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#$Date: 2021-06-05 21:47:25 +0300 (Sat, 05 Jun 2021) $
#$Revision: 266063 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/68/7706859.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7706859
loop_
_publ_author_name
'Hu, Lei'
'Mahaut, Damien'
'Tumanov, Nikolay'
'Wouters, Johan'
'Collard, Laurent'
'Robiette, Raphaël'
'Berionni, Guillaume'
_publ_section_title
;
 Sterically hindered ortho-substituted phosphatriptycenes as
 configurationally stable P-chirogenic triarylphosphines.
;
_journal_issue                   14
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4772
_journal_page_last               4777
_journal_paper_doi               10.1039/d1dt00816a
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C25 H19 Cl O3 P Rh'
_chemical_formula_sum            'C25 H19 Cl O3 P Rh'
_chemical_formula_weight         536.73
_chemical_name_common
'Rh(acac)CO(o-chloro-9-phosphatriptycene complex)'
_chemical_name_systematic
;
(acetylacetonato)-carbonylrhodium-ortho-chloro-9-phosphatriptycene 
complex
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   dual
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2021-02-08 deposited with the CCDC.	2021-03-15 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 107.1655(13)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.62702(10)
_cell_length_b                   21.4229(2)
_cell_length_c                   12.62171(15)
_cell_measurement_reflns_used    7474
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      66.9250
_cell_measurement_theta_min      4.1000
_cell_volume                     2228.78(5)
_computing_cell_refinement       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_data_collection       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      295(2)
_diffrn_detector_area_resol_mean 5.1856
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type
;
Oxford Diffraction Xcalibur, Ruby, Gemini Ultra
;
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  'multilayer mirror'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0250
_diffrn_reflns_av_unetI/netI     0.0243
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            11623
_diffrn_reflns_point_group_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        67.027
_diffrn_reflns_theta_max         67.027
_diffrn_reflns_theta_min         4.127
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    8.182
_exptl_absorpt_correction_T_max  0.416
_exptl_absorpt_correction_T_min  0.230
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.53 (Rigaku Oxford Diffraction, 2019)
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.600
_exptl_crystal_description       block
_exptl_crystal_F_000             1080
_exptl_crystal_size_max          0.360
_exptl_crystal_size_mid          0.230
_exptl_crystal_size_min          0.160
_refine_diff_density_max         0.521
_refine_diff_density_min         -0.595
_refine_diff_density_rms         0.053
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.090
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     292
_refine_ls_number_reflns         3948
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.090
_refine_ls_R_factor_all          0.0313
_refine_ls_R_factor_gt           0.0293
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0315P)²+1.3985P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0723
_refine_ls_wR_factor_ref         0.0736
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3716
_reflns_number_total             3948
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1dt00816a2.cif
_cod_data_source_block           nt0815_LHG203D
_cod_depositor_comments
'Adding full bibliography for 7706848--7706861.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7706859
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.157
_shelx_estimated_absorpt_t_max   0.354
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.37704(3) 0.70574(2) 0.65113(2) 0.04533(9) Uani 1 1 d . . . . .
Cl1 Cl 0.74794(13) 0.72642(5) 0.61671(9) 0.0734(4) Uani 0.912(3) 1 d . . P A 1
Cl2 Cl 0.3720(12) 0.6878(6) 0.9033(9) 0.070(4) Uani 0.088(3) 1 d . . P A 2
P1 P 0.52054(7) 0.62009(3) 0.71410(5) 0.03571(15) Uani 1 1 d . . . . .
O1 O 0.5825(7) 0.77240(16) 0.8440(3) 0.153(2) Uani 1 1 d . . . . .
O2 O 0.2375(3) 0.78550(10) 0.6059(2) 0.0629(6) Uani 1 1 d . . . . .
O3 O 0.2443(3) 0.66532(10) 0.50680(18) 0.0576(5) Uani 1 1 d . . . . .
C1 C 0.4564(3) 0.54213(12) 0.6590(2) 0.0379(5) Uani 1 1 d . . . . .
C2 C 0.3171(3) 0.52885(14) 0.5735(2) 0.0465(6) Uani 1 1 d . . . . .
