#------------------------------------------------------------------------------
#$Date: 2021-10-06 18:30:50 +0300 (Wed, 06 Oct 2021) $
#$Revision: 269702 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/79/7707987.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7707987
loop_
_publ_author_name
'Utochnikova, Valentina V.'
'Aslandukov, Andrey N.'
'Vashchenko, Andrey A.'
'Goloveshkin, Alexander S.'
'Alexandrov, Alexey A.'
'Grzibovskis, Raitis'
'Bünzli, Jean-Claude G'
_publ_section_title
;
 Identifying lifetime as one of the key parameters responsible for the low
 brightness of lanthanide-based OLEDs.
;
_journal_issue                   37
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12806
_journal_page_last               12813
_journal_paper_doi               10.1039/d1dt02269e
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety
'2(C24 H16 N2), C60 H50 Eu2 N4 O12, 2(C2 H5 O)'
_chemical_formula_sum            'C112 H92 Eu2 N8 O14'
_chemical_formula_weight         2077.86
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2021-06-14
_audit_creation_method
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_audit_update_record
;
2021-06-14 deposited with the CCDC.	2021-08-09 downloaded from the CCDC.
;
_cell_angle_alpha                97.899(5)
_cell_angle_beta                 99.011(5)
_cell_angle_gamma                105.648(4)
_cell_formula_units_Z            1
_cell_length_a                   9.849(2)
_cell_length_b                   10.323(2)
_cell_length_c                   24.422(5)
_cell_measurement_reflns_used    3108
_cell_measurement_temperature    120
_cell_measurement_theta_max      30.52
_cell_measurement_theta_min      2.19
_cell_volume                     2319.0(8)
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XH  (Sheldrick, 2008)'
_computing_structure_solution    'XS n/a (Sheldrick, 2008)'
_diffrn_ambient_temperature      120
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1103
_diffrn_reflns_av_unetI/netI     0.1584
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            26763
_diffrn_reflns_theta_full        28.28
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         1.72
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.413
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6239
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SADABS-2008/1 (Bruker,2008) was used for absorption correction. wR2(int) was 0.0939 before and 0.0660 after correction. The Ratio of minimum to maximum transmission is 0.8362. The λ/2 correction factor is 0.0015.'
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.488
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1058
_exptl_crystal_preparation       Luminescent
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.15
_refine_diff_density_max         3.205
_refine_diff_density_min         -4.336
_refine_diff_density_rms         0.211
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     618
_refine_ls_number_reflns         11424
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.034
_refine_ls_R_factor_all          0.1275
_refine_ls_R_factor_gt           0.0798
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0950P)²+1.8368P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1817
_refine_ls_wR_factor_ref         0.2020
_reflns_number_gt                7472
_reflns_number_total             11424
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            d1dt02269e2.cif
_cod_data_source_block           a_CCDC1
_cod_depositor_comments
'Adding full bibliography for 7707986--7707989.cif.'
_cod_original_cell_volume        2318.9(8)
_cod_database_code               7707987
_olex2_refinement_description
;
1.a Aromatic/amide H refined with riding coordinates:
 C8(H8), C35(H35), C48(H48), C69(H69), C77(H77), C80(H80), C85(H85), C89(H89),
 C91(H91), C93(H93), C98(H98), C110(H110), C112(H112), C114(H114), C119(H119),
 C129(H129), C11(H11), C24(H24), C44(H44), C52(H52), C56(H56), C65(H65),
 C70(H70), C74(H74), C76(H76), C78(H78), C84(H84), C87(H87), C95(H95), C96(H96),
  C97(H97), C113(H113), C3(H3)
1.b Idealised Me refined as rotating group:
 C1(H1A,H1B,H1C), C12(H12A,H12B,H12C), C81(H81A,H81B,H81C), C7(H7A,H7B,H7C)
1.c Idealised tetrahedral OH refined as rotating group:
 O23(H23)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C8 C 0.4584(10) 0.1522(9) -0.4980(4) 0.0291(19) Uani 1 1 d . . .
H8 H 0.5358 0.2177 -0.5052 0.035 Uiso 1 1 calc R . .
N33 N 0.1603(7) -0.0860(7) -0.6312(3) 0.0241(15) Uani 1 1 d . . .
C35 C -0.1775(9) -0.5240(8) -0.5878(3) 0.0211(17) Uani 1 1 d . . .
H35 H -0.0861 -0.5196 -0.5690 0.025 Uiso 1 1 calc R . .
C39 C 0.2313(8) -0.0376(8) -0.4754(3) 0.0195(16) Uani 1 1 d . . .
C40 C 0.2467(8) -0.0175(8) -0.5307(3) 0.0207(17) Uani 1 1 d . . .
C48 C 0.1089(8) -0.1406(8) -0.4678(3) 0.0201(16) Uani 1 1 d . . .
H48 H 0.0965 -0.1513 -0.4315 0.024 Uiso 1 1 calc R . .
N59 N 0.3578(7) 0.0765(7) -0.5417(3) 0.0246(15) Uani 1 1 d . . .
C63 C 0.0245(8) -0.2120(8) -0.5700(3) 0.0201(16) Uani 1 1 d . . .
C64 C -0.0730(8) -0.3002(8) -0.6178(3) 0.0215(17) Uani 1 1 d . . .
C68 C -0.1968(8) -0.4156(8) -0.6135(3) 0.0190(16) Uani 1 1 d . . .
C69 C -0.0527(9) -0.2778(8) -0.6705(3) 0.0216(17) Uani 1 1 d . . .
H69 H -0.1154 -0.3333 -0.7029 0.026 Uiso 1 1 calc R . .
C77 C 0.0110(9) -0.2225(8) -0.5130(3) 0.0218(17) Uani 1 1 d . . .
H77 H -0.0680 -0.2880 -0.5069 0.026 Uiso 1 1 calc R . .
C80 C 0.4852(10) 0.0108(9) -0.2813(4) 0.032(2) Uani 1 1 d . . .
H80 H 0.5686 0.0003 -0.2612 0.038 Uiso 1 1 calc R . .
C85 C -0.4298(10) -0.6442(9) -0.6163(4) 0.0281(19) Uani 1 1 d . . .
H85 H -0.5071 -0.7205 -0.6175 0.034 Uiso 1 1 calc R . .
C88 C 0.1409(8) -0.1074(8) -0.5789(3) 0.0191(16) Uani 1 1 d . . .
C89 C 0.4558(9) 0.1401(9) -0.4420(4) 0.0259(18) Uani 1 1 d . . .
H89 H 0.5303 0.1962 -0.4132 0.031 Uiso 1 1 calc R . .
C91 C 0.2362(9) 0.0405(8) -0.3413(4) 0.0240(18) Uani 1 1 d . . .
H91 H 0.1523 0.0504 -0.3613 0.029 Uiso 1 1 calc R . .
