#------------------------------------------------------------------------------
#$Date: 2020-10-06 12:02:34 +0300 (Tue, 06 Oct 2020) $
#$Revision: 257564 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/52/7705208.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7705208
loop_
_publ_author_name
'Siewert, Jan-Erik'
'Schumann, André'
'Fischer, Malte'
'Schmidt, Christoph'
'Taeufer, Tobias'
'Hering-Junghans, Christian'
_publ_section_title
;
 Terphenyl(bisamino)phosphines: electron-rich ligands for gold-catalysis.
;
_journal_issue                   35
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12354
_journal_page_last               12364
_journal_paper_doi               10.1039/d0dt02435j
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C56 H74 Ag2 Cl2 N4 P2'
_chemical_formula_sum            'C56 H74 Ag2 Cl2 N4 P2'
_chemical_formula_weight         1151.77
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-07-07 deposited with the CCDC.	2020-08-18 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 98.4356(16)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   9.7963(9)
_cell_length_b                   14.5920(14)
_cell_length_c                   19.4635(18)
_cell_measurement_reflns_used    9917
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      29.58
_cell_measurement_theta_min      2.52
_cell_volume                     2752.2(4)
_computing_cell_refinement       'SAINT (Bruker, 2013)'
_computing_data_collection       'APEX2 (Bruker, 2014)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'ORTEP-3v2.01 (Farrugia, 1997)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0441
_diffrn_reflns_av_unetI/netI     0.0305
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            56649
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.560
_diffrn_reflns_theta_min         1.751
_exptl_absorpt_coefficient_mu    0.906
_exptl_absorpt_correction_T_max  0.961
_exptl_absorpt_correction_T_min  0.807
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2014/5'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.390
_exptl_crystal_description       plate
_exptl_crystal_F_000             1192
_exptl_crystal_size_max          0.247
_exptl_crystal_size_mid          0.126
_exptl_crystal_size_min          0.044
_refine_diff_density_max         1.039
_refine_diff_density_min         -0.969
_refine_diff_density_rms         0.072
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     308
_refine_ls_number_reflns         8407
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.0554
_refine_ls_R_factor_gt           0.0349
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0424P)²+1.3912P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0830
_refine_ls_wR_factor_ref         0.0941
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6269
_reflns_number_total             8407
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0dt02435j2.cif
_cod_data_source_block           ax1925_TerP_NMe2_2_AgCl_cmp6a
_cod_depositor_comments
