#------------------------------------------------------------------------------
#$Date: 2021-06-05 21:43:56 +0300 (Sat, 05 Jun 2021) $
#$Revision: 266051 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/68/7706837.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7706837
loop_
_publ_author_name
'Zhong, Yu-Jie'
'Liao, Jian-Hong'
'Chiu, Tzu-Hao'
'Wu, Ying-Yann'
'Kahlal, Samia'
'McGlinchey, Michael J.'
'Saillard, Jean-Yves'
'Liu, C. W.'
_publ_section_title
;
 Intercluster exchanges leading to hydride-centered bimetallic clusters: a
 multi-NMR, X-ray crystallographic, and DFT study.
;
_journal_issue                   13
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4727
_journal_page_last               4734
_journal_paper_doi               10.1039/d1dt00072a
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C36 H85 Ag6 Cu O12 P6 Se12'
_chemical_formula_weight         2554.14
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-12-18 deposited with the CCDC.	2021-03-11 downloaded from the CCDC.
;
_cell_angle_alpha                110.4600(10)
_cell_angle_beta                 105.8160(10)
_cell_angle_gamma                109.9450(10)
_cell_formula_units_Z            1
_cell_length_a                   12.5584(6)
_cell_length_b                   13.4971(6)
_cell_length_c                   13.5892(7)
_cell_measurement_reflns_used    5126
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.07
_cell_measurement_theta_min      2.65
_cell_volume                     1816.87(16)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.973
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0399
_diffrn_reflns_av_unetI/netI     0.0608
_diffrn_reflns_Laue_measured_fraction_full 0.986
_diffrn_reflns_Laue_measured_fraction_max 0.973
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            16325
_diffrn_reflns_point_group_measured_fraction_full 0.986
_diffrn_reflns_point_group_measured_fraction_max 0.973
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.182
_diffrn_reflns_theta_min         1.786
_exptl_absorpt_coefficient_mu    8.057
_exptl_absorpt_correction_T_max  0.7455
_exptl_absorpt_correction_T_min  0.5047
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.334
_exptl_crystal_description       block
_exptl_crystal_F_000             1206
_exptl_crystal_size_max          0.060
_exptl_crystal_size_mid          0.060
_exptl_crystal_size_min          0.050
_refine_diff_density_max         0.977
_refine_diff_density_min         -0.689
_refine_diff_density_rms         0.152
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     374
_refine_ls_number_reflns         7859
_refine_ls_number_restraints     108
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0487
_refine_ls_R_factor_gt           0.0347
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0254P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0701
_refine_ls_wR_factor_ref         0.0759
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6378
_reflns_number_total             7859
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1dt00072a2.cif
_cod_data_source_block           6a
_cod_depositor_comments
'Adding full bibliography for 7706835--7706837.cif.'
_cod_original_cell_volume        1816.87(15)
_cod_database_code               7706837
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.644
_shelx_estimated_absorpt_t_max   0.689
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.65021(7) 0.60957(6) 0.65464(7) 0.01832(15) Uani 0.5 1 d . . P A .
Ag2 Ag 0.48939(6) 0.33792(7) 0.44602(6) 0.01873(15) Uani 0.5 1 d . . P A .
Ag3 Ag 0.54527(6) 0.55480(6) 0.39258(6) 0.01773(15) Uani 0.5 1 d . . P A .
Ag4 Ag 0.63848(6) 0.49926(6) 0.50104(5) 0.01499(14) Uani 0.5 1 d . . P A .
Ag5 Ag 0.71554(7) 0.67234(7) 0.74076(7) 0.01451(16) Uani 0.3333 1 d . . P A 1
Ag6 Ag 0.55529(7) 0.58258(6) 0.33832(6) 0.01460(16) Uani 0.3333 1 d . . P A 1
Ag7 Ag 0.46696(7) 0.25061(7) 0.42505(6) 0.01494(16) Uani 0.3333 1 d . . P A 1
Cu5 Cu 0.71554(7) 0.67234(7) 0.74076(7) 0.01451(16) Uani 0.1667 1 d . . P A 2
Cu6 Cu 0.55529(7) 0.58258(6) 0.33832(6) 0.01460(16) Uani 0.1667 1 d . . P A 2
Cu7 Cu 0.46696(7) 0.25061(7) 0.42505(6) 0.01494(16) Uani 0.1667 1 d . . P A 2
H1M H 0.500000 0.500000 0.500000 0.07(3) Uiso 1 2 d S . P . .
Se1 Se 0.29525(4) 0.65866(4) 0.45493(4) 0.01689(10) Uani 1 1 d . . . . .
Se2 Se 0.33181(4) 0.48439(4) 0.19566(4) 0.01768(11) Uani 1 1 d . . . . .
Se3 Se 0.63090(4) 0.81292(4) 0.78954(4) 0.01899(11) Uani 1 1 d . . . . .
Se4 Se 0.32950(4) 0.54142(4) 0.69444(4) 0.01825(11) Uani 1 1 d . . . . .
Se5 Se 0.32809(4) 0.19932(4) 0.51386(4) 0.02028(11) Uani 1 1 d . . . . .
Se6 Se 0.13455(4) 0.30376(4) 0.35854(4) 0.01900(11) Uani 1 1 d . . . . .
P1 P 0.27967(10) 0.61683(10) 0.28141(9) 0.0131(2) Uani 1 1 d . . . . .
P2 P 0.47998(10) 0.72033(9) 0.82669(9) 0.0134(2) Uani 1 1 d . . . . .
P3 P 0.14694(10) 0.16273(9) 0.39263(9) 0.0132(2) Uani 1 1 d . . . . .
O1 O 0.3564(3) 0.7302(2) 0.2731(2) 0.0154(6) Uani 1 1 d . . . . .
O2 O 0.1388(3) 0.5755(2) 0.1981(2) 0.0172(7) Uani 1 1 d . . . . .
O3 O 0.4193(3) 0.8034(3) 0.8636(3) 0.0181(7) Uani 1 1 d . . . . .
O4 O 0.5514(3) 0.7283(2) 0.9461(2) 0.0169(7) Uani 1 1 d . . . . .
O5 O 0.0427(3) 0.1135(2) 0.4338(2) 0.0164(7) Uani 1 1 d . . . . .
O6 O 0.1056(3) 0.0453(2) 0.2783(2) 0.0152(6) Uani 1 1 d . . . . .
C1 C 0.3595(4) 0.8482(4) 0.3286(4) 0.0202(10) Uani 1 1 d . . . . .
H1 H 0.351663 0.861715 0.402924 0.024 Uiso 1 1 calc R U . . .
C2 C 0.4861(5) 0.9422(4) 0.3561(4) 0.0273(12) Uani 1 1 d . . . . .
H2A H 0.552923 0.941096 0.412692 0.041 Uiso 1 1 calc R U . . .
H2B H 0.491839 1.022021 0.389517 0.041 Uiso 1 1 calc R U . . .
