#------------------------------------------------------------------------------
#$Date: 2021-11-17 02:15:37 +0200 (Wed, 17 Nov 2021) $
#$Revision: 270707 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/88/7708860.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7708860
loop_
_publ_author_name
'King, Rhys'
'Levason, William'
'Reid, Gillian'
_publ_section_title
;
 Neutral and cationic germanium(IV) fluoride complexes with phosphine
 coordination -- synthesis, spectroscopy and structures
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D1DT03339E
_journal_year                    2021
_chemical_formula_moiety         'C14 H30 As2 Cl2 F6 Ge O6 S2'
_chemical_formula_sum            'C14 H30 As2 Cl2 F6 Ge O6 S2'
_chemical_formula_weight         765.83
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_date             2021-09-14
_audit_creation_method
;
Olex2 1.5
(compiled 2021.08.20 svn.r13c46975 for OlexSys, GUI svn.r6396)
;
_audit_update_record
;
2021-09-30 deposited with the CCDC.	2021-11-15 downloaded from the CCDC.
;
_cell_angle_alpha                104.887(3)
_cell_angle_beta                 101.440(3)
_cell_angle_gamma                97.269(3)
_cell_formula_units_Z            2
_cell_length_a                   9.6136(3)
_cell_length_b                   9.7490(4)
_cell_length_c                   15.2210(5)
_cell_measurement_reflns_used    10889
_cell_measurement_temperature    100.01(10)
_cell_measurement_theta_max      32.6400
_cell_measurement_theta_min      3.5760
_cell_volume                     1327.35(9)
_computing_cell_refinement       'CrysAlisPro 1.171.40.61a (Rigaku OD, 2019)'
_computing_data_collection       'CrysAlisPro 1.171.40.61a (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.61a (Rigaku OD, 2019)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2017/1 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.01(10)
_diffrn_detector                 'CCD plate'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.898
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω   -100.00 -63.00   1.00    1.42    --  -13.90 -38.00  90.00   37
  2  ω    -38.00 -12.00   1.00    1.42    --  -13.90 -38.00  90.00   26
  3  ω    -71.00  12.00   1.00    1.42    --  -13.90 -60.00  30.00   83
  4  ω   -103.00  -4.00   1.00    1.42    --  -13.90 -60.00-150.00   99
  5  ω    -82.00  11.00   1.00    1.42    --  -13.90 -60.00 -60.00   93
  6  ω    -26.00  48.00   1.00    1.42    --  -13.90  38.00-180.00   74
  7  ω     12.00  39.00   1.00    1.42    --  -13.90  19.00  60.00   27
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB AFC12 (RCD3): Kappa single'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0280254000
_diffrn_orient_matrix_UB_12      0.0222925000
_diffrn_orient_matrix_UB_13      0.0492490000
_diffrn_orient_matrix_UB_21      0.0192397000
_diffrn_orient_matrix_UB_22      0.0721152000
_diffrn_orient_matrix_UB_23      -0.0010952000
_diffrn_orient_matrix_UB_31      -0.0686809000
_diffrn_orient_matrix_UB_32      0.0132757000
_diffrn_orient_matrix_UB_33      0.0064409000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0600
_diffrn_reflns_av_unetI/netI     0.0740
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.898
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            22109
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.898
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         32.908
_diffrn_reflns_theta_min         2.897
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    4.057
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.36618
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.61a (Rigaku Oxford Diffraction, 2019)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.916
_exptl_crystal_description       block
_exptl_crystal_F_000             760
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.167
_refine_diff_density_min         -1.118
_refine_diff_density_rms         0.154
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     304
_refine_ls_number_reflns         8925
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.029
_refine_ls_R_factor_all          0.0593
_refine_ls_R_factor_gt           0.0420
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0290P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0809
_refine_ls_wR_factor_ref         0.0882
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7063
_reflns_number_total             8925
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1dt03339e2.cif
_cod_data_source_block           gecl2(aset3)2otf2
_cod_original_cell_volume        1327.35(8)
_cod_database_code               7708860
_shelx_shelxl_version_number     2017/1
_chemical_oxdiff_formula         'Ge Cl2 As2 O6 F6 S2 H30 C13'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.823
_shelx_estimated_absorpt_t_min   0.498
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C1(H1A,H1B), C9(H9A,H9B), C3(H3A,H3B), C11(H11A,H11B), C5(H5A,H5B)
2.b Idealised Me refined as rotating group:
 C12(H12A,H12B,H12C), C2(H2A,H2B,H2C), C6(H6A,H6B,H6C), C4(H4A,H4B,H4C),
 C8(H8A,H8B,H8C), C10(H10A,H10B,H10C)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 3.857
_oxdiff_exptl_absorpt_empirical_full_min 0.368
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
As1 As 0.66705(3) 0.57721(3) 0.81861(2) 0.01029(7) Uani 1 1 d . . . . .
