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#$Date: 2020-09-06 12:35:15 +0300 (Sun, 06 Sep 2020) $
#$Revision: 256075 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/50/7705070.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7705070
loop_
_publ_author_name
'Adcock, Alyssa K.'
'Ayscue, 3rd, R Lee'
'Breuer, Leticia M.'
'Verwiel, Chloe P.'
'Marwitz, Alexander C.'
'Bertke, Jeffery A.'
'Vallet, Valérie'
'Réal, Florent'
'Knope, Karah E.'
_publ_section_title
;
 Synthesis and photoluminescence of three bismuth(III)-organic compounds
 bearing heterocyclic N-donor ligands.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11756
_journal_page_last               11771
_journal_paper_doi               10.1039/d0dt02360d
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C24 H16 Bi Cl3 N4'
_chemical_formula_sum            'C24 H16 Bi Cl3 N4'
_chemical_formula_weight         675.74
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-05-03 deposited with the CCDC.	2020-08-06 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 109.3280(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.6115(3)
_cell_length_b                   31.7985(10)
_cell_length_c                   7.5977(2)
_cell_measurement_reflns_used    9930
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      56.577
_cell_measurement_theta_min      4.670
_cell_volume                     2191.22(11)
_computing_cell_refinement       'SAINT V8.37A (Bruker, 2005)'
_computing_data_collection       'APEX3 V2016.5-0 (Bruker, 2016)'
_computing_data_reduction
; 
SAINT V8.37A, XPREP v2014/2, SADABS V2016/2 (Bruker, 2016) 
;
_computing_molecular_graphics    'SHELXLE v817 (Hubschle, 2011)'
_computing_publication_material  'XCIF V2014-2 (Bruker, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELX-2014-5 (Sheldrick, 2015)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker D8 Quest/Photon 100'
_diffrn_measurement_method       'profile data from φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0224
_diffrn_reflns_av_unetI/netI     0.0128
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       42
_diffrn_reflns_limit_k_min       -42
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            41900
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.312
_diffrn_reflns_theta_min         2.562
_diffrn_source                   'microfocus sealed tube'
_exptl_absorpt_coefficient_mu    8.433
_exptl_absorpt_correction_T_max  0.66848
_exptl_absorpt_correction_T_min  0.30142
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS V2016/2 (Bruker, 2016)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.048
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'thick needles'
_exptl_crystal_F_000             1288
_exptl_crystal_preparation       Luminescent
_exptl_crystal_size_max          0.133
_exptl_crystal_size_mid          0.072
_exptl_crystal_size_min          0.042
_refine_diff_density_max         0.731
_refine_diff_density_min         -1.328
_refine_diff_density_rms         0.083
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.168
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     289
_refine_ls_number_reflns         5443
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.168
_refine_ls_R_factor_all          0.0173
_refine_ls_R_factor_gt           0.0152
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0090P)²+2.7525P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0313
_refine_ls_wR_factor_ref         0.0317
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5122
_reflns_number_total             5443
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0dt02360d2.cif
_cod_data_source_block           p21onc
_cod_depositor_comments
'Adding full bibliography for 7705069--7705071.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7705070
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.400
_shelx_estimated_absorpt_t_max   0.718
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Bi1 Bi 0.83472(2) 0.37383(2) 0.71963(2) 0.00869(2) Uani 1 1 d . . . . .
Cl1 Cl 0.70419(6) 0.41045(2) 0.95314(7) 0.01381(10) Uani 1 1 d . . . . .
Cl2 Cl 1.09807(6) 0.36215(2) 0.97937(8) 0.01721(11) Uani 1 1 d . . . . .
Cl3 Cl 0.95954(6) 0.36822(2) 0.46500(7) 0.01529(10) Uani 1 1 d . . . . .
N11 N 0.57973(19) 0.32684(6) 0.6536(3) 0.0136(4) Uani 1 1 d . . . . .
N12 N 0.84402(19) 0.29010(5) 0.6816(3) 0.0123(3) Uani 1 1 d . . . . .
C11 C 0.4521(2) 0.34437(7) 0.6433(3) 0.0171(4) Uani 1 1 d . . . . .
H11 H 0.4495 0.3739 0.6605 0.021 Uiso 1 1 calc R U . . .