C93 C 0.2488(9) 0.0363(8) -0.2845(4) 0.0252(18) Uani 1 1 d . . .
H93 H 0.1744 0.0444 -0.2663 0.030 Uiso 1 1 calc R . .
C98 C -0.3365(9) -0.4233(9) -0.6400(3) 0.0244(18) Uani 1 1 d . . .
H98 H -0.3517 -0.3518 -0.6571 0.029 Uiso 1 1 calc R . .
C110 C -0.4515(9) -0.5350(9) -0.6410(4) 0.030(2) Uani 1 1 d . . .
H110 H -0.5437 -0.5380 -0.6583 0.036 Uiso 1 1 calc R . .
C112 C 0.4728(9) 0.0171(9) -0.3379(4) 0.0261(18) Uani 1 1 d . . .
H112 H 0.5490 0.0126 -0.3555 0.031 Uiso 1 1 calc R . .
C114 C 0.3733(10) 0.0200(9) -0.2547(4) 0.0286(19) Uani 1 1 d . . .
H114 H 0.3815 0.0153 -0.2166 0.034 Uiso 1 1 calc R . .
C116 C 0.3427(9) 0.0449(9) -0.4294(4) 0.0240(18) Uani 1 1 d . . .
C119 C 0.0655(9) -0.1686(9) -0.6744(3) 0.0256(18) Uani 1 1 d . . .
H119 H 0.0772 -0.1539 -0.7104 0.031 Uiso 1 1 calc R . .
C129 C -0.2921(9) -0.6376(9) -0.5900(3) 0.0235(18) Uani 1 1 d . . .
H129 H -0.2770 -0.7101 -0.5736 0.028 Uiso 1 1 calc R . .
C131 C 0.3469(9) 0.0302(9) -0.3690(4) 0.0245(18) Uani 1 1 d . . .
Eu1 Eu 0.10777(4) -0.01299(4) -0.060893(17) 0.01644(13) Uani 1 1 d . . .
O18 O 0.2127(6) 0.1812(6) -0.1034(2) 0.0271(13) Uani 1 1 d . . .
O118 O -0.0157(6) -0.2603(6) -0.0798(2) 0.0241(13) Uani 1 1 d . . .
O121 O 0.0929(6) 0.1466(5) 0.0147(2) 0.0204(12) Uani 1 1 d . . .
O122 O 0.2174(6) -0.0801(6) 0.0196(2) 0.0207(12) Uani 1 1 d . . .
O124 O 0.3578(6) 0.1445(6) -0.0340(2) 0.0225(12) Uani 1 1 d . . .
O126 O -0.1059(6) 0.0439(6) -0.0910(2) 0.0235(13) Uani 1 1 d . . .
N13 N 0.0369(7) -0.1001(7) -0.1709(3) 0.0199(14) Uani 1 1 d . . .
N15 N 0.2685(7) -0.1378(7) -0.1060(3) 0.0178(13) Uani 1 1 d . . .
C1 C 0.4455(10) 0.3446(10) -0.0728(4) 0.036(2) Uani 1 1 d . . .
H1A H 0.4740 0.3351 -0.1086 0.055 Uiso 1 1 calc R . .
H1B H 0.5278 0.3609 -0.0430 0.055 Uiso 1 1 calc R . .
H1C H 0.4064 0.4203 -0.0685 0.055 Uiso 1 1 calc R . .
C11 C 0.3853(9) -0.1520(9) -0.0750(3) 0.0236(18) Uani 1 1 d . . .
H11 H 0.4132 -0.1073 -0.0375 0.028 Uiso 1 1 calc R . .
C12 C -0.3170(10) 0.1149(11) -0.1091(4) 0.036(2) Uani 1 1 d . . .
H12A H -0.3956 0.1185 -0.0908 0.054 Uiso 1 1 calc R . .
H12B H -0.3519 0.0481 -0.1435 0.054 Uiso 1 1 calc R . .
H12C H -0.2743 0.2032 -0.1175 0.054 Uiso 1 1 calc R . .
C17 C 0.0570(8) -0.2550(8) -0.2520(3) 0.0153(15) Uani 1 1 d . . .
C21 C -0.0702(8) -0.2421(8) -0.2836(3) 0.0182(16) Uani 1 1 d . . .
C24 C -0.1305(9) -0.1482(8) -0.2593(3) 0.0213(17) Uani 1 1 d . . .
H24 H -0.2090 -0.1307 -0.2800 0.026 Uiso 1 1 calc R . .
C25 C 0.1045(8) -0.1853(8) -0.1949(3) 0.0160(15) Uani 1 1 d . . .
C26 C 0.3334(9) 0.2156(8) -0.0700(3) 0.0211(17) Uani 1 1 d . . .
C29 C 0.4293(8) -0.2999(8) -0.1508(3) 0.0186(16) Uani 1 1 d . . .
C37 C 0.0922(8) 0.2606(8) 0.0437(3) 0.0192(16) Uani 1 1 d . . .
C43 C 0.5133(8) -0.3883(8) -0.1739(3) 0.0180(16) Uani 1 1 d . . .
C44 C 0.1451(8) -0.3285(8) -0.2755(3) 0.0201(17) Uani 1 1 d . . .
H44 H 0.1184 -0.3698 -0.3135 0.024 Uiso 1 1 calc R . .
C46 C 0.3086(8) -0.2825(8) -0.1853(3) 0.0188(16) Uani 1 1 d . . .
C47 C -0.1376(8) -0.3271(8) -0.3406(3) 0.0173(16) Uani 1 1 d . . .
C50 C -0.2052(8) 0.0752(8) -0.0705(3) 0.0197(16) Uani 1 1 d . . .
C51 C 0.2305(8) -0.2023(8) -0.1611(3) 0.0164(15) Uani 1 1 d . . .
C52 C -0.1559(8) -0.4671(8) -0.3487(3) 0.0202(16) Uani 1 1 d . . .
H52 H -0.1227 -0.5054 -0.3190 0.024 Uiso 1 1 calc R . .
C56 C -0.1896(8) -0.2713(9) -0.3847(3) 0.0220(17) Uani 1 1 d . . .
H56 H -0.1802 -0.1781 -0.3795 0.026 Uiso 1 1 calc R . .
C65 C 0.4685(9) -0.2302(9) -0.0956(3) 0.0227(17) Uani 1 1 d . . .
H65 H 0.5502 -0.2352 -0.0722 0.027 Uiso 1 1 calc R . .
C70 C 0.6621(9) -0.3379(9) -0.1670(3) 0.0235(18) Uani 1 1 d . . .
H70 H 0.7101 -0.2490 -0.1477 0.028 Uiso 1 1 calc R . .
C74 C -0.2238(8) -0.5504(9) -0.4010(4) 0.0246(19) Uani 1 1 d . . .