As2 As 0.35373(3) 0.81656(3) 0.72523(2) 0.01037(7) Uani 1 1 d . . . . .
Ge1 Ge 0.54536(3) 0.77980(3) 0.84122(2) 0.01075(7) Uani 1 1 d . . . . .
Cl2 Cl 0.70981(7) 0.97226(7) 0.88212(5) 0.01526(14) Uani 1 1 d . . . . .
Cl1 Cl 0.47552(7) 0.79613(8) 0.96832(5) 0.01677(14) Uani 1 1 d . . . . .
S1 S 0.24333(7) 0.43131(8) 0.80439(5) 0.01348(14) Uani 1 1 d . . . . .
S2 S 0.70835(7) 0.73639(8) 0.60202(5) 0.01313(14) Uani 1 1 d . . . . .
O1 O 0.33844(19) 0.5417(2) 0.78370(14) 0.0157(4) Uani 1 1 d . . . . .
F2 F 0.04100(18) 0.4483(2) 0.66869(13) 0.0267(4) Uani 1 1 d . . . . .
F6 F 0.7190(2) 1.0113(2) 0.61532(14) 0.0296(4) Uani 1 1 d . . . . .
F5 F 0.89563(19) 0.9661(2) 0.70804(13) 0.0283(4) Uani 1 1 d . . . . .
O2 O 0.63554(19) 0.7546(2) 0.67865(14) 0.0152(4) Uani 1 1 d . . . . .
F4 F 0.88815(19) 0.9224(2) 0.56104(13) 0.0267(4) Uani 1 1 d . . . . .
F3 F 0.0201(2) 0.2401(2) 0.69347(15) 0.0361(5) Uani 1 1 d . . . . .
F1 F 0.1804(2) 0.3046(2) 0.62364(14) 0.0380(5) Uani 1 1 d . . . . .
O5 O 0.6127(2) 0.7040(3) 0.51149(15) 0.0256(5) Uani 1 1 d . . . . .
O4 O 0.3116(2) 0.3151(2) 0.82239(17) 0.0255(5) Uani 1 1 d . . . . .
O3 O 0.1553(2) 0.4872(3) 0.86536(15) 0.0249(5) Uani 1 1 d . . . . .
O6 O 0.8215(2) 0.6541(2) 0.61099(16) 0.0232(5) Uani 1 1 d . . . . .
C7 C 0.3045(3) 0.6664(3) 0.60650(19) 0.0132(5) Uani 1 1 d . . . . .
H7A H 0.374770 0.683568 0.570935 0.016 Uiso 1 1 calc R U . . .
H7B H 0.309781 0.573774 0.618186 0.016 Uiso 1 1 calc R U . . .
C1 C 0.5820(3) 0.4306(3) 0.70061(19) 0.0144(5) Uani 1 1 d . . . . .
H1A H 0.507315 0.362302 0.709534 0.017 Uiso 1 1 calc R U . . .
H1B H 0.536171 0.476008 0.655785 0.017 Uiso 1 1 calc R U . . .
C9 C 0.4225(3) 1.0025(3) 0.7094(2) 0.0160(6) Uani 1 1 d . . . . .