C12 C 0.3208(2) 0.32160(8) 0.6085(4) 0.0205(5) Uani 1 1 d . . . . .
H12 H 0.2313 0.3355 0.6001 0.025 Uiso 1 1 calc R U . . .
C13 C 0.3245(2) 0.27892(8) 0.5869(3) 0.0190(5) Uani 1 1 d . . . . .
H13 H 0.2367 0.2629 0.5611 0.023 Uiso 1 1 calc R U . . .
C14 C 0.4584(2) 0.25889(7) 0.6027(3) 0.0141(4) Uani 1 1 d . . . . .
C15 C 0.5843(2) 0.28443(6) 0.6347(3) 0.0119(4) Uani 1 1 d . . . . .
C16 C 0.4701(3) 0.21406(7) 0.5864(3) 0.0181(5) Uani 1 1 d . . . . .
H16 H 0.3854 0.1969 0.5667 0.022 Uiso 1 1 calc R U . . .
C17 C 0.5999(3) 0.19611(7) 0.5988(3) 0.0179(5) Uani 1 1 d . . . . .
H17 H 0.6053 0.1665 0.5871 0.021 Uiso 1 1 calc R U . . .
C18 C 0.7301(2) 0.22111(6) 0.6293(3) 0.0129(4) Uani 1 1 d . . . . .
C19 C 0.7237(2) 0.26524(6) 0.6489(3) 0.0106(4) Uani 1 1 d . . . . .
C110 C 0.8664(3) 0.20319(7) 0.6406(3) 0.0146(4) Uani 1 1 d . . . . .
H110 H 0.8749 0.1737 0.6262 0.018 Uiso 1 1 calc R U . . .
C111 C 0.9871(3) 0.22884(7) 0.6726(3) 0.0164(4) Uani 1 1 d . . . . .
H111 H 1.0802 0.2173 0.6805 0.020 Uiso 1 1 calc R U . . .
C112 C 0.9717(2) 0.27206(7) 0.6933(3) 0.0153(4) Uani 1 1 d . . . . .
H112 H 1.0564 0.2894 0.7169 0.018 Uiso 1 1 calc R U . . .
N21 N 0.91104(19) 0.44799(5) 0.7124(2) 0.0097(3) Uani 1 1 d . . . . .
N22 N 0.65377(19) 0.41758(6) 0.4623(2) 0.0119(3) Uani 1 1 d . . . . .
C21 C 1.0380(2) 0.46241(7) 0.8278(3) 0.0127(4) Uani 1 1 d . . . . .
H21 H 1.1040 0.4432 0.9095 0.015 Uiso 1 1 calc R U . . .
C22 C 1.0786(2) 0.50481(7) 0.8340(3) 0.0141(4) Uani 1 1 d . . . . .
H22 H 1.1709 0.5139 0.9178 0.017 Uiso 1 1 calc R U . . .
C23 C 0.9843(2) 0.53302(7) 0.7184(3) 0.0138(4) Uani 1 1 d . . . . .
H23 H 1.0091 0.5620 0.7234 0.017 Uiso 1 1 calc R U . . .
C24 C 0.8499(2) 0.51854(6) 0.5920(3) 0.0118(4) Uani 1 1 d . . . . .
C25 C 0.8167(2) 0.47535(6) 0.5927(3) 0.0100(4) Uani 1 1 d . . . . .
C26 C 0.7484(2) 0.54607(7) 0.4617(3) 0.0162(4) Uani 1 1 d . . . . .
H26 H 0.7698 0.5753 0.4634 0.019 Uiso 1 1 calc R U . . .
C27 C 0.6227(2) 0.53108(7) 0.3365(3) 0.0169(4) Uani 1 1 d . . . . .
H27 H 0.5571 0.5498 0.2513 0.020 Uiso 1 1 calc R U . . .
C28 C 0.5878(2) 0.48718(7) 0.3312(3) 0.0138(4) Uani 1 1 d . . . . .
C29 C 0.6827(2) 0.45947(6) 0.4611(3) 0.0112(4) Uani 1 1 d . . . . .
C210 C 0.4607(2) 0.47006(7) 0.1990(3) 0.0181(5) Uani 1 1 d . . . . .
H210 H 0.3932 0.4878 0.1107 0.022 Uiso 1 1 calc R U . . .
