#------------------------------------------------------------------------------
#$Date: 2020-07-06 06:03:05 +0300 (Mon, 06 Jul 2020) $
#$Revision: 253887 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/43/7704389.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7704389
loop_
_publ_author_name
'Yang, Dongdong'
'Lu, Liping'
'Feng, Sisi'
'Zhu, Miaoli'
_publ_section_title
;
 First Ln-MOF as a trifunctional luminescent probe for the efficient
 sensing of aspartic acid, Fe³⁺ and DMSO.
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7514
_journal_page_last               7524
_journal_paper_doi               10.1039/d0dt00938e
_journal_volume                  49
_journal_year                    2020
_chemical_formula_sum            'C23 H17 Eu O15'
_chemical_formula_weight         685.33
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2019-09-29 deposited with the CCDC.	2020-05-12 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 112.0393(14)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.0093(6)
_cell_length_b                   16.7313(9)
_cell_length_c                   13.0739(8)
_cell_measurement_reflns_used    9747
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.21
_cell_measurement_theta_min      2.43
_cell_volume                     2232.2(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0618
_diffrn_reflns_av_unetI/netI     0.0670
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            28293
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.266
_diffrn_reflns_theta_min         2.435
_exptl_absorpt_coefficient_mu    2.896
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.039
_exptl_crystal_description       block
_exptl_crystal_F_000             1352
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.25
_exptl_transmission_factor_max   0.7457
_exptl_transmission_factor_min   0.5705
_refine_diff_density_max         1.253
_refine_diff_density_min         -0.902
_refine_diff_density_rms         0.168
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     354
_refine_ls_number_reflns         5505
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.0765
_refine_ls_R_factor_gt           0.0440
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0036P)²+10.9430P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0620
_refine_ls_wR_factor_ref         0.0700
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4002
_reflns_number_total             5505
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0dt00938e2.cif
_cod_data_source_block           eu+L79-4
_cod_depositor_comments
'Adding full bibliography for 7704388--7704392.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7704389
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.75756(2) 0.00537(2) 0.51404(2) 0.01431(7) Uani 1 1 d . . . . .
C1 C 0.5045(5) 0.1244(3) 0.5223(4) 0.0205(12) Uani 1 1 d . . . . .
C2 C 0.4773(4) 0.2084(3) 0.5487(4) 0.0179(10) Uani 1 1 d . . . . .
C3 C 0.3869(4) 0.2222(3) 0.5966(4) 0.0193(10) Uani 1 1 d . . . . .
H3 H 0.3404 0.1799 0.6103 0.023 Uiso 1 1 calc R U . . .
C4 C 0.3660(5) 0.2992(3) 0.6239(4) 0.0192(10) Uani 1 1 d . . . . .
C5 C 0.2716(5) 0.3168(3) 0.6770(4) 0.0252(12) Uani 1 1 d . . . . .
C6 C 0.4309(5) 0.3629(3) 0.6010(4) 0.0219(11) Uani 1 1 d . . . . .
H6 H 0.4161 0.4146 0.6199 0.026 Uiso 1 1 calc R U . . .
C7 C 0.5188(5) 0.3493(3) 0.5495(4) 0.0201(11) Uani 1 1 d . . . . .
C8 C 0.5448(4) 0.2718(3) 0.5250(4) 0.0196(11) Uani 1 1 d . . . . .
H8 H 0.6062 0.2625 0.4933 0.023 Uiso 1 1 calc R U . . .
C9 C 0.6460(5) 0.4085(3) 0.4573(4) 0.0184(10) Uani 1 1 d . . . . .
C10 C 0.5829(5) 0.4262(3) 0.3474(4) 0.0202(11) Uani 1 1 d . . . . .
H10 H 0.4946 0.4401 0.3193 0.024 Uiso 1 1 calc R U . . .
C11 C 0.6540(4) 0.4229(3) 0.2785(4) 0.0163(10) Uani 1 1 d . . . . .