'Adding full bibliography for 7705201--7705209.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7705208
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.807
_shelx_estimated_absorpt_t_max   0.961
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.27608(19) 0.24030(14) 0.64205(9) 0.0274(4) Uani 1 1 d . . . A 1
C2 C 0.3766(2) 0.17774(18) 0.62464(10) 0.0382(5) Uani 1 1 d . . . A 1
C3 C 0.4250(3) 0.1072(2) 0.66963(12) 0.0548(8) Uani 1 1 d . . . A 1
H3 H 0.4886 0.0641 0.6560 0.066 Uiso 1 1 calc R U . A 1
C4 C 0.3819(3) 0.0986(2) 0.73427(12) 0.0527(7) Uani 1 1 d . . . A 1
H4 H 0.4141 0.0495 0.7645 0.063 Uiso 1 1 calc R U . A 1
C5 C 0.2911(2) 0.16297(17) 0.75373(10) 0.0392(5) Uani 1 1 d . . . A 1
H5 H 0.2647 0.1592 0.7987 0.047 Uiso 1 1 calc R U . A 1
C6 C 0.2369(2) 0.23350(14) 0.70907(9) 0.0282(4) Uani 1 1 d . . . A 1
C7 C 0.4493(2) 0.19179(18) 0.56225(10) 0.0403(6) Uani 1 1 d . . . A 1
C8 C 0.5617(2) 0.2529(2) 0.56985(12) 0.0508(7) Uani 1 1 d . . . A 1
C9 C 0.6238(2) 0.2736(3) 0.51112(13) 0.0578(8) Uani 1 1 d . . . A 1
H9 H 0.6971 0.3168 0.5153 0.069 Uiso 1 1 calc R U . A 1
C10 C 0.5818(2) 0.2332(2) 0.44786(13) 0.0511(7) Uani 1 1 d . . . A 1
C11 C 0.4795(3) 0.1668(2) 0.44330(11) 0.0458(6) Uani 1 1 d . . . A 1
H11 H 0.4544 0.1354 0.4005 0.055 Uiso 1 1 calc R U . A 1
C12 C 0.4117(2) 0.14427(18) 0.50003(11) 0.0403(5) Uani 1 1 d . . . A 1
C13 C 0.6181(3) 0.2926(3) 0.63983(13) 0.0652(9) Uani 1 1 d . . . A 1
H13A H 0.6890 0.3383 0.6343 0.098 Uiso 1 1 calc R U . A 1
H13B H 0.6587 0.2435 0.6706 0.098 Uiso 1 1 calc R U . A 1
H13C H 0.5431 0.3218 0.6601 0.098 Uiso 1 1 calc R U . A 1
C14 C 0.6436(3) 0.2624(3) 0.38372(14) 0.0663(9) Uani 1 1 d . . . A 1
H14A H 0.5998 0.3193 0.3652 0.099 Uiso 1 1 calc R U . A 1
H14B H 0.6276 0.2142 0.3483 0.099 Uiso 1 1 calc R U . A 1
H14C H 0.7430 0.2722 0.3964 0.099 Uiso 1 1 calc R U . A 1
C15 C 0.3060(3) 0.06883(18) 0.49278(13) 0.0489(6) Uani 1 1 d . . . A 1
H15A H 0.3523 0.0096 0.4908 0.073 Uiso 1 1 calc R U . A 1
H15B H 0.2409 0.0780 0.4500 0.073 Uiso 1 1 calc R U . A 1
H15C H 0.2558 0.0698 0.5328 0.073 Uiso 1 1 calc R U . A 1
C16 C 0.1470(2) 0.29979(14) 0.74128(9) 0.0268(4) Uani 1 1 d . . . A 1
C17 C 0.2015(2) 0.38456(16) 0.76576(10) 0.0346(4) Uani 1 1 d . . . A 1
C18 C 0.1240(3) 0.44037(16) 0.80359(11) 0.0426(6) Uani 1 1 d . . . A 1
H18 H 0.1610 0.4979 0.8199 0.051 Uiso 1 1 calc R U . A 1
C20 C -0.0047(3) 0.41499(15) 0.81824(12) 0.0409(6) Uani 1 1 d . . . A 1
C21 C -0.0576(2) 0.33162(15) 0.79291(11) 0.0354(5) Uani 1 1 d . . . A 1
H21 H -0.1471 0.3139 0.8011 0.042 Uiso 1 1 calc R U . A 1
C22 C 0.0168(2) 0.27286(13) 0.75565(10) 0.0279(4) Uani 1 1 d . . . A 1
C23 C 0.3437(3) 0.4139(2) 0.75352(13) 0.0510(7) Uani 1 1 d . . . A 1
H23A H 0.3678 0.4720 0.7776 0.076 Uiso 1 1 calc R U . A 1
H23B H 0.3446 0.4220 0.7036 0.076 Uiso 1 1 calc R U . A 1
H23C H 0.4110 0.3669 0.7714 0.076 Uiso 1 1 calc R U . A 1
C24 C -0.0838(4) 0.47535(18) 0.86221(15) 0.0617(9) Uani 1 1 d . . . A 1
H24A H -0.1306 0.5243 0.8333 0.093 Uiso 1 1 calc R U . A 1
H24B H -0.0195 0.5024 0.9001 0.093 Uiso 1 1 calc R U . A 1
