#------------------------------------------------------------------------------
#$Date: 2021-11-12 02:05:47 +0200 (Fri, 12 Nov 2021) $
#$Revision: 270611 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/88/7708803.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7708803
loop_
_publ_author_name
'Bould, Jonathan'
'Londesborough, Michael G. S.'
'Passarelli, Vincenzo'
'Clegg, William'
'Waddell, Paul G.'
'Cvačka, Josef'
'Macías, Ramón'
_publ_section_title
;
 A simple and high-yield route to iridium, rhodium, osmium and ruthenium
 nido-6-metalladecaborane compounds
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D1DT02971A
_journal_year                    2021
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C35 H46 B9 O P3 Pt Ru'
_chemical_formula_sum            'C35 H46 B9 O P3 Pt Ru'
_chemical_formula_weight         969.08
_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_Hall           'P 2yb'
_space_group_name_H-M_alt        'P 1 21 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2021-08-15 deposited with the CCDC.	2021-11-02 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 116.8368(15)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   11.49283(13)
_cell_length_b                   16.98921(13)
_cell_length_c                   11.52564(15)
_cell_measurement_reflns_used    19016
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      66.85
_cell_measurement_theta_min      4.26
_cell_volume                     2008.05(5)
_computing_cell_refinement       'CrysAlisPro 1.171.38.42b (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.42b (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.42b (Rigaku OD, 2015)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'SHELXL and local programs'
_computing_structure_refinement  SHELXL-2018/3
_computing_structure_solution    SHELXT-2018/2
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 10.3968
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type
'Oxford Diffraction Gemini A Ultra diffractometer'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0256
_diffrn_reflns_av_unetI/netI     0.0239
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            28920
_diffrn_reflns_point_group_measured_fraction_full 0.932
_diffrn_reflns_point_group_measured_fraction_max 0.932
_diffrn_reflns_theta_full        66.913
_diffrn_reflns_theta_max         66.913
_diffrn_reflns_theta_min         4.299
_diffrn_source                   'fine-focus sealed X-ray tube'
_exptl_absorpt_coefficient_mu    10.796
_exptl_absorpt_correction_T_max  0.658
_exptl_absorpt_correction_T_min  0.252
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.42b (Rigaku Oxford Diffraction, 2015)
Analytical numeric absorption correction using a multifaceted crystal
   model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.603
_exptl_crystal_description       block
_exptl_crystal_F_000             952
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: dichloromethane and hexane'
_exptl_crystal_size_max          0.210
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.040
_refine_diff_density_max         0.343
_refine_diff_density_min         -0.306
_refine_diff_density_rms         0.051
_refine_ls_abs_structure_details
;
 Flack x determined using 2891 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.042(4)
_refine_ls_extinction_coef       0.00005(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     484
_refine_ls_number_reflns         6668
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.051
_refine_ls_R_factor_all          0.0156
_refine_ls_R_factor_gt           0.0151
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0187P)²+0.1917P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0338
_refine_ls_wR_factor_ref         0.0341
_reflns_Friedel_coverage         0.804
_reflns_Friedel_fraction_full    0.863
_reflns_Friedel_fraction_max     0.863
_reflns_number_gt                6589
_reflns_number_total             6668
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1dt02971a2.cif
_cod_data_source_block           ewc190013_compound6
_cod_original_cell_volume        2008.05(4)
_cod_original_sg_symbol_H-M      'P 21'
_cod_database_code               7708803
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.210
_shelx_estimated_absorpt_t_max   0.672
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.79357(2) 0.50461(2) 0.43972(2) 0.01654(5) Uani 1 1 d . . . . .
Ru1 Ru 1.00991(2) 0.42046(2) 0.42970(3) 0.01570(7) Uani 1 1 d . . . . .
H1 H 0.831(6) 0.456(3) 0.337(6) 0.047(16) Uiso 1 1 d . . . . .
B2 B 0.9845(4) 0.4893(3) 0.5670(4) 0.0203(9) Uani 1 1 d . . . . .
B3 B 1.1133(4) 0.3357(3) 0.5849(5) 0.0249(9) Uani 1 1 d . . . . .
H3 H 1.103(5) 0.265(3) 0.574(5) 0.030 Uiso 1 1 d . U . . .
B4 B 1.1988(4) 0.4791(3) 0.4946(4) 0.0216(9) Uani 1 1 d . . . . .
H4 H 1.246(4) 0.505(4) 0.436(4) 0.026 Uiso 1 1 d . U . . .
B5 B 1.0363(4) 0.3985(3) 0.6470(5) 0.0230(9) Uani 1 1 d . . . . .
H5 H 0.974(5) 0.371(3) 0.679(5) 0.028 Uiso 1 1 d . U . . .
B6 B 1.2357(4) 0.3893(3) 0.5735(5) 0.0239(9) Uani 1 1 d . . . . .
H6 H 1.310(5) 0.355(3) 0.561(5) 0.029 Uiso 1 1 d . U . . .
B7 B 1.1186(4) 0.5346(3) 0.5626(4) 0.0195(8) Uani 1 1 d . . . . .
H7 H 1.108(4) 0.595(3) 0.541(5) 0.023 Uiso 1 1 d . U . . .
B8 B 1.1308(4) 0.4872(3) 0.7079(4) 0.0236(10) Uani 1 1 d . . . . .
H8 H 1.140(4) 0.515(3) 0.798(4) 0.028 Uiso 1 1 d . U . . .
B9 B 1.2105(4) 0.3941(3) 0.7180(5) 0.0247(10) Uani 1 1 d . . . . .
H9 H 1.282(5) 0.371(3) 0.816(5) 0.030 Uiso 1 1 d . U . . .
B10 B 1.2619(4) 0.4807(3) 0.6638(5) 0.0239(10) Uani 1 1 d . . . . .
H10 H 1.357(4) 0.503(4) 0.723(4) 0.029 Uiso 1 1 d . U . . .
C1 C 0.9200(4) 0.3223(3) 0.3535(4) 0.0254(9) Uani 1 1 d . . . . .
O1 O 0.8629(3) 0.26629(19) 0.3102(4) 0.0401(8) Uani 1 1 d . . . . .
P1 P 0.58154(8) 0.49332(6) 0.27118(9) 0.0196(2) Uani 1 1 d . . . . .
C11 C 0.5298(4) 0.5712(2) 0.1497(4) 0.0213(8) Uani 1 1 d . . . . .
C12 C 0.4126(4) 0.5686(3) 0.0352(4) 0.0273(9) Uani 1 1 d . . . . .
H12 H 0.356954 0.524170 0.018053 0.033 Uiso 1 1 calc R U . . .
