#------------------------------------------------------------------------------
#$Date: 2021-09-06 14:22:03 +0300 (Mon, 06 Sep 2021) $
#$Revision: 268792 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/78/7707840.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7707840
loop_
_publ_author_name
'Preißing, Lars'
'Behling, Elias'
'Schnepf, Andreas'
_publ_section_title
;
 GeClₓ[Co(CO)₃PR₃]₄₋ₓ (x =
 0-3; R = ⁿPr, ⁿBu): from cobalt substituted
 germanes to novel binary cluster compounds.
;
_journal_issue                   31
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10789
_journal_page_last               10797
_journal_paper_doi               10.1039/d1dt02016a
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C36 H63 Cl Co3 Ge O9 P3, C4 H10 O'
_chemical_formula_sum            'C40 H73 Cl Co3 Ge O10 P3'
_chemical_formula_weight         1091.72
_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_Hall           'P 2yb'
_space_group_name_H-M_alt        'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2020-08-18
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2021-05-12 deposited with the CCDC.	2021-07-15 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 106.851(2)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   13.6499(2)
_cell_length_b                   14.5313(2)
_cell_length_c                   13.9137(2)
_cell_measurement_reflns_used    46230
_cell_measurement_temperature    100.00(14)
_cell_measurement_theta_max      45.4210
_cell_measurement_theta_min      2.2930
_cell_volume                     2641.29(7)
_computing_cell_refinement       'CrysAlisPro 1.171.41.79a (Rigaku OD, 2020)'
_computing_data_collection       'CrysAlisPro 1.171.41.79a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.41.79a (Rigaku OD, 2020)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(14)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -60.00 -35.00   0.50   31.08    --  -45.08 126.00 172.00   50
  2  ω     16.00  42.00   0.50   31.08    --   46.33-126.00  95.00   52
  3  ω    -24.00   2.00   0.50   31.08    --  -45.08  57.00 -90.00   52
  4  ω    -94.00 -39.00   0.50   31.08    --  -45.08 131.00  96.82  110
  5  ω    -46.00 -10.00   0.50   31.08    --  -45.08  77.00 -30.00   72
  6  ω    -46.00  18.00   0.50   31.08    --  -45.08  19.00 -60.00  128
  7  ω    -88.00 -38.00   0.50   31.08    --  -45.08 118.00  22.73  100
  8  ω    -25.00  34.00   0.50   31.08    --  -45.08  19.00  30.00  118
  9  ω    -98.00 -62.00   0.50   31.08    --  -45.08 137.00 106.81   72
 10  ω   -106.00 -37.00   0.50   31.08    --  -45.08 -37.00 -30.00  138
 11  ω   -104.00 -39.00   0.50   31.08    --  -45.08 -37.00 120.00  130
 12  ω    -94.00 -69.00   0.50   31.08    --  -45.08 131.00  45.15   50
 13  ω    -51.00 -25.00   0.50   31.08    --  -45.08  37.00 -30.00   52
 14  ω      5.00  30.00   0.50   31.08    --  -45.08  37.00 -30.00   50
 15  ω      0.00  34.00   0.50   31.08    --  -45.08  19.00-120.00   68
 16  ω    -57.00 -31.00   0.50   31.08    --  -45.08  57.00 -90.00   52
 17  ω    -31.00   5.00   0.50   31.08    --   46.33 -19.00 -90.00   72
 18  ω    -31.00   5.00   0.50   31.08    --   46.33 -19.00 -30.00   72
 19  ω    -10.00  31.00   0.50   31.08    --    0.62  57.00 120.00   82
 20  ω   -118.00 -85.00   0.50   31.08    --  -45.08 -52.00 -77.09   66
 21  ω    -56.00 -31.00   0.50   31.08    --  -45.08 -60.00-145.68   50
 22  ω    -56.00 -31.00   0.50   31.08    --  -45.08 -60.00  49.95   50
 23  ω   -100.00 -65.00   0.50   31.08    --  -45.08 -51.00 -34.27   70
 24  ω    -61.00 -35.00   0.50   31.08    --  -45.08 -51.00 -34.27   52
 25  ω    -74.00 -34.00   0.50   31.08    --  -45.08 -52.00 -77.09   80
 26  ω    -58.00 -32.00   0.50   31.08    --  -45.08 -58.00-119.60   52
 27  ω    -59.00 -33.00   0.50   31.08    --  -45.08 -55.00-111.25   52
 28  ω    -59.00 -33.00   0.50   31.08    --  -45.08 -55.00  -5.89   52
 29  ω   -116.00 -78.00   0.50   31.08    --  -45.08 -52.00 108.34   76
 30  ω    -65.00 -34.00   0.50   31.08    --  -45.08 -52.00 108.34   62
 31  ω    -57.00 -32.00   0.50   31.08    --  -45.08 -58.00  70.75   50
 32  ω    -60.00 -34.00   0.50   31.08    --  -45.08 -54.00  17.19   52
 33  ω    -58.00 -32.00   0.50   31.08    --  -45.08 -59.00-169.42   52
 34  ω    -59.00 -33.00   0.50   31.08    --  -45.08 -56.00 -41.59   52
 35  ω    -95.00 -43.00   0.50   31.08    --  -45.08 133.00 -91.22  104
 36  ω    -53.00  32.00   0.50   31.08    --  -45.08  37.00 150.00  170
 37  ω    -95.00 -42.00   0.50   31.08    --  -45.08 133.00-129.77  106
 38  ω    -50.00  30.00   0.50   31.08    --  -45.08  37.00-150.00  160