H74 H -0.2358 -0.6441 -0.4065 0.029 Uiso 1 1 calc R . .
C76 C -0.2727(9) -0.4924(9) -0.4445(4) 0.0270(19) Uani 1 1 d . . .
H76 H -0.3178 -0.5473 -0.4796 0.032 Uiso 1 1 calc R . .
C78 C 0.2646(9) -0.3395(8) -0.2445(3) 0.0212(17) Uani 1 1 d . . .
H78 H 0.3207 -0.3853 -0.2618 0.025 Uiso 1 1 calc R . .
C81 C 0.1827(10) 0.3926(9) 0.0322(4) 0.035(2) Uani 1 1 d . . .
H81A H 0.1274 0.4228 0.0033 0.052 Uiso 1 1 calc R . .
H81B H 0.2663 0.3785 0.0198 0.052 Uiso 1 1 calc R . .
H81C H 0.2121 0.4610 0.0661 0.052 Uiso 1 1 calc R . .
C84 C 0.7393(9) -0.4198(9) -0.1889(4) 0.0258(19) Uani 1 1 d . . .
H84 H 0.8385 -0.3854 -0.1851 0.031 Uiso 1 1 calc R . .
C87 C -0.0733(9) -0.0796(8) -0.2036(3) 0.0213(17) Uani 1 1 d . . .
H87 H -0.1150 -0.0158 -0.1886 0.026 Uiso 1 1 calc R . .
C95 C -0.2558(9) -0.3553(9) -0.4367(3) 0.0262(19) Uani 1 1 d . . .
H95 H -0.2891 -0.3176 -0.4666 0.031 Uiso 1 1 calc R . .
C96 C 0.6675(9) -0.5533(9) -0.2164(4) 0.0276(19) Uani 1 1 d . . .
H96 H 0.7187 -0.6087 -0.2310 0.033 Uiso 1 1 calc R . .
C97 C 0.4435(9) -0.5231(9) -0.2014(3) 0.0234(17) Uani 1 1 d . . .
H97 H 0.3443 -0.5587 -0.2057 0.028 Uiso 1 1 calc R . .
C113 C 0.5224(9) -0.6035(8) -0.2222(4) 0.0261(18) Uani 1 1 d . . .
H113 H 0.4755 -0.6935 -0.2404 0.031 Uiso 1 1 calc R . .
C3 C 0.0148(13) -0.6483(14) -0.1802(5) 0.056(3) Uani 1 1 d . . .
H3 H -0.0706 -0.6542 -0.2043 0.067 Uiso 1 1 calc R . .
C7 C 0.0579(16) -0.5647(14) -0.1249(5) 0.068(4) Uani 1 1 d . . .
H7A H 0.1502 -0.4992 -0.1215 0.102 Uiso 1 1 calc R . .
H7B H 0.0640 -0.6216 -0.0971 0.102 Uiso 1 1 calc R . .
H7C H -0.0117 -0.5175 -0.1189 0.102 Uiso 1 1 calc R . .
O23 O 0.1089(7) -0.7211(7) -0.1962(3) 0.0349(15) Uani 1 1 d . . .
H23 H 0.1539 -0.7368 -0.1679 0.052 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N59 C8 H8 117.9 . . ?
N59 C8 C89 124.3(8) . . ?
C89 C8 H8 117.9 . . ?
C119 N33 C88 116.9(7) . . ?
C68 C35 H35 119.6 . . ?
C129 C35 H35 119.6 . . ?
C129 C35 C68 120.9(8) . . ?
C40 C39 C48 119.6(7) . . ?
C40 C39 C116 117.6(7) . . ?
C116 C39 C48 122.8(7) . . ?
C39 C40 C88 119.1(7) . . ?
N59 C40 C39 123.6(7) . . ?
N59 C40 C88 117.2(7) . . ?
C39 C48 H48 119.7 . . ?
C77 C48 C39 120.5(7) . . ?
C77 C48 H48 119.7 . . ?
C8 N59 C40 117.1(7) . . ?
C64 C63 C77 123.4(7) . . ?
C64 C63 C88 118.2(7) . . ?
C88 C63 C77 118.4(7) . . ?
C63 C64 C68 122.9(7) . . ?
C69 C64 C63 118.5(8) . . ?
C69 C64 C68 118.5(7) . . ?
C35 C68 C64 121.8(7) . . ?
C35 C68 C98 118.3(8) . . ?
C98 C68 C64 119.7(7) . . ?
C64 C69 H69 120.8 . . ?
C64 C69 C119 118.4(8) . . ?
C119 C69 H69 120.8 . . ?
C48 C77 C63 122.5(8) . . ?
C48 C77 H77 118.8 . . ?
C63 C77 H77 118.8 . . ?
C112 C80 H80 120.1 . . ?
C112 C80 C114 119.8(9) . . ?
C114 C80 H80 120.1 . . ?
C110 C85 H85 120.3 . . ?
C129 C85 H85 120.3 . . ?
C129 C85 C110 119.4(8) . . ?
N33 C88 C40 117.3(7) . . ?
N33 C88 C63 122.9(7) . . ?
C63 C88 C40 119.8(7) . . ?
C8 C89 H89 120.1 . . ?
C116 C89 C8 119.9(8) . . ?
C116 C89 H89 120.1 . . ?
C93 C91 H91 119.5 . . ?
C93 C91 C131 121.1(8) . . ?
C131 C91 H91 119.5 . . ?
C91 C93 H93 120.3 . . ?
C91 C93 C114 119.5(8) . . ?
C114 C93 H93 120.3 . . ?
C68 C98 H98 119.5 . . ?
C110 C98 C68 120.9(8) . . ?
C110 C98 H98 119.5 . . ?
C85 C110 H110 120.0 . . ?
C98 C110 C85 120.1(8) . . ?
C98 C110 H110 120.0 . . ?
C80 C112 H112 119.6 . . ?
C80 C112 C131 120.7(8) . . ?
C131 C112 H112 119.6 . . ?
C80 C114 C93 120.4(8) . . ?
C80 C114 H114 119.8 . . ?
C93 C114 H114 119.8 . . ?
C39 C116 C131 124.1(7) . . ?
C89 C116 C39 117.5(8) . . ?
C89 C116 C131 118.4(8) . . ?
N33 C119 C69 125.0(8) . . ?
N33 C119 H119 117.5 . . ?
C69 C119 H119 117.5 . . ?
C35 C129 C85 120.4(8) . . ?
C35 C129 H129 119.8 . . ?
C85 C129 H129 119.8 . . ?
C91 C131 C112 118.5(8) . . ?
C91 C131 C116 122.9(8) . . ?
C112 C131 C116 118.4(7) . . ?
O18 Eu1 Eu1 123.35(14) . 2 ?
O18 Eu1 O118 144.60(19) . . ?
O18 Eu1 O121 150.96(18) . 2 ?
