#------------------------------------------------------------------------------
#$Date: 2021-05-05 11:39:41 +0300 (Wed, 05 May 2021) $
#$Revision: 264902 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/66/7706685.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7706685
loop_
_publ_author_name
'Suzuki, Satoshi'
'Toda, Tatsuro'
'Kuwata, Shigeki'
_publ_section_title
;
 A diazene-bridged diruthenium complex with structural restraint defined
 by single meta-diphosphinobenzene.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4789
_journal_page_last               4795
_journal_paper_doi               10.1039/d0dt04398b
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C56 H62 Cl2 N2 P2 Ru2'
_chemical_formula_sum            'C56 H62 Cl2 N2 P2 Ru2'
_chemical_formula_weight         1098.11
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'by CrystalStructure 4.3'
_audit_update_record
;
2021-02-08 deposited with the CCDC.	2021-02-18 downloaded from the CCDC.
;
_cell_angle_alpha                90.0000
_cell_angle_beta                 108.829(12)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   12.728(14)
_cell_length_b                   35.75(4)
_cell_length_c                   12.407(14)
_cell_measurement_reflns_used    10470
_cell_measurement_temperature    93
_cell_measurement_theta_max      27.49
_cell_measurement_theta_min      4.03
_cell_volume                     5343(10)
_computing_cell_refinement       CrystalClear
_computing_data_collection       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'CrystalStructure 4.3'
_computing_publication_material  'CrystalStructure 4.3 (Rigaku, 2018)'
_computing_structure_refinement  'SHELXL Version 2014/7 (Sheldrick, 2008)'
_computing_structure_solution    'SIR92 (Altomare, et al., 1994)'
_diffrn_ambient_temperature      93
_diffrn_detector_area_resol_mean 7.111
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.932
_diffrn_measurement_device_type  'Rigaku Saturn724'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.1065
_diffrn_reflns_av_unetI/netI     0.0979
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.932
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       45
_diffrn_reflns_limit_k_min       -44
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            53170
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.932
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.068
_diffrn_reflns_theta_min         3.010
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.762
_exptl_absorpt_correction_T_max  0.941
_exptl_absorpt_correction_T_min  0.591
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.365
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2256.00
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: THF/hexane'
_exptl_crystal_size_max          0.120
_exptl_crystal_size_mid          0.110
_exptl_crystal_size_min          0.080
_refine_diff_density_max         2.37
_refine_diff_density_min         -1.29
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.966
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     588
_refine_ls_number_reflns         11726
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1110
_refine_ls_R_factor_gt           0.0956
_refine_ls_shift/su_max          0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.2900P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3061
_refine_ls_wR_factor_ref         0.3417
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8677
_reflns_number_total             11726
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            d0dt04398b2.cif
_cod_data_source_block           Compound4
_cod_depositor_comments
'Adding full bibliography for 7706683--7706685.cif.'
_cod_database_code               7706685
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 -X,1/2+Y,1/2-Z
3 -X,-Y,-Z
4 +X,-1/2-Y,-1/2+Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.23265(5) 0.88526(2) 0.32694(6) 0.0205(2) Uani 1 1 d . . . . .
Ru2 Ru 0.58585(5) 0.85984(2) 0.65338(6) 0.0197(2) Uani 1 1 d . . . . .
Cl1 Cl 0.31735(19) 0.82451(6) 0.29543(19) 0.0268(5) Uani 1 1 d . . . . .
Cl2 Cl 0.60821(17) 0.91801(6) 0.54757(18) 0.0254(4) Uani 1 1 d . . . . .
P1 P 0.10827(18) 0.85373(6) 0.4026(2) 0.0231(5) Uani 1 1 d . . . . .
P2 P 0.55687(19) 0.89780(6) 0.79706(19) 0.0225(5) Uani 1 1 d . . . . .
N1 N 0.3626(6) 0.8872(2) 0.4796(7) 0.0250(16) Uani 1 1 d . . . . .
H1 H 0.3817 0.9099 0.5056 0.030 Uiso 1 1 calc R U . . .
N2 N 0.4215(6) 0.8607(2) 0.5442(6) 0.0217(15) Uani 1 1 d . . . . .
H2 H 0.3856 0.8395 0.5413 0.026 Uiso 1 1 calc R U . . .
C1 C 0.2929(8) 0.9197(3) 0.2077(8) 0.0294(19) Uani 1 1 d . . . . .
C2 C 0.2635(8) 0.9449(3) 0.2865(8) 0.0259(18) Uani 1 1 d . . . . .
C3 C 0.1450(8) 0.9401(3) 0.2694(8) 0.0290(19) Uani 1 1 d . . . . .
C4 C 0.1026(8) 0.9128(3) 0.1768(8) 0.0276(19) Uani 1 1 d . . . . .
C5 C 0.1911(9) 0.8999(3) 0.1403(9) 0.031(2) Uani 1 1 d . . . . .
C6 C 0.4082(9) 0.9165(3) 0.1910(10) 0.041(3) Uani 1 1 d . . . . .
H3 H 0.4151 0.9358 0.1378 0.061 Uiso 1 1 calc R U . . .
H4 H 0.4156 0.8917 0.1602 0.061 Uiso 1 1 calc R U . . .
H5 H 0.4666 0.9198 0.2644 0.061 Uiso 1 1 calc R U . . .
C7 C 0.3406(8) 0.9727(3) 0.3664(9) 0.033(2) Uani 1 1 d . . . . .
H6 H 0.3163 0.9767 0.4328 0.050 Uiso 1 1 calc R U . . .
H7 H 0.3390 0.9964 0.3265 0.050 Uiso 1 1 calc R U . . .
H8 H 0.4165 0.9627 0.3914 0.050 Uiso 1 1 calc R U . . .
C8 C 0.0750(9) 0.9659(3) 0.3178(9) 0.036(2) Uani 1 1 d . . . . .
H9 H 0.0618 0.9896 0.2758 0.053 Uiso 1 1 calc R U . . .
H10 H 0.1147 0.9707 0.3984 0.053 Uiso 1 1 calc R U . . .