C211 C 0.4350(2) 0.42778(8) 0.1982(3) 0.0180(5) Uani 1 1 d . . . . .
H211 H 0.3511 0.4158 0.1078 0.022 Uiso 1 1 calc R U . . .
C212 C 0.5343(2) 0.40250(7) 0.3328(3) 0.0148(4) Uani 1 1 d . . . . .
H212 H 0.5155 0.3732 0.3317 0.018 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N21 Bi1 N22 66.18(6) . . ?
N21 Bi1 Cl3 80.54(4) . . ?
N22 Bi1 Cl3 80.37(4) . . ?
N21 Bi1 Cl2 86.19(4) . . ?
N22 Bi1 Cl2 151.58(4) . . ?
Cl3 Bi1 Cl2 88.990(18) . . ?
N21 Bi1 N12 157.26(6) . . ?
N22 Bi1 N12 119.76(6) . . ?
Cl3 Bi1 N12 79.15(4) . . ?
Cl2 Bi1 N12 83.36(4) . . ?
N21 Bi1 Cl1 79.19(4) . . ?
N22 Bi1 Cl1 85.57(4) . . ?
Cl3 Bi1 Cl1 158.721(16) . . ?
Cl2 Bi1 Cl1 96.055(17) . . ?
N12 Bi1 Cl1 121.92(4) . . ?
N21 Bi1 N11 139.51(5) . . ?
N22 Bi1 N11 79.50(5) . . ?
Cl3 Bi1 N11 115.27(4) . . ?
Cl2 Bi1 N11 128.61(4) . . ?
N12 Bi1 N11 60.28(5) . . ?
Cl1 Bi1 N11 77.29(4) . . ?
C11 N11 C15 118.22(19) . . ?
C11 N11 Bi1 121.97(14) . . ?
C15 N11 Bi1 119.79(13) . . ?
C112 N12 C19 118.24(18) . . ?
C112 N12 Bi1 118.91(14) . . ?
C19 N12 Bi1 122.85(13) . . ?
N11 C11 C12 123.4(2) . . ?
N11 C11 H11 118.3 . . ?
C12 C11 H11 118.3 . . ?
C13 C12 C11 118.5(2) . . ?
C13 C12 H12 120.7 . . ?
C11 C12 H12 120.7 . . ?
C12 C13 C14 119.9(2) . . ?
C12 C13 H13 120.0 . . ?
C14 C13 H13 120.0 . . ?
C13 C14 C15 117.6(2) . . ?
C13 C14 C16 122.5(2) . . ?
C15 C14 C16 119.9(2) . . ?
N11 C15 C14 122.27(19) . . ?
N11 C15 C19 118.26(18) . . ?
C14 C15 C19 119.47(19) . . ?
C17 C16 C14 120.8(2) . . ?
C17 C16 H16 119.6 . . ?
C14 C16 H16 119.6 . . ?
C16 C17 C18 121.0(2) . . ?
C16 C17 H17 119.5 . . ?
C18 C17 H17 119.5 . . ?
C110 C18 C19 117.88(19) . . ?
C110 C18 C17 122.1(2) . . ?
C19 C18 C17 120.1(2) . . ?
N12 C19 C18 122.33(19) . . ?
N12 C19 C15 118.82(18) . . ?
C18 C19 C15 118.86(19) . . ?
C111 C110 C18 119.11(19) . . ?
C111 C110 H110 120.4 . . ?
C18 C110 H110 120.4 . . ?
C110 C111 C112 119.3(2) . . ?
C110 C111 H111 120.3 . . ?
C112 C111 H111 120.3 . . ?
N12 C112 C111 123.1(2) . . ?
N12 C112 H112 118.4 . . ?
C111 C112 H112 118.4 . . ?
C21 N21 C25 118.89(18) . . ?
C21 N21 Bi1 121.96(13) . . ?
C25 N21 Bi1 119.07(13) . . ?
C212 N22 C29 118.44(18) . . ?
C212 N22 Bi1 124.88(14) . . ?
C29 N22 Bi1 116.67(13) . . ?
N21 C21 C22 122.72(19) . . ?
N21 C21 H21 118.6 . . ?
C22 C21 H21 118.6 . . ?
C23 C22 C21 119.5(2) . . ?