C12 C 0.5876(5) 0.4463(3) 0.1598(4) 0.0191(10) Uani 1 1 d . . . . .
C13 C 0.7850(4) 0.4001(3) 0.3207(4) 0.0179(10) Uani 1 1 d . . . . .
H13 H 0.8316 0.3962 0.2745 0.021 Uiso 1 1 calc R U . . .
C14 C 0.8451(4) 0.3833(3) 0.4314(4) 0.0178(10) Uani 1 1 d . . . . .
C15 C 0.7773(4) 0.3876(3) 0.5019(4) 0.0196(11) Uani 1 1 d . . . . .
H15 H 0.8187 0.3769 0.5769 0.024 Uiso 1 1 calc R U . . .
C16 C 1.0474(4) 0.3497(3) 0.4174(4) 0.0194(11) Uani 1 1 d . . . . .
C17 C 1.0869(4) 0.4132(3) 0.3710(4) 0.0202(11) Uani 1 1 d . . . . .
H17 H 1.0636 0.4649 0.3821 0.024 Uiso 1 1 calc R U . . .
C18 C 1.1614(4) 0.4000(3) 0.3077(4) 0.0157(10) Uani 1 1 d . . . . .
C19 C 1.1907(4) 0.4684(3) 0.2453(4) 0.0184(10) Uani 1 1 d . . . . .
C20 C 1.2017(4) 0.3226(3) 0.2967(4) 0.0186(10) Uani 1 1 d . . . . .
H20 H 1.2531 0.3135 0.2554 0.022 Uiso 1 1 calc R U . . .
C21 C 1.1652(4) 0.2591(3) 0.3476(4) 0.0176(10) Uani 1 1 d . . . . .
C22 C 1.2087(5) 0.1758(3) 0.3405(4) 0.0208(11) Uani 1 1 d . . . . .
C29 C 1.0861(5) 0.2727(3) 0.4064(4) 0.0216(11) Uani 1 1 d . . . . .
H29 H 1.0589 0.2302 0.4385 0.026 Uiso 1 1 calc R U . . .
O1 O 0.6025(3) 0.11344(19) 0.4943(3) 0.0276(9) Uani 1 1 d . . . . .
O2 O 0.4316(3) 0.06982(19) 0.5314(3) 0.0247(8) Uani 1 1 d . . . . .
O3 O 0.1957(4) 0.2569(2) 0.6775(4) 0.0440(11) Uani 1 1 d . . . . .
H3A H 0.1460 0.2705 0.7080 0.066 Uiso 1 1 calc R U . . .
O4 O 0.2661(4) 0.3817(2) 0.7177(4) 0.0439(11) Uani 1 1 d . . . . .
O5 O 0.5783(3) 0.41625(19) 0.5280(3) 0.0219(8) Uani 1 1 d . . . . .
O6 O 0.4770(3) 0.4784(2) 0.1313(3) 0.0298(9) Uani 1 1 d . . . . .
O7 O 0.6459(3) 0.43320(19) 0.0938(3) 0.0233(8) Uani 1 1 d . . . . .
O8 O 0.9750(3) 0.3612(2) 0.4832(3) 0.0257(9) Uani 1 1 d . . . . .
O9 O 1.1761(3) 0.12048(19) 0.3874(3) 0.0242(8) Uani 1 1 d . . . . .
O10 O 1.2829(4) 0.1670(2) 0.2842(3) 0.0283(8) Uani 1 1 d . . . . .
H10A H 1.2985 0.1194 0.2805 0.042 Uiso 1 1 calc R U . . .
O11 O 1.2584(3) 0.4564(2) 0.1898(3) 0.0253(8) Uani 1 1 d . . . . .
O12 O 1.1404(3) 0.53543(19) 0.2526(3) 0.0235(8) Uani 1 1 d . . . . .
