#------------------------------------------------------------------------------
#$Date: 2021-02-05 01:14:54 +0200 (Fri, 05 Feb 2021) $
#$Revision: 261674 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/59/7705978.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7705978
loop_
_publ_author_name
'Cheng, Ming-Chuan'
'Lee, Gene-Hsiang'
'Lin, Tien-Sung'
'Liu, Yu-Chiao'
'Chiang, Ming-Hsi'
'Peng, Shie-Ming'
_publ_section_title
;
 A new series of heteronuclear metal strings,
 MRhRh(dpa)₄Cl₂ and
 MRhRhM(dpa)₄X₂, from the reactions of
 Rh₂(dpa)₄ with metal ions of group 7 to group 12.
;
_journal_issue                   2
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              520
_journal_page_last               534
_journal_paper_doi               10.1039/d0dt03311a
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C41.5 H33.5 Au Cl6.5 N12 Rh2'
_chemical_formula_weight         1333.51
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-09-21 deposited with the CCDC.	2020-12-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 95.1383(9)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.9453(2)
_cell_length_b                   34.2269(9)
_cell_length_c                   15.0001(4)
_cell_measurement_reflns_used    26326
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.50
_cell_measurement_theta_min      1.19
_cell_volume                     4574.1(2)
_computing_cell_refinement       DENZO-SMN
_computing_data_collection       'NONIUS COLLECT'
_computing_data_reduction        DENZO-SMN
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'NONIUS KappaCCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0399
_diffrn_reflns_av_unetI/netI     0.0590
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       44
_diffrn_reflns_limit_k_min       -35
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            26318
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.479
_diffrn_reflns_theta_min         2.246
_exptl_absorpt_coefficient_mu    4.339
_exptl_absorpt_correction_T_max  0.8813
_exptl_absorpt_correction_T_min  0.4291
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SORTAV (Blessing, 1995)'
_exptl_crystal_colour            dark-brown
_exptl_crystal_density_diffrn    1.936
_exptl_crystal_description       plate
_exptl_crystal_F_000             2584
_exptl_crystal_size_max          0.330
_exptl_crystal_size_mid          0.230
_exptl_crystal_size_min          0.030
_refine_diff_density_max         2.400
_refine_diff_density_min         -1.710
_refine_diff_density_rms         0.150
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     577
_refine_ls_number_reflns         10427
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.029
_refine_ls_R_factor_all          0.0771
_refine_ls_R_factor_gt           0.0427
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0324P)²+22.8208P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0856
_refine_ls_wR_factor_ref         0.0985
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7515
_reflns_number_total             10427
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0dt03311a2.cif
_cod_data_source_block           ic17172
_cod_depositor_comments
'Adding full bibliography for 7705966--7705984.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C41.50 H33.50 Au Cl6.50 N12 Rh2'
_cod_database_code               7705978
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.329
_shelx_estimated_absorpt_t_max   0.881
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.90842(3) 0.14053(2) 0.36314(2) 0.03453(8) Uani 1 1 d . . . . .
Cl1 Cl 0.83709(19) 0.19008(6) 0.44917(12) 0.0458(4) Uani 1 1 d . . . . .
Cl2 Cl 0.9852(2) 0.09246(7) 0.27399(14) 0.0602(6) Uani 1 1 d . . . . .
Rh1 Rh 0.49772(4) 0.32196(2) 0.39533(3) 0.01693(10) Uani 1 1 d . . . . .
Rh2 Rh 0.43844(5) 0.38380(2) 0.32594(3) 0.01945(10) Uani 1 1 d . . . . .
N1 N 0.6977(5) 0.32410(14) 0.3404(3) 0.0209(10) Uani 1 1 d . . . . .
N2 N 0.6219(5) 0.37947(14) 0.2577(3) 0.0229(10) Uani 1 1 d . . . . .
N3 N 0.5592(7) 0.43523(17) 0.1762(4) 0.0451(15) Uani 1 1 d . . . . .
N4 N 0.2918(5) 0.32373(14) 0.4492(3) 0.0202(10) Uani 1 1 d . . . . .
