#------------------------------------------------------------------------------
#$Date: 2021-05-05 11:39:41 +0300 (Wed, 05 May 2021) $
#$Revision: 264902 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/66/7706684.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7706684
loop_
_publ_author_name
'Suzuki, Satoshi'
'Toda, Tatsuro'
'Kuwata, Shigeki'
_publ_section_title
;
 A diazene-bridged diruthenium complex with structural restraint defined
 by single meta-diphosphinobenzene.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4789
_journal_page_last               4795
_journal_paper_doi               10.1039/d0dt04398b
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C50 H56 Cl2 N2 P2 Ru2'
_chemical_formula_sum            'C50 H56 Cl2 N2 P2 Ru2'
_chemical_formula_weight         1020.00
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'by CrystalStructure 4.3'
_audit_update_record
;
2021-02-08 deposited with the CCDC.	2021-02-18 downloaded from the CCDC.
;
_cell_angle_alpha                90.0000
_cell_angle_beta                 91.5563(19)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   17.001(2)
_cell_length_b                   18.285(2)
_cell_length_c                   14.7640(18)
_cell_measurement_reflns_used    15361
_cell_measurement_temperature    93
_cell_measurement_theta_max      31.43
_cell_measurement_theta_min      1.64
_cell_volume                     4587.9(9)
_computing_cell_refinement       CrystalClear
_computing_data_collection       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'CrystalStructure 4.2.5'
_computing_publication_material  'CrystalStructure 4.2.5 (Rigaku, 2017)'
_computing_structure_refinement  'SHELXL Version 2014/7 (Sheldrick, 2008)'
_computing_structure_solution    'SIR92 (Altomare, et al., 1994)'
_diffrn_ambient_temperature      93
_diffrn_detector_area_resol_mean 7.111
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Rigaku Saturn724'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0595
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            37126
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.493
_diffrn_reflns_theta_min         3.012
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.881
_exptl_absorpt_correction_T_max  0.916
_exptl_absorpt_correction_T_min  0.687
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.477
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2088.00
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: diethyl ether'
_exptl_crystal_size_max          0.250
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.69
_refine_diff_density_min         -0.74
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.004
_refine_ls_hydrogen_treatment    mixed
_refine_ls_number_parameters     541
_refine_ls_number_reflns         10445
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0594
_refine_ls_R_factor_gt           0.0462
_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0581P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1110
_refine_ls_wR_factor_ref         0.1187
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7693
_reflns_number_total             10445
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            d0dt04398b2.cif
_cod_data_source_block           Compound3
_cod_depositor_comments
'Adding full bibliography for 7706683--7706685.cif.'
_cod_original_cell_volume        4587.9(10)
_cod_database_code               7706684
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 -X,1/2+Y,1/2-Z
3 -X,-Y,-Z
4 +X,-1/2-Y,-1/2+Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.31946(2) 0.51423(2) 0.64002(2) 0.01814(9) Uani 1 1 d . . . . .
Ru2 Ru 0.29452(2) 0.39073(2) 0.93802(2) 0.01781(9) Uani 1 1 d . . . . .
Cl1 Cl 0.21430(5) 0.42320(5) 0.62320(6) 0.0251(2) Uani 1 1 d . . . . .
Cl2 Cl 0.34314(5) 0.51314(5) 0.97943(6) 0.02345(19) Uani 1 1 d . . . . .
P1 P 0.22970(5) 0.60888(5) 0.66452(6) 0.01709(19) Uani 1 1 d . . . . .
P2 P 0.16520(5) 0.43351(5) 0.94342(6) 0.01601(19) Uani 1 1 d . . . . .
N1 N 0.31725(17) 0.48847(16) 0.7743(2) 0.0180(6) Uani 1 1 d . . . . .
N2 N 0.30381(18) 0.42543(17) 0.8090(2) 0.0194(6) Uani 1 1 d . . . . .
C1 C 0.4457(2) 0.4904(2) 0.6345(3) 0.0274(9) Uani 1 1 d . . . . .
C2 C 0.4323(2) 0.5648(2) 0.6095(3) 0.0255(8) Uani 1 1 d . . . . .
C3 C 0.3842(2) 0.5644(2) 0.5290(3) 0.0316(9) Uani 1 1 d . . . . .
C4 C 0.3660(3) 0.4909(3) 0.5066(3) 0.0360(10) Uani 1 1 d . . . . .
C5 C 0.4048(2) 0.4440(2) 0.5722(3) 0.0292(9) Uani 1 1 d . . . . .
C6 C 0.4961(3) 0.4658(3) 0.7138(3) 0.0451(12) Uani 1 1 d . . . . .
H3 H 0.5514 0.4655 0.6968 0.068 Uiso 1 1 calc R U . . .
H4 H 0.4804 0.4164 0.7317 0.068 Uiso 1 1 calc R U . . .
H5 H 0.4893 0.4995 0.7647 0.068 Uiso 1 1 calc R U . . .
C7 C 0.4739(3) 0.6299(3) 0.6498(4) 0.0503(14) Uani 1 1 d . . . . .
H6 H 0.4450 0.6745 0.6331 0.076 Uiso 1 1 calc R U . . .
H7 H 0.5273 0.6326 0.6266 0.076 Uiso 1 1 calc R U . . .
H8 H 0.4766 0.6252 0.7159 0.076 Uiso 1 1 calc R U . . .
C8 C 0.3642(3) 0.6300(3) 0.4710(4) 0.0626(17) Uani 1 1 d . . . . .
H9 H 0.3119 0.6234 0.4425 0.094 Uiso 1 1 calc R U . . .
H10 H 0.4033 0.6352 0.4239 0.094 Uiso 1 1 calc R U . . .
H11 H 0.3643 0.6741 0.5088 0.094 Uiso 1 1 calc R U . . .
