#------------------------------------------------------------------------------
#$Date: 2021-09-06 14:08:13 +0300 (Mon, 06 Sep 2021) $
#$Revision: 268750 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/78/7707881.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7707881
loop_
_publ_author_name
'Gao, Wei'
'Wei, Han'
'Wang, Cui-Li'
'Liu, Jie-Ping'
'Zhang, Xiu-Mei'
_publ_section_title
;
 Multifunctional Zn-Ln (Ln = Eu and Tb) heterometallic metal-organic
 frameworks with highly efficient I₂ capture, dye adsorption,
 luminescence sensing and white-light emission.
;
_journal_issue                   33
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11619
_journal_page_last               11630
_journal_paper_doi               10.1039/d1dt01968f
_journal_volume                  50
_journal_year                    2021
_chemical_formula_sum            'C72 H99 Eu2 N25 O28 Zn3'
_chemical_formula_weight         2262.79
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2021-06-09 deposited with the CCDC.	2021-07-21 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.701(2)
_cell_length_b                   21.472(3)
_cell_length_c                   27.809(4)
_cell_measurement_reflns_used    9926
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.60
_cell_measurement_theta_min      2.17
_cell_volume                     9375(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0449
_diffrn_reflns_av_unetI/netI     0.0588
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            49098
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        24.999
_diffrn_reflns_theta_max         24.999
_diffrn_reflns_theta_min         2.174
_exptl_absorpt_coefficient_mu    2.162
_exptl_absorpt_correction_T_max  0.672
_exptl_absorpt_correction_T_min  0.625
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.603
_exptl_crystal_description       block
_exptl_crystal_F_000             4584
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.200
_refine_diff_density_max         1.521
_refine_diff_density_min         -0.770
_refine_diff_density_rms         0.125
_refine_ls_abs_structure_details
;
 Flack x determined using 5660 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.014(6)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1216
_refine_ls_number_reflns         16460
_refine_ls_number_restraints     3154
_refine_ls_restrained_S_all      1.049
_refine_ls_R_factor_all          0.0582
_refine_ls_R_factor_gt           0.0487
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0768P)²+10.2948P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1260
_refine_ls_wR_factor_ref         0.1324
_reflns_Friedel_coverage         0.832
_reflns_Friedel_fraction_full    0.995
_reflns_Friedel_fraction_max     0.995
_reflns_number_gt                14335
_reflns_number_total             16460
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1dt01968f2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7707881--7707882.cif.'
_cod_original_cell_volume        9376(2)
_cod_database_code               7707881
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.625
_shelx_estimated_absorpt_t_max   0.672
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 1.01580(3) 0.19808(2) 0.39234(2) 0.02304(14) Uani 1 1 d . U . . .
Eu2 Eu -0.01221(3) 0.20759(2) 0.09116(2) 0.02580(14) Uani 1 1 d . U . . .
Zn1 Zn 0.50563(8) 0.54151(7) 0.26194(6) 0.0441(4) Uani 1 1 d . U . . .
Zn2 Zn 0.86698(7) 0.33876(5) 0.44263(4) 0.0234(3) Uani 1 1 d . U . . .
Zn3 Zn 0.14589(7) 0.33904(5) 0.04476(5) 0.0245(3) Uani 1 1 d . U . . .
N1S N 0.0517(19) 0.6792(12) 0.8798(10) 0.189(7) Uani 1 1 d D U . . .
N1 N 0.9868(12) 0.0082(7) 0.3342(6) 0.098(3) Uani 1 1 d . U . . .
N2S N 0.7339(13) 0.6488(10) 0.2882(7) 0.132(4) Uani 1 1 d D U . . .
N2 N 1.2720(10) 0.1001(9) 0.4003(6) 0.099(4) Uani 1 1 d . U . . .
N3 N 0.2055(6) -0.0362(4) 0.0327(4) 0.0350(18) Uani 1 1 d . U . . .
N3S N 0.3912(14) 0.7734(11) 0.3221(9) 0.157(5) Uani 1 1 d D U . . .
N4 N 0.2144(6) -0.0981(4) 0.0312(4) 0.0318(18) Uani 1 1 d . U . . .
N4S N 0.3105(15) 0.5870(13) 0.1518(10) 0.179(6) Uani 1 1 d D U . . .
N5 N 0.2912(6) -0.1123(4) 0.0157(4) 0.037(2) Uani 1 1 d . U . . .
N6 N 0.3327(6) -0.0604(4) 0.0065(4) 0.0375(19) Uani 1 1 d . U . . .
N7 N 0.2838(8) 0.4679(6) 0.3053(5) 0.062(2) Uani 1 1 d . U . . .
N8 N 0.3479(8) 0.5078(7) 0.3051(5) 0.072(2) Uani 1 1 d . U . . .
N9 N 0.3955(8) 0.4985(6) 0.2668(5) 0.058(2) Uani 1 1 d . U . . .
N10 N 0.3631(7) 0.4519(6) 0.2407(4) 0.052(2) Uani 1 1 d . U . . .
N11 N 0.4704(11) 0.5475(8) 0.3981(6) 0.097(3) Uani 1 1 d . U . . .
N12 N 0.6556(7) 0.4576(6) 0.2588(4) 0.047(2) Uani 1 1 d . U . . .
N13 N 0.5969(7) 0.4903(6) 0.2337(4) 0.051(2) Uani 1 1 d . U . . .
N14 N 0.6061(8) 0.4829(6) 0.1886(4) 0.058(2) Uani 1 1 d . U . . .
N15 N 0.6704(7) 0.4408(6) 0.1819(4) 0.055(2) Uani 1 1 d . U . . .
N16 N -0.0637(11) 0.1194(9) -0.0588(6) 0.099(4) Uani 1 1 d . U . . .
N17 N -0.0171(10) 0.0080(5) 0.1398(5) 0.070(3) Uani 1 1 d . U . . .
N18 N 0.7838(6) -0.0356(4) 0.4713(4) 0.0359(18) Uani 1 1 d . U . . .
N19 N 0.7793(6) -0.0949(4) 0.4843(4) 0.0352(19) Uani 1 1 d . U . . .
N20 N 0.7281(6) -0.1007(5) 0.5213(4) 0.044(2) Uani 1 1 d . U . . .
N21 N 0.6946(7) -0.0448(4) 0.5308(4) 0.046(2) Uani 1 1 d . U . . .
O1 O 0.1047(5) 0.2828(4) 0.3598(3) 0.0421(18) Uani 1 1 d . U . . .
O1S O 0.0579(14) 0.6545(10) 0.9536(8) 0.173(6) Uani 1 1 d D U . . .
O2 O 0.0697(5) 0.2111(4) 0.3086(3) 0.0385(17) Uani 1 1 d . U . . .
O2S O 0.6192(11) 0.6994(8) 0.2638(7) 0.138(4) Uani 1 1 d D U . . .
O3S O 0.2799(12) 0.7271(10) 0.3612(8) 0.154(5) Uani 1 1 d D U . . .
O3 O 1.1496(6) 0.1491(5) 0.3928(4) 0.068(2) Uani 1 1 d . U . . .
O4S O 0.3788(13) 0.6671(11) 0.1862(9) 0.180(5) Uani 1 1 d D U . . .
O4 O 0.9721(6) 0.1059(4) 0.3551(4) 0.057(2) Uani 1 1 d . U . . .
O5 O 1.0268(6) 0.1310(4) 0.4633(3) 0.048(2) Uani 1 1 d D U . . .
H1O H 1.005(7) 0.156(5) 0.488(3) 0.058 Uiso 1 1 d D U . . .
H2O H 1.077(5) 0.114(5) 0.477(3) 0.058 Uiso 1 1 d D U . . .
O6 O 0.1673(5) 0.3478(4) 0.1131(3) 0.0428(17) Uani 1 1 d . U . . .
O7 O 0.0955(5) 0.2632(4) 0.1324(3) 0.0443(17) Uani 1 1 d . U . . .
O8 O 0.1986(5) 0.2620(4) 0.0228(3) 0.0354(16) Uani 1 1 d . U . . .
O9 O 0.1211(5) 0.1852(4) 0.0547(3) 0.0420(16) Uani 1 1 d . U . . .
O10 O 0.4900(5) 0.2159(3) -0.0319(3) 0.0356(15) Uani 1 1 d . U . . .
O11 O 0.5368(5) 0.1199(4) -0.0286(3) 0.0407(18) Uani 1 1 d . U . . .
O12 O 0.5094(8) 0.6215(6) 0.2293(5) 0.093(3) Uani 1 1 d D U . . .
H5O H 0.478(9) 0.633(5) 0.257(3) 0.112 Uiso 1 1 d D U . . .
H6O H 0.491(11) 0.580(3) 0.224(6) 0.112 Uiso 1 1 d D U . . .
O13 O 0.5322(7) 0.5671(5) 0.3276(4) 0.081(2) Uani 1 1 d . U . . .
O14 O 0.9369(5) 0.2180(4) 0.1740(3) 0.0371(17) Uani 1 1 d . U . . .
O15 O 0.9154(5) 0.2987(4) 0.1270(3) 0.0371(16) Uani 1 1 d . U . . .
O16 O -0.1618(5) 0.1958(4) 0.0781(3) 0.046(2) Uani 1 1 d D U . . .
H3O H -0.206(6) 0.168(4) 0.087(4) 0.055 Uiso 1 1 d D U . . .