N5 N 0.2525(5) 0.38554(14) 0.3914(3) 0.0228(10) Uani 1 1 d . . . . .
N6 N 0.2731(6) 0.43907(15) 0.3113(3) 0.0330(12) Uani 1 1 d . . . . .
N7 N 0.3291(5) 0.35486(14) 0.2206(3) 0.0205(10) Uani 1 1 d . . . . .
N8 N 0.3992(5) 0.29438(13) 0.2856(3) 0.0186(10) Uani 1 1 d . . . . .
N9 N 0.2262(5) 0.24249(15) 0.2651(3) 0.0262(11) Uani 1 1 d . . . . .
N10 N 0.5669(5) 0.40937(14) 0.4318(3) 0.0237(11) Uani 1 1 d . . . . .
N11 N 0.5917(5) 0.35027(14) 0.5029(3) 0.0202(10) Uani 1 1 d . . . . .
N12 N 0.5932(5) 0.28601(14) 0.5210(3) 0.0198(10) Uani 1 1 d . . . . .
C1 C 0.8026(6) 0.29620(18) 0.3631(3) 0.0251(13) Uani 1 1 d . . . . .
H1 H 0.782814 0.278053 0.408502 0.030 Uiso 1 1 calc R U . . .
C2 C 0.9347(6) 0.2927(2) 0.3245(4) 0.0320(15) Uani 1 1 d . . . . .
H2 H 1.003149 0.272185 0.341031 0.038 Uiso 1 1 calc R U . . .
C3 C 0.9657(7) 0.3201(2) 0.2603(4) 0.0376(16) Uani 1 1 d . . . . .
H3 H 1.056310 0.318618 0.231973 0.045 Uiso 1 1 calc R U . . .
C4 C 0.8652(7) 0.3492(2) 0.2385(4) 0.0334(15) Uani 1 1 d . . . . .
H4 H 0.888193 0.368464 0.196247 0.040 Uiso 1 1 calc R U . . .
C5 C 0.7278(6) 0.35119(18) 0.2773(3) 0.0236(13) Uani 1 1 d . . . . .
C6 C 0.6110(7) 0.39852(18) 0.1743(4) 0.0280(13) Uani 1 1 d . . . . .
C7 C 0.6367(8) 0.3797(2) 0.0948(4) 0.0352(15) Uani 1 1 d . . . . .
H7 H 0.675101 0.353815 0.095622 0.042 Uiso 1 1 calc R U . . .
C8 C 0.6058(10) 0.3992(2) 0.0150(5) 0.056(2) Uani 1 1 d . . . . .
H8 H 0.624589 0.387089 -0.039839 0.068 Uiso 1 1 calc R U . . .
C9 C 0.5478(13) 0.4362(3) 0.0153(5) 0.075(3) Uani 1 1 d . . . . .
H9 H 0.523005 0.449803 -0.039208 0.090 Uiso 1 1 calc R U . . .
C10 C 0.5260(11) 0.4532(2) 0.0971(5) 0.063(3) Uani 1 1 d . . . . .
H10 H 0.485696 0.478923 0.097208 0.076 Uiso 1 1 calc R U . . .
C11 C 0.2468(6) 0.29244(18) 0.4943(4) 0.0243(12) Uani 1 1 d . . . . .
H11 H 0.302905 0.268923 0.492793 0.029 Uiso 1 1 calc R U . . .
C12 C 0.1227(6) 0.2931(2) 0.5425(4) 0.0313(14) Uani 1 1 d . . . . .
H12 H 0.092202 0.270380 0.572381 0.038 Uiso 1 1 calc R U . . .
C13 C 0.0432(7) 0.3279(2) 0.5461(4) 0.0340(16) Uani 1 1 d . . . . .
H13 H -0.039114 0.329678 0.581775 0.041 Uiso 1 1 calc R U . . .
C14 C 0.0836(6) 0.35961(19) 0.4984(4) 0.0279(13) Uani 1 1 d . . . . .
H14 H 0.029246 0.383371 0.500791 0.034 Uiso 1 1 calc R U . . .
C15 C 0.2076(6) 0.35708(17) 0.4447(3) 0.0219(12) Uani 1 1 d . . . . .