C9 C 0.3193(3) 0.4654(4) 0.4241(3) 0.0627(17) Uani 1 1 d . . . . .
H12 H 0.3551 0.4445 0.3801 0.094 Uiso 1 1 calc R U . . .
H13 H 0.2911 0.5069 0.3967 0.094 Uiso 1 1 calc R U . . .
H14 H 0.2813 0.4281 0.4420 0.094 Uiso 1 1 calc R U . . .
C10 C 0.4042(3) 0.3625(2) 0.5720(4) 0.0508(14) Uani 1 1 d . . . . .
H15 H 0.4201 0.3444 0.6323 0.076 Uiso 1 1 calc R U . . .
H16 H 0.4411 0.3444 0.5273 0.076 Uiso 1 1 calc R U . . .
H17 H 0.3511 0.3450 0.5564 0.076 Uiso 1 1 calc R U . . .
C11 C 0.3478(3) 0.2855(3) 0.9111(3) 0.0473(13) Uani 1 1 d . . . . .
C12 C 0.2782(3) 0.2723(2) 0.9568(4) 0.0459(13) Uani 1 1 d . . . . .
C13 C 0.2861(3) 0.3041(2) 1.0432(3) 0.0377(11) Uani 1 1 d . . . . .
C14 C 0.3605(3) 0.3380(2) 1.0506(3) 0.0407(12) Uani 1 1 d . . . . .
C15 C 0.3997(3) 0.3256(3) 0.9662(3) 0.0436(12) Uani 1 1 d . . . . .
C16 C 0.3636(6) 0.2577(4) 0.8164(4) 0.139(4) Uani 1 1 d . . . . .
H18 H 0.3722 0.2047 0.8185 0.209 Uiso 1 1 calc R U . . .
H19 H 0.4105 0.2818 0.7935 0.209 Uiso 1 1 calc R U . . .
H20 H 0.3183 0.2685 0.7762 0.209 Uiso 1 1 calc R U . . .
C17 C 0.2141(5) 0.2199(3) 0.9265(6) 0.146(5) Uani 1 1 d . . . . .
H21 H 0.2204 0.1736 0.9593 0.219 Uiso 1 1 calc R U . . .
H22 H 0.2176 0.2110 0.8613 0.219 Uiso 1 1 calc R U . . .
H23 H 0.1626 0.2411 0.9392 0.219 Uiso 1 1 calc R U . . .
C18 C 0.2286(4) 0.2907(4) 1.1156(5) 0.113(4) Uani 1 1 d . . . . .
H24 H 0.2373 0.3262 1.1647 0.169 Uiso 1 1 calc R U . . .
H25 H 0.2357 0.2411 1.1394 0.169 Uiso 1 1 calc R U . . .
H26 H 0.1750 0.2962 1.0905 0.169 Uiso 1 1 calc R U . . .
C19 C 0.3957(6) 0.3763(3) 1.1300(4) 0.122(4) Uani 1 1 d . . . . .
H27 H 0.4318 0.3432 1.1628 0.182 Uiso 1 1 calc R U . . .
H28 H 0.3539 0.3917 1.1703 0.182 Uiso 1 1 calc R U . . .
H29 H 0.4246 0.4194 1.1097 0.182 Uiso 1 1 calc R U . . .
C20 C 0.4820(3) 0.3487(5) 0.9487(7) 0.141(5) Uani 1 1 d . . . . .
H30 H 0.4908 0.3475 0.8834 0.211 Uiso 1 1 calc R U . . .
H31 H 0.5188 0.3152 0.9797 0.211 Uiso 1 1 calc R U . . .
H32 H 0.4904 0.3985 0.9715 0.211 Uiso 1 1 calc R U . . .
C21 C 0.1840(2) 0.60652(18) 0.7761(2) 0.0167(7) Uani 1 1 d . . . . .
C22 C 0.16931(19) 0.53758(18) 0.8113(2) 0.0154(7) Uani 1 1 d . . . . .
H33 H 0.1704 0.4963 0.7723 0.019 Uiso 1 1 calc R U . . .
C23 C 0.15289(19) 0.52758(18) 0.9032(2) 0.0158(7) Uani 1 1 d . . . . .
C24 C 0.1412(2) 0.58892(19) 0.9561(2) 0.0175(7) Uani 1 1 d . . . . .
H34 H 0.1301 0.5834 1.0185 0.021 Uiso 1 1 calc R U . . .
C25 C 0.1456(2) 0.65840(19) 0.9186(2) 0.0195(7) Uani 1 1 d . . . . .
H35 H 0.1318 0.6999 0.9534 0.023 Uiso 1 1 calc R U . . .
C26 C 0.1702(2) 0.66727(19) 0.8306(2) 0.0195(7) Uani 1 1 d . . . . .
H36 H 0.1777 0.7151 0.8072 0.023 Uiso 1 1 calc R U . . .
C27 C 0.1428(2) 0.6184(2) 0.5887(2) 0.0222(8) Uani 1 1 d . . . . .
C28 C 0.0835(2) 0.6676(2) 0.6085(3) 0.0291(9) Uani 1 1 d . . . . .
H37 H 0.0894 0.6983 0.6601 0.035 Uiso 1 1 calc R U . . .
C29 C 0.0161(3) 0.6727(3) 0.5545(3) 0.0389(11) Uani 1 1 d . . . . .
H38 H -0.0233 0.7076 0.5681 0.047 Uiso 1 1 calc R U . . .
C30 C 0.0061(3) 0.6266(3) 0.4799(3) 0.0454(12) Uani 1 1 d . . . . .
H39 H -0.0410 0.6283 0.4438 0.055 Uiso 1 1 calc R U . . .
C31 C 0.0649(3) 0.5787(3) 0.4593(3) 0.0496(13) Uani 1 1 d . . . . .