H2 H 0.248861 0.560923 0.537777 0.056 Uiso 1 1 calc R U . . .
C3 C 0.2804(4) 0.46725(16) 0.5418(3) 0.0593(8) Uani 1 1 d . . . . .
H3 H 0.186314 0.458081 0.485222 0.071 Uiso 1 1 calc R U . . .
C4 C 0.3810(5) 0.41999(15) 0.5928(3) 0.0608(8) Uani 1 1 d . . . . .
H4 H 0.355926 0.378995 0.569902 0.073 Uiso 1 1 calc R U . . .
C5 C 0.5209(4) 0.43269(14) 0.6789(3) 0.0521(7) Uani 1 1 d . . . . .
H5 H 0.588422 0.400301 0.713988 0.063 Uiso 1 1 calc R U . . .
C6 C 0.5588(3) 0.49377(13) 0.7119(2) 0.0398(6) Uani 1 1 d . . . . .
C7 C 0.7073(3) 0.51202(13) 0.8053(2) 0.0427(6) Uani 1 1 d . . . . .
H7 H 0.771074 0.474968 0.836528 0.051 Uiso 1 1 calc R U . . .
C8 C 0.6543(3) 0.54643(13) 0.8944(2) 0.0396(6) Uani 1 1 d . . . . .
C9 C 0.6981(4) 0.52795(15) 1.0045(2) 0.0492(7) Uani 1 1 d . . . . .
H9 H 0.762266 0.492701 1.027090 0.059 Uiso 1 1 calc R U . . .
C10 C 0.6461(4) 0.56206(17) 1.0810(3) 0.0572(8) Uani 1 1 d . . . . .
H10 H 0.678312 0.550306 1.155232 0.069 Uiso 1 1 calc R U . . .
C11 C 0.5478(4) 0.61286(17) 1.0479(3) 0.0576(8) Uani 1 1 d . . . . .
H11 H 0.510689 0.634691 1.099333 0.069 Uiso 1 1 calc R U . . .
C12 C 0.5030(4) 0.63210(14) 0.9375(3) 0.0483(7) Uani 1 1 d . . . . .
H12 H 0.435970 0.666620 0.915154 0.058 Uiso 0.912(3) 1 calc R U P A 1
C13 C 0.5589(3) 0.59956(12) 0.8613(2) 0.0372(5) Uani 1 1 d . . . . .
C14 C 0.7339(3) 0.61304(14) 0.7145(2) 0.0412(6) Uani 1 1 d . . . . .
C15 C 0.8253(4) 0.65598(16) 0.6763(2) 0.0517(7) Uani 1 1 d . . . . .
H15 H 0.778087 0.693209 0.644702 0.062 Uiso 0.088(3) 1 calc R U P A 2
C16 C 0.9866(4) 0.6438(2) 0.6847(3) 0.0700(11) Uani 1 1 d . . . . .
H16 H 1.047745 0.673318 0.660647 0.084 Uiso 1 1 calc R U . . .
C17 C 1.0558(4) 0.5885(2) 0.7284(3) 0.0730(11) Uani 1 1 d . . . . .
H17 H 1.163573 0.580563 0.733164 0.088 Uiso 1 1 calc R U . . .
C18 C 0.9678(4) 0.54450(19) 0.7655(3) 0.0604(9) Uani 1 1 d . . . . .
H18 H 1.015146 0.506708 0.794005 0.072 Uiso 1 1 calc R U . . .
C19 C 0.8080(3) 0.55698(14) 0.7601(2) 0.0436(6) Uani 1 1 d . . . . .
C20 C 0.5012(6) 0.74557(16) 0.7724(4) 0.0836(13) Uani 1 1 d . . . . .
C21 C 0.0282(6) 0.8526(2) 0.5139(4) 0.0866(13) Uani 1 1 d . . . . .
H21A H -0.053145 0.855736 0.443301 0.130 Uiso 1 1 calc R U . . .
H21B H 0.104363 0.886241 0.521607 0.130 Uiso 1 1 calc R U . . .
H21C H -0.022288 0.855028 0.572078 0.130 Uiso 1 1 calc R U . . .
