34 C33 C35 C37 -2.4(8) . . . . ?
C32 C33 C35 C37 175.2(5) . . . . ?
C33 C34 C36 C38 0.0(10) . . . . ?
C33 C35 C37 C38 -0.6(9) . . . . ?
C34 C36 C38 C37 -2.9(10) . . . . ?
C34 C36 C38 C39 172.9(7) . . . . ?
C35 C37 C38 C36 3.2(10) . . . . ?
C35 C37 C38 C39 -172.6(7) . . . . ?
C31 Pt2 C41 C42 3(5) . . . . ?
C11 Pt2 C41 C42 77(4) . . . . ?
P1 Pt2 C41 C42 -104(4) . . . . ?
Ag1 Pt2 C41 C42 33(4) . . . . ?
Ag2 Pt2 C41 C42 -9(4) . . . . ?
Pt2 C41 C42 C43 143(13) . . . . ?
C41 C42 C43 C45 149(15) . . . . ?
C41 C42 C43 C44 -31(15) . . . . ?
C45 C43 C44 C46 -0.2(9) . . . . ?
C42 C43 C44 C46 180.0(6) . . . . ?
C44 C43 C45 C47 -0.4(9) . . . . ?
C42 C43 C45 C47 179.5(5) . . . . ?
C43 C44 C46 C48 0.5(12) . . . . ?
C43 C45 C47 C48 0.6(10) . . . . ?
C45 C47 C48 C46 -0.2(11) . . . . ?
C45 C47 C48 C49 179.3(7) . . . . ?
C44 C46 C48 C47 -0.3(12) . . . . ?
C44 C46 C48 C49 -179.8(8) . . . . ?
C21 Pt1 C51 C52 14(3) . . . . ?
C1 Pt1 C51 C52 75(2) . . . . ?
P2 Pt1 C51 C52 -100(2) . . . . ?
Ag2 Pt1 C51 C52 28(2) . . . . ?
Ag1 Pt1 C51 C52 14(2) . . . . ?
C21 Pt1 C51 Ag2 -13.5(13) . . . . ?
C1 Pt1 C51 Ag2 46.77(15) . . . . ?
P2 Pt1 C51 Ag2 -127.45(10) . . . . ?
Ag1 Pt1 C51 Ag2 -14.10(18) . . . . ?
C31 Ag2 C51 C52 -69.7(5) . . . . ?
C1 Ag2 C51 C52 145.5(3) . . . . ?
C32 Ag2 C51 C52 -4.9(5) . . . . ?
Pt1 Ag2 C51 C52 -175.5(4) . . . . ?
Pt2 Ag2 C51 C52 -117.8(3) . . . . ?
C31 Ag2 C51 Pt1 105.8(3) . . . . ?
C1 Ag2 C51 Pt1 -38.98(14) . . . . ?
C32 Ag2 C51 Pt1 170.5(2) . . . . ?
C52 Ag2 C51 Pt1 175.5(4) . . . . ?
Pt2 Ag2 C51 Pt1 57.70(16) . . . . ?
Pt1 C51 C52 C53 93(4) . . . . ?
Ag2 C51 C52 C53 120(4) . . . . ?
Pt1 C51 C52 Ag2 -28(2) . . . . ?
C31 Ag2 C52 C51 144.1(3) . . . . ?
C1 Ag2 C52 C51 -32.0(3) . . . . ?
C32 Ag2 C52 C51 177.1(3) . . . . ?
Pt1 Ag2 C52 C51 3.2(3) . . . . ?
Pt2 Ag2 C52 C51 84.0(3) . . . . ?
C31 Ag2 C52 C53 -29.6(4) . . . . ?
C51 Ag2 C52 C53 -173.7(5) . . . . ?
C1 Ag2 C52 C53 154.3(3) . . . . ?
C32 Ag2 C52 C53 3.4(4) . . . . ?
Pt1 Ag2 C52 C53 -170.5(3) . . . . ?
Pt2 Ag2 C52 C53 -89.7(3) . . . . ?
C51 C52 C53 C55 169(4) . . . . ?
Ag2 C52 C53 C55 -73.6(5) . . . . ?
C51 C52 C53 C54 -14(4) . . . . ?
Ag2 C52 C53 C54 103.2(4) . . . . ?
C55 C53 C54 C56 0.7(7) . . . . ?
C52 C53 C54 C56 -176.2(4) . . . . ?
C54 C53 C55 C57 -1.7(6) . . . . ?
C52 C53 C55 C57 175.2(4) . . . . ?
C53 C54 C56 C58 1.9(7) . . . . ?
C53 C55 C57 C58 0.1(7) . . . . ?
C55 C57 C58 C56 2.4(7) . . . . ?
C55 C57 C58 C59 -177.0(4) . . . . ?
C54 C56 C58 C57 -3.4(7) . . . . ?
C54 C56 C58 C59 176.0(5) . . . . ?
C111 P1 C101 C106 -15.0(4) . . . . ?
C202 P1 C101 C106 -125.7(4) . . . . ?
Pt2 P1 C101 C106 111.4(4) . . . . ?
C111 P1 C101 C102 165.7(3) . . . . ?
C202 P1 C101 C102 55.0(4) . . . . ?
Pt2 P1 C101 C102 -68.0(4) . . . . ?
C106 C101 C102 C103 0.0(7) . . . . ?
P1 C101 C102 C103 179.4(4) . . . . ?