H40 H 0.0590 0.5482 0.4074 0.059 Uiso 1 1 calc R U . . .
C32 C 0.1329(3) 0.5739(3) 0.5129(3) 0.0380(11) Uani 1 1 d . . . . .
H41 H 0.1730 0.5401 0.4978 0.046 Uiso 1 1 calc R U . . .
C33 C 0.2713(2) 0.70111(19) 0.6670(2) 0.0209(8) Uani 1 1 d . . . . .
C34 C 0.2557(2) 0.7530(2) 0.5999(3) 0.0304(9) Uani 1 1 d . . . . .
H42 H 0.2201 0.7413 0.5513 0.036 Uiso 1 1 calc R U . . .
C35 C 0.2912(3) 0.8217(2) 0.6027(3) 0.0381(11) Uani 1 1 d . . . . .
H43 H 0.2800 0.8562 0.5560 0.046 Uiso 1 1 calc R U . . .
C36 C 0.3418(3) 0.8394(2) 0.6720(3) 0.0362(10) Uani 1 1 d . . . . .
H44 H 0.3652 0.8866 0.6744 0.043 Uiso 1 1 calc R U . . .
C37 C 0.3593(2) 0.7884(2) 0.7396(3) 0.0344(10) Uani 1 1 d . . . . .
H45 H 0.3951 0.8006 0.7878 0.041 Uiso 1 1 calc R U . . .
C38 C 0.3247(2) 0.7196(2) 0.7367(3) 0.0258(8) Uani 1 1 d . . . . .
H46 H 0.3376 0.6848 0.7825 0.031 Uiso 1 1 calc R U . . .
C39 C 0.1285(2) 0.43445(18) 1.0590(2) 0.0185(7) Uani 1 1 d . . . . .
C40 C 0.0617(2) 0.39723(19) 1.0862(2) 0.0205(8) Uani 1 1 d . . . . .
H47 H 0.0290 0.3730 1.0425 0.025 Uiso 1 1 calc R U . . .
C41 C 0.0428(2) 0.3954(2) 1.1774(3) 0.0248(8) Uani 1 1 d . . . . .
H48 H -0.0029 0.3699 1.1953 0.030 Uiso 1 1 calc R U . . .
C42 C 0.0894(2) 0.4299(2) 1.2415(3) 0.0280(9) Uani 1 1 d . . . . .
H49 H 0.0761 0.4281 1.3035 0.034 Uiso 1 1 calc R U . . .
C43 C 0.1561(2) 0.4676(2) 1.2154(3) 0.0268(8) Uani 1 1 d . . . . .
H50 H 0.1882 0.4921 1.2595 0.032 Uiso 1 1 calc R U . . .
C44 C 0.1758(2) 0.46926(19) 1.1247(2) 0.0228(8) Uani 1 1 d . . . . .
H51 H 0.2220 0.4943 1.1072 0.027 Uiso 1 1 calc R U . . .
C45 C 0.0909(2) 0.38762(18) 0.8713(2) 0.0160(7) Uani 1 1 d . . . . .
C46 C 0.0116(2) 0.40732(19) 0.8707(2) 0.0201(7) Uani 1 1 d . . . . .
H52 H -0.0060 0.4442 0.9107 0.024 Uiso 1 1 calc R U . . .
C47 C -0.0418(2) 0.3729(2) 0.8116(2) 0.0235(8) Uani 1 1 d . . . . .
H53 H -0.0961 0.3853 0.8127 0.028 Uiso 1 1 calc R U . . .
C48 C -0.0164(2) 0.3210(2) 0.7517(3) 0.0261(8) Uani 1 1 d . . . . .
H54 H -0.0533 0.2979 0.7115 0.031 Uiso 1 1 calc R U . . .
C49 C 0.0619(2) 0.3024(2) 0.7494(3) 0.0281(9) Uani 1 1 d . . . . .
H55 H 0.0792 0.2670 0.7073 0.034 Uiso 1 1 calc R U . . .
C50 C 0.1155(2) 0.33551(19) 0.8090(2) 0.0219(8) Uani 1 1 d . . . . .
H56 H 0.1695 0.3226 0.8074 0.026 Uiso 1 1 calc R U . . .
H1 H 0.328(2) 0.517(2) 0.823(2) 0.017(10) Uiso 1 1 d . . . . .
H2 H 0.289(2) 0.395(2) 0.769(3) 0.022(11) Uiso 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
Cl Cl 0.1484 0.1585
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
P P 0.1023 0.0942
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Ru Ru -1.2594 0.8363
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ru1 C4 148.05(15) . . ?
N1 Ru1 C2 109.72(13) . . ?
C4 Ru1 C2 63.62(15) . . ?
N1 Ru1 C1 91.95(13) . . ?
C4 Ru1 C1 63.22(16) . . ?
C2 Ru1 C1 38.01(14) . . ?
N1 Ru1 C3 147.52(15) . . ?
C4 Ru1 C3 37.69(16) . . ?
C2 Ru1 C3 37.87(15) . . ?
C1 Ru1 C3 62.96(15) . . ?
N1 Ru1 C5 109.72(14) . . ?
C4 Ru1 C5 38.40(16) . . ?
C2 Ru1 C5 63.88(14) . . ?
C1 Ru1 C5 37.69(15) . . ?
C3 Ru1 C5 63.55(15) . . ?
N1 Ru1 P1 89.50(9) . . ?
C4 Ru1 P1 122.45(13) . . ?
C2 Ru1 P1 107.36(10) . . ?
C1 Ru1 P1 142.65(11) . . ?
C3 Ru1 P1 98.53(11) . . ?
C5 Ru1 P1 160.51(11) . . ?
N1 Ru1 Cl1 84.78(9) . . ?
