#------------------------------------------------------------------------------
#$Date: 2021-03-05 04:10:13 +0200 (Fri, 05 Mar 2021) $
#$Revision: 262662 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/57/7705776.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7705776
loop_
_publ_author_name
'Plajer, Alex J.'
'Crusius, Daniel'
'Jethwa, Rajesh B.'
'García-Romero, Álvaro'
'Bond, Andrew D.'
'García-Rodríguez, Raúl'
'Wright, Dominic S.'
_publ_section_title
;
 Coordination chemistry of the bench-stable tris-2-pyridyl pnictogen
 ligands [E(6-Me-2-py)₃] (E = As, As[double bond, length as
 m-dash]O, Sb).
;
_journal_issue                   7
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2393
_journal_page_last               2402
_journal_paper_doi               10.1039/d0dt03732j
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety
'(C72 H72 Ag4 As4 N12 4+), 4(C2 F3 O2 -), 4(C H3 N)'
_chemical_formula_sum            'C88 H84 Ag4 As4 F12 N16 O8'
_chemical_formula_weight         2452.87
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/1
_audit_update_record
;
2020-11-18 deposited with the CCDC.	2020-11-26 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 94.593(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   23.6574(8)
_cell_length_b                   16.1326(6)
_cell_length_c                   23.9153(9)
_cell_measurement_reflns_used    9532
_cell_measurement_temperature    180(2)
_cell_measurement_theta_max      54.31
_cell_measurement_theta_min      2.74
_cell_volume                     9098.1(6)
_computing_cell_refinement       'SAINT (Bruker, 2016)'
_computing_data_collection       'APEX3 (Bruker, 2016)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'Mercury (Macrae et al., 2008)'
_computing_publication_material  SHELXL
_computing_structure_refinement  'SHELXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      180(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker D8-QUEST PHOTON-100'
_diffrn_measurement_method       'ω and φ-scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.1000
_diffrn_reflns_av_unetI/netI     0.0782
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            59701
_diffrn_reflns_point_group_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        54.505
_diffrn_reflns_theta_max         54.505
_diffrn_reflns_theta_min         2.528
_diffrn_source                   'Incoatec I\mS Cu microsource'
_exptl_absorpt_coefficient_mu    9.193
_exptl_absorpt_correction_T_max  0.7507
_exptl_absorpt_correction_T_min  0.4831
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2014)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.791
_exptl_crystal_description       block
_exptl_crystal_F_000             4864
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.364
_refine_diff_density_min         -0.657
_refine_diff_density_rms         0.118
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     852
_refine_ls_number_reflns         11129
_refine_ls_number_restraints     471
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.1320
_refine_ls_R_factor_gt           0.0801
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0613P)²+122.2747P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1766
_refine_ls_wR_factor_ref         0.2046
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7033
_reflns_number_total             11129
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0dt03732j2.cif
_cod_data_source_block           3_sq
_cod_depositor_comments
'Adding full bibliography for 7705770--7705782.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7705776
_cambridge_user_name             'Alex Plajer'
_cambridge_user_crsid            ajp233
_cambridge_supervisor_name       'Dominic Wright'
_cambridge_supervisor_crsid      dsw1000
_cambridge_crystallographer_name 'Andrew Bond'
_cambridge_crystallographer_crsid adb29
_cambridge_sample_id             DC-AgO2CCF3-As(III)
_cambridge_data_id               DW_B1_0286
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.261
_shelx_estimated_absorpt_t_max   0.460
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.51519(4) 0.76294(6) 0.26898(4) 0.0596(3) Uani 1 1 d . . . . .
Ag2 Ag 0.62108(5) 0.83702(7) 0.33184(5) 0.0782(5) Uani 0.972(2) 1 d . . P . .
Ag3 Ag 0.41788(5) 0.88596(8) 0.25872(5) 0.0713(5) Uani 0.864(2) 1 d . . P . .
Ag4 Ag 0.54045(7) 0.70603(11) 0.15171(7) 0.0945(6) Uani 0.806(2) 1 d . . P . .
Ag5 Ag 0.48574(14) 0.6194(2) 0.33257(17) 0.0924(14) Uani 0.358(3) 1 d . . P . .
As6 As 0.59787(6) 0.65446(10) 0.27508(8) 0.0717(5) Uani 1 1 d . . . . .
As7 As 0.54665(7) 0.89243(11) 0.21449(7) 0.0713(5) Uani 1 1 d . . . . .
As8 As 0.49087(7) 0.81129(10) 0.36766(7) 0.0680(5) Uani 1 1 d . . . . .
As9 As 0.42588(7) 0.69425(11) 0.21774(7) 0.0741(5) Uani 1 1 d . . . . .
N1 N 0.6518(5) 0.7178(9) 0.3730(6) 0.089(4) Uani 1 1 d . . . . .
N2 N 0.6359(6) 0.6960(8) 0.1725(7) 0.095(4) Uani 1 1 d . . . . .
N3 N 0.5286(7) 0.5223(9) 0.2805(7) 0.104(5) Uani 1 1 d . . . . .
N4 N 0.6600(5) 0.8807(7) 0.2530(6) 0.075(4) Uani 1 1 d . . . . .
N5 N 0.4763(6) 1.0013(8) 0.2633(5) 0.078(4) Uani 1 1 d . . . . .
N6 N 0.5123(5) 0.8278(11) 0.1107(6) 0.103(5) Uani 1 1 d . . . . .
N7 N 0.5725(5) 0.9328(7) 0.3778(4) 0.064(3) Uani 1 1 d . . . . .
N8 N 0.3778(5) 0.8483(8) 0.3377(5) 0.081(4) Uani 1 1 d . . . . .
N10 N 0.3817(5) 0.8423(9) 0.1748(5) 0.084(4) Uani 1 1 d . . . . .
N11 N 0.4815(7) 0.5953(9) 0.1455(6) 0.109(5) Uani 1 1 d . . . . .
N12 N 0.3870(5) 0.6357(7) 0.3161(6) 0.077(4) Uani 1 1 d . . . . .
C11 C 0.6403(6) 0.6441(10) 0.3472(7) 0.073(4) Uani 1 1 d . U . . .
C12 C 0.6582(7) 0.5688(11) 0.3714(7) 0.090(5) Uani 1 1 d . U . . .
H12 H 0.651442 0.517895 0.352011 0.107 Uiso 1 1 calc R U . . .