 39  ω   -113.00 -35.00   0.50   31.08    --  -45.08 -47.00  67.84  156
 40  ω    -98.00 -40.00   0.50   31.08    --  -45.08 -50.00 156.94  116
 41  ω    -93.00 -40.00   0.50   31.08    --  -45.08 130.00 -16.24  106
 42  ω    -33.00  34.00   0.50   31.08    --  -45.08  19.00  60.00  134
 43  ω   -117.00 -34.00   0.50   31.08    --  -45.08 -51.00-142.88  166
 44  ω    -60.00 -33.00   0.50   31.08    --  -45.08 -56.00 144.96   54
 45  ω    -48.00  21.00   0.50   31.08    --  -45.08  19.00 150.00  138
 46  ω    -26.00  26.00   0.50   31.08    --   46.33 -57.00-150.00  104
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0384843000
_diffrn_orient_matrix_UB_12      -0.0337875000
_diffrn_orient_matrix_UB_13      0.0179308000
_diffrn_orient_matrix_UB_21      0.0358078000
_diffrn_orient_matrix_UB_22      0.0350816000
_diffrn_orient_matrix_UB_23      0.0213671000
_diffrn_orient_matrix_UB_31      -0.0135980000
_diffrn_orient_matrix_UB_32      -0.0031977000
_diffrn_orient_matrix_UB_33      0.0453733000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0873
_diffrn_reflns_av_unetI/netI     0.0499
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            176659
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         35.500
_diffrn_reflns_theta_min         2.074
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    1.677
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.787
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.79a (Rigaku Oxford Diffraction, 2020)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.373
_exptl_crystal_description       plate
_exptl_crystal_F_000             1136
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.553
_refine_diff_density_min         -0.326
_refine_diff_density_rms         0.076
_refine_ls_abs_structure_details
;
 Flack x determined using 9032 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.005(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     534
_refine_ls_number_reflns         24143
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0449
_refine_ls_R_factor_gt           0.0343
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0149P)²+0.8018P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0614
_refine_ls_wR_factor_ref         0.0645
_reflns_Friedel_coverage         0.939
_reflns_Friedel_fraction_full    0.999
_reflns_Friedel_fraction_max     1.000
_reflns_number_gt                21199
_reflns_number_total             24143
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1dt02016a2.cif
_cod_data_source_block           1001
_cod_depositor_comments
'Adding full bibliography for 7707835--7707841.cif.'
_cod_database_code               7707840
_shelx_shelxl_version_number     2014/7
_chemical_oxdiff_formula         'C80 H146 Cl2 Co6 Ge2 O20 P6'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.967
_shelx_estimated_absorpt_t_min   0.811
_diffrn_oxdiff_digest_frames
;
01069a217aef9a6202b272f35f2eb8d26203902b85f
;
_diffrn_oxdiff_digest_hkl
;
018c0ba13d74e666bded72d623499990c8612c
;
_reflns_odcompleteness_completeness 99.95
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     45.18
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C101(H10A,H10B), C102(H10C,H10D), C104(H10H,H10I), C105(H10J,H10K), C107(H10O,
 H10P), C108(H10Q,H10R), C201(H20A,H20B), C202(H20C,H20D), C204(H20H,H20I),
 C205(H20J,H20K), C207(H20O,H20P), C208(H20Q,H20R), C301(H30A,H30B), C302(H30C,
 H30D), C304(H30H,H30I), C305(H30J,H30K), C307(H30O,H30P), C308(H30Q,H30R),
 C402(H40D,H40E), C404(H40F,H40G)
2.b Idealised Me refined as rotating group:
 C103(H10E,H10F,H10G), C106(H10L,H10M,H10N), C109(H10S,H10T,H10U), C203(H20E,
 H20F,H20G), C206(H20L,H20M,H20N), C209(H20S,H20T,H20U), C303(H30E,H30F,H30G),
 C306(H30L,H30M,H30N), C309(H30S,H30T,H30U), C401(H40A,H40B,H40C), C405(H40H,
 H40I,H40J)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.544
_oxdiff_exptl_absorpt_empirical_full_min 0.741
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.30165(2) 0.47167(2) 0.66321(2) 0.01048(4) Uani 1 1 d . . . . .
Co1 Co 0.13839(2) 0.39482(2) 0.64238(2) 0.01339(6) Uani 1 1 d . . . . .
Co2 Co 0.42041(2) 0.38055(2) 0.60044(2) 0.01231(5) Uani 1 1 d . . . . .
Co3 Co 0.37444(2) 0.54163(2) 0.82723(2) 0.01159(5) Uani 1 1 d . . . . .
Cl1 Cl 0.26262(5) 0.59749(4) 0.56019(4) 0.01865(10) Uani 1 1 d . . . . .
P1 P 0.00031(5) 0.31327(4) 0.63694(5) 0.01773(11) Uani 1 1 d . . . . .
P2 P 0.50943(4) 0.28984(4) 0.52863(4) 0.01291(10) Uani 1 1 d . . . . .
P3 P 0.43604(5) 0.60390(4) 0.97757(4) 0.01429(10) Uani 1 1 d . . . . .
O15 O 0.02658(16) 0.56918(15) 0.61209(18) 0.0318(5) Uani 1 1 d . . . . .
