#------------------------------------------------------------------------------
#$Date: 2021-02-05 01:14:54 +0200 (Fri, 05 Feb 2021) $
#$Revision: 261674 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/59/7705966.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7705966
loop_
_publ_author_name
'Cheng, Ming-Chuan'
'Lee, Gene-Hsiang'
'Lin, Tien-Sung'
'Liu, Yu-Chiao'
'Chiang, Ming-Hsi'
'Peng, Shie-Ming'
_publ_section_title
;
 A new series of heteronuclear metal strings,
 MRhRh(dpa)₄Cl₂ and
 MRhRhM(dpa)₄X₂, from the reactions of
 Rh₂(dpa)₄ with metal ions of group 7 to group 12.
;
_journal_issue                   2
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              520
_journal_page_last               534
_journal_paper_doi               10.1039/d0dt03311a
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C40 H32 Ag2 Cl2 N14 O6 Rh2'
_chemical_formula_weight         1226.35
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-09-21 deposited with the CCDC.	2020-12-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 96.1754(12)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   14.8400(3)
_cell_length_b                   16.9282(4)
_cell_length_c                   16.3244(3)
_cell_measurement_reflns_used    9304
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.50
_cell_measurement_theta_min      1.38
_cell_volume                     4077.13(15)
_computing_cell_refinement       DENZO-SMN
_computing_data_collection       'NONIUS COLLECT'
_computing_data_reduction        DENZO-SMN
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      150
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'NONIUS KappaCCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0439
_diffrn_reflns_av_unetI/netI     0.0598
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            21338
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.499
_diffrn_reflns_theta_min         1.738
_exptl_absorpt_coefficient_mu    1.810
_exptl_absorpt_correction_T_max  0.8992
_exptl_absorpt_correction_T_min  0.8691
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SORTAV (Blessing, 1995)'
_exptl_crystal_colour            dark-yellow
_exptl_crystal_density_diffrn    1.998
_exptl_crystal_description       block
_exptl_crystal_F_000             2408
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: CH2Cl2'
_exptl_crystal_size_max          0.080
_exptl_crystal_size_mid          0.080
_exptl_crystal_size_min          0.060
_refine_diff_density_max         0.707
_refine_diff_density_min         -0.918
_refine_diff_density_rms         0.125
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     577
_refine_ls_number_reflns         9304
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.0643
_refine_ls_R_factor_gt           0.0355
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0264P)²+2.1498P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0687
_refine_ls_wR_factor_ref         0.0768
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6695
_reflns_number_total             9304
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0dt03311a2.cif
_cod_data_source_block           ic17174
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_diffrn_ambient_temperature' value '150K' was changed to
'150' -- the value should be numeric and without a unit designator.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7705966--7705984.cif.
;
_cod_original_sg_symbol_H-M      P21/c
_cod_original_formula_sum        'C40 H32 Cl2 Ag2 N14 O6 Rh2'
_cod_database_code               7705966
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.869
_shelx_estimated_absorpt_t_max   0.899
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.55140(2) 0.05147(2) 0.89133(2) 0.02832(8) Uani 1 1 d . . . . .
Ag2 Ag 0.93067(2) -0.00687(2) 0.61639(2) 0.02512(8) Uani 1 1 d . . . . .
Rh1 Rh 0.67666(2) 0.02772(2) 0.79307(2) 0.02072(8) Uani 1 1 d . . . . .
Rh2 Rh 0.79497(2) 0.00830(2) 0.70872(2) 0.01916(8) Uani 1 1 d . . . . .
O1 O 0.43139(19) 0.06601(17) 0.97310(18) 0.0413(8) Uani 1 1 d . . . . .
O2 O 0.4518(2) 0.18931(19) 0.9496(2) 0.0646(11) Uani 1 1 d . . . . .
O3 O 0.3172(2) 0.1454(2) 0.9528(2) 0.0622(10) Uani 1 1 d . . . . .
O4 O 1.05676(18) -0.06140(17) 0.53725(18) 0.0372(7) Uani 1 1 d . . . . .
O5 O 1.0234(2) -0.1468(2) 0.6277(2) 0.0687(12) Uani 1 1 d . . . . .
O6 O 1.0707(2) -0.18738(18) 0.5146(2) 0.0529(9) Uani 1 1 d . . . . .