H2C H 0.496304 0.924802 0.283946 0.041 Uiso 1 1 calc R U . . .
C3 C 0.2519(5) 0.8472(4) 0.2458(5) 0.0339(12) Uani 1 1 d . . . . .
H3A H 0.262367 0.838430 0.174841 0.051 Uiso 1 1 calc R U . . .
H3B H 0.250805 0.923132 0.283590 0.051 Uiso 1 1 calc R U . . .
H3C H 0.171981 0.779260 0.224604 0.051 Uiso 1 1 calc R U . . .
C4 C 0.0303(4) 0.4772(4) 0.1883(4) 0.0213(10) Uani 1 1 d . . . . .
H4 H 0.061415 0.445767 0.240112 0.026 Uiso 1 1 calc R U . . .
C5 C -0.0471(5) 0.5301(5) 0.2279(5) 0.0432(16) Uani 1 1 d . . . . .
H5A H 0.003446 0.593444 0.310262 0.065 Uiso 1 1 calc R U . . .
H5B H -0.122232 0.466657 0.219555 0.065 Uiso 1 1 calc R U . . .
H5C H -0.073137 0.565014 0.179732 0.065 Uiso 1 1 calc R U . . .
C6 C -0.0401(5) 0.3780(4) 0.0617(4) 0.0316(12) Uani 1 1 d . . . . .
H6A H -0.075675 0.407428 0.011866 0.047 Uiso 1 1 calc R U . . .
H6B H -0.108538 0.308008 0.053170 0.047 Uiso 1 1 calc R U . . .
H6C H 0.018376 0.354367 0.038092 0.047 Uiso 1 1 calc R U . . .
C7 C 0.3488(4) 0.8344(4) 0.7831(4) 0.0203(10) Uani 1 1 d . . . . .
H7 H 0.365358 0.812823 0.712664 0.024 Uiso 1 1 calc R U . . .
C8 C 0.2103(5) 0.7628(5) 0.7449(6) 0.0536(18) Uani 1 1 d . . . . .
H8A H 0.193378 0.783489 0.813528 0.080 Uiso 1 1 calc R U . . .
H8B H 0.183834 0.676349 0.705549 0.080 Uiso 1 1 calc R U . . .
H8C H 0.163025 0.781717 0.690461 0.080 Uiso 1 1 calc R U . . .
C9 C 0.4001(5) 0.9687(4) 0.8482(4) 0.0308(12) Uani 1 1 d . . . . .
H9A H 0.356212 0.993145 0.797670 0.046 Uiso 1 1 calc R U . . .
H9B H 0.490807 1.009829 0.870592 0.046 Uiso 1 1 calc R U . . .
H9C H 0.386708 0.990758 0.918847 0.046 Uiso 1 1 calc R U . . .
C10 C 0.4898(4) 0.6531(4) 0.9927(4) 0.0186(10) Uani 1 1 d . . . . .
H10 H 0.445968 0.565842 0.932223 0.022 Uiso 1 1 calc R U . . .
C11 C 0.3947(5) 0.6847(5) 1.0237(4) 0.0304(12) Uani 1 1 d . . . . .
H11A H 0.437263 0.770462 1.082260 0.046 Uiso 1 1 calc R U . . .
H11B H 0.356910 0.635349 1.055767 0.046 Uiso 1 1 calc R U . . .
H11C H 0.328319 0.668925 0.953092 0.046 Uiso 1 1 calc R U . . .
C12 C 0.5970(5) 0.6773(4) 1.0975(4) 0.0296(12) Uani 1 1 d . . . . .
H12A H 0.655888 0.655645 1.072745 0.044 Uiso 1 1 calc R U . . .
H12B H 0.562999 0.628645 1.131762 0.044 Uiso 1 1 calc R U . . .
H12C H 0.641540 0.763180 1.156027 0.044 Uiso 1 1 calc R U . . .
C13 C 0.0223(4) 0.1891(4) 0.5280(4) 0.0197(10) Uani 1 1 d . . . . .
H13 H 0.045593 0.269842 0.532876 0.024 Uiso 1 1 calc R U . . .
C14 C 0.1017(5) 0.2043(4) 0.6432(4) 0.0270(11) Uani 1 1 d . . . . .
H14A H 0.080519 0.124696 0.636724 0.041 Uiso 1 1 calc R U . . .
H14B H 0.084865 0.250698 0.704889 0.041 Uiso 1 1 calc R U . . .
H14C H 0.191469 0.247559 0.662773 0.041 Uiso 1 1 calc R U . . .
C15 C -0.1176(5) 0.1213(5) 0.4914(5) 0.0343(13) Uani 1 1 d . . . . .
H15A H -0.140183 0.040949 0.483597 0.051 Uiso 1 1 calc R U . . .
H15B H -0.165388 0.112899 0.416026 0.051 Uiso 1 1 calc R U . . .
H15C H -0.137970 0.166002 0.550907 0.051 Uiso 1 1 calc R U . . .
C16 C 0.0059(4) 0.0009(4) 0.1607(4) 0.0182(9) Uani 1 1 d . . . . .
H16 H 0.024835 0.067420 0.140521 0.022 Uiso 1 1 calc R U . . .
C17 C -0.1215(5) -0.0396(5) 0.1588(4) 0.0360(13) Uani 1 1 d . . . . .
H17A H -0.138891 -0.102432 0.181804 0.054 Uiso 1 1 calc R U . . .
H17B H -0.186040 -0.072264 0.079489 0.054 Uiso 1 1 calc R U . . .
H17C H -0.123233 0.029248 0.213823 0.054 Uiso 1 1 calc R U . . .
C18 C 0.0178(5) -0.0988(4) 0.0780(4) 0.0302(12) Uani 1 1 d . . . . .
H18A H 0.103680 -0.066902 0.084701 0.045 Uiso 1 1 calc R U . . .
H18B H -0.043202 -0.130602 -0.002583 0.045 Uiso 1 1 calc R U . . .
H18C H 0.000507 -0.163694 0.098185 0.045 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cu5 Ag1 Ag4 140.83(7) . . ?
Ag5 Ag1 Ag4 140.83(7) . . ?
Ag5 Ag1 Ag2 117.86(7) . 2_666 ?
Ag4 Ag1 Ag2 90.52(4) . 2_666 ?
Ag5 Ag1 Ag3 121.23(6) . 2_666 ?
Ag4 Ag1 Ag3 86.82(4) . 2_666 ?
Ag2 Ag1 Ag3 82.45(3) 2_666 2_666 ?
Cu5 Ag1 Se6 76.37(5) . 2_666 ?
Ag5 Ag1 Se6 76.37(5) . 2_666 ?
Ag4 Ag1 Se6 68.53(3) . 2_666 ?
Ag2 Ag1 Se6 109.47(3) 2_666 2_666 ?
Ag3 Ag1 Se6 152.17(4) 2_666 2_666 ?
Ag5 Ag1 Se2 65.67(5) . 2_666 ?