O16 O 0.23413(17) 0.32125(15) 0.84192(15) 0.0280(4) Uani 1 1 d . . . . .
O18 O 0.15002(17) 0.3136(2) 0.45414(17) 0.0424(6) Uani 1 1 d . . . . .
O22 O 0.35934(16) 0.22111(14) 0.69692(16) 0.0271(4) Uani 1 1 d . . . . .
O24 O 0.32073(18) 0.45815(16) 0.40319(14) 0.0331(5) Uani 1 1 d . . . . .
O26 O 0.59932(16) 0.4722(2) 0.73200(17) 0.0377(5) Uani 1 1 d . . . . .
O32 O 0.16770(16) 0.57746(17) 0.83659(17) 0.0330(5) Uani 1 1 d . . . . .
O34 O 0.48166(18) 0.67602(15) 0.73949(15) 0.0297(4) Uani 1 1 d . . . . .
O36 O 0.47633(16) 0.36611(13) 0.88994(14) 0.0240(4) Uani 1 1 d . . . . .
C14 C 0.07268(19) 0.50254(18) 0.62469(19) 0.0196(4) Uani 1 1 d . . . . .
C17 C 0.1495(2) 0.3457(2) 0.5291(2) 0.0239(5) Uani 1 1 d . . . . .
C018 C 0.19883(19) 0.35172(17) 0.76373(19) 0.0181(4) Uani 1 1 d . . . . .
C21 C 0.38043(19) 0.28507(17) 0.65871(18) 0.0175(4) Uani 1 1 d . . . . .
C23 C 0.3564(2) 0.42895(18) 0.48168(18) 0.0203(5) Uani 1 1 d . . . . .
C25 C 0.5280(2) 0.43880(19) 0.6794(2) 0.0213(5) Uani 1 1 d . . . . .
C31 C 0.24736(19) 0.56246(17) 0.82954(18) 0.0190(4) Uani 1 1 d . . . . .
C33 C 0.4375(2) 0.62275(17) 0.77060(17) 0.0185(4) Uani 1 1 d . . . . .
C35 C 0.43502(19) 0.43466(17) 0.86418(17) 0.0164(4) Uani 1 1 d . . . . .
C101 C -0.09056(19) 0.3691(2) 0.6929(2) 0.0230(5) Uani 1 1 d . . . . .
H10A H -0.1182 0.4248 0.6532 0.028 Uiso 1 1 calc R . . . .
H10B H -0.1485 0.3267 0.6879 0.028 Uiso 1 1 calc R . . . .
C102 C -0.0454(2) 0.3970(2) 0.8025(2) 0.0276(5) Uani 1 1 d . . . . .
H10C H 0.0094 0.4430 0.8075 0.033 Uiso 1 1 calc R . . . .
H10D H -0.0141 0.3424 0.8421 0.033 Uiso 1 1 calc R . . . .
C103 C -0.1259(3) 0.4375(3) 0.8466(3) 0.0356(7) Uani 1 1 d . . . . .
H10E H -0.1576 0.4911 0.8071 0.053 Uiso 1 1 calc GR . . . .
H10F H -0.0934 0.4562 0.9163 0.053 Uiso 1 1 calc GR . . . .
H10G H -0.1784 0.3910 0.8450 0.053 Uiso 1 1 calc GR . . . .
C104 C -0.0769(2) 0.2770(2) 0.5134(2) 0.0256(5) Uani 1 1 d . . . . .
H10H H -0.0373 0.2308 0.4878 0.031 Uiso 1 1 calc R . . . .
H10I H -0.1386 0.2456 0.5211 0.031 Uiso 1 1 calc R . . . .
C105 C -0.1119(2) 0.3516(2) 0.4338(2) 0.0257(5) Uani 1 1 d . . . . .
H10J H -0.0519 0.3875 0.4288 0.031 Uiso 1 1 calc R . . . .
H10K H -0.1592 0.3942 0.4536 0.031 Uiso 1 1 calc R . . . .
C106 C -0.1660(3) 0.3091(2) 0.3314(2) 0.0315(6) Uani 1 1 d . . . . .
H10L H -0.1862 0.3579 0.2810 0.047 Uiso 1 1 calc GR . . . .
H10M H -0.2271 0.2758 0.3357 0.047 Uiso 1 1 calc GR . . . .
H10N H -0.1195 0.2663 0.3122 0.047 Uiso 1 1 calc GR . . . .
C107 C 0.0252(2) 0.20260(19) 0.7029(2) 0.0246(5) Uani 1 1 d . . . . .
H10O H 0.0529 0.2145 0.7759 0.030 Uiso 1 1 calc R . . . .
H10P H -0.0405 0.1695 0.6919 0.030 Uiso 1 1 calc R . . . .
C108 C 0.0997(3) 0.1406(2) 0.6702(2) 0.0300(6) Uani 1 1 d . . . . .
H10Q H 0.0689 0.1227 0.5992 0.036 Uiso 1 1 calc R . . . .
H10R H 0.1632 0.1754 0.6746 0.036 Uiso 1 1 calc R . . . .
C109 C 0.1265(4) 0.0546(3) 0.7338(3) 0.0562(11) Uani 1 1 d . . . . .
H10S H 0.1759 0.0179 0.7111 0.084 Uiso 1 1 calc GR . . . .
H10T H 0.0644 0.0182 0.7271 0.084 Uiso 1 1 calc GR . . . .