H4O H -0.149(7) 0.184(5) 0.0460(17) 0.055 Uiso 1 1 d D U . . .
O17 O -0.0377(7) 0.1497(5) 0.0181(4) 0.072(2) Uani 1 1 d . U . . .
O18 O -0.0002(7) 0.1070(4) 0.1222(3) 0.061(2) Uani 1 1 d . U . . .
O19 O 0.9205(5) 0.2643(4) 0.3530(3) 0.0421(16) Uani 1 1 d . U . . .
O20 O 0.8468(5) 0.3489(4) 0.3741(3) 0.0426(17) Uani 1 1 d . U . . .
O21 O 0.8168(5) 0.2651(4) 0.4686(3) 0.0389(16) Uani 1 1 d . U . . .
O22 O 0.8801(5) 0.1854(3) 0.4313(3) 0.0339(15) Uani 1 1 d . U . . .
O23 O 0.5344(5) 0.2295(3) 0.5457(3) 0.0342(16) Uani 1 1 d . U . . .
O24 O 0.4803(5) 0.1348(3) 0.5387(3) 0.0385(16) Uani 1 1 d . U . . .
C1S C 0.0121(18) 0.6835(16) 0.9277(11) 0.194(7) Uani 1 1 d D U . . .
C1 C 1.3607(11) 0.0866(10) 0.4083(7) 0.102(5) Uani 1 1 d D U . . .
H1A H 1.3940 0.1230 0.4016 0.154 Uiso 1 1 calc DR U . . .
H1B H 1.3781 0.0533 0.3875 0.154 Uiso 1 1 calc R U . . .
H1C H 1.3690 0.0744 0.4412 0.154 Uiso 1 1 calc R U . . .
C2S C -0.0731(18) 0.7099(15) 0.9106(13) 0.191(8) Uani 1 1 d D U . . .
H2SA H -0.0683 0.7542 0.9069 0.287 Uiso 1 1 calc R U . . .
H2SB H -0.1164 0.7006 0.9338 0.287 Uiso 1 1 calc R U . . .
H2SC H -0.0879 0.6915 0.8803 0.287 Uiso 1 1 calc R U . . .
C2 C 1.2075(14) 0.0391(11) 0.3851(8) 0.112(5) Uani 1 1 d . U . . .
H2A H 1.1528 0.0547 0.3756 0.168 Uiso 1 1 calc R U . . .
H2B H 1.2010 0.0120 0.4123 0.168 Uiso 1 1 calc R U . . .
H2C H 1.2326 0.0164 0.3590 0.168 Uiso 1 1 calc R U . . .
C3S C 0.018(2) 0.7027(14) 0.8330(10) 0.198(8) Uani 1 1 d D U . . .
H3SA H -0.0287 0.6770 0.8229 0.297 Uiso 1 1 calc R U . . .
H3SB H 0.0622 0.7014 0.8093 0.297 Uiso 1 1 calc R U . . .
H3SC H -0.0014 0.7448 0.8369 0.297 Uiso 1 1 calc R U . . .
C3 C 1.2248(11) 0.1418(10) 0.3990(6) 0.084(3) Uani 1 1 d . U . . .
C4S C 0.1384(19) 0.6493(15) 0.8806(12) 0.191(8) Uani 1 1 d D U . . .
H4SA H 0.1384 0.6135 0.8599 0.286 Uiso 1 1 calc R U . . .
H4SB H 0.1519 0.6366 0.9128 0.286 Uiso 1 1 calc R U . . .
H4SC H 0.1802 0.6786 0.8695 0.286 Uiso 1 1 calc R U . . .
C4 C 1.2852(12) 0.1981(10) 0.4097(7) 0.104(5) Uani 1 1 d D U . . .
H4A H 1.2529 0.2360 0.4093 0.156 Uiso 1 1 calc R U . . .
H4B H 1.3289 0.1999 0.3857 0.156 Uiso 1 1 calc DR U . . .
H4C H 1.3108 0.1928 0.4408 0.156 Uiso 1 1 calc R U . . .
C5S C 0.6611(14) 0.6871(11) 0.2977(7) 0.124(4) Uani 1 1 d D U . . .
C5 C 0.9992(14) 0.0716(11) 0.2705(7) 0.116(5) Uani 1 1 d . U . . .
H5A H 1.0452 0.0450 0.2607 0.173 Uiso 1 1 calc R U . . .
H5B H 1.0137 0.1142 0.2638 0.173 Uiso 1 1 calc R U . . .
H5C H 0.9486 0.0605 0.2532 0.173 Uiso 1 1 calc R U . . .
C6S C 0.6714(14) 0.6919(11) 0.3519(7) 0.137(5) Uani 1 1 d D U . . .
H6SA H 0.7046 0.7281 0.3595 0.205 Uiso 1 1 calc R U . . .
H6SB H 0.6998 0.6554 0.3637 0.205 Uiso 1 1 calc DR U . . .
H6SC H 0.6163 0.6953 0.3666 0.205 Uiso 1 1 calc R U . . .
C6 C 0.9826(13) 0.0632(8) 0.3285(7) 0.084(3) Uani 1 1 d . U . . .
C7S C 0.8003(14) 0.6254(12) 0.3211(9) 0.144(6) Uani 1 1 d D U . . .
H7SA H 0.8494 0.6131 0.3028 0.216 Uiso 1 1 calc R U . . .
H7SB H 0.7788 0.5902 0.3385 0.216 Uiso 1 1 calc DR U . . .
H7SC H 0.8160 0.6576 0.3433 0.216 Uiso 1 1 calc R U . . .
C7 C 0.9670(14) -0.0047(9) 0.3889(8) 0.103(4) Uani 1 1 d . U . . .
H7A H 0.9111 0.0105 0.3965 0.155 Uiso 1 1 calc R U . . .
H7B H 1.0084 0.0162 0.4085 0.155 Uiso 1 1 calc R U . . .
H7C H 0.9695 -0.0487 0.3949 0.155 Uiso 1 1 calc R U . . .
C8S C 0.7333(15) 0.6338(12) 0.2354(7) 0.127(5) Uani 1 1 d D U . . .
H8SA H 0.7198 0.6707 0.2174 0.191 Uiso 1 1 calc R U . . .
H8SB H 0.6913 0.6024 0.2291 0.191 Uiso 1 1 calc R U . . .
H8SC H 0.7884 0.6188 0.2260 0.191 Uiso 1 1 calc R U . . .
C8 C 0.9951(16) -0.0476(8) 0.3074(8) 0.118(5) Uani 1 1 d . U . . .
H8A H 0.9457 -0.0533 0.2876 0.178 Uiso 1 1 calc R U . . .
H8B H 1.0005 -0.0823 0.3291 0.178 Uiso 1 1 calc R U . . .
H8C H 1.0449 -0.0452 0.2875 0.178 Uiso 1 1 calc R U . . .
C9 C 0.1027(7) 0.2612(6) 0.3182(4) 0.038(2) Uani 1 1 d . U . . .
C9S C 0.3595(19) 0.8110(14) 0.4039(11) 0.175(7) Uani 1 1 d D U . . .
H9S1 H 0.3170 0.8100 0.4287 0.262 Uiso 1 1 calc R U . . .
H9S2 H 0.3623 0.8521 0.3904 0.262 Uiso 1 1 calc R U . . .
H9S3 H 0.4138 0.8001 0.4173 0.262 Uiso 1 1 calc R U . . .
C10 C 0.1446(7) 0.2987(6) 0.2780(4) 0.0369(18) Uani 1 1 d . U . . .
C10S C 0.3360(16) 0.7643(13) 0.3645(10) 0.157(6) Uani 1 1 d D U . . .
C11 C 0.1979(8) 0.3467(6) 0.2898(5) 0.0428(19) Uani 1 1 d . U . . .
H11 H 0.2077 0.3562 0.3219 0.051 Uiso 1 1 calc R U . . .
C11S C 0.4647(16) 0.8172(13) 0.3191(12) 0.171(7) Uani 1 1 d D U . . .
H11A H 0.4812 0.8296 0.3509 0.256 Uiso 1 1 calc R U . . .
H11B H 0.4485 0.8532 0.3009 0.256 Uiso 1 1 calc R U . . .
H11C H 0.5117 0.7968 0.3036 0.256 Uiso 1 1 calc R U . . .
C12 C 0.2382(8) 0.3822(7) 0.2532(5) 0.044(2) Uani 1 1 d . U . . .
C12S C 0.3628(18) 0.7370(14) 0.2792(10) 0.168(6) Uani 1 1 d D U . . .
H12A H 0.4067 0.7082 0.2701 0.252 Uiso 1 1 calc DR U . . .
H12B H 0.3516 0.7649 0.2530 0.252 Uiso 1 1 calc R U . . .
H12C H 0.3119 0.7144 0.2870 0.252 Uiso 1 1 calc R U . . .
C13 C 0.2198(7) 0.3681(6) 0.2062(5) 0.0404(19) Uani 1 1 d . U . . .
H13 H 0.2450 0.3913 0.1818 0.048 Uiso 1 1 calc R U . . .
C13S C 0.3087(15) 0.6460(14) 0.1782(12) 0.179(6) Uani 1 1 d D U . . .
C14 C 0.1269(7) 0.2845(6) 0.2304(4) 0.0368(18) Uani 1 1 d . U . . .
H14 H 0.0905 0.2518 0.2228 0.044 Uiso 1 1 calc R U . . .
