#------------------------------------------------------------------------------
#$Date: 2021-02-05 01:18:54 +0200 (Fri, 05 Feb 2021) $
#$Revision: 261693 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/59/7705986.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7705986
loop_
_publ_author_name
'Yeo, Alyssa'
'Sanz, Corey A.'
'Fryzuk, Michael D.'
_publ_section_title
;
 Forays into rhodium macrocyclic chemistry stabilized by a
 P₂N₂ donor set. Activation of dihydrogen and
 benzene.
;
_journal_issue                   3
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              899
_journal_page_last               907
_journal_paper_doi               10.1039/d0dt03688a
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         '2(C26 H45 Li N2 O P2 Rh Si4), C6 H14'
_chemical_formula_sum            'C58 H104 Li2 N4 O2 P4 Rh2 Si8'
_chemical_formula_weight         1457.75
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_date             2020-03-03
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2020-05-16 deposited with the CCDC.	2020-12-02 downloaded from the CCDC.
;
_cell_angle_alpha                101.806(7)
_cell_angle_beta                 108.701(5)
_cell_angle_gamma                90.185(7)
_cell_formula_units_Z            2
_cell_length_a                   13.1434(14)
_cell_length_b                   15.766(2)
_cell_length_c                   19.777(2)
_cell_measurement_reflns_used    9918
_cell_measurement_temperature    90(2)
_cell_measurement_theta_max      30.518
_cell_measurement_theta_min      2.433
_cell_volume                     3789.2(8)
_computing_cell_refinement       'SAINT V8.40A (2016)'
_computing_data_reduction        'SAINT V8.40A (2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_diffrn_ambient_temperature      90.0
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_unetI/netI     0.0950
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            22984
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.692
_diffrn_reflns_theta_min         2.265
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.685
_exptl_absorpt_correction_T_max  0.973
_exptl_absorpt_correction_T_min  0.785
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 TWINABS-2012/1 (Bruker,2012) was used for absorption correction.

Final HKLF 4 output contains 93347 reflections, Rint = 0.1029
 (29896 with I > 3sig(I), Rint = 0.0721)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.278
_exptl_crystal_description       prisms
_exptl_crystal_F_000             1528
_exptl_crystal_size_max          0.48
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.04
_refine_diff_density_max         2.789
_refine_diff_density_min         -2.150
_refine_diff_density_rms         0.172
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     738
_refine_ls_number_reflns         22984
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.1015
_refine_ls_R_factor_gt           0.0641
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0828P)²+4.2298P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1492
_refine_ls_wR_factor_ref         0.1685
_reflns_Friedel_coverage         0.000
_reflns_number_gt                16311
_reflns_number_total             22984
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0dt03688a2.cif
_cod_data_source_block           mf1441_4-new
_cod_depositor_comments
'Adding full bibliography for 7705986--7705991.cif.'
_cod_original_cell_volume        3789.4(8)
_cod_database_code               7705986
_shelx_shelxl_version_number     2016/4
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.973
_shelx_estimated_absorpt_t_min   0.735
_olex2_refinement_description
;
1. Twinned data refinement
 Scales: 0.5023(11)
 0.4977(11)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
3.a Secondary CH2 refined with riding coordinates:
 C12A(H12A,H12B), C19(H19C,H19D), C19A(H19A,H19B), C12(H12C,H12D), C26(H26C,
 H26D), C7(H7A,H7B), C26A(H26A,H26B), C9A(H9AA,H9AB), C25A(H25A,H25B), C25(H25C,
 H25D), C24(H24C,H24D), C7A(H7AA,H7AB), C11(H11D,H11E), C30(H30A,H30B),
 C29(H29A,H29B), C24A(H24A,H24B), C28(H28A,H28B), C31(H31A,H31B)
3.b Aromatic/amide H refined with riding coordinates:
 C17(H17), C14(H14), C4(H4), C3(H3), C18A(H18A), C6(H6), C2(H2), C14A(H14A),
 C18(H18), C3A(H3A), C15(H15), C5A(H5A), C17A(H17A), C6A(H6A), C2A(H2A),
 C16A(H16A), C15A(H15A), C4A(H4A), C5(H5), C16(H16)
3.c Idealised Me refined as rotating group:
 C11A(H11A,H11B,H11C), C21(H21D,H21E,H21F), C21A(H21A,H21B,H21C), C10(H10D,
 H10E,H10F), C10A(H10A,H10B,H10C), C20A(H20A,H20B,H20C), C8A(H8AA,H8AB,H8AC),
 C8(H8A,H8B,H8C), C23A(H23A,H23B,H23C), C22(H22D,H22E,H22F), C23(H23D,H23E,
 H23F), C20(H20D,H20E,H20F), C22A(H22A,H22B,H22C), C27(H27A,H27B,H27C),
 C32(H32A,H32B,H32C), C9(H9A,H9B,H9C)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1A Rh 0.66805(4) 0.85728(3) 0.75455(3) 0.01547(10) Uani 1 1 d . . . . .
Rh1 Rh 0.83391(4) 0.48990(3) 0.24523(3) 0.01525(10) Uani 1 1 d . . . . .
P2 P 0.66707(13) 0.53845(10) 0.20446(9) 0.0182(3) Uani 1 1 d . . . . .
Si3 Si 0.82215(14) 0.69246(10) 0.23066(9) 0.0189(4) Uani 1 1 d . . . . .
Si2 Si 0.69246(14) 0.43387(11) 0.06569(9) 0.0185(4) Uani 1 1 d . . . . .
Si1A Si 0.81061(14) 0.90051(10) 0.93283(9) 0.0189(4) Uani 1 1 d . . . . .
P1A P 0.83385(13) 0.92794(9) 0.79158(9) 0.0181(3) Uani 1 1 d . . . . .
P1 P 0.99922(13) 0.43427(9) 0.27442(8) 0.0163(3) Uani 1 1 d . . . . .
Si3A Si 0.45906(14) 0.96870(11) 0.72091(10) 0.0198(4) Uani 1 1 d . . . . .
Si2A Si 0.64599(14) 0.74566(10) 0.87029(9) 0.0181(3) Uani 1 1 d . . . . .
P2A P 0.50445(13) 0.78511(9) 0.72763(8) 0.0162(3) Uani 1 1 d . . . . .
Si4A Si 0.67557(15) 1.06911(10) 0.76877(9) 0.0199(4) Uani 1 1 d . . . . .
Si1 Si 0.85828(14) 0.31626(10) 0.13348(9) 0.0180(3) Uani 1 1 d . . . . .
Si4 Si 1.04195(14) 0.62208(10) 0.27365(10) 0.0195(4) Uani 1 1 d . . . . .
O1A O 0.5202(4) 0.9863(3) 0.9325(2) 0.0263(10) Uani 1 1 d . . . . .
N1A N 0.6900(4) 0.8496(3) 0.8751(3) 0.0189(11) Uani 1 1 d . . . . .
N2 N 0.9070(4) 0.6106(3) 0.2241(3) 0.0165(10) Uani 1 1 d . . . . .
O1 O 0.9804(4) 0.5238(3) 0.0673(2) 0.0255(10) Uani 1 1 d . . . . .
C12A C 0.5130(5) 0.7154(4) 0.7929(3) 0.0188(12) Uani 1 1 d . . . . .
H12A H 0.509048 0.653549 0.768239 0.023 Uiso 1 1 calc R . . . .
H12B H 0.452258 0.723983 0.812377 0.023 Uiso 1 1 calc R . . . .
C17 C 0.3920(6) 0.5737(5) 0.2598(4) 0.0397(18) Uani 1 1 d . . . . .
H17 H 0.322648 0.593289 0.240009 0.048 Uiso 1 1 calc R . . . .
N1 N 0.8131(4) 0.4162(3) 0.1258(3) 0.0163(10) Uani 1 1 d . . . . .
C14 C 0.5945(5) 0.5176(4) 0.3185(3) 0.0251(13) Uani 1 1 d . . . . .
H14 H 0.664383 0.499618 0.339687 0.030 Uiso 1 1 calc R . . . .
C19 C 0.6779(5) 0.6459(4) 0.1828(3) 0.0218(13) Uani 1 1 d . . . . .
H19C H 0.628127 0.684722 0.200039 0.026 Uiso 1 1 calc R . . . .
H19D H 0.658881 0.639847 0.129275 0.026 Uiso 1 1 calc R . . . .
C1 C 1.0741(5) 0.4137(4) 0.3639(3) 0.0189(11) Uani 1 1 d . . . . .
C1A C 0.9280(5) 0.9068(4) 0.7405(4) 0.0238(14) Uani 1 1 d . . . . .