H10U H 0.1566 0.0718 0.8043 0.084 Uiso 1 1 calc GR . . . .
C201 C 0.44055(19) 0.18603(16) 0.47221(18) 0.0173(4) Uani 1 1 d . . . . .
H20A H 0.4856 0.1490 0.4429 0.021 Uiso 1 1 calc R . . . .
H20B H 0.4253 0.1488 0.5257 0.021 Uiso 1 1 calc R . . . .
C202 C 0.3406(2) 0.20541(19) 0.3907(2) 0.0222(5) Uani 1 1 d . . . . .
H20C H 0.3083 0.2609 0.4095 0.027 Uiso 1 1 calc R . . . .
H20D H 0.3561 0.2188 0.3269 0.027 Uiso 1 1 calc R . . . .
C203 C 0.2653(2) 0.1260(2) 0.3742(3) 0.0389(8) Uani 1 1 d . . . . .
H20E H 0.2032 0.1419 0.3206 0.058 Uiso 1 1 calc GR . . . .
H20F H 0.2475 0.1138 0.4364 0.058 Uiso 1 1 calc GR . . . .
H20G H 0.2965 0.0709 0.3549 0.058 Uiso 1 1 calc GR . . . .
C204 C 0.54900(19) 0.34220(17) 0.42659(17) 0.0172(4) Uani 1 1 d . . . . .
H20H H 0.5913 0.2974 0.4027 0.021 Uiso 1 1 calc R . . . .
H20I H 0.4872 0.3550 0.3701 0.021 Uiso 1 1 calc R . . . .
C205 C 0.6096(2) 0.43119(18) 0.4551(2) 0.0221(5) Uani 1 1 d . . . . .
H20J H 0.5715 0.4736 0.4870 0.027 Uiso 1 1 calc R . . . .
H20K H 0.6761 0.4173 0.5049 0.027 Uiso 1 1 calc R . . . .
C206 C 0.6288(2) 0.4785(2) 0.3648(2) 0.0278(5) Uani 1 1 d . . . . .
H20L H 0.5636 0.5001 0.3195 0.042 Uiso 1 1 calc GR . . . .
H20M H 0.6605 0.4349 0.3291 0.042 Uiso 1 1 calc GR . . . .
H20N H 0.6746 0.5311 0.3874 0.042 Uiso 1 1 calc GR . . . .
C207 C 0.63070(18) 0.24678(17) 0.60999(17) 0.0165(4) Uani 1 1 d . . . . .
H20O H 0.6653 0.2118 0.5682 0.020 Uiso 1 1 calc R . . . .
H20P H 0.6746 0.3002 0.6382 0.020 Uiso 1 1 calc R . . . .
C208 C 0.6240(2) 0.1855(2) 0.6967(2) 0.0234(5) Uani 1 1 d . . . . .
H20Q H 0.5909 0.2198 0.7403 0.028 Uiso 1 1 calc R . . . .
H20R H 0.5813 0.1310 0.6699 0.028 Uiso 1 1 calc R . . . .
C209 C 0.7297(2) 0.1542(2) 0.7583(2) 0.0267(5) Uani 1 1 d . . . . .
H20S H 0.7642 0.1235 0.7144 0.040 Uiso 1 1 calc GR . . . .
H20T H 0.7231 0.1111 0.8104 0.040 Uiso 1 1 calc GR . . . .
H20U H 0.7700 0.2077 0.7900 0.040 Uiso 1 1 calc GR . . . .
C301 C 0.5629(2) 0.65571(18) 1.0025(2) 0.0213(5) Uani 1 1 d . . . . .
H30A H 0.5583 0.7097 0.9580 0.026 Uiso 1 1 calc R . . . .
H30B H 0.5850 0.6780 1.0727 0.026 Uiso 1 1 calc R . . . .
C302 C 0.6442(2) 0.5897(2) 0.9865(2) 0.0273(6) Uani 1 1 d . . . . .
H30C H 0.6627 0.5450 1.0426 0.033 Uiso 1 1 calc R . . . .
H30D H 0.6151 0.5548 0.9236 0.033 Uiso 1 1 calc R . . . .
C303 C 0.7399(3) 0.6394(3) 0.9807(3) 0.0460(9) Uani 1 1 d . . . . .
H30E H 0.7229 0.6805 0.9223 0.069 Uiso 1 1 calc GR . . . .
H30F H 0.7909 0.5943 0.9740 0.069 Uiso 1 1 calc GR . . . .
H30G H 0.7679 0.6756 1.0419 0.069 Uiso 1 1 calc GR . . . .
C304 C 0.35877(19) 0.69665(17) 1.00701(18) 0.0176(4) Uani 1 1 d . . . . .
H30H H 0.2937 0.6701 1.0123 0.021 Uiso 1 1 calc R . . . .
H30I H 0.3956 0.7223 1.0736 0.021 Uiso 1 1 calc R . . . .
C305 C 0.3337(2) 0.77537(17) 0.93106(18) 0.0196(4) Uani 1 1 d . . . . .
H30J H 0.3979 0.8064 0.9299 0.024 Uiso 1 1 calc R . . . .
H30K H 0.3010 0.7501 0.8632 0.024 Uiso 1 1 calc R . . . .
C306 C 0.2623(2) 0.8453(2) 0.9567(2) 0.0283(6) Uani 1 1 d . . . . .