Ag4 Ag1 Se2 111.02(3) . 2_666 ?
Ag2 Ag1 Se2 139.13(3) 2_666 2_666 ?
Ag3 Ag1 Se2 65.35(2) 2_666 2_666 ?
Se6 Ag1 Se2 110.66(3) 2_666 2_666 ?
Cu5 Ag1 Se3 57.71(6) . . ?
Ag5 Ag1 Se3 57.71(6) . . ?
Ag4 Ag1 Se3 149.34(4) . . ?
Ag2 Ag1 Se3 61.81(2) 2_666 . ?
Ag3 Ag1 Se3 101.21(3) 2_666 . ?
Se6 Ag1 Se3 106.59(3) 2_666 . ?
Se2 Ag1 Se3 99.11(2) 2_666 . ?
Ag5 Ag1 Ag6 106.67(5) . 2_666 ?
Ag4 Ag1 Ag6 96.62(3) . 2_666 ?
Ag2 Ag1 Ag6 94.40(3) 2_666 2_666 ?
Ag3 Ag1 Ag6 15.54(2) 2_666 2_666 ?
Se6 Ag1 Ag6 151.43(3) 2_666 2_666 ?
Se2 Ag1 Ag6 50.37(2) 2_666 2_666 ?
Se3 Ag1 Ag6 98.34(2) . 2_666 ?
Ag5 Ag1 Ag7 103.13(6) . 2_666 ?
Ag4 Ag1 Ag7 99.78(4) . 2_666 ?
Ag2 Ag1 Ag7 16.29(2) 2_666 2_666 ?
Ag3 Ag1 Ag7 96.33(3) 2_666 2_666 ?
Se6 Ag1 Ag7 100.30(2) 2_666 2_666 ?
Se2 Ag1 Ag7 142.33(3) 2_666 2_666 ?
Se3 Ag1 Ag7 50.24(2) . 2_666 ?
Ag6 Ag1 Ag7 106.39(3) 2_666 2_666 ?
Ag5 Ag1 Ag4 137.32(6) . 2_666 ?
Ag4 Ag1 Ag4 81.82(3) . 2_666 ?
Ag2 Ag1 Ag4 40.46(2) 2_666 2_666 ?
Ag3 Ag1 Ag4 42.82(2) 2_666 2_666 ?
Se6 Ag1 Ag4 138.51(3) 2_666 2_666 ?
Se2 Ag1 Ag4 106.69(2) 2_666 2_666 ?
Se3 Ag1 Ag4 84.31(2) . 2_666 ?
Ag6 Ag1 Ag4 56.65(2) 2_666 2_666 ?
Ag7 Ag1 Ag4 55.85(2) 2_666 2_666 ?
Cu5 Ag1 Ag3 146.49(6) . . ?
Ag5 Ag1 Ag3 146.49(6) . . ?
Ag4 Ag1 Ag3 42.03(3) . . ?
Ag2 Ag1 Ag3 49.44(2) 2_666 . ?
Ag3 Ag1 Ag3 89.98(3) 2_666 . ?
Se6 Ag1 Ag3 80.38(2) 2_666 . ?
Se2 Ag1 Ag3 146.65(3) 2_666 . ?
Se3 Ag1 Ag3 107.86(3) . . ?
Ag6 Ag1 Ag3 105.32(3) 2_666 . ?
Ag7 Ag1 Ag3 57.79(2) 2_666 . ?
Ag4 Ag1 Ag3 58.33(2) 2_666 . ?
Cu5 Ag1 H1M 167.70(7) . . ?
Ag5 Ag1 H1M 167.70(7) . . ?
Ag4 Ag1 H1M 51.41(3) . . ?
Ag2 Ag1 H1M 53.40(3) 2_666 . ?
Ag3 Ag1 H1M 52.58(2) 2_666 . ?
Se6 Ag1 H1M 113.85(3) 2_666 . ?
Se2 Ag1 H1M 114.22(3) 2_666 . ?
Se3 Ag1 H1M 111.20(3) . . ?
Ag6 Ag1 H1M 67.96(2) 2_666 . ?
Ag7 Ag1 H1M 69.12(3) 2_666 . ?
Ag4 Ag1 H1M 30.409(16) 2_666 . ?
Ag3 Ag1 H1M 37.396(17) . . ?
Cu7 Ag2 Ag4 141.19(7) . . ?
Ag7 Ag2 Ag4 141.19(7) . . ?
Ag7 Ag2 Ag1 122.93(7) . 2_666 ?
Ag4 Ag2 Ag1 90.01(4) . 2_666 ?
Ag7 Ag2 Ag3 115.51(6) . 2_666 ?
Ag4 Ag2 Ag3 86.52(3) . 2_666 ?
Ag1 Ag2 Ag3 82.05(3) 2_666 2_666 ?
Ag7 Ag2 Se1 73.60(6) . 2_666 ?
Ag4 Ag2 Se1 69.79(3) . 2_666 ?
Ag1 Ag2 Se1 157.78(3) 2_666 2_666 ?
Ag3 Ag2 Se1 105.06(3) 2_666 2_666 ?
Ag7 Ag2 Se3 67.79(6) . 2_666 ?
Ag4 Ag2 Se3 114.89(3) . 2_666 ?
Ag1 Ag2 Se3 67.66(3) 2_666 2_666 ?
Ag3 Ag2 Se3 141.92(3) 2_666 2_666 ?
Se1 Ag2 Se3 111.71(3) 2_666 2_666 ?
Cu7 Ag2 Se5 56.01(5) . . ?
Ag7 Ag2 Se5 56.01(5) . . ?
Ag4 Ag2 Se5 145.29(3) . . ?
Ag1 Ag2 Se5 99.37(3) 2_666 . ?
Ag3 Ag2 Se5 62.17(2) 2_666 . ?
Se1 Ag2 Se5 102.55(3) 2_666 . ?
Se3 Ag2 Se5 99.52(3) 2_666 . ?
Ag7 Ag2 Ag5 106.85(6) . 2_666 ?
Ag4 Ag2 Ag5 101.62(4) . 2_666 ?
Ag1 Ag2 Ag5 17.71(2) 2_666 2_666 ?
Ag3 Ag2 Ag5 96.08(3) 2_666 2_666 ?
Se1 Ag2 Ag5 156.36(3) 2_666 2_666 ?
Se3 Ag2 Ag5 50.60(2) 2_666 2_666 ?
Se5 Ag2 Ag5 96.55(3) . 2_666 ?
Ag7 Ag2 Ag6 100.59(6) . 2_666 ?
Ag4 Ag2 Ag6 96.39(3) . 2_666 ?
Ag1 Ag2 Ag6 94.06(3) 2_666 2_666 ?
Ag3 Ag2 Ag6 15.56(2) 2_666 2_666 ?
Se1 Ag2 Ag6 97.24(3) 2_666 2_666 ?
Se3 Ag2 Ag6 142.80(3) 2_666 2_666 ?