C14S C 0.2267(17) 0.6485(16) 0.2086(12) 0.188(6) Uani 1 1 d D U . . .
H14A H 0.1804 0.6307 0.1906 0.282 Uiso 1 1 calc R U . . .
H14B H 0.2136 0.6910 0.2163 0.282 Uiso 1 1 calc R U . . .
H14C H 0.2349 0.6253 0.2377 0.282 Uiso 1 1 calc R U . . .
C15 C 0.1644(7) 0.3199(6) 0.1941(4) 0.0363(19) Uani 1 1 d . U . . .
C15S C 0.3990(16) 0.5836(16) 0.1348(12) 0.185(6) Uani 1 1 d D U . . .
H15A H 0.4099 0.5429 0.1220 0.277 Uiso 1 1 calc R U . . .
H15B H 0.4370 0.5915 0.1612 0.277 Uiso 1 1 calc R U . . .
H15C H 0.4079 0.6143 0.1102 0.277 Uiso 1 1 calc R U . . .
C16 C 0.1415(7) 0.3091(6) 0.1434(4) 0.0354(19) Uani 1 1 d . U . . .
C16S C 0.2341(16) 0.5471(14) 0.1438(13) 0.181(7) Uani 1 1 d D U . . .
H16A H 0.1852 0.5730 0.1384 0.271 Uiso 1 1 calc R U . . .
H16B H 0.2246 0.5216 0.1717 0.271 Uiso 1 1 calc R U . . .
H16C H 0.2434 0.5209 0.1163 0.271 Uiso 1 1 calc R U . . .
C17 C 0.1842(6) 0.2060(5) 0.0335(4) 0.0325(17) Uani 1 1 d . U . . .
C18 C 0.2527(6) 0.1597(5) 0.0202(4) 0.0291(17) Uani 1 1 d . U . . .
C19 C 0.2387(7) 0.0962(5) 0.0259(4) 0.0321(18) Uani 1 1 d . U . . .
H19 H 0.1871 0.0829 0.0388 0.039 Uiso 1 1 calc R U . . .
C20 C 0.2980(7) 0.0528(5) 0.0132(4) 0.0328(17) Uani 1 1 d . U . . .
C21 C 0.3768(7) 0.0731(5) -0.0048(4) 0.0313(17) Uani 1 1 d . U . . .
H21 H 0.4184 0.0445 -0.0137 0.038 Uiso 1 1 calc R U . . .
C22 C 0.3916(7) 0.1365(5) -0.0091(4) 0.0307(18) Uani 1 1 d . U . . .
C23 C 0.3302(6) 0.1794(5) 0.0009(4) 0.0294(17) Uani 1 1 d . U . . .
H23 H 0.3398 0.2214 -0.0051 0.035 Uiso 1 1 calc R U . . .
C24 C 0.2800(7) -0.0136(5) 0.0170(4) 0.0308(18) Uani 1 1 d . U . . .
C25 C 0.4779(7) 0.1593(5) -0.0250(4) 0.0317(19) Uani 1 1 d . U . . .
C26 C 0.2950(9) 0.4338(7) 0.2654(5) 0.049(2) Uani 1 1 d . U . . .
C27 C 0.5157(13) 0.5339(9) 0.3674(7) 0.086(3) Uani 1 1 d . U . . .
C28 C 0.5611(14) 0.4683(10) 0.3755(8) 0.103(5) Uani 1 1 d . U . . .
H28A H 0.5201 0.4355 0.3716 0.154 Uiso 1 1 calc R U . . .
H28B H 0.5845 0.4666 0.4074 0.154 Uiso 1 1 calc DR U . . .
H28C H 0.6060 0.4632 0.3524 0.154 Uiso 1 1 calc R U . . .
C29 C 0.4240(15) 0.6125(10) 0.3897(9) 0.115(5) Uani 1 1 d . U . . .
H29A H 0.4658 0.6451 0.3884 0.173 Uiso 1 1 calc R U . . .
H29B H 0.3853 0.6203 0.4157 0.173 Uiso 1 1 calc R U . . .
H29C H 0.3931 0.6112 0.3600 0.173 Uiso 1 1 calc R U . . .
C30 C 0.4405(13) 0.5091(10) 0.4396(7) 0.101(5) Uani 1 1 d . U . . .
H30A H 0.3951 0.4823 0.4293 0.152 Uiso 1 1 calc R U . . .
H30B H 0.4203 0.5361 0.4647 0.152 Uiso 1 1 calc R U . . .
H30C H 0.4869 0.4844 0.4516 0.152 Uiso 1 1 calc DR U . . .
C31 C 0.6994(8) 0.4268(6) 0.2255(5) 0.042(2) Uani 1 1 d . U . . .
C32 C 0.7656(8) 0.3835(6) 0.2351(5) 0.041(2) Uani 1 1 d . U . . .
C33 C 0.8086(7) 0.3518(6) 0.1979(4) 0.0369(19) Uani 1 1 d . U . . .
H33 H 0.7953 0.3611 0.1661 0.044 Uiso 1 1 calc R U . . .
C34 C 0.8698(7) 0.3074(6) 0.2074(4) 0.0343(18) Uani 1 1 d . U . . .
C35 C 0.8905(7) 0.2914(6) 0.2551(4) 0.0348(18) Uani 1 1 d . U . . .
H35 H 0.9295 0.2599 0.2617 0.042 Uiso 1 1 calc R U . . .
C36 C 0.7903(7) 0.3697(6) 0.2828(5) 0.0387(19) Uani 1 1 d . U . . .
H36 H 0.7654 0.3915 0.3081 0.046 Uiso 1 1 calc R U . . .
C37 C 0.8504(7) 0.3245(5) 0.2928(4) 0.0332(18) Uani 1 1 d . U . . .
C38 C 0.8750(7) 0.3109(5) 0.3434(4) 0.0336(19) Uani 1 1 d . U . . .
C39 C 0.9112(7) 0.2726(5) 0.1670(4) 0.032(2) Uani 1 1 d . U . . .
C40 C -0.0321(12) 0.1131(9) -0.0157(7) 0.081(3) Uani 1 1 d . U . . .
C41 C 0.0212(13) 0.0491(8) -0.0065(7) 0.090(4) Uani 1 1 d . U . . .
H41A H -0.0132 0.0140 -0.0154 0.135 Uiso 1 1 calc R U . . .
H41B H 0.0361 0.0461 0.0269 0.135 Uiso 1 1 calc R U . . .
H41C H 0.0722 0.0495 -0.0256 0.135 Uiso 1 1 calc R U . . .
C42 C -0.1083(16) 0.1808(12) -0.0681(9) 0.120(6) Uani 1 1 d . U . . .
H42A H -0.1295 0.1814 -0.1005 0.180 Uiso 1 1 calc R U . . .
H42B H -0.0688 0.2144 -0.0636 0.180 Uiso 1 1 calc R U . . .
H42C H -0.1550 0.1854 -0.0460 0.180 Uiso 1 1 calc R U . . .
C43 C -0.0660(15) 0.0690(11) -0.0937(8) 0.115(5) Uani 1 1 d . U . . .
H43A H -0.0118 0.0659 -0.1094 0.172 Uiso 1 1 calc R U . . .
H43B H -0.1095 0.0773 -0.1171 0.172 Uiso 1 1 calc R U . . .
H43C H -0.0784 0.0306 -0.0775 0.172 Uiso 1 1 calc R U . . .
C44 C -0.1356(10) 0.0709(8) 0.1519(6) 0.071(4) Uani 1 1 d . U . . .
H44A H -0.1424 0.1133 0.1622 0.106 Uiso 1 1 calc R U . . .
H44B H -0.1496 0.0434 0.1779 0.106 Uiso 1 1 calc R U . . .
H44C H -0.1728 0.0629 0.1252 0.106 Uiso 1 1 calc R U . . .
C45 C -0.0463(10) 0.0604(6) 0.1371(6) 0.061(3) Uani 1 1 d . U . . .
C46 C -0.0607(13) -0.0475(8) 0.1553(8) 0.092(5) Uani 1 1 d . U . . .
H46A H -0.1199 -0.0445 0.1470 0.137 Uiso 1 1 calc R U . . .
H46B H -0.0551 -0.0518 0.1895 0.137 Uiso 1 1 calc R U . . .
H46C H -0.0361 -0.0831 0.1397 0.137 Uiso 1 1 calc R U . . .
C47 C 0.0711(12) -0.0026(8) 0.1233(7) 0.084(4) Uani 1 1 d . U . . .
H47A H 0.0741 -0.0415 0.1063 0.126 Uiso 1 1 calc R U . . .
H47B H 0.1086 -0.0038 0.1505 0.126 Uiso 1 1 calc R U . . .
H47C H 0.0879 0.0306 0.1022 0.126 Uiso 1 1 calc R U . . .
C48 C 0.8254(6) 0.2077(5) 0.4579(4) 0.0297(18) Uani 1 1 d . U . . .
C49 C 0.7587(7) 0.1661(5) 0.4786(4) 0.0303(18) Uani 1 1 d . U . . .
C50 C 0.6850(7) 0.1892(5) 0.4993(4) 0.0306(17) Uani 1 1 d . U . . .
H50 H 0.6765 0.2320 0.5016 0.037 Uiso 1 1 calc R U . . .
C51 C 0.6248(7) 0.1488(5) 0.5164(4) 0.0315(18) Uani 1 1 d . U . . .