C13 C 0.6857(7) 0.5706(12) 0.4235(8) 0.096(5) Uani 1 1 d . U . . .
H13 H 0.697194 0.520030 0.441298 0.115 Uiso 1 1 calc R U . . .
C14 C 0.6967(7) 0.6417(12) 0.4500(8) 0.096(5) Uani 1 1 d . U . . .
H14 H 0.715579 0.641963 0.486555 0.115 Uiso 1 1 calc R U . . .
C15 C 0.6804(7) 0.7160(11) 0.4238(8) 0.088(5) Uani 1 1 d . U . . .
C16 C 0.6889(8) 0.7943(12) 0.4535(8) 0.125(7) Uani 1 1 d . U . . .
H16A H 0.710208 0.784535 0.489730 0.187 Uiso 1 1 calc R U . . .
H16B H 0.710206 0.832342 0.431097 0.187 Uiso 1 1 calc R U . . .
H16C H 0.651997 0.818819 0.459656 0.187 Uiso 1 1 calc R U . . .
C21 C 0.6560(7) 0.6701(10) 0.2245(8) 0.083(5) Uani 1 1 d . U . . .
C22 C 0.7132(8) 0.6601(11) 0.2397(8) 0.102(6) Uani 1 1 d . U . . .
H22 H 0.726138 0.642155 0.276316 0.122 Uiso 1 1 calc R U . . .
C23 C 0.7507(11) 0.6767(14) 0.2003(11) 0.141(8) Uani 1 1 d . U . . .
H23 H 0.790224 0.670515 0.209900 0.170 Uiso 1 1 calc R U . . .
C24 C 0.7327(8) 0.7011(12) 0.1495(9) 0.112(6) Uani 1 1 d . U . . .
H24 H 0.759681 0.714500 0.123532 0.134 Uiso 1 1 calc R U . . .
C25 C 0.6750(9) 0.7079(13) 0.1329(9) 0.113(6) Uani 1 1 d . U . . .
C26 C 0.6520(10) 0.7355(16) 0.0791(10) 0.166(9) Uani 1 1 d . U . . .
H26A H 0.682692 0.742108 0.054249 0.249 Uiso 1 1 calc R U . . .
H26B H 0.624674 0.694652 0.063080 0.249 Uiso 1 1 calc R U . . .
H26C H 0.632885 0.788878 0.083022 0.249 Uiso 1 1 calc R U . . .
C31 C 0.5743(8) 0.5433(12) 0.2571(8) 0.095(5) Uani 1 1 d . U . . .
C32 C 0.6025(8) 0.4891(13) 0.2226(8) 0.112(6) Uani 1 1 d . U . . .
H32 H 0.637263 0.505340 0.208491 0.134 Uiso 1 1 calc R U . . .
C33 C 0.5795(10) 0.4120(14) 0.2094(9) 0.129(7) Uani 1 1 d . U . . .
H33 H 0.595739 0.375249 0.184128 0.154 Uiso 1 1 calc R U . . .
C34 C 0.5316(10) 0.3925(14) 0.2355(9) 0.123(7) Uani 1 1 d . U . . .
H34 H 0.515063 0.339475 0.228515 0.147 Uiso 1 1 calc R U . . .
C35 C 0.5071(10) 0.4431(16) 0.2697(10) 0.126(7) Uani 1 1 d . U . . .
C36 C 0.4591(10) 0.4236(15) 0.2954(11) 0.161(9) Uani 1 1 d . U . . .
H36A H 0.448679 0.470380 0.318684 0.241 Uiso 1 1 calc R U . . .
H36B H 0.427977 0.412066 0.266907 0.241 Uiso 1 1 calc R U . . .
H36C H 0.466228 0.374567 0.319084 0.241 Uiso 1 1 calc R U . . .
C41 C 0.6281(7) 0.9042(9) 0.2071(7) 0.075(4) Uani 1 1 d . U . . .
C42 C 0.6492(8) 0.9316(11) 0.1572(8) 0.103(6) Uani 1 1 d . U . . .
H42 H 0.624980 0.946784 0.125220 0.124 Uiso 1 1 calc R U . . .
C43 C 0.7083(8) 0.9350(12) 0.1576(8) 0.108(6) Uani 1 1 d . U . . .
H43 H 0.725986 0.954145 0.125680 0.130 Uiso 1 1 calc R U . . .
C44 C 0.7393(9) 0.9110(12) 0.2036(9) 0.112(6) Uani 1 1 d . U . . .
H44 H 0.779272 0.910026 0.202055 0.134 Uiso 1 1 calc R U . . .
C45 C 0.7189(8) 0.8880(11) 0.2520(8) 0.093(5) Uani 1 1 d . U . . .
C46 C 0.7530(7) 0.8584(12) 0.3025(8) 0.117(6) Uani 1 1 d . U . . .
H46A H 0.727934 0.845714 0.332025 0.175 Uiso 1 1 calc R U . . .
H46B H 0.773825 0.808363 0.293287 0.175 Uiso 1 1 calc R U . . .
H46C H 0.780024 0.901631 0.315734 0.175 Uiso 1 1 calc R U . . .
C51 C 0.5283(8) 0.9958(11) 0.2436(7) 0.090(5) Uani 1 1 d . U . . .
C52 C 0.5639(8) 1.0657(12) 0.2461(8) 0.106(6) Uani 1 1 d . U . . .
H52 H 0.600833 1.061516 0.233372 0.128 Uiso 1 1 calc R U . . .
C53 C 0.5462(10) 1.1392(15) 0.2664(9) 0.132(7) Uani 1 1 d . U . . .
H53 H 0.569916 1.186788 0.267013 0.159 Uiso 1 1 calc R U . . .
C54 C 0.4923(8) 1.1428(12) 0.2862(7) 0.099(5) Uani 1 1 d . U . . .
H54 H 0.479275 1.193415 0.300851 0.119 Uiso 1 1 calc R U . . .
C55 C 0.4577(8) 1.0735(12) 0.2848(7) 0.094(5) Uani 1 1 d . U . . .
C56 C 0.4000(7) 1.0774(12) 0.3046(8) 0.110(6) Uani 1 1 d . U . . .
H56A H 0.393008 1.133151 0.318723 0.165 Uiso 1 1 calc R U . . .
H56B H 0.371921 1.064602 0.273380 0.165 Uiso 1 1 calc R U . . .