H24C H -0.1524 0.4383 0.8816 0.093 Uiso 1 1 calc R U . A 1
C25 C -0.0446(3) 0.18086(15) 0.73258(13) 0.0398(5) Uani 1 1 d . . . A 1
H25A H -0.1376 0.1760 0.7452 0.060 Uiso 1 1 calc R U . A 1
H25B H 0.0136 0.1318 0.7554 0.060 Uiso 1 1 calc R U . A 1
H25C H -0.0498 0.1751 0.6821 0.060 Uiso 1 1 calc R U . A 1
C26 C 0.0280(2) 0.19724(16) 0.52413(12) 0.0368(5) Uani 1 1 d . . . A 1
H26A H -0.0628 0.2265 0.5148 0.055 Uiso 1 1 calc R U . A 1
H26B H 0.0445 0.1758 0.5724 0.055 Uiso 1 1 calc R U . A 1
H26C H 0.0310 0.1450 0.4928 0.055 Uiso 1 1 calc R U . A 1
C27 C 0.1265(2) 0.29081(16) 0.44023(11) 0.0373(5) Uani 1 1 d . . . A 1
H27A H 0.1377 0.2368 0.4117 0.056 Uiso 1 1 calc R U . A 1
H27B H 0.1998 0.3351 0.4357 0.056 Uiso 1 1 calc R U . A 1
H27C H 0.0365 0.3190 0.4246 0.056 Uiso 1 1 calc R U . A 1
C28 C -0.0301(2) 0.38561(16) 0.60953(11) 0.0343(4) Uani 1 1 d . . . A 1
H28A H -0.0550 0.4159 0.6509 0.051 Uiso 1 1 calc R U . A 1
H28B H -0.0442 0.3194 0.6130 0.051 Uiso 1 1 calc R U . A 1
H28C H -0.0883 0.4092 0.5680 0.051 Uiso 1 1 calc R U . A 1
C29 C 0.1447(3) 0.50204(15) 0.60488(13) 0.0443(6) Uani 1 1 d . . . A 1
H29A H 0.0827 0.5322 0.5676 0.066 Uiso 1 1 calc R U . A 1
H29B H 0.2406 0.5115 0.5976 0.066 Uiso 1 1 calc R U . A 1
H29C H 0.1310 0.5283 0.6497 0.066 Uiso 1 1 calc R U . A 1
P1 P 0.22131(5) 0.32868(3) 0.57496(2) 0.02274(10) Uani 1 1 d . . . A 1
Cl1 Cl 0.41530(8) 0.47414(6) 0.41084(3) 0.0606(2) Uani 1 1 d . . . A 1
Ag1 Ag 0.40166(2) 0.41287(2) 0.53209(2) 0.04275(7) Uani 1 1 d . . . A 1
N1 N 0.13439(16) 0.26325(11) 0.51291(8) 0.0266(3) Uani 1 1 d . . . A 1
N2 N 0.11470(17) 0.40393(11) 0.60448(9) 0.0276(3) Uani 1 1 d . . . A 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 C1 C2 117.79(17) . . ?
C6 C1 P1 127.35(15) . . ?
C2 C1 P1 114.67(14) . . ?
C3 C2 C1 120.70(19) . . ?
C3 C2 C7 116.74(19) . . ?
C1 C2 C7 122.05(19) . . ?
C2 C3 C4 121.1(2) . . ?
C2 C3 H3 119.4 . . ?
C4 C3 H3 119.4 . . ?
C5 C4 C3 118.6(2) . . ?
C5 C4 H4 120.7 . . ?
C3 C4 H4 120.7 . . ?
C4 C5 C6 121.96(19) . . ?
C4 C5 H5 119.0 . . ?
C6 C5 H5 119.0 . . ?
C5 C6 C1 119.59(18) . . ?
C5 C6 C16 113.91(16) . . ?
C1 C6 C16 126.36(17) . . ?
C12 C7 C8 120.5(2) . . ?
C12 C7 C2 122.3(2) . . ?
C8 C7 C2 117.1(2) . . ?
C9 C8 C7 118.4(2) . . ?
C9 C8 C13 120.5(3) . . ?
C7 C8 C13 121.0(2) . . ?
C10 C9 C8 121.9(3) . . ?
C10 C9 H9 119.0 . . ?
C8 C9 H9 119.0 . . ?
C9 C10 C11 118.4(2) . . ?
C9 C10 C14 120.8(3) . . ?
C11 C10 C14 120.8(2) . . ?
C10 C11 C12 122.1(2) . . ?
C10 C11 H11 118.9 . . ?
C12 C11 H11 118.9 . . ?
C7 C12 C11 118.0(2) . . ?
C7 C12 C15 122.3(2) . . ?
C11 C12 C15 119.6(2) . . ?
C8 C13 H13A 109.5 . . ?
C8 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C8 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C10 C14 H14A 109.5 . . ?
C10 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C10 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C12 C15 H15A 109.5 . . ?
C12 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C12 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C22 C16 C17 119.45(18) . . ?
C22 C16 C6 120.53(18) . . ?
