#------------------------------------------------------------------------------
#$Date: 2021-09-06 14:29:58 +0300 (Mon, 06 Sep 2021) $
#$Revision: 268812 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/79/7707933.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7707933
loop_
_publ_author_name
'Abeynayake, Niroshani S.'
'Zamora-Moreno, Julio'
'Gorla, Saidulu'
'Donnadieu, Bruno'
'Muñoz-Hernández, Miguel A'
'Montiel-Palma, Virginia'
_publ_section_title
;
 14-Electron Rh and Ir silylphosphine complexes and their catalytic
 activity in alkene functionalization with hydrosilanes.
;
_journal_issue                   34
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11783
_journal_page_last               11792
_journal_paper_doi               10.1039/d1dt00677k
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C64 H90 I2 P2 Rh2 Si4'
_chemical_formula_sum            'C64 H90 I2 P2 Rh2 Si4'
_chemical_formula_weight         1493.27
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-09-08 deposited with the CCDC.	2021-07-27 downloaded from the CCDC.
;
_cell_angle_alpha                93.3520(10)
_cell_angle_beta                 90.1870(10)
_cell_angle_gamma                98.870(2)
_cell_formula_units_Z            2
_cell_length_a                   9.5705(3)
_cell_length_b                   17.6043(6)
_cell_length_c                   19.2246(7)
_cell_measurement_reflns_used    2194
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      72.490
_cell_measurement_theta_min      2.302
_cell_volume                     3194.54(19)
_computing_cell_refinement       'APEX3 v2019.1.0'
_computing_data_collection       'APEX3 v2019.1.0'
_computing_data_reduction        'Saint, APEX v2019.1.0.'
_computing_molecular_graphics    'Mercury V.4.2.0,POV-Ray v 3.7'
_computing_publication_material  'APEX3 v2018.7.2'
_computing_structure_refinement  SHELXTL-2018/3
_computing_structure_solution    SHELXT
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'Bruker AXS D8 Venture '
_diffrn_measurement_method       'profile data from θ/2θ scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0358
_diffrn_reflns_av_unetI/netI     0.0256
_diffrn_reflns_Laue_measured_fraction_full 0.990
_diffrn_reflns_Laue_measured_fraction_max 0.985
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            68424
_diffrn_reflns_point_group_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.985
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         72.490
_diffrn_reflns_theta_min         2.302
_exptl_absorpt_coefficient_mu    13.238
_exptl_absorpt_correction_T_max  0.345
_exptl_absorpt_correction_T_min  0.120
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   Sadabs
_exptl_crystal_colour            'orange yellow'
_exptl_crystal_density_diffrn    1.552
_exptl_crystal_description       'prism frag'
_exptl_crystal_F_000             1512
_exptl_crystal_size_max          0.278
_exptl_crystal_size_mid          0.134
_exptl_crystal_size_min          0.102
_refine_diff_density_max         0.841
_refine_diff_density_min         -0.931
_refine_diff_density_rms         0.090
_refine_ls_extinction_coef       0.000345(18)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.105
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     684
_refine_ls_number_reflns         12489
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.105
_refine_ls_R_factor_all          0.0252
_refine_ls_R_factor_gt           0.0236
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0126P)²+5.3898P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0543
_refine_ls_wR_factor_ref         0.0553
_reflns_Friedel_coverage         0.000
_reflns_number_gt                11961
_reflns_number_total             12489
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1dt00677k2.cif
_cod_data_source_block           Rh2
_cod_depositor_comments
'Adding full bibliography for 7707933--7707936.cif.'
_cod_database_code               7707933
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.120
_shelx_estimated_absorpt_t_max   0.345
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1A Rh 0.41185(2) 0.79567(2) 0.02896(2) 0.01213(5) Uani 1 1 d . . . . .
I1A I 0.25686(2) 0.84179(2) -0.06659(2) 0.02170(5) Uani 1 1 d . . . . .
P1A P 0.54391(6) 0.79561(3) 0.12296(3) 0.01163(12) Uani 1 1 d . . . . .
Si1A Si 0.60086(7) 0.76831(4) -0.03736(3) 0.01397(13) Uani 1 1 d . . . . .
Si2A Si 0.31489(7) 0.67237(4) 0.05241(3) 0.01522(13) Uani 1 1 d . . . . .
C1A C 0.7629(3) 0.75963(15) 0.01814(13) 0.0165(5) Uani 1 1 d . . . . .
H1A1 H 0.740909 0.714771 0.047152 0.020 Uiso 1 1 calc R U . . .
H1A2 H 0.842001 0.750602 -0.012763 0.020 Uiso 1 1 calc R U . . .
C2A C 0.8075(3) 0.83093(15) 0.06447(13) 0.0168(5) Uani 1 1 d . . . . .
C3A C 0.9386(3) 0.87617(17) 0.05751(14) 0.0228(6) Uani 1 1 d . . . . .
H3A H 1.003312 0.859825 0.024600 0.027 Uiso 1 1 calc R U . . .
C4A C 0.9776(3) 0.94441(18) 0.09725(16) 0.0285(6) Uani 1 1 d . . . . .
H4A H 1.067562 0.974391 0.090946 0.034 Uiso 1 1 calc R U . . .
C5A C 0.8856(3) 0.96915(17) 0.14630(15) 0.0266(6) Uani 1 1 d . . . . .
H5A H 0.912040 1.015971 0.173576 0.032 Uiso 1 1 calc R U . . .
C6A C 0.7548(3) 0.92478(15) 0.15501(13) 0.0197(5) Uani 1 1 d . . . . .
H6A H 0.691405 0.941353 0.188498 0.024 Uiso 1 1 calc R U . . .
C7A C 0.7150(3) 0.85575(14) 0.11492(12) 0.0146(5) Uani 1 1 d . . . . .
C8A C 0.5970(3) 0.71053(14) 0.16043(12) 0.0132(5) Uani 1 1 d . . . . .
C9A C 0.7006(3) 0.72612(15) 0.21299(12) 0.0165(5) Uani 1 1 d . . . . .
H9A H 0.737467 0.778114 0.226610 0.020 Uiso 1 1 calc R U . . .
C10A C 0.7505(3) 0.66760(16) 0.24548(13) 0.0208(5) Uani 1 1 d . . . . .
H10A H 0.822240 0.679238 0.280430 0.025 Uiso 1 1 calc R U . . .
C11A C 0.6951(3) 0.59187(16) 0.22675(14) 0.0229(6) Uani 1 1 d . . . . .
H11A H 0.726341 0.551226 0.249965 0.027 Uiso 1 1 calc R U . . .