H11 H 0.0038 0.9538 0.3100 0.053 Uiso 1 1 calc R U . . .
C9 C -0.0235(8) 0.9026(3) 0.1229(9) 0.036(2) Uani 1 1 d . . . . .
H12 H -0.0306 0.8790 0.0808 0.055 Uiso 1 1 calc R U . . .
H13 H -0.0617 0.9226 0.0708 0.055 Uiso 1 1 calc R U . . .
H14 H -0.0568 0.8999 0.1835 0.055 Uiso 1 1 calc R U . . .
C10 C 0.1850(11) 0.8733(3) 0.0416(9) 0.043(3) Uani 1 1 d . . . . .
H15 H 0.1793 0.8880 -0.0269 0.065 Uiso 1 1 calc R U . . .
H16 H 0.1198 0.8572 0.0271 0.065 Uiso 1 1 calc R U . . .
H17 H 0.2522 0.8579 0.0615 0.065 Uiso 1 1 calc R U . . .
C11 C 0.0154(7) 0.8167(3) 0.3132(9) 0.029(2) Uani 1 1 d . . . . .
C12 C -0.0640(8) 0.7972(3) 0.3504(10) 0.036(2) Uani 1 1 d . . . . .
H18 H -0.0743 0.8042 0.4202 0.043 Uiso 1 1 calc R U . . .
C13 C -0.1275(9) 0.7680(3) 0.2860(11) 0.042(3) Uani 1 1 d . . . . .
H19 H -0.1799 0.7554 0.3129 0.050 Uiso 1 1 calc R U . . .
C14 C -0.1145(9) 0.7570(3) 0.1811(11) 0.041(3) Uani 1 1 d . . . . .
H20 H -0.1590 0.7376 0.1370 0.049 Uiso 1 1 calc R U . . .
C15 C -0.0340(9) 0.7754(3) 0.1429(9) 0.040(3) Uani 1 1 d . . . . .
H21 H -0.0228 0.7677 0.0741 0.048 Uiso 1 1 calc R U . . .
C16 C 0.0306(8) 0.8057(3) 0.2080(9) 0.0289(19) Uani 1 1 d . . . . .
H22 H 0.0831 0.8183 0.1814 0.035 Uiso 1 1 calc R U . . .
C17 C 0.0094(8) 0.8867(2) 0.4363(9) 0.0269(19) Uani 1 1 d . . . . .
C18 C -0.1069(8) 0.8880(3) 0.3759(9) 0.029(2) Uani 1 1 d . . . . .
H23 H -0.1386 0.8699 0.3183 0.035 Uiso 1 1 calc R U . . .
C19 C -0.1765(8) 0.9158(3) 0.4002(10) 0.035(2) Uani 1 1 d . . . . .
H24 H -0.2533 0.9166 0.3575 0.042 Uiso 1 1 calc R U . . .
C20 C -0.1313(9) 0.9423(3) 0.4878(10) 0.034(2) Uani 1 1 d . . . . .
H25 H -0.1781 0.9605 0.5049 0.040 Uiso 1 1 calc R U . . .
C21 C -0.0151(9) 0.9417(3) 0.5507(9) 0.030(2) Uani 1 1 d . . . . .
H26 H 0.0156 0.9591 0.6105 0.036 Uiso 1 1 calc R U . . .
C22 C 0.0541(8) 0.9145(3) 0.5223(8) 0.0288(19) Uani 1 1 d . . . . .
H27 H 0.1317 0.9149 0.5614 0.035 Uiso 1 1 calc R U . . .
C23 C 0.1622(7) 0.8247(2) 0.5385(8) 0.0234(17) Uani 1 1 d . . . . .
C24 C 0.2136(8) 0.7895(3) 0.5294(9) 0.031(2) Uani 1 1 d . . . . .
H28 H 0.2245 0.7830 0.4596 0.037 Uiso 1 1 calc R U . . .
C25 C 0.2481(8) 0.7644(3) 0.6225(9) 0.032(2) Uani 1 1 d . . . . .
H29 H 0.2801 0.7410 0.6145 0.039 Uiso 1 1 calc R U . . .
C26 C 0.2343(8) 0.7745(3) 0.7288(9) 0.031(2) Uani 1 1 d . . . . .
H30 H 0.2574 0.7579 0.7917 0.038 Uiso 1 1 calc R U . . .
C27 C 0.1861(8) 0.8095(3) 0.7397(9) 0.034(2) Uani 1 1 d . . . . .
H31 H 0.1778 0.8164 0.8105 0.040 Uiso 1 1 calc R U . . .
C28 C 0.1501(8) 0.8344(3) 0.6453(9) 0.031(2) Uani 1 1 d . . . . .
H32 H 0.1176 0.8577 0.6535 0.037 Uiso 1 1 calc R U . . .
C29 C 0.6753(7) 0.8224(2) 0.5680(8) 0.0240(18) Uani 1 1 d . . . . .
C30 C 0.6006(8) 0.7992(2) 0.6095(8) 0.0262(18) Uani 1 1 d . . . . .
C31 C 0.6338(8) 0.8031(3) 0.7332(8) 0.0274(19) Uani 1 1 d . . . . .
C32 C 0.7328(8) 0.8271(3) 0.7686(8) 0.030(2) Uani 1 1 d . . . . .
C33 C 0.7573(7) 0.8387(3) 0.6688(7) 0.0262(19) Uani 1 1 d . . . . .
C34 C 0.6722(8) 0.8266(3) 0.4459(8) 0.031(2) Uani 1 1 d . . . . .
H33 H 0.7256 0.8093 0.4309 0.046 Uiso 1 1 calc R U . . .
H34 H 0.6915 0.8524 0.4327 0.046 Uiso 1 1 calc R U . . .
H35 H 0.5974 0.8208 0.3948 0.046 Uiso 1 1 calc R U . . .
C35 C 0.5085(8) 0.7735(2) 0.5364(8) 0.0269(19) Uani 1 1 d . . . . .
H36 H 0.4460 0.7736 0.5663 0.040 Uiso 1 1 calc R U . . .
