#------------------------------------------------------------------------------
#$Date: 2021-10-06 18:41:33 +0300 (Wed, 06 Oct 2021) $
#$Revision: 269725 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/80/7708038.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7708038
loop_
_publ_author_name
'Rummel, Lena'
'Lassandro, Giuliano'
'Seidl, Michael'
'Timoshkin, Alexey Y.'
'Scheer, Manfred'
_publ_section_title
;
 Reactivity of the pentelidene complexes
 [Cp*E{W(CO)₅}₂] (E = P, As) towards dichalcogenides
 and chalcogenols - synthesis of novel chalcogenopentelidene complexes.
;
_journal_issue                   36
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12648
_journal_page_last               12654
_journal_paper_doi               10.1039/d1dt01866c
_journal_volume                  50
_journal_year                    2021
_chemical_formula_moiety         'C16 H5 O10 P Se W2'
_chemical_formula_sum            'C16 H5 O10 P Se W2'
_chemical_formula_weight         834.83
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2021-05-07
_audit_creation_method
;
Olex2 1.3-alpha
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_audit_update_record
;
2021-05-13 deposited with the CCDC.	2021-08-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 99.7400(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.01510(10)
_cell_length_b                   16.4460(2)
_cell_length_c                   18.4907(2)
_cell_measurement_reflns_used    13435
_cell_measurement_temperature    123(1)
_cell_measurement_theta_max      71.7750
_cell_measurement_theta_min      4.8240
_cell_volume                     2102.53(5)
_computing_cell_refinement       'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_data_collection       'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.41.81a (Rigaku OD, 2020)'
_computing_molecular_graphics    'Olex2 1.3-alpha (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3-alpha (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      123(1)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 5.2548
_diffrn_detector_type            AtlasS2
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -40.00  27.00   1.00    7.50    --   41.28 -19.00  90.00   67
  2  ω    -40.00  27.00   1.00    7.50    --   41.28 -19.00-180.00   67
  3  ω    -40.00  27.00   1.00    7.50    --   41.28 -19.00-150.00   67
  4  ω     30.00  71.00   1.00   22.50    --  104.28 -61.00-180.00   41
  5  ω     30.00  71.00   1.00   22.50    --  104.28 -61.00  30.00   41
  6  ω     30.00  71.00   1.00   22.50    --  104.28 -61.00-150.00   41
  7  ω     26.00  83.00   1.00   22.50    --  104.28-111.00 150.00   57
  8  ω     74.00 178.00   1.00   22.50    --  104.28  61.00 -90.00  104
  9  ω     30.00  71.00   1.00   22.50    --  104.28 -61.00 120.00   41
 10  ω     26.00 105.00   1.00   22.50    --  104.28 -77.00 -30.00   79
 11  ω     77.00 178.00   1.00   22.50    --  104.28  45.00  30.00  101
 12  ω     12.00 115.00   1.00    7.50    --   41.28  57.00 -30.00  103
 13  ω     -5.00 123.00   1.00    7.50    --   41.28  19.00-120.00  128
 14  ω     43.00 178.00   1.00   22.50    --  104.28  15.00-180.00  135
 15  ω     74.00 178.00   1.00   22.50    --  104.28  61.00 -30.00  104
 16  ω     74.00 178.00   1.00   22.50    --  104.28  61.00-150.00  104
 17  ω     74.00 178.00   1.00   22.50    --  104.28  61.00  60.00  104
 18  ω     26.00 105.00   1.00   22.50    --  104.28 -77.00-180.00   79
 19  ω     30.00  71.00   1.00   22.50    --  104.28 -61.00 -90.00   41
 20  ω    -99.00 -22.00   1.00    7.50    --  -41.28 125.00 -30.00   77
 21  ω     12.00 115.00   1.00    7.50    --   41.28  57.00  90.00  103
 22  ω     74.00 178.00   1.00   22.50    --  104.28  61.00 150.00  104
 23  ω     74.00 153.00   1.00   22.50    --  104.28  61.00-120.00   79
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, AtlasS2, Gemini ultra'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0410140000