N2A N 0.5931(4) 0.9871(3) 0.7737(3) 0.0197(11) Uani 1 1 d . . . . .
C11A C 0.7402(6) 0.6609(4) 0.8515(4) 0.0293(16) Uani 1 1 d . . . . .
H11A H 0.744947 0.658226 0.802676 0.044 Uiso 1 1 calc GR . . . .
H11B H 0.712759 0.604139 0.853949 0.044 Uiso 1 1 calc GR . . . .
H11C H 0.811884 0.676342 0.888164 0.044 Uiso 1 1 calc GR . . . .
C19A C 0.4107(5) 0.8662(4) 0.7420(3) 0.0215(12) Uani 1 1 d . . . . .
H19A H 0.410974 0.877318 0.793130 0.026 Uiso 1 1 calc R . . . .
H19B H 0.336630 0.846089 0.708931 0.026 Uiso 1 1 calc R . . . .
C4 C 1.1839(6) 0.3771(4) 0.4999(4) 0.0301(14) Uani 1 1 d . . . . .
H4 H 1.221101 0.365295 0.546428 0.036 Uiso 1 1 calc R . . . .
C12 C 0.5948(5) 0.4658(4) 0.1174(3) 0.0224(13) Uani 1 1 d . . . . .
H12C H 0.535301 0.495340 0.088551 0.027 Uiso 1 1 calc R . . . .
H12D H 0.563638 0.413321 0.125987 0.027 Uiso 1 1 calc R . . . .
C3 C 1.2331(5) 0.3693(4) 0.4479(4) 0.0276(13) Uani 1 1 d . . . . .
H3 H 1.304585 0.351707 0.458225 0.033 Uiso 1 1 calc R . . . .
C26 C 1.0437(5) 0.4527(4) 0.0537(3) 0.0241(14) Uani 1 1 d . . . . .
H26C H 1.035114 0.408475 0.080915 0.029 Uiso 1 1 calc R . . . .
H26D H 1.120692 0.473593 0.071109 0.029 Uiso 1 1 calc R . . . .
C18A C 0.3297(5) 0.6776(4) 0.6216(3) 0.0241(13) Uani 1 1 d . . . . .
H18A H 0.293000 0.689562 0.656460 0.029 Uiso 1 1 calc R . . . .
C21 C 0.8265(6) 0.7449(5) 0.3254(4) 0.0336(15) Uani 1 1 d . . . . .
H21D H 0.810828 0.700478 0.349648 0.050 Uiso 1 1 calc GR . . . .
H21E H 0.772641 0.787970 0.323146 0.050 Uiso 1 1 calc GR . . . .
H21F H 0.898307 0.773565 0.353208 0.050 Uiso 1 1 calc GR . . . .
C7 C 0.9924(5) 0.3303(4) 0.2112(3) 0.0197(12) Uani 1 1 d . . . . .
H7A H 0.998076 0.282131 0.237164 0.024 Uiso 1 1 calc R . . . .
H7B H 1.052783 0.329300 0.191418 0.024 Uiso 1 1 calc R . . . .
C6 C 1.0243(6) 0.4210(4) 0.4168(3) 0.0252(13) Uani 1 1 d . . . . .
H6 H 0.952878 0.438661 0.406453 0.030 Uiso 1 1 calc R . . . .
C26A C 0.5089(6) 1.0719(4) 0.9703(4) 0.0280(15) Uani 1 1 d . . . . .
H26A H 0.432970 1.086243 0.952377 0.034 Uiso 1 1 calc R . . . .
H26B H 0.554205 1.115020 0.960499 0.034 Uiso 1 1 calc R . . . .
C9A C 0.7908(5) 1.0155(4) 0.9738(4) 0.0277(15) Uani 1 1 d . . . . .
H9AA H 0.832374 1.061900 0.964768 0.033 Uiso 1 1 calc R . . . .
H9AB H 0.788625 1.026527 1.024397 0.033 Uiso 1 1 calc R . . . .
C25A C 0.4576(6) 0.9241(4) 0.9492(4) 0.0293(16) Uani 1 1 d . . . . .
H25A H 0.466086 0.864994 0.923640 0.035 Uiso 1 1 calc R . . . .
H25B H 0.380517 0.935326 0.931150 0.035 Uiso 1 1 calc R . . . .
C2 C 1.1789(5) 0.3871(4) 0.3799(3) 0.0247(13) Uani 1 1 d . . . . .
H2 H 1.213527 0.381090 0.343953 0.030 Uiso 1 1 calc R . . . .
C25 C 0.9915(6) 0.5877(4) 0.0272(4) 0.0309(17) Uani 1 1 d . . . . .
H25C H 1.067555 0.611084 0.044122 0.037 Uiso 1 1 calc R . . . .
H25D H 0.946854 0.636400 0.036211 0.037 Uiso 1 1 calc R . . . .
C14A C 0.4861(5) 0.6979(4) 0.5863(3) 0.0245(13) Uani 1 1 d . . . . .
H14A H 0.556336 0.723806 0.596646 0.029 Uiso 1 1 calc R . . . .
C18 C 0.4683(6) 0.5756(5) 0.2242(4) 0.0343(16) Uani 1 1 d . . . . .
H18 H 0.451159 0.596805 0.180516 0.041 Uiso 1 1 calc R . . . .
C21A C 0.3761(6) 1.0593(4) 0.7452(4) 0.0314(15) Uani 1 1 d . . . . .
H21A H 0.381011 1.066290 0.796581 0.047 Uiso 1 1 calc GR . . . .
H21B H 0.300830 1.045513 0.713988 0.047 Uiso 1 1 calc GR . . . .
H21C H 0.403324 1.113445 0.737801 0.047 Uiso 1 1 calc GR . . . .
C10 C 0.6233(5) 0.3410(4) -0.0128(4) 0.0281(15) Uani 1 1 d . . . . .
H10D H 0.662909 0.332095 -0.047786 0.042 Uiso 1 1 calc GR . . . .
H10E H 0.549565 0.354521 -0.037207 0.042 Uiso 1 1 calc GR . . . .
H10F H 0.621353 0.288073 0.005582 0.042 Uiso 1 1 calc GR . . . .
C3A C 0.9763(6) 0.8245(4) 0.6401(4) 0.0316(15) Uani 1 1 d . . . . .
H3A H 0.958004 0.780567 0.596516 0.038 Uiso 1 1 calc R . . . .
C10A C 0.6257(6) 0.7305(4) 0.9576(3) 0.0276(15) Uani 1 1 d . . . . .
H10A H 0.695936 0.732244 0.995365 0.041 Uiso 1 1 calc GR . . . .
H10B H 0.586205 0.674284 0.948574 0.041 Uiso 1 1 calc GR . . . .
H10C H 0.584417 0.777202 0.974106 0.041 Uiso 1 1 calc GR . . . .
C24 C 1.0914(5) 0.5089(4) 0.2564(3) 0.0199(12) Uani 1 1 d . . . . .
H24C H 1.090462 0.491213 0.205190 0.024 Uiso 1 1 calc R . . . .
H24D H 1.165974 0.507930 0.289349 0.024 Uiso 1 1 calc R . . . .
C20A C 0.4250(6) 0.9455(4) 0.6194(3) 0.0313(15) Uani 1 1 d . . . . .
H20A H 0.434402 0.999358 0.603925 0.047 Uiso 1 1 calc GR . . . .
H20B H 0.350054 0.921580 0.596142 0.047 Uiso 1 1 calc GR . . . .
H20C H 0.472778 0.903243 0.604782 0.047 Uiso 1 1 calc GR . . . .
C15 C 0.5179(5) 0.5153(4) 0.3528(4) 0.0272(14) Uani 1 1 d . . . . .
H15 H 0.534796 0.494193 0.396479 0.033 Uiso 1 1 calc R . . . .
C13A C 0.4344(5) 0.7161(4) 0.6383(3) 0.0196(12) Uani 1 1 d . . . . .
C5A C 1.1028(6) 0.9346(5) 0.7303(5) 0.0432(19) Uani 1 1 d . . . . .
H5A H 1.171345 0.966062 0.748628 0.052 Uiso 1 1 calc R . . . .
C17A C 0.2805(5) 0.6220(4) 0.5542(4) 0.0308(15) Uani 1 1 d . . . . .
H17A H 0.209866 0.596297 0.542848 0.037 Uiso 1 1 calc R . . . .
C7A C 0.9076(5) 0.9049(4) 0.8799(3) 0.0223(13) Uani 1 1 d . . . . .