C12A C 0.5943(3) 0.57547(15) 0.17414(14) 0.0209(5) Uani 1 1 d . . . . .
H12A H 0.556823 0.523229 0.161811 0.025 Uiso 1 1 calc R U . . .
C13A C 0.5454(3) 0.63399(15) 0.13828(12) 0.0162(5) Uani 1 1 d . . . . .
C14A C 0.4516(3) 0.61017(15) 0.07505(13) 0.0186(5) Uani 1 1 d . . . . .
H14A H 0.401055 0.557602 0.081288 0.022 Uiso 1 1 calc R U . . .
H14B H 0.513626 0.606674 0.034250 0.022 Uiso 1 1 calc R U . . .
C15A C 0.4584(3) 0.84388(15) 0.19433(12) 0.0151(5) Uani 1 1 d . . . . .
C16A C 0.4080(3) 0.91190(17) 0.17994(14) 0.0241(6) Uani 1 1 d . . . . .
H16A H 0.419195 0.930746 0.134664 0.029 Uiso 1 1 calc R U . . .
C17A C 0.3417(3) 0.95220(18) 0.23096(15) 0.0283(6) Uani 1 1 d . . . . .
H17A H 0.308938 0.998649 0.220785 0.034 Uiso 1 1 calc R U . . .
C18A C 0.3236(3) 0.92431(17) 0.29678(14) 0.0246(6) Uani 1 1 d . . . . .
H18A H 0.278525 0.951744 0.331891 0.030 Uiso 1 1 calc R U . . .
C19A C 0.3708(3) 0.85680(17) 0.31133(13) 0.0217(6) Uani 1 1 d . . . . .
H19A H 0.357254 0.837595 0.356376 0.026 Uiso 1 1 calc R U . . .
C20A C 0.4385(3) 0.81642(15) 0.26041(13) 0.0169(5) Uani 1 1 d . . . . .
H20A H 0.471114 0.770044 0.270973 0.020 Uiso 1 1 calc R U . . .
C21A C 0.6513(3) 0.85657(16) -0.09027(13) 0.0207(5) Uani 1 1 d . . . . .
H21A H 0.577335 0.854136 -0.127540 0.025 Uiso 1 1 calc R U . . .
C22A C 0.6558(3) 0.93426(16) -0.04901(15) 0.0246(6) Uani 1 1 d . . . . .
H22A H 0.726740 0.938728 -0.011527 0.037 Uiso 1 1 calc R U . . .
H22B H 0.562726 0.937453 -0.028918 0.037 Uiso 1 1 calc R U . . .
H22C H 0.680693 0.976180 -0.080230 0.037 Uiso 1 1 calc R U . . .
C23A C 0.7930(3) 0.85330(18) -0.12727(15) 0.0278(6) Uani 1 1 d . . . . .
H23A H 0.811053 0.895269 -0.158951 0.042 Uiso 1 1 calc R U . . .
H23B H 0.788641 0.803783 -0.153912 0.042 Uiso 1 1 calc R U . . .
H23C H 0.869558 0.858787 -0.092482 0.042 Uiso 1 1 calc R U . . .
C24A C 0.5604(3) 0.67713(16) -0.09783(13) 0.0195(5) Uani 1 1 d . . . . .
H24A H 0.485818 0.641499 -0.074571 0.023 Uiso 1 1 calc R U . . .
C25A C 0.6881(3) 0.63430(17) -0.10776(14) 0.0238(6) Uani 1 1 d . . . . .
H25A H 0.660807 0.587757 -0.138279 0.036 Uiso 1 1 calc R U . . .
H25B H 0.719160 0.619933 -0.062402 0.036 Uiso 1 1 calc R U . . .
H25C H 0.765513 0.667920 -0.128937 0.036 Uiso 1 1 calc R U . . .
C26A C 0.4982(3) 0.69245(18) -0.16844(13) 0.0249(6) Uani 1 1 d . . . . .
H26A H 0.569394 0.725589 -0.194064 0.037 Uiso 1 1 calc R U . . .
H26B H 0.415121 0.718066 -0.160846 0.037 Uiso 1 1 calc R U . . .
H26C H 0.470356 0.643484 -0.195493 0.037 Uiso 1 1 calc R U . . .
C27A C 0.2039(3) 0.67623(16) 0.13437(13) 0.0209(5) Uani 1 1 d . . . . .
H27A H 0.272853 0.691194 0.173827 0.025 Uiso 1 1 calc R U . . .
C28A C 0.1049(3) 0.73694(19) 0.13725(16) 0.0296(6) Uani 1 1 d . . . . .
H28A H 0.028534 0.722173 0.102698 0.044 Uiso 1 1 calc R U . . .
H28B H 0.158284 0.787050 0.126995 0.044 Uiso 1 1 calc R U . . .
H28C H 0.064446 0.740404 0.183885 0.044 Uiso 1 1 calc R U . . .
C29A C 0.1230(3) 0.59634(19) 0.14991(15) 0.0309(7) Uani 1 1 d . . . . .
H29A H 0.072736 0.600239 0.193988 0.046 Uiso 1 1 calc R U . . .
H29B H 0.190122 0.559907 0.153433 0.046 Uiso 1 1 calc R U . . .
H29C H 0.054799 0.578147 0.112167 0.046 Uiso 1 1 calc R U . . .
C30A C 0.2107(3) 0.62213(16) -0.02726(13) 0.0209(5) Uani 1 1 d . . . . .
H30A H 0.258980 0.644602 -0.069089 0.025 Uiso 1 1 calc R U . . .
C31A C 0.2150(3) 0.53529(18) -0.03484(16) 0.0311(7) Uani 1 1 d . . . . .
H31A H 0.170515 0.510609 0.005643 0.047 Uiso 1 1 calc R U . . .
H31B H 0.313531 0.526497 -0.037653 0.047 Uiso 1 1 calc R U . . .
H31C H 0.163733 0.513287 -0.077349 0.047 Uiso 1 1 calc R U . . .
C32A C 0.0577(3) 0.63793(19) -0.03092(15) 0.0277(6) Uani 1 1 d . . . . .
H32A H 0.012277 0.613199 -0.073973 0.042 Uiso 1 1 calc R U . . .
H32B H 0.057375 0.693599 -0.030430 0.042 Uiso 1 1 calc R U . . .
H32C H 0.005597 0.617070 0.009304 0.042 Uiso 1 1 calc R U . . .
Rh1B Rh -0.03635(2) 0.77696(2) 0.58369(2) 0.00970(5) Uani 1 1 d . . . . .
I1B I -0.12000(2) 0.87723(2) 0.67180(2) 0.02342(5) Uani 1 1 d . . . . .