H56C H 0.396818 1.036884 0.334729 0.165 Uiso 1 1 calc R U . . .
C61 C 0.5140(6) 0.8984(11) 0.1389(7) 0.075(4) Uani 1 1 d . U . . .
C62 C 0.4952(7) 0.9727(12) 0.1146(7) 0.094(5) Uani 1 1 d . U . . .
H62 H 0.500142 1.023159 0.134923 0.113 Uiso 1 1 calc R U . . .
C63 C 0.4692(8) 0.9728(15) 0.0609(9) 0.122(7) Uani 1 1 d . U . . .
H63 H 0.454285 1.022690 0.044561 0.146 Uiso 1 1 calc R U . . .
C64 C 0.4655(8) 0.9023(14) 0.0324(8) 0.107(6) Uani 1 1 d . U . . .
H64 H 0.447576 0.902860 -0.004620 0.128 Uiso 1 1 calc R U . . .
C65 C 0.4864(8) 0.8277(14) 0.0541(9) 0.109(6) Uani 1 1 d . U . . .
C66 C 0.4860(9) 0.7476(14) 0.0260(8) 0.137(8) Uani 1 1 d . U . . .
H66A H 0.503719 0.706004 0.051628 0.205 Uiso 1 1 calc R U . . .
H66B H 0.446743 0.731375 0.015042 0.205 Uiso 1 1 calc R U . . .
H66C H 0.507157 0.751581 -0.007439 0.205 Uiso 1 1 calc R U . . .
C71 C 0.5197(7) 0.9207(9) 0.3920(6) 0.066(4) Uani 1 1 d . U . . .
C72 C 0.4891(8) 0.9757(11) 0.4205(7) 0.090(5) Uani 1 1 d . U . . .
H72 H 0.451680 0.963579 0.429718 0.108 Uiso 1 1 calc R U . . .
C73 C 0.5151(8) 1.0498(12) 0.4351(7) 0.097(5) Uani 1 1 d . U . . .
H73 H 0.495137 1.090702 0.454210 0.116 Uiso 1 1 calc R U . . .
C74 C 0.5685(8) 1.0646(11) 0.4226(7) 0.090(5) Uani 1 1 d . U . . .
H74 H 0.586382 1.115427 0.433565 0.108 Uiso 1 1 calc R U . . .
C75 C 0.5973(7) 1.0062(9) 0.3940(6) 0.071(4) Uani 1 1 d . U . . .
C76 C 0.6555(7) 1.0205(12) 0.3787(8) 0.115(6) Uani 1 1 d . U . . .
H76A H 0.668653 1.074950 0.392564 0.173 Uiso 1 1 calc R U . . .
H76B H 0.680585 0.977346 0.395593 0.173 Uiso 1 1 calc R U . . .
H76C H 0.656183 1.018762 0.337818 0.173 Uiso 1 1 calc R U . . .
C81 C 0.4112(7) 0.8204(10) 0.3815(7) 0.080(4) Uani 1 1 d . U . . .
C82 C 0.3909(7) 0.8008(11) 0.4333(7) 0.094(5) Uani 1 1 d . U . . .
H82 H 0.416211 0.783017 0.463773 0.112 Uiso 1 1 calc R U . . .
C83 C 0.3346(9) 0.8074(13) 0.4393(9) 0.119(6) Uani 1 1 d . U . . .
H83 H 0.319392 0.792939 0.473578 0.143 Uiso 1 1 calc R U . . .
C84 C 0.2995(8) 0.8361(12) 0.3934(8) 0.109(6) Uani 1 1 d . U . . .
H84 H 0.259856 0.841084 0.396596 0.130 Uiso 1 1 calc R U . . .
C85 C 0.3215(8) 0.8574(11) 0.3437(8) 0.095(5) Uani 1 1 d . U . . .
C86 C 0.2863(7) 0.8879(12) 0.2971(8) 0.112(6) Uani 1 1 d . U . . .
H86A H 0.247048 0.891413 0.307109 0.168 Uiso 1 1 calc R U . . .
H86B H 0.299417 0.943150 0.286899 0.168 Uiso 1 1 calc R U . . .
H86C H 0.288406 0.850279 0.265166 0.168 Uiso 1 1 calc R U . . .
N9 N 0.5212(6) 0.6570(9) 0.4181(6) 0.079(4) Uani 0.43(3) 1 d . . P A 1
C91 C 0.5216(6) 0.7378(10) 0.4287(6) 0.072(4) Uani 0.43(3) 1 d . U P A 1
C92 C 0.5398(7) 0.7726(10) 0.4777(7) 0.105(5) Uani 0.43(3) 1 d . U P A 1
H92 H 0.537051 0.830624 0.483758 0.126 Uiso 0.43(3) 1 calc R U P A 1
C93 C 0.5623(9) 0.7209(13) 0.5182(9) 0.116(6) Uani 0.43(3) 1 d . U P A 1
H93 H 0.577426 0.742596 0.553137 0.140 Uiso 0.43(3) 1 calc R U P A 1
C94 C 0.5632(7) 0.6367(12) 0.5086(8) 0.096(5) Uani 0.43(3) 1 d . U P A 1
H94 H 0.577289 0.600930 0.538081 0.116 Uiso 0.43(3) 1 calc R U P A 1
C95 C 0.5450(8) 0.6042(12) 0.4600(8) 0.098(5) Uani 0.43(3) 1 d D U P A 1
C96 C 0.5428(19) 0.5143(17) 0.4454(18) 0.115(17) Uani 0.43(3) 1 d D U P A 1
H96A H 0.527502 0.507660 0.406363 0.173 Uiso 0.43(3) 1 calc R U P A 1
H96B H 0.581127 0.490918 0.450036 0.173 Uiso 0.43(3) 1 calc R U P A 1
H96C H 0.518355 0.485376 0.470218 0.173 Uiso 0.43(3) 1 calc R U P A 1
N9A N 0.5398(7) 0.7726(10) 0.4777(7) 0.105(5) Uani 0.57(3) 1 d . . P A 2
C91A C 0.5216(6) 0.7378(10) 0.4287(6) 0.072(4) Uani 0.57(3) 1 d . U P A 2
C92A C 0.5212(6) 0.6570(9) 0.4181(6) 0.079(4) Uani 0.57(3) 1 d . U P A 2
H92A H 0.505407 0.635763 0.383222 0.095 Uiso 0.57(3) 1 calc R U P A 2
C93A C 0.5450(8) 0.6042(12) 0.4600(8) 0.098(5) Uani 0.57(3) 1 d . U P A 2
H93A H 0.548054 0.546319 0.453504 0.118 Uiso 0.57(3) 1 calc R U P A 2
C94A C 0.5632(7) 0.6367(12) 0.5086(8) 0.096(5) Uani 0.57(3) 1 d . U P A 2
H94A H 0.577289 0.600930 0.538081 0.116 Uiso 0.57(3) 1 calc R U P A 2
C95A C 0.5623(9) 0.7209(13) 0.5182(9) 0.116(6) Uani 0.57(3) 1 d D U P A 2
C96A C 0.5727(14) 0.7609(19) 0.5758(10) 0.113(13) Uani 0.57(3) 1 d D U P A 2
H96D H 0.588909 0.719799 0.602729 0.169 Uiso 0.57(3) 1 calc R U P A 2
H96E H 0.599156 0.807293 0.573670 0.169 Uiso 0.57(3) 1 calc R U P A 2
H96F H 0.536712 0.781290 0.588192 0.169 Uiso 0.57(3) 1 calc R U P A 2
C101 C 0.3866(6) 0.7637(12) 0.1606(6) 0.074(4) Uani 1 1 d . U . . .
