#------------------------------------------------------------------------------
#$Date: 2021-09-06 14:10:33 +0300 (Mon, 06 Sep 2021) $
#$Revision: 268759 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/76/7707615.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7707615
loop_
_publ_author_name
'Garg, Palak'
'Dange, Deepak'
'Jones, Cameron'
_publ_section_title
;
 Bulky arene-bridged bis(amide) and bis(amidinate) complexes of
 germanium(II) and tin(II).
;
_journal_issue                   26
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9118
_journal_page_last               9122
_journal_paper_doi               10.1039/d1dt01642c
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C48 H92 N4 Si4 Sn2'
_chemical_formula_weight         1074.99
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2021-06-08 deposited with the CCDC.	2021-06-08 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 97.133(3)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   14.8476(6)
_cell_length_b                   9.5319(3)
_cell_length_c                   19.2672(6)
_cell_measurement_reflns_used    11390
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      29.2670
_cell_measurement_theta_min      3.4160
_cell_volume                     2705.70(16)
_computing_cell_refinement       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.39.46 (Rigaku OD, 2018)'
_computing_molecular_graphics    xseed
_computing_publication_material  Ciftab
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0497
_diffrn_reflns_av_unetI/netI     0.0351
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            25186
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.500
_diffrn_reflns_theta_min         3.429
_diffrn_source                   'micro-focus sealed X-ray tube'
_exptl_absorpt_coefficient_mu    1.046
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.80166
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.81a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.319
_exptl_crystal_description       block
_exptl_crystal_F_000             1128
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.180
_exptl_crystal_size_min          0.130
_refine_diff_density_max         3.904
_refine_diff_density_min         -1.824
_refine_diff_density_rms         0.154
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     274
_refine_ls_number_reflns         5018
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.041
_refine_ls_R_factor_all          0.0904
_refine_ls_R_factor_gt           0.0781
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1112P)²+20.5523P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2033
_refine_ls_wR_factor_ref         0.2152
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4180
_reflns_number_total             5018
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1dt01642c2.cif
_cod_data_source_block           Cj1495
_cod_depositor_comments
'Adding full bibliography for 7707610--7707619.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7707615
_shelx_shelxl_version_number     2016/6
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.803
_shelx_estimated_absorpt_t_max   0.876
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn 0.66795(4) 0.26939(6) 0.60801(3) 0.0455(2) Uani 1 1 d . . . . .
Si1 Si 0.76278(12) 0.33437(19) 0.46409(9) 0.0320(4) Uani 1 1 d . . . . .
N1 N 0.6657(4) 0.3396(7) 0.5056(3) 0.0423(14) Uani 1 1 d . . . . .
C1 C 0.7751(5) 0.4955(8) 0.4084(4) 0.0398(16) Uani 1 1 d . . . . .
H1 H 0.717496 0.501099 0.375592 0.048 Uiso 1 1 calc R U . . .
Si2 Si 0.45164(12) 0.61237(19) 0.27269(9) 0.0312(4) Uani 1 1 d . . . . .
N2 N 0.4248(4) 0.5904(6) 0.3574(3) 0.0383(13) Uani 1 1 d . . . . .
C2 C 0.8501(6) 0.4865(11) 0.3623(5) 0.062(2) Uani 1 1 d . . . . .
H2A H 0.843948 0.563825 0.328453 0.093 Uiso 1 1 calc R U . . .
H2B H 0.846007 0.396854 0.337195 0.093 Uiso 1 1 calc R U . . .
H2C H 0.909117 0.493152 0.391198 0.093 Uiso 1 1 calc R U . . .
C3 C 0.7793(6) 0.6335(8) 0.4513(5) 0.054(2) Uani 1 1 d . . . . .
H3A H 0.836423 0.637030 0.482776 0.080 Uiso 1 1 calc R U . . .
H3B H 0.728125 0.636812 0.478845 0.080 Uiso 1 1 calc R U . . .
H3C H 0.776029 0.713895 0.419375 0.080 Uiso 1 1 calc R U . . .