Se5 Ag2 Ag6 49.920(19) . 2_666 ?
Ag5 Ag2 Ag6 105.73(3) 2_666 2_666 ?
Ag7 Ag2 Ag4 136.60(6) . 2_666 ?
Ag4 Ag2 Ag4 81.48(3) . 2_666 ?
Ag1 Ag2 Ag4 40.19(2) 2_666 2_666 ?
Ag3 Ag2 Ag4 42.65(2) 2_666 2_666 ?
Se1 Ag2 Ag4 138.85(3) 2_666 2_666 ?
Se3 Ag2 Ag4 106.82(3) 2_666 2_666 ?
Se5 Ag2 Ag4 84.46(2) . 2_666 ?
Ag5 Ag2 Ag4 56.32(2) 2_666 2_666 ?
Ag6 Ag2 Ag4 56.49(2) 2_666 2_666 ?
Cu7 Ag2 Ag3 153.53(6) . . ?
Ag7 Ag2 Ag3 153.53(6) . . ?
Ag4 Ag2 Ag3 41.88(3) . . ?
Ag1 Ag2 Ag3 49.13(2) 2_666 . ?
Ag3 Ag2 Ag3 89.66(3) 2_666 . ?
Se1 Ag2 Ag3 109.17(3) 2_666 . ?
Se3 Ag2 Ag3 87.51(2) 2_666 . ?
Se5 Ag2 Ag3 142.22(3) . . ?
Ag5 Ag2 Ag3 59.78(2) 2_666 . ?
Ag6 Ag2 Ag3 105.03(3) 2_666 . ?
Ag4 Ag2 Ag3 58.14(2) 2_666 . ?
Cu7 Ag2 H1M 165.89(6) . . ?
Ag7 Ag2 H1M 165.89(6) . . ?
Ag4 Ag2 H1M 51.21(3) . . ?
Ag1 Ag2 H1M 52.99(3) 2_666 . ?
Ag3 Ag2 H1M 52.36(2) 2_666 . ?
Se1 Ag2 H1M 114.67(3) 2_666 . ?
Se3 Ag2 H1M 116.27(3) 2_666 . ?
Se5 Ag2 H1M 110.06(3) . . ?
Ag5 Ag2 H1M 70.47(3) 2_666 . ?
Ag6 Ag2 H1M 67.76(2) 2_666 . ?
Ag4 Ag2 H1M 30.273(16) 2_666 . ?
Ag3 Ag2 H1M 37.296(17) . . ?
Cu6 Ag3 Ag4 139.22(7) . . ?
Ag6 Ag3 Ag4 139.22(7) . . ?
Ag6 Ag3 Ag1 121.99(7) . 2_666 ?
Ag4 Ag3 Ag1 87.01(3) . 2_666 ?
Ag6 Ag3 Ag2 121.74(7) . 2_666 ?
Ag4 Ag3 Ag2 87.19(3) . 2_666 ?
Ag1 Ag3 Ag2 82.59(3) 2_666 2_666 ?
Ag6 Ag3 Se4 75.82(6) . 2_666 ?
Ag4 Ag3 Se4 67.97(3) . 2_666 ?
Ag1 Ag3 Se4 106.96(3) 2_666 2_666 ?
Ag2 Ag3 Se4 152.37(4) 2_666 2_666 ?
Ag6 Ag3 Se5 64.51(6) . 2_666 ?
Ag4 Ag3 Se5 111.01(3) . 2_666 ?
Ag1 Ag3 Se5 142.65(3) 2_666 2_666 ?
Ag2 Ag3 Se5 66.65(3) 2_666 2_666 ?
Se4 Ag3 Se5 110.10(3) 2_666 2_666 ?
Cu6 Ag3 Se2 60.33(6) . . ?
Ag6 Ag3 Se2 60.33(6) . . ?
Ag4 Ag3 Se2 146.31(3) . . ?
Ag1 Ag3 Se2 63.21(3) 2_666 . ?
Ag2 Ag3 Se2 103.08(3) 2_666 . ?
Se4 Ag3 Se2 104.35(3) 2_666 . ?
Se5 Ag3 Se2 102.46(3) 2_666 . ?
Ag6 Ag3 Ag7 104.53(7) . 2_666 ?
Ag4 Ag3 Ag7 99.16(3) . 2_666 ?
Ag1 Ag3 Ag7 96.48(3) 2_666 2_666 ?
Ag2 Ag3 Ag7 17.91(2) 2_666 2_666 ?
Se4 Ag3 Ag7 152.14(3) 2_666 2_666 ?
Se5 Ag3 Ag7 49.758(19) 2_666 2_666 ?
Se2 Ag3 Ag7 99.51(3) . 2_666 ?
Ag6 Ag3 Ag4 138.70(7) . 2_666 ?
Ag4 Ag3 Ag4 82.07(3) . 2_666 ?
Ag1 Ag3 Ag4 41.41(2) 2_666 2_666 ?
Ag2 Ag3 Ag4 41.51(2) 2_666 2_666 ?
Se4 Ag3 Ag4 138.68(3) 2_666 2_666 ?
Se5 Ag3 Ag4 106.82(3) 2_666 2_666 ?
Se2 Ag3 Ag4 84.86(2) . 2_666 ?
Ag7 Ag3 Ag4 57.16(2) 2_666 2_666 ?
Ag6 Ag3 Ag5 106.31(7) . 2_666 ?
Ag4 Ag3 Ag5 97.21(3) . 2_666 ?
Ag1 Ag3 Ag5 16.73(2) 2_666 2_666 ?
Ag2 Ag3 Ag5 96.30(3) 2_666 2_666 ?
Se4 Ag3 Ag5 98.57(3) 2_666 2_666 ?
Se5 Ag3 Ag5 145.42(3) 2_666 2_666 ?
Se2 Ag3 Ag5 50.26(2) . 2_666 ?
Ag7 Ag3 Ag5 107.75(3) 2_666 2_666 ?
Ag4 Ag3 Ag5 56.51(2) 2_666 2_666 ?
Cu6 Ag3 Ag1 146.89(7) . . ?
Ag6 Ag3 Ag1 146.89(7) . . ?
Ag4 Ag3 Ag1 39.57(2) . . ?
Ag1 Ag3 Ag1 90.02(3) 2_666 . ?
Ag2 Ag3 Ag1 48.51(3) 2_666 . ?
Se4 Ag3 Ag1 104.66(3) 2_666 . ?
Se5 Ag3 Ag1 85.18(2) 2_666 . ?
Se2 Ag3 Ag1 145.16(3) . . ?
Ag7 Ag3 Ag1 59.63(2) 2_666 . ?
Ag4 Ag3 Ag1 60.54(2) 2_666 . ?
Ag5 Ag3 Ag1 106.32(3) 2_666 . ?
Cu6 Ag3 H1M 170.88(8) . . ?
Ag6 Ag3 H1M 170.88(8) . . ?
Ag4 Ag3 H1M 49.89(2) . . ?