C16 C 0.1775(7) 0.41844(18) 0.3579(4) 0.0277(13) Uani 1 1 d . . . . .
C17 C 0.0283(8) 0.4298(2) 0.3606(5) 0.0449(18) Uani 1 1 d . . . . .
H17 H -0.038727 0.414784 0.392414 0.054 Uiso 1 1 calc R U . . .
C18 C -0.0195(10) 0.4633(3) 0.3158(5) 0.060(2) Uani 1 1 d . . . . .
H18 H -0.120314 0.471860 0.316676 0.072 Uiso 1 1 calc R U . . .
C19 C 0.0810(11) 0.4844(2) 0.2694(5) 0.060(2) Uani 1 1 d . . . . .
H19 H 0.049758 0.507638 0.238530 0.072 Uiso 1 1 calc R U . . .
C20 C 0.2241(9) 0.4716(2) 0.2686(4) 0.0440(18) Uani 1 1 d . . . . .
H20 H 0.292118 0.486153 0.236594 0.053 Uiso 1 1 calc R U . . .
C21 C 0.2615(7) 0.3758(2) 0.1511(4) 0.0310(14) Uani 1 1 d . . . . .
H21 H 0.254530 0.403378 0.156961 0.037 Uiso 1 1 calc R U . . .
C22 C 0.2029(7) 0.3586(2) 0.0729(4) 0.0336(15) Uani 1 1 d . . . . .
H22 H 0.150767 0.373781 0.027084 0.040 Uiso 1 1 calc R U . . .
C23 C 0.2213(7) 0.31871(19) 0.0622(4) 0.0298(14) Uani 1 1 d . . . . .
H23 H 0.186612 0.306389 0.007506 0.036 Uiso 1 1 calc R U . . .
C24 C 0.2898(6) 0.29729(19) 0.1310(3) 0.0257(13) Uani 1 1 d . . . . .
H24 H 0.304695 0.270050 0.123453 0.031 Uiso 1 1 calc R U . . .
C25 C 0.3389(6) 0.31527(17) 0.2133(3) 0.0199(12) Uani 1 1 d . . . . .
C26 C 0.3647(6) 0.25475(16) 0.2950(3) 0.0196(11) Uani 1 1 d . . . . .
C27 C 0.4691(6) 0.23006(17) 0.3411(4) 0.0244(12) Uani 1 1 d . . . . .
H27 H 0.565361 0.239676 0.362336 0.029 Uiso 1 1 calc R U . . .
C28 C 0.4319(7) 0.19185(19) 0.3556(4) 0.0323(14) Uani 1 1 d . . . . .
H28 H 0.502129 0.174655 0.386413 0.039 Uiso 1 1 calc R U . . .
C29 C 0.2891(7) 0.17865(19) 0.3243(4) 0.0323(14) Uani 1 1 d . . . . .
H29 H 0.259436 0.152394 0.333275 0.039 Uiso 1 1 calc R U . . .
C30 C 0.1930(7) 0.20494(19) 0.2801(4) 0.0307(14) Uani 1 1 d . . . . .
H30 H 0.095990 0.195902 0.258602 0.037 Uiso 1 1 calc R U . . .
C31 C 0.5992(7) 0.44781(18) 0.4255(4) 0.0286(13) Uani 1 1 d . . . . .
H31 H 0.553020 0.462131 0.376182 0.034 Uiso 1 1 calc R U . . .
C32 C 0.6956(8) 0.4672(2) 0.4870(4) 0.0363(15) Uani 1 1 d . . . . .
H32 H 0.714240 0.494319 0.481078 0.044 Uiso 1 1 calc R U . . .
C33 C 0.7651(7) 0.44581(19) 0.5581(4) 0.0349(15) Uani 1 1 d . . . . .
H33 H 0.833642 0.458271 0.601096 0.042 Uiso 1 1 calc R U . . .
C34 C 0.7345(6) 0.40691(19) 0.5660(4) 0.0275(13) Uani 1 1 d . . . . .
H34 H 0.782531 0.392360 0.614298 0.033 Uiso 1 1 calc R U . . .