H30L H 0.2474 0.8945 0.9063 0.042 Uiso 1 1 calc GR . . . .
H30M H 0.2951 0.8717 1.0231 0.042 Uiso 1 1 calc GR . . . .
H30N H 0.1984 0.8149 0.9573 0.042 Uiso 1 1 calc GR . . . .
C307 C 0.4480(2) 0.52335(18) 1.08175(17) 0.0215(5) Uani 1 1 d . . . . .
H30O H 0.5073 0.4825 1.0867 0.026 Uiso 1 1 calc R . . . .
H30P H 0.4623 0.5587 1.1451 0.026 Uiso 1 1 calc R . . . .
C308 C 0.3529(2) 0.46406(19) 1.07108(18) 0.0236(5) Uani 1 1 d . . . . .
H30Q H 0.3400 0.4264 1.0094 0.028 Uiso 1 1 calc R . . . .
H30R H 0.2929 0.5045 1.0640 0.028 Uiso 1 1 calc R . . . .
C309 C 0.3650(3) 0.4007(2) 1.1614(2) 0.0339(7) Uani 1 1 d . . . . .
H30S H 0.3048 0.3607 1.1496 0.051 Uiso 1 1 calc GR . . . .
H30T H 0.3715 0.4378 1.2217 0.051 Uiso 1 1 calc GR . . . .
H30U H 0.4265 0.3628 1.1709 0.051 Uiso 1 1 calc GR . . . .
O403 O -0.03224(19) 0.8000(2) 0.90847(19) 0.0423(6) Uani 1 1 d . . . . .
C401 C -0.0878(4) 0.9455(4) 0.8344(5) 0.0743(16) Uani 1 1 d . . . . .
H40A H -0.1207 0.9766 0.7706 0.111 Uiso 1 1 calc GR . . . .
H40B H -0.0201 0.9726 0.8649 0.111 Uiso 1 1 calc GR . . . .
H40C H -0.1301 0.9531 0.8800 0.111 Uiso 1 1 calc GR . . . .
C402 C -0.0762(3) 0.8442(3) 0.8154(4) 0.0523(10) Uani 1 1 d . . . . .
H40D H -0.1439 0.8169 0.7817 0.063 Uiso 1 1 calc R . . . .
H40E H -0.0317 0.8359 0.7711 0.063 Uiso 1 1 calc R . . . .
C404 C -0.0180(3) 0.7046(3) 0.8969(3) 0.0437(8) Uani 1 1 d . . . . .
H40F H 0.0256 0.6950 0.8519 0.052 Uiso 1 1 calc R . . . .
H40G H -0.0849 0.6748 0.8661 0.052 Uiso 1 1 calc R . . . .
C405 C 0.0315(3) 0.6627(4) 0.9964(3) 0.0571(11) Uani 1 1 d . . . . .
H40H H 0.0413 0.5967 0.9882 0.086 Uiso 1 1 calc GR . . . .
H40I H -0.0122 0.6717 1.0404 0.086 Uiso 1 1 calc GR . . . .
H40J H 0.0980 0.6920 1.0264 0.086 Uiso 1 1 calc GR . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
2 1 -2 0.0293
-1 0 2 0.0507
-1 0 0 0.0077
0 -1 0 0.0488
0 1 0 0.0488
-1 -1 2 0.0416
1 0 -2 0.0441
1 0 0 0.0107
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Co1 Ge1 Co2 112.858(13) . . ?
Co3 Ge1 Co1 114.487(13) . . ?
Co3 Ge1 Co2 115.422(14) . . ?
Cl1 Ge1 Co1 104.662(19) . . ?
Cl1 Ge1 Co2 105.498(18) . . ?
Cl1 Ge1 Co3 102.203(19) . . ?
P1 Co1 Ge1 173.20(2) . . ?
C14 Co1 Ge1 91.16(8) . . ?
C14 Co1 P1 94.36(8) . . ?
C17 Co1 Ge1 88.80(9) . . ?
C17 Co1 P1 92.62(9) . . ?
C17 Co1 C14 113.47(13) . . ?
C018 Co1 Ge1 83.74(8) . . ?
C018 Co1 P1 90.00(8) . . ?
C018 Co1 C14 121.32(12) . . ?
C018 Co1 C17 124.74(13) . . ?
P2 Co2 Ge1 172.19(2) . . ?
C21 Co2 Ge1 86.36(7) . . ?
C21 Co2 P2 91.28(8) . . ?
C21 Co2 C23 127.07(12) . . ?
C21 Co2 C25 113.59(12) . . ?
C23 Co2 Ge1 85.39(8) . . ?
C23 Co2 P2 90.12(8) . . ?
C25 Co2 Ge1 92.08(8) . . ?
C25 Co2 P2 95.68(8) . . ?
C25 Co2 C23 118.89(13) . . ?
P3 Co3 Ge1 178.14(2) . . ?
C31 Co3 Ge1 87.28(8) . . ?
C31 Co3 P3 91.08(8) . . ?
C31 Co3 C33 119.93(12) . . ?
C33 Co3 Ge1 88.84(8) . . ?
C33 Co3 P3 92.74(8) . . ?
C35 Co3 Ge1 86.26(8) . . ?
C35 Co3 P3 93.86(8) . . ?
C35 Co3 C31 121.60(12) . . ?
C35 Co3 C33 117.89(12) . . ?
C101 P1 Co1 115.04(9) . . ?
C104 P1 Co1 116.35(9) . . ?