H37 H 0.5372 0.7480 0.5387 0.040 Uiso 1 1 calc R U . . .
H38 H 0.4834 0.7826 0.4577 0.040 Uiso 1 1 calc R U . . .
C36 C 0.5891(9) 0.7787(3) 0.8109(9) 0.034(2) Uani 1 1 d . . . . .
H39 H 0.6114 0.7895 0.8875 0.051 Uiso 1 1 calc R U . . .
H40 H 0.6196 0.7534 0.8146 0.051 Uiso 1 1 calc R U . . .
H41 H 0.5079 0.7776 0.7800 0.051 Uiso 1 1 calc R U . . .
C37 C 0.8064(9) 0.8342(3) 0.8932(8) 0.037(2) Uani 1 1 d . . . . .
H42 H 0.8677 0.8162 0.9144 0.056 Uiso 1 1 calc R U . . .
H43 H 0.7618 0.8312 0.9439 0.056 Uiso 1 1 calc R U . . .
H44 H 0.8363 0.8596 0.9002 0.056 Uiso 1 1 calc R U . . .
C38 C 0.8590(8) 0.8604(3) 0.6674(10) 0.038(2) Uani 1 1 d . . . . .
H45 H 0.8368 0.8805 0.6108 0.057 Uiso 1 1 calc R U . . .
H46 H 0.9107 0.8435 0.6476 0.057 Uiso 1 1 calc R U . . .
H47 H 0.8954 0.8712 0.7428 0.057 Uiso 1 1 calc R U . . .
C39 C 0.6674(9) 0.9341(3) 0.8610(8) 0.032(2) Uani 1 1 d . . . . .
C40 C 0.6522(11) 0.9626(3) 0.9370(10) 0.045(3) Uani 1 1 d . . . . .
H48 H 0.5879 0.9624 0.9601 0.054 Uiso 1 1 calc R U . . .
C41 C 0.7331(13) 0.9908(3) 0.9770(12) 0.059(4) Uani 1 1 d . . . . .
H49 H 0.7235 1.0094 1.0275 0.071 Uiso 1 1 calc R U . . .
C42 C 0.8302(12) 0.9914(3) 0.9415(11) 0.056(4) Uani 1 1 d . . . . .
H50 H 0.8834 1.0109 0.9667 0.068 Uiso 1 1 calc R U . . .
C43 C 0.8463(10) 0.9631(4) 0.8691(10) 0.048(3) Uani 1 1 d . . . . .
H51 H 0.9120 0.9626 0.8486 0.057 Uiso 1 1 calc R U . . .
C44 C 0.7632(9) 0.9351(3) 0.8271(9) 0.039(2) Uani 1 1 d . . . . .
H52 H 0.7724 0.9168 0.7753 0.047 Uiso 1 1 calc R U . . .
C45 C 0.5463(8) 0.8715(3) 0.9248(8) 0.0295(19) Uani 1 1 d . . . . .
C46 C 0.6230(9) 0.8754(3) 1.0377(8) 0.032(2) Uani 1 1 d . . . . .
H53 H 0.6823 0.8928 1.0524 0.038 Uiso 1 1 calc R U . . .
C47 C 0.6104(9) 0.8531(3) 1.1282(9) 0.035(2) Uani 1 1 d . . . . .
H54 H 0.6624 0.8552 1.2027 0.042 Uiso 1 1 calc R U . . .
C48 C 0.5203(9) 0.8276(3) 1.1072(9) 0.034(2) Uani 1 1 d . . . . .
H55 H 0.5112 0.8130 1.1675 0.041 Uiso 1 1 calc R U . . .
C49 C 0.4446(9) 0.8242(3) 0.9962(9) 0.031(2) Uani 1 1 d . . . . .
H56 H 0.3831 0.8077 0.9825 0.038 Uiso 1 1 calc R U . . .
C50 C 0.4586(8) 0.8448(3) 0.9060(8) 0.0266(18) Uani 1 1 d . . . . .
H57 H 0.4092 0.8409 0.8311 0.032 Uiso 1 1 calc R U . . .
C51 C 0.4321(8) 0.9298(2) 0.7614(8) 0.0255(18) Uani 1 1 d . . . . .
C52 C 0.4337(8) 0.9621(3) 0.6958(9) 0.032(2) Uani 1 1 d . . . . .
H58 H 0.4937 0.9658 0.6672 0.038 Uiso 1 1 calc R U . . .
C53 C 0.3477(9) 0.9890(3) 0.6720(9) 0.035(2) Uani 1 1 d . . . . .
H59 H 0.3509 1.0106 0.6284 0.041 Uiso 1 1 calc R U . . .
C54 C 0.2574(9) 0.9839(3) 0.7129(10) 0.039(2) Uani 1 1 d . . . . .
H60 H 0.2013 1.0025 0.7004 0.047 Uiso 1 1 calc R U . . .
C55 C 0.2516(9) 0.9505(3) 0.7733(9) 0.034(2) Uani 1 1 d . . . . .
H61 H 0.1884 0.9459 0.7961 0.041 Uiso 1 1 calc R U . . .
C56 C 0.3396(8) 0.9242(3) 0.7997(8) 0.032(2) Uani 1 1 d . . . . .
H62 H 0.3366 0.9026 0.8434 0.038 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
Cl Cl 0.1484 0.1585
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
P P 0.1023 0.0942
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Ru Ru -1.2594 0.8363
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ru1 C1 104.1(4) . . ?
N1 Ru1 C2 91.6(3) . . ?
C1 Ru1 C2 38.0(3) . . ?
N1 Ru1 C3 115.3(3) . . ?
C1 Ru1 C3 63.5(4) . . ?
C2 Ru1 C3 37.9(3) . . ?
N1 Ru1 C5 141.3(3) . . ?
C1 Ru1 C5 38.3(4) . . ?
C2 Ru1 C5 63.5(3) . . ?
C3 Ru1 C5 63.1(3) . . ?
N1 Ru1 C4 152.5(3) . . ?
C1 Ru1 C4 62.3(3) . . ?
C2 Ru1 C4 62.7(3) . . ?
