#------------------------------------------------------------------------------
#$Date: 2022-03-16 01:58:16 +0200 (Wed, 16 Mar 2022) $
#$Revision: 273708 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/70/97/7709757.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7709757
loop_
_publ_author_name
'Priola, Emanuele'
'Giordana, Alessia'
'Gomila, Rosa Maria'
'Zangrando, Ennio'
'Andreo, Luca'
'Rabezzana, Roberto'
'Operti, Lorenza'
'Diana, Eliano'
'Mahmoudi, Ghodrat'
'Frontera, Antonio'
_publ_section_title
;
 Metallophilic interactions in silver(I) dicyanoaurate complexes
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D2DT00615D
_journal_year                    2022
_chemical_formula_moiety         'C43 H27 Ag4 Au4 N15'
_chemical_formula_sum            'C43 H27 Ag4 Au4 N15'
_chemical_formula_weight         1973.14
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2022-02-25 deposited with the CCDC.	2022-03-15 downloaded from the CCDC.
;
_cell_angle_alpha                116.322(7)
_cell_angle_beta                 95.174(5)
_cell_angle_gamma                101.927(6)
_cell_formula_units_Z            2
_cell_length_a                   11.3724(8)
_cell_length_b                   14.8294(10)
_cell_length_c                   16.3394(11)
_cell_measurement_reflns_used    4029
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      24.83
_cell_measurement_theta_min      3.75
_cell_volume                     2364.0(3)
_computing_cell_refinement       'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_data_collection       'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, AtlasS2, Gemini ultra'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0483
_diffrn_reflns_av_unetI/netI     0.0870
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            21036
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.369
_diffrn_reflns_theta_min         3.221
_exptl_absorpt_coefficient_mu    14.031
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.50193
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.93a (Rigaku Oxford Diffraction, 2020)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.772
_exptl_crystal_description       prism
_exptl_crystal_F_000             1788
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.752
_refine_diff_density_min         -0.887
_refine_diff_density_rms         0.206
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     595
_refine_ls_number_reflns         9662
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.071
_refine_ls_R_factor_all          0.1358
_refine_ls_R_factor_gt           0.0644
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0324P)²+4.9520P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1041
_refine_ls_wR_factor_ref         0.1271
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5331
_reflns_number_total             9662
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt00615d2.cif
_cod_data_source_block           4
_cod_database_code               7709757
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.227
_shelx_estimated_absorpt_t_max   0.334
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.54336(13) 0.81021(10) 0.07292(8) 0.0710(4) Uani 1 1 d . . . . .
Ag2 Ag -0.03343(12) 0.67960(10) -0.07171(8) 0.0723(4) Uani 1 1 d . . . . .
Ag3 Ag 0.74684(12) 0.86997(10) 0.44394(8) 0.0706(4) Uani 1 1 d . . . . .
Ag4 Ag 0.26108(15) 1.35489(11) 0.43614(9) 0.0832(5) Uani 1 1 d . . . . .
Au1 Au 0.32615(6) 1.09046(5) 0.07422(4) 0.0598(2) Uani 1 1 d . . . . .
Au2 Au 0.35207(6) 0.76596(5) 0.19017(4) 0.05499(18) Uani 1 1 d . . . . .
Au3 Au 0.15505(6) 0.72997(5) 0.30944(4) 0.05912(19) Uani 1 1 d . . . . .
Au4 Au 1.03139(6) 0.63333(5) 0.44725(4) 0.0626(2) Uani 1 1 d . . . . .
N1 N 0.4651(12) 0.9378(11) 0.0940(8) 0.068(4) Uani 1 1 d . . . . .
N2 N 0.1675(13) 1.2293(11) 0.0591(9) 0.076(4) Uani 1 1 d . . . . .
N3 N 0.5788(14) 0.8165(12) 0.3389(9) 0.083(5) Uani 1 1 d . . . . .
N4 N 0.1234(13) 0.7171(11) 0.0432(9) 0.073(4) Uani 1 1 d . . . . .
N5 N 0.2135(14) 0.9671(12) 0.4475(9) 0.081(4) Uani 1 1 d . . . . .
N6 N 0.0919(15) 0.4940(11) 0.1705(9) 0.087(5) Uani 1 1 d . . . . .
N7 N 1.1849(12) 0.4774(12) 0.4518(7) 0.069(4) Uani 1 1 d . . . . .
N8 N 0.8628(12) 0.7759(11) 0.4462(8) 0.069(4) Uani 1 1 d . . . . .
N9 N 0.1025(13) 0.7217(11) -0.1624(9) 0.073(4) Uani 1 1 d . . . . .
N10 N 0.7284(11) 0.9004(10) 0.1978(7) 0.065(4) Uani 1 1 d . . . . .
N11 N 0.6674(12) 0.7013(9) 0.0696(7) 0.052(3) Uani 1 1 d . . . . .