Ag1 Ag3 H1M 52.61(2) 2_666 . ?
Ag2 Ag3 H1M 52.79(2) 2_666 . ?
Se4 Ag3 H1M 112.23(3) 2_666 . ?
Se5 Ag3 H1M 114.60(3) 2_666 . ?
Se2 Ag3 H1M 112.22(3) . . ?
Ag7 Ag3 H1M 70.54(2) 2_666 . ?
Ag4 Ag3 H1M 32.178(17) 2_666 . ?
Ag5 Ag3 H1M 68.99(2) 2_666 . ?
Ag1 Ag3 H1M 37.414(18) . . ?
Ag1 Ag4 Ag2 103.28(3) . . ?
Ag1 Ag4 Ag3 98.41(4) . . ?
Ag2 Ag4 Ag3 98.59(4) . . ?
Ag1 Ag4 Se6 66.64(3) . 2_666 ?
Ag2 Ag4 Se6 158.01(4) . 2_666 ?
Ag3 Ag4 Se6 102.16(3) . 2_666 ?
Ag1 Ag4 Se4 152.16(3) . 2_666 ?
Ag2 Ag4 Se4 101.22(3) . 2_666 ?
Ag3 Ag4 Se4 64.80(3) . 2_666 ?
Se6 Ag4 Se4 94.18(2) 2_666 2_666 ?
Ag1 Ag4 Se1 104.38(3) . 2_666 ?
Ag2 Ag4 Se1 65.82(3) . 2_666 ?
Ag3 Ag4 Se1 154.74(3) . 2_666 ?
Se6 Ag4 Se1 96.83(3) 2_666 2_666 ?
Se4 Ag4 Se1 97.55(2) 2_666 2_666 ?
Ag1 Ag4 Ag7 109.43(3) . . ?
Ag2 Ag4 Ag7 12.77(3) . . ?
Ag3 Ag4 Ag7 108.07(3) . . ?
Se6 Ag4 Ag7 149.73(3) 2_666 . ?
Se4 Ag4 Ag7 97.25(2) 2_666 . ?
Se1 Ag4 Ag7 53.95(2) 2_666 . ?
Ag1 Ag4 Cu7 109.43(3) . . ?
Ag2 Ag4 Cu7 12.77(3) . . ?
Ag3 Ag4 Cu7 108.07(3) . . ?
Se6 Ag4 Cu7 149.73(3) 2_666 . ?
Se4 Ag4 Cu7 97.25(2) 2_666 . ?
Se1 Ag4 Cu7 53.95(2) 2_666 . ?
Ag1 Ag4 Ag5 13.01(3) . . ?
Ag2 Ag4 Ag5 111.64(3) . . ?
Ag3 Ag4 Ag5 106.15(3) . . ?
Se6 Ag4 Ag5 55.32(2) 2_666 . ?
Se4 Ag4 Ag5 147.02(3) 2_666 . ?
Se1 Ag4 Ag5 98.31(3) 2_666 . ?
Ag7 Ag4 Ag5 115.44(3) . . ?
Ag1 Ag4 Cu5 13.01(3) . . ?
Ag2 Ag4 Cu5 111.64(3) . . ?
Ag3 Ag4 Cu5 106.15(3) . . ?
Se6 Ag4 Cu5 55.32(2) 2_666 . ?
Se4 Ag4 Cu5 147.02(3) 2_666 . ?
Se1 Ag4 Cu5 98.31(3) 2_666 . ?
Cu7 Ag4 Cu5 115.44(3) . . ?
Ag1 Ag4 Cu6 105.77(4) . . ?
Ag2 Ag4 Cu6 105.93(4) . . ?
Ag3 Ag4 Cu6 12.33(2) . . ?
Se6 Ag4 Cu6 95.79(2) 2_666 . ?
Se4 Ag4 Cu6 54.21(2) 2_666 . ?
Se1 Ag4 Cu6 149.84(3) 2_666 . ?
Cu7 Ag4 Cu6 113.61(3) . . ?
Cu5 Ag4 Cu6 111.38(3) . . ?
Ag1 Ag4 Ag6 105.77(4) . . ?
Ag2 Ag4 Ag6 105.93(4) . . ?
Ag3 Ag4 Ag6 12.33(2) . . ?
Se6 Ag4 Ag6 95.79(2) 2_666 . ?
Se4 Ag4 Ag6 54.21(2) 2_666 . ?
Se1 Ag4 Ag6 149.84(3) 2_666 . ?
Ag7 Ag4 Ag6 113.61(3) . . ?
Ag5 Ag4 Ag6 111.38(3) . . ?
Ag1 Ag4 H1M 62.95(3) . . ?
Ag2 Ag4 H1M 63.24(3) . . ?
Ag3 Ag4 H1M 60.59(3) . . ?
Se6 Ag4 H1M 122.06(3) 2_666 . ?
Se4 Ag4 H1M 118.70(3) 2_666 . ?
Se1 Ag4 H1M 121.43(3) 2_666 . ?
Ag7 Ag4 H1M 75.84(2) . . ?
Cu7 Ag4 H1M 75.84(2) . . ?
Ag5 Ag4 H1M 75.96(3) . . ?
Cu5 Ag4 H1M 75.96(3) . . ?
Cu6 Ag4 H1M 72.92(3) . . ?
Ag6 Ag4 H1M 72.92(3) . . ?
Ag1 Ag5 Se3 101.46(7) . . ?
Ag1 Ag5 Se2 92.23(6) . 2_666 ?
Se3 Ag5 Se2 118.25(3) . 2_666 ?
Ag1 Ag5 Se6 80.86(5) . 2_666 ?
Se3 Ag5 Se6 121.07(3) . 2_666 ?
Se2 Ag5 Se6 120.50(3) 2_666 2_666 ?
Ag1 Ag5 Ag4 26.16(5) . . ?
Se3 Ag5 Ag4 122.64(4) . . ?
Se2 Ag5 Ag4 93.73(3) 2_666 . ?
Se6 Ag5 Ag4 57.88(2) 2_666 . ?
Ag1 Ag5 Ag2 44.43(5) . 2_666 ?
Se3 Ag5 Ag2 58.61(2) . 2_666 ?
Se2 Ag5 Ag2 121.15(3) 2_666 2_666 ?
Se6 Ag5 Ag2 93.79(3) 2_666 2_666 ?
Ag4 Ag5 Ag2 64.17(3) . 2_666 ?
Ag1 Ag5 Ag3 42.04(4) . 2_666 ?
Se3 Ag5 Ag3 94.17(3) . 2_666 ?
Se2 Ag5 Ag3 59.16(2) 2_666 2_666 ?
Se6 Ag5 Ag3 119.24(3) 2_666 2_666 ?
Ag4 Ag5 Ag3 61.50(2) . 2_666 ?
Ag2 Ag5 Ag3 62.51(3) 2_666 2_666 ?
Ag3 Ag6 Se2 100.03(6) . . ?