C3 Ru1 C4 37.9(3) . . ?
C5 Ru1 C4 36.4(3) . . ?
N1 Ru1 P1 95.3(2) . . ?
C1 Ru1 P1 159.6(3) . . ?
C2 Ru1 P1 136.4(2) . . ?
C3 Ru1 P1 102.3(3) . . ?
C5 Ru1 P1 123.3(3) . . ?
C4 Ru1 P1 97.3(2) . . ?
N1 Ru1 Cl1 85.1(2) . . ?
C1 Ru1 Cl1 96.7(3) . . ?
C2 Ru1 Cl1 132.0(3) . . ?
C3 Ru1 Cl1 153.7(3) . . ?
C5 Ru1 Cl1 90.6(3) . . ?
C4 Ru1 Cl1 118.8(3) . . ?
P1 Ru1 Cl1 91.47(10) . . ?
N2 Ru2 C29 104.9(3) . . ?
N2 Ru2 C31 111.7(3) . . ?
C29 Ru2 C31 64.1(3) . . ?
N2 Ru2 C30 90.1(3) . . ?
C29 Ru2 C30 38.4(3) . . ?
C31 Ru2 C30 37.8(3) . . ?
N2 Ru2 C33 142.8(3) . . ?
C29 Ru2 C33 38.1(3) . . ?
C31 Ru2 C33 62.9(3) . . ?
C30 Ru2 C33 63.0(3) . . ?
N2 Ru2 C32 149.3(3) . . ?
C29 Ru2 C32 63.2(3) . . ?
C31 Ru2 C32 37.8(4) . . ?
C30 Ru2 C32 62.7(4) . . ?
C33 Ru2 C32 36.9(3) . . ?
N2 Ru2 P2 96.5(2) . . ?
C29 Ru2 P2 158.4(3) . . ?
C31 Ru2 P2 105.7(3) . . ?
C30 Ru2 P2 141.2(2) . . ?
C33 Ru2 P2 120.7(2) . . ?
C32 Ru2 P2 96.8(3) . . ?
N2 Ru2 Cl2 84.7(2) . . ?
C29 Ru2 Cl2 94.9(2) . . ?
C31 Ru2 Cl2 155.6(2) . . ?
C30 Ru2 Cl2 129.3(2) . . ?
C33 Ru2 Cl2 92.9(3) . . ?
C32 Ru2 Cl2 122.9(3) . . ?
P2 Ru2 Cl2 89.46(11) . . ?
C17 P1 C11 103.6(4) . . ?
C17 P1 C23 102.8(4) . . ?
C11 P1 C23 96.7(4) . . ?
C17 P1 Ru1 111.9(3) . . ?
C11 P1 Ru1 118.3(4) . . ?
C23 P1 Ru1 120.8(3) . . ?
C45 P2 C51 102.5(4) . . ?
C45 P2 C39 103.6(4) . . ?
C51 P2 C39 97.9(4) . . ?
C45 P2 Ru2 114.8(3) . . ?
C51 P2 Ru2 119.7(3) . . ?
C39 P2 Ru2 115.8(4) . . ?
N2 N1 Ru1 131.8(6) . . ?
N2 N1 H1 114.1 . . ?
Ru1 N1 H1 114.1 . . ?
N1 N2 Ru2 131.5(6) . . ?
N1 N2 H2 114.3 . . ?
Ru2 N2 H2 114.3 . . ?
C2 C1 C5 107.9(8) . . ?
C2 C1 C6 126.2(9) . . ?
C5 C1 C6 125.7(9) . . ?
C2 C1 Ru1 71.5(5) . . ?
C5 C1 Ru1 71.7(5) . . ?
C6 C1 Ru1 126.0(7) . . ?
C3 C2 C1 107.7(8) . . ?
C3 C2 C7 126.2(9) . . ?
C1 C2 C7 126.0(9) . . ?
C3 C2 Ru1 71.1(5) . . ?
C1 C2 Ru1 70.5(5) . . ?
C7 C2 Ru1 126.6(6) . . ?
C2 C3 C4 107.0(8) . . ?
C2 C3 C8 125.1(9) . . ?
C4 C3 C8 126.3(9) . . ?
C2 C3 Ru1 71.0(5) . . ?
C4 C3 Ru1 71.9(5) . . ?
C8 C3 Ru1 133.6(7) . . ?
C5 C4 C3 109.7(8) . . ?
C5 C4 C9 126.5(9) . . ?
C3 C4 C9 123.7(9) . . ?
C5 C4 Ru1 71.2(6) . . ?
C3 C4 Ru1 70.2(5) . . ?
C9 C4 Ru1 128.4(6) . . ?
C4 C5 C1 107.7(9) . . ?
C4 C5 C10 128.1(10) . . ?
C1 C5 C10 124.0(9) . . ?
C4 C5 Ru1 72.4(6) . . ?
C1 C5 Ru1 70.0(5) . . ?
C10 C5 Ru1 127.6(7) . . ?
C1 C6 H3 109.5 . . ?
C1 C6 H4 109.5 . . ?
H3 C6 H4 109.5 . . ?
C1 C6 H5 109.5 . . ?
H3 C6 H5 109.5 . . ?
H4 C6 H5 109.5 . . ?
C2 C7 H6 109.5 . . ?
C2 C7 H7 109.5 . . ?
H6 C7 H7 109.5 . . ?
C2 C7 H8 109.5 . . ?
H6 C7 H8 109.5 . . ?
H7 C7 H8 109.5 . . ?
C3 C8 H9 109.5 . . ?
C3 C8 H10 109.5 . . ?
H9 C8 H10 109.5 . . ?
C3 C8 H11 109.5 . . ?
H9 C8 H11 109.5 . . ?
H10 C8 H11 109.5 . . ?
C4 C9 H12 109.5 . . ?
C4 C9 H13 109.5 . . ?
H12 C9 H13 109.5 . . ?
C4 C9 H14 109.5 . . ?
H12 C9 H14 109.5 . . ?
H13 C9 H14 109.5 . . ?
C5 C10 H15 109.5 . . ?
C5 C10 H16 109.5 . . ?