H9A H 0.413193 1.078798 0.761946 0.019 Uiso 1 1 calc R U . . .
H9B H 0.524127 1.011073 0.709355 0.019 Uiso 1 1 calc R U . . .
C3 C 0.6577(3) 0.4897(3) 0.9180(2) 0.0153(6) Uani 1 1 d . . . . .
H3A H 0.700824 0.560755 0.978171 0.018 Uiso 1 1 calc R U . . .
H3B H 0.557611 0.455424 0.916153 0.018 Uiso 1 1 calc R U . . .
C11 C 0.1856(3) 0.8267(3) 0.7772(2) 0.0149(6) Uani 1 1 d . . . . .
H11A H 0.100292 0.807038 0.726365 0.018 Uiso 1 1 calc R U . . .
H11B H 0.175896 0.751693 0.808101 0.018 Uiso 1 1 calc R U . . .
C14 C 0.8078(3) 0.9181(3) 0.6224(2) 0.0176(6) Uani 1 1 d . . . . .
C5 C 0.8698(3) 0.6534(3) 0.8354(2) 0.0157(6) Uani 1 1 d . . . . .
H5A H 0.917031 0.575513 0.809703 0.019 Uiso 1 1 calc R U . . .
H5B H 0.878623 0.723826 0.800913 0.019 Uiso 1 1 calc R U . . .
C12 C 0.1914(3) 0.9716(3) 0.8469(2) 0.0196(6) Uani 1 1 d . . . . .
H12A H 0.200834 1.046667 0.816987 0.029 Uiso 1 1 calc R U . . .
H12B H 0.272805 0.989886 0.899125 0.029 Uiso 1 1 calc R U . . .
H12C H 0.104138 0.969803 0.868568 0.029 Uiso 1 1 calc R U . . .
C2 C 0.6898(3) 0.3486(3) 0.6600(2) 0.0184(6) Uani 1 1 d . . . . .
H2A H 0.639793 0.273812 0.603816 0.028 Uiso 1 1 calc R U . . .
H2B H 0.738353 0.306183 0.704807 0.028 Uiso 1 1 calc R U . . .
H2C H 0.759333 0.413923 0.645691 0.028 Uiso 1 1 calc R U . . .
C6 C 0.9458(3) 0.7246(3) 0.9382(2) 0.0201(6) Uani 1 1 d . . . . .
H6A H 1.045472 0.761481 0.943311 0.030 Uiso 1 1 calc R U . . .
H6B H 0.939673 0.654662 0.972221 0.030 Uiso 1 1 calc R U . . .
H6C H 0.900168 0.802622 0.963653 0.030 Uiso 1 1 calc R U . . .
C4 C 0.7384(3) 0.3633(3) 0.9067(2) 0.0194(6) Uani 1 1 d . . . . .
H4A H 0.686171 0.286217 0.852282 0.029 Uiso 1 1 calc R U . . .
H4B H 0.746648 0.329631 0.961135 0.029 Uiso 1 1 calc R U . . .
H4C H 0.833162 0.394539 0.899397 0.029 Uiso 1 1 calc R U . . .
C8 C 0.1535(3) 0.6602(3) 0.5484(2) 0.0161(6) Uani 1 1 d . . . . .
H8A H 0.134113 0.584244 0.490609 0.024 Uiso 1 1 calc R U . . .
H8B H 0.148311 0.750817 0.535254 0.024 Uiso 1 1 calc R U . . .
H8C H 0.083251 0.641483 0.582780 0.024 Uiso 1 1 calc R U . . .
C13 C 0.1149(3) 0.3501(3) 0.6913(2) 0.0193(6) Uani 1 1 d . . . . .
C10 C 0.3390(4) 1.0224(4) 0.6185(3) 0.0346(9) Uani 1 1 d . . . . .
H10A H 0.347881 0.947216 0.566172 0.052 Uiso 1 1 calc R U . . .
H10B H 0.377602 1.114695 0.612843 0.052 Uiso 1 1 calc R U . . .