C102 C 0.3650(7) 0.7306(11) 0.1079(7) 0.090(5) Uani 1 1 d . U . . .
H102 H 0.369291 0.673240 0.100236 0.107 Uiso 1 1 calc R U . . .
C103 C 0.3389(8) 0.7798(14) 0.0694(8) 0.111(6) Uani 1 1 d . U . . .
H103 H 0.323842 0.758548 0.034307 0.133 Uiso 1 1 calc R U . . .
C104 C 0.3345(8) 0.8617(13) 0.0821(8) 0.106(6) Uani 1 1 d . U . . .
H104 H 0.317462 0.898423 0.054599 0.127 Uiso 1 1 calc R U . . .
C105 C 0.3550(7) 0.8943(12) 0.1363(7) 0.085(5) Uani 1 1 d . U . . .
C106 C 0.3503(7) 0.9786(11) 0.1515(7) 0.098(6) Uani 1 1 d . U . . .
H10D H 0.330395 1.009196 0.120436 0.147 Uiso 1 1 calc R U . . .
H10E H 0.329011 0.982922 0.184839 0.147 Uiso 1 1 calc R U . . .
H10F H 0.388285 1.002044 0.159609 0.147 Uiso 1 1 calc R U . . .
C111 C 0.4367(8) 0.5926(11) 0.1746(7) 0.084(5) Uani 1 1 d . U . . .
C112 C 0.3977(8) 0.5305(12) 0.1740(8) 0.103(6) Uani 1 1 d . U . . .
H112 H 0.366281 0.533475 0.196264 0.124 Uiso 1 1 calc R U . . .
C113 C 0.4053(10) 0.4632(16) 0.1399(10) 0.143(8) Uani 1 1 d . U . . .
H113 H 0.380389 0.416900 0.138530 0.172 Uiso 1 1 calc R U . . .
C114 C 0.4510(9) 0.4672(14) 0.1082(9) 0.123(7) Uani 1 1 d . U . . .
H114 H 0.456341 0.423619 0.082423 0.147 Uiso 1 1 calc R U . . .
C115 C 0.4892(10) 0.5307(15) 0.1119(9) 0.121(7) Uani 1 1 d . U . . .
C116 C 0.5398(11) 0.5290(16) 0.0815(10) 0.171(10) Uani 1 1 d . U . . .
H11E H 0.539909 0.478546 0.058662 0.257 Uiso 1 1 calc R U . . .
H11F H 0.540241 0.577712 0.056984 0.257 Uiso 1 1 calc R U . . .
H11G H 0.573461 0.529691 0.108150 0.257 Uiso 1 1 calc R U . . .
C121 C 0.3667(6) 0.6645(10) 0.2662(7) 0.074(4) Uani 1 1 d . U . . .
C122 C 0.3094(6) 0.6743(10) 0.2496(7) 0.082(5) Uani 1 1 d . U . . .
H122 H 0.296808 0.696546 0.214042 0.099 Uiso 1 1 calc R U . . .
C123 C 0.2720(8) 0.6498(12) 0.2878(8) 0.109(6) Uani 1 1 d . U . . .
H123 H 0.232244 0.652850 0.278351 0.130 Uiso 1 1 calc R U . . .
C124 C 0.2918(8) 0.6217(11) 0.3382(8) 0.105(6) Uani 1 1 d . U . . .
H124 H 0.265755 0.607807 0.364919 0.126 Uiso 1 1 calc R U . . .
C125 C 0.3501(8) 0.6121(11) 0.3527(8) 0.101(6) Uani 1 1 d . U . . .
C126 C 0.3718(8) 0.5823(12) 0.4085(8) 0.117(6) Uani 1 1 d . U . . .
H12F H 0.339859 0.567414 0.430170 0.176 Uiso 1 1 calc R U . . .
H12G H 0.395738 0.533429 0.404325 0.176 Uiso 1 1 calc R U . . .
H12H H 0.394186 0.626092 0.428040 0.176 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As -0.9300 1.0051 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
As8 Ag1 As7 107.90(6) . . ?
As8 Ag1 As9 109.00(6) . . ?
As7 Ag1 As9 111.09(6) . . ?
As8 Ag1 As6 111.67(6) . . ?
As7 Ag1 As6 108.78(6) . . ?
As9 Ag1 As6 108.42(6) . . ?
As8 Ag1 Ag5 71.42(9) . . ?
As7 Ag1 Ag5 177.14(9) . . ?
As9 Ag1 Ag5 71.67(8) . . ?
As6 Ag1 Ag5 69.23(8) . . ?
As8 Ag1 Ag3 69.81(5) . . ?
As7 Ag1 Ag3 71.34(5) . . ?
As9 Ag1 Ag3 70.03(5) . . ?
As6 Ag1 Ag3 178.26(6) . . ?
Ag5 Ag1 Ag3 110.72(8) . . ?
As8 Ag1 Ag4 178.47(6) . . ?
As7 Ag1 Ag4 72.35(6) . . ?
As9 Ag1 Ag4 69.58(5) . . ?
As6 Ag1 Ag4 69.53(6) . . ?
Ag5 Ag1 Ag4 108.41(9) . . ?