C52 C 0.6387(7) 0.0848(5) 0.5168(4) 0.0338(18) Uani 1 1 d . U . . .
H52 H 0.5976 0.0580 0.5291 0.041 Uiso 1 1 calc R U . . .
C53 C 0.7137(7) 0.0619(5) 0.4988(5) 0.0351(18) Uani 1 1 d . U . . .
C54 C 0.7730(7) 0.1015(5) 0.4789(4) 0.0332(18) Uani 1 1 d . U . . .
H54 H 0.8228 0.0854 0.4657 0.040 Uiso 1 1 calc R U . . .
C55 C 0.7298(7) -0.0056(5) 0.4999(4) 0.0343(19) Uani 1 1 d . U . . .
C56 C 0.5407(6) 0.1735(5) 0.5361(4) 0.0281(19) Uani 1 1 d . U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O19 Eu1 O4 96.9(3) . . ?
O19 Eu1 O23 91.1(3) . 4_556 ?
O4 Eu1 O23 157.9(3) . 4_556 ?
O19 Eu1 O3 148.0(3) . . ?
O4 Eu1 O3 83.4(4) . . ?
O23 Eu1 O3 100.5(3) 4_556 . ?
O19 Eu1 O22 73.3(3) . . ?
O4 Eu1 O22 81.0(3) . . ?
O23 Eu1 O22 81.6(3) 4_556 . ?
O3 Eu1 O22 137.7(3) . . ?
O19 Eu1 O5 141.3(3) . . ?
O4 Eu1 O5 83.1(3) . . ?
O23 Eu1 O5 77.8(3) 4_556 . ?
O3 Eu1 O5 70.7(3) . . ?
O22 Eu1 O5 68.5(3) . . ?
O19 Eu1 O1 75.0(3) . 1_655 ?
O4 Eu1 O1 128.9(3) . 1_655 ?
O23 Eu1 O1 73.0(3) 4_556 1_655 ?
O3 Eu1 O1 80.0(3) . 1_655 ?
O22 Eu1 O1 138.6(3) . 1_655 ?
O5 Eu1 O1 133.6(3) . 1_655 ?
O19 Eu1 O2 73.3(3) . 1_655 ?
O4 Eu1 O2 77.3(3) . 1_655 ?
O23 Eu1 O2 124.8(3) 4_556 1_655 ?
O3 Eu1 O2 75.6(3) . 1_655 ?
O22 Eu1 O2 137.2(3) . 1_655 ?
O5 Eu1 O2 142.6(3) . 1_655 ?
O1 Eu1 O2 51.9(3) 1_655 1_655 ?
O19 Eu1 C9 71.1(3) . 1_655 ?
O4 Eu1 C9 103.0(3) . 1_655 ?
O23 Eu1 C9 99.1(3) 4_556 1_655 ?
O3 Eu1 C9 77.6(4) . 1_655 ?
O22 Eu1 C9 144.3(3) . 1_655 ?
O5 Eu1 C9 146.9(3) . 1_655 ?
O1 Eu1 C9 26.2(3) 1_655 1_655 ?
O2 Eu1 C9 25.7(3) 1_655 1_655 ?
O19 Eu1 H1O 126.7(15) . . ?
O4 Eu1 H1O 98(2) . . ?
O23 Eu1 H1O 61.6(19) 4_556 . ?
O3 Eu1 H1O 84.7(16) . . ?
O22 Eu1 H1O 59(2) . . ?
O5 Eu1 H1O 19.0(13) . . ?
O1 Eu1 H1O 128(2) 1_655 . ?
O2 Eu1 H1O 160.0(14) 1_655 . ?
C9 Eu1 H1O 151(2) 1_655 . ?
O10 Eu2 O18 156.1(3) 4_455 . ?
O10 Eu2 O7 88.6(3) 4_455 . ?
O18 Eu2 O7 103.3(3) . . ?
O10 Eu2 O9 80.0(3) 4_455 . ?
O18 Eu2 O9 84.2(3) . . ?
O7 Eu2 O9 71.3(3) . . ?
O10 Eu2 O16 89.0(3) 4_455 . ?
O18 Eu2 O16 92.2(4) . . ?
O7 Eu2 O16 146.0(3) . . ?
O9 Eu2 O16 141.2(3) . . ?
O10 Eu2 O17 76.7(3) 4_455 . ?
O18 Eu2 O17 81.2(4) . . ?
O7 Eu2 O17 141.8(3) . . ?
O9 Eu2 O17 71.5(3) . . ?
O16 Eu2 O17 69.8(3) . . ?
O10 Eu2 O14 127.4(3) 4_455 1_455 ?
O18 Eu2 O14 76.3(3) . 1_455 ?
O7 Eu2 O14 74.4(3) . 1_455 ?
O9 Eu2 O14 135.1(3) . 1_455 ?
O16 Eu2 O14 80.3(3) . 1_455 ?
O17 Eu2 O14 141.7(3) . 1_455 ?
O10 Eu2 O15 74.5(3) 4_455 1_455 ?
O18 Eu2 O15 128.4(3) . 1_455 ?
O7 Eu2 O15 74.6(3) . 1_455 ?
O9 Eu2 O15 137.5(3) . 1_455 ?
O16 Eu2 O15 72.1(3) . 1_455 ?
O17 Eu2 O15 132.1(3) . 1_455 ?
O14 Eu2 O15 53.0(3) 1_455 1_455 ?
O10 Eu2 C39 100.8(3) 4_455 1_455 ?
O18 Eu2 C39 102.6(3) . 1_455 ?
O7 Eu2 C39 72.0(3) . 1_455 ?
O9 Eu2 C39 143.2(3) . 1_455 ?
O16 Eu2 C39 75.2(3) . 1_455 ?
O17 Eu2 C39 145.0(3) . 1_455 ?
O14 Eu2 C39 26.6(3) 1_455 1_455 ?
O15 Eu2 C39 26.4(3) 1_455 1_455 ?
O10 Eu2 H4O 79(2) 4_455 . ?
O18 Eu2 H4O 94(3) . . ?
O7 Eu2 H4O 161(3) . . ?
O9 Eu2 H4O 119.5(11) . . ?
O16 Eu2 H4O 22.0(9) . . ?
O17 Eu2 H4O 48.7(14) . . ?
O14 Eu2 H4O 102.0(9) 1_455 . ?
O15 Eu2 H4O 88(2) 1_455 . ?
C39 Eu2 H4O 96.3(13) 1_455 . ?
O12 Zn1 O13 100.5(6) . . ?
O12 Zn1 N9 118.4(6) . . ?
O13 Zn1 N9 104.8(5) . . ?
O12 Zn1 N13 106.5(6) . . ?
O13 Zn1 N13 112.0(5) . . ?
N9 Zn1 N13 113.9(5) . . ?
O12 Zn1 H5O 27.7(9) . . ?
O13 Zn1 H5O 80(3) . . ?
N9 Zn1 H5O 106(4) . . ?
N13 Zn1 H5O 132(2) . . ?
O12 Zn1 H6O 27(3) . . ?
O13 Zn1 H6O 127(3) . . ?
N9 Zn1 H6O 101(6) . . ?
N13 Zn1 H6O 99(6) . . ?
H5O Zn1 H6O 48(3) . . ?
O21 Zn2 O24 121.3(3) . 4_556 ?
O21 Zn2 O20 113.4(4) . . ?
O24 Zn2 O20 112.3(4) 4_556 . ?
O21 Zn2 N4 99.2(3) . 3_655 ?
O24 Zn2 N4 106.9(3) 4_556 3_655 ?
O20 Zn2 N4 100.2(4) . 3_655 ?
O6 Zn3 O8 108.5(4) . . ?
O6 Zn3 O11 109.2(4) . 4_455 ?
O8 Zn3 O11 132.5(3) . 4_455 ?
O6 Zn3 N19 103.0(4) . 3_655 ?
O8 Zn3 N19 103.0(3) . 3_655 ?
O11 Zn3 N19 95.7(4) 4_455 3_655 ?
C1S N1S C3S 128(3) . . ?
C1S N1S C4S 113.4(18) . . ?
C3S N1S C4S 118(3) . . ?
C6 N1 C8 141(2) . . ?
C6 N1 C7 106.9(16) . . ?
C8 N1 C7 112.2(16) . . ?
C5S N2S C7S 130.2(19) . . ?
C5S N2S C8S 107.4(19) . . ?
C7S N2S C8S 122(2) . . ?
C3 N2 C1 141(2) . . ?
C3 N2 C2 101.8(17) . . ?
C1 N2 C2 117.2(16) . . ?
N4 N3 C24 105.0(9) . . ?
C10S N3S C11S 126(2) . . ?
C10S N3S C12S 113(2) . . ?
C11S N3S C12S 121(3) . . ?
N5 N4 N3 109.7(9) . . ?
N5 N4 Zn2 123.2(7) . 3_645 ?
N3 N4 Zn2 126.5(7) . 3_645 ?
C13S N4S C15S 103(2) . . ?
C13S N4S C16S 124(2) . . ?
C15S N4S C16S 133(3) . . ?
N4 N5 N6 108.7(9) . . ?
N5 N6 C24 106.7(9) . . ?
N8 N7 C26 104.4(12) . . ?
N9 N8 N7 109.8(12) . . ?
N8 N9 N10 109.7(11) . . ?
N8 N9 Zn1 118.9(10) . . ?
N10 N9 Zn1 130.5(9) . . ?