H7AA H 0.966172 0.950921 0.907441 0.027 Uiso 1 1 calc R . . . .
H7AB H 0.940292 0.848660 0.873079 0.027 Uiso 1 1 calc R . . . .
C6A C 1.0289(6) 0.9532(5) 0.7671(4) 0.0353(17) Uani 1 1 d . . . . .
H6A H 1.046916 0.997443 0.810528 0.042 Uiso 1 1 calc R . . . .
C11 C 0.7122(5) 0.5245(5) 0.0208(4) 0.0289(15) Uani 1 1 d . . . . .
H11D H 0.668294 0.574720 0.026273 0.035 Uiso 1 1 calc R . . . .
H11E H 0.716969 0.506601 -0.029060 0.035 Uiso 1 1 calc R . . . .
C13 C 0.5697(5) 0.5459(4) 0.2536(3) 0.0215(13) Uani 1 1 d . . . . .
C8A C 0.8824(6) 0.8533(4) 1.0142(3) 0.0285(15) Uani 1 1 d . . . . .
H8AA H 0.835706 0.852167 1.043976 0.043 Uiso 1 1 calc GR . . . .
H8AB H 0.948979 0.889168 1.043561 0.043 Uiso 1 1 calc GR . . . .
H8AC H 0.899711 0.794006 0.997206 0.043 Uiso 1 1 calc GR . . . .
C8 C 0.7671(5) 0.2427(4) 0.1553(4) 0.0279(15) Uani 1 1 d . . . . .
H8A H 0.765583 0.265521 0.204891 0.042 Uiso 1 1 calc GR . . . .
H8B H 0.793696 0.184478 0.152178 0.042 Uiso 1 1 calc GR . . . .
H8C H 0.694196 0.239416 0.120236 0.042 Uiso 1 1 calc GR . . . .
C23A C 0.6569(6) 1.0822(5) 0.6737(4) 0.0352(17) Uani 1 1 d . . . . .
H23A H 0.654983 1.025197 0.642104 0.053 Uiso 1 1 calc GR . . . .
H23B H 0.716947 1.119722 0.674295 0.053 Uiso 1 1 calc GR . . . .
H23C H 0.589057 1.108701 0.655019 0.053 Uiso 1 1 calc GR . . . .
C22 C 1.1212(5) 0.6970(4) 0.2428(4) 0.0292(14) Uani 1 1 d . . . . .
H22D H 1.111302 0.675394 0.190857 0.044 Uiso 1 1 calc GR . . . .
H22E H 1.197779 0.699035 0.271390 0.044 Uiso 1 1 calc GR . . . .
H22F H 1.095829 0.755416 0.250244 0.044 Uiso 1 1 calc GR . . . .
C23 C 1.0795(6) 0.6597(4) 0.3742(4) 0.0322(15) Uani 1 1 d . . . . .
H23D H 1.052812 0.716986 0.385695 0.048 Uiso 1 1 calc GR . . . .
H23E H 1.158106 0.663614 0.396248 0.048 Uiso 1 1 calc GR . . . .
H23F H 1.047514 0.618305 0.393870 0.048 Uiso 1 1 calc GR . . . .
C20 C 0.8429(6) 0.7802(5) 0.1845(4) 0.0358(17) Uani 1 1 d . . . . .
H20D H 0.908132 0.817046 0.215310 0.054 Uiso 1 1 calc GR . . . .
H20E H 0.780687 0.815482 0.176729 0.054 Uiso 1 1 calc GR . . . .
H20F H 0.850924 0.753978 0.137228 0.054 Uiso 1 1 calc GR . . . .
C2A C 0.9028(5) 0.8432(4) 0.6777(3) 0.0243(13) Uani 1 1 d . . . . .
H2A H 0.834456 0.811479 0.659632 0.029 Uiso 1 1 calc R . . . .
C16A C 0.3332(6) 0.6041(4) 0.5038(3) 0.0325(15) Uani 1 1 d . . . . .
H16A H 0.299089 0.565504 0.458060 0.039 Uiso 1 1 calc R . . . .
C15A C 0.4351(6) 0.6414(4) 0.5188(4) 0.0335(15) Uani 1 1 d . . . . .
H15A H 0.470738 0.628919 0.483419 0.040 Uiso 1 1 calc R . . . .
C30 C 0.2337(6) 0.0448(4) 0.4709(4) 0.0411(16) Uani 1 1 d . . . . .
H30A H 0.286222 -0.000291 0.476151 0.049 Uiso 1 1 calc R . . . .
H30B H 0.220355 0.058275 0.422196 0.049 Uiso 1 1 calc R . . . .
Li1 Li 0.8958(8) 0.5253(6) 0.1325(5) 0.018(2) Uani 1 1 d . . . . .
C29 C 0.2825(6) 0.1259(4) 0.5291(4) 0.0377(15) Uani 1 1 d . . . . .
H29A H 0.293638 0.112949 0.577784 0.045 Uiso 1 1 calc R . . . .
H29B H 0.230891 0.171618 0.522891 0.045 Uiso 1 1 calc R . . . .
C4A C 1.0770(6) 0.8708(5) 0.6671(4) 0.0423(19) Uani 1 1 d . . . . .
H4A H 1.127650 0.858336 0.641996 0.051 Uiso 1 1 calc R . . . .
C24A C 0.8222(5) 1.0457(4) 0.8087(4) 0.0235(13) Uani 1 1 d . . . . .
H24A H 0.866738 1.073135 0.785999 0.028 Uiso 1 1 calc R . . . .
H24B H 0.848739 1.070419 0.862024 0.028 Uiso 1 1 calc R . . . .
C22A C 0.6590(6) 1.1784(4) 0.8235(4) 0.0330(16) Uani 1 1 d . . . . .
H22A H 0.585115 1.194532 0.803373 0.050 Uiso 1 1 calc GR . . . .
H22B H 0.709635 1.222326 0.820810 0.050 Uiso 1 1 calc GR . . . .
H22C H 0.673545 1.174984 0.874617 0.050 Uiso 1 1 calc GR . . . .
C28 C 0.3891(6) 0.1608(5) 0.5271(4) 0.0426(17) Uani 1 1 d . . . . .
H28A H 0.376640 0.179500 0.480453 0.051 Uiso 1 1 calc R . . . .
H28B H 0.438351 0.113321 0.528222 0.051 Uiso 1 1 calc R . . . .
C27 C 0.4434(8) 0.2368(5) 0.5902(6) 0.063(3) Uani 1 1 d . . . . .
H27A H 0.402583 0.288124 0.583742 0.095 Uiso 1 1 calc GR . . . .
H27B H 0.516980 0.249232 0.590977 0.095 Uiso 1 1 calc GR . . . .
H27C H 0.445754 0.222020 0.636384 0.095 Uiso 1 1 calc GR . . . .
C31 C 0.1292(7) 0.0087(5) 0.4746(5) 0.063(2) Uani 1 1 d . . . . .
H31A H 0.142773 -0.005932 0.522942 0.076 Uiso 1 1 calc R . . . .
H31B H 0.077049 0.054053 0.470239 0.076 Uiso 1 1 calc R . . . .
C32 C 0.0802(10) -0.0711(7) 0.4156(8) 0.104(5) Uani 1 1 d . . . . .
H32A H 0.044706 -0.053903 0.369261 0.157 Uiso 1 1 calc GR . . . .
H32B H 0.027151 -0.101846 0.429026 0.157 Uiso 1 1 calc GR . . . .
H32C H 0.136917 -0.109492 0.410222 0.157 Uiso 1 1 calc GR . . . .
C5 C 1.0775(6) 0.4029(4) 0.4843(3) 0.0299(14) Uani 1 1 d . . . . .
H5 H 1.042556 0.407741 0.520066 0.036 Uiso 1 1 calc R . . . .
C16 C 0.4171(5) 0.5436(5) 0.3236(4) 0.0329(16) Uani 1 1 d . . . . .
H16 H 0.365010 0.542267 0.347402 0.039 Uiso 1 1 calc R . . . .
C9 C 0.8800(6) 0.2538(4) 0.0481(3) 0.0267(15) Uani 1 1 d . . . . .
H9A H 0.811845 0.245001 0.007428 0.040 Uiso 1 1 calc GR . . . .
H9B H 0.906131 0.197206 0.055853 0.040 Uiso 1 1 calc GR . . . .
H9C H 0.933404 0.286471 0.036495 0.040 Uiso 1 1 calc GR . . . .
Li1A Li 0.6050(10) 0.9509(7) 0.8665(6) 0.027(3) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1A Rh1A P2A 174.99(6) . . ?