Ag3 Ag6 Se5 95.18(6) . 2_666 ?
Se2 Ag6 Se5 121.37(4) . 2_666 ?
Ag3 Ag6 Se4 83.02(6) . 2_666 ?
Se2 Ag6 Se4 116.71(3) . 2_666 ?
Se5 Ag6 Se4 121.21(3) 2_666 2_666 ?
Ag3 Ag6 Ag4 28.44(6) . . ?
Se2 Ag6 Ag4 122.07(3) . . ?
Se5 Ag6 Ag4 96.06(3) 2_666 . ?
Se4 Ag6 Ag4 58.30(2) 2_666 . ?
Ag3 Ag6 Ag1 42.47(5) . 2_666 ?
Se2 Ag6 Ag1 59.01(2) . 2_666 ?
Se5 Ag6 Ag1 124.37(3) 2_666 2_666 ?
Se4 Ag6 Ag1 92.42(3) 2_666 2_666 ?
Ag4 Ag6 Ag1 63.51(2) . 2_666 ?
Ag3 Ag6 Ag2 42.70(5) . 2_666 ?
Se2 Ag6 Ag2 95.57(3) . 2_666 ?
Se5 Ag6 Ag2 61.21(2) 2_666 2_666 ?
Se4 Ag6 Ag2 121.92(3) 2_666 2_666 ?
Ag4 Ag6 Ag2 63.70(2) . 2_666 ?
Ag1 Ag6 Ag2 63.45(2) 2_666 2_666 ?
Ag3 Ag6 Ag7 59.54(6) . 2_666 ?
Se2 Ag6 Ag7 97.44(3) . 2_666 ?
Se5 Ag6 Ag7 45.971(19) 2_666 2_666 ?
Se4 Ag6 Ag7 133.50(3) 2_666 2_666 ?
Ag4 Ag6 Ag7 77.35(3) . 2_666 ?
Ag1 Ag6 Ag7 78.48(2) 2_666 2_666 ?
Ag2 Ag6 Ag7 17.351(17) 2_666 2_666 ?
Ag2 Ag7 Se5 103.55(6) . . ?
Ag2 Ag7 Se3 90.12(6) . 2_666 ?
Se5 Ag7 Se3 118.46(3) . 2_666 ?
Ag2 Ag7 Se1 83.85(6) . 2_666 ?
Se5 Ag7 Se1 118.76(3) . 2_666 ?
Se3 Ag7 Se1 122.27(3) 2_666 2_666 ?
Ag2 Ag7 Ag4 26.05(5) . . ?
Se5 Ag7 Ag4 121.86(3) . . ?
Se3 Ag7 Ag4 95.59(3) 2_666 . ?
Se1 Ag7 Ag4 59.54(2) 2_666 . ?
Ag2 Ag7 Ag3 46.58(5) . 2_666 ?
Se5 Ag7 Ag3 59.55(2) . 2_666 ?
Se3 Ag7 Ag3 122.97(4) 2_666 2_666 ?
Se1 Ag7 Ag3 92.38(3) 2_666 2_666 ?
Ag4 Ag7 Ag3 62.45(2) . 2_666 ?
Ag2 Ag7 Ag1 40.78(6) . 2_666 ?
Se5 Ag7 Ag1 92.79(3) . 2_666 ?
Se3 Ag7 Ag1 60.61(2) 2_666 2_666 ?
Se1 Ag7 Ag1 122.80(3) 2_666 2_666 ?
Ag4 Ag7 Ag1 63.30(3) . 2_666 ?
Ag3 Ag7 Ag1 62.59(3) 2_666 2_666 ?
Ag2 Ag7 Ag6 62.06(5) . 2_666 ?
Se5 Ag7 Ag6 47.39(2) . 2_666 ?
Se3 Ag7 Ag6 134.97(3) 2_666 2_666 ?
Se1 Ag7 Ag6 91.08(3) 2_666 2_666 ?
Ag4 Ag7 Ag6 74.88(2) . 2_666 ?
Ag3 Ag7 Ag6 15.928(18) 2_666 2_666 ?
Ag1 Ag7 Ag6 76.38(3) 2_666 2_666 ?
Ag1 Cu5 Se3 101.46(7) . . ?
Ag1 Cu5 Se2 92.23(6) . 2_666 ?
Se3 Cu5 Se2 118.25(3) . 2_666 ?
Ag1 Cu5 Se6 80.86(5) . 2_666 ?
Se3 Cu5 Se6 121.07(3) . 2_666 ?
Se2 Cu5 Se6 120.50(3) 2_666 2_666 ?
Ag1 Cu5 Ag4 26.16(5) . . ?
Se3 Cu5 Ag4 122.64(4) . . ?
Se2 Cu5 Ag4 93.73(3) 2_666 . ?
Se6 Cu5 Ag4 57.88(2) 2_666 . ?
Ag1 Cu5 Ag2 44.43(5) . 2_666 ?
Se3 Cu5 Ag2 58.61(2) . 2_666 ?
Se2 Cu5 Ag2 121.15(3) 2_666 2_666 ?
Se6 Cu5 Ag2 93.79(3) 2_666 2_666 ?
Ag4 Cu5 Ag2 64.17(3) . 2_666 ?
Ag1 Cu5 Ag3 42.04(4) . 2_666 ?
Se3 Cu5 Ag3 94.17(3) . 2_666 ?
Se2 Cu5 Ag3 59.16(2) 2_666 2_666 ?
Se6 Cu5 Ag3 119.24(3) 2_666 2_666 ?
Ag4 Cu5 Ag3 61.50(2) . 2_666 ?
Ag2 Cu5 Ag3 62.51(3) 2_666 2_666 ?
Ag3 Cu6 Se2 100.03(6) . . ?
Ag3 Cu6 Se5 95.18(6) . 2_666 ?
Se2 Cu6 Se5 121.37(4) . 2_666 ?
Ag3 Cu6 Se4 83.02(6) . 2_666 ?
Se2 Cu6 Se4 116.71(3) . 2_666 ?
Se5 Cu6 Se4 121.21(3) 2_666 2_666 ?
Ag3 Cu6 Ag4 28.44(6) . . ?
Se2 Cu6 Ag4 122.07(3) . . ?
Se5 Cu6 Ag4 96.06(3) 2_666 . ?
Se4 Cu6 Ag4 58.30(2) 2_666 . ?
Ag3 Cu6 Ag1 42.47(5) . 2_666 ?
Se2 Cu6 Ag1 59.01(2) . 2_666 ?
Se5 Cu6 Ag1 124.37(3) 2_666 2_666 ?
Se4 Cu6 Ag1 92.42(3) 2_666 2_666 ?
Ag4 Cu6 Ag1 63.51(2) . 2_666 ?
Ag3 Cu6 Ag2 42.70(5) . 2_666 ?
Se2 Cu6 Ag2 95.57(3) . 2_666 ?
Se5 Cu6 Ag2 61.21(2) 2_666 2_666 ?