O18 Eu1 O124 52.62(19) . . ?
O18 Eu1 N13 73.5(2) . . ?
O18 Eu1 N15 87.7(2) . . ?
O18 Eu1 C26 26.4(2) . . ?
O18 Eu1 C37 160.7(2) . 2 ?
O118 Eu1 Eu1 86.29(12) . 2 ?
O118 Eu1 O121 51.47(16) . 2 ?
O118 Eu1 O124 138.62(19) . . ?
O118 Eu1 N13 71.5(2) . . ?
O118 Eu1 N15 71.80(19) . . ?
O118 Eu1 C26 151.72(19) . . ?
O118 Eu1 C37 25.14(18) . 2 ?
O121 Eu1 Eu1 39.50(13) . 2 ?
O121 Eu1 Eu1 35.16(11) 2 2 ?
O121 Eu1 O18 87.4(2) . . ?
O121 Eu1 O118 125.43(18) . . ?
O121 Eu1 O121 74.7(2) . 2 ?
O121 Eu1 O122 76.66(18) . . ?
O121 Eu1 O124 77.73(18) . . ?
O121 Eu1 O126 74.54(18) . . ?
O121 Eu1 N13 145.36(19) . . ?
O121 Eu1 N13 109.03(19) 2 . ?
O121 Eu1 N15 146.53(19) . . ?
O121 Eu1 C26 80.8(2) . . ?
O121 Eu1 C26 155.36(19) 2 . ?
O121 Eu1 C37 26.38(18) 2 2 ?
O121 Eu1 C37 100.5(2) . 2 ?
O122 Eu1 Eu1 69.57(12) . 2 ?
O122 Eu1 O18 127.08(19) . . ?
O122 Eu1 O118 78.46(19) . . ?
O122 Eu1 O121 71.32(18) . 2 ?
O122 Eu1 O124 74.63(19) . . ?
O122 Eu1 N13 137.82(19) . . ?
O122 Eu1 N15 80.13(18) . . ?
O122 Eu1 C26 100.7(2) . . ?
O122 Eu1 C37 72.1(2) . 2 ?
O124 Eu1 Eu1 112.25(12) . 2 ?
O124 Eu1 O121 140.04(17) . 2 ?
O124 Eu1 N13 110.14(19) . . ?
O124 Eu1 N15 73.05(19) . . ?
O124 Eu1 C26 26.3(2) . . ?
O124 Eu1 C37 146.1(2) . 2 ?
O126 Eu1 Eu1 68.31(13) . 2 ?
O126 Eu1 O18 82.0(2) . . ?
O126 Eu1 O118 93.6(2) . . ?
O126 Eu1 O121 71.39(19) . 2 ?
O126 Eu1 O122 137.54(18) . . ?
O126 Eu1 O124 127.3(2) . . ?
O126 Eu1 N13 74.39(18) . . ?
O126 Eu1 N15 137.22(19) . . ?
O126 Eu1 C26 104.7(2) . . ?
O126 Eu1 C37 83.2(2) . 2 ?
N13 Eu1 Eu1 134.94(14) . 2 ?
N13 Eu1 C26 92.6(2) . . ?
N13 Eu1 C37 90.6(2) . 2 ?
N15 Eu1 Eu1 145.67(14) . 2 ?
N15 Eu1 O121 119.79(18) . 2 ?
N15 Eu1 N13 62.88(19) . . ?
N15 Eu1 C26 80.2(2) . . ?
N15 Eu1 C37 94.9(2) . 2 ?
C26 Eu1 Eu1 120.29(15) . 2 ?
C26 Eu1 C37 172.0(2) . 2 ?
C37 Eu1 Eu1 61.17(15) 2 2 ?
C26 O18 Eu1 94.5(5) . . ?
C37 O118 Eu1 97.9(5) 2 . ?
Eu1 O121 Eu1 105.3(2) . 2 ?
C37 O121 Eu1 160.5(5) . . ?
C37 O121 Eu1 90.2(4) . 2 ?
C50 O122 Eu1 136.5(5) 2 . ?
C26 O124 Eu1 92.5(5) . . ?
C50 O126 Eu1 139.1(5) . . ?
C25 N13 Eu1 118.6(5) . . ?
C87 N13 Eu1 123.5(5) . . ?
C87 N13 C25 117.3(6) . . ?
C11 N15 Eu1 121.0(5) . . ?
C11 N15 C51 117.3(6) . . ?
C51 N15 Eu1 121.5(5) . . ?
H1A C1 H1B 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C26 C1 H1A 109.5 . . ?
C26 C1 H1B 109.5 . . ?
C26 C1 H1C 109.5 . . ?
N15 C11 H11 118.1 . . ?
N15 C11 C65 123.8(7) . . ?
C65 C11 H11 118.1 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C50 C12 H12A 109.5 . . ?
C50 C12 H12B 109.5 . . ?
C50 C12 H12C 109.5 . . ?
C21 C17 C25 118.6(6) . . ?
C21 C17 C44 123.2(7) . . ?
C25 C17 C44 118.1(7) . . ?
C17 C21 C47 121.5(6) . . ?
C24 C21 C17 117.5(7) . . ?
C24 C21 C47 121.0(7) . . ?
C21 C24 H24 120.1 . . ?
C21 C24 C87 119.9(7) . . ?
C87 C24 H24 120.1 . . ?
N13 C25 C17 122.3(7) . . ?
N13 C25 C51 118.3(6) . . ?
C17 C25 C51 119.4(6) . . ?
O18 C26 Eu1 59.2(4) . . ?
O18 C26 C1 119.2(8) . . ?
O124 C26 Eu1 61.2(4) . . ?
O124 C26 O18 120.3(7) . . ?
O124 C26 C1 120.5(8) . . ?
C1 C26 Eu1 174.9(6) . . ?
C46 C29 C43 121.1(7) . . ?
C65 C29 C43 121.4(7) . . ?
C65 C29 C46 117.5(7) . . ?
O118 C37 Eu1 56.9(4) 2 2 ?
O118 C37 O121 120.2(7) 2 . ?
O118 C37 C81 121.1(7) 2 . ?
O121 C37 Eu1 63.4(4) . 2 ?
O121 C37 C81 118.7(7) . . ?
C81 C37 Eu1 174.2(6) . 2 ?
C70 C43 C29 120.4(7) . . ?
C70 C43 C97 119.2(7) . . ?
C97 C43 C29 120.4(7) . . ?
C17 C44 H44 119.0 . . ?
C78 C44 C17 122.0(7) . . ?
C78 C44 H44 119.0 . . ?
C29 C46 C78 122.8(7) . . ?
C51 C46 C29 118.9(7) . . ?
C51 C46 C78 118.2(7) . . ?
C52 C47 C21 119.1(7) . . ?
C56 C47 C21 121.5(7) . . ?