C26 N10 N9 104.1(12) . . ?
C27 N11 C30 129(2) . . ?
C27 N11 C29 113(2) . . ?
C30 N11 C29 116.9(17) . . ?
C31 N12 N13 104.5(11) . . ?
N14 N13 N12 111.5(11) . . ?
N14 N13 Zn1 123.1(9) . . ?
N12 N13 Zn1 125.4(9) . . ?
N13 N14 N15 107.5(11) . . ?
C31 N15 N14 106.3(11) . . ?
C40 N16 C43 123(2) . . ?
C40 N16 C42 115.0(18) . . ?
C43 N16 C42 121.5(19) . . ?
C45 N17 C46 127.2(16) . . ?
C45 N17 C47 118.5(13) . . ?
C46 N17 C47 114.2(14) . . ?
N19 N18 C55 105.6(9) . . ?
N20 N19 N18 109.7(9) . . ?
N20 N19 Zn3 127.4(7) . 3_645 ?
N18 N19 Zn3 122.5(7) . 3_645 ?
N19 N20 N21 108.2(9) . . ?
C55 N21 N20 106.1(9) . . ?
C9 O1 Eu1 92.9(7) . 1_455 ?
C9 O2 Eu1 92.1(7) . 1_455 ?
C3 O3 Eu1 159.5(14) . . ?
C6 O4 Eu1 152.7(12) . . ?
Eu1 O5 H1O 104(7) . . ?
Eu1 O5 H2O 128(8) . . ?
H1O O5 H2O 103(3) . . ?
C16 O6 Zn3 122.6(8) . . ?
C16 O7 Eu2 157.2(8) . . ?
C17 O8 Zn3 131.3(7) . . ?
C17 O9 Eu2 146.7(8) . . ?
C25 O10 Eu2 142.7(7) . 4 ?
C25 O11 Zn3 110.8(7) . 4 ?
Zn1 O12 H5O 80(5) . . ?
Zn1 O12 H6O 40(10) . . ?
H5O O12 H6O 103(3) . . ?
C27 O13 Zn1 125.6(11) . . ?
C39 O14 Eu2 92.5(7) . 1_655 ?
C39 O15 Eu2 91.6(7) . 1_655 ?
Eu2 O16 H3O 138(8) . . ?
Eu2 O16 H4O 88(7) . . ?
H3O O16 H4O 104(3) . . ?
C40 O17 Eu2 164.0(13) . . ?
C45 O18 Eu2 141.6(10) . . ?
C38 O19 Eu1 161.4(8) . . ?
C38 O20 Zn2 122.3(8) . . ?
C48 O21 Zn2 132.0(7) . . ?
C48 O22 Eu1 147.7(7) . . ?
C56 O23 Eu1 144.8(7) . 4_456 ?
C56 O24 Zn2 120.8(6) . 4_456 ?
O1S C1S N1S 105(2) . . ?
O1S C1S C2S 155(3) . . ?
N1S C1S C2S 96(2) . . ?
N2 C1 H1A 109.5 . . ?
N2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
N2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C1S C2S H2SA 109.5 . . ?
C1S C2S H2SB 109.5 . . ?
H2SA C2S H2SB 109.5 . . ?
C1S C2S H2SC 109.5 . . ?
H2SA C2S H2SC 109.5 . . ?
H2SB C2S H2SC 109.5 . . ?
N2 C2 H2A 109.5 . . ?
N2 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
N2 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
N1S C3S H3SA 109.5 . . ?
N1S C3S H3SB 109.5 . . ?
H3SA C3S H3SB 109.5 . . ?
N1S C3S H3SC 109.5 . . ?
H3SA C3S H3SC 109.5 . . ?
H3SB C3S H3SC 109.5 . . ?
N2 C3 O3 137(2) . . ?
N2 C3 C4 101.7(17) . . ?
O3 C3 C4 121.4(18) . . ?
N1S C4S H4SA 109.5 . . ?
N1S C4S H4SB 109.5 . . ?
H4SA C4S H4SB 109.5 . . ?
N1S C4S H4SC 109.5 . . ?
H4SA C4S H4SC 109.5 . . ?
H4SB C4S H4SC 109.5 . . ?
C3 C4 H4A 109.5 . . ?
C3 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C3 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
O2S C5S N2S 115(2) . . ?
O2S C5S C6S 147(2) . . ?
N2S C5S C6S 97.9(17) . . ?
C6 C5 H5A 109.5 . . ?
C6 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C6 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C5S C6S H6SA 109.5 . . ?
C5S C6S H6SB 109.5 . . ?
H6SA C6S H6SB 109.5 . . ?
C5S C6S H6SC 109.5 . . ?
H6SA C6S H6SC 109.5 . . ?
H6SB C6S H6SC 109.5 . . ?
O4 C6 N1 134(2) . . ?
O4 C6 C5 123.2(17) . . ?
N1 C6 C5 103.3(17) . . ?
N2S C7S H7SA 109.5 . . ?
N2S C7S H7SB 109.5 . . ?
H7SA C7S H7SB 109.5 . . ?
N2S C7S H7SC 109.5 . . ?
H7SA C7S H7SC 109.5 . . ?
H7SB C7S H7SC 109.5 . . ?
N1 C7 H7A 109.5 . . ?
N1 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
N1 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
N2S C8S H8SA 109.5 . . ?
N2S C8S H8SB 109.5 . . ?
H8SA C8S H8SB 109.5 . . ?
N2S C8S H8SC 109.5 . . ?
H8SA C8S H8SC 109.5 . . ?
H8SB C8S H8SC 109.5 . . ?
N1 C8 H8A 109.5 . . ?
N1 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
N1 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
O2 C9 O1 122.8(11) . . ?
O2 C9 C10 119.0(11) . . ?
O1 C9 C10 118.2(11) . . ?
O2 C9 Eu1 62.1(6) . 1_455 ?
O1 C9 Eu1 60.9(6) . 1_455 ?
C10 C9 Eu1 175.9(9) . 1_455 ?
C10S C9S H9S1 109.5 . . ?
C10S C9S H9S2 109.5 . . ?
H9S1 C9S H9S2 109.5 . . ?
C10S C9S H9S3 109.5 . . ?
H9S1 C9S H9S3 109.5 . . ?
H9S2 C9S H9S3 109.5 . . ?
C11 C10 C14 121.1(11) . . ?
C11 C10 C9 119.0(11) . . ?
C14 C10 C9 119.9(11) . . ?
O3S C10S N3S 117(2) . . ?
O3S C10S C9S 132(3) . . ?
N3S C10S C9S 110(2) . . ?
C10 C11 C12 120.4(12) . . ?
C10 C11 H11 119.8 . . ?
C12 C11 H11 119.8 . . ?
N3S C11S H11A 109.5 . . ?
N3S C11S H11B 109.5 . . ?
H11A C11S H11B 109.5 . . ?
N3S C11S H11C 109.5 . . ?
H11A C11S H11C 109.5 . . ?
H11B C11S H11C 109.5 . . ?
C13 C12 C11 118.0(12) . . ?
C13 C12 C26 121.0(12) . . ?
C11 C12 C26 120.9(12) . . ?
N3S C12S H12A 109.5 . . ?
N3S C12S H12B 109.5 . . ?
H12A C12S H12B 109.5 . . ?
N3S C12S H12C 109.5 . . ?
H12A C12S H12C 109.5 . . ?
H12B C12S H12C 109.5 . . ?
C12 C13 C15 121.7(12) . . ?
C12 C13 H13 119.2 . . ?
C15 C13 H13 119.2 . . ?
O4S C13S N4S 113(3) . . ?
O4S C13S C14S 130(3) . . ?
N4S C13S C14S 109(2) . . ?
C10 C14 C15 119.2(11) . . ?
C10 C14 H14 120.4 . . ?
C15 C14 H14 120.4 . . ?
C13S C14S H14A 109.5 . . ?
C13S C14S H14B 109.5 . . ?
H14A C14S H14B 109.5 . . ?
C13S C14S H14C 109.5 . . ?
H14A C14S H14C 109.5 . . ?
H14B C14S H14C 109.5 . . ?
C13 C15 C14 119.6(11) . . ?
C13 C15 C16 120.1(11) . . ?
C14 C15 C16 120.3(10) . . ?
N4S C15S H15A 109.5 . . ?
N4S C15S H15B 109.5 . . ?
H15A C15S H15B 109.5 . . ?
N4S C15S H15C 109.5 . . ?
H15A C15S H15C 109.5 . . ?
H15B C15S H15C 109.5 . . ?
O6 C16 O7 122.9(11) . . ?
O6 C16 C15 117.4(11) . . ?
O7 C16 C15 119.7(11) . . ?
N4S C16S H16A 109.5 . . ?
N4S C16S H16B 109.5 . . ?
H16A C16S H16B 109.5 . . ?
N4S C16S H16C 109.5 . . ?
H16A C16S H16C 109.5 . . ?
H16B C16S H16C 109.5 . . ?
O9 C17 O8 127.1(10) . . ?
O9 C17 C18 116.7(10) . . ?
O8 C17 C18 116.2(9) . . ?
C19 C18 C23 118.6(10) . . ?
C19 C18 C17 120.2(9) . . ?
C23 C18 C17 121.1(10) . . ?
C20 C19 C18 122.2(10) . . ?
C20 C19 H19 118.9 . . ?
C18 C19 H19 118.9 . . ?
C19 C20 C21 118.8(10) . . ?