C13 C 0.3767(5) 0.6296(3) -0.0531(5) 0.0344(10) Uani 1 1 d . . . . .
H13 H 0.296774 0.627140 -0.130683 0.041 Uiso 1 1 calc R U . . .
C14 C 0.4574(5) 0.6947(3) -0.0285(5) 0.0372(11) Uani 1 1 d . . . . .
H14 H 0.432650 0.736830 -0.089201 0.045 Uiso 1 1 calc R U . . .
C15 C 0.5731(5) 0.6982(3) 0.0835(5) 0.0350(10) Uani 1 1 d . . . . .
H15 H 0.627802 0.743017 0.100010 0.042 Uiso 1 1 calc R U . . .
C16 C 0.6107(4) 0.6369(3) 0.1727(4) 0.0265(9) Uani 1 1 d . . . . .
H16 H 0.691380 0.639580 0.249334 0.032 Uiso 1 1 calc R U . . .
C17 C 0.4479(4) 0.4886(3) 0.3152(4) 0.0289(10) Uani 1 1 d . . . . .
H17A H 0.466005 0.447491 0.380721 0.043 Uiso 1 1 calc R U . . .
H17B H 0.366560 0.476339 0.237760 0.043 Uiso 1 1 calc R U . . .
H17C H 0.439339 0.539490 0.350654 0.043 Uiso 1 1 calc R U . . .
C18 C 0.5581(4) 0.4024(2) 0.1795(4) 0.0249(9) Uani 1 1 d . . . . .
H18A H 0.622839 0.399191 0.146278 0.037 Uiso 1 1 calc R U . . .
H18B H 0.470248 0.401685 0.106443 0.037 Uiso 1 1 calc R U . . .
H18C H 0.568526 0.357263 0.236389 0.037 Uiso 1 1 calc R U . . .
P2 P 0.77381(9) 0.57286(6) 0.59645(10) 0.0235(2) Uani 1 1 d . . . . .
C21 C 0.6215(4) 0.6251(2) 0.5546(4) 0.0242(8) Uani 1 1 d . . . . .
C22 C 0.5369(4) 0.6070(3) 0.6071(5) 0.0302(9) Uani 1 1 d . . . . .
H22 H 0.556804 0.564682 0.666950 0.036 Uiso 1 1 calc R U . . .
C23 C 0.4235(4) 0.6503(3) 0.5725(5) 0.0372(11) Uani 1 1 d . . . . .
H23 H 0.366758 0.637871 0.609406 0.045 Uiso 1 1 calc R U . . .
C24 C 0.3931(4) 0.7115(3) 0.4846(5) 0.0390(12) Uani 1 1 d . . . . .
H24 H 0.314721 0.740392 0.460107 0.047 Uiso 1 1 calc R U . . .
C25 C 0.4765(5) 0.7306(3) 0.4324(5) 0.0369(11) Uani 1 1 d . . . . .
H25 H 0.456674 0.773614 0.373775 0.044 Uiso 1 1 calc R U . . .
C26 C 0.5894(4) 0.6871(3) 0.4654(4) 0.0283(9) Uani 1 1 d . . . . .
H26 H 0.645127 0.699493 0.427263 0.034 Uiso 1 1 calc R U . . .
C27 C 0.8931(4) 0.6516(3) 0.6659(6) 0.0429(13) Uani 1 1 d . . . . .
H27A H 0.981067 0.629146 0.706569 0.064 Uiso 1 1 calc R U . . .
H27B H 0.877154 0.679876 0.731480 0.064 Uiso 1 1 calc R U . . .
H27C H 0.885113 0.688197 0.596937 0.064 Uiso 1 1 calc R U . . .
C28 C 0.8000(5) 0.5135(5) 0.7361(5) 0.0515(15) Uani 1 1 d . . . . .
H28A H 0.735957 0.470764 0.709288 0.077 Uiso 1 1 calc R U . . .
H28B H 0.790122 0.546357 0.801056 0.077 Uiso 1 1 calc R U . . .
H28C H 0.888178 0.491338 0.773851 0.077 Uiso 1 1 calc R U . . .
P3 P 1.00270(9) 0.45176(6) 0.22200(10) 0.0168(2) Uani 1 1 d . . . . .
C311 C 1.1062(4) 0.3918(2) 0.1743(4) 0.0190(8) Uani 1 1 d . . . . .
C312 C 1.2010(4) 0.3432(2) 0.2628(4) 0.0207(8) Uani 1 1 d . . . . .
H312 H 1.214542 0.341893 0.350406 0.025 Uiso 1 1 calc R U . . .
C313 C 1.2769(4) 0.2959(3) 0.2248(5) 0.0275(9) Uani 1 1 d . . . . .
H313 H 1.342763 0.263237 0.286705 0.033 Uiso 1 1 calc R U . . .
C314 C 1.2564(4) 0.2965(3) 0.0977(5) 0.0278(9) Uani 1 1 d . . . . .
H314 H 1.307364 0.263835 0.071550 0.033 Uiso 1 1 calc R U . . .
C315 C 1.1613(4) 0.3449(3) 0.0077(4) 0.0312(10) Uani 1 1 d . . . . .
H315 H 1.147952 0.345720 -0.079844 0.037 Uiso 1 1 calc R U . . .
C316 C 1.0862(4) 0.3917(3) 0.0451(4) 0.0267(9) Uani 1 1 d . . . . .
H316 H 1.020318 0.424230 -0.017261 0.032 Uiso 1 1 calc R U . . .
C321 C 1.0381(4) 0.5538(2) 0.2002(4) 0.0224(9) Uani 1 1 d . . . . .
C322 C 1.1106(4) 0.5754(3) 0.1359(5) 0.0292(9) Uani 1 1 d . . . . .
H322 H 1.144268 0.535736 0.101147 0.035 Uiso 1 1 calc R U . . .
C323 C 1.1342(5) 0.6536(3) 0.1218(6) 0.0399(12) Uani 1 1 d . . . . .
H323 H 1.184677 0.667501 0.078464 0.048 Uiso 1 1 calc R U . . .
C324 C 1.0844(5) 0.7121(3) 0.1709(5) 0.0382(11) Uani 1 1 d . . . . .
H324 H 1.099947 0.765963 0.160825 0.046 Uiso 1 1 calc R U . . .
C325 C 1.0125(5) 0.6911(3) 0.2342(5) 0.0349(10) Uani 1 1 d . . . . .
H325 H 0.978216 0.731100 0.267678 0.042 Uiso 1 1 calc R U . . .
C326 C 0.9890(4) 0.6130(3) 0.2501(4) 0.0262(9) Uani 1 1 d . . . . .
H326 H 0.939663 0.599631 0.294758 0.031 Uiso 1 1 calc R U . . .