C4 Ru1 Cl1 93.26(12) . . ?
C2 Ru1 Cl1 155.19(10) . . ?
C1 Ru1 Cl1 124.95(11) . . ?
C3 Ru1 Cl1 125.90(12) . . ?
C5 Ru1 Cl1 92.62(11) . . ?
P1 Ru1 Cl1 92.35(3) . . ?
N2 Ru2 C11 93.55(15) . . ?
N2 Ru2 C15 105.51(15) . . ?
C11 Ru2 C15 37.4(2) . . ?
N2 Ru2 C14 143.04(17) . . ?
C11 Ru2 C14 62.81(18) . . ?
C15 Ru2 C14 38.56(18) . . ?
N2 Ru2 C12 116.19(17) . . ?
C11 Ru2 C12 37.3(2) . . ?
C15 Ru2 C12 62.85(18) . . ?
C14 Ru2 C12 62.44(16) . . ?
N2 Ru2 C13 152.96(16) . . ?
C11 Ru2 C13 62.08(17) . . ?
C15 Ru2 C13 62.96(16) . . ?
C14 Ru2 C13 37.10(17) . . ?
C12 Ru2 C13 37.02(18) . . ?
N2 Ru2 P2 91.42(9) . . ?
C11 Ru2 P2 134.55(17) . . ?
C15 Ru2 P2 160.76(12) . . ?
C14 Ru2 P2 125.52(15) . . ?
C12 Ru2 P2 101.71(14) . . ?
C13 Ru2 P2 97.82(11) . . ?
N2 Ru2 Cl2 85.06(9) . . ?
C11 Ru2 Cl2 135.60(17) . . ?
C15 Ru2 Cl2 100.48(15) . . ?
C14 Ru2 Cl2 92.89(11) . . ?
C12 Ru2 Cl2 155.13(13) . . ?
C13 Ru2 Cl2 120.14(14) . . ?
P2 Ru2 Cl2 89.83(3) . . ?
C33 P1 C27 103.26(17) . . ?
C33 P1 C21 100.14(15) . . ?
C27 P1 C21 101.27(16) . . ?
C33 P1 Ru1 115.54(12) . . ?
C27 P1 Ru1 119.49(13) . . ?
C21 P1 Ru1 114.43(11) . . ?
C23 P2 C45 99.84(15) . . ?
C23 P2 C39 104.76(15) . . ?
C45 P2 C39 107.36(16) . . ?
C23 P2 Ru2 113.76(11) . . ?
C45 P2 Ru2 117.45(12) . . ?
C39 P2 Ru2 112.29(11) . . ?
N2 N1 Ru1 127.1(2) . . ?
N2 N1 H1 104(2) . . ?
Ru1 N1 H1 129(2) . . ?
N1 N2 Ru2 132.7(3) . . ?
N1 N2 H2 111(3) . . ?
Ru2 N2 H2 115(3) . . ?
C5 C1 C2 109.3(4) . . ?
C5 C1 C6 125.9(4) . . ?
C2 C1 C6 124.8(4) . . ?
C5 C1 Ru1 71.4(2) . . ?
C2 C1 Ru1 70.7(2) . . ?
C6 C1 Ru1 124.7(3) . . ?
C3 C2 C1 107.2(3) . . ?
C3 C2 C7 126.0(4) . . ?
C1 C2 C7 125.7(4) . . ?
C3 C2 Ru1 71.5(2) . . ?
C1 C2 Ru1 71.3(2) . . ?
C7 C2 Ru1 131.4(3) . . ?
C4 C3 C2 108.5(4) . . ?
C4 C3 C8 125.2(4) . . ?
C2 C3 C8 125.9(4) . . ?
C4 C3 Ru1 70.6(2) . . ?
C2 C3 Ru1 70.6(2) . . ?
C8 C3 Ru1 130.2(3) . . ?
C3 C4 C5 108.3(4) . . ?
C3 C4 C9 126.1(5) . . ?
C5 C4 C9 125.4(4) . . ?
C3 C4 Ru1 71.7(2) . . ?
C5 C4 Ru1 71.4(2) . . ?
C9 C4 Ru1 126.4(3) . . ?
C1 C5 C4 106.7(4) . . ?
C1 C5 C10 127.1(4) . . ?
C4 C5 C10 126.2(4) . . ?
C1 C5 Ru1 70.9(2) . . ?
C4 C5 Ru1 70.2(2) . . ?
C10 C5 Ru1 125.5(3) . . ?
C1 C6 H3 109.5 . . ?
C1 C6 H4 109.5 . . ?
H3 C6 H4 109.5 . . ?
C1 C6 H5 109.5 . . ?
H3 C6 H5 109.5 . . ?
H4 C6 H5 109.5 . . ?
C2 C7 H6 109.5 . . ?
C2 C7 H7 109.5 . . ?
H6 C7 H7 109.5 . . ?
C2 C7 H8 109.5 . . ?
H6 C7 H8 109.5 . . ?
H7 C7 H8 109.5 . . ?
C3 C8 H9 109.5 . . ?
C3 C8 H10 109.5 . . ?
H9 C8 H10 109.5 . . ?
C3 C8 H11 109.5 . . ?
H9 C8 H11 109.5 . . ?
H10 C8 H11 109.5 . . ?
C4 C9 H12 109.5 . . ?
C4 C9 H13 109.5 . . ?
H12 C9 H13 109.5 . . ?
C4 C9 H14 109.5 . . ?
H12 C9 H14 109.5 . . ?
H13 C9 H14 109.5 . . ?
C5 C10 H15 109.5 . . ?
C5 C10 H16 109.5 . . ?
H15 C10 H16 109.5 . . ?
C5 C10 H17 109.5 . . ?
H15 C10 H17 109.5 . . ?