C23 C22 H22 120.3 . . ?
C21 C22 H22 120.3 . . ?
C22 C23 C24 119.15(19) . . ?
C22 C23 H23 120.4 . . ?
C24 C23 H23 120.4 . . ?
C23 C24 C25 118.25(19) . . ?
C23 C24 C26 122.12(19) . . ?
C25 C24 C26 119.62(19) . . ?
N21 C25 C24 121.50(19) . . ?
N21 C25 C29 119.02(18) . . ?
C24 C25 C29 119.46(18) . . ?
C27 C26 C24 121.0(2) . . ?
C27 C26 H26 119.5 . . ?
C24 C26 H26 119.5 . . ?
C26 C27 C28 120.6(2) . . ?
C26 C27 H27 119.7 . . ?
C28 C27 H27 119.7 . . ?
C210 C28 C29 117.7(2) . . ?
C210 C28 C27 122.4(2) . . ?
C29 C28 C27 119.8(2) . . ?
N22 C29 C28 122.00(19) . . ?
N22 C29 C25 118.54(18) . . ?
C28 C29 C25 119.43(19) . . ?
C211 C210 C28 119.7(2) . . ?
C211 C210 H210 120.1 . . ?
C28 C210 H210 120.1 . . ?
C210 C211 C212 118.9(2) . . ?
C210 C211 H211 120.5 . . ?
C212 C211 H211 120.5 . . ?
N22 C212 C211 123.1(2) . . ?
N22 C212 H212 118.4 . . ?
C211 C212 H212 118.4 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Bi1 N21 2.4756(17) . ?
Bi1 N22 2.5559(18) . ?
Bi1 Cl3 2.5981(5) . ?
Bi1 Cl2 2.6707(5) . ?
Bi1 N12 2.6827(18) . ?
Bi1 Cl1 2.7480(5) . ?
Bi1 N11 2.7707(18) . ?
N11 C11 1.326(3) . ?
N11 C15 1.358(3) . ?
N12 C112 1.331(3) . ?
N12 C19 1.354(3) . ?
C11 C12 1.402(3) . ?
C11 H11 0.9500 . ?
C12 C13 1.369(3) . ?
C12 H12 0.9500 . ?
C13 C14 1.405(3) . ?
C13 H13 0.9500 . ?
C14 C15 1.410(3) . ?
C14 C16 1.438(3) . ?
C15 C19 1.444(3) . ?
C16 C17 1.346(3) . ?
C16 H16 0.9500 . ?
C17 C18 1.435(3) . ?
C17 H17 0.9500 . ?
C18 C110 1.405(3) . ?
C18 C19 1.414(3) . ?
C110 C111 1.373(3) . ?
C110 H110 0.9500 . ?
C111 C112 1.397(3) . ?
C111 H111 0.9500 . ?
C112 H112 0.9500 . ?
N21 C21 1.326(3) . ?
N21 C25 1.364(3) . ?
N22 C212 1.330(3) . ?
N22 C29 1.361(3) . ?
C21 C22 1.400(3) . ?
C21 H21 0.9500 . ?
C22 C23 1.367(3) . ?
C22 H22 0.9500 . ?
C23 C24 1.408(3) . ?
C23 H23 0.9500 . ?
C24 C25 1.410(3) . ?
C24 C26 1.434(3) . ?
C25 C29 1.436(3) . ?
C26 C27 1.353(3) . ?
C26 H26 0.9500 . ?
C27 C28 1.433(3) . ?
C27 H27 0.9500 . ?
C28 C210 1.409(3) . ?
C28 C29 1.410(3) . ?
C210 C211 1.366(3) . ?
C210 H210 0.9500 . ?
C211 C212 1.399(3) . ?
C211 H211 0.9500 . ?
C212 H212 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C15 N11 C11 C12 -2.0(3) . . . . ?
Bi1 N11 C11 C12 179.42(18) . . . . ?
N11 C11 C12 C13 1.1(4) . . . . ?
C11 C12 C13 C14 1.0(4) . . . . ?
C12 C13 C14 C15 -2.1(3) . . . . ?
C12 C13 C14 C16 178.3(2) . . . . ?
C11 N11 C15 C14 0.8(3) . . . . ?
Bi1 N11 C15 C14 179.38(15) . . . . ?