C56 C47 C52 119.4(7) . . ?
O122 C50 C12 116.7(6) 2 . ?
O126 C50 O122 125.4(7) . 2 ?
O126 C50 C12 117.9(7) . . ?
N15 C51 C25 117.2(6) . . ?
N15 C51 C46 122.6(7) . . ?
C46 C51 C25 120.2(7) . . ?
C47 C52 H52 119.8 . . ?
C47 C52 C74 120.5(8) . . ?
C74 C52 H52 119.8 . . ?
C47 C56 H56 120.2 . . ?
C47 C56 C95 119.5(8) . . ?
C95 C56 H56 120.2 . . ?
C11 C65 H65 120.1 . . ?
C29 C65 C11 119.9(7) . . ?
C29 C65 H65 120.1 . . ?
C43 C70 H70 119.9 . . ?
C84 C70 C43 120.2(8) . . ?
C84 C70 H70 119.9 . . ?
C52 C74 H74 120.4 . . ?
C76 C74 C52 119.1(8) . . ?
C76 C74 H74 120.4 . . ?
C74 C76 H76 119.7 . . ?
C95 C76 C74 120.7(8) . . ?
C95 C76 H76 119.7 . . ?
C44 C78 C46 121.7(7) . . ?
C44 C78 H78 119.2 . . ?
C46 C78 H78 119.2 . . ?
C37 C81 H81A 109.5 . . ?
C37 C81 H81B 109.5 . . ?
C37 C81 H81C 109.5 . . ?
H81A C81 H81B 109.5 . . ?
H81A C81 H81C 109.5 . . ?
H81B C81 H81C 109.5 . . ?
C70 C84 H84 120.2 . . ?
C96 C84 C70 119.5(8) . . ?
C96 C84 H84 120.2 . . ?
N13 C87 C24 123.9(7) . . ?
N13 C87 H87 118.0 . . ?
C24 C87 H87 118.0 . . ?
C56 C95 H95 119.6 . . ?
C76 C95 C56 120.8(8) . . ?
C76 C95 H95 119.6 . . ?
C84 C96 H96 119.9 . . ?
C113 C96 C84 120.2(7) . . ?
C113 C96 H96 119.9 . . ?
C43 C97 H97 120.1 . . ?
C113 C97 C43 119.7(8) . . ?
C113 C97 H97 120.1 . . ?
C96 C113 C97 121.1(8) . . ?
C96 C113 H113 119.5 . . ?
C97 C113 H113 119.5 . . ?
C7 C3 H3 121.8 . . ?
O23 C3 H3 121.8 . . ?
O23 C3 C7 116.3(10) . . ?
C3 C7 H7A 109.5 . . ?
C3 C7 H7B 109.5 . . ?
C3 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C3 O23 H23 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C8 H8 0.9300 . ?
C8 N59 1.324(11) . ?
C8 C89 1.394(12) . ?
N33 C88 1.359(10) . ?
N33 C119 1.314(11) . ?
C35 H35 0.9300 . ?
C35 C68 1.398(11) . ?
C35 C129 1.379(12) . ?
C39 C40 1.420(11) . ?
C39 C48 1.432(11) . ?
C39 C116 1.427(11) . ?
C40 N59 1.343(10) . ?
C40 C88 1.459(11) . ?
C48 H48 0.9300 . ?
C48 C77 1.354(11) . ?
C63 C64 1.414(11) . ?
C63 C77 1.434(11) . ?
C63 C88 1.415(11) . ?
C64 C68 1.485(11) . ?
C64 C69 1.375(11) . ?
C68 C98 1.402(11) . ?
C69 H69 0.9300 . ?
C69 C119 1.412(12) . ?
C77 H77 0.9300 . ?
C80 H80 0.9300 . ?
C80 C112 1.380(12) . ?
C80 C114 1.382(13) . ?
C85 H85 0.9300 . ?
C85 C110 1.399(13) . ?
C85 C129 1.386(12) . ?
C89 H89 0.9300 . ?
C89 C116 1.380(11) . ?
C91 H91 0.9300 . ?
C91 C93 1.382(11) . ?
C91 C131 1.391(11) . ?
C93 H93 0.9300 . ?
C93 C114 1.388(12) . ?
C98 H98 0.9300 . ?
C98 C110 1.375(12) . ?
C110 H110 0.9300 . ?
C112 H112 0.9300 . ?
C112 C131 1.398(12) . ?
C114 H114 0.9300 . ?
C116 C131 1.498(12) . ?
C119 H119 0.9300 . ?
C129 H129 0.9300 . ?
Eu1 Eu1 3.9357(10) 2 ?
Eu1 O18 2.440(6) . ?
Eu1 O118 2.456(6) . ?
Eu1 O121 2.596(5) 2 ?
Eu1 O121 2.350(5) . ?
Eu1 O122 2.372(5) . ?
Eu1 O124 2.486(5) . ?
Eu1 O126 2.370(5) . ?
Eu1 N13 2.631(6) . ?
Eu1 N15 2.576(6) . ?
Eu1 C26 2.833(8) . ?
Eu1 C37 2.903(8) 2 ?
O18 C26 1.263(10) . ?
O118 C37 1.245(9) 2 ?
O121 Eu1 2.596(5) 2 ?
O121 C37 1.289(9) . ?
O122 C50 1.262(9) 2 ?
O124 C26 1.255(10) . ?
O126 C50 1.262(9) . ?
N13 C25 1.364(9) . ?
N13 C87 1.327(10) . ?
N15 C11 1.329(10) . ?
N15 C51 1.363(9) . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C1 C26 1.501(12) . ?
C11 H11 0.9300 . ?
C11 C65 1.397(11) . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C12 C50 1.514(11) . ?
C17 C21 1.413(10) . ?
C17 C25 1.420(10) . ?
C17 C44 1.431(10) . ?
C21 C24 1.381(10) . ?
C21 C47 1.485(10) . ?
C24 H24 0.9300 . ?
C24 C87 1.396(11) . ?
C25 C51 1.445(10) . ?
C29 C43 1.498(10) . ?
C29 C46 1.413(11) . ?
C29 C65 1.380(11) . ?
C37 Eu1 2.903(8) 2 ?
C37 O118 1.245(9) 2 ?
C37 C81 1.503(12) . ?
C43 C70 1.391(11) . ?
C43 C97 1.393(11) . ?
C44 H44 0.9300 . ?
C44 C78 1.338(11) . ?
C46 C51 1.406(10) . ?
C46 C78 1.434(10) . ?
C47 C52 1.389(11) . ?
C47 C56 1.383(11) . ?
C50 O122 1.262(9) 2 ?
C52 H52 0.9300 . ?
C52 C74 1.393(11) . ?
C56 H56 0.9300 . ?
C56 C95 1.387(11) . ?
C65 H65 0.9300 . ?
C70 H70 0.9300 . ?