H16 C10 H17 109.5 . . ?
C15 C11 C12 109.8(4) . . ?
C15 C11 C16 126.2(6) . . ?
C12 C11 C16 124.0(6) . . ?
C15 C11 Ru2 71.8(3) . . ?
C12 C11 Ru2 72.7(3) . . ?
C16 C11 Ru2 123.5(3) . . ?
C11 C12 C13 107.7(4) . . ?
C11 C12 C17 125.5(6) . . ?
C13 C12 C17 125.7(6) . . ?
C11 C12 Ru2 70.0(3) . . ?
C13 C12 Ru2 72.3(2) . . ?
C17 C12 Ru2 132.8(3) . . ?
C12 C13 C14 108.5(4) . . ?
C12 C13 C18 122.3(6) . . ?
C14 C13 C18 128.4(6) . . ?
C12 C13 Ru2 70.6(2) . . ?
C14 C13 Ru2 70.6(2) . . ?
C18 C13 Ru2 132.4(3) . . ?
C13 C14 C15 107.3(4) . . ?
C13 C14 C19 127.8(6) . . ?
C15 C14 C19 124.8(6) . . ?
C13 C14 Ru2 72.3(2) . . ?
C15 C14 Ru2 69.9(2) . . ?
C19 C14 Ru2 125.3(3) . . ?
C11 C15 C14 106.7(4) . . ?
C11 C15 C20 129.1(6) . . ?
C14 C15 C20 124.2(6) . . ?
C11 C15 Ru2 70.9(2) . . ?
C14 C15 Ru2 71.6(2) . . ?
C20 C15 Ru2 125.5(4) . . ?
C11 C16 H18 109.5 . . ?
C11 C16 H19 109.5 . . ?
H18 C16 H19 109.5 . . ?
C11 C16 H20 109.5 . . ?
H18 C16 H20 109.5 . . ?
H19 C16 H20 109.5 . . ?
C12 C17 H21 109.5 . . ?
C12 C17 H22 109.5 . . ?
H21 C17 H22 109.5 . . ?
C12 C17 H23 109.5 . . ?
H21 C17 H23 109.5 . . ?
H22 C17 H23 109.5 . . ?
C13 C18 H24 109.5 . . ?
C13 C18 H25 109.5 . . ?
H24 C18 H25 109.5 . . ?
C13 C18 H26 109.5 . . ?
H24 C18 H26 109.5 . . ?
H25 C18 H26 109.5 . . ?
C14 C19 H27 109.5 . . ?
C14 C19 H28 109.5 . . ?
H27 C19 H28 109.5 . . ?
C14 C19 H29 109.5 . . ?
H27 C19 H29 109.5 . . ?
H28 C19 H29 109.5 . . ?
C15 C20 H30 109.5 . . ?
C15 C20 H31 109.5 . . ?
H30 C20 H31 109.5 . . ?
C15 C20 H32 109.5 . . ?
H30 C20 H32 109.5 . . ?
H31 C20 H32 109.5 . . ?
C22 C21 C26 118.2(3) . . ?
C22 C21 P1 116.1(2) . . ?
C26 C21 P1 125.4(3) . . ?
C21 C22 C23 121.5(3) . . ?
C21 C22 H33 119.3 . . ?
C23 C22 H33 119.3 . . ?
C24 C23 C22 118.4(3) . . ?
C24 C23 P2 126.5(3) . . ?
C22 C23 P2 114.3(2) . . ?
C23 C24 C25 120.3(3) . . ?
C23 C24 H34 119.8 . . ?
C25 C24 H34 119.8 . . ?
C26 C25 C24 120.2(3) . . ?
C26 C25 H35 119.9 . . ?
C24 C25 H35 119.9 . . ?
C25 C26 C21 120.5(3) . . ?
C25 C26 H36 119.7 . . ?
C21 C26 H36 119.7 . . ?
C28 C27 C32 118.4(4) . . ?
C28 C27 P1 120.7(3) . . ?
C32 C27 P1 120.8(3) . . ?
C29 C28 C27 121.2(4) . . ?
C29 C28 H37 119.4 . . ?
C27 C28 H37 119.4 . . ?
C28 C29 C30 119.8(4) . . ?
C28 C29 H38 120.1 . . ?
C30 C29 H38 120.1 . . ?
C31 C30 C29 119.3(4) . . ?
C31 C30 H39 120.4 . . ?
C29 C30 H39 120.4 . . ?
C30 C31 C32 121.1(4) . . ?
C30 C31 H40 119.5 . . ?
C32 C31 H40 119.5 . . ?
C31 C32 C27 120.2(4) . . ?
C31 C32 H41 119.9 . . ?
C27 C32 H41 119.9 . . ?
C34 C33 C38 117.9(3) . . ?
C34 C33 P1 123.2(3) . . ?
C38 C33 P1 118.8(3) . . ?
C33 C34 C35 121.2(4) . . ?
C33 C34 H42 119.4 . . ?
C35 C34 H42 119.4 . . ?
C36 C35 C34 120.1(4) . . ?
C36 C35 H43 119.9 . . ?
C34 C35 H43 119.9 . . ?
C35 C36 C37 120.0(4) . . ?
C35 C36 H44 120.0 . . ?
C37 C36 H44 120.0 . . ?
C38 C37 C36 120.1(4) . . ?
C38 C37 H45 119.9 . . ?
C36 C37 H45 119.9 . . ?
C37 C38 C33 120.6(4) . . ?
C37 C38 H46 119.7 . . ?
C33 C38 H46 119.7 . . ?
C40 C39 C44 118.8(3) . . ?
C40 C39 P2 124.4(3) . . ?
C44 C39 P2 116.5(3) . . ?
C39 C40 C41 120.2(3) . . ?