N12 N 0.4602(12) 0.6403(9) -0.0562(8) 0.063(3) Uani 1 1 d . . . . .
N13 N 0.4387(14) 1.4469(11) 0.5661(8) 0.082(4) Uani 1 1 d . . . . .
N14 N 0.3911(12) 1.2440(10) 0.4394(8) 0.058(3) Uani 1 1 d . . . . .
N15 N 0.1860(13) 1.1839(10) 0.3069(8) 0.071(4) Uani 1 1 d . . . . .
C1 C 0.4164(13) 0.9925(12) 0.0862(8) 0.052(4) Uani 1 1 d . . . . .
C2 C 0.2254(15) 1.1791(12) 0.0612(9) 0.058(4) Uani 1 1 d . . . . .
C3 C 0.4945(15) 0.7988(12) 0.2829(10) 0.062(4) Uani 1 1 d . . . . .
C4 C 0.2057(15) 0.7332(12) 0.0961(10) 0.064(4) Uani 1 1 d . . . . .
C5 C 0.1933(16) 0.8822(14) 0.3969(11) 0.067(5) Uani 1 1 d . . . . .
C6 C 0.1104(14) 0.5777(13) 0.2198(9) 0.058(4) Uani 1 1 d . . . . .
C7 C 1.1281(16) 0.5387(11) 0.4498(9) 0.060(5) Uani 1 1 d . . . . .
C8 C 0.9211(17) 0.7231(13) 0.4473(10) 0.066(5) Uani 1 1 d . . . . .
C9 C 0.1964(19) 0.8070(15) -0.1214(13) 0.085(6) Uani 1 1 d . . . . .
H9 H 0.200963 0.853454 -0.059205 0.102 Uiso 1 1 calc R U . . .
C10 C 0.285(2) 0.832(2) -0.1624(17) 0.116(8) Uani 1 1 d . . . . .
H10 H 0.347857 0.893694 -0.129971 0.140 Uiso 1 1 calc R U . . .
C11 C 0.282(3) 0.762(2) -0.255(2) 0.127(10) Uani 1 1 d . . . . .
H11 H 0.341124 0.776008 -0.285893 0.152 Uiso 1 1 calc R U . . .
C12 C 0.187(3) 0.671(2) -0.2978(15) 0.120(9) Uani 1 1 d . . . . .
H12 H 0.181960 0.622561 -0.359446 0.144 Uiso 1 1 calc R U . . .
C13 C 0.1017(19) 0.6527(14) -0.2509(11) 0.083(6) Uani 1 1 d . . . . .
H13 H 0.039770 0.589988 -0.280781 0.099 Uiso 1 1 calc R U . . .
C14 C 0.3509(18) 0.6112(15) -0.1133(11) 0.089(6) Uani 1 1 d . . . . .
H14 H 0.305924 0.659794 -0.101113 0.107 Uiso 1 1 calc R U . . .
C15 C 0.3014(17) 0.5112(15) -0.1901(12) 0.088(6) Uani 1 1 d . . . . .
H15 H 0.225560 0.491584 -0.228898 0.106 Uiso 1 1 calc R U . . .
C16 C 0.374(3) 0.4448(15) -0.2033(13) 0.098(8) Uani 1 1 d . . . . .
H16 H 0.349385 0.379055 -0.255650 0.118 Uiso 1 1 calc R U . . .
C17 C 0.475(2) 0.4689(13) -0.1473(13) 0.078(6) Uani 1 1 d . . . . .
H17 H 0.517115 0.419066 -0.156413 0.094 Uiso 1 1 calc R U . . .
C18 C 0.5214(15) 0.5704(12) -0.0716(9) 0.058(4) Uani 1 1 d . . . . .
C19 C 0.6372(16) 0.6010(12) -0.0059(10) 0.064(5) Uani 1 1 d . . . . .
C20 C 0.7140(17) 0.5379(14) -0.0175(11) 0.075(5) Uani 1 1 d . . . . .
H20 H 0.691813 0.470792 -0.067935 0.090 Uiso 1 1 calc R U . . .
C21 C 0.8291(19) 0.5749(17) 0.0480(13) 0.092(6) Uani 1 1 d . . . . .
H21 H 0.883061 0.533827 0.041067 0.111 Uiso 1 1 calc R U . . .
C22 C 0.8540(17) 0.6741(15) 0.1211(11) 0.082(6) Uani 1 1 d . . . . .
H22 H 0.926639 0.702456 0.165568 0.099 Uiso 1 1 calc R U . . .
C23 C 0.7703(17) 0.7324(13) 0.1286(11) 0.065(5) Uani 1 1 d . . . . .
C24 C 0.8018(15) 0.8440(14) 0.2080(10) 0.066(5) Uani 1 1 d . . . . .
C25 C 0.8940(14) 0.8848(16) 0.2870(12) 0.073(5) Uani 1 1 d . . . . .