C22 C 0.1154(4) 0.79146(16) 0.5211(3) 0.0602(9) Uani 1 1 d . . . . .
C23 C 0.0597(5) 0.74806(18) 0.4392(3) 0.0665(9) Uani 1 1 d . . . . .
H23 H -0.030855 0.759113 0.381215 0.080 Uiso 1 1 calc R U . . .
C24 C 0.1243(4) 0.68912(18) 0.4338(3) 0.0616(8) Uani 1 1 d . . . . .
C25 C 0.0497(7) 0.6481(3) 0.3351(4) 0.1082(19) Uani 1 1 d . . . . .
H25A H -0.025493 0.672110 0.278493 0.162 Uiso 1 1 calc R U . . .
H25B H -0.006378 0.614076 0.356970 0.162 Uiso 1 1 calc R U . . .
H25C H 0.133501 0.632017 0.306736 0.162 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C20 Rh1 O3 175.48(17) . . ?
C20 Rh1 O2 89.69(14) . . ?
O3 Rh1 O2 88.67(9) . . ?
C20 Rh1 P1 87.62(12) . . ?
O3 Rh1 P1 94.34(6) . . ?
O2 Rh1 P1 174.71(7) . . ?
C1 P1 C13 96.30(12) . . ?
C1 P1 C14 96.66(12) . . ?
C13 P1 C14 95.47(12) . . ?
C1 P1 Rh1 122.86(9) . . ?
C13 P1 Rh1 118.21(9) . . ?
C14 P1 Rh1 121.19(10) . . ?
C22 O2 Rh1 125.9(2) . . ?
C24 O3 Rh1 126.9(2) . . ?
C2 C1 C6 120.0(3) . . ?
C2 C1 P1 125.3(2) . . ?
C6 C1 P1 114.64(19) . . ?
C1 C2 C3 119.4(3) . . ?
C1 C2 H2 120.3 . . ?
C3 C2 H2 120.3 . . ?
C4 C3 C2 120.7(3) . . ?
C4 C3 H3 119.7 . . ?
C2 C3 H3 119.7 . . ?
C3 C4 C5 120.5(3) . . ?
C3 C4 H4 119.7 . . ?
C5 C4 H4 119.7 . . ?
C6 C5 C4 119.6(3) . . ?
C6 C5 H5 120.2 . . ?
C4 C5 H5 120.2 . . ?
C5 C6 C1 119.8(3) . . ?
C5 C6 C7 123.3(3) . . ?
C1 C6 C7 116.8(2) . . ?
C6 C7 C19 108.6(2) . . ?
C6 C7 C8 109.3(2) . . ?
C19 C7 C8 107.5(2) . . ?
C6 C7 H7 110.5 . . ?
C19 C7 H7 110.5 . . ?
C8 C7 H7 110.5 . . ?
C9 C8 C13 119.7(3) . . ?
C9 C8 C7 123.3(3) . . ?
C13 C8 C7 116.9(2) . . ?
C8 C9 C10 119.9(3) . . ?
C8 C9 H9 120.0 . . ?
C10 C9 H9 120.0 . . ?
C11 C10 C9 120.4(3) . . ?
C11 C10 H10 119.8 . . ?
C9 C10 H10 119.8 . . ?
C10 C11 C12 120.3(3) . . ?
C10 C11 H11 119.9 . . ?
C12 C11 H11 119.9 . . ?
C13 C12 C11 119.7(3) . . ?
C13 C12 Cl2 123.2(4) . . ?
C11 C12 Cl2 116.9(4) . . ?
C13 C12 H12 120.2 . . ?
C11 C12 H12 120.2 . . ?
C12 C13 C8 119.9(3) . . ?
C12 C13 P1 125.8(2) . . ?
C8 C13 P1 114.32(19) . . ?
C15 C14 C19 118.3(3) . . ?
C15 C14 P1 127.8(2) . . ?
C19 C14 P1 113.9(2) . . ?
C14 C15 C16 120.5(3) . . ?
C14 C15 Cl1 122.9(2) . . ?
C16 C15 Cl1 116.5(3) . . ?
C14 C15 H15 119.7 . . ?