C17 C16 C6 119.43(18) . . ?
C18 C17 C16 119.0(2) . . ?
C18 C17 C23 120.3(2) . . ?
C16 C17 C23 120.7(2) . . ?
C20 C18 C17 122.4(2) . . ?
C20 C18 H18 118.8 . . ?
C17 C18 H18 118.8 . . ?
C18 C20 C21 117.8(2) . . ?
C18 C20 C24 121.1(2) . . ?
C21 C20 C24 121.0(2) . . ?
C20 C21 C22 121.9(2) . . ?
C20 C21 H21 119.1 . . ?
C22 C21 H21 119.1 . . ?
C21 C22 C16 119.43(19) . . ?
C21 C22 C25 118.97(19) . . ?
C16 C22 C25 121.60(17) . . ?
C17 C23 H23A 109.5 . . ?
C17 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C17 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C20 C24 H24A 109.5 . . ?
C20 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C20 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C22 C25 H25A 109.5 . . ?
C22 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C22 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
N1 C26 H26A 109.5 . . ?
N1 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
N1 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
N1 C27 H27A 109.5 . . ?
N1 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
N1 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
N2 C28 H28A 109.5 . . ?
N2 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
N2 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
N2 C29 H29A 109.5 . . ?
N2 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
N2 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
N1 P1 N2 110.20(9) . . ?
N1 P1 C1 100.10(9) . . ?
N2 P1 C1 110.15(8) . . ?
N1 P1 Ag1 111.36(6) . . ?
N2 P1 Ag1 108.16(6) . . ?
C1 P1 Ag1 116.64(6) . . ?
Ag1 Cl1 Ag1 87.291(19) . 3_666 ?
P1 Ag1 Cl1 130.064(19) . . ?
P1 Ag1 Cl1 132.984(18) . 3_666 ?
Cl1 Ag1 Cl1 92.708(19) . 3_666 ?
C26 N1 C27 112.88(16) . . ?
C26 N1 P1 124.63(14) . . ?
C27 N1 P1 119.43(14) . . ?
C28 N2 C29 112.06(18) . . ?
C28 N2 P1 124.32(14) . . ?
C29 N2 P1 120.60(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C6 1.416(2) . ?
C1 C2 1.419(3) . ?
C1 P1 1.858(2) . ?
C2 C3 1.389(3) . ?
C2 C7 1.509(3) . ?
C3 C4 1.390(3) . ?
C3 H3 0.9500 . ?
C4 C5 1.384(3) . ?
C4 H4 0.9500 . ?
C5 C6 1.400(3) . ?
C5 H5 0.9500 . ?
C6 C16 1.505(3) . ?
C7 C12 1.397(3) . ?
C7 C8 1.408(4) . ?
C8 C9 1.404(3) . ?
C8 C13 1.508(4) . ?
C9 C10 1.373(4) . ?
C9 H9 0.9500 . ?
C10 C11 1.388(4) . ?
C10 C14 1.525(3) . ?
C11 C12 1.408(3) . ?
C11 H11 0.9500 . ?
C12 C15 1.504(4) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C22 1.402(3) . ?
C16 C17 1.403(3) . ?
C17 C18 1.395(3) . ?
C17 C23 1.510(3) . ?
C18 C20 1.383(4) . ?
C18 H18 0.9500 . ?
C20 C21 1.384(3) . ?
C20 C24 1.518(3) . ?
C21 C22 1.395(3) . ?
C21 H21 0.9500 . ?
C22 C25 1.512(3) . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 N1 1.459(3) . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 N1 1.462(3) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 N2 1.461(3) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 N2 1.461(3) . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
P1 N1 1.6714(17) . ?
P1 N2 1.6742(17) . ?
P1 Ag1 2.3999(5) . ?
Cl1 Ag1 2.5454(6) . ?
Cl1 Ag1 2.5657(6) 3_666 ?
Ag1 Cl1 2.5658(6) 3_666 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 5.7(4) . . . . ?
P1 C1 C2 C3 -178.9(2) . . . . ?
C6 C1 C2 C7 -165.8(2) . . . . ?
P1 C1 C2 C7 9.6(3) . . . . ?
C1 C2 C3 C4 -3.3(5) . . . . ?
C7 C2 C3 C4 168.7(3) . . . . ?