P1A Rh1A N1A 90.20(13) . . ?
P1A Rh1A N2A 90.28(13) . . ?
P1A Rh1A Li1A 95.7(3) . . ?
P2A Rh1A N1A 84.81(13) . . ?
P2A Rh1A N2A 89.98(13) . . ?
P2A Rh1A Li1A 80.9(2) . . ?
N1A Rh1A Li1A 44.2(3) . . ?
N2A Rh1A N1A 88.99(18) . . ?
N2A Rh1A Li1A 45.3(3) . . ?
P2 Rh1 P1 174.29(6) . . ?
P2 Rh1 N2 89.65(12) . . ?
P2 Rh1 N1 89.41(12) . . ?
P2 Rh1 Li1 94.3(2) . . ?
P1 Rh1 N2 90.22(12) . . ?
P1 Rh1 N1 84.88(12) . . ?
P1 Rh1 Li1 81.6(2) . . ?
N2 Rh1 N1 89.70(16) . . ?
N2 Rh1 Li1 45.1(2) . . ?
N1 Rh1 Li1 45.1(2) . . ?
C19 P2 Rh1 109.8(2) . . ?
C12 P2 Rh1 107.0(2) . . ?
C12 P2 C19 105.3(3) . . ?
C12 P2 C13 102.8(3) . . ?
C13 P2 Rh1 124.2(2) . . ?
C13 P2 C19 106.1(3) . . ?
N2 Si3 C19 109.0(3) . . ?
N2 Si3 C21 115.8(3) . . ?
N2 Si3 C20 112.5(3) . . ?
C21 Si3 C19 104.5(3) . . ?
C20 Si3 C19 106.4(3) . . ?
C20 Si3 C21 108.0(4) . . ?
N1 Si2 C12 109.0(3) . . ?
N1 Si2 C10 117.1(3) . . ?
N1 Si2 C11 109.8(3) . . ?
N1 Si2 Li1 44.5(3) . . ?
C12 Si2 Li1 113.5(3) . . ?
C10 Si2 C12 107.0(3) . . ?
C10 Si2 C11 104.4(3) . . ?
C10 Si2 Li1 139.3(3) . . ?
C11 Si2 C12 109.2(3) . . ?
C11 Si2 Li1 66.8(3) . . ?
N1A Si1A C9A 109.7(3) . . ?
N1A Si1A C7A 109.8(3) . . ?
N1A Si1A C8A 117.4(3) . . ?
N1A Si1A Li1A 43.7(3) . . ?
C9A Si1A C7A 108.0(3) . . ?
C9A Si1A C8A 104.4(3) . . ?
C9A Si1A Li1A 67.1(3) . . ?
C7A Si1A Li1A 114.5(3) . . ?
C8A Si1A C7A 107.1(3) . . ?
C8A Si1A Li1A 138.2(3) . . ?
C1A P1A Rh1A 123.4(2) . . ?
C1A P1A C24A 106.3(3) . . ?
C7A P1A Rh1A 106.9(2) . . ?
C7A P1A C1A 103.5(3) . . ?
C7A P1A C24A 105.6(3) . . ?
C24A P1A Rh1A 109.8(2) . . ?
C1 P1 Rh1 124.9(2) . . ?
C1 P1 C7 104.0(3) . . ?
C1 P1 C24 104.5(3) . . ?
C7 P1 Rh1 109.4(2) . . ?
C7 P1 C24 105.9(3) . . ?
C24 P1 Rh1 106.64(19) . . ?
N2A Si3A C19A 105.0(3) . . ?
N2A Si3A C21A 112.7(3) . . ?
N2A Si3A C20A 117.9(3) . . ?
N2A Si3A Li1A 40.1(3) . . ?
C19A Si3A Li1A 72.0(3) . . ?
C21A Si3A C19A 108.6(3) . . ?
C21A Si3A Li1A 102.6(3) . . ?
C20A Si3A C19A 105.4(3) . . ?
C20A Si3A C21A 106.8(3) . . ?
C20A Si3A Li1A 149.5(3) . . ?
N1A Si2A C12A 109.2(2) . . ?
N1A Si2A C11A 114.3(3) . . ?
N1A Si2A C10A 113.1(3) . . ?
C11A Si2A C12A 106.5(3) . . ?
C11A Si2A C10A 104.9(3) . . ?
C10A Si2A C12A 108.4(3) . . ?
C12A P2A Rh1A 109.6(2) . . ?
C19A P2A Rh1A 107.3(2) . . ?
C19A P2A C12A 106.6(3) . . ?
C13A P2A Rh1A 122.7(2) . . ?
C13A P2A C12A 104.8(3) . . ?
C13A P2A C19A 104.8(3) . . ?
N2A Si4A C23A 114.4(3) . . ?
N2A Si4A C24A 109.5(3) . . ?
N2A Si4A C22A 112.5(3) . . ?
C23A Si4A C24A 106.1(3) . . ?
C23A Si4A C22A 107.3(3) . . ?
C22A Si4A C24A 106.5(3) . . ?
N1 Si1 C7 108.9(3) . . ?
N1 Si1 C8 114.6(3) . . ?
N1 Si1 C9 113.2(3) . . ?
C8 Si1 C7 106.4(3) . . ?
C8 Si1 C9 105.4(3) . . ?
C9 Si1 C7 107.9(3) . . ?
N2 Si4 C24 105.3(2) . . ?
N2 Si4 C22 113.0(3) . . ?
N2 Si4 C23 117.1(3) . . ?
N2 Si4 Li1 40.9(3) . . ?
C24 Si4 Li1 72.7(3) . . ?
C22 Si4 C24 108.2(3) . . ?
C22 Si4 Li1 100.9(3) . . ?
C23 Si4 C24 106.6(3) . . ?
C23 Si4 C22 106.2(3) . . ?
C23 Si4 Li1 151.3(3) . . ?
C26A O1A Li1A 129.0(5) . . ?
C25A O1A C26A 109.3(5) . . ?
C25A O1A Li1A 121.7(5) . . ?
Si1A N1A Rh1A 110.6(3) . . ?
Si1A N1A Si2A 125.0(3) . . ?
Si1A N1A Li1A 99.2(4) . . ?
Si2A N1A Rh1A 105.3(2) . . ?
Si2A N1A Li1A 127.7(5) . . ?
Li1A N1A Rh1A 79.5(4) . . ?
Si3 N2 Rh1 107.7(2) . . ?
Si3 N2 Li1 124.6(4) . . ?
Si4 N2 Rh1 107.6(2) . . ?
Si4 N2 Si3 123.0(3) . . ?
Si4 N2 Li1 104.6(4) . . ?
Li1 N2 Rh1 79.8(3) . . ?
C26 O1 C25 109.8(5) . . ?
C26 O1 Li1 121.2(4) . . ?
C25 O1 Li1 128.9(5) . . ?
Si2A C12A H12A 110.0 . . ?
Si2A C12A H12B 110.0 . . ?
P2A C12A Si2A 108.2(3) . . ?
P2A C12A H12A 110.0 . . ?
P2A C12A H12B 110.0 . . ?
H12A C12A H12B 108.4 . . ?
C18 C17 H17 119.8 . . ?
C16 C17 H17 119.8 . . ?
C16 C17 C18 120.4(7) . . ?
Si2 N1 Rh1 111.4(2) . . ?
Si2 N1 Li1 98.4(4) . . ?
Si1 N1 Rh1 105.3(2) . . ?
Si1 N1 Si2 124.6(3) . . ?
Si1 N1 Li1 128.9(4) . . ?
Li1 N1 Rh1 78.7(3) . . ?
C15 C14 H14 119.8 . . ?
C15 C14 C13 120.4(6) . . ?
C13 C14 H14 119.8 . . ?
P2 C19 Si3 107.5(3) . . ?
P2 C19 H19C 110.2 . . ?
P2 C19 H19D 110.2 . . ?
Si3 C19 H19C 110.2 . . ?
Si3 C19 H19D 110.2 . . ?
H19C C19 H19D 108.5 . . ?
C6 C1 P1 119.2(5) . . ?
C6 C1 C2 118.8(6) . . ?
C2 C1 P1 121.9(5) . . ?
C6A C1A P1A 119.9(5) . . ?
C2A C1A P1A 120.6(5) . . ?
C2A C1A C6A 119.5(6) . . ?
Si3A N2A Rh1A 106.2(2) . . ?
Si3A N2A Li1A 106.1(4) . . ?
Si4A N2A Rh1A 109.5(3) . . ?
Si4A N2A Si3A 122.6(3) . . ?