C39 C40 H47 119.9 . . ?
C41 C40 H47 119.9 . . ?
C42 C41 C40 120.7(4) . . ?
C42 C41 H48 119.6 . . ?
C40 C41 H48 119.6 . . ?
C41 C42 C43 119.8(3) . . ?
C41 C42 H49 120.1 . . ?
C43 C42 H49 120.1 . . ?
C44 C43 C42 119.9(4) . . ?
C44 C43 H50 120.1 . . ?
C42 C43 H50 120.1 . . ?
C43 C44 C39 120.6(4) . . ?
C43 C44 H51 119.7 . . ?
C39 C44 H51 119.7 . . ?
C50 C45 C46 118.5(3) . . ?
C50 C45 P2 118.8(3) . . ?
C46 C45 P2 122.4(3) . . ?
C47 C46 C45 120.0(3) . . ?
C47 C46 H52 120.0 . . ?
C45 C46 H52 120.0 . . ?
C48 C47 C46 120.3(4) . . ?
C48 C47 H53 119.9 . . ?
C46 C47 H53 119.9 . . ?
C47 C48 C49 120.5(4) . . ?
C47 C48 H54 119.7 . . ?
C49 C48 H54 119.7 . . ?
C48 C49 C50 119.7(3) . . ?
C48 C49 H55 120.2 . . ?
C50 C49 H55 120.2 . . ?
C49 C50 C45 120.8(3) . . ?
C49 C50 H56 119.6 . . ?
C45 C50 H56 119.6 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 N1 2.039(3) . ?
Ru1 C4 2.185(4) . ?
Ru1 C2 2.187(4) . ?
Ru1 C1 2.193(4) . ?
Ru1 C3 2.199(4) . ?
Ru1 C5 2.200(4) . ?
Ru1 P1 2.3418(10) . ?
Ru1 Cl1 2.4504(9) . ?
Ru2 N2 2.017(3) . ?
Ru2 C11 2.168(4) . ?
Ru2 C15 2.179(4) . ?
Ru2 C14 2.202(4) . ?
Ru2 C12 2.203(4) . ?
Ru2 C13 2.225(4) . ?
Ru2 P2 2.3371(9) . ?
Ru2 Cl2 2.4575(9) . ?
P1 C33 1.829(4) . ?
P1 C27 1.837(4) . ?
P1 C21 1.841(3) . ?
P2 C23 1.830(3) . ?
P2 C45 1.832(3) . ?
P2 C39 1.834(3) . ?
N1 N2 1.285(4) . ?
N1 H1 0.91(4) . ?
N2 H2 0.85(4) . ?
C1 C5 1.419(6) . ?
C1 C2 1.426(5) . ?
C1 C6 1.500(6) . ?
C2 C3 1.423(6) . ?
C2 C7 1.501(6) . ?
C3 C4 1.416(6) . ?
C3 C8 1.508(6) . ?
C4 C5 1.442(6) . ?
C4 C9 1.509(6) . ?
C5 C10 1.490(6) . ?
C6 H3 0.9800 . ?
C6 H4 0.9800 . ?
C6 H5 0.9800 . ?
C7 H6 0.9800 . ?
C7 H7 0.9800 . ?
C7 H8 0.9800 . ?
C8 H9 0.9800 . ?
C8 H10 0.9800 . ?
C8 H11 0.9800 . ?
C9 H12 0.9800 . ?
C9 H13 0.9800 . ?
C9 H14 0.9800 . ?
C10 H15 0.9800 . ?
C10 H16 0.9800 . ?
C10 H17 0.9800 . ?
C11 C15 1.392(7) . ?
C11 C12 1.400(7) . ?
C11 C16 1.518(7) . ?
C12 C13 1.406(7) . ?
C12 C17 1.509(7) . ?
C13 C14 1.408(6) . ?
C13 C18 1.489(6) . ?
C14 C15 1.447(7) . ?
C14 C19 1.479(7) . ?
C15 C20 1.491(7) . ?
C16 H18 0.9800 . ?
C16 H19 0.9800 . ?
C16 H20 0.9800 . ?
C17 H21 0.9800 . ?
C17 H22 0.9800 . ?
C17 H23 0.9800 . ?
C18 H24 0.9800 . ?
C18 H25 0.9800 . ?
C18 H26 0.9800 . ?
C19 H27 0.9800 . ?
C19 H28 0.9800 . ?
C19 H29 0.9800 . ?
C20 H30 0.9800 . ?
C20 H31 0.9800 . ?
C20 H32 0.9800 . ?
C21 C22 1.389(4) . ?
C21 C26 1.395(4) . ?
C22 C23 1.404(5) . ?
C22 H33 0.9500 . ?
C23 C24 1.385(5) . ?
C24 C25 1.389(5) . ?
C24 H34 0.9500 . ?
C25 C26 1.385(5) . ?
C25 H35 0.9500 . ?
C26 H36 0.9500 . ?
C27 C28 1.388(5) . ?
C27 C32 1.390(5) . ?
C28 C29 1.382(6) . ?
C28 H37 0.9500 . ?
C29 C30 1.393(7) . ?
C29 H38 0.9500 . ?
C30 C31 1.370(7) . ?
C30 H39 0.9500 . ?
C31 C32 1.387(6) . ?
C31 H40 0.9500 . ?
C32 H41 0.9500 . ?
C33 C34 1.392(5) . ?
C33 C38 1.395(5) . ?
C34 C35 1.395(5) . ?
C34 H42 0.9500 . ?
C35 C36 1.358(6) . ?
C35 H43 0.9500 . ?
C36 C37 1.392(6) . ?
C36 H44 0.9500 . ?
C37 C38 1.389(5) . ?
C37 H45 0.9500 . ?
C38 H46 0.9500 . ?
C39 C40 1.392(5) . ?