O13 O 0.8663(4) 0.1133(2) 0.4492(3) 0.0435(11) Uani 1 1 d . . . . .
H13A H 0.8463 0.1201 0.3771 0.065 Uiso 1 1 d R U . . .
H13B H 0.9247 0.1204 0.5000 0.065 Uiso 1 1 d R U . . .
O14 O 0.6295(3) 0.0314(2) 0.3195(3) 0.0281(8) Uani 1 1 d D . . . .
H14A H 0.6365 0.0595 0.2685 0.042 Uiso 1 1 d DR U . . .
H14B H 0.5503 0.0328 0.3050 0.042 Uiso 1 1 d DR U . . .
O15 O 0.0437(5) 0.2903(3) 0.7827(4) 0.0775(17) Uani 1 1 d . . . . .
H15A H -0.0244 0.2641 0.7568 0.116 Uiso 1 1 d R U . . .
H15B H 0.0463 0.3088 0.8417 0.116 Uiso 1 1 d R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Eu1 O6 147.14(12) 3_656 4_666 ?
O2 Eu1 O11 94.06(12) 3_656 4_566 ?
O6 Eu1 O11 72.98(11) 4_666 4_566 ?
O2 Eu1 O7 97.52(11) 3_656 2_645 ?
O6 Eu1 O7 82.34(11) 4_666 2_645 ?
O11 Eu1 O7 149.76(12) 4_566 2_645 ?
O2 Eu1 O9 74.21(11) 3_656 3_756 ?
O6 Eu1 O9 73.88(12) 4_666 3_756 ?
O11 Eu1 O9 80.19(11) 4_566 3_756 ?
O7 Eu1 O9 76.30(11) 2_645 3_756 ?
O2 Eu1 O1 81.28(12) 3_656 . ?
O6 Eu1 O1 119.60(12) 4_666 . ?
O11 Eu1 O1 69.62(12) 4_566 . ?
O7 Eu1 O1 139.76(12) 2_645 . ?
O9 Eu1 O1 139.35(11) 3_756 . ?
O2 Eu1 O14 73.55(12) 3_656 . ?
O6 Eu1 O14 135.45(11) 4_666 . ?
O11 Eu1 O14 138.54(11) 4_566 . ?
O7 Eu1 O14 71.69(11) 2_645 . ?
O9 Eu1 O14 130.35(11) 3_756 . ?
O1 Eu1 O14 69.44(12) . . ?
O2 Eu1 O13 144.17(13) 3_656 . ?
O6 Eu1 O13 68.19(12) 4_666 . ?
O11 Eu1 O13 107.83(13) 4_566 . ?
O7 Eu1 O13 77.75(13) 2_645 . ?
O9 Eu1 O13 136.22(12) 3_756 . ?
O1 Eu1 O13 80.36(12) . . ?
O14 Eu1 O13 71.26(12) . . ?
O2 Eu1 H13B 159.4 3_656 . ?
O6 Eu1 H13B 53.4 4_666 . ?
O11 Eu1 H13B 96.8 4_566 . ?
O7 Eu1 H13B 81.7 2_645 . ?
O9 Eu1 H13B 124.9 3_756 . ?
O1 Eu1 H13B 86.1 . . ?
O14 Eu1 H13B 86.8 . . ?
O13 Eu1 H13B 15.6 . . ?
O2 C1 O1 124.4(4) . . ?
O2 C1 C2 118.1(4) . . ?
O1 C1 C2 117.5(4) . . ?
C3 C2 C8 120.5(4) . . ?
C3 C2 C1 120.0(4) . . ?
C8 C2 C1 119.5(4) . . ?
C4 C3 C2 119.5(4) . . ?
C4 C3 H3 120.2 . . ?
C2 C3 H3 120.2 . . ?
C6 C4 C3 121.1(4) . . ?
C6 C4 C5 117.4(4) . . ?
C3 C4 C5 121.5(4) . . ?