H15 C10 H16 109.5 . . ?
C5 C10 H17 109.5 . . ?
H15 C10 H17 109.5 . . ?
H16 C10 H17 109.5 . . ?
C12 C11 C16 118.7(9) . . ?
C12 C11 P1 122.1(8) . . ?
C16 C11 P1 119.1(7) . . ?
C13 C12 C11 121.3(11) . . ?
C13 C12 H18 119.4 . . ?
C11 C12 H18 119.4 . . ?
C12 C13 C14 120.8(10) . . ?
C12 C13 H19 119.6 . . ?
C14 C13 H19 119.6 . . ?
C13 C14 C15 119.2(9) . . ?
C13 C14 H20 120.4 . . ?
C15 C14 H20 120.4 . . ?
C14 C15 C16 120.2(10) . . ?
C14 C15 H21 119.9 . . ?
C16 C15 H21 119.9 . . ?
C11 C16 C15 119.8(9) . . ?
C11 C16 H22 120.1 . . ?
C15 C16 H22 120.1 . . ?
C18 C17 C22 117.6(8) . . ?
C18 C17 P1 124.2(7) . . ?
C22 C17 P1 118.0(7) . . ?
C17 C18 C19 121.4(9) . . ?
C17 C18 H23 119.3 . . ?
C19 C18 H23 119.3 . . ?
C20 C19 C18 120.1(9) . . ?
C20 C19 H24 119.9 . . ?
C18 C19 H24 119.9 . . ?
C19 C20 C21 120.0(9) . . ?
C19 C20 H25 120.0 . . ?
C21 C20 H25 120.0 . . ?
C22 C21 C20 119.1(9) . . ?
C22 C21 H26 120.5 . . ?
C20 C21 H26 120.5 . . ?
C21 C22 C17 121.7(9) . . ?
C21 C22 H27 119.1 . . ?
C17 C22 H27 119.1 . . ?
C28 C23 C24 118.3(8) . . ?
C28 C23 P1 124.9(7) . . ?
C24 C23 P1 116.7(7) . . ?
C25 C24 C23 121.3(9) . . ?
C25 C24 H28 119.4 . . ?
C23 C24 H28 119.4 . . ?
C24 C25 C26 119.6(9) . . ?
C24 C25 H29 120.2 . . ?
C26 C25 H29 120.2 . . ?
C27 C26 C25 119.7(9) . . ?
C27 C26 H30 120.1 . . ?
C25 C26 H30 120.1 . . ?
C26 C27 C28 120.4(9) . . ?
C26 C27 H31 119.8 . . ?
C28 C27 H31 119.8 . . ?
C27 C28 C23 120.7(9) . . ?
C27 C28 H32 119.6 . . ?
C23 C28 H32 119.6 . . ?
C33 C29 C30 106.6(8) . . ?
C33 C29 C34 126.7(8) . . ?
C30 C29 C34 126.5(8) . . ?
C33 C29 Ru2 71.9(5) . . ?
C30 C29 Ru2 71.7(5) . . ?
C34 C29 Ru2 124.4(6) . . ?
C31 C30 C29 108.3(8) . . ?
C31 C30 C35 125.8(8) . . ?
C29 C30 C35 125.9(8) . . ?
C31 C30 Ru2 71.0(5) . . ?
C29 C30 Ru2 69.9(5) . . ?
C35 C30 Ru2 127.6(6) . . ?
C30 C31 C32 107.4(8) . . ?
C30 C31 C36 124.4(9) . . ?
C32 C31 C36 126.7(9) . . ?
C30 C31 Ru2 71.2(5) . . ?
C32 C31 Ru2 72.0(5) . . ?
C36 C31 Ru2 133.1(6) . . ?
C33 C32 C31 108.4(8) . . ?
C33 C32 C37 125.8(9) . . ?
C31 C32 C37 125.4(9) . . ?
C33 C32 Ru2 70.8(5) . . ?
C31 C32 Ru2 70.2(5) . . ?
C37 C32 Ru2 130.7(7) . . ?
C32 C33 C29 109.2(8) . . ?
C32 C33 C38 125.7(9) . . ?
C29 C33 C38 124.7(8) . . ?
C32 C33 Ru2 72.3(5) . . ?
C29 C33 Ru2 70.0(5) . . ?
C38 C33 Ru2 129.4(7) . . ?
C29 C34 H33 109.5 . . ?
C29 C34 H34 109.5 . . ?
H33 C34 H34 109.5 . . ?
C29 C34 H35 109.5 . . ?
H33 C34 H35 109.5 . . ?
H34 C34 H35 109.5 . . ?
C30 C35 H36 109.5 . . ?
C30 C35 H37 109.5 . . ?
H36 C35 H37 109.5 . . ?
C30 C35 H38 109.5 . . ?
H36 C35 H38 109.5 . . ?
H37 C35 H38 109.5 . . ?
C31 C36 H39 109.5 . . ?
C31 C36 H40 109.5 . . ?
H39 C36 H40 109.5 . . ?
C31 C36 H41 109.5 . . ?
H39 C36 H41 109.5 . . ?
H40 C36 H41 109.5 . . ?
C32 C37 H42 109.5 . . ?
C32 C37 H43 109.5 . . ?
H42 C37 H43 109.5 . . ?
C32 C37 H44 109.5 . . ?
H42 C37 H44 109.5 . . ?
H43 C37 H44 109.5 . . ?
C33 C38 H45 109.5 . . ?
C33 C38 H46 109.5 . . ?
H45 C38 H46 109.5 . . ?
C33 C38 H47 109.5 . . ?
H45 C38 H47 109.5 . . ?
H46 C38 H47 109.5 . . ?
C44 C39 C40 119.3(10) . . ?
C44 C39 P2 119.2(8) . . ?
C40 C39 P2 121.4(9) . . ?
C41 C40 C39 119.8(13) . . ?
C41 C40 H48 120.1 . . ?
C39 C40 H48 120.1 . . ?
C40 C41 C42 120.3(12) . . ?
C40 C41 H49 119.8 . . ?
C42 C41 H49 119.8 . . ?