C104 P1 C101 104.61(13) . . ?
C104 P1 C107 101.07(13) . . ?
C107 P1 Co1 114.88(9) . . ?
C107 P1 C101 103.04(13) . . ?
C201 P2 Co2 113.76(8) . . ?
C204 P2 Co2 115.28(8) . . ?
C204 P2 C201 103.95(11) . . ?
C207 P2 Co2 116.21(8) . . ?
C207 P2 C201 104.15(11) . . ?
C207 P2 C204 101.88(11) . . ?
C301 P3 Co3 115.36(8) . . ?
C301 P3 C304 103.30(12) . . ?
C301 P3 C307 104.52(13) . . ?
C304 P3 Co3 115.32(8) . . ?
C304 P3 C307 102.61(11) . . ?
C307 P3 Co3 114.16(9) . . ?
O15 C14 Co1 176.9(2) . . ?
O18 C17 Co1 175.6(2) . . ?
O16 C018 Co1 176.8(2) . . ?
O22 C21 Co2 176.5(2) . . ?
O24 C23 Co2 175.4(2) . . ?
O26 C25 Co2 176.6(3) . . ?
O32 C31 Co3 176.1(2) . . ?
O34 C33 Co3 176.1(2) . . ?
O36 C35 Co3 178.3(2) . . ?
P1 C101 H10A 108.6 . . ?
P1 C101 H10B 108.6 . . ?
H10A C101 H10B 107.6 . . ?
C102 C101 P1 114.53(18) . . ?
C102 C101 H10A 108.6 . . ?
C102 C101 H10B 108.6 . . ?
C101 C102 H10C 109.2 . . ?
C101 C102 H10D 109.2 . . ?
C101 C102 C103 112.1(2) . . ?
H10C C102 H10D 107.9 . . ?
C103 C102 H10C 109.2 . . ?
C103 C102 H10D 109.2 . . ?
C102 C103 H10E 109.5 . . ?
C102 C103 H10F 109.5 . . ?
C102 C103 H10G 109.5 . . ?
H10E C103 H10F 109.5 . . ?
H10E C103 H10G 109.5 . . ?
H10F C103 H10G 109.5 . . ?
P1 C104 H10H 108.0 . . ?
P1 C104 H10I 108.0 . . ?
H10H C104 H10I 107.3 . . ?
C105 C104 P1 117.1(2) . . ?
C105 C104 H10H 108.0 . . ?
C105 C104 H10I 108.0 . . ?
C104 C105 H10J 109.5 . . ?
C104 C105 H10K 109.5 . . ?
C104 C105 C106 110.7(2) . . ?
H10J C105 H10K 108.1 . . ?
C106 C105 H10J 109.5 . . ?
C106 C105 H10K 109.5 . . ?
C105 C106 H10L 109.5 . . ?
C105 C106 H10M 109.5 . . ?
C105 C106 H10N 109.5 . . ?
H10L C106 H10M 109.5 . . ?
H10L C106 H10N 109.5 . . ?
H10M C106 H10N 109.5 . . ?
P1 C107 H10O 108.7 . . ?
P1 C107 H10P 108.7 . . ?
H10O C107 H10P 107.6 . . ?
C108 C107 P1 114.34(19) . . ?
C108 C107 H10O 108.7 . . ?
C108 C107 H10P 108.7 . . ?
C107 C108 H10Q 109.1 . . ?
C107 C108 H10R 109.1 . . ?
H10Q C108 H10R 107.8 . . ?
C109 C108 C107 112.5(3) . . ?
C109 C108 H10Q 109.1 . . ?
C109 C108 H10R 109.1 . . ?
C108 C109 H10S 109.5 . . ?
C108 C109 H10T 109.5 . . ?
C108 C109 H10U 109.5 . . ?
H10S C109 H10T 109.5 . . ?
H10S C109 H10U 109.5 . . ?
H10T C109 H10U 109.5 . . ?
P2 C201 H20A 108.8 . . ?
P2 C201 H20B 108.8 . . ?
H20A C201 H20B 107.7 . . ?
C202 C201 P2 113.84(17) . . ?
C202 C201 H20A 108.8 . . ?
C202 C201 H20B 108.8 . . ?
C201 C202 H20C 109.0 . . ?
C201 C202 H20D 109.0 . . ?
H20C C202 H20D 107.8 . . ?
C203 C202 C201 113.1(2) . . ?
C203 C202 H20C 109.0 . . ?
C203 C202 H20D 109.0 . . ?
C202 C203 H20E 109.5 . . ?
C202 C203 H20F 109.5 . . ?
C202 C203 H20G 109.5 . . ?
H20E C203 H20F 109.5 . . ?
H20E C203 H20G 109.5 . . ?
H20F C203 H20G 109.5 . . ?
P2 C204 H20H 108.7 . . ?
P2 C204 H20I 108.7 . . ?
H20H C204 H20I 107.6 . . ?
C205 C204 P2 114.33(17) . . ?
C205 C204 H20H 108.7 . . ?
C205 C204 H20I 108.7 . . ?
C204 C205 H20J 109.1 . . ?
C204 C205 H20K 109.1 . . ?
H20J C205 H20K 107.9 . . ?
C206 C205 C204 112.3(2) . . ?
C206 C205 H20J 109.1 . . ?
C206 C205 H20K 109.1 . . ?
C205 C206 H20L 109.5 . . ?