C331 C 0.8421(3) 0.4346(2) 0.0837(4) 0.0208(8) Uani 1 1 d . . . . .
C332 C 0.7524(3) 0.4952(3) 0.0317(4) 0.0234(8) Uani 1 1 d . . . . .
H332 H 0.774562 0.546871 0.066299 0.028 Uiso 1 1 calc R U . . .
C333 C 0.6300(4) 0.4806(3) -0.0710(4) 0.0265(9) Uani 1 1 d . . . . .
H333 H 0.568642 0.522227 -0.105668 0.032 Uiso 1 1 calc R U . . .
C334 C 0.5974(4) 0.4059(3) -0.1227(4) 0.0303(10) Uani 1 1 d . . . . .
H334 H 0.514245 0.396273 -0.193592 0.036 Uiso 1 1 calc R U . . .
C335 C 0.6861(4) 0.3450(3) -0.0709(4) 0.0298(9) Uani 1 1 d . . . . .
H335 H 0.663853 0.293373 -0.105841 0.036 Uiso 1 1 calc R U . . .
C336 C 0.8077(4) 0.3595(3) 0.0321(4) 0.0259(9) Uani 1 1 d . . . . .
H336 H 0.868188 0.317582 0.067794 0.031 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru 0.0552 3.2960 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 0 0 0.0185
0 0 0 0.0205
-1 0 0 0.0571
1 0 0 0.0421
0 1 0 0.0885
0 -1 0 0.1215
0 -2 1 0.0853
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ru1 Pt1 H1 39(2) . . ?
Ru1 Pt1 B2 45.83(12) . . ?
Ru1 Pt1 P1 120.94(3) . . ?
Ru1 Pt1 P2 133.14(3) . . ?
H1 Pt1 B2 85(2) . . ?
H1 Pt1 P1 83(2) . . ?
H1 Pt1 P2 172(2) . . ?
B2 Pt1 P1 165.80(12) . . ?
B2 Pt1 P2 87.36(12) . . ?
P1 Pt1 P2 105.36(3) . . ?
Pt1 Ru1 H1 32.5(19) . . ?
Pt1 Ru1 B2 44.18(11) . . ?
Pt1 Ru1 B3 116.71(12) . . ?
Pt1 Ru1 B4 119.65(12) . . ?
Pt1 Ru1 B5 75.19(10) . . ?
Pt1 Ru1 B6 138.48(11) . . ?
Pt1 Ru1 B7 77.84(10) . . ?
Pt1 Ru1 C1 98.57(12) . . ?
Pt1 Ru1 P3 106.43(2) . . ?
H1 Ru1 B2 76.6(19) . . ?
H1 Ru1 B3 134.8(18) . . ?
H1 Ru1 B4 133.7(18) . . ?
H1 Ru1 B5 102.9(19) . . ?
H1 Ru1 B6 170.9(19) . . ?
H1 Ru1 B7 102.5(18) . . ?
H1 Ru1 C1 78.5(18) . . ?
H1 Ru1 P3 80.4(19) . . ?
B2 Ru1 B3 87.65(18) . . ?
B2 Ru1 B4 86.71(17) . . ?
B2 Ru1 B5 45.24(16) . . ?
B2 Ru1 B6 94.41(17) . . ?
B2 Ru1 B7 44.50(15) . . ?
B2 Ru1 C1 126.32(17) . . ?
B2 Ru1 P3 132.24(12) . . ?
B3 Ru1 B4 86.07(17) . . ?
B3 Ru1 B5 43.98(16) . . ?
B3 Ru1 B6 43.69(17) . . ?
B3 Ru1 B7 94.30(17) . . ?
B3 Ru1 C1 77.69(18) . . ?
B3 Ru1 P3 136.00(13) . . ?
B4 Ru1 B5 94.31(16) . . ?
B4 Ru1 B6 43.64(17) . . ?
B4 Ru1 B7 43.57(15) . . ?
B4 Ru1 C1 141.73(17) . . ?
B4 Ru1 P3 79.83(12) . . ?
B5 Ru1 B6 70.25(16) . . ?
B5 Ru1 B7 71.46(16) . . ?
B5 Ru1 C1 97.36(17) . . ?
B5 Ru1 P3 173.98(12) . . ?
B6 Ru1 B7 69.96(16) . . ?
B6 Ru1 C1 107.89(17) . . ?
B6 Ru1 P3 105.83(12) . . ?
B7 Ru1 C1 168.77(16) . . ?
B7 Ru1 P3 103.04(11) . . ?
C1 Ru1 P3 88.17(13) . . ?
Pt1 B2 Ru1 89.98(17) . . ?
Pt1 B2 B5 119.4(3) . . ?
Pt1 B2 B7 127.1(3) . . ?
Pt1 B2 B8 162.6(3) . . ?
Ru1 B2 B5 77.1(2) . . ?
Ru1 B2 B7 78.3(2) . . ?
Ru1 B2 B8 106.9(2) . . ?
B5 B2 B7 107.9(3) . . ?
B5 B2 B8 62.3(3) . . ?
B7 B2 B8 62.6(3) . . ?
Ru1 B3 H3 125(3) . . ?
Ru1 B3 B5 75.0(2) . . ?
Ru1 B3 B6 75.6(2) . . ?
Ru1 B3 B9 104.0(3) . . ?
H3 B3 B5 128(2) . . ?
H3 B3 B6 124(2) . . ?
H3 B3 B9 131(3) . . ?
B5 B3 B6 106.9(4) . . ?
B5 B3 B9 62.0(3) . . ?
B6 B3 B9 63.1(3) . . ?
Ru1 B4 H4 130(2) . . ?
Ru1 B4 B6 75.4(2) . . ?
Ru1 B4 B7 75.8(2) . . ?
Ru1 B4 B10 103.7(3) . . ?
H4 B4 B6 126(3) . . ?
H4 B4 B7 124(3) . . ?
H4 B4 B10 126(2) . . ?
B6 B4 B7 107.2(3) . . ?
B6 B4 B10 63.0(3) . . ?
B7 B4 B10 61.6(3) . . ?
Ru1 B5 B2 57.69(19) . . ?
Ru1 B5 B3 61.0(2) . . ?
Ru1 B5 H5 130(3) . . ?
Ru1 B5 B8 92.7(2) . . ?
Ru1 B5 B9 94.1(2) . . ?
B2 B5 B3 116.0(3) . . ?
B2 B5 H5 117(3) . . ?
B2 B5 B8 58.2(3) . . ?
B2 B5 B9 108.8(3) . . ?
B3 B5 H5 115(3) . . ?
B3 B5 B8 110.2(3) . . ?
B3 B5 B9 59.2(3) . . ?