C4 C 0.8624(6) 0.3041(9) 0.5348(4) 0.0490(19) Uani 1 1 d . . . . .
H4 H 0.843345 0.226644 0.564789 0.059 Uiso 1 1 calc R U . . .
C5 C 0.9480(6) 0.2533(12) 0.5073(6) 0.071(3) Uani 1 1 d . . . . .
H5A H 0.968563 0.324269 0.475958 0.107 Uiso 1 1 calc R U . . .
H5B H 0.935363 0.165394 0.481539 0.107 Uiso 1 1 calc R U . . .
H5C H 0.995495 0.237440 0.546576 0.107 Uiso 1 1 calc R U . . .
C6 C 0.8816(8) 0.4325(11) 0.5837(5) 0.068(3) Uani 1 1 d . . . . .
H6A H 0.923741 0.405412 0.624717 0.102 Uiso 1 1 calc R U . . .
H6B H 0.824630 0.465535 0.598775 0.102 Uiso 1 1 calc R U . . .
H6C H 0.908625 0.507843 0.558483 0.102 Uiso 1 1 calc R U . . .
C7 C 0.7585(6) 0.1776(9) 0.4041(5) 0.054(2) Uani 1 1 d . . . . .
H7 H 0.819158 0.172174 0.386770 0.065 Uiso 1 1 calc R U . . .
C8 C 0.7468(9) 0.0400(9) 0.4435(7) 0.082(3) Uani 1 1 d . . . . .
H8A H 0.687871 0.040078 0.461350 0.122 Uiso 1 1 calc R U . . .
H8B H 0.795400 0.031494 0.482611 0.122 Uiso 1 1 calc R U . . .
H8C H 0.749807 -0.039451 0.411527 0.122 Uiso 1 1 calc R U . . .
C9 C 0.6871(6) 0.1920(10) 0.3381(5) 0.058(2) Uani 1 1 d . . . . .
H9A H 0.693206 0.113056 0.306507 0.087 Uiso 1 1 calc R U . . .
H9B H 0.697148 0.280203 0.314101 0.087 Uiso 1 1 calc R U . . .
H9C H 0.625927 0.191951 0.352308 0.087 Uiso 1 1 calc R U . . .
C10 C 0.5740(5) 0.3440(8) 0.4699(4) 0.0404(16) Uani 1 1 d . . . . .
C11 C 0.5128(6) 0.2344(8) 0.4765(4) 0.0451(18) Uani 1 1 d . . . . .
H11 H 0.535005 0.150626 0.499232 0.054 Uiso 1 1 calc R U . . .
C12 C 0.4262(5) 0.2425(6) 0.4527(5) 0.0442(19) Uani 1 1 d . . . . .
H12 H 0.384948 0.172773 0.464523 0.053 Uiso 1 1 calc R U . . .
C13 C 0.3939(5) 0.3609(8) 0.4075(4) 0.0430(17) Uani 1 1 d . . . . .
H13 H 0.333198 0.363609 0.385205 0.052 Uiso 1 1 calc R U . . .
C14 C 0.4546(5) 0.4700(7) 0.3980(4) 0.0382(15) Uani 1 1 d . . . . .
C15 C 0.5449(5) 0.4644(8) 0.4309(3) 0.0374(15) Uani 1 1 d . . . . .
H15 H 0.585397 0.540304 0.426860 0.045 Uiso 1 1 calc R U . . .
C16 C 0.5128(5) 0.4494(8) 0.2485(4) 0.0409(16) Uani 1 1 d . . . . .
H16 H 0.556876 0.424676 0.290322 0.049 Uiso 1 1 calc R U . . .
C17 C 0.4508(8) 0.3210(10) 0.2334(5) 0.068(3) Uani 1 1 d . . . . .
H17A H 0.411248 0.335434 0.189369 0.101 Uiso 1 1 calc R U . . .
H17B H 0.413586 0.308755 0.271577 0.101 Uiso 1 1 calc R U . . .
H17C H 0.488023 0.237114 0.229679 0.101 Uiso 1 1 calc R U . . .
C18 C 0.5682(7) 0.4649(10) 0.1877(4) 0.062(2) Uani 1 1 d . . . . .