Si4A N2A Li1A 123.2(4) . . ?
Li1A N2A Rh1A 80.0(4) . . ?
Si2A C11A H11A 109.5 . . ?
Si2A C11A H11B 109.5 . . ?
Si2A C11A H11C 109.5 . . ?
H11A C11A H11B 109.5 . . ?
H11A C11A H11C 109.5 . . ?
H11B C11A H11C 109.5 . . ?
Si3A C19A H19A 110.5 . . ?
Si3A C19A H19B 110.5 . . ?
P2A C19A Si3A 106.1(3) . . ?
P2A C19A H19A 110.5 . . ?
P2A C19A H19B 110.5 . . ?
H19A C19A H19B 108.7 . . ?
C3 C4 H4 120.1 . . ?
C3 C4 C5 119.8(6) . . ?
C5 C4 H4 120.1 . . ?
P2 C12 Si2 108.6(3) . . ?
P2 C12 H12C 110.0 . . ?
P2 C12 H12D 110.0 . . ?
Si2 C12 H12C 110.0 . . ?
Si2 C12 H12D 110.0 . . ?
H12C C12 H12D 108.3 . . ?
C4 C3 H3 119.9 . . ?
C4 C3 C2 120.1(6) . . ?
C2 C3 H3 119.9 . . ?
O1 C26 H26C 109.6 . . ?
O1 C26 H26D 109.6 . . ?
O1 C26 C25 110.1(5) . 2_765 ?
H26C C26 H26D 108.1 . . ?
C25 C26 H26C 109.6 2_765 . ?
C25 C26 H26D 109.6 2_765 . ?
C13A C18A H18A 120.1 . . ?
C17A C18A H18A 120.1 . . ?
C17A C18A C13A 119.8(6) . . ?
Si3 C21 H21D 109.5 . . ?
Si3 C21 H21E 109.5 . . ?
Si3 C21 H21F 109.5 . . ?
H21D C21 H21E 109.5 . . ?
H21D C21 H21F 109.5 . . ?
H21E C21 H21F 109.5 . . ?
P1 C7 Si1 108.5(3) . . ?
P1 C7 H7A 110.0 . . ?
P1 C7 H7B 110.0 . . ?
Si1 C7 H7A 110.0 . . ?
Si1 C7 H7B 110.0 . . ?
H7A C7 H7B 108.4 . . ?
C1 C6 H6 119.6 . . ?
C5 C6 C1 120.7(6) . . ?
C5 C6 H6 119.6 . . ?
O1A C26A H26A 109.7 . . ?
O1A C26A H26B 109.7 . . ?
O1A C26A C25A 109.8(5) . 2_677 ?
H26A C26A H26B 108.2 . . ?
C25A C26A H26A 109.7 2_677 . ?
C25A C26A H26B 109.7 2_677 . ?
Si1A C9A H9AA 116.3 . . ?
Si1A C9A H9AB 116.3 . . ?
Si1A C9A Li1A 72.8(3) . . ?
H9AA C9A H9AB 113.3 . . ?
Li1A C9A H9AA 116.3 . . ?
Li1A C9A H9AB 116.3 . . ?
O1A C25A C26A 111.6(5) . 2_677 ?
O1A C25A H25A 109.3 . . ?
O1A C25A H25B 109.3 . . ?
C26A C25A H25A 109.3 2_677 . ?
C26A C25A H25B 109.3 2_677 . ?
H25A C25A H25B 108.0 . . ?
C1 C2 H2 119.6 . . ?
C3 C2 C1 120.8(6) . . ?
C3 C2 H2 119.6 . . ?
O1 C25 C26 110.1(5) . 2_765 ?
O1 C25 H25C 109.6 . . ?
O1 C25 H25D 109.6 . . ?
C26 C25 H25C 109.6 2_765 . ?
C26 C25 H25D 109.6 2_765 . ?
H25C C25 H25D 108.2 . . ?
C13A C14A H14A 119.9 . . ?
C13A C14A C15A 120.2(6) . . ?
C15A C14A H14A 119.9 . . ?
C17 C18 H18 120.4 . . ?
C13 C18 C17 119.3(7) . . ?
C13 C18 H18 120.4 . . ?
Si3A C21A H21A 109.5 . . ?
Si3A C21A H21B 109.5 . . ?
Si3A C21A H21C 109.5 . . ?
H21A C21A H21B 109.5 . . ?
H21A C21A H21C 109.5 . . ?
H21B C21A H21C 109.5 . . ?
Si2 C10 H10D 109.5 . . ?
Si2 C10 H10E 109.5 . . ?
Si2 C10 H10F 109.5 . . ?
H10D C10 H10E 109.5 . . ?
H10D C10 H10F 109.5 . . ?
H10E C10 H10F 109.5 . . ?
C2A C3A H3A 120.3 . . ?
C2A C3A C4A 119.5(7) . . ?
C4A C3A H3A 120.3 . . ?
Si2A C10A H10A 109.5 . . ?
Si2A C10A H10B 109.5 . . ?
Si2A C10A H10C 109.5 . . ?
H10A C10A H10B 109.5 . . ?
H10A C10A H10C 109.5 . . ?
H10B C10A H10C 109.5 . . ?
P1 C24 Si4 107.0(3) . . ?
P1 C24 H24C 110.3 . . ?
P1 C24 H24D 110.3 . . ?
Si4 C24 H24C 110.3 . . ?
Si4 C24 H24D 110.3 . . ?
H24C C24 H24D 108.6 . . ?
Si3A C20A H20A 109.5 . . ?
Si3A C20A H20B 109.5 . . ?
Si3A C20A H20C 109.5 . . ?
H20A C20A H20B 109.5 . . ?
H20A C20A H20C 109.5 . . ?
H20B C20A H20C 109.5 . . ?
C14 C15 H15 119.9 . . ?
C16 C15 C14 120.2(7) . . ?
C16 C15 H15 119.9 . . ?
C18A C13A P2A 121.2(5) . . ?
C14A C13A P2A 119.7(5) . . ?
C14A C13A C18A 119.0(5) . . ?
C6A C5A H5A 119.9 . . ?
C4A C5A H5A 119.9 . . ?
C4A C5A C6A 120.2(7) . . ?
C18A C17A H17A 119.8 . . ?
C16A C17A C18A 120.4(6) . . ?
C16A C17A H17A 119.8 . . ?
Si1A C7A H7AA 109.9 . . ?
Si1A C7A H7AB 109.9 . . ?
P1A C7A Si1A 108.7(3) . . ?
P1A C7A H7AA 109.9 . . ?
P1A C7A H7AB 109.9 . . ?
H7AA C7A H7AB 108.3 . . ?
C1A C6A H6A 119.9 . . ?
C5A C6A C1A 120.1(7) . . ?
C5A C6A H6A 119.9 . . ?
Si2 C11 H11D 116.2 . . ?
Si2 C11 H11E 116.2 . . ?
Si2 C11 Li1 73.2(3) . . ?
H11D C11 H11E 113.2 . . ?
Li1 C11 H11D 116.2 . . ?
Li1 C11 H11E 116.2 . . ?
C14 C13 P2 119.8(5) . . ?
C14 C13 C18 119.6(6) . . ?
C18 C13 P2 120.5(5) . . ?
Si1A C8A H8AA 109.5 . . ?
Si1A C8A H8AB 109.5 . . ?
Si1A C8A H8AC 109.5 . . ?
H8AA C8A H8AB 109.5 . . ?
H8AA C8A H8AC 109.5 . . ?
H8AB C8A H8AC 109.5 . . ?
Si1 C8 H8A 109.5 . . ?
Si1 C8 H8B 109.5 . . ?
Si1 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
Si4A C23A H23A 109.5 . . ?
Si4A C23A H23B 109.5 . . ?
Si4A C23A H23C 109.5 . . ?
H23A C23A H23B 109.5 . . ?
H23A C23A H23C 109.5 . . ?
H23B C23A H23C 109.5 . . ?
Si4 C22 H22D 109.5 . . ?
Si4 C22 H22E 109.5 . . ?
Si4 C22 H22F 109.5 . . ?
H22D C22 H22E 109.5 . . ?
H22D C22 H22F 109.5 . . ?
H22E C22 H22F 109.5 . . ?
Si4 C23 H23D 109.5 . . ?
Si4 C23 H23E 109.5 . . ?
Si4 C23 H23F 109.5 . . ?
H23D C23 H23E 109.5 . . ?
H23D C23 H23F 109.5 . . ?
H23E C23 H23F 109.5 . . ?
Si3 C20 H20D 109.5 . . ?