H5 B5 B8 129(3) . . ?
H5 B5 B9 128(3) . . ?
B8 B5 B9 60.3(2) . . ?
Ru1 B6 B3 60.7(2) . . ?
Ru1 B6 B4 60.99(19) . . ?
Ru1 B6 H6 133(3) . . ?
Ru1 B6 B9 93.0(2) . . ?
Ru1 B6 B10 93.1(2) . . ?
B3 B6 B4 119.4(3) . . ?
B3 B6 H6 116(3) . . ?
B3 B6 B9 58.8(3) . . ?
B3 B6 B10 109.7(3) . . ?
B4 B6 H6 115(3) . . ?
B4 B6 B9 109.9(3) . . ?
B4 B6 B10 59.0(3) . . ?
H6 B6 B9 127(3) . . ?
H6 B6 B10 127(3) . . ?
B9 B6 B10 59.4(3) . . ?
Ru1 B7 B2 57.16(18) . . ?
Ru1 B7 B4 60.6(2) . . ?
Ru1 B7 H7 131(3) . . ?
Ru1 B7 B8 91.8(2) . . ?
Ru1 B7 B10 93.6(2) . . ?
B2 B7 B4 115.5(3) . . ?
B2 B7 H7 115(2) . . ?
B2 B7 B8 58.4(2) . . ?
B2 B7 B10 108.8(3) . . ?
B4 B7 H7 117(2) . . ?
B4 B7 B8 110.0(3) . . ?
B4 B7 B10 59.6(3) . . ?
H7 B7 B8 127(3) . . ?
H7 B7 B10 129(2) . . ?
B8 B7 B10 60.1(2) . . ?
B2 B8 B5 59.5(3) . . ?
B2 B8 B7 59.0(2) . . ?
B2 B8 H8 121(2) . . ?
B2 B8 B9 109.1(3) . . ?
B2 B8 B10 108.6(3) . . ?
B5 B8 B7 103.3(3) . . ?
B5 B8 H8 121(3) . . ?
B5 B8 B9 59.4(2) . . ?
B5 B8 B10 105.8(3) . . ?
B7 B8 H8 128(3) . . ?
B7 B8 B9 106.0(3) . . ?
B7 B8 B10 59.3(2) . . ?
H8 B8 B9 119(3) . . ?
H8 B8 B10 124(2) . . ?
B9 B8 B10 60.0(3) . . ?
B3 B9 B5 58.8(3) . . ?
B3 B9 B6 58.1(3) . . ?
B3 B9 B8 109.7(3) . . ?
B3 B9 H9 125(3) . . ?
B3 B9 B10 109.9(3) . . ?
B5 B9 B6 101.0(3) . . ?
B5 B9 B8 60.2(2) . . ?
B5 B9 H9 129(3) . . ?
B5 B9 B10 106.3(3) . . ?
B6 B9 B8 105.4(3) . . ?
B6 B9 H9 124(3) . . ?
B6 B9 B10 60.3(3) . . ?
B8 B9 H9 119(3) . . ?
B8 B9 B10 59.8(3) . . ?
H9 B9 B10 115(3) . . ?
B4 B10 B6 58.0(3) . . ?
B4 B10 B7 58.8(2) . . ?
B4 B10 B8 109.8(3) . . ?
B4 B10 B9 109.8(3) . . ?
B4 B10 H10 121(2) . . ?
B6 B10 B7 101.5(3) . . ?
B6 B10 B8 105.7(3) . . ?
B6 B10 B9 60.3(3) . . ?
B6 B10 H10 122(3) . . ?
B7 B10 B8 60.6(2) . . ?
B7 B10 B9 107.2(3) . . ?
B7 B10 H10 128(3) . . ?
B8 B10 B9 60.2(2) . . ?
B8 B10 H10 123(2) . . ?
B9 B10 H10 118(3) . . ?
Ru1 C1 O1 176.8(4) . . ?
Pt1 P1 C11 115.78(13) . . ?
Pt1 P1 C17 117.71(15) . . ?
Pt1 P1 C18 112.15(14) . . ?
C11 P1 C17 102.85(19) . . ?
C11 P1 C18 105.0(2) . . ?
C17 P1 C18 101.6(2) . . ?
P1 C11 C12 122.9(3) . . ?
P1 C11 C16 118.4(3) . . ?
C12 C11 C16 118.7(4) . . ?
C11 C12 H12 119.6 . . ?
C11 C12 C13 120.8(4) . . ?
H12 C12 C13 119.6 . . ?
C12 C13 H13 120.1 . . ?
C12 C13 C14 119.9(4) . . ?
H13 C13 C14 120.1 . . ?
C13 C14 H14 120.0 . . ?
C13 C14 C15 120.1(4) . . ?
H14 C14 C15 120.0 . . ?
C14 C15 H15 119.7 . . ?
C14 C15 C16 120.6(4) . . ?
H15 C15 C16 119.7 . . ?
C11 C16 C15 120.0(4) . . ?
C11 C16 H16 120.0 . . ?
C15 C16 H16 120.0 . . ?
P1 C17 H17A 109.5 . . ?
P1 C17 H17B 109.5 . . ?
P1 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
P1 C18 H18A 109.5 . . ?
P1 C18 H18B 109.5 . . ?
P1 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Pt1 P2 C21 118.21(14) . . ?
Pt1 P2 C27 113.82(18) . . ?
Pt1 P2 C28 113.1(2) . . ?
C21 P2 C27 101.6(2) . . ?
C21 P2 C28 105.2(2) . . ?
C27 P2 C28 103.2(3) . . ?
P2 C21 C22 123.6(3) . . ?
P2 C21 C26 117.7(3) . . ?
C22 C21 C26 118.8(4) . . ?
C21 C22 H22 119.8 . . ?
C21 C22 C23 120.4(4) . . ?
H22 C22 C23 119.8 . . ?
C22 C23 H23 119.9 . . ?
C22 C23 C24 120.2(4) . . ?
H23 C23 C24 119.9 . . ?
C23 C24 H24 120.0 . . ?
C23 C24 C25 120.0(4) . . ?
H24 C24 C25 120.0 . . ?
C24 C25 H25 120.0 . . ?
C24 C25 C26 120.1(5) . . ?
H25 C25 C26 120.0 . . ?
C21 C26 C25 120.4(4) . . ?
C21 C26 H26 119.8 . . ?
C25 C26 H26 119.8 . . ?
P2 C27 H27A 109.5 . . ?
P2 C27 H27B 109.5 . . ?
P2 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
P2 C28 H28A 109.5 . . ?
P2 C28 H28B 109.5 . . ?
P2 C28 H28C 109.5 . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
Ru1 P3 C311 116.05(13) . . ?