C19 C20 C24 121.2(10) . . ?
C21 C20 C24 120.0(10) . . ?
C22 C21 C20 118.9(10) . . ?
C22 C21 H21 120.5 . . ?
C20 C21 H21 120.5 . . ?
C23 C22 C21 121.8(10) . . ?
C23 C22 C25 118.5(10) . . ?
C21 C22 C25 119.7(10) . . ?
C22 C23 C18 119.5(10) . . ?
C22 C23 H23 120.3 . . ?
C18 C23 H23 120.3 . . ?
N6 C24 N3 109.9(9) . . ?
N6 C24 C20 127.0(10) . . ?
N3 C24 C20 123.2(10) . . ?
O10 C25 O11 122.2(10) . . ?
O10 C25 C22 119.9(10) . . ?
O11 C25 C22 117.8(9) . . ?
N10 C26 N7 112.0(12) . . ?
N10 C26 C12 126.3(13) . . ?
N7 C26 C12 121.6(12) . . ?
N11 C27 O13 127(2) . . ?
N11 C27 C28 113(2) . . ?
O13 C27 C28 120.0(17) . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
N11 C29 H29A 109.5 . . ?
N11 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
N11 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
N11 C30 H30A 109.5 . . ?
N11 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
N11 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
N15 C31 N12 110.1(11) . . ?
N15 C31 C32 124.9(12) . . ?
N12 C31 C32 124.9(12) . . ?
C33 C32 C36 117.1(11) . . ?
C33 C32 C31 121.9(12) . . ?
C36 C32 C31 121.0(12) . . ?
C34 C33 C32 121.8(11) . . ?
C34 C33 H33 119.1 . . ?
C32 C33 H33 119.1 . . ?
C33 C34 C35 120.6(11) . . ?
C33 C34 C39 120.3(10) . . ?
C35 C34 C39 119.0(10) . . ?
C34 C35 C37 118.3(11) . . ?
C34 C35 H35 120.9 . . ?
C37 C35 H35 120.9 . . ?
C37 C36 C32 121.5(11) . . ?
C37 C36 H36 119.2 . . ?
C32 C36 H36 119.2 . . ?
C36 C37 C35 120.6(11) . . ?
C36 C37 C38 120.3(10) . . ?
C35 C37 C38 119.1(10) . . ?
O19 C38 O20 124.7(11) . . ?
O19 C38 C37 120.3(10) . . ?
O20 C38 C37 115.0(10) . . ?
O15 C39 O14 122.8(10) . . ?
O15 C39 C34 117.9(10) . . ?
O14 C39 C34 119.2(10) . . ?
O15 C39 Eu2 62.0(6) . 1_655 ?
O14 C39 Eu2 60.9(6) . 1_655 ?
C34 C39 Eu2 179.6(8) . 1_655 ?
O17 C40 N16 128(2) . . ?
O17 C40 C41 117.1(17) . . ?
N16 C40 C41 115.4(16) . . ?
C40 C41 H41A 109.5 . . ?
C40 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
C40 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
N16 C42 H42A 109.5 . . ?
N16 C42 H42B 109.5 . . ?
H42A C42 H42B 109.5 . . ?
N16 C42 H42C 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
N16 C43 H43A 109.5 . . ?
N16 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
N16 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C45 C44 H44A 109.5 . . ?
C45 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C45 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
N17 C45 O18 121.3(15) . . ?
N17 C45 C44 118.7(14) . . ?
O18 C45 C44 119.9(13) . . ?
N17 C46 H46A 109.5 . . ?
N17 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
N17 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
N17 C47 H47A 109.5 . . ?
N17 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
N17 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
O22 C48 O21 126.2(10) . . ?
O22 C48 C49 119.3(10) . . ?
O21 C48 C49 114.4(9) . . ?
C50 C49 C54 119.0(10) . . ?
C50 C49 C48 122.2(10) . . ?
C54 C49 C48 118.7(9) . . ?
C51 C50 C49 119.6(10) . . ?
C51 C50 H50 120.2 . . ?
C49 C50 H50 120.2 . . ?
C50 C51 C52 121.4(10) . . ?
C50 C51 C56 120.2(10) . . ?
C52 C51 C56 118.4(10) . . ?
C53 C52 C51 119.1(11) . . ?
C53 C52 H52 120.5 . . ?
C51 C52 H52 120.5 . . ?
C52 C53 C54 120.4(10) . . ?
C52 C53 C55 119.6(10) . . ?
C54 C53 C55 120.0(10) . . ?
C53 C54 C49 120.2(10) . . ?
C53 C54 H54 119.9 . . ?
C49 C54 H54 119.9 . . ?
N21 C55 N18 110.3(10) . . ?
N21 C55 C53 124.6(10) . . ?
N18 C55 C53 125.1(10) . . ?
O23 C56 O24 124.5(9) . . ?
O23 C56 C51 119.1(9) . . ?
O24 C56 C51 116.3(9) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O19 2.336(8) . ?
Eu1 O4 2.337(9) . ?
Eu1 O23 2.339(7) 4_556 ?
Eu1 O3 2.349(9) . ?
Eu1 O22 2.406(7) . ?
Eu1 O5 2.448(8) . ?
Eu1 O1 2.466(8) 1_655 ?
Eu1 O2 2.493(8) 1_655 ?
Eu1 C9 2.818(12) 1_655 ?
Eu1 H1O 2.83(10) . ?
Eu2 O10 2.328(7) 4_455 ?
Eu2 O18 2.334(8) . ?
Eu2 O7 2.367(8) . ?
Eu2 O9 2.375(7) . ?
Eu2 O16 2.389(8) . ?
Eu2 O17 2.416(10) . ?
Eu2 O14 2.449(8) 1_455 ?
Eu2 O15 2.472(8) 1_455 ?
Eu2 C39 2.800(11) 1_455 ?
Eu2 H4O 2.54(11) . ?
Zn1 O12 1.944(12) . ?
Zn1 O13 1.951(12) . ?
Zn1 N9 1.965(12) . ?
Zn1 N13 1.969(12) . ?
Zn1 H5O 2.02(8) . ?
Zn1 H6O 1.36(17) . ?
Zn2 O21 1.910(8) . ?
Zn2 O24 1.938(8) 4_556 ?
Zn2 O20 1.944(8) . ?
Zn2 N4 2.001(9) 3_655 ?
Zn3 O6 1.940(9) . ?
Zn3 O8 1.948(8) . ?
Zn3 O11 1.978(7) 4_455 ?
Zn3 N19 2.011(9) 3_655 ?
N1S C1S 1.472(14) . ?
N1S C3S 1.493(14) . ?
N1S C4S 1.505(13) . ?
N1 C6 1.20(2) . ?
N1 C8 1.42(2) . ?
N1 C7 1.58(2) . ?
N2S C5S 1.432(13) . ?
N2S C7S 1.476(13) . ?
N2S C8S 1.503(13) . ?
N2 C3 1.16(2) . ?
N2 C1 1.44(2) . ?
N2 C2 1.71(3) . ?
N3 N4 1.336(12) . ?
N3 C24 1.339(13) . ?
N3S C10S 1.476(14) . ?
N3S C11S 1.490(13) . ?
N3S C12S 1.494(13) . ?
N4 N5 1.315(12) . ?
N4 Zn2 2.001(9) 3_645 ?
N4S C13S 1.465(14) . ?
N4S C15S 1.470(14) . ?
N4S C16S 1.490(13) . ?
N5 N6 1.316(13) . ?
N6 C24 1.334(14) . ?
N7 N8 1.322(16) . ?
N7 C26 1.341(18) . ?
N8 N9 1.317(17) . ?
N9 N10 1.337(16) . ?
N10 C26 1.329(17) . ?
N11 C27 1.15(2) . ?
N11 C30 1.49(2) . ?
N11 C29 1.59(3) . ?
N12 C31 1.331(16) . ?
N12 N13 1.353(15) . ?
N13 N14 1.273(16) . ?
N14 N15 1.367(15) . ?
N15 C31 1.328(17) . ?
N16 C40 1.30(2) . ?
N16 C43 1.45(2) . ?
N16 C42 1.51(3) . ?
N17 C45 1.218(17) . ?
N17 C46 1.441(18) . ?
N17 C47 1.48(2) . ?
N18 N19 1.326(13) . ?
N18 C55 1.328(14) . ?
N19 N20 1.311(13) . ?
N19 Zn3 2.011(9) 3_645 ?
N20 N21 1.336(13) . ?
N21 C55 1.323(15) . ?
O1 C9 1.246(14) . ?
O1 Eu1 2.466(8) 1_455 ?
O1S C1S 1.194(13) . ?
O2 C9 1.224(14) . ?
O2 Eu1 2.494(8) 1_455 ?
O2S C5S 1.179(13) . ?
O3S C10S 1.194(13) . ?
O3 C3 1.204(18) . ?
O4S C13S 1.212(13) . ?
O4 C6 1.188(18) . ?
O5 H1O 0.948(14) . ?
O5 H2O 0.952(14) . ?
O6 C16 1.249(14) . ?
O7 C16 1.260(14) . ?
O8 C17 1.258(13) . ?
O9 C17 1.236(13) . ?
O10 C25 1.245(12) . ?
O10 Eu2 2.328(7) 4 ?
O11 C25 1.256(12) . ?
O11 Zn3 1.978(7) 4 ?
O12 H5O 0.952(14) . ?
O12 H6O 0.958(14) . ?