Ag3 Ag1 Ag4 108.98(5) . . ?
As8 Ag1 Ag2 70.61(5) . . ?
As7 Ag1 Ag2 71.14(5) . . ?
As9 Ag1 Ag2 177.65(6) . . ?
As6 Ag1 Ag2 69.84(5) . . ?
Ag5 Ag1 Ag2 106.09(8) . . ?
Ag3 Ag1 Ag2 111.73(5) . . ?
Ag4 Ag1 Ag2 110.84(5) . . ?
N1 Ag2 N7 121.9(5) . . ?
N1 Ag2 N4 119.3(5) . . ?
N7 Ag2 N4 116.5(4) . . ?
N1 Ag2 Ag1 96.0(3) . . ?
N7 Ag2 Ag1 94.5(3) . . ?
N4 Ag2 Ag1 94.8(3) . . ?
N10 Ag3 N8 120.6(5) . . ?
N10 Ag3 N5 118.8(4) . . ?
N8 Ag3 N5 117.7(4) . . ?
N10 Ag3 Ag1 95.7(4) . . ?
N8 Ag3 Ag1 97.0(3) . . ?
N5 Ag3 Ag1 94.3(3) . . ?
N11 Ag4 N6 119.8(5) . . ?
N11 Ag4 N2 123.6(5) . . ?
N6 Ag4 N2 114.0(5) . . ?
N11 Ag4 Ag1 97.6(4) . . ?
N6 Ag4 Ag1 93.7(4) . . ?
N2 Ag4 Ag1 94.9(4) . . ?
C92A Ag5 N3 122.3(5) . . ?
N9 Ag5 N3 122.3(5) . . ?
C92A Ag5 N12 114.8(5) . . ?
N9 Ag5 N12 114.8(5) . . ?
N3 Ag5 N12 117.6(5) . . ?
C92A Ag5 Ag1 100.1(4) . . ?
N9 Ag5 Ag1 100.1(4) . . ?
N3 Ag5 Ag1 97.3(4) . . ?
N12 Ag5 Ag1 95.8(3) . . ?
C92A Ag5 As6 94.8(4) . . ?
N9 Ag5 As6 94.8(4) . . ?
N3 Ag5 As6 57.1(4) . . ?
N12 Ag5 As6 140.4(4) . . ?
Ag1 Ag5 As6 51.38(7) . . ?
C31 As6 C21 101.1(8) . . ?
C31 As6 C11 103.9(7) . . ?
C21 As6 C11 103.1(7) . . ?
C31 As6 Ag1 114.2(6) . . ?
C21 As6 Ag1 116.5(5) . . ?
C11 As6 Ag1 116.1(5) . . ?
C31 As6 Ag5 71.8(7) . . ?
C21 As6 Ag5 166.9(5) . . ?
C11 As6 Ag5 89.4(4) . . ?
Ag1 As6 Ag5 59.40(8) . . ?
C51 As7 C61 102.6(7) . . ?
C51 As7 C41 101.9(7) . . ?
C61 As7 C41 103.6(7) . . ?
C51 As7 Ag1 116.4(5) . . ?
C61 As7 Ag1 113.8(5) . . ?
C41 As7 Ag1 116.5(5) . . ?
C81 As8 C71 101.5(6) . . ?
C81 As8 C91A 102.9(7) . . ?
C71 As8 C91A 102.8(6) . . ?
C81 As8 C91 102.9(7) . . ?
C71 As8 C91 102.8(6) . . ?
C81 As8 Ag1 117.8(5) . . ?
C71 As8 Ag1 116.3(4) . . ?
C91A As8 Ag1 113.4(5) . . ?
C91 As8 Ag1 113.4(5) . . ?
C101 As9 C121 103.5(6) . . ?
C101 As9 C111 100.8(7) . . ?
C121 As9 C111 103.7(7) . . ?
C101 As9 Ag1 114.2(5) . . ?
C121 As9 Ag1 114.8(4) . . ?
C111 As9 Ag1 117.9(5) . . ?
C15 N1 C11 117.4(14) . . ?
C15 N1 Ag2 122.3(12) . . ?
C11 N1 Ag2 120.2(10) . . ?
C21 N2 C25 117.7(16) . . ?
C21 N2 Ag4 119.2(11) . . ?
C25 N2 Ag4 122.9(14) . . ?
C31 N3 C35 117.5(19) . . ?
C31 N3 Ag5 118.4(12) . . ?
C35 N3 Ag5 123.9(16) . . ?
C41 N4 C45 117.3(14) . . ?
C41 N4 Ag2 122.1(10) . . ?
C45 N4 Ag2 120.6(11) . . ?
C51 N5 C55 121.1(15) . . ?
C51 N5 Ag3 119.1(11) . . ?
C55 N5 Ag3 119.8(12) . . ?
C61 N6 C65 118.2(17) . . ?
C61 N6 Ag4 122.0(12) . . ?
C65 N6 Ag4 119.5(14) . . ?
C71 N7 C75 116.5(12) . . ?
C71 N7 Ag2 123.1(10) . . ?
C75 N7 Ag2 120.4(10) . . ?
C81 N8 C85 118.4(14) . . ?
C81 N8 Ag3 118.9(10) . . ?
C85 N8 Ag3 122.6(11) . . ?
C101 N10 C105 117.6(15) . . ?
C101 N10 Ag3 120.0(10) . . ?
C105 N10 Ag3 122.4(12) . . ?
C111 N11 C115 116.6(19) . . ?
C111 N11 Ag4 120.6(12) . . ?
C115 N11 Ag4 122.7(16) . . ?
C121 N12 C125 118.4(14) . . ?
C121 N12 Ag5 118.1(10) . . ?
C125 N12 Ag5 123.3(12) . . ?
N1 C11 C12 122.1(15) . . ?
N1 C11 As6 113.6(11) . . ?
C12 C11 As6 124.3(13) . . ?
C13 C12 C11 117.9(17) . . ?
C13 C12 H12 121.1 . . ?
C11 C12 H12 121.1 . . ?
C14 C13 C12 121.2(18) . . ?
C14 C13 H13 119.4 . . ?
C12 C13 H13 119.4 . . ?
C13 C14 C15 119.5(17) . . ?
C13 C14 H14 120.2 . . ?
C15 C14 H14 120.2 . . ?
N1 C15 C14 121.8(17) . . ?