C16 C15 H15 119.7 . . ?
C17 C16 C15 120.1(3) . . ?
C17 C16 H16 119.9 . . ?
C15 C16 H16 119.9 . . ?
C16 C17 C18 120.8(3) . . ?
C16 C17 H17 119.6 . . ?
C18 C17 H17 119.6 . . ?
C17 C18 C19 119.4(4) . . ?
C17 C18 H18 120.3 . . ?
C19 C18 H18 120.3 . . ?
C18 C19 C14 120.8(3) . . ?
C18 C19 C7 122.0(3) . . ?
C14 C19 C7 117.1(2) . . ?
O1 C20 Rh1 175.8(5) . . ?
C22 C21 H21A 109.5 . . ?
C22 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C22 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
O2 C22 C23 126.1(3) . . ?
O2 C22 C21 114.6(3) . . ?
C23 C22 C21 119.3(3) . . ?
C22 C23 C24 126.7(3) . . ?
C22 C23 H23 116.6 . . ?
C24 C23 H23 116.6 . . ?
O3 C24 C23 125.5(3) . . ?
O3 C24 C25 115.1(3) . . ?
C23 C24 C25 119.4(3) . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C24 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C20 1.803(4) . ?
Rh1 O3 2.037(2) . ?
Rh1 O2 2.071(2) . ?
Rh1 P1 2.2248(7) . ?
Cl1 C15 1.730(4) . ?
Cl2 C12 1.612(11) . ?
P1 C1 1.831(3) . ?
P1 C13 1.842(3) . ?
P1 C14 1.845(3) . ?
O1 C20 1.124(5) . ?
O2 C22 1.268(4) . ?
O3 C24 1.272(4) . ?
C1 C2 1.387(4) . ?
C1 C6 1.397(4) . ?
C2 C3 1.388(4) . ?
C2 H2 0.9300 . ?
C3 C4 1.365(5) . ?
C3 H3 0.9300 . ?
C4 C5 1.391(5) . ?
C4 H4 0.9300 . ?
C5 C6 1.383(4) . ?
C5 H5 0.9300 . ?
C6 C7 1.514(4) . ?
C7 C19 1.517(4) . ?
C7 C8 1.524(4) . ?
C7 H7 0.9800 . ?
C8 C9 1.386(4) . ?
C8 C13 1.394(4) . ?
C9 C10 1.386(5) . ?
C9 H9 0.9300 . ?
C10 C11 1.367(5) . ?
C10 H10 0.9300 . ?
C11 C12 1.394(5) . ?
C11 H11 0.9300 . ?
C12 C13 1.385(4) . ?
C12 H12 0.9300 . ?
C14 C15 1.388(4) . ?
C14 C19 1.402(4) . ?
C15 C16 1.389(5) . ?
C15 H15 0.9300 . ?
C16 C17 1.367(6) . ?
C16 H16 0.9300 . ?
C17 C18 1.377(6) . ?
C17 H17 0.9300 . ?
C18 C19 1.386(4) . ?
C18 H18 0.9300 . ?
C21 C22 1.500(5) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 C23 1.367(5) . ?
C23 C24 1.390(5) . ?
C23 H23 0.9300 . ?
C24 C25 1.505(6) . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C13 P1 C1 C2 130.7(2) . . . . ?
C14 P1 C1 C2 -133.0(2) . . . . ?
Rh1 P1 C1 C2 1.1(3) . . . . ?
C13 P1 C1 C6 -47.9(2) . . . . ?
C14 P1 C1 C6 48.4(2) . . . . ?
Rh1 P1 C1 C6 -177.53(16) . . . . ?
C6 C1 C2 C3 0.3(4) . . . . ?
P1 C1 C2 C3 -178.2(2) . . . . ?
C1 C2 C3 C4 -0.9(5) . . . . ?
C2 C3 C4 C5 1.1(5) . . . . ?
C3 C4 C5 C6 -0.7(5) . . . . ?
C4 C5 C6 C1 0.2(4) . . . . ?
C4 C5 C6 C7 179.4(3) . . . . ?
C2 C1 C6 C5 0.0(4) . . . . ?