P1B P -0.02075(6) 0.71148(3) 0.48349(3) 0.00890(11) Uani 1 1 d . . . . .
Si1B Si 0.20551(7) 0.80970(4) 0.58390(3) 0.01108(12) Uani 1 1 d . . . . .
Si2B Si -0.04829(6) 0.66433(4) 0.64021(3) 0.00983(12) Uani 1 1 d . . . . .
C1B C 0.2953(2) 0.72465(14) 0.55368(12) 0.0122(5) Uani 1 1 d . . . . .
H1B1 H 0.398071 0.738519 0.563179 0.015 Uiso 1 1 calc R U . . .
H1B2 H 0.259856 0.680699 0.582020 0.015 Uiso 1 1 calc R U . . .
C2B C 0.2741(2) 0.69861(13) 0.47811(12) 0.0106(4) Uani 1 1 d . . . . .
C3B C 0.3921(3) 0.68456(13) 0.43884(13) 0.0135(5) Uani 1 1 d . . . . .
H3B H 0.483286 0.694724 0.460183 0.016 Uiso 1 1 calc R U . . .
C4B C 0.3794(3) 0.65633(14) 0.36991(13) 0.0154(5) Uani 1 1 d . . . . .
H4B H 0.461410 0.648472 0.344436 0.018 Uiso 1 1 calc R U . . .
C5B C 0.2471(3) 0.63955(14) 0.33813(12) 0.0154(5) Uani 1 1 d . . . . .
H5B H 0.237508 0.618578 0.291384 0.018 Uiso 1 1 calc R U . . .
C6B C 0.1287(3) 0.65368(14) 0.37526(12) 0.0134(5) Uani 1 1 d . . . . .
H6B H 0.037978 0.641871 0.353628 0.016 Uiso 1 1 calc R U . . .
C7B C 0.1407(2) 0.68512(13) 0.44424(12) 0.0104(4) Uani 1 1 d . . . . .
C8B C -0.1458(2) 0.62224(13) 0.47226(12) 0.0107(4) Uani 1 1 d . . . . .
C9B C -0.2510(3) 0.60982(14) 0.42019(12) 0.0145(5) Uani 1 1 d . . . . .
H9B H -0.256671 0.648232 0.388037 0.017 Uiso 1 1 calc R U . . .
C10B C -0.3471(3) 0.54190(15) 0.41508(13) 0.0159(5) Uani 1 1 d . . . . .
H10B H -0.416829 0.533521 0.379008 0.019 Uiso 1 1 calc R U . . .
C11B C -0.3408(3) 0.48652(14) 0.46276(13) 0.0148(5) Uani 1 1 d . . . . .
H11B H -0.406977 0.440256 0.459851 0.018 Uiso 1 1 calc R U . . .
C12B C -0.2375(3) 0.49880(13) 0.51490(12) 0.0125(5) Uani 1 1 d . . . . .
H12B H -0.234327 0.460608 0.547548 0.015 Uiso 1 1 calc R U . . .
C13B C -0.1385(2) 0.56578(13) 0.52040(11) 0.0105(4) Uani 1 1 d . . . . .
C14B C -0.0299(2) 0.57806(13) 0.57814(11) 0.0105(4) Uani 1 1 d . . . . .
H14C H 0.065676 0.585772 0.557632 0.013 Uiso 1 1 calc R U . . .
H14D H -0.038780 0.531204 0.604877 0.013 Uiso 1 1 calc R U . . .
C15B C -0.0821(3) 0.77588(13) 0.42288(12) 0.0119(4) Uani 1 1 d . . . . .
C16B C -0.0036(3) 0.80687(14) 0.36749(13) 0.0155(5) Uani 1 1 d . . . . .
H16B H 0.086156 0.792391 0.357516 0.019 Uiso 1 1 calc R U . . .
C17B C -0.0568(3) 0.85920(15) 0.32662(13) 0.0198(5) Uani 1 1 d . . . . .
H17B H -0.002692 0.880740 0.289226 0.024 Uiso 1 1 calc R U . . .
C18B C -0.1881(3) 0.87968(15) 0.34055(13) 0.0210(6) Uani 1 1 d . . . . .
H18B H -0.224636 0.914514 0.312083 0.025 Uiso 1 1 calc R U . . .
C19B C -0.2664(3) 0.84981(15) 0.39559(14) 0.0200(5) Uani 1 1 d . . . . .
H19B H -0.356289 0.864308 0.405068 0.024 Uiso 1 1 calc R U . . .
C20B C -0.2136(3) 0.79862(14) 0.43704(13) 0.0160(5) Uani 1 1 d . . . . .
H20B H -0.267061 0.778816 0.475329 0.019 Uiso 1 1 calc R U . . .
C21B C 0.2488(3) 0.87999(15) 0.51249(13) 0.0189(5) Uani 1 1 d . . . . .
H21B H 0.219283 0.849738 0.467805 0.023 Uiso 1 1 calc R U . . .
C22B C 0.4101(3) 0.90370(17) 0.50773(15) 0.0284(6) Uani 1 1 d . . . . .
H22D H 0.431951 0.934508 0.467201 0.043 Uiso 1 1 calc R U . . .
H22E H 0.455479 0.857453 0.502803 0.043 Uiso 1 1 calc R U . . .
H22F H 0.445628 0.934234 0.550170 0.043 Uiso 1 1 calc R U . . .
C23B C 0.1702(4) 0.94950(16) 0.51386(15) 0.0308(7) Uani 1 1 d . . . . .
H23D H 0.195221 0.981777 0.556694 0.046 Uiso 1 1 calc R U . . .
H23E H 0.068032 0.931610 0.512383 0.046 Uiso 1 1 calc R U . . .
H23F H 0.197134 0.979595 0.473369 0.046 Uiso 1 1 calc R U . . .
C24B C 0.2816(3) 0.84731(14) 0.67391(13) 0.0164(5) Uani 1 1 d . . . . .
H24B H 0.215001 0.822249 0.708745 0.020 Uiso 1 1 calc R U . . .
C25B C 0.4265(3) 0.82466(17) 0.68953(15) 0.0243(6) Uani 1 1 d . . . . .
H25D H 0.495095 0.846203 0.655382 0.036 Uiso 1 1 calc R U . . .
H25E H 0.418929 0.768404 0.686700 0.036 Uiso 1 1 calc R U . . .
H25F H 0.458156 0.844900 0.736472 0.036 Uiso 1 1 calc R U . . .
C26B C 0.2874(3) 0.93444(16) 0.68789(15) 0.0251(6) Uani 1 1 d . . . . .