N1 N 0.4705(2) 0.03429(19) 0.7704(2) 0.0259(7) Uani 1 1 d . . . . .
N2 N 0.59074(18) 0.05211(18) 0.69210(18) 0.0215(7) Uani 1 1 d . . . . .
N3 N 0.71714(19) 0.07890(17) 0.62419(18) 0.0202(7) Uani 1 1 d . . . . .
N4 N 0.6749(2) 0.07107(19) 0.97266(18) 0.0257(7) Uani 1 1 d . . . . .
N5 N 0.7672(2) 0.00256(19) 0.89217(19) 0.0242(7) Uani 1 1 d . . . . .
N6 N 0.85598(19) -0.06107(18) 0.80326(18) 0.0223(7) Uani 1 1 d . . . . .
N7 N 0.82357(19) -0.08465(18) 0.55603(19) 0.0236(7) Uani 1 1 d . . . . .
N8 N 0.73119(19) -0.08932(18) 0.66201(19) 0.0228(7) Uani 1 1 d . . . . .
N9 N 0.64675(19) -0.09031(18) 0.77418(19) 0.0224(7) Uani 1 1 d . . . . .
N10 N 0.99255(19) 0.06904(19) 0.71594(19) 0.0243(7) Uani 1 1 d . . . . .
N11 N 0.85562(19) 0.10681(18) 0.75996(18) 0.0215(7) Uani 1 1 d . . . . .
N12 N 0.71512(19) 0.14459(18) 0.79751(18) 0.0218(7) Uani 1 1 d . . . . .
N13 N 0.3988(2) 0.1349(2) 0.9585(2) 0.0345(8) Uani 1 1 d . . . . .
N14 N 1.0510(2) -0.1329(2) 0.5598(2) 0.0363(9) Uani 1 1 d . . . . .
C1 C 0.3824(3) 0.0161(2) 0.7765(3) 0.0313(10) Uani 1 1 d . . . . .
H1 H 0.361918 0.015141 0.829624 0.038 Uiso 1 1 calc R U . . .
C2 C 0.3221(3) -0.0009(2) 0.7101(3) 0.0342(10) Uani 1 1 d . . . . .
H2A H 0.260546 -0.011808 0.716950 0.041 Uiso 1 1 calc R U . . .
C3 C 0.3519(3) -0.0022(2) 0.6314(3) 0.0352(10) Uani 1 1 d . . . . .
H3A H 0.311411 -0.014677 0.584095 0.042 Uiso 1 1 calc R U . . .
C4 C 0.4407(2) 0.0151(2) 0.6245(3) 0.0292(9) Uani 1 1 d . . . . .
H4 H 0.462455 0.013341 0.571834 0.035 Uiso 1 1 calc R U . . .
C5 C 0.5005(2) 0.0353(2) 0.6941(2) 0.0235(8) Uani 1 1 d . . . . .
C6 C 0.6257(2) 0.0873(2) 0.6267(2) 0.0215(8) Uani 1 1 d . . . . .
C7 C 0.5767(3) 0.1369(2) 0.5690(2) 0.0277(9) Uani 1 1 d . . . . .
H7 H 0.512727 0.140848 0.568298 0.033 Uiso 1 1 calc R U . . .
C8 C 0.6201(3) 0.1798(2) 0.5137(2) 0.0297(9) Uani 1 1 d . . . . .
H8 H 0.586613 0.213639 0.475246 0.036 Uiso 1 1 calc R U . . .
C9 C 0.7132(3) 0.1731(2) 0.5145(2) 0.0290(9) Uani 1 1 d . . . . .
H9 H 0.744777 0.202789 0.477279 0.035 Uiso 1 1 calc R U . . .
C10 C 0.7585(3) 0.1227(2) 0.5702(2) 0.0254(9) Uani 1 1 d . . . . .
H10 H 0.822414 0.118416 0.570798 0.030 Uiso 1 1 calc R U . . .
C11 C 0.6629(3) 0.1142(2) 1.0404(2) 0.0342(10) Uani 1 1 d . . . . .
H11 H 0.604172 0.134751 1.045541 0.041 Uiso 1 1 calc R U . . .