H10C H 0.238883 1.017940 0.619213 0.052 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 As1 Ge1 112.97(8) . . ?
C1 As1 C5 113.81(12) . . ?
C3 As1 Ge1 108.84(9) . . ?
C3 As1 C1 108.00(13) . . ?
C3 As1 C5 105.79(12) . . ?
C5 As1 Ge1 107.11(9) . . ?
C7 As2 Ge1 113.86(8) . . ?
C7 As2 C9 110.76(12) . . ?
C9 As2 Ge1 105.31(8) . . ?
C11 As2 Ge1 107.48(8) . . ?
C11 As2 C7 109.66(12) . . ?
C11 As2 C9 109.61(12) . . ?
As1 Ge1 As2 125.186(16) . . ?
As1 Ge1 O1 73.60(4) . . ?
As1 Ge1 O2 72.71(4) . . ?
As2 Ge1 O1 72.61(4) . . ?
As2 Ge1 O2 71.52(4) . . ?
Cl2 Ge1 As1 106.87(2) . . ?
Cl2 Ge1 As2 105.54(2) . . ?
Cl2 Ge1 O1 177.79(5) . . ?
Cl2 Ge1 O2 79.17(5) . . ?
Cl1 Ge1 As1 106.40(2) . . ?
Cl1 Ge1 As2 109.00(2) . . ?
Cl1 Ge1 Cl2 101.36(3) . . ?
Cl1 Ge1 O1 80.50(5) . . ?
Cl1 Ge1 O2 179.08(5) . . ?
O1 Ge1 O2 98.99(6) . . ?
O1 S1 C13 101.53(12) . . ?
O4 S1 O1 113.57(12) . . ?
O4 S1 C13 104.38(15) . . ?
O3 S1 O1 114.38(13) . . ?
O3 S1 O4 116.86(14) . . ?
O3 S1 C13 103.67(13) . . ?
O2 S2 C14 102.61(13) . . ?
O5 S2 O2 113.96(12) . . ?
O5 S2 O6 117.10(14) . . ?
O5 S2 C14 104.50(13) . . ?
O6 S2 O2 113.56(12) . . ?
O6 S2 C14 102.74(13) . . ?
S1 O1 Ge1 150.51(12) . . ?
S2 O2 Ge1 169.32(11) . . ?
As2 C7 H7A 109.1 . . ?
As2 C7 H7B 109.1 . . ?
H7A C7 H7B 107.8 . . ?
C8 C7 As2 112.62(19) . . ?
C8 C7 H7A 109.1 . . ?
C8 C7 H7B 109.1 . . ?
As1 C1 H1A 108.8 . . ?
As1 C1 H1B 108.8 . . ?
H1A C1 H1B 107.7 . . ?
C2 C1 As1 113.76(19) . . ?
C2 C1 H1A 108.8 . . ?
C2 C1 H1B 108.8 . . ?
As2 C9 H9A 109.2 . . ?
As2 C9 H9B 109.2 . . ?
H9A C9 H9B 107.9 . . ?
C10 C9 As2 112.2(2) . . ?
C10 C9 H9A 109.2 . . ?
C10 C9 H9B 109.2 . . ?
As1 C3 H3A 109.7 . . ?
As1 C3 H3B 109.7 . . ?
H3A C3 H3B 108.2 . . ?
C4 C3 As1 109.70(19) . . ?
C4 C3 H3A 109.7 . . ?
C4 C3 H3B 109.7 . . ?
As2 C11 H11A 108.8 . . ?
As2 C11 H11B 108.8 . . ?
H11A C11 H11B 107.7 . . ?
C12 C11 As2 113.92(19) . . ?
C12 C11 H11A 108.8 . . ?
C12 C11 H11B 108.8 . . ?
F6 C14 S2 111.55(19) . . ?
F6 C14 F5 107.5(2) . . ?
F5 C14 S2 110.83(19) . . ?
F4 C14 S2 111.7(2) . . ?
F4 C14 F6 107.3(2) . . ?
F4 C14 F5 107.7(2) . . ?