H26D H 0.318340 0.949074 0.736120 0.038 Uiso 1 1 calc R U . . .
H26E H 0.193275 0.948104 0.680461 0.038 Uiso 1 1 calc R U . . .
H26F H 0.354428 0.961799 0.656013 0.038 Uiso 1 1 calc R U . . .
C27B C -0.2363(3) 0.64929(14) 0.67586(12) 0.0143(5) Uani 1 1 d . . . . .
H27B H -0.236979 0.686687 0.717017 0.017 Uiso 1 1 calc R U . . .
C28B C -0.3508(3) 0.66517(16) 0.62492(13) 0.0190(5) Uani 1 1 d . . . . .
H28D H -0.352876 0.629973 0.583379 0.029 Uiso 1 1 calc R U . . .
H28E H -0.329451 0.718486 0.611356 0.029 Uiso 1 1 calc R U . . .
H28F H -0.443096 0.657198 0.647516 0.029 Uiso 1 1 calc R U . . .
C29B C -0.2765(3) 0.56840(16) 0.70256(14) 0.0213(5) Uani 1 1 d . . . . .
H29D H -0.370994 0.563624 0.722857 0.032 Uiso 1 1 calc R U . . .
H29E H -0.207697 0.560160 0.738150 0.032 Uiso 1 1 calc R U . . .
H29F H -0.276372 0.529788 0.663724 0.032 Uiso 1 1 calc R U . . .
C30B C 0.0869(3) 0.66451(14) 0.71364(12) 0.0149(5) Uani 1 1 d . . . . .
H30B H 0.176889 0.695601 0.698563 0.018 Uiso 1 1 calc R U . . .
C31B C 0.1213(3) 0.58406(16) 0.72770(15) 0.0253(6) Uani 1 1 d . . . . .
H31D H 0.187519 0.588288 0.767242 0.038 Uiso 1 1 calc R U . . .
H31E H 0.164290 0.562644 0.686269 0.038 Uiso 1 1 calc R U . . .
H31F H 0.034050 0.550079 0.738528 0.038 Uiso 1 1 calc R U . . .
C32B C 0.0434(3) 0.70470(17) 0.78111(13) 0.0223(6) Uani 1 1 d . . . . .
H32D H -0.041489 0.674278 0.799422 0.033 Uiso 1 1 calc R U . . .
H32E H 0.023331 0.756054 0.771563 0.033 Uiso 1 1 calc R U . . .
H32F H 0.120463 0.709513 0.815543 0.033 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.3257 6.8362 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1A Rh1A Si2A 86.60(2) . . ?
P1A Rh1A Si1A 88.62(2) . . ?
Si2A Rh1A Si1A 98.97(2) . . ?
P1A Rh1A I1A 161.285(18) . . ?
Si2A Rh1A I1A 108.071(18) . . ?
Si1A Rh1A I1A 100.115(18) . . ?
C7A P1A C15A 104.20(11) . . ?
C7A P1A C8A 100.88(11) . . ?
C15A P1A C8A 105.00(11) . . ?
C7A P1A Rh1A 111.40(8) . . ?
C15A P1A Rh1A 107.12(8) . . ?
C8A P1A Rh1A 126.18(8) . . ?
C21A Si1A C1A 106.53(12) . . ?
C21A Si1A C24A 110.44(12) . . ?
C1A Si1A C24A 107.89(11) . . ?
C21A Si1A Rh1A 104.71(8) . . ?
C1A Si1A Rh1A 112.59(8) . . ?
C24A Si1A Rh1A 114.39(8) . . ?
C14A Si2A C27A 104.04(12) . . ?
C14A Si2A C30A 106.96(12) . . ?
C27A Si2A C30A 113.53(12) . . ?
C14A Si2A Rh1A 113.33(9) . . ?
C27A Si2A Rh1A 108.75(9) . . ?
C30A Si2A Rh1A 110.18(9) . . ?
C2A C1A Si1A 111.56(17) . . ?
C2A C1A H1A1 109.3 . . ?
Si1A C1A H1A1 109.3 . . ?
C2A C1A H1A2 109.3 . . ?
Si1A C1A H1A2 109.3 . . ?
H1A1 C1A H1A2 108.0 . . ?
C3A C2A C7A 117.8(2) . . ?
C3A C2A C1A 121.3(2) . . ?
C7A C2A C1A 120.8(2) . . ?
C4A C3A C2A 121.8(3) . . ?
C4A C3A H3A 119.1 . . ?
C2A C3A H3A 119.1 . . ?
C3A C4A C5A 120.2(3) . . ?
C3A C4A H4A 119.9 . . ?
C5A C4A H4A 119.9 . . ?
C6A C5A C4A 119.3(3) . . ?
C6A C5A H5A 120.4 . . ?
C4A C5A H5A 120.4 . . ?
C5A C6A C7A 120.7(2) . . ?
C5A C6A H6A 119.7 . . ?
C7A C6A H6A 119.7 . . ?
C6A C7A C2A 120.2(2) . . ?
C6A C7A P1A 122.79(19) . . ?
C2A C7A P1A 116.95(19) . . ?
C9A C8A C13A 119.7(2) . . ?
C9A C8A P1A 115.35(19) . . ?
C13A C8A P1A 124.86(18) . . ?
C10A C9A C8A 121.4(2) . . ?
C10A C9A H9A 119.3 . . ?
C8A C9A H9A 119.3 . . ?
C9A C10A C11A 119.5(2) . . ?
C9A C10A H10A 120.3 . . ?
C11A C10A H10A 120.3 . . ?
C12A C11A C10A 119.8(2) . . ?
C12A C11A H11A 120.1 . . ?
C10A C11A H11A 120.1 . . ?
C11A C12A C13A 121.9(2) . . ?
C11A C12A H12A 119.1 . . ?
C13A C12A H12A 119.1 . . ?
C8A C13A C12A 117.5(2) . . ?
C8A C13A C14A 124.5(2) . . ?
C12A C13A C14A 117.8(2) . . ?
C13A C14A Si2A 118.67(18) . . ?
C13A C14A H14A 107.6 . . ?
Si2A C14A H14A 107.6 . . ?
C13A C14A H14B 107.6 . . ?
Si2A C14A H14B 107.6 . . ?
H14A C14A H14B 107.1 . . ?
C20A C15A C16A 118.7(2) . . ?
C20A C15A P1A 124.21(19) . . ?
C16A C15A P1A 117.04(19) . . ?
C17A C16A C15A 120.9(2) . . ?
C17A C16A H16A 119.6 . . ?
C15A C16A H16A 119.6 . . ?