O13 C27 1.34(2) . ?
O14 C39 1.256(13) . ?
O14 Eu2 2.449(8) 1_655 ?
O15 C39 1.248(13) . ?
O15 Eu2 2.473(8) 1_655 ?
O16 H3O 0.952(14) . ?
O16 H4O 0.952(14) . ?
O17 C40 1.228(18) . ?
O18 C45 1.301(15) . ?
O19 C38 1.258(13) . ?
O20 C38 1.262(13) . ?
O21 C48 1.275(13) . ?
O22 C48 1.230(13) . ?
O23 C56 1.235(12) . ?
O23 Eu1 2.339(7) 4_456 ?
O24 C56 1.264(12) . ?
O24 Zn2 1.938(8) 4_456 ?
C1S C2S 1.528(14) . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C2S H2SA 0.9600 . ?
C2S H2SB 0.9600 . ?
C2S H2SC 0.9600 . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C3S H3SA 0.9600 . ?
C3S H3SB 0.9600 . ?
C3S H3SC 0.9600 . ?
C3 C4 1.56(3) . ?
C4S H4SA 0.9600 . ?
C4S H4SB 0.9600 . ?
C4S H4SC 0.9600 . ?
C4 H4A 0.9600 . ?
C4 H4B 0.9600 . ?
C4 H4C 0.9600 . ?
C5S C6S 1.519(13) . ?
C5 C6 1.64(3) . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C6S H6SA 0.9600 . ?
C6S H6SB 0.9600 . ?
C6S H6SC 0.9600 . ?
C7S H7SA 0.9600 . ?
C7S H7SB 0.9600 . ?
C7S H7SC 0.9600 . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9600 . ?
C7 H7C 0.9600 . ?
C8S H8SA 0.9600 . ?
C8S H8SB 0.9600 . ?
C8S H8SC 0.9600 . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 C10 1.528(16) . ?
C9 Eu1 2.818(12) 1_455 ?
C9S C10S 1.529(14) . ?
C9S H9S1 0.9600 . ?
C9S H9S2 0.9600 . ?
C9S H9S3 0.9600 . ?
C10 C11 1.368(17) . ?
C10 C14 1.386(16) . ?
C11 C12 1.418(18) . ?
C11 H11 0.9300 . ?
C11S H11A 0.9600 . ?
C11S H11B 0.9600 . ?
C11S H11C 0.9600 . ?
C12 C13 1.375(18) . ?
C12 C26 1.463(18) . ?
C12S H12A 0.9600 . ?
C12S H12B 0.9600 . ?
C12S H12C 0.9600 . ?
C13 C15 1.392(16) . ?
C13 H13 0.9300 . ?
C13S C14S 1.541(14) . ?
C14 C15 1.395(16) . ?
C14 H14 0.9300 . ?
C14S H14A 0.9600 . ?
C14S H14B 0.9600 . ?
C14S H14C 0.9600 . ?
C15 C16 1.473(17) . ?
C15S H15A 0.9600 . ?
C15S H15B 0.9600 . ?
C15S H15C 0.9600 . ?
C16S H16A 0.9600 . ?
C16S H16B 0.9600 . ?
C16S H16C 0.9600 . ?
C17 C18 1.512(15) . ?
C18 C19 1.390(16) . ?
C18 C23 1.394(14) . ?
C19 C20 1.364(15) . ?
C19 H19 0.9300 . ?
C20 C21 1.406(14) . ?
C20 C24 1.458(15) . ?
C21 C22 1.385(15) . ?
C21 H21 0.9300 . ?
C22 C23 1.362(15) . ?
C22 C25 1.507(14) . ?
C23 H23 0.9300 . ?
C27 C28 1.59(3) . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
C31 C32 1.419(17) . ?
C32 C33 1.411(17) . ?
C32 C36 1.414(18) . ?
C33 C34 1.380(16) . ?
C33 H33 0.9300 . ?
C34 C35 1.410(16) . ?
C34 C39 1.497(16) . ?
C35 C37 1.412(15) . ?
C35 H35 0.9300 . ?
C36 C37 1.383(16) . ?
C36 H36 0.9300 . ?
C37 C38 1.489(16) . ?
C39 Eu2 2.800(11) 1_655 ?
C40 C41 1.63(2) . ?
C41 H41A 0.9600 . ?
C41 H41B 0.9600 . ?
C41 H41C 0.9600 . ?
C42 H42A 0.9600 . ?
C42 H42B 0.9600 . ?
C42 H42C 0.9600 . ?
C43 H43A 0.9600 . ?
C43 H43B 0.9600 . ?
C43 H43C 0.9600 . ?
C44 C45 1.48(2) . ?
C44 H44A 0.9600 . ?
C44 H44B 0.9600 . ?
C44 H44C 0.9600 . ?
C46 H46A 0.9600 . ?
C46 H46B 0.9600 . ?
C46 H46C 0.9600 . ?
C47 H47A 0.9600 . ?
C47 H47B 0.9600 . ?
C47 H47C 0.9600 . ?
C48 C49 1.492(15) . ?
C49 C50 1.384(14) . ?
C49 C54 1.406(15) . ?
C50 C51 1.368(15) . ?
C50 H50 0.9300 . ?
C51 C52 1.391(15) . ?
C51 C56 1.525(14) . ?
C52 C53 1.370(15) . ?
C52 H52 0.9300 . ?
C53 C54 1.377(15) . ?
C53 C55 1.472(15) . ?
C54 H54 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C24 N3 N4 N5 0.6(13) . . . . ?
C24 N3 N4 Zn2 171.7(8) . . . 3_645 ?
N3 N4 N5 N6 -0.6(14) . . . . ?
Zn2 N4 N5 N6 -172.1(8) 3_645 . . . ?
N4 N5 N6 C24 0.4(13) . . . . ?
C26 N7 N8 N9 0.1(18) . . . . ?
N7 N8 N9 N10 0.3(19) . . . . ?
N7 N8 N9 Zn1 -170.2(10) . . . . ?
N8 N9 N10 C26 -0.6(17) . . . . ?
Zn1 N9 N10 C26 168.4(11) . . . . ?
C31 N12 N13 N14 -3.1(16) . . . . ?
C31 N12 N13 Zn1 175.4(9) . . . . ?
N12 N13 N14 N15 3.6(16) . . . . ?
Zn1 N13 N14 N15 -174.9(9) . . . . ?
N13 N14 N15 C31 -2.6(16) . . . . ?
C55 N18 N19 N20 -3.3(14) . . . . ?
C55 N18 N19 Zn3 -176.1(8) . . . 3_645 ?
N18 N19 N20 N21 3.6(14) . . . . ?
Zn3 N19 N20 N21 175.9(9) 3_645 . . . ?
N19 N20 N21 C55 -2.4(15) . . . . ?
C3S N1S C1S O1S 175(3) . . . . ?
C4S N1S C1S O1S -8(4) . . . . ?
C3S N1S C1S C2S 7(5) . . . . ?
C4S N1S C1S C2S -176(3) . . . . ?
C1 N2 C3 O3 -178(2) . . . . ?
C2 N2 C3 O3 5(3) . . . . ?
C1 N2 C3 C4 0(3) . . . . ?
C2 N2 C3 C4 -176.5(14) . . . . ?
Eu1 O3 C3 N2 164(2) . . . . ?
Eu1 O3 C3 C4 -14(4) . . . . ?
C7S N2S C5S O2S 179(2) . . . . ?
C8S N2S C5S O2S -2(3) . . . . ?
C7S N2S C5S C6S -3(3) . . . . ?
C8S N2S C5S C6S 176.1(18) . . . . ?
Eu1 O4 C6 N1 117(3) . . . . ?
Eu1 O4 C6 C5 -60(4) . . . . ?
C8 N1 C6 O4 177(3) . . . . ?
C7 N1 C6 O4 5(4) . . . . ?
C8 N1 C6 C5 -6(4) . . . . ?
C7 N1 C6 C5 -177.3(16) . . . . ?
Eu1 O2 C9 O1 5.3(13) 1_455 . . . ?
Eu1 O2 C9 C10 -175.5(10) 1_455 . . . ?
Eu1 O1 C9 O2 -5.3(13) 1_455 . . . ?
Eu1 O1 C9 C10 175.5(9) 1_455 . . . ?
O2 C9 C10 C11 -165.2(12) . . . . ?
O1 C9 C10 C11 14.1(17) . . . . ?
O2 C9 C10 C14 16.2(17) . . . . ?
O1 C9 C10 C14 -164.6(12) . . . . ?
C11S N3S C10S O3S -179(3) . . . . ?
C12S N3S C10S O3S 5(4) . . . . ?
C11S N3S C10S C9S 6(4) . . . . ?
C12S N3S C10S C9S -170(2) . . . . ?
C14 C10 C11 C12 -2(2) . . . . ?
C9 C10 C11 C12 179.6(12) . . . . ?
C10 C11 C12 C13 2(2) . . . . ?
C10 C11 C12 C26 179.8(12) . . . . ?
C11 C12 C13 C15 -1(2) . . . . ?
C26 C12 C13 C15 -178.6(12) . . . . ?
C15S N4S C13S O4S -13(4) . . . . ?
C16S N4S C13S O4S 171(3) . . . . ?
C15S N4S C13S C14S -166(3) . . . . ?
C16S N4S C13S C14S 18(5) . . . . ?
C11 C10 C14 C15 0.1(19) . . . . ?