Si3 C20 H20E 109.5 . . ?
Si3 C20 H20F 109.5 . . ?
H20D C20 H20E 109.5 . . ?
H20D C20 H20F 109.5 . . ?
H20E C20 H20F 109.5 . . ?
C1A C2A C3A 120.8(6) . . ?
C1A C2A H2A 119.6 . . ?
C3A C2A H2A 119.6 . . ?
C17A C16A H16A 119.6 . . ?
C17A C16A C15A 120.7(6) . . ?
C15A C16A H16A 119.6 . . ?
C14A C15A H15A 120.0 . . ?
C16A C15A C14A 119.9(6) . . ?
C16A C15A H15A 120.0 . . ?
H30A C30 H30B 107.7 . . ?
C29 C30 H30A 108.9 . . ?
C29 C30 H30B 108.9 . . ?
C29 C30 C31 113.5(7) . . ?
C31 C30 H30A 108.9 . . ?
C31 C30 H30B 108.9 . . ?
Rh1 Li1 Si2 74.3(3) . . ?
Rh1 Li1 Si4 69.8(2) . . ?
Si2 Li1 Si4 142.7(4) . . ?
N2 Li1 Rh1 55.2(3) . . ?
N2 Li1 Si2 113.3(5) . . ?
N2 Li1 Si4 34.5(2) . . ?
N2 Li1 N1 110.7(5) . . ?
N2 Li1 C11 114.8(5) . . ?
O1 Li1 Rh1 159.1(5) . . ?
O1 Li1 Si2 114.2(4) . . ?
O1 Li1 Si4 103.0(4) . . ?
O1 Li1 N2 128.9(5) . . ?
O1 Li1 N1 118.4(5) . . ?
O1 Li1 C11 90.6(4) . . ?
N1 Li1 Rh1 56.2(3) . . ?
N1 Li1 Si2 37.1(2) . . ?
N1 Li1 Si4 120.8(4) . . ?
N1 Li1 C11 76.3(4) . . ?
C11 Li1 Rh1 106.1(4) . . ?
C11 Li1 Si2 40.0(2) . . ?
C11 Li1 Si4 146.5(4) . . ?
C30 C29 H29A 108.8 . . ?
C30 C29 H29B 108.8 . . ?
C30 C29 C28 113.6(6) . . ?
H29A C29 H29B 107.7 . . ?
C28 C29 H29A 108.8 . . ?
C28 C29 H29B 108.8 . . ?
C3A C4A H4A 120.0 . . ?
C5A C4A C3A 120.0(7) . . ?
C5A C4A H4A 120.0 . . ?
P1A C24A Si4A 109.6(3) . . ?
P1A C24A H24A 109.7 . . ?
P1A C24A H24B 109.7 . . ?
Si4A C24A H24A 109.7 . . ?
Si4A C24A H24B 109.7 . . ?
H24A C24A H24B 108.2 . . ?
Si4A C22A H22A 109.5 . . ?
Si4A C22A H22B 109.5 . . ?
Si4A C22A H22C 109.5 . . ?
H22A C22A H22B 109.5 . . ?
H22A C22A H22C 109.5 . . ?
H22B C22A H22C 109.5 . . ?
C29 C28 H28A 108.9 . . ?
C29 C28 H28B 108.9 . . ?
C29 C28 C27 113.5(7) . . ?
H28A C28 H28B 107.7 . . ?
C27 C28 H28A 108.9 . . ?
C27 C28 H28B 108.9 . . ?
C28 C27 H27A 109.5 . . ?
C28 C27 H27B 109.5 . . ?
C28 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C30 C31 H31A 109.0 . . ?
C30 C31 H31B 109.0 . . ?
H31A C31 H31B 107.8 . . ?
C32 C31 C30 113.1(9) . . ?
C32 C31 H31A 109.0 . . ?
C32 C31 H31B 109.0 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C4 C5 H5 120.1 . . ?
C6 C5 C4 119.7(6) . . ?
C6 C5 H5 120.1 . . ?
C17 C16 C15 120.1(7) . . ?
C17 C16 H16 120.0 . . ?
C15 C16 H16 120.0 . . ?
Si1 C9 H9A 109.5 . . ?
Si1 C9 H9B 109.5 . . ?
Si1 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
Rh1A Li1A Si1A 74.0(3) . . ?
Rh1A Li1A Si3A 68.4(2) . . ?
Si1A Li1A Si3A 140.6(4) . . ?
O1A Li1A Rh1A 160.5(6) . . ?
O1A Li1A Si1A 115.2(5) . . ?
O1A Li1A Si3A 104.1(5) . . ?
O1A Li1A N2A 128.3(7) . . ?
O1A Li1A C9A 91.8(4) . . ?
N1A Li1A Rh1A 56.3(3) . . ?
N1A Li1A Si1A 37.1(3) . . ?
N1A Li1A Si3A 119.9(5) . . ?
N1A Li1A O1A 119.9(6) . . ?
N1A Li1A N2A 110.3(5) . . ?
N1A Li1A C9A 76.5(4) . . ?
N2A Li1A Rh1A 54.7(3) . . ?
N2A Li1A Si1A 112.0(5) . . ?
N2A Li1A Si3A 33.8(2) . . ?
N2A Li1A C9A 112.1(5) . . ?
C9A Li1A Rh1A 104.7(4) . . ?
C9A Li1A Si1A 40.0(2) . . ?
C9A Li1A Si3A 143.7(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1A P1A 2.2702(16) . ?
Rh1A P2A 2.2812(16) . ?
Rh1A N1A 2.336(5) . ?
Rh1A N2A 2.289(5) . ?
Rh1A Li1A 2.760(11) . ?
Rh1 P2 2.2746(17) . ?
Rh1 P1 2.2888(16) . ?
Rh1 N2 2.301(5) . ?
Rh1 N1 2.337(5) . ?
Rh1 Li1 2.759(10) . ?
P2 C19 1.846(6) . ?
P2 C12 1.821(6) . ?
P2 C13 1.829(7) . ?
Si3 N2 1.720(5) . ?
Si3 C19 1.894(6) . ?
Si3 C21 1.870(7) . ?
Si3 C20 1.870(7) . ?
Si2 N1 1.713(5) . ?
Si2 C12 1.893(7) . ?
Si2 C10 1.881(6) . ?
Si2 C11 1.888(7) . ?
Si2 Li1 2.810(10) . ?
Si1A N1A 1.708(5) . ?
Si1A C9A 1.883(7) . ?
Si1A C7A 1.900(6) . ?
Si1A C8A 1.885(7) . ?
Si1A Li1A 2.797(13) . ?
P1A C1A 1.825(7) . ?
P1A C7A 1.817(6) . ?
P1A C24A 1.833(6) . ?
P1 C1 1.824(6) . ?
P1 C7 1.830(6) . ?
P1 C24 1.848(6) . ?
Si3A N2A 1.724(5) . ?
Si3A C19A 1.905(6) . ?
Si3A C21A 1.877(7) . ?
Si3A C20A 1.868(7) . ?
Si3A Li1A 2.974(12) . ?
Si2A N1A 1.710(5) . ?
Si2A C12A 1.899(6) . ?
Si2A C11A 1.887(7) . ?
Si2A C10A 1.890(6) . ?
P2A C12A 1.837(6) . ?
P2A C19A 1.822(6) . ?
P2A C13A 1.822(6) . ?
Si4A N2A 1.722(5) . ?
Si4A C23A 1.871(7) . ?
Si4A C24A 1.903(7) . ?
Si4A C22A 1.892(7) . ?
Si1 N1 1.704(5) . ?
Si1 C7 1.908(6) . ?
Si1 C8 1.870(6) . ?
Si1 C9 1.880(7) . ?
Si4 N2 1.718(5) . ?
Si4 C24 1.904(6) . ?
Si4 C22 1.882(6) . ?
Si4 C23 1.854(7) . ?
Si4 Li1 2.934(10) . ?
O1A C26A 1.436(7) . ?
O1A C25A 1.432(8) . ?
O1A Li1A 1.973(12) . ?
N1A Li1A 1.958(13) . ?
N2 Li1 1.985(11) . ?
O1 C26 1.431(7) . ?
O1 C25 1.438(7) . ?
O1 Li1 1.951(11) . ?
C12A H12A 0.9900 . ?
C12A H12B 0.9900 . ?
C17 H17 0.9500 . ?
C17 C18 1.401(10) . ?
C17 C16 1.379(11) . ?
N1 Li1 1.991(10) . ?
C14 H14 0.9500 . ?
C14 C15 1.386(9) . ?
C14 C13 1.387(9) . ?