C18A C17A C16A 119.7(3) . . ?
C18A C17A H17A 120.2 . . ?
C16A C17A H17A 120.2 . . ?
C19A C18A C17A 120.0(2) . . ?
C19A C18A H18A 120.0 . . ?
C17A C18A H18A 120.0 . . ?
C18A C19A C20A 120.5(2) . . ?
C18A C19A H19A 119.7 . . ?
C20A C19A H19A 119.7 . . ?
C15A C20A C19A 120.2(2) . . ?
C15A C20A H20A 119.9 . . ?
C19A C20A H20A 119.9 . . ?
C22A C21A C23A 110.1(2) . . ?
C22A C21A Si1A 114.94(18) . . ?
C23A C21A Si1A 110.62(19) . . ?
C22A C21A H21A 106.9 . . ?
C23A C21A H21A 106.9 . . ?
Si1A C21A H21A 106.9 . . ?
C21A C22A H22A 109.5 . . ?
C21A C22A H22B 109.5 . . ?
H22A C22A H22B 109.5 . . ?
C21A C22A H22C 109.5 . . ?
H22A C22A H22C 109.5 . . ?
H22B C22A H22C 109.5 . . ?
C21A C23A H23A 109.5 . . ?
C21A C23A H23B 109.5 . . ?
H23A C23A H23B 109.5 . . ?
C21A C23A H23C 109.5 . . ?
H23A C23A H23C 109.5 . . ?
H23B C23A H23C 109.5 . . ?
C26A C24A C25A 110.9(2) . . ?
C26A C24A Si1A 112.64(19) . . ?
C25A C24A Si1A 113.03(18) . . ?
C26A C24A H24A 106.6 . . ?
C25A C24A H24A 106.6 . . ?
Si1A C24A H24A 106.6 . . ?
C24A C25A H25A 109.5 . . ?
C24A C25A H25B 109.5 . . ?
H25A C25A H25B 109.5 . . ?
C24A C25A H25C 109.5 . . ?
H25A C25A H25C 109.5 . . ?
H25B C25A H25C 109.5 . . ?
C24A C26A H26A 109.5 . . ?
C24A C26A H26B 109.5 . . ?
H26A C26A H26B 109.5 . . ?
C24A C26A H26C 109.5 . . ?
H26A C26A H26C 109.5 . . ?
H26B C26A H26C 109.5 . . ?
C28A C27A C29A 110.9(2) . . ?
C28A C27A Si2A 115.49(19) . . ?
C29A C27A Si2A 112.1(2) . . ?
C28A C27A H27A 105.8 . . ?
C29A C27A H27A 105.8 . . ?
Si2A C27A H27A 105.8 . . ?
C27A C28A H28A 109.5 . . ?
C27A C28A H28B 109.5 . . ?
H28A C28A H28B 109.5 . . ?
C27A C28A H28C 109.5 . . ?
H28A C28A H28C 109.5 . . ?
H28B C28A H28C 109.5 . . ?
C27A C29A H29A 109.5 . . ?
C27A C29A H29B 109.5 . . ?
H29A C29A H29B 109.5 . . ?
C27A C29A H29C 109.5 . . ?
H29A C29A H29C 109.5 . . ?
H29B C29A H29C 109.5 . . ?
C32A C30A C31A 110.6(2) . . ?
C32A C30A Si2A 113.61(19) . . ?
C31A C30A Si2A 113.20(19) . . ?
C32A C30A H30A 106.3 . . ?
C31A C30A H30A 106.3 . . ?
Si2A C30A H30A 106.3 . . ?
C30A C31A H31A 109.5 . . ?
C30A C31A H31B 109.5 . . ?
H31A C31A H31B 109.5 . . ?
C30A C31A H31C 109.5 . . ?
H31A C31A H31C 109.5 . . ?
H31B C31A H31C 109.5 . . ?
C30A C32A H32A 109.5 . . ?
C30A C32A H32B 109.5 . . ?
H32A C32A H32B 109.5 . . ?
C30A C32A H32C 109.5 . . ?
H32A C32A H32C 109.5 . . ?
H32B C32A H32C 109.5 . . ?
P1B Rh1B Si1B 88.29(2) . . ?
P1B Rh1B Si2B 89.44(2) . . ?
Si1B Rh1B Si2B 97.92(2) . . ?
P1B Rh1B I1B 157.885(17) . . ?
Si1B Rh1B I1B 104.168(17) . . ?
Si2B Rh1B I1B 106.474(16) . . ?
C8B P1B C15B 104.91(11) . . ?
C8B P1B C7B 102.88(10) . . ?
C15B P1B C7B 104.59(11) . . ?
C8B P1B Rh1B 114.60(7) . . ?
C15B P1B Rh1B 100.95(8) . . ?
C7B P1B Rh1B 126.64(8) . . ?
C1B Si1B C21B 103.41(11) . . ?
C1B Si1B C24B 107.90(11) . . ?
C21B Si1B C24B 114.37(12) . . ?
C1B Si1B Rh1B 111.57(8) . . ?
C21B Si1B Rh1B 106.51(9) . . ?
C24B Si1B Rh1B 112.74(8) . . ?
C14B Si2B C30B 106.39(11) . . ?
C14B Si2B C27B 107.76(11) . . ?
C30B Si2B C27B 110.50(11) . . ?
C14B Si2B Rh1B 112.48(7) . . ?
C30B Si2B Rh1B 116.06(8) . . ?
C27B Si2B Rh1B 103.43(8) . . ?
C2B C1B Si1B 115.56(16) . . ?
C2B C1B H1B1 108.4 . . ?
Si1B C1B H1B1 108.4 . . ?
C2B C1B H1B2 108.4 . . ?
Si1B C1B H1B2 108.4 . . ?
H1B1 C1B H1B2 107.5 . . ?
C3B C2B C7B 117.6(2) . . ?
C3B C2B C1B 118.8(2) . . ?
C7B C2B C1B 123.6(2) . . ?
C4B C3B C2B 122.0(2) . . ?
C4B C3B H3B 119.0 . . ?
C2B C3B H3B 119.0 . . ?
C3B C4B C5B 120.0(2) . . ?
C3B C4B H4B 120.0 . . ?
C5B C4B H4B 120.0 . . ?
C4B C5B C6B 119.4(2) . . ?
C4B C5B H5B 120.3 . . ?
C6B C5B H5B 120.3 . . ?
C5B C6B C7B 121.2(2) . . ?
C5B C6B H6B 119.4 . . ?
C7B C6B H6B 119.4 . . ?
C6B C7B C2B 119.7(2) . . ?
C6B C7B P1B 116.53(18) . . ?