N1 C15 C16 117.6(16) . . ?
C14 C15 C16 120.3(17) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
N2 C21 C22 122.5(17) . . ?
N2 C21 As6 113.7(12) . . ?
C22 C21 As6 123.8(15) . . ?
C23 C22 C21 118(2) . . ?
C23 C22 H22 120.9 . . ?
C21 C22 H22 120.9 . . ?
C24 C23 C22 121(2) . . ?
C24 C23 H23 119.5 . . ?
C22 C23 H23 119.5 . . ?
C23 C24 C25 122(2) . . ?
C23 C24 H24 119.2 . . ?
C25 C24 H24 119.2 . . ?
N2 C25 C24 119(2) . . ?
N2 C25 C26 116(2) . . ?
C24 C25 C26 125(2) . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
N3 C31 C32 122.7(19) . . ?
N3 C31 As6 112.6(14) . . ?
C32 C31 As6 124.8(17) . . ?
C33 C32 C31 120(2) . . ?
C33 C32 H32 120.1 . . ?
C31 C32 H32 120.1 . . ?
C34 C33 C32 115(2) . . ?
C34 C33 H33 122.4 . . ?
C32 C33 H33 122.4 . . ?
C35 C34 C33 124(2) . . ?
C35 C34 H34 118.0 . . ?
C33 C34 H34 118.0 . . ?
C34 C35 C36 124(3) . . ?
C34 C35 N3 121(2) . . ?
C36 C35 N3 115(2) . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
N4 C41 C42 125.0(15) . . ?
N4 C41 As7 113.1(11) . . ?
C42 C41 As7 121.8(14) . . ?
C43 C42 C41 115.5(18) . . ?
C43 C42 H42 122.3 . . ?
C41 C42 H42 122.3 . . ?
C44 C43 C42 118.5(19) . . ?
C44 C43 H43 120.7 . . ?
C42 C43 H43 120.7 . . ?
C43 C44 C45 126(2) . . ?
C43 C44 H44 117.2 . . ?
C45 C44 H44 117.2 . . ?
C44 C45 N4 117.7(18) . . ?
C44 C45 C46 125.8(18) . . ?
N4 C45 C46 116.0(16) . . ?
C45 C46 H46A 109.5 . . ?
C45 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C45 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
N5 C51 C52 119.4(17) . . ?
N5 C51 As7 115.5(13) . . ?
C52 C51 As7 125.0(15) . . ?
C53 C52 C51 121(2) . . ?
C53 C52 H52 119.5 . . ?
C51 C52 H52 119.5 . . ?
C52 C53 C54 118(2) . . ?
C52 C53 H53 120.9 . . ?
C54 C53 H53 120.9 . . ?
C55 C54 C53 120.8(19) . . ?
C55 C54 H54 119.6 . . ?
C53 C54 H54 119.6 . . ?
N5 C55 C54 119.5(17) . . ?
N5 C55 C56 119.4(17) . . ?
C54 C55 C56 121.1(19) . . ?
C55 C56 H56A 109.5 . . ?
C55 C56 H56B 109.5 . . ?
H56A C56 H56B 109.5 . . ?
C55 C56 H56C 109.5 . . ?
H56A C56 H56C 109.5 . . ?
H56B C56 H56C 109.5 . . ?
N6 C61 C62 122.4(17) . . ?
N6 C61 As7 115.5(13) . . ?
C62 C61 As7 122.1(14) . . ?
C63 C62 C61 119.6(19) . . ?
C63 C62 H62 120.2 . . ?
C61 C62 H62 120.2 . . ?
C64 C63 C62 119(2) . . ?
C64 C63 H63 120.5 . . ?
C62 C63 H63 120.5 . . ?
C63 C64 C65 123(2) . . ?
C63 C64 H64 118.5 . . ?
C65 C64 H64 118.5 . . ?
C64 C65 N6 117.6(19) . . ?
C64 C65 C66 127(2) . . ?
N6 C65 C66 115(2) . . ?
C65 C66 H66A 109.5 . . ?
C65 C66 H66B 109.5 . . ?
H66A C66 H66B 109.5 . . ?
C65 C66 H66C 109.5 . . ?
H66A C66 H66C 109.5 . . ?
H66B C66 H66C 109.5 . . ?
N7 C71 C72 125.3(15) . . ?
N7 C71 As8 111.5(10) . . ?
C72 C71 As8 123.2(13) . . ?
C71 C72 C73 116.6(17) . . ?
C71 C72 H72 121.7 . . ?
C73 C72 H72 121.7 . . ?
C74 C73 C72 120.5(18) . . ?
C74 C73 H73 119.8 . . ?
C72 C73 H73 119.8 . . ?
C73 C74 C75 120.1(17) . . ?
C73 C74 H74 120.0 . . ?
C75 C74 H74 120.0 . . ?
N7 C75 C74 121.0(15) . . ?
N7 C75 C76 117.1(14) . . ?
C74 C75 C76 121.9(16) . . ?
C75 C76 H76A 109.5 . . ?
C75 C76 H76B 109.5 . . ?
H76A C76 H76B 109.5 . . ?
C75 C76 H76C 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
N8 C81 C82 123.1(15) . . ?
N8 C81 As8 114.3(11) . . ?
C82 C81 As8 122.6(13) . . ?
C83 C82 C81 119.0(18) . . ?
C83 C82 H82 120.5 . . ?
C81 C82 H82 120.5 . . ?
C82 C83 C84 118.0(19) . . ?
C82 C83 H83 121.0 . . ?
C84 C83 H83 121.0 . . ?
C85 C84 C83 121.1(19) . . ?
C85 C84 H84 119.4 . . ?
C83 C84 H84 119.4 . . ?
N8 C85 C84 120.3(17) . . ?
N8 C85 C86 118.0(16) . . ?
C84 C85 C86 121.6(18) . . ?
C85 C86 H86A 109.5 . . ?
C85 C86 H86B 109.5 . . ?
H86A C86 H86B 109.5 . . ?
C85 C86 H86C 109.5 . . ?
H86A C86 H86C 109.5 . . ?
H86B C86 H86C 109.5 . . ?
C91 N9 C95 117.7(15) . . ?
C91 N9 Ag5 116.0(10) . . ?
C95 N9 Ag5 126.3(13) . . ?
N9 C91 C92 125.1(15) . . ?
N9 C91 As8 116.9(12) . . ?
C92 C91 As8 118.0(13) . . ?