H18A H 0.602519 0.378530 0.182614 0.094 Uiso 1 1 calc R U . . .
H18B H 0.610308 0.543809 0.196685 0.094 Uiso 1 1 calc R U . . .
H18C H 0.527298 0.482419 0.144610 0.094 Uiso 1 1 calc R U . . .
C19 C 0.5276(5) 0.7679(8) 0.2642(4) 0.0410(16) Uani 1 1 d . . . . .
H19 H 0.541223 0.767852 0.214623 0.049 Uiso 1 1 calc R U . . .
C20 C 0.6190(6) 0.7549(9) 0.3096(6) 0.061(3) Uani 1 1 d . . . . .
H20A H 0.658113 0.833424 0.299884 0.091 Uiso 1 1 calc R U . . .
H20B H 0.647979 0.666265 0.299150 0.091 Uiso 1 1 calc R U . . .
H20C H 0.609641 0.756497 0.359096 0.091 Uiso 1 1 calc R U . . .
C21 C 0.4856(7) 0.9109(8) 0.2760(5) 0.059(2) Uani 1 1 d . . . . .
H21A H 0.469773 0.915816 0.323839 0.088 Uiso 1 1 calc R U . . .
H21B H 0.430822 0.923621 0.242672 0.088 Uiso 1 1 calc R U . . .
H21C H 0.529433 0.985012 0.269166 0.088 Uiso 1 1 calc R U . . .
C22 C 0.3416(5) 0.6529(8) 0.2129(4) 0.0434(17) Uani 1 1 d . . . . .
H22 H 0.323084 0.749607 0.225336 0.052 Uiso 1 1 calc R U . . .
C23 C 0.2619(6) 0.5581(10) 0.2219(5) 0.063(2) Uani 1 1 d . . . . .
H23A H 0.207881 0.591447 0.192016 0.094 Uiso 1 1 calc R U . . .
H23B H 0.250415 0.559655 0.270878 0.094 Uiso 1 1 calc R U . . .
H23C H 0.275845 0.462066 0.208581 0.094 Uiso 1 1 calc R U . . .
C24 C 0.3567(6) 0.6582(11) 0.1369(4) 0.059(2) Uani 1 1 d . . . . .
H24A H 0.374931 0.565297 0.122001 0.088 Uiso 1 1 calc R U . . .
H24B H 0.404528 0.726365 0.130941 0.088 Uiso 1 1 calc R U . . .
H24C H 0.300281 0.686566 0.108427 0.088 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Sn1 N2 99.4(2) . 3_666 ?
N1 Si1 C7 109.8(4) . . ?
N1 Si1 C1 112.5(3) . . ?
C7 Si1 C1 107.1(4) . . ?
N1 Si1 C4 106.9(3) . . ?
C7 Si1 C4 106.4(4) . . ?
C1 Si1 C4 114.0(4) . . ?
C10 N1 Si1 124.7(5) . . ?
C10 N1 Sn1 111.3(4) . . ?
Si1 N1 Sn1 120.8(3) . . ?
C2 C1 C3 112.2(7) . . ?
C2 C1 Si1 114.7(6) . . ?
C3 C1 Si1 112.7(5) . . ?
C2 C1 H1 105.4 . . ?
C3 C1 H1 105.4 . . ?
Si1 C1 H1 105.4 . . ?
N2 Si2 C19 112.7(3) . . ?
N2 Si2 C16 107.8(3) . . ?
C19 Si2 C16 108.3(4) . . ?
N2 Si2 C22 108.1(3) . . ?
C19 Si2 C22 105.3(3) . . ?
C16 Si2 C22 114.7(3) . . ?
C14 N2 Si2 121.3(5) . . ?
C14 N2 Sn1 120.8(4) . 3_666 ?
Si2 N2 Sn1 117.3(3) . 3_666 ?
C1 C2 H2A 109.5 . . ?
C1 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
C1 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C1 C3 H3A 109.5 . . ?
C1 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C1 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C5 C4 C6 111.4(8) . . ?