Ru1 P3 C321 115.82(15) . . ?
Ru1 P3 C331 113.33(13) . . ?
C311 P3 C321 105.79(17) . . ?
C311 P3 C331 100.72(18) . . ?
C321 P3 C331 103.32(19) . . ?
P3 C311 C312 120.9(3) . . ?
P3 C311 C316 120.2(3) . . ?
C312 C311 C316 118.8(4) . . ?
C311 C312 H312 119.7 . . ?
C311 C312 C313 120.6(4) . . ?
H312 C312 C313 119.7 . . ?
C312 C313 H313 120.0 . . ?
C312 C313 C314 120.0(4) . . ?
H313 C313 C314 120.0 . . ?
C313 C314 H314 120.0 . . ?
C313 C314 C315 120.0(4) . . ?
H314 C314 C315 120.0 . . ?
C314 C315 H315 119.9 . . ?
C314 C315 C316 120.1(4) . . ?
H315 C315 C316 119.9 . . ?
C311 C316 C315 120.5(4) . . ?
C311 C316 H316 119.8 . . ?
C315 C316 H316 119.8 . . ?
P3 C321 C322 123.2(3) . . ?
P3 C321 C326 118.1(3) . . ?
C322 C321 C326 118.7(4) . . ?
C321 C322 H322 119.6 . . ?
C321 C322 C323 120.8(4) . . ?
H322 C322 C323 119.6 . . ?
C322 C323 H323 119.9 . . ?
C322 C323 C324 120.1(4) . . ?
H323 C323 C324 119.9 . . ?
C323 C324 H324 120.3 . . ?
C323 C324 C325 119.3(4) . . ?
H324 C324 C325 120.3 . . ?
C324 C325 H325 119.4 . . ?
C324 C325 C326 121.3(4) . . ?
H325 C325 C326 119.4 . . ?
C321 C326 C325 119.8(4) . . ?
C321 C326 H326 120.1 . . ?
C325 C326 H326 120.1 . . ?
P3 C331 C332 121.1(3) . . ?
P3 C331 C336 119.8(3) . . ?
C332 C331 C336 119.0(4) . . ?
C331 C332 H332 119.9 . . ?
C331 C332 C333 120.2(4) . . ?
H332 C332 C333 119.9 . . ?
C332 C333 H333 119.9 . . ?
C332 C333 C334 120.3(4) . . ?
H333 C333 C334 119.9 . . ?
C333 C334 H334 120.1 . . ?
C333 C334 C335 119.9(4) . . ?
H334 C334 C335 120.1 . . ?
C334 C335 H335 120.1 . . ?
C334 C335 C336 119.8(4) . . ?
H335 C335 C336 120.1 . . ?
C331 C336 C335 120.9(4) . . ?
C331 C336 H336 119.6 . . ?
C335 C336 H336 119.6 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Ru1 2.9152(3) . ?
Pt1 H1 1.65(6) . ?
Pt1 B2 2.032(4) . ?
Pt1 P1 2.3397(9) . ?
Pt1 P2 2.2426(10) . ?
Ru1 H1 1.93(6) . ?
Ru1 B2 2.091(4) . ?
Ru1 B3 2.183(5) . ?
Ru1 B4 2.191(4) . ?
Ru1 B5 2.412(5) . ?
Ru1 B6 2.424(4) . ?
Ru1 B7 2.438(4) . ?
Ru1 C1 1.950(4) . ?
Ru1 P3 2.4169(10) . ?
B2 B5 1.757(6) . ?
B2 B7 1.745(6) . ?
B2 B8 1.733(6) . ?
B3 H3 1.21(5) . ?
B3 B5 1.734(6) . ?
B3 B6 1.729(7) . ?
B3 B9 1.742(7) . ?
B4 H4 1.12(5) . ?
B4 B6 1.729(7) . ?
B4 B7 1.733(6) . ?
B4 B10 1.747(7) . ?
B5 H5 1.05(5) . ?
B5 B8 1.804(7) . ?
B5 B9 1.790(6) . ?
B6 H6 1.10(5) . ?
B6 B9 1.816(7) . ?
B6 B10 1.817(7) . ?
B7 H7 1.06(5) . ?
B7 B8 1.806(6) . ?
B7 B10 1.782(6) . ?
B8 H8 1.10(5) . ?
B8 B9 1.806(6) . ?
B8 B10 1.798(6) . ?
B9 H9 1.12(5) . ?
B9 B10 1.801(7) . ?
B10 H10 1.06(5) . ?
C1 O1 1.135(6) . ?
P1 C11 1.821(4) . ?
P1 C17 1.823(4) . ?
P1 C18 1.822(4) . ?
C11 C12 1.398(6) . ?
C11 C16 1.399(6) . ?
C12 H12 0.950 . ?
C12 C13 1.380(7) . ?
C13 H13 0.950 . ?
C13 C14 1.388(7) . ?
C14 H14 0.950 . ?
C14 C15 1.374(8) . ?
C15 H15 0.950 . ?
C15 C16 1.388(7) . ?
C16 H16 0.950 . ?
C17 H17A 0.980 . ?
C17 H17B 0.980 . ?
C17 H17C 0.980 . ?
C18 H18A 0.980 . ?
C18 H18B 0.980 . ?
C18 H18C 0.980 . ?
P2 C21 1.823(4) . ?
P2 C27 1.822(5) . ?
P2 C28 1.806(5) . ?
C21 C22 1.392(6) . ?
C21 C26 1.400(6) . ?
C22 H22 0.950 . ?
C22 C23 1.389(7) . ?
C23 H23 0.950 . ?
C23 C24 1.381(8) . ?
C24 H24 0.950 . ?
C24 C25 1.382(8) . ?
C25 H25 0.950 . ?
C25 C26 1.388(7) . ?
C26 H26 0.950 . ?
C27 H27A 0.980 . ?
C27 H27B 0.980 . ?
C27 H27C 0.980 . ?
C28 H28A 0.980 . ?
C28 H28B 0.980 . ?
C28 H28C 0.980 . ?
P3 C311 1.829(4) . ?
P3 C321 1.824(4) . ?
P3 C331 1.838(4) . ?
C311 C312 1.381(6) . ?
C311 C316 1.400(6) . ?
C312 H312 0.950 . ?
C312 C313 1.394(6) . ?
C313 H313 0.950 . ?
C313 C314 1.375(7) . ?
C314 H314 0.950 . ?
C314 C315 1.386(7) . ?
C315 H315 0.950 . ?
C315 C316 1.379(6) . ?
C316 H316 0.950 . ?
C321 C322 1.392(6) . ?
C321 C326 1.398(6) . ?
C322 H322 0.950 . ?
C322 C323 1.382(7) . ?