C2B C7B P1B 123.66(17) . . ?
C9B C8B C13B 119.6(2) . . ?
C9B C8B P1B 122.71(18) . . ?
C13B C8B P1B 117.60(17) . . ?
C10B C9B C8B 120.7(2) . . ?
C10B C9B H9B 119.6 . . ?
C8B C9B H9B 119.6 . . ?
C11B C10B C9B 119.7(2) . . ?
C11B C10B H10B 120.1 . . ?
C9B C10B H10B 120.1 . . ?
C10B C11B C12B 119.8(2) . . ?
C10B C11B H11B 120.1 . . ?
C12B C11B H11B 120.1 . . ?
C11B C12B C13B 121.6(2) . . ?
C11B C12B H12B 119.2 . . ?
C13B C12B H12B 119.2 . . ?
C12B C13B C8B 118.6(2) . . ?
C12B C13B C14B 120.3(2) . . ?
C8B C13B C14B 121.1(2) . . ?
C13B C14B Si2B 112.92(15) . . ?
C13B C14B H14C 109.0 . . ?
Si2B C14B H14C 109.0 . . ?
C13B C14B H14D 109.0 . . ?
Si2B C14B H14D 109.0 . . ?
H14C C14B H14D 107.8 . . ?
C16B C15B C20B 119.0(2) . . ?
C16B C15B P1B 124.52(19) . . ?
C20B C15B P1B 116.35(18) . . ?
C15B C16B C17B 120.1(2) . . ?
C15B C16B H16B 120.0 . . ?
C17B C16B H16B 120.0 . . ?
C18B C17B C16B 120.1(2) . . ?
C18B C17B H17B 120.0 . . ?
C16B C17B H17B 120.0 . . ?
C19B C18B C17B 120.4(2) . . ?
C19B C18B H18B 119.8 . . ?
C17B C18B H18B 119.8 . . ?
C18B C19B C20B 119.9(2) . . ?
C18B C19B H19B 120.0 . . ?
C20B C19B H19B 120.0 . . ?
C19B C20B C15B 120.5(2) . . ?
C19B C20B H20B 119.7 . . ?
C15B C20B H20B 119.7 . . ?
C23B C21B C22B 112.2(2) . . ?
C23B C21B Si1B 117.00(19) . . ?
C22B C21B Si1B 110.08(19) . . ?
C23B C21B H21B 105.5 . . ?
C22B C21B H21B 105.5 . . ?
Si1B C21B H21B 105.5 . . ?
C21B C22B H22D 109.5 . . ?
C21B C22B H22E 109.5 . . ?
H22D C22B H22E 109.5 . . ?
C21B C22B H22F 109.5 . . ?
H22D C22B H22F 109.5 . . ?
H22E C22B H22F 109.5 . . ?
C21B C23B H23D 109.5 . . ?
C21B C23B H23E 109.5 . . ?
H23D C23B H23E 109.5 . . ?
C21B C23B H23F 109.5 . . ?
H23D C23B H23F 109.5 . . ?
H23E C23B H23F 109.5 . . ?
C26B C24B C25B 109.9(2) . . ?
C26B C24B Si1B 113.60(18) . . ?
C25B C24B Si1B 113.85(17) . . ?
C26B C24B H24B 106.3 . . ?
C25B C24B H24B 106.3 . . ?
Si1B C24B H24B 106.3 . . ?
C24B C25B H25D 109.5 . . ?
C24B C25B H25E 109.5 . . ?
H25D C25B H25E 109.5 . . ?
C24B C25B H25F 109.5 . . ?
H25D C25B H25F 109.5 . . ?
H25E C25B H25F 109.5 . . ?
C24B C26B H26D 109.5 . . ?
C24B C26B H26E 109.5 . . ?
H26D C26B H26E 109.5 . . ?
C24B C26B H26F 109.5 . . ?
H26D C26B H26F 109.5 . . ?
H26E C26B H26F 109.5 . . ?
C29B C27B C28B 109.6(2) . . ?
C29B C27B Si2B 111.56(17) . . ?
C28B C27B Si2B 114.75(17) . . ?
C29B C27B H27B 106.8 . . ?
C28B C27B H27B 106.8 . . ?
Si2B C27B H27B 106.8 . . ?
C27B C28B H28D 109.5 . . ?
C27B C28B H28E 109.5 . . ?
H28D C28B H28E 109.5 . . ?
C27B C28B H28F 109.5 . . ?
H28D C28B H28F 109.5 . . ?
H28E C28B H28F 109.5 . . ?
C27B C29B H29D 109.5 . . ?
C27B C29B H29E 109.5 . . ?
H29D C29B H29E 109.5 . . ?
C27B C29B H29F 109.5 . . ?
H29D C29B H29F 109.5 . . ?
H29E C29B H29F 109.5 . . ?
C32B C30B C31B 110.4(2) . . ?
C32B C30B Si2B 111.89(17) . . ?
C31B C30B Si2B 114.03(17) . . ?
C32B C30B H30B 106.7 . . ?
C31B C30B H30B 106.7 . . ?
Si2B C30B H30B 106.7 . . ?
C30B C31B H31D 109.5 . . ?
C30B C31B H31E 109.5 . . ?
H31D C31B H31E 109.5 . . ?
C30B C31B H31F 109.5 . . ?
H31D C31B H31F 109.5 . . ?
H31E C31B H31F 109.5 . . ?
C30B C32B H32D 109.5 . . ?
C30B C32B H32E 109.5 . . ?
H32D C32B H32E 109.5 . . ?
C30B C32B H32F 109.5 . . ?
H32D C32B H32F 109.5 . . ?
H32E C32B H32F 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1A P1A 2.2021(6) . ?
Rh1A Si2A 2.2960(7) . ?
Rh1A Si1A 2.3112(6) . ?
Rh1A I1A 2.6004(2) . ?
P1A C7A 1.820(3) . ?
P1A C15A 1.833(2) . ?
P1A C8A 1.838(2) . ?
Si1A C21A 1.908(3) . ?
Si1A C1A 1.910(3) . ?
Si1A C24A 1.915(3) . ?
Si2A C14A 1.896(3) . ?
Si2A C27A 1.907(3) . ?
Si2A C30A 1.919(3) . ?
C1A C2A 1.501(4) . ?
C1A H1A1 0.9900 . ?
C1A H1A2 0.9900 . ?
C2A C3A 1.391(4) . ?
C2A C7A 1.410(3) . ?
C3A C4A 1.385(4) . ?
C3A H3A 0.9500 . ?
C4A C5A 1.389(4) . ?
C4A H4A 0.9500 . ?