C11 N11 C15 C19 -179.0(2) . . . . ?
Bi1 N11 C15 C19 -0.4(3) . . . . ?
C13 C14 C15 N11 1.3(3) . . . . ?
C16 C14 C15 N11 -179.1(2) . . . . ?
C13 C14 C15 C19 -179.0(2) . . . . ?
C16 C14 C15 C19 0.6(3) . . . . ?
C13 C14 C16 C17 178.7(2) . . . . ?
C15 C14 C16 C17 -0.9(3) . . . . ?
C14 C16 C17 C18 0.3(4) . . . . ?
C16 C17 C18 C110 -179.2(2) . . . . ?
C16 C17 C18 C19 0.7(3) . . . . ?
C112 N12 C19 C18 0.8(3) . . . . ?
Bi1 N12 C19 C18 -179.93(15) . . . . ?
C112 N12 C19 C15 -179.61(19) . . . . ?
Bi1 N12 C19 C15 -0.3(3) . . . . ?
C110 C18 C19 N12 -1.4(3) . . . . ?
C17 C18 C19 N12 178.6(2) . . . . ?
C110 C18 C19 C15 178.97(19) . . . . ?
C17 C18 C19 C15 -1.0(3) . . . . ?
N11 C15 C19 N12 0.5(3) . . . . ?
C14 C15 C19 N12 -179.29(19) . . . . ?
N11 C15 C19 C18 -179.93(19) . . . . ?
C14 C15 C19 C18 0.3(3) . . . . ?
C19 C18 C110 C111 1.0(3) . . . . ?
C17 C18 C110 C111 -179.1(2) . . . . ?
C18 C110 C111 C112 0.1(3) . . . . ?
C19 N12 C112 C111 0.3(3) . . . . ?
Bi1 N12 C112 C111 -178.98(17) . . . . ?
C110 C111 C112 N12 -0.8(4) . . . . ?
C25 N21 C21 C22 1.0(3) . . . . ?
Bi1 N21 C21 C22 -175.71(16) . . . . ?
N21 C21 C22 C23 0.6(3) . . . . ?
C21 C22 C23 C24 -1.7(3) . . . . ?
C22 C23 C24 C25 1.4(3) . . . . ?
C22 C23 C24 C26 -177.5(2) . . . . ?
C21 N21 C25 C24 -1.3(3) . . . . ?
Bi1 N21 C25 C24 175.45(15) . . . . ?
C21 N21 C25 C29 176.80(19) . . . . ?
Bi1 N21 C25 C29 -6.4(2) . . . . ?
C23 C24 C25 N21 0.2(3) . . . . ?
C26 C24 C25 N21 179.04(19) . . . . ?
C23 C24 C25 C29 -177.94(19) . . . . ?
C26 C24 C25 C29 0.9(3) . . . . ?
C23 C24 C26 C27 177.3(2) . . . . ?
C25 C24 C26 C27 -1.5(3) . . . . ?
C24 C26 C27 C28 0.1(3) . . . . ?
C26 C27 C28 C210 -177.8(2) . . . . ?
C26 C27 C28 C29 1.9(3) . . . . ?
C212 N22 C29 C28 2.0(3) . . . . ?
Bi1 N22 C29 C28 -177.26(15) . . . . ?
C212 N22 C29 C25 -175.87(19) . . . . ?
Bi1 N22 C29 C25 4.9(2) . . . . ?
C210 C28 C29 N22 -0.6(3) . . . . ?
C27 C28 C29 N22 179.7(2) . . . . ?
C210 C28 C29 C25 177.2(2) . . . . ?
C27 C28 C29 C25 -2.5(3) . . . . ?
N21 C25 C29 N22 0.8(3) . . . . ?
C24 C25 C29 N22 179.00(19) . . . . ?
N21 C25 C29 C28 -177.08(19) . . . . ?
C24 C25 C29 C28 1.1(3) . . . . ?
C29 C28 C210 C211 -1.2(3) . . . . ?
C27 C28 C210 C211 178.5(2) . . . . ?
C28 C210 C211 C212 1.6(3) . . . . ?
C29 N22 C212 C211 -1.6(3) . . . . ?
Bi1 N22 C212 C211 177.61(16) . . . . ?
C210 C211 C212 N22 -0.2(3) . . . . ?