C5 C4 Si1 114.1(6) . . ?
C6 C4 Si1 112.6(6) . . ?
C5 C4 H4 106.0 . . ?
C6 C4 H4 106.0 . . ?
Si1 C4 H4 106.0 . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C4 C6 H6A 109.5 . . ?
C4 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C4 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C8 C7 C9 111.8(8) . . ?
C8 C7 Si1 111.8(7) . . ?
C9 C7 Si1 113.4(6) . . ?
C8 C7 H7 106.4 . . ?
C9 C7 H7 106.4 . . ?
Si1 C7 H7 106.4 . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C11 C10 C15 119.8(7) . . ?
C11 C10 N1 121.1(7) . . ?
C15 C10 N1 119.0(7) . . ?
C12 C11 C10 122.9(7) . . ?
C12 C11 H11 118.6 . . ?
C10 C11 H11 118.6 . . ?
C11 C12 C13 119.0(6) . . ?
C11 C12 H12 120.5 . . ?
C13 C12 H12 120.5 . . ?
C14 C13 C12 118.7(7) . . ?
C14 C13 H13 120.7 . . ?
C12 C13 H13 120.7 . . ?
C13 C14 C15 120.2(7) . . ?
C13 C14 N2 120.5(6) . . ?
C15 C14 N2 119.3(6) . . ?
C10 C15 C14 118.7(7) . . ?
C10 C15 H15 120.6 . . ?
C14 C15 H15 120.6 . . ?
C18 C16 C17 107.5(7) . . ?
C18 C16 Si2 115.6(5) . . ?
C17 C16 Si2 114.0(6) . . ?
C18 C16 H16 106.4 . . ?
C17 C16 H16 106.4 . . ?
Si2 C16 H16 106.4 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C16 C18 H18A 109.5 . . ?
C16 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C16 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C20 C19 C21 109.7(7) . . ?
C20 C19 Si2 112.7(5) . . ?
C21 C19 Si2 115.4(6) . . ?
C20 C19 H19 106.1 . . ?
C21 C19 H19 106.1 . . ?
Si2 C19 H19 106.1 . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C19 C21 H21A 109.5 . . ?
C19 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C19 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C24 C22 C23 110.1(7) . . ?
C24 C22 Si2 111.8(6) . . ?
C23 C22 Si2 115.5(6) . . ?
C24 C22 H22 106.3 . . ?
C23 C22 H22 106.3 . . ?
Si2 C22 H22 106.3 . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C22 C24 H24A 109.5 . . ?
C22 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C22 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sn1 N1 2.080(6) . ?
Sn1 N2 2.087(6) 3_666 ?
Si1 N1 1.733(6) . ?
Si1 C7 1.885(8) . ?
Si1 C1 1.895(8) . ?
Si1 C4 1.904(8) . ?
N1 C10 1.449(10) . ?
C1 C2 1.512(11) . ?
C1 C3 1.551(11) . ?
C1 H1 1.0000 . ?
Si2 N2 1.740(6) . ?
Si2 C19 1.882(7) . ?
Si2 C16 1.887(7) . ?
Si2 C22 1.918(7) . ?
N2 C14 1.428(9) . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 C5 1.517(13) . ?
C4 C6 1.550(12) . ?
C4 H4 1.0000 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 C8 1.536(14) . ?
C7 C9 1.557(12) . ?
C7 H7 1.0000 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 C11 1.400(11) . ?
C10 C15 1.409(10) . ?
C11 C12 1.314(12) . ?
C11 H11 0.9500 . ?
C12 C13 1.469(11) . ?
C12 H12 0.9500 . ?
C13 C14 1.403(10) . ?
C13 H13 0.9500 . ?
C14 C15 1.411(10) . ?
C15 H15 0.9500 . ?
C16 C18 1.520(11) . ?
C16 C17 1.537(12) . ?
C16 H16 1.0000 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C20 1.526(11) . ?
C19 C21 1.528(11) . ?
C19 H19 1.0000 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 C24 1.509(12) . ?
C22 C23 1.515(11) . ?
C22 H22 1.0000 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