C5A C6A 1.386(4) . ?
C5A H5A 0.9500 . ?
C6A C7A 1.400(4) . ?
C6A H6A 0.9500 . ?
C8A C9A 1.399(3) . ?
C8A C13A 1.402(4) . ?
C9A C10A 1.380(4) . ?
C9A H9A 0.9500 . ?
C10A C11A 1.383(4) . ?
C10A H10A 0.9500 . ?
C11A C12A 1.383(4) . ?
C11A H11A 0.9500 . ?
C12A C13A 1.409(4) . ?
C12A H12A 0.9500 . ?
C13A C14A 1.509(3) . ?
C14A H14A 0.9900 . ?
C14A H14B 0.9900 . ?
C15A C20A 1.389(3) . ?
C15A C16A 1.400(4) . ?
C16A C17A 1.389(4) . ?
C16A H16A 0.9500 . ?
C17A C18A 1.386(4) . ?
C17A H17A 0.9500 . ?
C18A C19A 1.378(4) . ?
C18A H18A 0.9500 . ?
C19A C20A 1.396(4) . ?
C19A H19A 0.9500 . ?
C20A H20A 0.9500 . ?
C21A C22A 1.535(4) . ?
C21A C23A 1.541(4) . ?
C21A H21A 1.0000 . ?
C22A H22A 0.9800 . ?
C22A H22B 0.9800 . ?
C22A H22C 0.9800 . ?
C23A H23A 0.9800 . ?
C23A H23B 0.9800 . ?
C23A H23C 0.9800 . ?
C24A C26A 1.535(4) . ?
C24A C25A 1.538(4) . ?
C24A H24A 1.0000 . ?
C25A H25A 0.9800 . ?
C25A H25B 0.9800 . ?
C25A H25C 0.9800 . ?
C26A H26A 0.9800 . ?
C26A H26B 0.9800 . ?
C26A H26C 0.9800 . ?
C27A C28A 1.533(4) . ?
C27A C29A 1.543(4) . ?
C27A H27A 1.0000 . ?
C28A H28A 0.9800 . ?
C28A H28B 0.9800 . ?
C28A H28C 0.9800 . ?
C29A H29A 0.9800 . ?
C29A H29B 0.9800 . ?
C29A H29C 0.9800 . ?
C30A C32A 1.534(4) . ?
C30A C31A 1.534(4) . ?
C30A H30A 1.0000 . ?
C31A H31A 0.9800 . ?
C31A H31B 0.9800 . ?
C31A H31C 0.9800 . ?
C32A H32A 0.9800 . ?
C32A H32B 0.9800 . ?
C32A H32C 0.9800 . ?
Rh1B P1B 2.2040(6) . ?
Rh1B Si1B 2.2975(7) . ?
Rh1B Si2B 2.3039(6) . ?
Rh1B I1B 2.5924(2) . ?
P1B C8B 1.823(2) . ?
P1B C15B 1.828(2) . ?
P1B C7B 1.833(2) . ?
Si1B C1B 1.902(2) . ?
Si1B C21B 1.906(3) . ?
Si1B C24B 1.916(2) . ?
Si2B C14B 1.906(2) . ?
Si2B C30B 1.911(2) . ?
Si2B C27B 1.913(2) . ?
C1B C2B 1.501(3) . ?
C1B H1B1 0.9900 . ?
C1B H1B2 0.9900 . ?
C2B C3B 1.406(3) . ?
C2B C7B 1.412(3) . ?
C3B C4B 1.386(3) . ?
C3B H3B 0.9500 . ?
C4B C5B 1.387(4) . ?
C4B H4B 0.9500 . ?
C5B C6B 1.388(3) . ?
C5B H5B 0.9500 . ?
C6B C7B 1.404(3) . ?
C6B H6B 0.9500 . ?
C8B C9B 1.401(3) . ?
C8B C13B 1.406(3) . ?
C9B C10B 1.390(4) . ?
C9B H9B 0.9500 . ?
C10B C11B 1.384(4) . ?
C10B H10B 0.9500 . ?
C11B C12B 1.390(3) . ?
C11B H11B 0.9500 . ?
C12B C13B 1.393(3) . ?
C12B H12B 0.9500 . ?
C13B C14B 1.502(3) . ?
C14B H14C 0.9900 . ?
C14B H14D 0.9900 . ?
C15B C16B 1.394(3) . ?
C15B C20B 1.401(3) . ?
C16B C17B 1.397(4) . ?
C16B H16B 0.9500 . ?
C17B C18B 1.382(4) . ?
C17B H17B 0.9500 . ?
C18B C19B 1.381(4) . ?
C18B H18B 0.9500 . ?
C19B C20B 1.387(4) . ?
C19B H19B 0.9500 . ?
C20B H20B 0.9500 . ?
C21B C23B 1.531(4) . ?
C21B C22B 1.541(4) . ?
C21B H21B 1.0000 . ?
C22B H22D 0.9800 . ?
C22B H22E 0.9800 . ?
C22B H22F 0.9800 . ?
C23B H23D 0.9800 . ?
C23B H23E 0.9800 . ?
C23B H23F 0.9800 . ?
C24B C26B 1.534(4) . ?
C24B C25B 1.535(4) . ?
C24B H24B 1.0000 . ?
C25B H25D 0.9800 . ?
C25B H25E 0.9800 . ?
C25B H25F 0.9800 . ?
C26B H26D 0.9800 . ?
C26B H26E 0.9800 . ?
C26B H26F 0.9800 . ?
C27B C29B 1.535(4) . ?
C27B C28B 1.536(3) . ?
C27B H27B 1.0000 . ?
C28B H28D 0.9800 . ?
C28B H28E 0.9800 . ?
C28B H28F 0.9800 . ?
C29B H29D 0.9800 . ?
C29B H29E 0.9800 . ?
C29B H29F 0.9800 . ?
C30B C32B 1.531(3) . ?
C30B C31B 1.541(4) . ?
C30B H30B 1.0000 . ?
C31B H31D 0.9800 . ?
C31B H31E 0.9800 . ?
C31B H31F 0.9800 . ?
C32B H32D 0.9800 . ?
C32B H32E 0.9800 . ?
C32B H32F 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Si1A C1A C2A C3A -117.1(2) . . . . ?
Si1A C1A C2A C7A 60.6(3) . . . . ?
C7A C2A C3A C4A -1.5(4) . . . . ?
C1A C2A C3A C4A 176.2(3) . . . . ?
C2A C3A C4A C5A 0.7(5) . . . . ?
C3A C4A C5A C6A 0.1(5) . . . . ?