C43 C42 C41 119.9(11) . . ?
C43 C42 H50 120.1 . . ?
C41 C42 H50 120.1 . . ?
C42 C43 C44 119.6(12) . . ?
C42 C43 H51 120.2 . . ?
C44 C43 H51 120.2 . . ?
C39 C44 C43 121.1(12) . . ?
C39 C44 H52 119.4 . . ?
C43 C44 H52 119.4 . . ?
C50 C45 C46 118.3(9) . . ?
C50 C45 P2 117.4(7) . . ?
C46 C45 P2 124.2(8) . . ?
C47 C46 C45 120.1(10) . . ?
C47 C46 H53 120.0 . . ?
C45 C46 H53 120.0 . . ?
C48 C47 C46 120.1(9) . . ?
C48 C47 H54 119.9 . . ?
C46 C47 H54 119.9 . . ?
C49 C48 C47 119.5(9) . . ?
C49 C48 H55 120.2 . . ?
C47 C48 H55 120.2 . . ?
C50 C49 C48 120.8(10) . . ?
C50 C49 H56 119.6 . . ?
C48 C49 H56 119.6 . . ?
C49 C50 C45 121.1(9) . . ?
C49 C50 H57 119.5 . . ?
C45 C50 H57 119.5 . . ?
C52 C51 C56 118.3(9) . . ?
C52 C51 P2 117.5(7) . . ?
C56 C51 P2 124.1(7) . . ?
C53 C52 C51 121.4(9) . . ?
C53 C52 H58 119.3 . . ?
C51 C52 H58 119.3 . . ?
C54 C53 C52 120.2(10) . . ?
C54 C53 H59 119.9 . . ?
C52 C53 H59 119.9 . . ?
C53 C54 C55 119.0(9) . . ?
C53 C54 H60 120.5 . . ?
C55 C54 H60 120.5 . . ?
C56 C55 C54 120.5(10) . . ?
C56 C55 H61 119.8 . . ?
C54 C55 H61 119.8 . . ?
C55 C56 C51 120.5(9) . . ?
C55 C56 H62 119.8 . . ?
C51 C56 H62 119.8 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 N1 2.075(8) . ?
Ru1 C1 2.241(9) . ?
Ru1 C2 2.254(9) . ?
Ru1 C3 2.256(9) . ?
Ru1 C5 2.264(10) . ?
Ru1 C4 2.279(9) . ?
Ru1 P1 2.370(3) . ?
Ru1 Cl1 2.510(3) . ?
Ru2 N2 2.094(8) . ?
Ru2 C29 2.232(9) . ?
Ru2 C31 2.254(9) . ?
Ru2 C30 2.257(9) . ?
Ru2 C33 2.258(9) . ?
Ru2 C32 2.278(9) . ?
Ru2 P2 2.362(3) . ?
Ru2 Cl2 2.524(3) . ?
P1 C17 1.867(10) . ?
P1 C11 1.880(10) . ?
P1 C23 1.909(9) . ?
P2 C45 1.885(10) . ?
P2 C51 1.890(9) . ?
P2 C39 1.890(10) . ?
N1 N2 1.307(10) . ?
N1 H1 0.8800 . ?
N2 H2 0.8800 . ?
C1 C2 1.464(13) . ?
C1 C5 1.477(14) . ?
C1 C6 1.551(14) . ?
C2 C3 1.464(13) . ?
C2 C7 1.517(13) . ?
C3 C4 1.471(13) . ?
C3 C8 1.532(13) . ?
C4 C5 1.420(14) . ?
C4 C9 1.569(13) . ?
C5 C10 1.530(15) . ?
C6 H3 0.9800 . ?
C6 H4 0.9800 . ?
C6 H5 0.9800 . ?
C7 H6 0.9800 . ?
C7 H7 0.9800 . ?
C7 H8 0.9800 . ?
C8 H9 0.9800 . ?
C8 H10 0.9800 . ?
C8 H11 0.9800 . ?
C9 H12 0.9800 . ?
C9 H13 0.9800 . ?
C9 H14 0.9800 . ?
C10 H15 0.9800 . ?
C10 H16 0.9800 . ?
C10 H17 0.9800 . ?
C11 C12 1.421(14) . ?
C11 C16 1.435(15) . ?
C12 C13 1.402(15) . ?
C12 H18 0.9500 . ?
C13 C14 1.419(18) . ?
C13 H19 0.9500 . ?
C14 C15 1.422(17) . ?
C14 H20 0.9500 . ?
C15 C16 1.438(13) . ?
C15 H21 0.9500 . ?
C16 H22 0.9500 . ?
C17 C18 1.427(14) . ?
C17 C22 1.436(13) . ?
C18 C19 1.428(13) . ?
C18 H23 0.9500 . ?
C19 C20 1.415(15) . ?
C19 H24 0.9500 . ?
C20 C21 1.433(15) . ?
C20 H25 0.9500 . ?
C21 C22 1.429(13) . ?
C21 H26 0.9500 . ?
C22 H27 0.9500 . ?
C23 C28 1.426(13) . ?
C23 C24 1.438(13) . ?
C24 C25 1.415(14) . ?
C24 H28 0.9500 . ?
C25 C26 1.431(15) . ?
C25 H29 0.9500 . ?
C26 C27 1.420(14) . ?
C26 H30 0.9500 . ?
C27 C28 1.424(14) . ?
C27 H31 0.9500 . ?
C28 H32 0.9500 . ?
C29 C33 1.466(13) . ?
C29 C30 1.475(13) . ?
C29 C34 1.510(13) . ?
C30 C31 1.461(13) . ?
C30 C35 1.534(13) . ?
C31 C32 1.469(14) . ?
C31 C36 1.538(13) . ?
C32 C33 1.434(14) . ?
C32 C37 1.548(14) . ?
C33 C38 1.514(14) . ?
C34 H33 0.9800 . ?
C34 H34 0.9800 . ?
C34 H35 0.9800 . ?
C35 H36 0.9800 . ?
C35 H37 0.9800 . ?
C35 H38 0.9800 . ?