O4 C5 O3 122.9(5) . . ?
O4 C5 C4 122.7(5) . . ?
O3 C5 C4 114.3(4) . . ?
C4 C6 C7 119.4(4) . . ?
C4 C6 H6 120.3 . . ?
C7 C6 H6 120.3 . . ?
O5 C7 C6 115.8(4) . . ?
O5 C7 C8 123.8(4) . . ?
C6 C7 C8 120.4(4) . . ?
C7 C8 C2 119.1(4) . . ?
C7 C8 H8 120.5 . . ?
C2 C8 H8 120.5 . . ?
C10 C9 C15 122.3(4) . . ?
C10 C9 O5 119.2(4) . . ?
C15 C9 O5 118.5(4) . . ?
C9 C10 C11 118.7(4) . . ?
C9 C10 H10 120.7 . . ?
C11 C10 H10 120.7 . . ?
C13 C11 C10 120.2(4) . . ?
C13 C11 C12 120.9(4) . . ?
C10 C11 C12 118.9(4) . . ?
O6 C12 O7 123.6(4) . . ?
O6 C12 C11 117.5(4) . . ?
O7 C12 C11 118.9(4) . . ?
C14 C13 C11 119.5(4) . . ?
C14 C13 H13 120.3 . . ?
C11 C13 H13 120.3 . . ?
C13 C14 O8 124.8(4) . . ?
C13 C14 C15 121.4(4) . . ?
O8 C14 C15 113.8(4) . . ?
C9 C15 C14 118.0(4) . . ?
C9 C15 H15 121.0 . . ?
C14 C15 H15 121.0 . . ?
C17 C16 C29 121.0(4) . . ?
C17 C16 O8 121.1(4) . . ?
C29 C16 O8 117.7(4) . . ?
C16 C17 C18 119.9(4) . . ?
C16 C17 H17 120.1 . . ?
C18 C17 H17 120.1 . . ?
C17 C18 C20 119.5(4) . . ?
C17 C18 C19 119.9(4) . . ?
C20 C18 C19 120.5(4) . . ?
O11 C19 O12 124.2(4) . . ?
O11 C19 C18 119.6(4) . . ?
O12 C19 C18 116.2(4) . . ?
C21 C20 C18 120.0(4) . . ?
C21 C20 H20 120.0 . . ?
C18 C20 H20 120.0 . . ?
C29 C21 C20 119.8(4) . . ?
C29 C21 C22 118.2(4) . . ?
C20 C21 C22 122.0(4) . . ?
O9 C22 O10 124.0(4) . . ?
O9 C22 C21 120.7(4) . . ?
O10 C22 C21 115.3(4) . . ?
C21 C29 C16 119.6(4) . . ?
C21 C29 H29 120.2 . . ?
C16 C29 H29 120.2 . . ?
C1 O1 Eu1 135.3(3) . . ?
C1 O2 Eu1 157.1(3) . 3_656 ?
C5 O3 H3A 109.5 . . ?
C7 O5 C9 118.2(3) . . ?
C12 O6 Eu1 153.3(3) . 4_565 ?
C12 O7 Eu1 139.7(3) . 2_655 ?
C14 O8 C16 117.6(4) . . ?
C22 O9 Eu1 145.6(3) . 3_756 ?
C22 O10 H10A 109.5 . . ?
C19 O11 Eu1 137.5(3) . 4_665 ?
Eu1 O13 H13A 119.6 . . ?
Eu1 O13 H13B 100.2 . . ?
H13A O13 H13B 135.6 . . ?
Eu1 O14 H14A 137.3 . . ?
Eu1 O14 H14B 113.3 . . ?
H14A O14 H14B 101.9 . . ?
H15A O15 H15B 107.1 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O2 2.312(3) 3_656 ?
Eu1 O6 2.341(3) 4_666 ?
Eu1 O11 2.382(3) 4_566 ?