Se4 Cu6 Ag2 121.92(3) 2_666 2_666 ?
Ag4 Cu6 Ag2 63.70(2) . 2_666 ?
Ag1 Cu6 Ag2 63.45(2) 2_666 2_666 ?
Ag2 Cu7 Se5 103.55(6) . . ?
Ag2 Cu7 Se3 90.12(6) . 2_666 ?
Se5 Cu7 Se3 118.46(3) . 2_666 ?
Ag2 Cu7 Se1 83.85(6) . 2_666 ?
Se5 Cu7 Se1 118.76(3) . 2_666 ?
Se3 Cu7 Se1 122.27(3) 2_666 2_666 ?
Ag2 Cu7 Ag4 26.05(5) . . ?
Se5 Cu7 Ag4 121.86(3) . . ?
Se3 Cu7 Ag4 95.59(3) 2_666 . ?
Se1 Cu7 Ag4 59.54(2) 2_666 . ?
Ag2 Cu7 Ag3 46.58(5) . 2_666 ?
Se5 Cu7 Ag3 59.55(2) . 2_666 ?
Se3 Cu7 Ag3 122.97(4) 2_666 2_666 ?
Se1 Cu7 Ag3 92.38(3) 2_666 2_666 ?
Ag4 Cu7 Ag3 62.45(2) . 2_666 ?
Ag2 Cu7 Ag1 40.78(6) . 2_666 ?
Se5 Cu7 Ag1 92.79(3) . 2_666 ?
Se3 Cu7 Ag1 60.61(2) 2_666 2_666 ?
Se1 Cu7 Ag1 122.80(3) 2_666 2_666 ?
Ag4 Cu7 Ag1 63.30(3) . 2_666 ?
Ag3 Cu7 Ag1 62.59(3) 2_666 2_666 ?
P1 Se1 Ag7 101.79(4) . 2_666 ?
P1 Se1 Ag2 101.01(4) . 2_666 ?
Ag7 Se1 Ag2 22.56(2) 2_666 2_666 ?
P1 Se1 Ag4 104.01(4) . 2_666 ?
Ag7 Se1 Ag4 66.50(2) 2_666 2_666 ?
Ag2 Se1 Ag4 44.38(2) 2_666 2_666 ?
P1 Se2 Cu6 99.87(4) . . ?
P1 Se2 Ag6 99.87(4) . . ?
P1 Se2 Ag5 109.61(3) . 2_666 ?
Ag6 Se2 Ag5 88.30(3) . 2_666 ?
P1 Se2 Ag1 98.93(3) . 2_666 ?
Ag6 Se2 Ag1 70.61(3) . 2_666 ?
Ag5 Se2 Ag1 22.10(2) 2_666 2_666 ?
P1 Se2 Ag3 97.49(4) . . ?
Cu6 Se2 Ag3 19.643(19) . . ?
Ag6 Se2 Ag3 19.643(19) . . ?
Ag5 Se2 Ag3 70.59(3) 2_666 . ?
Ag1 Se2 Ag3 51.44(2) 2_666 . ?
P2 Se3 Cu5 102.88(4) . . ?
P2 Se3 Ag5 102.88(4) . . ?
P2 Se3 Ag7 107.06(4) . 2_666 ?
Ag5 Se3 Ag7 87.60(3) . 2_666 ?
P2 Se3 Ag2 96.33(3) . 2_666 ?
Ag5 Se3 Ag2 70.79(3) . 2_666 ?
Ag7 Se3 Ag2 22.09(2) 2_666 2_666 ?
P2 Se3 Ag1 98.54(3) . . ?
Cu5 Se3 Ag1 20.82(2) . . ?
Ag5 Se3 Ag1 20.82(2) . . ?
Ag7 Se3 Ag1 69.15(3) 2_666 . ?
Ag2 Se3 Ag1 50.53(2) 2_666 . ?
P2 Se4 Ag6 103.33(4) . 2_666 ?
P2 Se4 Ag3 101.17(4) . 2_666 ?
Ag6 Se4 Ag3 21.16(2) 2_666 2_666 ?
P2 Se4 Ag4 105.62(3) . 2_666 ?
Ag6 Se4 Ag4 67.48(2) 2_666 2_666 ?
Ag3 Se4 Ag4 47.23(2) 2_666 2_666 ?
P3 Se5 Cu7 103.84(4) . . ?
P3 Se5 Ag7 103.84(4) . . ?
P3 Se5 Ag6 107.40(4) . 2_666 ?
Ag7 Se5 Ag6 86.64(3) . 2_666 ?
P3 Se5 Ag3 98.43(4) . 2_666 ?
Ag7 Se5 Ag3 70.69(3) . 2_666 ?
Ag6 Se5 Ag3 20.31(2) 2_666 2_666 ?
P3 Se5 Ag2 98.95(3) . . ?
Cu7 Se5 Ag2 20.44(2) . . ?
Ag7 Se5 Ag2 20.44(2) . . ?
Ag6 Se5 Ag2 68.86(2) 2_666 . ?
Ag3 Se5 Ag2 51.18(2) 2_666 . ?
P3 Se6 Ag5 98.96(4) . 2_666 ?
P3 Se6 Ag1 98.48(4) . 2_666 ?
Ag5 Se6 Ag1 22.77(2) 2_666 2_666 ?
P3 Se6 Ag4 106.38(4) . 2_666 ?
Ag5 Se6 Ag4 66.80(2) 2_666 2_666 ?
Ag1 Se6 Ag4 44.83(2) 2_666 2_666 ?
O1 P1 O2 101.57(16) . . ?
O1 P1 Se1 113.59(11) . . ?
O2 P1 Se1 108.23(11) . . ?
O1 P1 Se2 104.38(11) . . ?
O2 P1 Se2 108.41(12) . . ?
Se1 P1 Se2 119.17(5) . . ?
O4 P2 O3 101.78(16) . . ?
O4 P2 Se4 113.52(12) . . ?
O3 P2 Se4 108.20(12) . . ?
O4 P2 Se3 104.21(11) . . ?
O3 P2 Se3 108.33(11) . . ?
Se4 P2 Se3 119.31(5) . . ?
O6 P3 O5 101.22(15) . . ?
O6 P3 Se6 112.89(12) . . ?
O5 P3 Se6 109.20(13) . . ?
O6 P3 Se5 103.99(13) . . ?
O5 P3 Se5 108.84(13) . . ?
Se6 P3 Se5 119.13(5) . . ?
C1 O1 P1 124.1(2) . . ?
C4 O2 P1 121.0(3) . . ?
C7 O3 P2 123.5(3) . . ?
C10 O4 P2 123.9(3) . . ?
C13 O5 P3 125.4(2) . . ?
C16 O6 P3 124.8(3) . . ?
O1 C1 C3 109.2(4) . . ?
O1 C1 C2 105.9(4) . . ?
C3 C1 C2 112.7(4) . . ?
O1 C1 H1 109.7 . . ?
C3 C1 H1 109.7 . . ?