C323 H323 0.950 . ?
C323 C324 1.387(8) . ?
C324 H324 0.950 . ?
C324 C325 1.374(7) . ?
C325 H325 0.950 . ?
C325 C326 1.383(6) . ?
C326 H326 0.950 . ?
C331 C332 1.387(6) . ?
C331 C336 1.387(6) . ?
C332 H332 0.950 . ?
C332 C333 1.392(6) . ?
C333 H333 0.950 . ?
C333 C334 1.380(7) . ?
C334 H334 0.950 . ?
C334 C335 1.385(7) . ?
C335 H335 0.950 . ?
C335 C336 1.388(6) . ?
C336 H336 0.950 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ru1 B3 B5 B2 -18.0(3) . . . . ?
Ru1 B3 B5 B8 -81.6(3) . . . . ?
Ru1 B3 B5 B9 -115.2(3) . . . . ?
B6 B3 B5 Ru1 69.5(3) . . . . ?
B6 B3 B5 B2 51.5(4) . . . . ?
B6 B3 B5 B8 -12.1(4) . . . . ?
B6 B3 B5 B9 -45.7(3) . . . . ?
B9 B3 B5 Ru1 115.2(3) . . . . ?
B9 B3 B5 B2 97.2(4) . . . . ?
B9 B3 B5 B8 33.6(3) . . . . ?
Pt1 B2 B5 Ru1 82.5(2) . . . . ?
Pt1 B2 B5 B3 101.2(4) . . . . ?
Pt1 B2 B5 B8 -160.3(3) . . . . ?
Pt1 B2 B5 B9 165.4(3) . . . . ?
Ru1 B2 B5 B3 18.6(3) . . . . ?
Ru1 B2 B5 B8 117.2(2) . . . . ?
Ru1 B2 B5 B9 82.8(3) . . . . ?
B7 B2 B5 Ru1 -73.0(2) . . . . ?
B7 B2 B5 B3 -54.4(5) . . . . ?
B7 B2 B5 B8 44.2(3) . . . . ?
B7 B2 B5 B9 9.8(4) . . . . ?
B8 B2 B5 Ru1 -117.2(2) . . . . ?
B8 B2 B5 B3 -98.6(4) . . . . ?
B8 B2 B5 B9 -34.4(3) . . . . ?
Ru1 B3 B6 B4 17.6(3) . . . . ?
Ru1 B3 B6 B9 114.2(2) . . . . ?
Ru1 B3 B6 B10 82.3(3) . . . . ?
B5 B3 B6 Ru1 -69.1(3) . . . . ?
B5 B3 B6 B4 -51.5(5) . . . . ?
B5 B3 B6 B9 45.2(3) . . . . ?
B5 B3 B6 B10 13.2(4) . . . . ?
B9 B3 B6 Ru1 -114.2(2) . . . . ?
B9 B3 B6 B4 -96.7(4) . . . . ?
B9 B3 B6 B10 -31.9(3) . . . . ?
Ru1 B4 B6 B3 -17.5(3) . . . . ?
Ru1 B4 B6 B9 -82.1(3) . . . . ?
Ru1 B4 B6 B10 -114.0(2) . . . . ?
B7 B4 B6 Ru1 69.7(2) . . . . ?
B7 B4 B6 B3 52.2(5) . . . . ?
B7 B4 B6 B9 -12.4(4) . . . . ?
B7 B4 B6 B10 -44.3(3) . . . . ?
B10 B4 B6 Ru1 114.0(2) . . . . ?
B10 B4 B6 B3 96.5(4) . . . . ?
B10 B4 B6 B9 31.8(3) . . . . ?
Ru1 B4 B7 B2 16.8(3) . . . . ?
Ru1 B4 B7 B8 80.4(3) . . . . ?
Ru1 B4 B7 B10 114.4(2) . . . . ?
B6 B4 B7 Ru1 -69.4(3) . . . . ?
B6 B4 B7 B2 -52.7(4) . . . . ?
B6 B4 B7 B8 10.9(4) . . . . ?
B6 B4 B7 B10 45.0(3) . . . . ?
B10 B4 B7 Ru1 -114.4(2) . . . . ?
B10 B4 B7 B2 -97.7(4) . . . . ?
B10 B4 B7 B8 -34.1(3) . . . . ?
Pt1 B2 B7 Ru1 -81.0(3) . . . . ?
Pt1 B2 B7 B4 -98.4(4) . . . . ?
Pt1 B2 B7 B8 162.9(4) . . . . ?
Pt1 B2 B7 B10 -162.9(3) . . . . ?
Ru1 B2 B7 B4 -17.4(3) . . . . ?
Ru1 B2 B7 B8 -116.1(2) . . . . ?
Ru1 B2 B7 B10 -81.9(3) . . . . ?
B5 B2 B7 Ru1 72.1(3) . . . . ?
B5 B2 B7 B4 54.7(4) . . . . ?
B5 B2 B7 B8 -44.0(3) . . . . ?
B5 B2 B7 B10 -9.8(4) . . . . ?
B8 B2 B7 Ru1 116.1(2) . . . . ?
B8 B2 B7 B4 98.7(4) . . . . ?
B8 B2 B7 B10 34.2(3) . . . . ?
Pt1 B2 B8 B5 100.2(10) . . . . ?
Pt1 B2 B8 B7 -128.1(10) . . . . ?
Pt1 B2 B8 B9 134.3(9) . . . . ?
Pt1 B2 B8 B10 -162.0(9) . . . . ?
Ru1 B2 B8 B5 -64.9(2) . . . . ?
Ru1 B2 B8 B7 66.7(2) . . . . ?
Ru1 B2 B8 B9 -30.9(4) . . . . ?
Ru1 B2 B8 B10 32.9(4) . . . . ?
B5 B2 B8 B7 131.7(3) . . . . ?
B5 B2 B8 B9 34.1(3) . . . . ?
B5 B2 B8 B10 97.8(3) . . . . ?
B7 B2 B8 B5 -131.7(3) . . . . ?
B7 B2 B8 B9 -97.6(3) . . . . ?
B7 B2 B8 B10 -33.9(3) . . . . ?
Ru1 B5 B8 B2 48.8(2) . . . . ?
Ru1 B5 B8 B7 7.7(3) . . . . ?
Ru1 B5 B8 B9 -93.2(2) . . . . ?
Ru1 B5 B8 B10 -53.7(3) . . . . ?
B2 B5 B8 B7 -41.2(3) . . . . ?
B2 B5 B8 B9 -142.0(3) . . . . ?
B2 B5 B8 B10 -102.6(3) . . . . ?
B3 B5 B8 B2 108.8(4) . . . . ?
B3 B5 B8 B7 67.7(4) . . . . ?