C205 C206 H20M 109.5 . . ?
C205 C206 H20N 109.5 . . ?
H20L C206 H20M 109.5 . . ?
H20L C206 H20N 109.5 . . ?
H20M C206 H20N 109.5 . . ?
P2 C207 H20O 108.3 . . ?
P2 C207 H20P 108.3 . . ?
H20O C207 H20P 107.4 . . ?
C208 C207 P2 116.12(17) . . ?
C208 C207 H20O 108.3 . . ?
C208 C207 H20P 108.3 . . ?
C207 C208 H20Q 109.4 . . ?
C207 C208 H20R 109.4 . . ?
H20Q C208 H20R 108.0 . . ?
C209 C208 C207 111.0(2) . . ?
C209 C208 H20Q 109.4 . . ?
C209 C208 H20R 109.4 . . ?
C208 C209 H20S 109.5 . . ?
C208 C209 H20T 109.5 . . ?
C208 C209 H20U 109.5 . . ?
H20S C209 H20T 109.5 . . ?
H20S C209 H20U 109.5 . . ?
H20T C209 H20U 109.5 . . ?
P3 C301 H30A 108.8 . . ?
P3 C301 H30B 108.8 . . ?
H30A C301 H30B 107.7 . . ?
C302 C301 P3 113.64(18) . . ?
C302 C301 H30A 108.8 . . ?
C302 C301 H30B 108.8 . . ?
C301 C302 H30C 109.1 . . ?
C301 C302 H30D 109.1 . . ?
H30C C302 H30D 107.9 . . ?
C303 C302 C301 112.4(3) . . ?
C303 C302 H30C 109.1 . . ?
C303 C302 H30D 109.1 . . ?
C302 C303 H30E 109.5 . . ?
C302 C303 H30F 109.5 . . ?
C302 C303 H30G 109.5 . . ?
H30E C303 H30F 109.5 . . ?
H30E C303 H30G 109.5 . . ?
H30F C303 H30G 109.5 . . ?
P3 C304 H30H 108.5 . . ?
P3 C304 H30I 108.5 . . ?
H30H C304 H30I 107.5 . . ?
C305 C304 P3 115.16(16) . . ?
C305 C304 H30H 108.5 . . ?
C305 C304 H30I 108.5 . . ?
C304 C305 H30J 109.3 . . ?
C304 C305 H30K 109.3 . . ?
H30J C305 H30K 108.0 . . ?
C306 C305 C304 111.6(2) . . ?
C306 C305 H30J 109.3 . . ?
C306 C305 H30K 109.3 . . ?
C305 C306 H30L 109.5 . . ?
C305 C306 H30M 109.5 . . ?
C305 C306 H30N 109.5 . . ?
H30L C306 H30M 109.5 . . ?
H30L C306 H30N 109.5 . . ?
H30M C306 H30N 109.5 . . ?
P3 C307 H30O 108.8 . . ?
P3 C307 H30P 108.8 . . ?
H30O C307 H30P 107.7 . . ?
C308 C307 P3 113.87(18) . . ?
C308 C307 H30O 108.8 . . ?
C308 C307 H30P 108.8 . . ?
C307 C308 H30Q 109.2 . . ?
C307 C308 H30R 109.2 . . ?
C307 C308 C309 112.0(2) . . ?
H30Q C308 H30R 107.9 . . ?
C309 C308 H30Q 109.2 . . ?
C309 C308 H30R 109.2 . . ?
C308 C309 H30S 109.5 . . ?
C308 C309 H30T 109.5 . . ?
C308 C309 H30U 109.5 . . ?
H30S C309 H30T 109.5 . . ?
H30S C309 H30U 109.5 . . ?
H30T C309 H30U 109.5 . . ?
C402 O403 C404 112.1(3) . . ?
H40A C401 H40B 109.5 . . ?
H40A C401 H40C 109.5 . . ?
H40B C401 H40C 109.5 . . ?
C402 C401 H40A 109.5 . . ?
C402 C401 H40B 109.5 . . ?
C402 C401 H40C 109.5 . . ?
O403 C402 C401 108.7(4) . . ?
O403 C402 H40D 110.0 . . ?
O403 C402 H40E 110.0 . . ?
C401 C402 H40D 110.0 . . ?
C401 C402 H40E 110.0 . . ?
H40D C402 H40E 108.3 . . ?
O403 C404 H40F 109.7 . . ?
O403 C404 H40G 109.7 . . ?
O403 C404 C405 109.7(3) . . ?
H40F C404 H40G 108.2 . . ?
C405 C404 H40F 109.7 . . ?
C405 C404 H40G 109.7 . . ?
C404 C405 H40H 109.5 . . ?
C404 C405 H40I 109.5 . . ?
C404 C405 H40J 109.5 . . ?
H40H C405 H40I 109.5 . . ?
H40H C405 H40J 109.5 . . ?
H40I C405 H40J 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 Co1 2.4336(4) . ?
Ge1 Co2 2.4423(4) . ?
Ge1 Co3 2.4319(4) . ?
Ge1 Cl1 2.2888(6) . ?
Co1 P1 2.2090(7) . ?
Co1 C14 1.785(3) . ?
Co1 C17 1.777(3) . ?
Co1 C018 1.765(3) . ?
Co2 P2 2.2172(6) . ?
Co2 C21 1.771(2) . ?
Co2 C23 1.775(3) . ?