C2 C1 H1 109.7 . . ?
C1 C2 H2A 109.5 . . ?
C1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
C1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C1 C3 H3A 109.5 . . ?
C1 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C1 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
O2 C4 C5 106.9(4) . . ?
O2 C4 C6 107.1(3) . . ?
C5 C4 C6 113.3(4) . . ?
O2 C4 H4 109.8 . . ?
C5 C4 H4 109.8 . . ?
C6 C4 H4 109.8 . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C4 C6 H6A 109.5 . . ?
C4 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C4 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
O3 C7 C8 109.0(4) . . ?
O3 C7 C9 106.8(4) . . ?
C8 C7 C9 113.8(4) . . ?
O3 C7 H7 109.0 . . ?
C8 C7 H7 109.0 . . ?
C9 C7 H7 109.0 . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
O4 C10 C12 105.1(3) . . ?
O4 C10 C11 111.1(4) . . ?
C12 C10 C11 112.8(4) . . ?
O4 C10 H10 109.3 . . ?
C12 C10 H10 109.3 . . ?
C11 C10 H10 109.3 . . ?
C10 C11 H11A 109.5 . . ?
C10 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C10 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C10 C12 H12A 109.5 . . ?
C10 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C10 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
O5 C13 C14 109.4(4) . . ?
O5 C13 C15 105.0(4) . . ?
C14 C13 C15 112.3(4) . . ?
O5 C13 H13 110.0 . . ?
C14 C13 H13 110.0 . . ?
C15 C13 H13 110.0 . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C13 C15 H15A 109.5 . . ?
C13 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C13 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
O6 C16 C17 110.9(3) . . ?
O6 C16 C18 104.7(4) . . ?
C17 C16 C18 113.5(4) . . ?
O6 C16 H16 109.2 . . ?
C17 C16 H16 109.2 . . ?
C18 C16 H16 109.2 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Cu5 1.0343(10) . ?
Ag1 Ag5 1.0343(10) . ?
Ag1 Ag4 2.0262(9) . ?
Ag1 Ag2 2.3801(11) 2_666 ?
Ag1 Ag3 2.4063(9) 2_666 ?
Ag1 Se6 2.6383(7) 2_666 ?
Ag1 Se2 2.7471(8) 2_666 ?
Ag1 Se3 2.8515(8) . ?
Ag1 Ag6 3.0227(9) 2_666 ?
Ag1 Ag7 3.0584(11) 2_666 ?
Ag1 Ag4 3.1289(10) 2_666 ?
Ag1 Ag3 3.1468(10) . ?
Ag1 H1M 1.9811(8) . ?
Ag2 Cu7 1.0219(10) . ?
Ag2 Ag7 1.0219(10) . ?
Ag2 Ag4 2.0306(9) . ?
Ag2 Ag3 2.4139(9) 2_666 ?
Ag2 Se1 2.6487(9) 2_666 ?
Ag2 Se3 2.7173(8) 2_666 ?
Ag2 Se5 2.8444(7) . ?
Ag2 Ag5 3.0059(11) 2_666 ?
Ag2 Ag6 3.0271(9) 2_666 ?
Ag2 Ag4 3.1396(10) 2_666 ?
Ag2 Ag3 3.1545(10) . ?
Ag2 H1M 1.9918(8) . ?
Ag3 Cu6 0.9549(9) . ?
Ag3 Ag6 0.9549(9) . ?
Ag3 Ag4 2.1296(10) . ?
Ag3 Se4 2.6252(8) 2_666 ?
Ag3 Se5 2.7397(8) 2_666 ?
Ag3 Se2 2.7972(9) . ?
Ag3 Ag7 2.9993(10) 2_666 ?
Ag3 Ag4 3.0584(8) 2_666 ?
Ag3 Ag5 3.0726(10) 2_666 ?
Ag3 H1M 1.9803(7) . ?
Ag4 Se6 2.6745(8) 2_666 ?
Ag4 Se4 2.6895(7) 2_666 ?
Ag4 Se1 2.7246(8) 2_666 ?
Ag4 Ag7 2.8986(10) . ?
Ag4 Cu7 2.8986(10) . ?
Ag4 Ag5 2.9026(10) . ?
Ag4 Cu5 2.9026(10) . ?
Ag4 Cu6 2.9201(10) . ?
Ag4 Ag6 2.9201(10) . ?
Ag4 H1M 1.7387(6) . ?
Ag5 Se3 2.4597(9) . ?
Ag5 Se2 2.5050(8) 2_666 ?
Ag5 Se6 2.5969(7) 2_666 ?
Ag6 Se2 2.4681(9) . ?
Ag6 Se5 2.4832(8) 2_666 ?
Ag6 Se4 2.5642(9) 2_666 ?
Ag6 Ag7 3.3682(10) 2_666 ?
Ag7 Se5 2.4259(7) . ?
Ag7 Se3 2.5158(8) 2_666 ?
Ag7 Se1 2.5556(9) 2_666 ?
Cu5 Se3 2.4597(9) . ?
Cu5 Se2 2.5050(8) 2_666 ?
Cu5 Se6 2.5969(7) 2_666 ?
Cu6 Se2 2.4681(9) . ?
Cu6 Se5 2.4832(8) 2_666 ?
Cu6 Se4 2.5642(9) 2_666 ?
Cu7 Se5 2.4259(7) . ?
Cu7 Se3 2.5158(8) 2_666 ?
Cu7 Se1 2.5556(9) 2_666 ?
Se1 P1 2.1587(10) . ?
Se2 P1 2.1772(12) . ?
Se3 P2 2.1806(10) . ?
Se4 P2 2.1526(12) . ?
Se5 P3 2.1805(13) . ?
Se6 P3 2.1544(12) . ?
P1 O1 1.568(3) . ?
P1 O2 1.586(3) . ?
P2 O4 1.571(3) . ?
P2 O3 1.578(3) . ?
P3 O6 1.572(3) . ?
P3 O5 1.592(3) . ?
O1 C1 1.486(5) . ?
O2 C4 1.475(5) . ?
O3 C7 1.482(5) . ?
O4 C10 1.486(4) . ?
O5 C13 1.480(5) . ?
O6 C16 1.486(5) . ?
C1 C3 1.498(7) . ?
C1 C2 1.498(6) . ?
C1 H1 1.0000 . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 C5 1.495(6) . ?
C4 C6 1.512(6) . ?
C4 H4 1.0000 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 C8 1.496(7) . ?
C7 C9 1.502(6) . ?
C7 H7 1.0000 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 C12 1.509(7) . ?
C10 C11 1.511(6) . ?
C10 H10 1.0000 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 H12A 0.9800 . ?
C12 H12B 0.9800 . ?
C12 H12C 0.9800 . ?
C13 C14 1.506(6) . ?
C13 C15 1.510(6) . ?
C13 H13 1.0000 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C17 1.494(6) . ?
C16 C18 1.504(6) . ?
C16 H16 1.0000 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