B3 B5 B8 B9 -33.2(3) . . . . ?
B3 B5 B8 B10 6.3(4) . . . . ?
B9 B5 B8 B2 142.0(3) . . . . ?
B9 B5 B8 B7 100.9(3) . . . . ?
B9 B5 B8 B10 39.5(3) . . . . ?
Ru1 B7 B8 B2 -49.0(2) . . . . ?
Ru1 B7 B8 B5 -7.6(3) . . . . ?
Ru1 B7 B8 B9 54.0(3) . . . . ?
Ru1 B7 B8 B10 93.1(2) . . . . ?
B2 B7 B8 B5 41.4(3) . . . . ?
B2 B7 B8 B9 103.0(3) . . . . ?
B2 B7 B8 B10 142.1(3) . . . . ?
B4 B7 B8 B2 -108.2(3) . . . . ?
B4 B7 B8 B5 -66.8(3) . . . . ?
B4 B7 B8 B9 -5.2(4) . . . . ?
B4 B7 B8 B10 33.9(3) . . . . ?
B10 B7 B8 B2 -142.1(3) . . . . ?
B10 B7 B8 B5 -100.7(3) . . . . ?
B10 B7 B8 B9 -39.1(3) . . . . ?
Ru1 B3 B9 B5 64.3(2) . . . . ?
Ru1 B3 B9 B6 -65.5(2) . . . . ?
Ru1 B3 B9 B8 30.8(4) . . . . ?
Ru1 B3 B9 B10 -33.2(3) . . . . ?
B5 B3 B9 B6 -129.8(3) . . . . ?
B5 B3 B9 B8 -33.5(3) . . . . ?
B5 B3 B9 B10 -97.5(3) . . . . ?
B6 B3 B9 B5 129.8(3) . . . . ?
B6 B3 B9 B8 96.3(3) . . . . ?
B6 B3 B9 B10 32.3(3) . . . . ?
Ru1 B5 B9 B3 -52.5(2) . . . . ?
Ru1 B5 B9 B6 -10.9(3) . . . . ?
Ru1 B5 B9 B8 90.7(2) . . . . ?
Ru1 B5 B9 B10 51.2(3) . . . . ?
B2 B5 B9 B3 -109.7(4) . . . . ?
B2 B5 B9 B6 -68.1(4) . . . . ?
B2 B5 B9 B8 33.5(3) . . . . ?
B2 B5 B9 B10 -6.0(4) . . . . ?
B3 B5 B9 B6 41.6(3) . . . . ?
B3 B5 B9 B8 143.2(3) . . . . ?
B3 B5 B9 B10 103.7(4) . . . . ?
B8 B5 B9 B3 -143.2(3) . . . . ?
B8 B5 B9 B6 -101.6(3) . . . . ?
B8 B5 B9 B10 -39.5(3) . . . . ?
B2 B8 B9 B3 -1.2(4) . . . . ?
B2 B8 B9 B5 -34.1(3) . . . . ?
B2 B8 B9 B6 59.9(4) . . . . ?
B2 B8 B9 B10 100.9(3) . . . . ?
B5 B8 B9 B3 32.9(3) . . . . ?
B5 B8 B9 B6 94.0(3) . . . . ?
B5 B8 B9 B10 135.0(3) . . . . ?
B7 B8 B9 B3 -63.3(4) . . . . ?
B7 B8 B9 B5 -96.3(3) . . . . ?
B7 B8 B9 B6 -2.3(4) . . . . ?
B7 B8 B9 B10 38.8(3) . . . . ?
B10 B8 B9 B3 -102.1(4) . . . . ?
B10 B8 B9 B5 -135.0(3) . . . . ?
B10 B8 B9 B6 -41.0(3) . . . . ?
Ru1 B6 B9 B3 52.8(2) . . . . ?
Ru1 B6 B9 B5 10.8(3) . . . . ?
Ru1 B6 B9 B8 -51.1(3) . . . . ?
Ru1 B6 B9 B10 -91.8(2) . . . . ?
B3 B6 B9 B5 -42.0(3) . . . . ?
B3 B6 B9 B8 -103.9(3) . . . . ?
B3 B6 B9 B10 -144.7(3) . . . . ?
B4 B6 B9 B3 113.0(4) . . . . ?
B4 B6 B9 B5 71.0(4) . . . . ?
B4 B6 B9 B8 9.1(4) . . . . ?
B4 B6 B9 B10 -31.7(3) . . . . ?
B10 B6 B9 B3 144.7(3) . . . . ?
B10 B6 B9 B5 102.6(3) . . . . ?
B10 B6 B9 B8 40.8(3) . . . . ?
Ru1 B4 B10 B6 65.5(2) . . . . ?
Ru1 B4 B10 B7 -65.3(2) . . . . ?
Ru1 B4 B10 B8 -31.1(3) . . . . ?
Ru1 B4 B10 B9 33.3(3) . . . . ?
B6 B4 B10 B7 -130.8(3) . . . . ?
B6 B4 B10 B8 -96.6(3) . . . . ?
B6 B4 B10 B9 -32.1(3) . . . . ?
B7 B4 B10 B6 130.8(3) . . . . ?
B7 B4 B10 B8 34.2(3) . . . . ?
B7 B4 B10 B9 98.6(3) . . . . ?
Ru1 B7 B10 B4 52.6(2) . . . . ?
Ru1 B7 B10 B6 11.7(3) . . . . ?
Ru1 B7 B10 B8 -90.0(2) . . . . ?
Ru1 B7 B10 B9 -50.5(3) . . . . ?
B2 B7 B10 B4 109.1(3) . . . . ?
B2 B7 B10 B6 68.1(4) . . . . ?
B2 B7 B10 B8 -33.5(3) . . . . ?
B2 B7 B10 B9 6.0(4) . . . . ?
B4 B7 B10 B6 -41.0(3) . . . . ?
B4 B7 B10 B8 -142.6(3) . . . . ?
B4 B7 B10 B9 -103.1(3) . . . . ?
B8 B7 B10 B4 142.6(3) . . . . ?
B8 B7 B10 B6 101.7(3) . . . . ?
B8 B7 B10 B9 39.5(3) . . . . ?
B2 B8 B10 B4 0.3(4) . . . . ?
B2 B8 B10 B6 -60.8(4) . . . . ?
B2 B8 B10 B7 33.8(3) . . . . ?
B2 B8 B10 B9 -101.8(3) . . . . ?
B5 B8 B10 B4 62.8(4) . . . . ?
B5 B8 B10 B6 1.8(4) . . . . ?
B5 B8 B10 B7 96.3(3) . . . . ?
B5 B8 B10 B9 -39.2(3) . . . . ?