C70 C84 1.390(10) . ?
C74 H74 0.9300 . ?
C74 C76 1.374(13) . ?
C76 H76 0.9300 . ?
C76 C95 1.362(12) . ?
C78 H78 0.9300 . ?
C81 H81A 0.9600 . ?
C81 H81B 0.9600 . ?
C81 H81C 0.9600 . ?
C84 H84 0.9300 . ?
C84 C96 1.386(12) . ?
C87 H87 0.9300 . ?
C95 H95 0.9300 . ?
C96 H96 0.9300 . ?
C96 C113 1.359(12) . ?
C97 H97 0.9300 . ?
C97 C113 1.381(11) . ?
C113 H113 0.9300 . ?
C3 H3 0.9300 . ?
C3 C7 1.434(16) . ?
C3 O23 1.408(11) . ?
C7 H7A 0.9600 . ?
C7 H7B 0.9600 . ?
C7 H7C 0.9600 . ?
O23 H23 0.8200 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C8 C89 C116 C39 -0.3(12) . . . . ?
C8 C89 C116 C131 177.1(7) . . . . ?
C35 C68 C98 C110 -0.5(11) . . . . ?
C39 C40 N59 C8 0.9(12) . . . . ?
C39 C40 C88 N33 -179.2(7) . . . . ?
C39 C40 C88 C63 0.5(11) . . . . ?
C39 C48 C77 C63 0.6(12) . . . . ?
C39 C116 C131 C91 -57.1(12) . . . . ?
C39 C116 C131 C112 128.5(9) . . . . ?
C40 C39 C48 C77 2.7(11) . . . . ?
C40 C39 C116 C89 1.2(11) . . . . ?
C40 C39 C116 C131 -176.1(7) . . . . ?
C48 C39 C40 N59 -180.0(7) . . . . ?
C48 C39 C40 C88 -3.2(11) . . . . ?
C48 C39 C116 C89 179.6(7) . . . . ?
C48 C39 C116 C131 2.2(12) . . . . ?
N59 C8 C89 C116 -0.4(14) . . . . ?
N59 C40 C88 N33 -2.2(11) . . . . ?
N59 C40 C88 C63 177.5(7) . . . . ?
C63 C64 C68 C35 -61.3(10) . . . . ?
C63 C64 C68 C98 124.2(8) . . . . ?
C63 C64 C69 C119 0.7(11) . . . . ?
C64 C63 C77 C48 177.2(8) . . . . ?
C64 C63 C88 N33 1.9(11) . . . . ?
C64 C63 C88 C40 -177.8(7) . . . . ?
C64 C68 C98 C110 174.2(7) . . . . ?
C64 C69 C119 N33 0.8(13) . . . . ?
C68 C35 C129 C85 -2.0(12) . . . . ?
C68 C64 C69 C119 -179.7(7) . . . . ?
C68 C98 C110 C85 -1.0(12) . . . . ?
C69 C64 C68 C35 119.1(9) . . . . ?
C69 C64 C68 C98 -55.4(10) . . . . ?
C77 C63 C64 C68 -2.0(12) . . . . ?
C77 C63 C64 C69 177.6(7) . . . . ?
C77 C63 C88 N33 -177.7(7) . . . . ?
C77 C63 C88 C40 2.6(11) . . . . ?
C80 C112 C131 C91 1.8(13) . . . . ?
C80 C112 C131 C116 176.4(8) . . . . ?
C88 N33 C119 C69 -0.9(12) . . . . ?
C88 C40 N59 C8 -175.9(7) . . . . ?
C88 C63 C64 C68 178.5(7) . . . . ?
C88 C63 C64 C69 -1.9(11) . . . . ?
C88 C63 C77 C48 -3.3(11) . . . . ?
C89 C8 N59 C40 0.1(13) . . . . ?
C89 C116 C131 C91 125.6(9) . . . . ?
C89 C116 C131 C112 -48.9(11) . . . . ?
C91 C93 C114 C80 1.3(13) . . . . ?
C93 C91 C131 C112 -0.8(13) . . . . ?
C93 C91 C131 C116 -175.2(8) . . . . ?
C110 C85 C129 C35 0.4(12) . . . . ?
C112 C80 C114 C93 -0.3(14) . . . . ?
C114 C80 C112 C131 -1.2(13) . . . . ?
C116 C39 C40 N59 -1.6(11) . . . . ?
C116 C39 C40 C88 175.1(7) . . . . ?
C116 C39 C48 C77 -175.5(8) . . . . ?
C119 N33 C88 C40 179.2(7) . . . . ?
C119 N33 C88 C63 -0.5(11) . . . . ?
C129 C35 C68 C64 -172.6(7) . . . . ?
C129 C35 C68 C98 2.0(11) . . . . ?
C129 C85 C110 C98 1.0(12) . . . . ?
C131 C91 C93 C114 -0.7(13) . . . . ?
Eu1 Eu1 O18 C26 91.8(4) 2 . . . ?
Eu1 Eu1 O118 C37 2.5(5) 2 . . 2 ?
Eu1 Eu1 O121 C37 -141.8(16) 2 . . . ?
Eu1 Eu1 O122 C50 -10.9(7) 2 . . 2 ?
Eu1 Eu1 O124 C26 -113.7(4) 2 . . . ?
Eu1 Eu1 O126 C50 7.3(8) 2 . . . ?
Eu1 Eu1 N13 C25 -132.6(5) 2 . . . ?
Eu1 Eu1 N13 C87 38.8(7) 2 . . . ?
Eu1 Eu1 N15 C11 -51.6(7) 2 . . . ?
Eu1 Eu1 N15 C51 122.4(5) 2 . . . ?
Eu1 Eu1 C26 O18 -104.8(4) 2 . . . ?
Eu1 Eu1 C26 O124 78.9(4) 2 . . . ?
Eu1 Eu1 C26 C1 -32(7) 2 . . . ?
Eu1 O18 C26 O124 3.7(7) . . . . ?
Eu1 O18 C26 C1 -174.4(6) . . . . ?
Eu1 O121 C37 Eu1 143.4(15) . . . 2 ?
Eu1 O121 C37 O118 4.8(8) 2 . . 2 ?
Eu1 O121 C37 O118 148.2(12) . . . 2 ?
Eu1 O121 C37 C81 -30(2) . . . . ?
Eu1 O121 C37 C81 -173.9(7) 2 . . . ?
Eu1 O124 C26 O18 -3.6(7) . . . . ?
Eu1 O124 C26 C1 174.4(7) . . . . ?
Eu1 O126 C50 O122 -2.8(14) . . . 2 ?
Eu1 O126 C50 C12 175.1(6) . . . . ?
Eu1 N13 C25 C17 169.3(6) . . . . ?
Eu1 N13 C25 C51 -11.9(9) . . . . ?
Eu1 N13 C87 C24 -166.2(6) . . . . ?