C91 C92 C93 116.6(17) . . ?
C91 C92 H92 121.7 . . ?
C93 C92 H92 121.7 . . ?
C92 C93 C94 120.0(19) . . ?
C92 C93 H93 120.0 . . ?
C94 C93 H93 120.0 . . ?
C95 C94 C93 122.1(18) . . ?
C95 C94 H94 119.0 . . ?
C93 C94 H94 119.0 . . ?
C94 C95 N9 118.4(18) . . ?
C94 C95 C96 127(2) . . ?
N9 C95 C96 115(2) . . ?
C95 C96 H96A 109.5 . . ?
C95 C96 H96B 109.5 . . ?
H96A C96 H96B 109.5 . . ?
C95 C96 H96C 109.5 . . ?
H96A C96 H96C 109.5 . . ?
H96B C96 H96C 109.5 . . ?
C91A N9A C95A 116.6(17) . . ?
C92A C91A N9A 125.1(15) . . ?
C92A C91A As8 116.9(12) . . ?
N9A C91A As8 118.0(13) . . ?
C91A C92A C93A 117.7(15) . . ?
C91A C92A Ag5 116.0(10) . . ?
C93A C92A Ag5 126.3(13) . . ?
C91A C92A H92A 121.1 . . ?
C93A C92A H92A 121.1 . . ?
Ag5 C92A H92A 5.7 . . ?
C94A C93A C92A 118.4(18) . . ?
C94A C93A H93A 120.8 . . ?
C92A C93A H93A 120.8 . . ?
C93A C94A C95A 122.1(18) . . ?
C93A C94A H94A 119.0 . . ?
C95A C94A H94A 119.0 . . ?
N9A C95A C94A 120.0(19) . . ?
N9A C95A C96A 114(2) . . ?
C94A C95A C96A 124(2) . . ?
C95A C96A H96D 109.5 . . ?
C95A C96A H96E 109.5 . . ?
H96D C96A H96E 109.5 . . ?
C95A C96A H96F 109.5 . . ?
H96D C96A H96F 109.5 . . ?
H96E C96A H96F 109.5 . . ?
N10 C101 C102 123.8(16) . . ?
N10 C101 As9 114.8(11) . . ?
C102 C101 As9 121.5(14) . . ?
C103 C102 C101 120.1(18) . . ?
C103 C102 H102 120.0 . . ?
C101 C102 H102 120.0 . . ?
C102 C103 C104 118(2) . . ?
C102 C103 H103 121.1 . . ?
C104 C103 H103 121.1 . . ?
C103 C104 C105 121.7(19) . . ?
C103 C104 H104 119.2 . . ?
C105 C104 H104 119.2 . . ?
N10 C105 C106 117.4(16) . . ?
N10 C105 C104 119.1(17) . . ?
C106 C105 C104 123.5(17) . . ?
C105 C106 H10D 109.5 . . ?
C105 C106 H10E 109.5 . . ?
H10D C106 H10E 109.5 . . ?
C105 C106 H10F 109.5 . . ?
H10D C106 H10F 109.5 . . ?
H10E C106 H10F 109.5 . . ?
N11 C111 C112 126.3(18) . . ?
N11 C111 As9 113.2(13) . . ?
C112 C111 As9 120.3(15) . . ?
C111 C112 C113 118(2) . . ?
C111 C112 H112 121.1 . . ?
C113 C112 H112 121.1 . . ?
C114 C113 C112 116(2) . . ?
C114 C113 H113 122.1 . . ?
C112 C113 H113 122.1 . . ?
C115 C114 C113 123(2) . . ?
C115 C114 H114 118.4 . . ?
C113 C114 H114 118.4 . . ?
N11 C115 C114 120(2) . . ?
N11 C115 C116 118(2) . . ?
C114 C115 C116 122(2) . . ?
C115 C116 H11E 109.5 . . ?
C115 C116 H11F 109.5 . . ?
H11E C116 H11F 109.5 . . ?
C115 C116 H11G 109.5 . . ?
H11E C116 H11G 109.5 . . ?
H11F C116 H11G 109.5 . . ?
N12 C121 C122 124.6(14) . . ?
N12 C121 As9 113.2(10) . . ?
C122 C121 As9 122.2(12) . . ?
C123 C122 C121 116.2(16) . . ?
C123 C122 H122 121.9 . . ?
C121 C122 H122 121.9 . . ?
C124 C123 C122 119.7(18) . . ?
C124 C123 H123 120.2 . . ?
C122 C123 H123 120.2 . . ?
C123 C124 C125 121.8(19) . . ?
C123 C124 H124 119.1 . . ?
C125 C124 H124 119.1 . . ?
N12 C125 C124 119.1(17) . . ?
N12 C125 C126 119.1(17) . . ?
C124 C125 C126 121.6(18) . . ?
C125 C126 H12F 109.5 . . ?
C125 C126 H12G 109.5 . . ?
H12F C126 H12G 109.5 . . ?
C125 C126 H12H 109.5 . . ?
H12F C126 H12H 109.5 . . ?
H12G C126 H12H 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 As8 2.5936(19) . ?
Ag1 As7 2.6021(19) . ?
Ag1 As9 2.6037(19) . ?
Ag1 As6 2.6201(18) . ?
Ag1 Ag5 2.887(4) . ?
Ag1 Ag3 3.0345(16) . ?
Ag1 Ag4 3.0552(19) . ?
Ag1 Ag2 3.0594(15) . ?
Ag2 N1 2.254(14) . ?
Ag2 N7 2.263(11) . ?
Ag2 N4 2.275(13) . ?
Ag3 N10 2.232(14) . ?
Ag3 N8 2.264(12) . ?
Ag3 N5 2.315(13) . ?
Ag4 N11 2.265(17) . ?
Ag4 N6 2.271(17) . ?
Ag4 N2 2.279(15) . ?
Ag5 C92A 2.232(15) . ?
Ag5 N9 2.232(15) . ?
Ag5 N3 2.287(16) . ?
Ag5 N12 2.351(13) . ?
Ag5 As6 3.136(4) . ?
As6 C31 1.916(19) . ?
As6 C21 1.918(17) . ?
As6 C11 1.933(15) . ?
As7 C51 1.872(19) . ?
As7 C61 1.911(17) . ?
As7 C41 1.959(15) . ?
As8 C81 1.946(16) . ?
As8 C71 1.963(15) . ?