C35 C 0.6323(6) 0.38819(17) 0.5028(3) 0.0219(12) Uani 1 1 d . . . . .
C36 C 0.6298(6) 0.32032(18) 0.5629(3) 0.0221(12) Uani 1 1 d . . . . .
C37 C 0.6895(6) 0.32113(18) 0.6522(4) 0.0262(13) Uani 1 1 d . . . . .
H37 H 0.709734 0.345211 0.682412 0.031 Uiso 1 1 calc R U . . .
C38 C 0.7182(7) 0.2860(2) 0.6952(4) 0.0308(14) Uani 1 1 d . . . . .
H38 H 0.762092 0.285758 0.755304 0.037 Uiso 1 1 calc R U . . .
C39 C 0.6840(7) 0.25115(19) 0.6522(4) 0.0303(14) Uani 1 1 d . . . . .
H39 H 0.704195 0.226882 0.681571 0.036 Uiso 1 1 calc R U . . .
C40 C 0.6193(6) 0.25253(18) 0.5650(4) 0.0235(12) Uani 1 1 d . . . . .
H40 H 0.592388 0.228694 0.535383 0.028 Uiso 1 1 calc R U . . .
C41 C 0.3649(8) 0.0723(2) 0.2264(4) 0.0435(17) Uani 1 1 d . . . . .
H41 H 0.283107 0.086731 0.253643 0.052 Uiso 1 1 calc R U . . .
Cl3 Cl 0.3549(3) 0.02253(6) 0.25331(15) 0.0641(6) Uani 1 1 d . . . . .
Cl4 Cl 0.5392(3) 0.09058(7) 0.26961(13) 0.0664(6) Uani 1 1 d . . . . .
Cl5 Cl 0.3401(3) 0.07699(9) 0.10896(15) 0.0870(9) Uani 1 1 d . . . . .
C42 C 0.0090(16) 0.0244(3) 0.4941(9) 0.255(5) Uani 0.5 1 d . U P . .
H42 H -0.030299 0.031338 0.431635 0.305 Uiso 0.5 1 calc R U P A .
Cl6 Cl -0.0610(9) 0.0556(3) 0.5615(5) 0.137(3) Uani 0.5 1 d . . P A -1
Cl7 Cl 0.1868(8) 0.0284(3) 0.5006(5) 0.145(3) Uani 0.5 1 d . U P A -1
Cl8 Cl 0.0090(16) 0.0244(3) 0.4941(9) 0.255(5) Uani 0.5 1 d . . P A -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl1 Au1 Cl2 177.81(8) . . ?
N11 Rh1 N8 178.62(18) . . ?
N11 Rh1 N1 89.31(17) . . ?
N8 Rh1 N1 91.28(17) . . ?
N11 Rh1 N4 89.72(17) . . ?
N8 Rh1 N4 89.61(17) . . ?
N1 Rh1 N4 176.14(19) . . ?
N11 Rh1 N12 60.65(17) . . ?
N8 Rh1 N12 120.54(17) . . ?
N1 Rh1 N12 94.25(16) . . ?
N4 Rh1 N12 88.53(16) . . ?
N11 Rh1 Rh2 89.04(13) . . ?
N8 Rh1 Rh2 89.74(13) . . ?
N1 Rh1 Rh2 87.76(13) . . ?
N4 Rh1 Rh2 88.49(13) . . ?
N12 Rh1 Rh2 149.55(11) . . ?
N5 Rh2 N2 177.18(19) . . ?
N5 Rh2 N7 91.87(18) . . ?
N2 Rh2 N7 85.79(18) . . ?
N5 Rh2 N10 92.27(18) . . ?
N2 Rh2 N10 89.95(18) . . ?
N7 Rh2 N10 174.31(18) . . ?
N5 Rh2 Rh1 88.54(13) . . ?
N2 Rh2 Rh1 89.83(14) . . ?
N7 Rh2 Rh1 88.83(13) . . ?
N10 Rh2 Rh1 87.38(14) . . ?
N5 Rh2 N6 59.34(18) . . ?
N2 Rh2 N6 122.34(19) . . ?