C101 C102 C103 C104 -0.2(8) . . . . ?
C102 C103 C104 C105 -0.3(10) . . . . ?
C103 C104 C105 C106 0.8(11) . . . . ?
C102 C101 C106 C105 0.5(8) . . . . ?
P1 C101 C106 C105 -178.8(5) . . . . ?
C104 C105 C106 C101 -1.0(10) . . . . ?
C202 P1 C111 C116 5.2(4) . . . . ?
C101 P1 C111 C116 -101.6(4) . . . . ?
Pt2 P1 C111 C116 128.2(3) . . . . ?
C202 P1 C111 C112 -174.8(3) . . . . ?
C101 P1 C111 C112 78.4(3) . . . . ?
Pt2 P1 C111 C112 -51.8(3) . . . . ?
C116 C111 C112 C113 1.9(6) . . . . ?
P1 C111 C112 C113 -178.1(3) . . . . ?
C111 C112 C113 C114 -1.0(6) . . . . ?
C112 C113 C114 C115 -0.4(7) . . . . ?
C113 C114 C115 C116 0.9(7) . . . . ?
C112 C111 C116 C115 -1.4(6) . . . . ?
P1 C111 C116 C115 178.6(4) . . . . ?
C114 C115 C116 C111 0.0(7) . . . . ?
C203 P2 C121 C126 178.2(4) . . . . ?
C131 P2 C121 C126 -71.4(4) . . . . ?
Pt1 P2 C121 C126 60.6(4) . . . . ?
C203 P2 C121 C122 -4.0(6) . . . . ?
C131 P2 C121 C122 106.4(6) . . . . ?
Pt1 P2 C121 C122 -121.6(5) . . . . ?
C126 C121 C122 C123 1.3(12) . . . . ?
P2 C121 C122 C123 -176.4(7) . . . . ?
C121 C122 C123 C124 -3.8(14) . . . . ?
C122 C123 C124 C125 4.4(13) . . . . ?
C123 C124 C125 C126 -2.4(10) . . . . ?
C122 C121 C126 C125 0.8(9) . . . . ?
P2 C121 C126 C125 178.6(4) . . . . ?
C124 C125 C126 C121 -0.3(9) . . . . ?
C121 P2 C131 C136 142.8(4) . . . . ?
C203 P2 C131 C136 -108.7(4) . . . . ?
Pt1 P2 C131 C136 11.4(4) . . . . ?
C121 P2 C131 C132 -35.8(4) . . . . ?
C203 P2 C131 C132 72.7(4) . . . . ?
Pt1 P2 C131 C132 -167.2(3) . . . . ?
C136 C131 C132 C133 1.4(6) . . . . ?
P2 C131 C132 C133 180.0(3) . . . . ?
C131 C132 C133 C134 -0.7(7) . . . . ?
C132 C133 C134 C135 -0.3(7) . . . . ?
C133 C134 C135 C136 0.6(8) . . . . ?
C132 C131 C136 C135 -1.1(7) . . . . ?
P2 C131 C136 C135 -179.7(4) . . . . ?
C134 C135 C136 C131 0.1(7) . . . . ?
C203 C201 C202 C204 -2.5(6) . . . . ?
C203 C201 C202 P1 173.2(3) . . . . ?
C111 P1 C202 C201 117.5(3) . . . . ?
C101 P1 C202 C201 -133.9(3) . . . . ?
Pt2 P1 C202 C201 -6.2(4) . . . . ?
C111 P1 C202 C204 -67.0(4) . . . . ?
C101 P1 C202 C204 41.6(4) . . . . ?
Pt2 P1 C202 C204 169.3(3) . . . . ?
C202 C201 C203 C205 3.1(6) . . . . ?
C202 C201 C203 P2 -175.9(3) . . . . ?
C121 P2 C203 C205 93.9(4) . . . . ?
C131 P2 C203 C205 -14.6(4) . . . . ?
Pt1 P2 C203 C205 -141.7(3) . . . . ?
C121 P2 C203 C201 -87.2(3) . . . . ?
C131 P2 C203 C201 164.4(3) . . . . ?
Pt1 P2 C203 C201 37.2(3) . . . . ?
C201 C202 C204 C206 0.1(6) . . . . ?
P1 C202 C204 C206 -175.4(3) . . . . ?
C201 C203 C205 C206 -1.4(6) . . . . ?
P2 C203 C205 C206 177.6(3) . . . . ?
C202 C204 C206 C205 1.6(6) . . . . ?
C202 C204 C206 C207 -178.5(4) . . . . ?
C203 C205 C206 C204 -1.0(6) . . . . ?
C203 C205 C206 C207 179.1(4) . . . . ?
C204 C206 C207 C208 147.7(5) . . . . ?
C205 C206 C207 C208 -32.4(7) . . . . ?
C204 C206 C207 C209 -31.9(7) . . . . ?
C205 C206 C207 C209 148.0(5) . . . . ?
C209 C207 C208 C210 -0.5(8) . . . . ?
C206 C207 C208 C210 179.8(5) . . . . ?
C208 C207 C209 C211 -0.9(9) . . . . ?
C206 C207 C209 C211 178.7(6) . . . . ?
C207 C208 C210 N1 0.4(9) . . . . ?
C207 C209 C211 N1 2.7(11) . . . . ?
C208 C210 N1 C211 1.2(10) . . . . ?
C209 C211 N1 C210 -2.8(11) . . . . ?