Eu1 N15 C11 C65 173.3(6) . . . . ?
Eu1 N15 C51 C25 6.6(9) . . . . ?
Eu1 N15 C51 C46 -173.5(6) . . . . ?
O18 Eu1 O118 C37 -146.8(5) . . . 2 ?
O18 Eu1 O121 Eu1 156.9(2) . . . 2 ?
O18 Eu1 O121 C37 15.1(15) . . . . ?
O18 Eu1 O122 C50 106.1(8) . . . 2 ?
O18 Eu1 O124 C26 2.0(4) . . . . ?
O18 Eu1 O126 C50 -123.5(8) . . . . ?
O18 Eu1 N13 C25 106.4(6) . . . . ?
O18 Eu1 N13 C87 -82.1(6) . . . . ?
O18 Eu1 N15 C11 104.7(6) . . . . ?
O18 Eu1 N15 C51 -81.3(6) . . . . ?
O18 Eu1 C26 O124 -176.3(7) . . . . ?
O18 Eu1 C26 C1 72(7) . . . . ?
O118 Eu1 O18 C26 -125.8(5) . . . . ?
O118 Eu1 O121 Eu1 -8.9(3) . . . 2 ?
O118 Eu1 O121 C37 -150.7(15) . . . . ?
O118 Eu1 O122 C50 -101.2(8) . . . 2 ?
O118 Eu1 O124 C26 135.3(4) . . . . ?
O118 Eu1 O126 C50 91.8(8) . . . . ?
O118 Eu1 N13 C25 -68.1(6) . . . . ?
O118 Eu1 N13 C87 103.4(6) . . . . ?
O118 Eu1 N15 C11 -104.6(6) . . . . ?
O118 Eu1 N15 C51 69.4(6) . . . . ?
O118 Eu1 C26 O18 97.2(6) . . . . ?
O118 Eu1 C26 O124 -79.2(6) . . . . ?
O118 Eu1 C26 C1 170(7) . . . . ?
O121 Eu1 O18 C26 74.5(5) . . . . ?
O121 Eu1 O18 C26 125.6(5) 2 . . . ?
O121 Eu1 O118 C37 8.2(6) . . . 2 ?
O121 Eu1 O118 C37 -2.8(4) 2 . . 2 ?
O121 Eu1 O121 Eu1 -0.001(1) 2 . . 2 ?
O121 Eu1 O121 C37 -141.8(16) 2 . . . ?
O121 Eu1 O122 C50 29.8(7) . . . 2 ?
O121 Eu1 O122 C50 -48.2(7) 2 . . 2 ?
O121 Eu1 O124 C26 -94.2(4) . . . . ?
O121 Eu1 O124 C26 -141.2(4) 2 . . . ?
O121 Eu1 O126 C50 44.7(8) 2 . . . ?
O121 Eu1 O126 C50 -34.0(8) . . . . ?
O121 Eu1 N13 C25 -104.0(6) 2 . . . ?
O121 Eu1 N13 C25 165.6(5) . . . . ?
O121 Eu1 N13 C87 -22.9(8) . . . . ?
O121 Eu1 N13 C87 67.5(6) 2 . . . ?
O121 Eu1 N15 C11 22.9(8) . . . . ?
O121 Eu1 N15 C11 -85.3(6) 2 . . . ?
O121 Eu1 N15 C51 88.7(6) 2 . . . ?
O121 Eu1 N15 C51 -163.1(5) . . . . ?
O121 Eu1 C26 O18 -102.9(5) . . . . ?
O121 Eu1 C26 O18 -108.9(6) 2 . . . ?
O121 Eu1 C26 O124 74.8(7) 2 . . . ?
O121 Eu1 C26 O124 80.8(4) . . . . ?
O121 Eu1 C26 C1 -30(7) . . . . ?
O121 Eu1 C26 C1 -36(7) 2 . . . ?
O122 Eu1 O18 C26 3.4(5) . . . . ?
O122 Eu1 O118 C37 72.4(5) . . . 2 ?
O122 Eu1 O121 Eu1 -74.0(2) . . . 2 ?
O122 Eu1 O121 C37 144.2(15) . . . . ?
O122 Eu1 O124 C26 -173.5(5) . . . . ?
O122 Eu1 O126 C50 14.9(10) . . . . ?
O122 Eu1 N13 C25 -21.1(7) . . . . ?
O122 Eu1 N13 C87 150.4(6) . . . . ?
O122 Eu1 N15 C11 -23.6(6) . . . . ?
O122 Eu1 N15 C51 150.4(6) . . . . ?
O122 Eu1 C26 O18 -177.3(4) . . . . ?
O122 Eu1 C26 O124 6.4(4) . . . . ?
O122 Eu1 C26 C1 -105(7) . . . . ?
O124 Eu1 O18 C26 -2.0(4) . . . . ?
O124 Eu1 O118 C37 122.5(5) . . . 2 ?
O124 Eu1 O121 Eu1 -150.8(2) . . . 2 ?
O124 Eu1 O121 C37 67.3(15) . . . . ?
O124 Eu1 O122 C50 110.6(8) . . . 2 ?
O124 Eu1 O126 C50 -94.8(8) . . . . ?
O124 Eu1 N13 C25 68.0(6) . . . . ?
O124 Eu1 N13 C87 -120.5(6) . . . . ?
O124 Eu1 N15 C11 53.2(6) . . . . ?
O124 Eu1 N15 C51 -132.8(6) . . . . ?
O124 Eu1 C26 O18 176.3(7) . . . . ?
O124 Eu1 C26 C1 -111(7) . . . . ?
O126 Eu1 O18 C26 149.2(5) . . . . ?
O126 Eu1 O118 C37 -65.4(5) . . . 2 ?
O126 Eu1 O121 Eu1 74.5(2) . . . 2 ?
O126 Eu1 O121 C37 -67.3(15) . . . . ?
O126 Eu1 O122 C50 -18.5(9) . . . 2 ?
O126 Eu1 O124 C26 -34.7(5) . . . . ?
O126 Eu1 N13 C25 -167.4(6) . . . . ?
O126 Eu1 N13 C87 4.0(6) . . . . ?
O126 Eu1 N15 C11 -179.7(6) . . . . ?
O126 Eu1 N15 C51 -5.7(7) . . . . ?
O126 Eu1 C26 O18 -31.6(5) . . . . ?
O126 Eu1 C26 O124 152.1(4) . . . . ?
O126 Eu1 C26 C1 41(7) . . . . ?
N13 Eu1 O18 C26 -134.8(5) . . . . ?
N13 Eu1 O118 C37 -137.6(5) . . . 2 ?
N13 Eu1 O121 Eu1 101.4(3) . . . 2 ?
N13 Eu1 O121 C37 -40.4(17) . . . . ?
N13 Eu1 O122 C50 -146.2(7) . . . 2 ?