_diffrn_orient_matrix_UB_12      -0.0506953000
_diffrn_orient_matrix_UB_13      0.0657433000
_diffrn_orient_matrix_UB_21      -0.1501714000
_diffrn_orient_matrix_UB_22      -0.0503968000
_diffrn_orient_matrix_UB_23      -0.0517847000
_diffrn_orient_matrix_UB_31      0.1593912000
_diffrn_orient_matrix_UB_32      -0.0605321000
_diffrn_orient_matrix_UB_33      -0.0119453000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0470
_diffrn_reflns_av_unetI/netI     0.0279
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            22285
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         72.061
_diffrn_reflns_theta_min         3.620
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance Ultra (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    23.108
_exptl_absorpt_correction_T_max  0.647
_exptl_absorpt_correction_T_min  0.148
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.81a (Rigaku Oxford Diffraction, 2020)
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'dark red'
_exptl_crystal_colour_modifier   dark
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    2.637
_exptl_crystal_description       block
_exptl_crystal_F_000             1512
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.03
_refine_diff_density_max         2.641
_refine_diff_density_min         -1.062
_refine_diff_density_rms         0.187
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.088
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     271
_refine_ls_number_reflns         4109
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.088
_refine_ls_R_factor_all          0.0299
_refine_ls_R_factor_gt           0.0281
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0481P)²+1.5536P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0736
_refine_ls_wR_factor_ref         0.0750
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3880
_reflns_number_total             4109
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1dt01866c2.cif
_cod_data_source_block           lr131_abs2
_cod_depositor_comments
'Adding full bibliography for 7708032--7708039.cif.'
_cod_database_code               7708038
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         'C16 H5 Se P W2 O10'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.544
_shelx_estimated_absorpt_t_min   0.140
_reflns_odcompleteness_completeness 99.92
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C12(H12), C16(H16), C15(H15), C13(H13), C14(H14)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.553
_oxdiff_exptl_absorpt_empirical_full_min 0.642
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.82730(3) 0.83273(2) 0.55355(2) 0.01569(8) Uani 1 1 d . . . . .
W2 W 0.52373(3) 0.78490(2) 0.32708(2) 0.01613(8) Uani 1 1 d . . . . .
Se1 Se 0.58588(8) 0.63831(3) 0.50610(3) 0.02352(13) Uani 1 1 d . . . . .
P1 P 0.63819(16) 0.75561(7) 0.45499(6) 0.0157(2) Uani 1 1 d . . . . .
O8 O 0.7030(6) 0.6221(2) 0.2729(2) 0.0306(8) Uani 1 1 d . . . . .
O9 O 0.9271(5) 0.8750(2) 0.3309(2) 0.0296(8) Uani 1 1 d . . . . .
O1 O 0.4446(6) 0.8546(3) 0.6238(2) 0.0342(9) Uani 1 1 d . . . . .
O4 O 0.7505(6) 0.9968(2) 0.4623(2) 0.0347(9) Uani 1 1 d . . . . .
O5 O 1.0715(6) 0.9426(3) 0.6779(2) 0.0365(9) Uani 1 1 d . . . . .
O2 O 0.9378(6) 0.6889(3) 0.6686(2) 0.0356(9) Uani 1 1 d . . . . .
O7 O 0.1073(5) 0.7003(2) 0.3113(2) 0.0318(9) Uani 1 1 d . . . . .
O6 O 0.3429(6) 0.9504(3) 0.3753(3) 0.0404(10) Uani 1 1 d . . . . .
O3 O 1.1982(6) 0.8019(3) 0.4788(2) 0.0379(10) Uani 1 1 d . . . . .
O10 O 0.3827(7) 0.8432(3) 0.1627(2) 0.0427(11) Uani 1 1 d . . . . .
C9 C 0.7819(7) 0.8427(3) 0.3296(3) 0.0204(10) Uani 1 1 d . . . . .
C4 C 0.7739(7) 0.9374(3) 0.4935(3) 0.0215(10) Uani 1 1 d . . . . .
C8 C 0.6379(7) 0.6794(3) 0.2926(3) 0.0215(10) Uani 1 1 d . . . . .
C11 C 0.3812(7) 0.5833(3) 0.4421(3) 0.0207(10) Uani 1 1 d . . . . .
C7 C 0.2588(7) 0.7282(3) 0.3197(3) 0.0219(10) Uani 1 1 d . . . . .
C1 C 0.5793(7) 0.8492(3) 0.5987(3) 0.0216(10) Uani 1 1 d . . . . .