Eu1 O7 2.388(3) 2_645 ?
Eu1 O9 2.433(3) 3_756 ?
Eu1 O1 2.433(3) . ?
Eu1 O14 2.441(3) . ?
Eu1 O13 2.484(4) . ?
Eu1 H13B 2.7159 . ?
C1 O2 1.249(5) . ?
C1 O1 1.276(5) . ?
C1 C2 1.504(6) . ?
C2 C3 1.379(6) . ?
C2 C8 1.396(6) . ?
C3 C4 1.379(6) . ?
C3 H3 0.9300 . ?
C4 C6 1.377(6) . ?
C4 C5 1.481(6) . ?
C5 O4 1.219(6) . ?
C5 O3 1.307(6) . ?
C6 C7 1.390(6) . ?
C6 H6 0.9300 . ?
C7 O5 1.379(5) . ?
C7 C8 1.390(6) . ?
C8 H8 0.9300 . ?
C9 C10 1.373(7) . ?
C9 C15 1.385(6) . ?
C9 O5 1.395(5) . ?
C10 C11 1.398(6) . ?
C10 H10 0.9300 . ?
C11 C13 1.390(6) . ?
C11 C12 1.499(6) . ?
C12 O6 1.252(5) . ?
C12 O7 1.273(5) . ?
C13 C14 1.376(6) . ?
C13 H13 0.9300 . ?
C14 O8 1.383(5) . ?
C14 C15 1.389(6) . ?
C15 H15 0.9300 . ?
C16 C17 1.372(6) . ?
C16 C29 1.381(7) . ?
C16 O8 1.388(5) . ?
C17 C18 1.384(6) . ?
C17 H17 0.9300 . ?
C18 C20 1.393(6) . ?
C18 C19 1.509(6) . ?
C19 O11 1.236(5) . ?
C19 O12 1.271(5) . ?
C20 C21 1.390(6) . ?
C20 H20 0.9300 . ?
C21 C29 1.381(6) . ?
C21 C22 1.489(6) . ?
C22 O9 1.236(5) . ?
C22 O10 1.297(6) . ?
C29 H29 0.9300 . ?
O2 Eu1 2.312(3) 3_656 ?
O3 H3A 0.8200 . ?
O6 Eu1 2.341(3) 4_565 ?
O7 Eu1 2.388(3) 2_655 ?
O9 Eu1 2.433(3) 3_756 ?
O10 H10A 0.8200 . ?
O11 Eu1 2.382(3) 4_665 ?
O13 H13A 0.8910 . ?
O13 H13B 0.7407 . ?
O14 H14A 0.8432 . ?
O14 H14B 0.8200 . ?
O15 H15A 0.8231 . ?
O15 H15B 0.8210 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 C1 C2 C3 9.2(7) . . . . ?
O1 C1 C2 C3 -169.4(4) . . . . ?
O2 C1 C2 C8 -171.2(4) . . . . ?
O1 C1 C2 C8 10.2(7) . . . . ?
C8 C2 C3 C4 -1.8(7) . . . . ?
C1 C2 C3 C4 177.8(4) . . . . ?
C2 C3 C4 C6 2.1(7) . . . . ?
C2 C3 C4 C5 -179.0(4) . . . . ?
C6 C4 C5 O4 -13.0(8) . . . . ?
C3 C4 C5 O4 168.1(5) . . . . ?
C6 C4 C5 O3 167.6(5) . . . . ?
C3 C4 C5 O3 -11.3(7) . . . . ?
C3 C4 C6 C7 0.0(7) . . . . ?
C5 C4 C6 C7 -178.9(5) . . . . ?
C4 C6 C7 O5 179.1(4) . . . . ?
C4 C6 C7 C8 -2.4(7) . . . . ?
O5 C7 C8 C2 -178.9(4) . . . . ?
C6 C7 C8 C2 2.7(7) . . . . ?