C9 C10 C14 C15 178.8(11) . . . . ?
C12 C13 C15 C14 -0.6(19) . . . . ?
C12 C13 C15 C16 175.6(12) . . . . ?
C10 C14 C15 C13 1.1(18) . . . . ?
C10 C14 C15 C16 -175.2(11) . . . . ?
Zn3 O6 C16 O7 -4.1(16) . . . . ?
Zn3 O6 C16 C15 177.9(8) . . . . ?
Eu2 O7 C16 O6 -37(3) . . . . ?
Eu2 O7 C16 C15 140.8(17) . . . . ?
C13 C15 C16 O6 -6.3(17) . . . . ?
C14 C15 C16 O6 169.9(11) . . . . ?
C13 C15 C16 O7 175.7(11) . . . . ?
C14 C15 C16 O7 -8.1(17) . . . . ?
Eu2 O9 C17 O8 0(2) . . . . ?
Eu2 O9 C17 C18 178.8(10) . . . . ?
Zn3 O8 C17 O9 14.8(19) . . . . ?
Zn3 O8 C17 C18 -163.5(7) . . . . ?
O9 C17 C18 C19 8.5(17) . . . . ?
O8 C17 C18 C19 -173.1(11) . . . . ?
O9 C17 C18 C23 -173.2(11) . . . . ?
O8 C17 C18 C23 5.3(16) . . . . ?
C23 C18 C19 C20 0.0(19) . . . . ?
C17 C18 C19 C20 178.3(11) . . . . ?
C18 C19 C20 C21 2.0(19) . . . . ?
C18 C19 C20 C24 -176.5(11) . . . . ?
C19 C20 C21 C22 0.0(18) . . . . ?
C24 C20 C21 C22 178.5(11) . . . . ?
C20 C21 C22 C23 -4.1(18) . . . . ?
C20 C21 C22 C25 175.7(11) . . . . ?
C21 C22 C23 C18 6.1(18) . . . . ?
C25 C22 C23 C18 -173.7(10) . . . . ?
C19 C18 C23 C22 -3.9(17) . . . . ?
C17 C18 C23 C22 177.7(11) . . . . ?
N5 N6 C24 N3 0.0(14) . . . . ?
N5 N6 C24 C20 179.2(12) . . . . ?
N4 N3 C24 N6 -0.4(14) . . . . ?
N4 N3 C24 C20 -179.6(11) . . . . ?
C19 C20 C24 N6 -178.9(12) . . . . ?
C21 C20 C24 N6 3(2) . . . . ?
C19 C20 C24 N3 0(2) . . . . ?
C21 C20 C24 N3 -178.3(11) . . . . ?
Eu2 O10 C25 O11 90.7(15) 4 . . . ?
Eu2 O10 C25 C22 -92.9(14) 4 . . . ?
Zn3 O11 C25 O10 1.1(14) 4 . . . ?
Zn3 O11 C25 C22 -175.4(8) 4 . . . ?
C23 C22 C25 O10 -4.8(17) . . . . ?
C21 C22 C25 O10 175.4(11) . . . . ?
C23 C22 C25 O11 171.8(11) . . . . ?
C21 C22 C25 O11 -8.0(16) . . . . ?
N9 N10 C26 N7 0.7(17) . . . . ?
N9 N10 C26 C12 -177.5(14) . . . . ?
N8 N7 C26 N10 -0.5(18) . . . . ?
N8 N7 C26 C12 177.8(14) . . . . ?
C13 C12 C26 N10 -35(2) . . . . ?
C11 C12 C26 N10 147.3(15) . . . . ?
C13 C12 C26 N7 146.9(15) . . . . ?
C11 C12 C26 N7 -31(2) . . . . ?
C30 N11 C27 O13 170.7(18) . . . . ?
C29 N11 C27 O13 1(3) . . . . ?
C30 N11 C27 C28 -9(3) . . . . ?
C29 N11 C27 C28 -179.1(16) . . . . ?
Zn1 O13 C27 N11 -116(2) . . . . ?
Zn1 O13 C27 C28 64(2) . . . . ?
N14 N15 C31 N12 0.8(16) . . . . ?
N14 N15 C31 C32 178.7(13) . . . . ?
N13 N12 C31 N15 1.3(16) . . . . ?
N13 N12 C31 C32 -176.7(12) . . . . ?
N15 C31 C32 C33 1(2) . . . . ?
N12 C31 C32 C33 179.0(13) . . . . ?
N15 C31 C32 C36 -177.5(13) . . . . ?
N12 C31 C32 C36 0(2) . . . . ?
C36 C32 C33 C34 2.4(19) . . . . ?
C31 C32 C33 C34 -176.5(12) . . . . ?
C32 C33 C34 C35 1.0(19) . . . . ?
C32 C33 C34 C39 177.2(11) . . . . ?
C33 C34 C35 C37 -3.4(18) . . . . ?
C39 C34 C35 C37 -179.7(11) . . . . ?
C33 C32 C36 C37 -3.6(18) . . . . ?
C31 C32 C36 C37 175.4(12) . . . . ?
C32 C36 C37 C35 1.2(19) . . . . ?
C32 C36 C37 C38 -179.9(11) . . . . ?
C34 C35 C37 C36 2.3(18) . . . . ?
C34 C35 C37 C38 -176.6(11) . . . . ?
Eu1 O19 C38 O20 -25(3) . . . . ?
Eu1 O19 C38 C37 154.9(19) . . . . ?
Zn2 O20 C38 O19 -2.3(17) . . . . ?
Zn2 O20 C38 C37 177.6(7) . . . . ?
C36 C37 C38 O19 170.1(11) . . . . ?
C35 C37 C38 O19 -11.0(17) . . . . ?
C36 C37 C38 O20 -9.8(17) . . . . ?
C35 C37 C38 O20 169.1(11) . . . . ?
Eu2 O15 C39 O14 -2.7(11) 1_655 . . . ?
Eu2 O15 C39 C34 -179.6(9) 1_655 . . . ?
Eu2 O14 C39 O15 2.7(11) 1_655 . . . ?
Eu2 O14 C39 C34 179.6(9) 1_655 . . . ?
C33 C34 C39 O15 26.9(16) . . . . ?
C35 C34 C39 O15 -156.8(11) . . . . ?
C33 C34 C39 O14 -150.1(11) . . . . ?
C35 C34 C39 O14 26.2(16) . . . . ?
Eu2 O17 C40 N16 -154(3) . . . . ?
Eu2 O17 C40 C41 26(5) . . . . ?
C43 N16 C40 O17 -169.1(19) . . . . ?
C42 N16 C40 O17 3(3) . . . . ?
C43 N16 C40 C41 11(3) . . . . ?
C42 N16 C40 C41 -176.3(16) . . . . ?
C46 N17 C45 O18 -179.7(17) . . . . ?
C47 N17 C45 O18 -3(3) . . . . ?
C46 N17 C45 C44 1(3) . . . . ?
C47 N17 C45 C44 177.8(16) . . . . ?
Eu2 O18 C45 N17 160.8(12) . . . . ?
Eu2 O18 C45 C44 -20(3) . . . . ?
Eu1 O22 C48 O21 19(2) . . . . ?
Eu1 O22 C48 C49 -164.6(9) . . . . ?
Zn2 O21 C48 O22 11.5(18) . . . . ?
Zn2 O21 C48 C49 -165.3(8) . . . . ?
O22 C48 C49 C50 -164.7(11) . . . . ?
O21 C48 C49 C50 12.3(16) . . . . ?
O22 C48 C49 C54 18.1(16) . . . . ?
O21 C48 C49 C54 -164.8(11) . . . . ?
C54 C49 C50 C51 -4.8(18) . . . . ?
C48 C49 C50 C51 178.0(11) . . . . ?
C49 C50 C51 C52 5.0(18) . . . . ?
C49 C50 C51 C56 -175.7(10) . . . . ?
C50 C51 C52 C53 -1.3(19) . . . . ?
C56 C51 C52 C53 179.4(11) . . . . ?
C51 C52 C53 C54 -2.5(19) . . . . ?
C51 C52 C53 C55 178.9(11) . . . . ?
C52 C53 C54 C49 3(2) . . . . ?
C55 C53 C54 C49 -178.8(12) . . . . ?
C50 C49 C54 C53 1.2(18) . . . . ?
C48 C49 C54 C53 178.4(11) . . . . ?
N20 N21 C55 N18 0.3(15) . . . . ?
N20 N21 C55 C53 -177.4(12) . . . . ?
N19 N18 C55 N21 1.8(15) . . . . ?
N19 N18 C55 C53 179.5(12) . . . . ?
C52 C53 C55 N21 -25(2) . . . . ?
C54 C53 C55 N21 156.1(13) . . . . ?
C52 C53 C55 N18 157.3(12) . . . . ?
C54 C53 C55 N18 -21(2) . . . . ?
Eu1 O23 C56 O24 69.9(18) 4_456 . . . ?
Eu1 O23 C56 C51 -114.2(12) 4_456 . . . ?
Zn2 O24 C56 O23 1.7(16) 4_456 . . . ?
Zn2 O24 C56 C51 -174.2(7) 4_456 . . . ?
C50 C51 C56 O23 -15.0(17) . . . . ?
C52 C51 C56 O23 164.3(11) . . . . ?
C50 C51 C56 O24 161.2(11) . . . . ?
C52 C51 C56 O24 -19.5(16) . . . . ?