P1 C1 C6 C5 178.7(2) . . . . ?
C2 C1 C6 C7 -179.3(2) . . . . ?
P1 C1 C6 C7 -0.6(3) . . . . ?
C5 C6 C7 C19 122.3(3) . . . . ?
C1 C6 C7 C19 -58.4(3) . . . . ?
C5 C6 C7 C8 -120.7(3) . . . . ?
C1 C6 C7 C8 58.5(3) . . . . ?
C6 C7 C8 C9 124.2(3) . . . . ?
C19 C7 C8 C9 -118.2(3) . . . . ?
C6 C7 C8 C13 -56.8(3) . . . . ?
C19 C7 C8 C13 60.8(3) . . . . ?
C13 C8 C9 C10 0.4(4) . . . . ?
C7 C8 C9 C10 179.4(3) . . . . ?
C8 C9 C10 C11 1.9(5) . . . . ?
C9 C10 C11 C12 -2.1(5) . . . . ?
C10 C11 C12 C13 -0.1(5) . . . . ?
C10 C11 C12 Cl2 173.7(5) . . . . ?
C11 C12 C13 C8 2.5(4) . . . . ?
Cl2 C12 C13 C8 -170.9(5) . . . . ?
C11 C12 C13 P1 -177.0(2) . . . . ?
Cl2 C12 C13 P1 9.6(6) . . . . ?
C9 C8 C13 C12 -2.6(4) . . . . ?
C7 C8 C13 C12 178.3(2) . . . . ?
C9 C8 C13 P1 176.9(2) . . . . ?
C7 C8 C13 P1 -2.1(3) . . . . ?
C1 P1 C13 C12 -131.2(2) . . . . ?
C14 P1 C13 C12 131.5(3) . . . . ?
Rh1 P1 C13 C12 1.5(3) . . . . ?
C1 P1 C13 C8 49.3(2) . . . . ?
C14 P1 C13 C8 -48.0(2) . . . . ?
Rh1 P1 C13 C8 -177.95(16) . . . . ?
C1 P1 C14 C15 133.5(3) . . . . ?
C13 P1 C14 C15 -129.4(3) . . . . ?
Rh1 P1 C14 C15 -1.6(3) . . . . ?
C1 P1 C14 C19 -46.7(2) . . . . ?
C13 P1 C14 C19 50.3(2) . . . . ?
Rh1 P1 C14 C19 178.12(16) . . . . ?
C19 C14 C15 C16 -1.0(4) . . . . ?
P1 C14 C15 C16 178.7(2) . . . . ?
C19 C14 C15 Cl1 179.1(2) . . . . ?
P1 C14 C15 Cl1 -1.1(4) . . . . ?
C14 C15 C16 C17 1.7(5) . . . . ?
Cl1 C15 C16 C17 -178.5(3) . . . . ?
C15 C16 C17 C18 -0.6(5) . . . . ?
C16 C17 C18 C19 -1.1(5) . . . . ?
C17 C18 C19 C14 1.8(5) . . . . ?
C17 C18 C19 C7 -176.6(3) . . . . ?
C15 C14 C19 C18 -0.7(4) . . . . ?
P1 C14 C19 C18 179.5(2) . . . . ?
C15 C14 C19 C7 177.7(2) . . . . ?
P1 C14 C19 C7 -2.1(3) . . . . ?
C6 C7 C19 C18 -121.6(3) . . . . ?
C8 C7 C19 C18 120.3(3) . . . . ?
C6 C7 C19 C14 60.0(3) . . . . ?
C8 C7 C19 C14 -58.1(3) . . . . ?
Rh1 O2 C22 C23 -5.0(6) . . . . ?
Rh1 O2 C22 C21 174.9(3) . . . . ?
O2 C22 C23 C24 0.8(7) . . . . ?
C21 C22 C23 C24 -179.1(4) . . . . ?
Rh1 O3 C24 C23 -0.3(6) . . . . ?
Rh1 O3 C24 C25 179.9(3) . . . . ?
C22 C23 C24 O3 2.2(7) . . . . ?
C22 C23 C24 C25 -178.1(5) . . . . ?