C39 C44 1.397(5) . ?
C40 C41 1.392(5) . ?
C40 H47 0.9500 . ?
C41 C42 1.372(6) . ?
C41 H48 0.9500 . ?
C42 C43 1.391(6) . ?
C42 H49 0.9500 . ?
C43 C44 1.390(5) . ?
C43 H50 0.9500 . ?
C44 H51 0.9500 . ?
C45 C50 1.396(5) . ?
C45 C46 1.396(5) . ?
C46 C47 1.393(5) . ?
C46 H52 0.9500 . ?
C47 C48 1.374(5) . ?
C47 H53 0.9500 . ?
C48 C49 1.376(5) . ?
C48 H54 0.9500 . ?
C49 C50 1.388(5) . ?
C49 H55 0.9500 . ?
C50 H56 0.9500 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_D
_geom_hbond_site_symmetry_H
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DA
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
N1 H1 Cl2 . . . 3.082(3) 0.91(4) 2.31(4) 142(3) no
N2 H2 Cl1 . . . 3.102(3) 0.84(4) 2.52(4) 127(3) no
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ru1 N1 N2 Ru2 -176.85(16) . . . . ?
C5 C1 C2 C3 -1.6(4) . . . . ?
C6 C1 C2 C3 177.7(4) . . . . ?
Ru1 C1 C2 C3 -62.9(2) . . . . ?
C5 C1 C2 C7 -170.7(4) . . . . ?
C6 C1 C2 C7 8.6(6) . . . . ?
Ru1 C1 C2 C7 128.0(4) . . . . ?
C5 C1 C2 Ru1 61.3(3) . . . . ?
C6 C1 C2 Ru1 -119.4(4) . . . . ?
C1 C2 C3 C4 2.0(4) . . . . ?
C7 C2 C3 C4 171.1(4) . . . . ?
Ru1 C2 C3 C4 -60.7(3) . . . . ?
C1 C2 C3 C8 -171.1(4) . . . . ?
C7 C2 C3 C8 -2.1(6) . . . . ?
Ru1 C2 C3 C8 126.1(4) . . . . ?
C1 C2 C3 Ru1 62.7(2) . . . . ?
C7 C2 C3 Ru1 -128.2(4) . . . . ?
C2 C3 C4 C5 -1.7(4) . . . . ?
C8 C3 C4 C5 171.5(4) . . . . ?
Ru1 C3 C4 C5 -62.4(3) . . . . ?
C2 C3 C4 C9 -177.2(4) . . . . ?
C8 C3 C4 C9 -4.0(7) . . . . ?
Ru1 C3 C4 C9 122.1(4) . . . . ?
C2 C3 C4 Ru1 60.7(3) . . . . ?
C8 C3 C4 Ru1 -126.1(4) . . . . ?
C2 C1 C5 C4 0.6(4) . . . . ?
C6 C1 C5 C4 -178.7(4) . . . . ?
Ru1 C1 C5 C4 61.5(3) . . . . ?
C2 C1 C5 C10 178.6(4) . . . . ?
C6 C1 C5 C10 -0.7(6) . . . . ?
Ru1 C1 C5 C10 -120.5(4) . . . . ?
C2 C1 C5 Ru1 -60.9(3) . . . . ?
C6 C1 C5 Ru1 119.8(4) . . . . ?
C3 C4 C5 C1 0.6(4) . . . . ?
C9 C4 C5 C1 176.2(4) . . . . ?
Ru1 C4 C5 C1 -62.0(2) . . . . ?
C3 C4 C5 C10 -177.3(4) . . . . ?
C9 C4 C5 C10 -1.8(6) . . . . ?
Ru1 C4 C5 C10 120.1(4) . . . . ?
C3 C4 C5 Ru1 62.6(3) . . . . ?
C9 C4 C5 Ru1 -121.9(4) . . . . ?
C15 C11 C12 C13 -0.4(5) . . . . ?
C16 C11 C12 C13 177.9(4) . . . . ?
Ru2 C11 C12 C13 -62.9(3) . . . . ?
C15 C11 C12 C17 -168.6(4) . . . . ?
C16 C11 C12 C17 9.7(7) . . . . ?
Ru2 C11 C12 C17 128.9(5) . . . . ?
C15 C11 C12 Ru2 62.5(3) . . . . ?
C16 C11 C12 Ru2 -119.2(5) . . . . ?
C11 C12 C13 C14 0.7(5) . . . . ?
C17 C12 C13 C14 168.8(5) . . . . ?
Ru2 C12 C13 C14 -60.7(3) . . . . ?
C11 C12 C13 C18 -170.0(4) . . . . ?
C17 C12 C13 C18 -1.9(7) . . . . ?
Ru2 C12 C13 C18 128.6(4) . . . . ?
C11 C12 C13 Ru2 61.4(3) . . . . ?
C17 C12 C13 Ru2 -130.5(5) . . . . ?
C12 C13 C14 C15 -0.7(5) . . . . ?
C18 C13 C14 C15 169.3(4) . . . . ?
Ru2 C13 C14 C15 -61.4(3) . . . . ?
C12 C13 C14 C19 -177.9(5) . . . . ?
C18 C13 C14 C19 -7.9(8) . . . . ?
Ru2 C13 C14 C19 121.3(5) . . . . ?
C12 C13 C14 Ru2 60.8(3) . . . . ?
C18 C13 C14 Ru2 -129.3(4) . . . . ?
C12 C11 C15 C14 0.0(5) . . . . ?
C16 C11 C15 C14 -178.3(4) . . . . ?
Ru2 C11 C15 C14 63.1(3) . . . . ?
C12 C11 C15 C20 176.2(5) . . . . ?
C16 C11 C15 C20 -2.1(8) . . . . ?