C12 C 0.7306(3) 0.1297(3) 1.1019(3) 0.0444(12) Uani 1 1 d . . . . .
H12 H 0.719058 0.159457 1.149071 0.053 Uiso 1 1 calc R U . . .
C13 C 0.8166(3) 0.1009(3) 1.0936(3) 0.0431(12) Uani 1 1 d . . . . .
H13 H 0.865187 0.111276 1.135017 0.052 Uiso 1 1 calc R U . . .
C14 C 0.8315(3) 0.0573(3) 1.0251(3) 0.0349(10) Uani 1 1 d . . . . .
H14 H 0.890393 0.037736 1.018911 0.042 Uiso 1 1 calc R U . . .
C15 C 0.7590(3) 0.0419(2) 0.9644(2) 0.0251(9) Uani 1 1 d . . . . .
C16 C 0.8333(2) -0.0515(2) 0.8820(2) 0.0230(8) Uani 1 1 d . . . . .
C17 C 0.8722(3) -0.1017(2) 0.9449(3) 0.0326(10) Uani 1 1 d . . . . .
H17 H 0.858617 -0.093997 0.999928 0.039 Uiso 1 1 calc R U . . .
C18 C 0.9293(3) -0.1615(3) 0.9276(3) 0.0359(10) Uani 1 1 d . . . . .
H18 H 0.955387 -0.195227 0.970184 0.043 Uiso 1 1 calc R U . . .
C19 C 0.9488(3) -0.1723(2) 0.8464(3) 0.0341(10) Uani 1 1 d . . . . .
H19 H 0.987787 -0.213747 0.832935 0.041 Uiso 1 1 calc R U . . .
C20 C 0.9105(2) -0.1219(2) 0.7865(3) 0.0285(9) Uani 1 1 d . . . . .
H20 H 0.922750 -0.130016 0.731166 0.034 Uiso 1 1 calc R U . . .
C21 C 0.8427(3) -0.1078(2) 0.4805(2) 0.0263(9) Uani 1 1 d . . . . .
H21 H 0.896123 -0.087662 0.460918 0.032 Uiso 1 1 calc R U . . .
C22 C 0.7900(3) -0.1583(2) 0.4306(3) 0.0340(10) Uani 1 1 d . . . . .
H22 H 0.808235 -0.175444 0.379399 0.041 Uiso 1 1 calc R U . . .
C23 C 0.7097(3) -0.1836(3) 0.4569(2) 0.0352(10) Uani 1 1 d . . . . .
H23 H 0.670318 -0.217253 0.422980 0.042 Uiso 1 1 calc R U . . .
C24 C 0.6867(3) -0.1601(2) 0.5322(2) 0.0302(9) Uani 1 1 d . . . . .
H24 H 0.630344 -0.175814 0.549594 0.036 Uiso 1 1 calc R U . . .
C25 C 0.7462(2) -0.1128(2) 0.5838(2) 0.0243(9) Uani 1 1 d . . . . .
C26 C 0.6766(2) -0.1308(2) 0.7098(2) 0.0245(9) Uani 1 1 d . . . . .
C27 C 0.6559(3) -0.2121(2) 0.7009(2) 0.0296(9) Uani 1 1 d . . . . .
H27 H 0.681341 -0.242238 0.659997 0.035 Uiso 1 1 calc R U . . .
C28 C 0.5994(3) -0.2475(2) 0.7508(3) 0.0328(10) Uani 1 1 d . . . . .
H28 H 0.583371 -0.301492 0.742444 0.039 Uiso 1 1 calc R U . . .
C29 C 0.5655(3) -0.2052(2) 0.8134(3) 0.0321(10) Uani 1 1 d . . . . .
H29 H 0.524407 -0.228438 0.847181 0.038 Uiso 1 1 calc R U . . .
C30 C 0.5934(2) -0.1292(2) 0.8243(2) 0.0282(9) Uani 1 1 d . . . . .
H30 H 0.574550 -0.101089 0.869857 0.034 Uiso 1 1 calc R U . . .
C31 C 1.0844(2) 0.0690(2) 0.7248(2) 0.0290(9) Uani 1 1 d . . . . .
H31 H 1.114823 0.036958 0.688643 0.035 Uiso 1 1 calc R U . . .