C19 H19C 0.9900 . ?
C19 H19D 0.9900 . ?
C1 C6 1.387(9) . ?
C1 C2 1.396(8) . ?
C1A C6A 1.400(9) . ?
C1A C2A 1.372(9) . ?
N2A Li1A 1.992(12) . ?
C11A H11A 0.9800 . ?
C11A H11B 0.9800 . ?
C11A H11C 0.9800 . ?
C19A H19A 0.9900 . ?
C19A H19B 0.9900 . ?
C4 H4 0.9500 . ?
C4 C3 1.367(9) . ?
C4 C5 1.412(10) . ?
C12 H12C 0.9900 . ?
C12 H12D 0.9900 . ?
C3 H3 0.9500 . ?
C3 C2 1.392(9) . ?
C26 H26C 0.9900 . ?
C26 H26D 0.9900 . ?
C26 C25 1.512(9) 2_765 ?
C18A H18A 0.9500 . ?
C18A C13A 1.412(8) . ?
C18A C17A 1.390(9) . ?
C21 H21D 0.9800 . ?
C21 H21E 0.9800 . ?
C21 H21F 0.9800 . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C6 H6 0.9500 . ?
C6 C5 1.383(9) . ?
C26A H26A 0.9900 . ?
C26A H26B 0.9900 . ?
C26A C25A 1.497(9) 2_677 ?
C9A H9AA 0.9900 . ?
C9A H9AB 0.9900 . ?
C9A Li1A 2.697(14) . ?
C25A C26A 1.497(9) 2_677 ?
C25A H25A 0.9900 . ?
C25A H25B 0.9900 . ?
C2 H2 0.9500 . ?
C25 C26 1.512(9) 2_765 ?
C25 H25C 0.9900 . ?
C25 H25D 0.9900 . ?
C14A H14A 0.9500 . ?
C14A C13A 1.389(8) . ?
C14A C15A 1.400(9) . ?
C18 H18 0.9500 . ?
C18 C13 1.398(9) . ?
C21A H21A 0.9800 . ?
C21A H21B 0.9800 . ?
C21A H21C 0.9800 . ?
C10 H10D 0.9800 . ?
C10 H10E 0.9800 . ?
C10 H10F 0.9800 . ?
C3A H3A 0.9500 . ?
C3A C2A 1.395(9) . ?
C3A C4A 1.397(10) . ?
C10A H10A 0.9800 . ?
C10A H10B 0.9800 . ?
C10A H10C 0.9800 . ?
C24 H24C 0.9900 . ?
C24 H24D 0.9900 . ?
C20A H20A 0.9800 . ?
C20A H20B 0.9800 . ?
C20A H20C 0.9800 . ?
C15 H15 0.9500 . ?
C15 C16 1.380(9) . ?
C5A H5A 0.9500 . ?
C5A C6A 1.389(10) . ?
C5A C4A 1.378(11) . ?
C17A H17A 0.9500 . ?
C17A C16A 1.372(10) . ?
C7A H7AA 0.9900 . ?
C7A H7AB 0.9900 . ?
C6A H6A 0.9500 . ?
C11 H11D 0.9900 . ?
C11 H11E 0.9900 . ?
C11 Li1 2.697(12) . ?
C8A H8AA 0.9800 . ?
C8A H8AB 0.9800 . ?
C8A H8AC 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C23A H23A 0.9800 . ?
C23A H23B 0.9800 . ?
C23A H23C 0.9800 . ?
C22 H22D 0.9800 . ?
C22 H22E 0.9800 . ?
C22 H22F 0.9800 . ?
C23 H23D 0.9800 . ?
C23 H23E 0.9800 . ?
C23 H23F 0.9800 . ?
C20 H20D 0.9800 . ?
C20 H20E 0.9800 . ?
C20 H20F 0.9800 . ?
C2A H2A 0.9500 . ?
C16A H16A 0.9500 . ?
C16A C15A 1.377(10) . ?
C15A H15A 0.9500 . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C30 C29 1.514(9) . ?
C30 C31 1.514(12) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C29 C28 1.519(10) . ?
C4A H4A 0.9500 . ?
C24A H24A 0.9900 . ?
C24A H24B 0.9900 . ?
C22A H22A 0.9800 . ?
C22A H22B 0.9800 . ?
C22A H22C 0.9800 . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C28 C27 1.521(11) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C31 C32 1.507(13) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C5 H5 0.9500 . ?
C16 H16 0.9500 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1A P1A C1A C6A -179.9(5) . . . . ?
Rh1A P1A C1A C2A -2.8(6) . . . . ?
Rh1A P1A C7A Si1A -36.4(3) . . . . ?
Rh1A P1A C24A Si4A -13.4(4) . . . . ?
Rh1A P2A C12A Si2A 11.4(3) . . . . ?
Rh1A P2A C19A Si3A 30.6(3) . . . . ?
Rh1A P2A C13A C18A -175.2(4) . . . . ?
Rh1A P2A C13A C14A 7.5(6) . . . . ?
Rh1 P2 C19 Si3 -18.3(4) . . . . ?
Rh1 P2 C12 Si2 -37.5(3) . . . . ?
Rh1 P2 C13 C14 -2.7(6) . . . . ?
Rh1 P2 C13 C18 -179.3(4) . . . . ?
Rh1 P1 C1 C6 8.7(6) . . . . ?
Rh1 P1 C1 C2 -174.0(4) . . . . ?
Rh1 P1 C7 Si1 10.5(3) . . . . ?
Rh1 P1 C24 Si4 30.9(3) . . . . ?
P1A C1A C6A C5A 177.1(6) . . . . ?
P1A C1A C2A C3A -177.4(5) . . . . ?
P1 C1 C6 C5 177.7(5) . . . . ?
P1 C1 C2 C3 -178.1(5) . . . . ?
N1A Si1A C9A Li1A -10.0(3) . . . . ?
N1A Si2A C12A P2A 23.1(4) . . . . ?
N2 Si3 C19 P2 40.0(4) . . . . ?
C12A Si2A N1A Rh1A -45.9(3) . . . . ?
C12A Si2A N1A Si1A -175.5(3) . . . . ?
C12A Si2A N1A Li1A 42.5(6) . . . . ?
C12A P2A C19A Si3A 148.0(3) . . . . ?
C12A P2A C13A C18A 59.3(6) . . . . ?
C12A P2A C13A C14A -118.1(5) . . . . ?
C17 C18 C13 P2 174.6(5) . . . . ?
C17 C18 C13 C14 -1.9(10) . . . . ?
N1 Si2 C12 P2 40.2(4) . . . . ?
N1 Si2 C11 Li1 -11.5(3) . . . . ?
C14 C15 C16 C17 0.4(10) . . . . ?
C19 P2 C12 Si2 79.3(4) . . . . ?
C19 P2 C13 C14 -131.3(5) . . . . ?
C19 P2 C13 C18 52.2(6) . . . . ?
C19 Si3 N2 Rh1 -42.4(3) . . . . ?
C19 Si3 N2 Si4 -168.4(3) . . . . ?
C19 Si3 N2 Li1 47.2(5) . . . . ?
C1 P1 C7 Si1 146.0(3) . . . . ?
C1 P1 C24 Si4 -103.1(3) . . . . ?
C1 C6 C5 C4 0.4(10) . . . . ?
C1A P1A C7A Si1A -168.1(3) . . . . ?
C1A P1A C24A Si4A 122.2(3) . . . . ?
C11A Si2A N1A Rh1A 73.3(3) . . . . ?
C11A Si2A N1A Si1A -56.2(5) . . . . ?
C11A Si2A N1A Li1A 161.7(5) . . . . ?
C11A Si2A C12A P2A -100.9(4) . . . . ?
C19A Si3A N2A Rh1A 48.5(3) . . . . ?
C19A Si3A N2A Si4A 175.3(3) . . . . ?
C19A Si3A N2A Li1A -35.5(4) . . . . ?
C19A P2A C12A Si2A -104.5(3) . . . . ?
C19A P2A C13A C18A -52.8(6) . . . . ?
C19A P2A C13A C14A 129.9(5) . . . . ?
C4 C3 C2 C1 0.5(10) . . . . ?
C12 P2 C19 Si3 -133.3(3) . . . . ?
C12 P2 C13 C14 118.4(5) . . . . ?
C12 P2 C13 C18 -58.1(6) . . . . ?
C12 Si2 N1 Rh1 -23.4(3) . . . . ?
C12 Si2 N1 Si1 104.5(4) . . . . ?
C12 Si2 N1 Li1 -104.5(4) . . . . ?