C10 C 0.4367(7) 0.8211(4) 0.2214(3) 0.0265(11) Uani 1 1 d . . . . .
C2 C 0.8967(7) 0.7368(3) 0.6249(3) 0.0232(10) Uani 1 1 d . . . . .
C12 C 0.1976(8) 0.5867(3) 0.4603(3) 0.0284(11) Uani 1 1 d . . . . .
H12 H 0.175180 0.616109 0.502244 0.034 Uiso 1 1 calc R U . . .
C16 C 0.4168(8) 0.5386(3) 0.3821(3) 0.0256(11) Uani 1 1 d . . . . .
H16 H 0.544032 0.534887 0.371105 0.031 Uiso 1 1 calc R U . . .
C3 C 1.0690(7) 0.8126(3) 0.5066(3) 0.0229(10) Uani 1 1 d . . . . .
C5 C 0.9836(8) 0.9039(3) 0.6341(3) 0.0243(10) Uani 1 1 d . . . . .
C15 C 0.2637(9) 0.4992(3) 0.3382(3) 0.0303(12) Uani 1 1 d . . . . .
H15 H 0.285823 0.468808 0.296666 0.036 Uiso 1 1 calc R U . . .
C6 C 0.4065(7) 0.8910(3) 0.3588(3) 0.0244(10) Uani 1 1 d . . . . .
C13 C 0.0456(8) 0.5459(4) 0.4159(3) 0.0326(12) Uani 1 1 d . . . . .
H13 H -0.080602 0.547129 0.428069 0.039 Uiso 1 1 calc R U . . .
C14 C 0.0778(9) 0.5043(3) 0.3551(3) 0.0346(13) Uani 1 1 d . . . . .
H14 H -0.027096 0.478751 0.324186 0.042 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.7943 1.1372 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -5.4734 5.5774 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 -10 -5 0.0607
0 5 -10 0.0219
-1 -2 12 0.0116
2 1 -12 0.0161
-1 1 12 0.0280
3 -1 8 0.0426
0 5 10 0.0478
0 -5 -10 0.0345
-1 2 -11 0.0165
-4 2 -3 0.0522
0 8 8 0.0574
0 -8 -8 0.0505
4 0 4 0.0482
0 10 5 0.0653
-4 1 0 0.0538
-3 1 -7 0.0396
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C4 W1 P1 90.32(13) . . ?
C4 W1 C1 91.1(2) . . ?
C4 W1 C2 172.69(19) . . ?
C4 W1 C3 89.7(2) . . ?
C4 W1 C5 86.6(2) . . ?
C1 W1 P1 88.93(14) . . ?
C2 W1 P1 96.93(14) . . ?
C2 W1 C1 88.0(2) . . ?
C3 W1 P1 89.05(14) . . ?
C3 W1 C1 177.8(2) . . ?
C3 W1 C2 91.4(2) . . ?
C5 W1 P1 176.91(15) . . ?
C5 W1 C1 90.9(2) . . ?
C5 W1 C2 86.1(2) . . ?
C5 W1 C3 91.2(2) . . ?
C9 W2 P1 85.62(13) . . ?
C9 W2 C8 90.5(2) . . ?
C9 W2 C7 177.39(18) . . ?
C9 W2 C6 89.7(2) . . ?
C8 W2 P1 93.06(13) . . ?
C8 W2 C7 89.5(2) . . ?
C7 W2 P1 96.98(13) . . ?
C10 W2 P1 174.29(17) . . ?
C10 W2 C9 90.4(2) . . ?
C10 W2 C8 91.0(2) . . ?
C10 W2 C7 87.0(2) . . ?
C10 W2 C6 87.5(2) . . ?
C6 W2 P1 88.46(14) . . ?
C6 W2 C8 178.48(19) . . ?
C6 W2 C7 90.2(2) . . ?
C11 Se1 P1 107.95(14) . . ?
W2 P1 W1 132.95(5) . . ?
Se1 P1 W1 104.19(4) . . ?
Se1 P1 W2 122.84(5) . . ?
O9 C9 W2 179.9(5) . . ?
O4 C4 W1 177.1(4) . . ?
O8 C8 W2 178.7(5) . . ?
C12 C11 Se1 117.3(4) . . ?
C12 C11 C16 121.0(5) . . ?
C16 C11 Se1 121.6(4) . . ?