C32 C 1.1358(3) 0.1127(3) 0.7830(2) 0.0325(10) Uani 1 1 d . . . . .
H32 H 1.200057 0.112506 0.785783 0.039 Uiso 1 1 calc R U . . .
C33 C 1.0917(3) 0.1573(2) 0.8377(2) 0.0305(10) Uani 1 1 d . . . . .
H33 H 1.125437 0.188152 0.878803 0.037 Uiso 1 1 calc R U . . .
C34 C 0.9982(2) 0.1562(2) 0.8318(2) 0.0257(9) Uani 1 1 d . . . . .
H34 H 0.967482 0.185062 0.870234 0.031 Uiso 1 1 calc R U . . .
C35 C 0.9484(2) 0.1128(2) 0.7692(2) 0.0222(8) Uani 1 1 d . . . . .
C36 C 0.8013(2) 0.1663(2) 0.7836(2) 0.0227(8) Uani 1 1 d . . . . .
C37 C 0.8252(2) 0.2467(2) 0.7891(2) 0.0249(9) Uani 1 1 d . . . . .
H37 H 0.885530 0.262183 0.782612 0.030 Uiso 1 1 calc R U . . .
C38 C 0.7630(3) 0.3024(2) 0.8036(2) 0.0287(9) Uani 1 1 d . . . . .
H38 H 0.780033 0.356466 0.807803 0.034 Uiso 1 1 calc R U . . .
C39 C 0.6740(3) 0.2802(2) 0.8123(2) 0.0292(9) Uani 1 1 d . . . . .
H39 H 0.629143 0.318513 0.820574 0.035 Uiso 1 1 calc R U . . .
C40 C 0.6536(2) 0.2017(2) 0.8086(2) 0.0266(9) Uani 1 1 d . . . . .
H40 H 0.592951 0.186222 0.813968 0.032 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ag1 N1 154.93(11) . . ?
N4 Ag1 O1 106.15(11) . . ?
N1 Ag1 O1 98.57(11) . . ?
N4 Ag1 Rh1 77.84(8) . . ?
N1 Ag1 Rh1 77.63(8) . . ?
O1 Ag1 Rh1 175.48(8) . . ?
N10 Ag2 N7 154.41(11) . . ?
N10 Ag2 O4 108.35(10) . . ?
N7 Ag2 O4 95.15(10) . . ?
N10 Ag2 Rh2 78.78(8) . . ?
N7 Ag2 Rh2 75.99(8) . . ?
O4 Ag2 Rh2 164.28(7) . . ?
N2 Rh1 N5 177.83(12) . . ?
N2 Rh1 N12 88.88(12) . . ?
N5 Rh1 N12 90.94(12) . . ?
N2 Rh1 N9 88.23(12) . . ?
N5 Rh1 N9 91.67(12) . . ?
N12 Rh1 N9 172.20(12) . . ?
N2 Rh1 Rh2 89.79(8) . . ?
N5 Rh1 Rh2 88.05(9) . . ?
N12 Rh1 Rh2 86.20(8) . . ?
N9 Rh1 Rh2 86.54(8) . . ?
N2 Rh1 Ag1 92.37(8) . . ?
N5 Rh1 Ag1 89.80(9) . . ?
N12 Rh1 Ag1 92.49(8) . . ?
N9 Rh1 Ag1 94.87(8) . . ?
Rh2 Rh1 Ag1 177.459(16) . . ?
N8 Rh2 N11 177.43(12) . . ?
N8 Rh2 N6 88.10(12) . . ?
N11 Rh2 N6 91.14(12) . . ?
N8 Rh2 N3 90.89(12) . . ?
N11 Rh2 N3 89.50(11) . . ?
N6 Rh2 N3 171.34(11) . . ?
N8 Rh2 Rh1 89.22(8) . . ?
N11 Rh2 Rh1 88.28(8) . . ?
N6 Rh2 Rh1 86.41(8) . . ?
N3 Rh2 Rh1 84.98(8) . . ?
N8 Rh2 Ag2 93.44(8) . . ?
N11 Rh2 Ag2 89.06(8) . . ?
N6 Rh2 Ag2 94.06(8) . . ?
N3 Rh2 Ag2 94.58(8) . . ?