As1 C5 H5A 109.2 . . ?
As1 C5 H5B 109.2 . . ?
H5A C5 H5B 107.9 . . ?
C6 C5 As1 112.14(19) . . ?
C6 C5 H5A 109.2 . . ?
C6 C5 H5B 109.2 . . ?
C11 C12 H12A 109.5 . . ?
C11 C12 H12B 109.5 . . ?
C11 C12 H12C 109.5 . . ?
H12A C12 H12B 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C1 C2 H2A 109.5 . . ?
C1 C2 H2B 109.5 . . ?
C1 C2 H2C 109.5 . . ?
H2A C2 H2B 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C3 C4 H4A 109.5 . . ?
C3 C4 H4B 109.5 . . ?
C3 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
F2 C13 S1 109.6(2) . . ?
F3 C13 S1 111.5(2) . . ?
F3 C13 F2 107.6(2) . . ?
F1 C13 S1 111.9(2) . . ?
F1 C13 F2 107.2(2) . . ?
F1 C13 F3 108.9(3) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
As1 Ge1 2.4048(4) . ?
As1 C1 1.934(3) . ?
As1 C3 1.930(3) . ?
As1 C5 1.938(3) . ?
As2 Ge1 2.4169(4) . ?
As2 C7 1.939(3) . ?
As2 C9 1.941(3) . ?
As2 C11 1.938(3) . ?
Ge1 Cl2 2.1602(7) . ?
Ge1 Cl1 2.1453(7) . ?
Ge1 O1 2.6848(19) . ?
Ge1 O2 2.7436(19) . ?
S1 O1 1.460(2) . ?
S1 O4 1.437(2) . ?
S1 O3 1.429(2) . ?
S1 C13 1.824(3) . ?
S2 O2 1.4598(19) . ?
S2 O5 1.430(2) . ?
S2 O6 1.437(2) . ?
S2 C14 1.822(3) . ?
F2 C13 1.336(4) . ?
F6 C14 1.332(3) . ?
F5 C14 1.335(3) . ?
F4 C14 1.330(3) . ?
F3 C13 1.328(3) . ?
F1 C13 1.321(3) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C7 C8 1.527(4) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C1 C2 1.518(4) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C9 C10 1.528(4) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C3 C4 1.528(4) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C11 C12 1.520(4) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C5 C6 1.524(4) . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C4 H4A 0.9600 . ?
C4 H4B 0.9600 . ?
C4 H4C 0.9600 . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 S1 C13 F2 -63.8(2) . . . . ?
O1 S1 C13 F3 177.2(2) . . . . ?
O1 S1 C13 F1 55.0(2) . . . . ?
O2 S2 C14 F6 -62.9(2) . . . . ?
O2 S2 C14 F5 56.8(2) . . . . ?
O2 S2 C14 F4 176.97(19) . . . . ?
O5 S2 O2 Ge1 160.9(6) . . . . ?
O5 S2 C14 F6 56.2(2) . . . . ?
O5 S2 C14 F5 176.04(19) . . . . ?
O5 S2 C14 F4 -63.8(2) . . . . ?
O4 S1 O1 Ge1 -82.7(3) . . . . ?
O4 S1 C13 F2 177.98(18) . . . . ?
O4 S1 C13 F3 59.0(2) . . . . ?
O4 S1 C13 F1 -63.3(2) . . . . ?
O3 S1 O1 Ge1 54.9(3) . . . . ?
O3 S1 C13 F2 55.1(2) . . . . ?
O3 S1 C13 F3 -63.9(2) . . . . ?
O3 S1 C13 F1 173.9(2) . . . . ?
O6 S2 O2 Ge1 23.3(7) . . . . ?
O6 S2 C14 F6 179.0(2) . . . . ?
O6 S2 C14 F5 -61.2(2) . . . . ?
O6 S2 C14 F4 58.9(2) . . . . ?
C14 S2 O2 Ge1 -86.8(7) . . . . ?
C13 S1 O1 Ge1 165.9(2) . . . . ?