O7 C7 W2 175.0(4) . . ?
O1 C1 W1 177.0(5) . . ?
O10 C10 W2 177.5(5) . . ?
O2 C2 W1 174.2(5) . . ?
C11 C12 H12 120.5 . . ?
C11 C12 C13 119.0(5) . . ?
C13 C12 H12 120.5 . . ?
C11 C16 H16 120.4 . . ?
C11 C16 C15 119.2(5) . . ?
C15 C16 H16 120.4 . . ?
O3 C3 W1 178.0(4) . . ?
O5 C5 W1 179.0(5) . . ?
C16 C15 H15 120.0 . . ?
C16 C15 C14 120.0(5) . . ?
C14 C15 H15 120.0 . . ?
O6 C6 W2 178.8(5) . . ?
C12 C13 H13 119.8 . . ?
C14 C13 C12 120.4(5) . . ?
C14 C13 H13 119.8 . . ?
C15 C14 H14 119.8 . . ?
C13 C14 C15 120.4(5) . . ?
C13 C14 H14 119.8 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
W1 P1 2.4232(11) . ?
W1 C4 2.048(5) . ?
W1 C1 2.071(5) . ?
W1 C2 2.062(5) . ?
W1 C3 2.059(5) . ?
W1 C5 2.058(5) . ?
W2 P1 2.4141(11) . ?
W2 C9 2.038(5) . ?
W2 C8 2.058(5) . ?
W2 C7 2.063(5) . ?
W2 C10 2.036(5) . ?
W2 C6 2.056(5) . ?
Se1 P1 2.2060(13) . ?
Se1 C11 1.925(5) . ?
O8 C8 1.133(7) . ?
O9 C9 1.146(6) . ?
O1 C1 1.124(6) . ?
O4 C4 1.133(6) . ?
O5 C5 1.128(7) . ?
O2 C2 1.130(7) . ?
O7 C7 1.144(6) . ?
O6 C6 1.137(7) . ?
O3 C3 1.128(6) . ?
O10 C10 1.146(7) . ?
C11 C12 1.386(7) . ?
C11 C16 1.390(7) . ?
C12 H12 0.9500 . ?
C12 C13 1.402(8) . ?
C16 H16 0.9500 . ?
C16 C15 1.392(8) . ?
C15 H15 0.9500 . ?
C15 C14 1.394(9) . ?
C13 H13 0.9500 . ?
C13 C14 1.366(9) . ?
C14 H14 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Se1 C11 C12 C13 -178.6(4) . . . . ?
Se1 C11 C16 C15 179.2(4) . . . . ?
C11 C12 C13 C14 -0.7(8) . . . . ?
C11 C16 C15 C14 -0.6(8) . . . . ?
C12 C11 C16 C15 2.5(8) . . . . ?
C12 C13 C14 C15 2.6(8) . . . . ?
C16 C11 C12 C13 -1.8(8) . . . . ?
C16 C15 C14 C13 -1.9(8) . . . . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
0.0000 -10.0000 -5.0000 0.1782 0.7629 0.6650
-0.0000 5.0000 -10.0000 -0.9109 0.2659 -0.1832
-1.0000 -2.0000 12.0000 0.9313 -0.3705 -0.1817
2.0000 1.0000 -12.0000 -0.9216 0.2707 0.4016
-1.0000 1.0000 12.0000 0.7792 -0.5216 -0.3633
3.0000 -1.0000 8.0000 0.4536 -0.8144 0.4431
0.0000 5.0000 10.0000 0.4040 -0.7698 -0.4221
-0.0000 -5.0000 -10.0000 -0.4040 0.7698 0.4221
-1.0000 2.0000 -11.0000 -0.7836 0.6190 -0.1491
-4.0000 2.0000 -3.0000 -0.1346 0.6552 -0.7228
0.0000 8.0000 8.0000 0.1204 -0.8175 -0.5798
-0.0000 -8.0000 -8.0000 -0.1204 0.8175 0.5798
4.0000 -0.0000 4.0000 0.0989 -0.8078 0.5898
-0.0000 10.0000 5.0000 -0.1782 -0.7629 -0.6650
-4.0000 1.0000 0.0000 0.1134 0.5503 -0.6981
-3.0000 1.0000 -7.0000 -0.3879 0.7626 -0.4551