N7 Rh2 N6 93.63(17) . . ?
N10 Rh2 N6 91.84(18) . . ?
Rh1 Rh2 N6 147.83(13) . . ?
C1 N1 C5 118.3(5) . . ?
C1 N1 Rh1 119.0(4) . . ?
C5 N1 Rh1 122.6(4) . . ?
C5 N2 C6 120.7(5) . . ?
C5 N2 Rh2 121.5(4) . . ?
C6 N2 Rh2 115.0(4) . . ?
C6 N3 C10 117.3(6) . . ?
C11 N4 C15 120.0(5) . . ?
C11 N4 Rh1 119.2(4) . . ?
C15 N4 Rh1 120.6(4) . . ?
C15 N5 C16 130.2(5) . . ?
C15 N5 Rh2 125.1(4) . . ?
C16 N5 Rh2 104.1(4) . . ?
C20 N6 C16 119.1(6) . . ?
C20 N6 Rh2 150.7(5) . . ?
C16 N6 Rh2 87.4(4) . . ?
C21 N7 C25 119.3(5) . . ?
C21 N7 Rh2 119.1(4) . . ?
C25 N7 Rh2 121.0(3) . . ?
C25 N8 C26 120.7(4) . . ?
C25 N8 Rh1 120.8(4) . . ?
C26 N8 Rh1 116.9(3) . . ?
C30 N9 C26 116.9(5) . . ?
C31 N10 C35 119.2(5) . . ?
C31 N10 Rh2 117.7(4) . . ?
C35 N10 Rh2 122.7(4) . . ?
C35 N11 C36 131.5(5) . . ?
C35 N11 Rh1 124.0(4) . . ?
C36 N11 Rh1 103.1(3) . . ?
C40 N12 C36 119.4(5) . . ?
C40 N12 Rh1 152.1(4) . . ?
C36 N12 Rh1 88.5(3) . . ?
N1 C1 C2 124.0(6) . . ?
C1 C2 C3 117.9(6) . . ?
C4 C3 C2 119.5(6) . . ?
C3 C4 C5 121.2(6) . . ?
N2 C5 N1 116.9(5) . . ?
N2 C5 C4 124.0(6) . . ?
N1 C5 C4 119.1(5) . . ?
N3 C6 C7 122.4(6) . . ?
N3 C6 N2 114.3(5) . . ?
C7 C6 N2 122.9(6) . . ?
C8 C7 C6 119.0(7) . . ?
C9 C8 C7 119.5(7) . . ?
C8 C9 C10 118.4(7) . . ?
N3 C10 C9 123.3(7) . . ?
N4 C11 C12 122.8(6) . . ?
C11 C12 C13 118.2(6) . . ?
C14 C13 C12 119.9(5) . . ?
C13 C14 C15 120.1(6) . . ?
N5 C15 N4 116.2(5) . . ?
N5 C15 C14 125.4(5) . . ?
N4 C15 C14 118.4(5) . . ?
N6 C16 N5 107.7(5) . . ?
N6 C16 C17 121.4(6) . . ?
N5 C16 C17 130.7(6) . . ?
C18 C17 C16 118.3(7) . . ?
C17 C18 C19 119.4(7) . . ?
C20 C19 C18 119.4(7) . . ?
N6 C20 C19 122.3(7) . . ?
N7 C21 C22 122.5(6) . . ?
C21 C22 C23 118.7(6) . . ?
C24 C23 C22 119.4(5) . . ?
C23 C24 C25 120.6(6) . . ?
N7 C25 N8 118.6(5) . . ?
N7 C25 C24 119.1(5) . . ?
N8 C25 C24 122.3(5) . . ?
N9 C26 C27 122.1(5) . . ?
N9 C26 N8 118.2(5) . . ?
C27 C26 N8 119.5(5) . . ?
C28 C27 C26 119.7(5) . . ?
C27 C28 C29 118.9(6) . . ?
C30 C29 C28 117.7(6) . . ?
N9 C30 C29 124.7(6) . . ?
N10 C31 C32 123.1(6) . . ?
C31 C32 C33 118.1(6) . . ?