C3 C2 C8 C7 -0.5(7) . . . . ?
C1 C2 C8 C7 179.9(4) . . . . ?
C15 C9 C10 C11 0.0(7) . . . . ?
O5 C9 C10 C11 176.1(4) . . . . ?
C9 C10 C11 C13 1.7(7) . . . . ?
C9 C10 C11 C12 -176.8(4) . . . . ?
C13 C11 C12 O6 -168.7(4) . . . . ?
C10 C11 C12 O6 9.8(6) . . . . ?
C13 C11 C12 O7 10.9(7) . . . . ?
C10 C11 C12 O7 -170.6(4) . . . . ?
C10 C11 C13 C14 -2.1(7) . . . . ?
C12 C11 C13 C14 176.4(4) . . . . ?
C11 C13 C14 O8 -179.0(4) . . . . ?
C11 C13 C14 C15 0.8(7) . . . . ?
C10 C9 C15 C14 -1.3(7) . . . . ?
O5 C9 C15 C14 -177.4(4) . . . . ?
C13 C14 C15 C9 0.8(7) . . . . ?
O8 C14 C15 C9 -179.3(4) . . . . ?
C29 C16 C17 C18 3.1(7) . . . . ?
O8 C16 C17 C18 178.6(4) . . . . ?
C16 C17 C18 C20 -3.5(7) . . . . ?
C16 C17 C18 C19 172.5(4) . . . . ?
C17 C18 C19 O11 179.2(4) . . . . ?
C20 C18 C19 O11 -4.8(7) . . . . ?
C17 C18 C19 O12 -1.9(6) . . . . ?
C20 C18 C19 O12 174.0(4) . . . . ?
C17 C18 C20 C21 1.1(7) . . . . ?
C19 C18 C20 C21 -174.9(4) . . . . ?
C18 C20 C21 C29 1.7(7) . . . . ?
C18 C20 C21 C22 -178.5(4) . . . . ?
C29 C21 C22 O9 -1.0(7) . . . . ?
C20 C21 C22 O9 179.2(4) . . . . ?
C29 C21 C22 O10 -179.9(4) . . . . ?
C20 C21 C22 O10 0.3(7) . . . . ?
C20 C21 C29 C16 -2.2(7) . . . . ?
C22 C21 C29 C16 178.0(4) . . . . ?
C17 C16 C29 C21 -0.2(7) . . . . ?
O8 C16 C29 C21 -175.9(4) . . . . ?
O2 C1 O1 Eu1 -29.6(8) . . . . ?
C2 C1 O1 Eu1 148.9(3) . . . . ?
O1 C1 O2 Eu1 -109.2(8) . . . 3_656 ?
C2 C1 O2 Eu1 72.3(9) . . . 3_656 ?
C6 C7 O5 C9 -167.2(4) . . . . ?
C8 C7 O5 C9 14.4(7) . . . . ?
C10 C9 O5 C7 94.9(5) . . . . ?
C15 C9 O5 C7 -88.8(5) . . . . ?
O7 C12 O6 Eu1 46.1(10) . . . 4_565 ?
C11 C12 O6 Eu1 -134.3(6) . . . 4_565 ?
O6 C12 O7 Eu1 66.3(7) . . . 2_655 ?
C11 C12 O7 Eu1 -113.2(5) . . . 2_655 ?
C13 C14 O8 C16 -4.8(7) . . . . ?
C15 C14 O8 C16 175.4(4) . . . . ?
C17 C16 O8 C14 73.0(6) . . . . ?
C29 C16 O8 C14 -111.4(5) . . . . ?
O10 C22 O9 Eu1 34.2(9) . . . 3_756 ?
C21 C22 O9 Eu1 -144.7(4) . . . 3_756 ?
O12 C19 O11 Eu1 -40.6(7) . . . 4_665 ?
C18 C19 O11 Eu1 138.1(4) . . . 4_665 ?