C12 Si2 C11 Li1 108.0(3) . . . . ?
C3 C4 C5 C6 -0.8(10) . . . . ?
C26 O1 C25 C26 58.6(8) . . . 2_765 ?
C18A C17A C16A C15A -0.7(10) . . . . ?
C21 Si3 N2 Rh1 75.0(3) . . . . ?
C21 Si3 N2 Si4 -51.0(4) . . . . ?
C21 Si3 N2 Li1 164.6(5) . . . . ?
C21 Si3 C19 P2 -84.4(4) . . . . ?
C7 P1 C1 C6 -117.5(5) . . . . ?
C7 P1 C1 C2 59.7(5) . . . . ?
C7 P1 C24 Si4 147.4(3) . . . . ?
C7 Si1 N1 Rh1 -46.5(3) . . . . ?
C7 Si1 N1 Si2 -176.9(3) . . . . ?
C7 Si1 N1 Li1 41.2(6) . . . . ?
C6 C1 C2 C3 -0.8(9) . . . . ?
C26A O1A C25A C26A -58.3(8) . . . 2_677 ?
C9A Si1A N1A Rh1A 95.5(3) . . . . ?
C9A Si1A N1A Si2A -137.1(4) . . . . ?
C9A Si1A N1A Li1A 13.3(5) . . . . ?
C25A O1A C26A C25A 57.2(8) . . . 2_677 ?
C2 C1 C6 C5 0.4(9) . . . . ?
C25 O1 C26 C25 -58.6(8) . . . 2_765 ?
C18 C17 C16 C15 0.2(11) . . . . ?
C21A Si3A N2A Rh1A 166.5(3) . . . . ?
C21A Si3A N2A Si4A -66.8(4) . . . . ?
C21A Si3A N2A Li1A 82.5(5) . . . . ?
C10 Si2 N1 Rh1 -144.9(3) . . . . ?
C10 Si2 N1 Si1 -17.0(5) . . . . ?
C10 Si2 N1 Li1 133.9(4) . . . . ?
C10 Si2 C12 P2 167.7(3) . . . . ?
C10 Si2 C11 Li1 -137.9(3) . . . . ?
C10A Si2A N1A Rh1A -166.7(3) . . . . ?
C10A Si2A N1A Si1A 63.7(5) . . . . ?
C10A Si2A N1A Li1A -78.3(6) . . . . ?
C10A Si2A C12A P2A 146.7(3) . . . . ?
C24 P1 C1 C6 131.6(5) . . . . ?
C24 P1 C1 C2 -51.2(6) . . . . ?
C24 P1 C7 Si1 -104.1(3) . . . . ?
C24 Si4 N2 Rh1 45.8(3) . . . . ?
C24 Si4 N2 Si3 171.7(3) . . . . ?
C24 Si4 N2 Li1 -37.9(4) . . . . ?
C20A Si3A N2A Rh1A -68.4(3) . . . . ?
C20A Si3A N2A Si4A 58.4(4) . . . . ?
C20A Si3A N2A Li1A -152.4(4) . . . . ?
C15 C14 C13 P2 -174.0(5) . . . . ?
C15 C14 C13 C18 2.6(9) . . . . ?
C13A P2A C12A Si2A 144.7(3) . . . . ?
C13A P2A C19A Si3A -101.2(3) . . . . ?
C13A C18A C17A C16A 0.3(10) . . . . ?
C13A C14A C15A C16A 0.2(10) . . . . ?
C17A C18A C13A P2A -177.0(5) . . . . ?
C17A C18A C13A C14A 0.3(9) . . . . ?
C17A C16A C15A C14A 0.5(11) . . . . ?
C7A Si1A N1A Rh1A -23.0(3) . . . . ?
C7A Si1A N1A Si2A 104.4(4) . . . . ?
C7A Si1A N1A Li1A -105.2(4) . . . . ?
C7A Si1A C9A Li1A 109.7(3) . . . . ?
C7A P1A C1A C6A -58.9(6) . . . . ?
C7A P1A C1A C2A 118.3(5) . . . . ?
C7A P1A C24A Si4A -128.2(3) . . . . ?
C6A C1A C2A C3A -0.2(10) . . . . ?
C6A C5A C4A C3A -0.1(12) . . . . ?
C11 Si2 N1 Rh1 96.3(3) . . . . ?
C11 Si2 N1 Si1 -135.8(4) . . . . ?
C11 Si2 N1 Li1 15.1(4) . . . . ?
C11 Si2 C12 P2 -79.8(4) . . . . ?
C13 P2 C19 Si3 118.2(3) . . . . ?
C13 P2 C12 Si2 -169.7(3) . . . . ?
C13 C14 C15 C16 -1.9(9) . . . . ?
C8A Si1A N1A Rh1A -145.6(3) . . . . ?
C8A Si1A N1A Si2A -18.2(5) . . . . ?
C8A Si1A N1A Li1A 132.3(4) . . . . ?
C8A Si1A C9A Li1A -136.6(3) . . . . ?
C8 Si1 N1 Rh1 72.5(3) . . . . ?
C8 Si1 N1 Si2 -57.9(5) . . . . ?
C8 Si1 N1 Li1 160.2(5) . . . . ?
C23A Si4A N2A Rh1A 83.3(4) . . . . ?
C23A Si4A N2A Si3A -42.0(5) . . . . ?
C23A Si4A N2A Li1A 174.0(5) . . . . ?
C22 Si4 N2 Rh1 163.7(3) . . . . ?
C22 Si4 N2 Si3 -70.4(4) . . . . ?
C22 Si4 N2 Li1 80.0(4) . . . . ?
C23 Si4 N2 Rh1 -72.4(3) . . . . ?
C23 Si4 N2 Si3 53.5(4) . . . . ?
C23 Si4 N2 Li1 -156.1(4) . . . . ?
C20 Si3 N2 Rh1 -160.2(3) . . . . ?
C20 Si3 N2 Si4 73.9(4) . . . . ?
C20 Si3 N2 Li1 -70.6(5) . . . . ?
C20 Si3 C19 P2 161.5(3) . . . . ?
C2A C1A C6A C5A -0.1(11) . . . . ?
C2A C3A C4A C5A -0.3(11) . . . . ?
C15A C14A C13A P2A 176.8(5) . . . . ?
C15A C14A C13A C18A -0.6(9) . . . . ?
C30 C29 C28 C27 -174.2(6) . . . . ?
Li1 Si2 N1 Rh1 81.1(4) . . . . ?
Li1 Si2 N1 Si1 -151.0(6) . . . . ?
Li1 Si2 C12 P2 -7.5(4) . . . . ?
Li1 Si4 N2 Rh1 83.7(4) . . . . ?
Li1 Si4 N2 Si3 -150.4(5) . . . . ?
Li1 O1 C26 C25 121.7(6) . . . 2_765 ?
Li1 O1 C25 C26 -121.8(6) . . . 2_765 ?
C29 C30 C31 C32 178.9(8) . . . . ?
C4A C3A C2A C1A 0.4(10) . . . . ?
C4A C5A C6A C1A 0.3(12) . . . . ?
C24A P1A C1A C6A 52.1(6) . . . . ?
C24A P1A C1A C2A -130.7(5) . . . . ?
C24A P1A C7A Si1A 80.5(4) . . . . ?
C24A Si4A N2A Rh1A -35.7(3) . . . . ?
C24A Si4A N2A Si3A -161.0(3) . . . . ?
C24A Si4A N2A Li1A 55.0(6) . . . . ?
C22A Si4A N2A Rh1A -153.9(3) . . . . ?
C22A Si4A N2A Si3A 80.8(4) . . . . ?
C22A Si4A N2A Li1A -63.3(6) . . . . ?
C31 C30 C29 C28 178.2(6) . . . . ?
C5 C4 C3 C2 0.3(10) . . . . ?
C16 C17 C18 C13 0.5(11) . . . . ?
C9 Si1 N1 Rh1 -166.6(3) . . . . ?
C9 Si1 N1 Si2 63.0(4) . . . . ?
C9 Si1 N1 Li1 -78.9(5) . . . . ?
Li1A Si1A N1A Rh1A 82.1(4) . . . . ?
Li1A Si1A N1A Si2A -150.5(6) . . . . ?
Li1A Si3A N2A Rh1A 84.0(4) . . . . ?
Li1A Si3A N2A Si4A -149.3(6) . . . . ?
Li1A O1A C26A C25A -123.0(7) . . . 2_677 ?
Li1A O1A C25A C26A 121.9(6) . . . 2_677 ?
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.5023(11)
2 0.4977(11)