C2 C3 C4 C5 -1.2(5) . . . . ?
C3 C4 C5 C6 3.0(4) . . . . ?
C4 C5 C6 C1 -0.5(4) . . . . ?
C4 C5 C6 C16 -176.5(2) . . . . ?
C2 C1 C6 C5 -3.9(3) . . . . ?
P1 C1 C6 C5 -178.56(17) . . . . ?
C2 C1 C6 C16 171.6(2) . . . . ?
P1 C1 C6 C16 -3.1(3) . . . . ?
C3 C2 C7 C12 87.0(3) . . . . ?
C1 C2 C7 C12 -101.2(3) . . . . ?
C3 C2 C7 C8 -90.6(3) . . . . ?
C1 C2 C7 C8 81.2(3) . . . . ?
C12 C7 C8 C9 7.8(4) . . . . ?
C2 C7 C8 C9 -174.5(2) . . . . ?
C12 C7 C8 C13 -169.8(2) . . . . ?
C2 C7 C8 C13 7.9(4) . . . . ?
C7 C8 C9 C10 -2.7(4) . . . . ?
C13 C8 C9 C10 174.9(3) . . . . ?
C8 C9 C10 C11 -3.3(4) . . . . ?
C8 C9 C10 C14 175.3(3) . . . . ?
C9 C10 C11 C12 4.4(4) . . . . ?
C14 C10 C11 C12 -174.1(2) . . . . ?
C8 C7 C12 C11 -6.7(3) . . . . ?
C2 C7 C12 C11 175.7(2) . . . . ?
C8 C7 C12 C15 171.2(2) . . . . ?
C2 C7 C12 C15 -6.4(3) . . . . ?
C10 C11 C12 C7 0.6(3) . . . . ?
C10 C11 C12 C15 -177.4(2) . . . . ?
C5 C6 C16 C22 -70.5(3) . . . . ?
C1 C6 C16 C22 113.8(2) . . . . ?
C5 C6 C16 C17 100.7(2) . . . . ?
C1 C6 C16 C17 -75.0(3) . . . . ?
C22 C16 C17 C18 -0.4(3) . . . . ?
C6 C16 C17 C18 -171.66(19) . . . . ?
C22 C16 C17 C23 177.6(2) . . . . ?
C6 C16 C17 C23 6.4(3) . . . . ?
C16 C17 C18 C20 0.3(3) . . . . ?
C23 C17 C18 C20 -177.7(2) . . . . ?
C17 C18 C20 C21 -1.2(4) . . . . ?
C17 C18 C20 C24 177.3(2) . . . . ?
C18 C20 C21 C22 2.1(3) . . . . ?
C24 C20 C21 C22 -176.4(2) . . . . ?
C20 C21 C22 C16 -2.1(3) . . . . ?
C20 C21 C22 C25 177.0(2) . . . . ?
C17 C16 C22 C21 1.3(3) . . . . ?
C6 C16 C22 C21 172.43(17) . . . . ?
C17 C16 C22 C25 -177.91(19) . . . . ?
C6 C16 C22 C25 -6.7(3) . . . . ?
C6 C1 P1 N1 -115.82(19) . . . . ?
C2 C1 P1 N1 69.35(18) . . . . ?
C6 C1 P1 N2 0.2(2) . . . . ?
C2 C1 P1 N2 -174.61(16) . . . . ?
C6 C1 P1 Ag1 123.96(17) . . . . ?
C2 C1 P1 Ag1 -50.86(19) . . . . ?
N2 P1 N1 C26 -66.35(18) . . . . ?
C1 P1 N1 C26 49.65(18) . . . . ?
Ag1 P1 N1 C26 173.62(15) . . . . ?
N2 P1 N1 C27 92.44(17) . . . . ?
C1 P1 N1 C27 -151.56(16) . . . . ?
Ag1 P1 N1 C27 -27.60(17) . . . . ?
N1 P1 N2 C28 33.35(18) . . . . ?
C1 P1 N2 C28 -76.17(18) . . . . ?
Ag1 P1 N2 C28 155.29(14) . . . . ?
N1 P1 N2 C29 -125.44(18) . . . . ?
C1 P1 N2 C29 125.04(18) . . . . ?
Ag1 P1 N2 C29 -3.50(19) . . . . ?