Co2 C25 1.773(3) . ?
Co3 P3 2.2094(6) . ?
Co3 C31 1.770(3) . ?
Co3 C33 1.773(2) . ?
Co3 C35 1.766(2) . ?
P1 C101 1.834(3) . ?
P1 C104 1.815(3) . ?
P1 C107 1.834(3) . ?
P2 C201 1.830(2) . ?
P2 C204 1.825(2) . ?
P2 C207 1.824(2) . ?
P3 C301 1.827(3) . ?
P3 C304 1.830(2) . ?
P3 C307 1.833(2) . ?
O15 C14 1.140(3) . ?
O16 C018 1.144(3) . ?
O18 C17 1.144(3) . ?
O22 C21 1.148(3) . ?
O24 C23 1.141(3) . ?
O26 C25 1.143(3) . ?
O32 C31 1.141(3) . ?
O34 C33 1.141(3) . ?
O36 C35 1.150(3) . ?
C101 H10A 0.9900 . ?
C101 H10B 0.9900 . ?
C101 C102 1.524(4) . ?
C102 H10C 0.9900 . ?
C102 H10D 0.9900 . ?
C102 C103 1.524(4) . ?
C103 H10E 0.9800 . ?
C103 H10F 0.9800 . ?
C103 H10G 0.9800 . ?
C104 H10H 0.9900 . ?
C104 H10I 0.9900 . ?
C104 C105 1.524(4) . ?
C105 H10J 0.9900 . ?
C105 H10K 0.9900 . ?
C105 C106 1.531(4) . ?
C106 H10L 0.9800 . ?
C106 H10M 0.9800 . ?
C106 H10N 0.9800 . ?
C107 H10O 0.9900 . ?
C107 H10P 0.9900 . ?
C107 C108 1.524(4) . ?
C108 H10Q 0.9900 . ?
C108 H10R 0.9900 . ?
C108 C109 1.513(5) . ?
C109 H10S 0.9800 . ?
C109 H10T 0.9800 . ?
C109 H10U 0.9800 . ?
C201 H20A 0.9900 . ?
C201 H20B 0.9900 . ?
C201 C202 1.526(4) . ?
C202 H20C 0.9900 . ?
C202 H20D 0.9900 . ?
C202 C203 1.518(4) . ?
C203 H20E 0.9800 . ?
C203 H20F 0.9800 . ?
C203 H20G 0.9800 . ?
C204 H20H 0.9900 . ?
C204 H20I 0.9900 . ?
C204 C205 1.524(4) . ?
C205 H20J 0.9900 . ?
C205 H20K 0.9900 . ?
C205 C206 1.521(4) . ?
C206 H20L 0.9800 . ?
C206 H20M 0.9800 . ?
C206 H20N 0.9800 . ?
C207 H20O 0.9900 . ?
C207 H20P 0.9900 . ?
C207 C208 1.523(3) . ?
C208 H20Q 0.9900 . ?
C208 H20R 0.9900 . ?
C208 C209 1.518(4) . ?
C209 H20S 0.9800 . ?
C209 H20T 0.9800 . ?
C209 H20U 0.9800 . ?
C301 H30A 0.9900 . ?
C301 H30B 0.9900 . ?
C301 C302 1.531(4) . ?
C302 H30C 0.9900 . ?
C302 H30D 0.9900 . ?
C302 C303 1.516(5) . ?
C303 H30E 0.9800 . ?
C303 H30F 0.9800 . ?
C303 H30G 0.9800 . ?
C304 H30H 0.9900 . ?
C304 H30I 0.9900 . ?
C304 C305 1.527(3) . ?
C305 H30J 0.9900 . ?
C305 H30K 0.9900 . ?
C305 C306 1.520(4) . ?
C306 H30L 0.9800 . ?
C306 H30M 0.9800 . ?
C306 H30N 0.9800 . ?
C307 H30O 0.9900 . ?
C307 H30P 0.9900 . ?
C307 C308 1.528(4) . ?
C308 H30Q 0.9900 . ?
C308 H30R 0.9900 . ?
C308 C309 1.529(4) . ?
C309 H30S 0.9800 . ?
C309 H30T 0.9800 . ?
C309 H30U 0.9800 . ?
O403 C402 1.414(5) . ?
O403 C404 1.415(5) . ?
C401 H40A 0.9800 . ?
C401 H40B 0.9800 . ?
C401 H40C 0.9800 . ?
C401 C402 1.513(7) . ?
C402 H40D 0.9900 . ?
C402 H40E 0.9900 . ?
C404 H40F 0.9900 . ?
C404 H40G 0.9900 . ?
C404 C405 1.484(6) . ?
C405 H40H 0.9800 . ?
C405 H40I 0.9800 . ?
C405 H40J 0.9800 . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
1.9982 0.9978 -1.9944 0.0074 0.0639 -0.1209
-1.0011 0.0009 1.9952 -0.0028 0.0068 0.1041
-0.9974 -0.0005 -0.0005 -0.0384 -0.0357 0.0135
0.0003 -0.9982 -0.0003 0.0337 -0.0350 0.0032
-0.0003 0.9982 0.0003 -0.0337 0.0350 -0.0032
-1.0008 -0.9973 1.9949 0.0309 -0.0282 0.1073
1.0011 -0.0009 -1.9952 0.0028 -0.0068 -0.1041
0.9974 0.0005 0.0005 0.0384 0.0357 -0.0135