N13 Eu1 O124 C26 50.6(5) . . . . ?
N13 Eu1 O126 C50 161.5(9) . . . . ?
N13 Eu1 N15 C11 177.3(7) . . . . ?
N13 Eu1 N15 C51 -8.7(5) . . . . ?
N13 Eu1 C26 O18 42.9(5) . . . . ?
N13 Eu1 C26 O124 -133.4(4) . . . . ?
N13 Eu1 C26 C1 115(7) . . . . ?
N13 C25 C51 N15 3.8(11) . . . . ?
N13 C25 C51 C46 -176.1(7) . . . . ?
N15 Eu1 O18 C26 -72.4(5) . . . . ?
N15 Eu1 O118 C37 155.7(5) . . . 2 ?
N15 Eu1 O121 Eu1 -121.3(3) . . . 2 ?
N15 Eu1 O121 C37 96.9(15) . . . . ?
N15 Eu1 O122 C50 -174.5(8) . . . 2 ?
N15 Eu1 O124 C26 102.4(4) . . . . ?
N15 Eu1 O126 C50 158.8(8) . . . . ?
N15 Eu1 N13 C25 10.5(5) . . . . ?
N15 Eu1 N13 C87 -178.1(7) . . . . ?
N15 Eu1 C26 O18 104.8(5) . . . . ?
N15 Eu1 C26 O124 -71.5(4) . . . . ?
N15 Eu1 C26 C1 177(100) . . . . ?
N15 C11 C65 C29 -1.1(13) . . . . ?
C11 N15 C51 C25 -179.2(7) . . . . ?
C11 N15 C51 C46 0.7(11) . . . . ?
C17 C21 C24 C87 -5.8(12) . . . . ?
C17 C21 C47 C52 46.7(11) . . . . ?
C17 C21 C47 C56 -136.9(8) . . . . ?
C17 C25 C51 N15 -177.4(7) . . . . ?
C17 C25 C51 C46 2.7(11) . . . . ?
C17 C44 C78 C46 2.4(13) . . . . ?
C21 C17 C25 N13 -4.1(12) . . . . ?
C21 C17 C25 C51 177.1(7) . . . . ?
C21 C17 C44 C78 -179.7(8) . . . . ?
C21 C24 C87 N13 -1.1(13) . . . . ?
C21 C47 C52 C74 177.6(7) . . . . ?
C21 C47 C56 C95 -178.0(7) . . . . ?
C24 C21 C47 C52 -132.6(8) . . . . ?
C24 C21 C47 C56 43.8(11) . . . . ?
C25 N13 C87 C24 5.4(12) . . . . ?
C25 C17 C21 C24 8.2(11) . . . . ?
C25 C17 C21 C47 -171.2(7) . . . . ?
C25 C17 C44 C78 4.0(12) . . . . ?
C26 Eu1 O118 C37 163.7(5) . . . 2 ?
C26 Eu1 O121 Eu1 -177.4(3) . . . 2 ?
C26 Eu1 O121 C37 40.8(15) . . . . ?
C26 Eu1 O122 C50 107.6(8) . . . 2 ?
C26 Eu1 O126 C50 -109.9(8) . . . . ?
C26 Eu1 N13 C25 88.0(6) . . . . ?
C26 Eu1 N13 C87 -100.5(6) . . . . ?
C26 Eu1 N15 C11 79.2(6) . . . . ?
C26 Eu1 N15 C51 -106.8(6) . . . . ?
C29 C43 C70 C84 -179.5(8) . . . . ?
C29 C43 C97 C113 -179.7(7) . . . . ?
C29 C46 C51 N15 1.6(12) . . . . ?
C29 C46 C51 C25 -178.5(7) . . . . ?
C29 C46 C78 C44 175.9(8) . . . . ?
C37 Eu1 O18 C26 -170.5(6) 2 . . . ?
C37 Eu1 O121 Eu1 -5.3(2) 2 . . 2 ?
C37 Eu1 O121 C37 -147.2(14) 2 . . . ?
C37 Eu1 O122 C50 -76.0(8) 2 . . 2 ?
C37 Eu1 O124 C26 175.2(4) 2 . . . ?
C37 Eu1 O126 C50 68.9(8) 2 . . . ?
C37 Eu1 N13 C25 -84.7(6) 2 . . . ?
C37 Eu1 N13 C87 86.8(6) 2 . . . ?
C37 Eu1 N15 C11 -94.5(6) 2 . . . ?
C37 Eu1 N15 C51 79.5(6) 2 . . . ?
C37 Eu1 C26 O18 156.8(14) 2 . . . ?
C37 Eu1 C26 O124 -19.5(18) 2 . . . ?
C37 Eu1 C26 C1 -131(7) 2 . . . ?
C43 C29 C46 C51 177.9(7) . . . . ?
C43 C29 C46 C78 -4.2(12) . . . . ?
C43 C29 C65 C11 -178.1(7) . . . . ?
C43 C70 C84 C96 -1.6(13) . . . . ?
C43 C97 C113 C96 -0.1(13) . . . . ?
C44 C17 C21 C24 -168.1(8) . . . . ?
C44 C17 C21 C47 12.5(12) . . . . ?
C44 C17 C25 N13 172.4(7) . . . . ?
C44 C17 C25 C51 -6.4(11) . . . . ?
C46 C29 C43 C70 128.3(8) . . . . ?
C46 C29 C43 C97 -53.2(11) . . . . ?
C46 C29 C65 C11 3.3(12) . . . . ?
C47 C21 C24 C87 173.5(7) . . . . ?
C47 C52 C74 C76 -0.1(12) . . . . ?
C47 C56 C95 C76 1.2(12) . . . . ?
C51 N15 C11 C65 -1.0(12) . . . . ?
C51 C46 C78 C44 -6.1(12) . . . . ?
C52 C47 C56 C95 -1.6(11) . . . . ?
C52 C74 C76 C95 -0.3(12) . . . . ?
C56 C47 C52 C74 1.1(11) . . . . ?
C65 C29 C43 C70 -50.2(11) . . . . ?
C65 C29 C43 C97 128.2(9) . . . . ?
C65 C29 C46 C51 -3.5(11) . . . . ?
C65 C29 C46 C78 174.4(8) . . . . ?
C70 C43 C97 C113 -1.2(12) . . . . ?
C70 C84 C96 C113 0.2(14) . . . . ?
C74 C76 C95 C56 -0.3(12) . . . . ?
C78 C46 C51 N15 -176.4(7) . . . . ?
C78 C46 C51 C25 3.5(11) . . . . ?
C84 C96 C113 C97 0.6(14) . . . . ?
C87 N13 C25 C17 -2.7(11) . . . . ?
C87 N13 C25 C51 176.1(7) . . . . ?
C97 C43 C70 C84 2.1(12) . . . . ?