C36 H39 0.9800 . ?
C36 H40 0.9800 . ?
C36 H41 0.9800 . ?
C37 H42 0.9800 . ?
C37 H43 0.9800 . ?
C37 H44 0.9800 . ?
C38 H45 0.9800 . ?
C38 H46 0.9800 . ?
C38 H47 0.9800 . ?
C39 C44 1.413(16) . ?
C39 C40 1.442(15) . ?
C40 C41 1.412(18) . ?
C40 H48 0.9500 . ?
C41 C42 1.44(2) . ?
C41 H49 0.9500 . ?
C42 C43 1.41(2) . ?
C42 H50 0.9500 . ?
C43 C44 1.427(15) . ?
C43 H51 0.9500 . ?
C44 H52 0.9500 . ?
C45 C50 1.429(13) . ?
C45 C46 1.433(14) . ?
C46 C47 1.428(14) . ?
C46 H53 0.9500 . ?
C47 C48 1.420(16) . ?
C47 H54 0.9500 . ?
C48 C49 1.408(15) . ?
C48 H55 0.9500 . ?
C49 C50 1.398(14) . ?
C49 H56 0.9500 . ?
C50 H57 0.9500 . ?
C51 C52 1.416(13) . ?
C51 C56 1.420(14) . ?
C52 C53 1.414(14) . ?
C52 H58 0.9500 . ?
C53 C54 1.410(16) . ?
C53 H59 0.9500 . ?
C54 C55 1.423(15) . ?
C54 H60 0.9500 . ?
C55 C56 1.418(14) . ?
C55 H61 0.9500 . ?
C56 H62 0.9500 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_D
_geom_hbond_site_symmetry_H
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DA
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
N1 H1 Cl2 . . . 3.162(8) 0.880 2.775 108.1 no
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ru1 N1 N2 Ru2 150.1(5) . . . . ?
C5 C1 C2 C3 1.1(10) . . . . ?
C6 C1 C2 C3 176.7(9) . . . . ?
Ru1 C1 C2 C3 -61.7(6) . . . . ?
C5 C1 C2 C7 -175.6(9) . . . . ?
C6 C1 C2 C7 0.1(15) . . . . ?
Ru1 C1 C2 C7 121.6(9) . . . . ?
C5 C1 C2 Ru1 62.8(6) . . . . ?
C6 C1 C2 Ru1 -121.5(9) . . . . ?
C1 C2 C3 C4 -2.0(10) . . . . ?
C7 C2 C3 C4 174.6(8) . . . . ?
Ru1 C2 C3 C4 -63.4(6) . . . . ?
C1 C2 C3 C8 -168.2(9) . . . . ?
C7 C2 C3 C8 8.5(15) . . . . ?
Ru1 C2 C3 C8 130.5(9) . . . . ?
C1 C2 C3 Ru1 61.4(6) . . . . ?
C7 C2 C3 Ru1 -122.0(9) . . . . ?
C2 C3 C4 C5 2.3(10) . . . . ?
C8 C3 C4 C5 168.2(9) . . . . ?
Ru1 C3 C4 C5 -60.5(7) . . . . ?
C2 C3 C4 C9 -173.7(8) . . . . ?
C8 C3 C4 C9 -7.7(15) . . . . ?
Ru1 C3 C4 C9 123.6(9) . . . . ?
C2 C3 C4 Ru1 62.8(6) . . . . ?
C8 C3 C4 Ru1 -131.3(9) . . . . ?
C3 C4 C5 C1 -1.6(11) . . . . ?
C9 C4 C5 C1 174.2(9) . . . . ?
Ru1 C4 C5 C1 -61.5(6) . . . . ?
C3 C4 C5 C10 -175.7(9) . . . . ?
C9 C4 C5 C10 0.0(17) . . . . ?
Ru1 C4 C5 C10 124.4(10) . . . . ?
C3 C4 C5 Ru1 59.9(7) . . . . ?
C9 C4 C5 Ru1 -124.3(10) . . . . ?
C2 C1 C5 C4 0.3(10) . . . . ?
C6 C1 C5 C4 -175.4(9) . . . . ?
Ru1 C1 C5 C4 63.0(7) . . . . ?
C2 C1 C5 C10 174.8(9) . . . . ?
C6 C1 C5 C10 -0.9(15) . . . . ?
Ru1 C1 C5 C10 -122.6(10) . . . . ?
C2 C1 C5 Ru1 -62.7(6) . . . . ?
C6 C1 C5 Ru1 121.6(9) . . . . ?
C17 P1 C11 C12 -53.4(9) . . . . ?
C23 P1 C11 C12 51.6(9) . . . . ?
Ru1 P1 C11 C12 -178.0(7) . . . . ?
C17 P1 C11 C16 131.3(8) . . . . ?
C23 P1 C11 C16 -123.7(8) . . . . ?
Ru1 P1 C11 C16 6.7(9) . . . . ?
C16 C11 C12 C13 -0.5(15) . . . . ?
P1 C11 C12 C13 -175.8(8) . . . . ?
C11 C12 C13 C14 -0.2(17) . . . . ?
C12 C13 C14 C15 1.5(17) . . . . ?
C13 C14 C15 C16 -2.1(16) . . . . ?
C12 C11 C16 C15 -0.1(14) . . . . ?
P1 C11 C16 C15 175.3(7) . . . . ?
C14 C15 C16 C11 1.5(15) . . . . ?
C11 P1 C17 C18 -17.3(9) . . . . ?
C23 P1 C17 C18 -117.6(8) . . . . ?
Ru1 P1 C17 C18 111.3(8) . . . . ?
C11 P1 C17 C22 167.9(7) . . . . ?
C23 P1 C17 C22 67.7(8) . . . . ?
Ru1 P1 C17 C22 -63.5(8) . . . . ?
C22 C17 C18 C19 -0.2(14) . . . . ?
P1 C17 C18 C19 -175.0(7) . . . . ?
C17 C18 C19 C20 -1.8(15) . . . . ?
C18 C19 C20 C21 1.3(15) . . . . ?
C19 C20 C21 C22 1.1(14) . . . . ?