Rh1 Rh2 Ag2 177.309(16) . . ?
N13 O1 Ag1 106.5(2) . . ?
N14 O4 Ag2 97.0(2) . . ?
C1 N1 C5 118.7(3) . . ?
C1 N1 Ag1 113.5(3) . . ?
C5 N1 Ag1 127.7(2) . . ?
C6 N2 C5 124.0(3) . . ?
C6 N2 Rh1 117.8(2) . . ?
C5 N2 Rh1 118.1(2) . . ?
C10 N3 C6 119.0(3) . . ?
C10 N3 Rh2 119.4(2) . . ?
C6 N3 Rh2 121.4(2) . . ?
C11 N4 C15 118.7(3) . . ?
C11 N4 Ag1 113.9(3) . . ?
C15 N4 Ag1 127.3(2) . . ?
C16 N5 C15 124.2(3) . . ?
C16 N5 Rh1 117.7(2) . . ?
C15 N5 Rh1 118.1(2) . . ?
C20 N6 C16 119.4(3) . . ?
C20 N6 Rh2 120.2(3) . . ?
C16 N6 Rh2 120.0(2) . . ?
C21 N7 C25 117.9(3) . . ?
C21 N7 Ag2 111.6(2) . . ?
C25 N7 Ag2 130.6(3) . . ?
C26 N8 C25 122.8(3) . . ?
C26 N8 Rh2 119.1(2) . . ?
C25 N8 Rh2 118.2(2) . . ?
C30 N9 C26 118.3(3) . . ?
C30 N9 Rh1 120.4(3) . . ?
C26 N9 Rh1 121.2(2) . . ?
C31 N10 C35 118.7(3) . . ?
C31 N10 Ag2 114.5(2) . . ?
C35 N10 Ag2 126.8(2) . . ?
C36 N11 C35 121.9(3) . . ?
C36 N11 Rh2 118.1(2) . . ?
C35 N11 Rh2 120.0(2) . . ?
C40 N12 C36 118.9(3) . . ?
C40 N12 Rh1 120.1(2) . . ?
C36 N12 Rh1 120.8(2) . . ?
O3 N13 O2 121.6(4) . . ?
O3 N13 O1 120.1(4) . . ?
O2 N13 O1 118.2(3) . . ?
O6 N14 O5 120.8(4) . . ?
O6 N14 O4 120.7(4) . . ?
O5 N14 O4 118.5(4) . . ?
N1 C1 C2 123.1(4) . . ?
C1 C2 C3 119.1(4) . . ?
C4 C3 C2 118.3(4) . . ?
C3 C4 C5 121.0(4) . . ?
N1 C5 N2 116.0(3) . . ?
N1 C5 C4 119.6(3) . . ?
N2 C5 C4 124.3(3) . . ?
N3 C6 N2 115.9(3) . . ?
N3 C6 C7 119.0(3) . . ?
N2 C6 C7 124.7(3) . . ?
C8 C7 C6 120.8(3) . . ?
C7 C8 C9 119.3(4) . . ?
C10 C9 C8 118.4(4) . . ?
N3 C10 C9 123.4(3) . . ?
N4 C11 C12 123.6(4) . . ?
C11 C12 C13 118.1(4) . . ?
C14 C13 C12 119.9(4) . . ?
C13 C14 C15 119.6(4) . . ?
N4 C15 N5 115.3(3) . . ?
N4 C15 C14 120.1(3) . . ?
N5 C15 C14 124.4(4) . . ?
N5 C16 N6 116.5(3) . . ?
N5 C16 C17 124.0(3) . . ?
N6 C16 C17 119.3(3) . . ?
C18 C17 C16 120.6(4) . . ?
C17 C18 C19 119.3(4) . . ?
C20 C19 C18 118.8(4) . . ?
N6 C20 C19 122.5(4) . . ?
N7 C21 C22 124.3(4) . . ?
C21 C22 C23 117.7(4) . . ?
C24 C23 C22 119.8(4) . . ?
C23 C24 C25 120.2(4) . . ?
N7 C25 N8 115.6(3) . . ?
N7 C25 C24 119.9(3) . . ?
N8 C25 C24 124.5(3) . . ?
N9 C26 N8 116.0(3) . . ?
N9 C26 C27 118.9(3) . . ?