C4A C5A C6A C7A -0.1(4) . . . . ?
C5A C6A C7A C2A -0.7(4) . . . . ?
C5A C6A C7A P1A -179.1(2) . . . . ?
C3A C2A C7A C6A 1.5(4) . . . . ?
C1A C2A C7A C6A -176.2(2) . . . . ?
C3A C2A C7A P1A 179.9(2) . . . . ?
C1A C2A C7A P1A 2.2(3) . . . . ?
C15A P1A C7A C6A -3.5(2) . . . . ?
C8A P1A C7A C6A -112.2(2) . . . . ?
Rh1A P1A C7A C6A 111.7(2) . . . . ?
C15A P1A C7A C2A 178.09(19) . . . . ?
C8A P1A C7A C2A 69.4(2) . . . . ?
Rh1A P1A C7A C2A -66.7(2) . . . . ?
C7A P1A C8A C9A 42.4(2) . . . . ?
C15A P1A C8A C9A -65.7(2) . . . . ?
Rh1A P1A C8A C9A 169.35(14) . . . . ?
C7A P1A C8A C13A -135.1(2) . . . . ?
C15A P1A C8A C13A 116.8(2) . . . . ?
Rh1A P1A C8A C13A -8.2(3) . . . . ?
C13A C8A C9A C10A -2.2(4) . . . . ?
P1A C8A C9A C10A -179.8(2) . . . . ?
C8A C9A C10A C11A -1.3(4) . . . . ?
C9A C10A C11A C12A 2.2(4) . . . . ?
C10A C11A C12A C13A 0.2(4) . . . . ?
C9A C8A C13A C12A 4.4(3) . . . . ?
P1A C8A C13A C12A -178.16(19) . . . . ?
C9A C8A C13A C14A -170.0(2) . . . . ?
P1A C8A C13A C14A 7.5(4) . . . . ?
C11A C12A C13A C8A -3.5(4) . . . . ?
C11A C12A C13A C14A 171.3(2) . . . . ?
C8A C13A C14A Si2A -35.6(3) . . . . ?
C12A C13A C14A Si2A 150.0(2) . . . . ?
C27A Si2A C14A C13A -56.8(2) . . . . ?
C30A Si2A C14A C13A -177.24(19) . . . . ?
Rh1A Si2A C14A C13A 61.1(2) . . . . ?
C7A P1A C15A C20A -107.4(2) . . . . ?
C8A P1A C15A C20A -1.8(2) . . . . ?
Rh1A P1A C15A C20A 134.4(2) . . . . ?
C7A P1A C15A C16A 73.9(2) . . . . ?
C8A P1A C15A C16A 179.5(2) . . . . ?
Rh1A P1A C15A C16A -44.2(2) . . . . ?
C20A C15A C16A C17A 1.2(4) . . . . ?
P1A C15A C16A C17A 180.0(2) . . . . ?
C15A C16A C17A C18A -0.8(5) . . . . ?
C16A C17A C18A C19A -0.2(5) . . . . ?
C17A C18A C19A C20A 0.7(4) . . . . ?
C16A C15A C20A C19A -0.7(4) . . . . ?
P1A C15A C20A C19A -179.3(2) . . . . ?
C18A C19A C20A C15A -0.3(4) . . . . ?
Si1B C1B C2B C3B 133.21(19) . . . . ?
Si1B C1B C2B C7B -48.7(3) . . . . ?
C7B C2B C3B C4B -1.9(3) . . . . ?
C1B C2B C3B C4B 176.3(2) . . . . ?
C2B C3B C4B C5B -1.4(4) . . . . ?
C3B C4B C5B C6B 2.1(4) . . . . ?
C4B C5B C6B C7B 0.4(4) . . . . ?
C5B C6B C7B C2B -3.7(3) . . . . ?
C5B C6B C7B P1B 172.93(18) . . . . ?
C3B C2B C7B C6B 4.3(3) . . . . ?
C1B C2B C7B C6B -173.8(2) . . . . ?
C3B C2B C7B P1B -172.05(17) . . . . ?
C1B C2B C7B P1B 9.8(3) . . . . ?
C8B P1B C7B C6B 54.9(2) . . . . ?
C15B P1B C7B C6B -54.5(2) . . . . ?
Rh1B P1B C7B C6B -170.49(14) . . . . ?
C8B P1B C7B C2B -128.6(2) . . . . ?
C15B P1B C7B C2B 122.0(2) . . . . ?
Rh1B P1B C7B C2B 6.0(2) . . . . ?
C15B P1B C8B C9B 7.0(2) . . . . ?
C7B P1B C8B C9B -102.2(2) . . . . ?
Rh1B P1B C8B C9B 116.75(18) . . . . ?
C15B P1B C8B C13B -170.02(17) . . . . ?
C7B P1B C8B C13B 80.81(19) . . . . ?
Rh1B P1B C8B C13B -60.27(19) . . . . ?
C13B C8B C9B C10B -0.8(3) . . . . ?
P1B C8B C9B C10B -177.77(19) . . . . ?
C8B C9B C10B C11B 1.3(4) . . . . ?
C9B C10B C11B C12B -0.7(4) . . . . ?
C10B C11B C12B C13B -0.4(4) . . . . ?
C11B C12B C13B C8B 0.9(3) . . . . ?
C11B C12B C13B C14B 178.8(2) . . . . ?
C9B C8B C13B C12B -0.3(3) . . . . ?
P1B C8B C13B C12B 176.83(17) . . . . ?
C9B C8B C13B C14B -178.2(2) . . . . ?
P1B C8B C13B C14B -1.1(3) . . . . ?
C12B C13B C14B Si2B -116.5(2) . . . . ?
C8B C13B C14B Si2B 61.4(2) . . . . ?
C8B P1B C15B C16B -118.6(2) . . . . ?
C7B P1B C15B C16B -10.6(2) . . . . ?
Rh1B P1B C15B C16B 122.1(2) . . . . ?
C8B P1B C15B C20B 65.7(2) . . . . ?
C7B P1B C15B C20B 173.66(18) . . . . ?
Rh1B P1B C15B C20B -53.61(19) . . . . ?
C20B C15B C16B C17B -0.6(4) . . . . ?
P1B C15B C16B C17B -176.19(19) . . . . ?
C15B C16B C17B C18B -0.7(4) . . . . ?
C16B C17B C18B C19B 1.2(4) . . . . ?
C17B C18B C19B C20B -0.3(4) . . . . ?
C18B C19B C20B C15B -1.0(4) . . . . ?
C16B C15B C20B C19B 1.5(4) . . . . ?
P1B C15B C20B C19B 177.43(19) . . . . ?