C20 C21 C22 C17 -3.1(14) . . . . ?
C18 C17 C22 C21 2.7(14) . . . . ?
P1 C17 C22 C21 177.8(7) . . . . ?
C28 C23 C24 C25 2.1(14) . . . . ?
P1 C23 C24 C25 -174.7(8) . . . . ?
C23 C24 C25 C26 -1.6(15) . . . . ?
C24 C25 C26 C27 0.1(14) . . . . ?
C25 C26 C27 C28 0.8(14) . . . . ?
C26 C27 C28 C23 -0.3(14) . . . . ?
C24 C23 C28 C27 -1.1(14) . . . . ?
P1 C23 C28 C27 175.4(7) . . . . ?
C33 C29 C30 C31 2.9(9) . . . . ?
C34 C29 C30 C31 179.4(8) . . . . ?
Ru2 C29 C30 C31 -60.9(6) . . . . ?
C33 C29 C30 C35 -173.7(8) . . . . ?
C34 C29 C30 C35 2.8(14) . . . . ?
Ru2 C29 C30 C35 122.5(9) . . . . ?
C33 C29 C30 Ru2 63.8(6) . . . . ?
C34 C29 C30 Ru2 -119.7(9) . . . . ?
C29 C30 C31 C32 -3.1(10) . . . . ?
C35 C30 C31 C32 173.5(8) . . . . ?
Ru2 C30 C31 C32 -63.3(6) . . . . ?
C29 C30 C31 C36 -169.8(8) . . . . ?
C35 C30 C31 C36 6.8(14) . . . . ?
Ru2 C30 C31 C36 130.0(8) . . . . ?
C29 C30 C31 Ru2 60.3(6) . . . . ?
C35 C30 C31 Ru2 -123.1(9) . . . . ?
C30 C31 C32 C33 2.0(10) . . . . ?
C36 C31 C32 C33 168.3(8) . . . . ?
Ru2 C31 C32 C33 -60.8(7) . . . . ?
C30 C31 C32 C37 -170.7(9) . . . . ?
C36 C31 C32 C37 -4.4(15) . . . . ?
Ru2 C31 C32 C37 126.5(9) . . . . ?
C30 C31 C32 Ru2 62.8(6) . . . . ?
C36 C31 C32 Ru2 -130.9(9) . . . . ?
C31 C32 C33 C29 -0.2(10) . . . . ?
C37 C32 C33 C29 172.5(9) . . . . ?
Ru2 C32 C33 C29 -60.6(6) . . . . ?
C31 C32 C33 C38 -173.3(9) . . . . ?
C37 C32 C33 C38 -0.6(16) . . . . ?
Ru2 C32 C33 C38 126.3(10) . . . . ?
C31 C32 C33 Ru2 60.4(6) . . . . ?
C37 C32 C33 Ru2 -126.9(10) . . . . ?
C30 C29 C33 C32 -1.7(10) . . . . ?
C34 C29 C33 C32 -178.1(9) . . . . ?
Ru2 C29 C33 C32 62.1(6) . . . . ?
C30 C29 C33 C38 171.5(9) . . . . ?
C34 C29 C33 C38 -4.9(15) . . . . ?
Ru2 C29 C33 C38 -124.7(9) . . . . ?
C30 C29 C33 Ru2 -63.7(6) . . . . ?
C34 C29 C33 Ru2 119.8(9) . . . . ?
C45 P2 C39 C44 122.1(8) . . . . ?
C51 P2 C39 C44 -132.9(8) . . . . ?
Ru2 P2 C39 C44 -4.5(9) . . . . ?
C45 P2 C39 C40 -62.7(9) . . . . ?
C51 P2 C39 C40 42.3(9) . . . . ?
Ru2 P2 C39 C40 170.8(7) . . . . ?
C44 C39 C40 C41 -0.4(15) . . . . ?
P2 C39 C40 C41 -175.7(9) . . . . ?
C39 C40 C41 C42 0.5(17) . . . . ?
C40 C41 C42 C43 -1.9(18) . . . . ?
C41 C42 C43 C44 3.2(16) . . . . ?
C40 C39 C44 C43 1.7(14) . . . . ?
P2 C39 C44 C43 177.1(7) . . . . ?
C42 C43 C44 C39 -3.2(15) . . . . ?
C51 P2 C45 C50 70.7(8) . . . . ?
C39 P2 C45 C50 172.2(7) . . . . ?
Ru2 P2 C45 C50 -60.6(8) . . . . ?
C51 P2 C45 C46 -112.2(9) . . . . ?
C39 P2 C45 C46 -10.7(10) . . . . ?
Ru2 P2 C45 C46 116.5(8) . . . . ?
C50 C45 C46 C47 -0.4(14) . . . . ?
P2 C45 C46 C47 -177.5(7) . . . . ?
C45 C46 C47 C48 -1.5(15) . . . . ?
C46 C47 C48 C49 0.9(15) . . . . ?
C47 C48 C49 C50 1.8(14) . . . . ?
C48 C49 C50 C45 -3.8(14) . . . . ?
C46 C45 C50 C49 3.1(14) . . . . ?
P2 C45 C50 C49 -179.7(7) . . . . ?
C45 P2 C51 C52 158.9(8) . . . . ?
C39 P2 C51 C52 53.0(8) . . . . ?
Ru2 P2 C51 C52 -72.8(8) . . . . ?
C45 P2 C51 C56 -18.6(9) . . . . ?
C39 P2 C51 C56 -124.5(8) . . . . ?
Ru2 P2 C51 C56 109.7(8) . . . . ?
C56 C51 C52 C53 2.3(14) . . . . ?
P2 C51 C52 C53 -175.4(8) . . . . ?
C51 C52 C53 C54 -0.5(16) . . . . ?
C52 C53 C54 C55 -3.1(16) . . . . ?
C53 C54 C55 C56 4.9(16) . . . . ?
C54 C55 C56 C51 -3.2(15) . . . . ?
C52 C51 C56 C55 -0.4(14) . . . . ?
P2 C51 C56 C55 177.1(8) . . . . ?