N8 C26 C27 124.9(4) . . ?
C28 C27 C26 120.4(4) . . ?
C27 C28 C29 120.4(4) . . ?
C30 C29 C28 117.1(4) . . ?
C29 C30 N9 124.5(4) . . ?
N10 C31 C32 123.5(4) . . ?
C31 C32 C33 118.4(4) . . ?
C34 C33 C32 119.3(4) . . ?
C33 C34 C35 120.3(4) . . ?
N10 C35 N11 115.8(3) . . ?
N10 C35 C34 119.8(3) . . ?
N11 C35 C34 124.2(3) . . ?
N11 C36 N12 115.8(3) . . ?
N11 C36 C37 125.2(3) . . ?
N12 C36 C37 118.8(3) . . ?
C38 C37 C36 120.7(3) . . ?
C37 C38 C39 119.9(4) . . ?
C40 C39 C38 117.9(4) . . ?
N12 C40 C39 123.4(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N4 2.170(3) . ?
Ag1 N1 2.216(3) . ?
Ag1 O1 2.351(3) . ?
Ag1 Rh1 2.6137(4) . ?
Ag2 N10 2.194(3) . ?
Ag2 N7 2.212(3) . ?
Ag2 O4 2.558(3) . ?
Ag2 Rh2 2.6544(4) . ?
Rh1 N2 2.015(3) . ?
Rh1 N5 2.033(3) . ?
Rh1 N12 2.058(3) . ?
Rh1 N9 2.063(3) . ?
Rh1 Rh2 2.3679(4) . ?
Rh2 N8 2.013(3) . ?
Rh2 N11 2.032(3) . ?
Rh2 N6 2.069(3) . ?
Rh2 N3 2.079(3) . ?
O1 N13 1.275(4) . ?
O2 N13 1.230(4) . ?
O3 N13 1.218(4) . ?
O4 N14 1.270(4) . ?
O5 N14 1.244(4) . ?
O6 N14 1.236(4) . ?
N1 C1 1.358(4) . ?
N1 C5 1.367(5) . ?
N2 C6 1.371(4) . ?
N2 C5 1.373(4) . ?
N3 C10 1.350(4) . ?
N3 C6 1.370(4) . ?
N4 C11 1.353(5) . ?
N4 C15 1.363(5) . ?
N5 C16 1.365(5) . ?
N5 C15 1.370(5) . ?
N6 C20 1.356(5) . ?
N6 C16 1.372(4) . ?
N7 C21 1.352(4) . ?
N7 C25 1.365(5) . ?
N8 C26 1.377(4) . ?
N8 C25 1.379(4) . ?
N9 C30 1.367(4) . ?
N9 C26 1.368(5) . ?
N10 C31 1.356(4) . ?
N10 C35 1.362(4) . ?
N11 C36 1.372(4) . ?
N11 C35 1.372(4) . ?
N12 C40 1.356(4) . ?
N12 C36 1.373(4) . ?
C1 C2 1.360(5) . ?
C2 C3 1.404(6) . ?
C3 C4 1.366(5) . ?
C4 C5 1.407(5) . ?
C6 C7 1.406(5) . ?
C7 C8 1.372(5) . ?
C8 C9 1.385(5) . ?
C9 C10 1.369(5) . ?
C11 C12 1.368(6) . ?
C12 C13 1.387(6) . ?
C13 C14 1.378(6) . ?
C14 C15 1.406(5) . ?
C16 C17 1.409(5) . ?
C17 C18 1.370(6) . ?
C18 C19 1.398(6) . ?
C19 C20 1.374(5) . ?
C21 C22 1.368(5) . ?
C22 C23 1.379(5) . ?
C23 C24 1.369(5) . ?
C24 C25 1.402(5) . ?
C26 C27 1.413(5) . ?
C27 C28 1.369(5) . ?
C28 C29 1.386(6) . ?
C29 C30 1.358(5) . ?
C31 C32 1.369(5) . ?
C32 C33 1.385(5) . ?
C33 C34 1.380(5) . ?
C34 C35 1.403(5) . ?
C36 C37 1.406(5) . ?
C37 C38 1.358(5) . ?
C38 C39 1.394(5) . ?
C39 C40 1.362(5) . ?