As8 C91A 1.973(14) . ?
As8 C91 1.973(14) . ?
As9 C101 1.946(16) . ?
As9 C121 1.948(15) . ?
As9 C111 1.965(18) . ?
N1 C15 1.342(19) . ?
N1 C11 1.356(18) . ?
N2 C21 1.36(2) . ?
N2 C25 1.39(2) . ?
N3 C31 1.30(2) . ?
N3 C35 1.39(3) . ?
N4 C41 1.336(18) . ?
N4 C45 1.402(19) . ?
N5 C51 1.355(19) . ?
N5 C55 1.36(2) . ?
N6 C61 1.323(19) . ?
N6 C65 1.44(2) . ?
N7 C71 1.334(17) . ?
N7 C75 1.365(17) . ?
N8 C81 1.338(18) . ?
N8 C85 1.360(19) . ?
N10 C101 1.319(19) . ?
N10 C105 1.363(19) . ?
N11 C111 1.31(2) . ?
N11 C115 1.34(2) . ?
N12 C121 1.335(17) . ?
N12 C125 1.34(2) . ?
C11 C12 1.40(2) . ?
C12 C13 1.36(2) . ?
C12 H12 0.9500 . ?
C13 C14 1.33(2) . ?
C13 H13 0.9500 . ?
C14 C15 1.39(2) . ?
C14 H14 0.9500 . ?
C15 C16 1.46(2) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C21 C22 1.38(2) . ?
C22 C23 1.37(3) . ?
C22 H22 0.9500 . ?
C23 C24 1.32(3) . ?
C23 H23 0.9500 . ?
C24 C25 1.40(2) . ?
C24 H24 0.9500 . ?
C25 C26 1.43(3) . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C31 C32 1.41(2) . ?
C32 C33 1.38(3) . ?
C32 H32 0.9500 . ?
C33 C34 1.37(3) . ?
C33 H33 0.9500 . ?
C34 C35 1.32(3) . ?
C34 H34 0.9500 . ?
C35 C36 1.37(3) . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C41 C42 1.40(2) . ?
C42 C43 1.40(2) . ?
C42 H42 0.9500 . ?
C43 C44 1.33(2) . ?
C43 H43 0.9500 . ?
C44 C45 1.34(2) . ?
C44 H44 0.9500 . ?
C45 C46 1.48(2) . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C51 C52 1.41(2) . ?
C52 C53 1.36(2) . ?
C52 H52 0.9500 . ?
C53 C54 1.40(2) . ?
C53 H53 0.9500 . ?
C54 C55 1.38(2) . ?
C54 H54 0.9500 . ?
C55 C56 1.48(2) . ?
C56 H56A 0.9800 . ?
C56 H56B 0.9800 . ?
C56 H56C 0.9800 . ?
C61 C62 1.39(2) . ?
C62 C63 1.38(2) . ?
C62 H62 0.9500 . ?
C63 C64 1.33(2) . ?
C63 H63 0.9500 . ?
C64 C65 1.39(2) . ?
C64 H64 0.9500 . ?
C65 C66 1.46(3) . ?
C66 H66A 0.9800 . ?
C66 H66B 0.9800 . ?
C66 H66C 0.9800 . ?
C71 C72 1.36(2) . ?
C72 C73 1.38(2) . ?
C72 H72 0.9500 . ?
C73 C74 1.34(2) . ?
C73 H73 0.9500 . ?
C74 C75 1.38(2) . ?
C74 H74 0.9500 . ?
C75 C76 1.47(2) . ?
C76 H76A 0.9800 . ?
C76 H76B 0.9800 . ?
C76 H76C 0.9800 . ?
C81 C82 1.40(2) . ?
C82 C83 1.35(2) . ?
C82 H82 0.9500 . ?
C83 C84 1.40(2) . ?
C83 H83 0.9500 . ?
C84 C85 1.38(2) . ?
C84 H84 0.9500 . ?
C85 C86 1.42(2) . ?
C86 H86A 0.9800 . ?
C86 H86B 0.9800 . ?
C86 H86C 0.9800 . ?
N9 C91 1.329(19) . ?
N9 C95 1.40(2) . ?
C91 C92 1.339(19) . ?
C92 C93 1.35(2) . ?
C92 H92 0.9500 . ?
C93 C94 1.38(2) . ?
C93 H93 0.9500 . ?
C94 C95 1.32(2) . ?
C94 H94 0.9500 . ?
C95 C96 1.491(19) . ?
C96 H96A 0.9800 . ?
C96 H96B 0.9800 . ?
C96 H96C 0.9800 . ?
N9A C91A 1.339(19) . ?
N9A C95A 1.35(2) . ?
C91A C92A 1.329(19) . ?
C92A C93A 1.40(2) . ?
C92A H92A 0.9500 . ?
C93A C94A 1.32(2) . ?
C93A H93A 0.9500 . ?
C94A C95A 1.38(2) . ?
C94A H94A 0.9500 . ?
C95A C96A 1.525(18) . ?
C96A H96D 0.9800 . ?
C96A H96E 0.9800 . ?
C96A H96F 0.9800 . ?
C101 C102 1.43(2) . ?
C102 C103 1.33(2) . ?
C102 H102 0.9500 . ?
C103 C104 1.36(2) . ?
C103 H103 0.9500 . ?
C104 C105 1.45(2) . ?
C104 H104 0.9500 . ?
C105 C106 1.41(2) . ?
C106 H10D 0.9800 . ?
C106 H10E 0.9800 . ?
C106 H10F 0.9800 . ?
C111 C112 1.36(2) . ?
C112 C113 1.38(3) . ?
C112 H112 0.9500 . ?
C113 C114 1.37(3) . ?
C113 H113 0.9500 . ?
C114 C115 1.36(3) . ?
C114 H114 0.9500 . ?
C115 C116 1.45(3) . ?
C116 H11E 0.9800 . ?
C116 H11F 0.9800 . ?
C116 H11G 0.9800 . ?
C121 C122 1.389(19) . ?
C122 C123 1.38(2) . ?
C122 H122 0.9500 . ?
C123 C124 1.34(2) . ?
C123 H123 0.9500 . ?
C124 C125 1.40(2) . ?
C124 H124 0.9500 . ?
C125 C126 1.47(2) . ?
C126 H12F 0.9800 . ?
C126 H12G 0.9800 . ?
C126 H12H 0.9800 . ?