C34 C33 C32 119.9(6) . . ?
C33 C34 C35 120.5(6) . . ?
N11 C35 N10 114.4(5) . . ?
N11 C35 C34 126.5(5) . . ?
N10 C35 C34 119.1(5) . . ?
N12 C36 N11 107.7(4) . . ?
N12 C36 C37 121.1(5) . . ?
N11 C36 C37 131.2(6) . . ?
C38 C37 C36 118.1(6) . . ?
C39 C38 C37 120.8(5) . . ?
C38 C39 C40 118.1(6) . . ?
N12 C40 C39 122.5(6) . . ?
Cl4 C41 Cl3 108.9(4) . . ?
Cl4 C41 Cl5 111.4(4) . . ?
Cl3 C41 Cl5 108.3(4) . . ?
Cl7 C42 Cl6 110.1(8) . . ?
Cl7 C42 C42 100.5(13) . 3_556 ?
Cl6 C42 C42 122.5(12) . 3_556 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Cl1 2.2573(18) . ?
Au1 Cl2 2.265(2) . ?
Rh1 N11 2.002(4) . ?
Rh1 N8 2.029(4) . ?
Rh1 N1 2.037(4) . ?
Rh1 N4 2.077(4) . ?
Rh1 N12 2.347(4) . ?
Rh1 Rh2 2.3969(6) . ?
Rh2 N5 2.006(4) . ?
Rh2 N2 2.016(4) . ?
Rh2 N7 2.039(4) . ?
Rh2 N10 2.069(4) . ?
Rh2 N6 2.399(5) . ?
N1 C1 1.360(7) . ?
N1 C5 1.369(7) . ?
N2 C5 1.368(8) . ?
N2 C6 1.407(7) . ?
N3 C6 1.341(8) . ?
N3 C10 1.347(9) . ?
N4 C11 1.348(7) . ?
N4 C15 1.366(7) . ?
N5 C15 1.344(7) . ?
N5 C16 1.382(7) . ?
N6 C20 1.337(8) . ?
N6 C16 1.351(8) . ?
N7 C21 1.362(7) . ?
N7 C25 1.363(7) . ?
N8 C25 1.369(7) . ?
N8 C26 1.401(7) . ?
N9 C30 1.343(8) . ?
N9 C26 1.346(7) . ?
N10 C31 1.352(7) . ?
N10 C35 1.375(7) . ?
N11 C35 1.348(7) . ?
N11 C36 1.386(7) . ?
N12 C40 1.332(7) . ?
N12 C36 1.358(7) . ?
C1 C2 1.367(8) . ?
C2 C3 1.391(9) . ?
C3 C4 1.360(9) . ?
C4 C5 1.408(8) . ?
C6 C7 1.392(8) . ?
C7 C8 1.377(9) . ?
C8 C9 1.366(11) . ?
C9 C10 1.389(10) . ?
C11 C12 1.378(8) . ?
C12 C13 1.392(9) . ?
C13 C14 1.366(9) . ?
C14 C15 1.430(8) . ?
C16 C17 1.394(9) . ?
C17 C18 1.377(10) . ?
C18 C19 1.388(12) . ?
C19 C20 1.354(11) . ?
C21 C22 1.373(8) . ?
C22 C23 1.387(9) . ?
C23 C24 1.365(8) . ?
C24 C25 1.414(7) . ?
C26 C27 1.396(8) . ?
C27 C28 1.372(8) . ?
C28 C29 1.396(9) . ?
C29 C30 1.374(9) . ?
C31 C32 1.375(8) . ?
C32 C33 1.393(9) . ?
C33 C34 1.366(9) . ?
C34 C35 1.410(8) . ?
C36 C37 1.397(7) . ?
C37 C38 1.379(8) . ?
C38 C39 1.376(9) . ?
C39 C40 1.382(8) . ?
C41 Cl4 1.750(8) . ?
C41 Cl3 1.754(7) . ?
C41 Cl5 1.763(7) . ?
C42 Cl7 1.590(14) . ?
C42 Cl6 1.632(14) . ?
C42 C42 1.69(2) 3_556 ?