B7 B8 B10 B4 -33.5(3) . . . . ?
B7 B8 B10 B6 -94.5(3) . . . . ?
B7 B8 B10 B9 -135.6(3) . . . . ?
B9 B8 B10 B4 102.1(4) . . . . ?
B9 B8 B10 B6 41.0(3) . . . . ?
B9 B8 B10 B7 135.6(3) . . . . ?
B3 B9 B10 B4 -0.2(4) . . . . ?
B3 B9 B10 B6 -31.5(3) . . . . ?
B3 B9 B10 B7 62.1(4) . . . . ?
B3 B9 B10 B8 101.8(3) . . . . ?
B5 B9 B10 B4 -62.3(4) . . . . ?
B5 B9 B10 B6 -93.5(3) . . . . ?
B5 B9 B10 B7 0.1(4) . . . . ?
B5 B9 B10 B8 39.7(3) . . . . ?
B6 B9 B10 B4 31.3(3) . . . . ?
B6 B9 B10 B7 93.6(3) . . . . ?
B6 B9 B10 B8 133.3(3) . . . . ?
B8 B9 B10 B4 -102.0(3) . . . . ?
B8 B9 B10 B6 -133.3(3) . . . . ?
B8 B9 B10 B7 -39.7(3) . . . . ?
Ru1 B6 B10 B4 -53.1(2) . . . . ?
Ru1 B6 B10 B7 -11.8(3) . . . . ?
Ru1 B6 B10 B8 50.6(3) . . . . ?
Ru1 B6 B10 B9 91.7(2) . . . . ?
B3 B6 B10 B4 -113.1(3) . . . . ?
B3 B6 B10 B7 -71.7(4) . . . . ?
B3 B6 B10 B8 -9.3(4) . . . . ?
B3 B6 B10 B9 31.7(3) . . . . ?
B4 B6 B10 B7 41.4(3) . . . . ?
B4 B6 B10 B8 103.8(3) . . . . ?
B4 B6 B10 B9 144.8(3) . . . . ?
B9 B6 B10 B4 -144.8(3) . . . . ?
B9 B6 B10 B7 -103.4(3) . . . . ?
B9 B6 B10 B8 -41.0(3) . . . . ?
Pt1 P1 C11 C12 172.2(3) . . . . ?
Pt1 P1 C11 C16 -8.3(4) . . . . ?
C17 P1 C11 C12 -58.0(4) . . . . ?
C17 P1 C11 C16 121.4(3) . . . . ?
C18 P1 C11 C12 48.0(4) . . . . ?
C18 P1 C11 C16 -132.6(3) . . . . ?
P1 C11 C12 C13 179.0(3) . . . . ?
C16 C11 C12 C13 -0.4(6) . . . . ?
C11 C12 C13 C14 -0.1(7) . . . . ?
C12 C13 C14 C15 0.2(7) . . . . ?
C13 C14 C15 C16 0.3(7) . . . . ?
C14 C15 C16 C11 -0.8(7) . . . . ?
P1 C11 C16 C15 -178.6(3) . . . . ?
C12 C11 C16 C15 0.8(6) . . . . ?
Pt1 P2 C21 C22 115.8(3) . . . . ?
Pt1 P2 C21 C26 -64.8(4) . . . . ?
C27 P2 C21 C22 -118.9(4) . . . . ?
C27 P2 C21 C26 60.5(4) . . . . ?
C28 P2 C21 C22 -11.6(5) . . . . ?
C28 P2 C21 C26 167.8(4) . . . . ?
P2 C21 C22 C23 178.8(4) . . . . ?
C26 C21 C22 C23 -0.7(7) . . . . ?
C21 C22 C23 C24 0.6(7) . . . . ?
C22 C23 C24 C25 -1.1(8) . . . . ?
C23 C24 C25 C26 1.7(8) . . . . ?
C24 C25 C26 C21 -1.9(7) . . . . ?
P2 C21 C26 C25 -178.1(4) . . . . ?
C22 C21 C26 C25 1.3(7) . . . . ?
Ru1 P3 C311 C312 -12.5(4) . . . . ?
Ru1 P3 C311 C316 164.4(3) . . . . ?
C321 P3 C311 C312 117.4(3) . . . . ?
C321 P3 C311 C316 -65.6(4) . . . . ?
C331 P3 C311 C312 -135.3(3) . . . . ?
C331 P3 C311 C316 41.7(4) . . . . ?
P3 C311 C312 C313 178.1(3) . . . . ?
C316 C311 C312 C313 1.1(6) . . . . ?
C311 C312 C313 C314 -1.0(6) . . . . ?
C312 C313 C314 C315 0.8(6) . . . . ?
C313 C314 C315 C316 -0.7(7) . . . . ?
C314 C315 C316 C311 0.9(7) . . . . ?
P3 C311 C316 C315 -178.1(3) . . . . ?
C312 C311 C316 C315 -1.1(6) . . . . ?
Ru1 P3 C321 C322 141.1(3) . . . . ?
Ru1 P3 C321 C326 -39.3(4) . . . . ?
C311 P3 C321 C322 11.0(4) . . . . ?
C311 P3 C321 C326 -169.4(3) . . . . ?
C331 P3 C321 C322 -94.4(4) . . . . ?
C331 P3 C321 C326 85.2(4) . . . . ?
P3 C321 C322 C323 179.8(4) . . . . ?
C326 C321 C322 C323 0.3(7) . . . . ?
C321 C322 C323 C324 -0.7(8) . . . . ?
C322 C323 C324 C325 0.5(8) . . . . ?
C323 C324 C325 C326 0.1(8) . . . . ?
C324 C325 C326 C321 -0.5(7) . . . . ?
P3 C321 C326 C325 -179.3(4) . . . . ?
C322 C321 C326 C325 0.3(6) . . . . ?
Ru1 P3 C331 C332 95.3(3) . . . . ?
Ru1 P3 C331 C336 -82.9(3) . . . . ?
C311 P3 C331 C332 -140.0(3) . . . . ?
C311 P3 C331 C336 41.8(4) . . . . ?
C321 P3 C331 C332 -30.8(4) . . . . ?
C321 P3 C331 C336 151.0(3) . . . . ?
P3 C331 C332 C333 -178.4(3) . . . . ?
C336 C331 C332 C333 -0.2(6) . . . . ?
C331 C332 C333 C334 -0.6(6) . . . . ?
C332 C333 C334 C335 0.9(6) . . . . ?
C333 C334 C335 C336 -0.4(7) . . . . ?
P3 C331 C336 C335 178.9(3) . . . . ?
C332 C331 C336 C335 0.7(6) . . . . ?
C334 C335 C336 C331 -0.4(7) . . . . ?