Ru2 C11 C15 C20 -120.7(5) . . . . ?
C12 C11 C15 Ru2 -63.1(3) . . . . ?
C16 C11 C15 Ru2 118.6(5) . . . . ?
C13 C14 C15 C11 0.4(5) . . . . ?
C19 C14 C15 C11 177.7(4) . . . . ?
Ru2 C14 C15 C11 -62.6(3) . . . . ?
C13 C14 C15 C20 -176.0(5) . . . . ?
C19 C14 C15 C20 1.3(7) . . . . ?
Ru2 C14 C15 C20 120.9(5) . . . . ?
C13 C14 C15 Ru2 63.1(3) . . . . ?
C19 C14 C15 Ru2 -119.6(4) . . . . ?
C33 P1 C21 C22 -159.1(3) . . . . ?
C27 P1 C21 C22 95.1(3) . . . . ?
Ru1 P1 C21 C22 -34.9(3) . . . . ?
C33 P1 C21 C26 14.6(3) . . . . ?
C27 P1 C21 C26 -91.3(3) . . . . ?
Ru1 P1 C21 C26 138.8(3) . . . . ?
C26 C21 C22 C23 -9.8(5) . . . . ?
P1 C21 C22 C23 164.4(3) . . . . ?
C21 C22 C23 C24 8.5(5) . . . . ?
C21 C22 C23 P2 -162.1(3) . . . . ?
C45 P2 C23 C24 128.2(3) . . . . ?
C39 P2 C23 C24 17.2(3) . . . . ?
Ru2 P2 C23 C24 -105.8(3) . . . . ?
C45 P2 C23 C22 -62.1(3) . . . . ?
C39 P2 C23 C22 -173.1(2) . . . . ?
Ru2 P2 C23 C22 63.9(3) . . . . ?
C22 C23 C24 C25 0.1(5) . . . . ?
P2 C23 C24 C25 169.4(3) . . . . ?
C23 C24 C25 C26 -7.1(5) . . . . ?
C24 C25 C26 C21 5.7(5) . . . . ?
C22 C21 C26 C25 2.7(5) . . . . ?
P1 C21 C26 C25 -170.9(3) . . . . ?
C33 P1 C27 C28 -58.6(3) . . . . ?
C21 P1 C27 C28 44.8(3) . . . . ?
Ru1 P1 C27 C28 171.4(3) . . . . ?
C33 P1 C27 C32 124.7(3) . . . . ?
C21 P1 C27 C32 -131.9(3) . . . . ?
Ru1 P1 C27 C32 -5.2(4) . . . . ?
C32 C27 C28 C29 -0.1(6) . . . . ?
P1 C27 C28 C29 -176.8(3) . . . . ?
C27 C28 C29 C30 1.6(6) . . . . ?
C28 C29 C30 C31 -2.6(7) . . . . ?
C29 C30 C31 C32 2.0(8) . . . . ?
C30 C31 C32 C27 -0.4(8) . . . . ?
C28 C27 C32 C31 -0.6(6) . . . . ?
P1 C27 C32 C31 176.2(4) . . . . ?
C27 P1 C33 C34 -21.4(4) . . . . ?
C21 P1 C33 C34 -125.6(3) . . . . ?
Ru1 P1 C33 C34 111.0(3) . . . . ?
C27 P1 C33 C38 162.3(3) . . . . ?
C21 P1 C33 C38 58.0(3) . . . . ?
Ru1 P1 C33 C38 -65.4(3) . . . . ?
C38 C33 C34 C35 -1.0(6) . . . . ?
P1 C33 C34 C35 -177.4(3) . . . . ?
C33 C34 C35 C36 -0.4(7) . . . . ?
C34 C35 C36 C37 1.2(7) . . . . ?
C35 C36 C37 C38 -0.5(6) . . . . ?
C36 C37 C38 C33 -0.9(6) . . . . ?
C34 C33 C38 C37 1.6(6) . . . . ?
P1 C33 C38 C37 178.2(3) . . . . ?
C23 P2 C39 C40 113.8(3) . . . . ?
C45 P2 C39 C40 8.3(3) . . . . ?
Ru2 P2 C39 C40 -122.2(3) . . . . ?
C23 P2 C39 C44 -72.7(3) . . . . ?
C45 P2 C39 C44 -178.2(3) . . . . ?
Ru2 P2 C39 C44 51.3(3) . . . . ?
C44 C39 C40 C41 0.4(5) . . . . ?
P2 C39 C40 C41 173.7(3) . . . . ?
C39 C40 C41 C42 -0.1(5) . . . . ?
C40 C41 C42 C43 0.3(6) . . . . ?
C41 C42 C43 C44 -0.8(6) . . . . ?
C42 C43 C44 C39 1.0(6) . . . . ?
C40 C39 C44 C43 -0.8(5) . . . . ?
P2 C39 C44 C43 -174.7(3) . . . . ?
C23 P2 C45 C50 116.0(3) . . . . ?
C39 P2 C45 C50 -135.0(3) . . . . ?
Ru2 P2 C45 C50 -7.4(3) . . . . ?
C23 P2 C45 C46 -58.2(3) . . . . ?
C39 P2 C45 C46 50.8(3) . . . . ?
Ru2 P2 C45 C46 178.3(2) . . . . ?
C50 C45 C46 C47 2.8(5) . . . . ?
P2 C45 C46 C47 177.1(3) . . . . ?
C45 C46 C47 C48 -2.0(5) . . . . ?
C46 C47 C48 C49 0.1(6) . . . . ?
C47 C48 C49 C50 0.9(6) . . . . ?
C48 C49 C50 C45 0.0(6) . . . . ?
C46 C45 C50 C49 -1.8(5) . . . . ?
P2 C45 C50 C49 -176.3(3) . . . . ?