H25 H 0.940813 0.843077 0.293869 0.088 Uiso 1 1 calc R U . . .
C26 C 0.9156(17) 0.9851(18) 0.3536(12) 0.086(6) Uani 1 1 d . . . . .
H26 H 0.981328 1.014287 0.404076 0.103 Uiso 1 1 calc R U . . .
C27 C 0.839(2) 1.0456(16) 0.3466(11) 0.094(6) Uani 1 1 d . . . . .
H27 H 0.848924 1.113735 0.392898 0.113 Uiso 1 1 calc R U . . .
C28 C 0.7451(18) 0.9974(16) 0.2658(12) 0.089(6) Uani 1 1 d . . . . .
H28 H 0.692316 1.035267 0.259542 0.106 Uiso 1 1 calc R U . . .
C29 C 0.463(2) 1.5483(16) 0.6281(13) 0.094(6) Uani 1 1 d . . . . .
H29 H 0.411574 1.585321 0.618659 0.113 Uiso 1 1 calc R U . . .
C30 C 0.556(3) 1.601(2) 0.7021(15) 0.120(8) Uani 1 1 d . . . . .
H30 H 0.570045 1.671851 0.742984 0.143 Uiso 1 1 calc R U . . .
C31 C 0.629(2) 1.545(2) 0.7137(13) 0.101(7) Uani 1 1 d . . . . .
H31 H 0.692815 1.578711 0.765616 0.121 Uiso 1 1 calc R U . . .
C32 C 0.6155(16) 1.4421(17) 0.6560(12) 0.077(5) Uani 1 1 d . . . . .
H32 H 0.667299 1.405768 0.666737 0.093 Uiso 1 1 calc R U . . .
C33 C 0.5181(16) 1.3952(14) 0.5789(10) 0.070(5) Uani 1 1 d . . . . .
C34 C 0.4896(16) 1.2857(13) 0.5038(10) 0.063(4) Uani 1 1 d . . . . .
C35 C 0.5731(15) 1.2226(16) 0.4988(12) 0.081(6) Uani 1 1 d . . . . .
H35 H 0.648362 1.252750 0.540721 0.098 Uiso 1 1 calc R U . . .
C36 C 0.543(2) 1.1188(16) 0.4330(14) 0.105(7) Uani 1 1 d . . . . .
H36 H 0.588036 1.074226 0.435659 0.126 Uiso 1 1 calc R U . . .
C37 C 0.4377(18) 1.0832(14) 0.3604(12) 0.090(6) Uani 1 1 d . . . . .
H37 H 0.423087 1.018434 0.307754 0.108 Uiso 1 1 calc R U . . .
C38 C 0.3564(16) 1.1443(13) 0.3672(10) 0.063(5) Uani 1 1 d . . . . .
C39 C 0.2432(15) 1.1090(12) 0.3007(10) 0.059(4) Uani 1 1 d . . . . .
C40 C 0.193(2) 1.0061(15) 0.2331(14) 0.084(6) Uani 1 1 d . . . . .
H40 H 0.232100 0.956633 0.232562 0.100 Uiso 1 1 calc R U . . .
C41 C 0.093(2) 0.9744(14) 0.1693(13) 0.093(7) Uani 1 1 d . . . . .
H41 H 0.061941 0.905251 0.122783 0.112 Uiso 1 1 calc R U . . .
C42 C 0.0335(19) 1.0548(17) 0.1764(12) 0.100(7) Uani 1 1 d . . . . .
H42 H -0.038934 1.037199 0.134632 0.120 Uiso 1 1 calc R U . . .
C43 C 0.0838(18) 1.1560(15) 0.2443(11) 0.090(6) Uani 1 1 d . . . . .
H43 H 0.045893 1.206849 0.246873 0.108 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N11 167.5(5) . . ?
N1 Ag1 N12 122.2(4) . . ?
N11 Ag1 N12 69.3(4) . . ?
N1 Ag1 N10 101.3(4) . . ?
N11 Ag1 N10 66.9(4) . . ?
N12 Ag1 N10 136.2(4) . . ?
N1 Ag1 Au2 83.3(4) . . ?
N11 Ag1 Au2 102.0(3) . . ?
N12 Ag1 Au2 92.4(3) . . ?
N10 Ag1 Au2 98.6(3) . . ?
N2 Ag2 N4 125.1(5) 2_575 . ?
N2 Ag2 N6 119.3(5) 2_575 2_565 ?
N4 Ag2 N6 109.7(5) . 2_565 ?
N2 Ag2 N9 105.9(5) 2_575 . ?
N4 Ag2 N9 92.8(5) . . ?
N6 Ag2 N9 94.7(5) 2_565 . ?
N8 Ag3 N5 121.1(5) . 2_676 ?
N8 Ag3 N3 124.8(5) . . ?
N5 Ag3 N3 114.1(5) 2_676 . ?
N7 Ag4 N15 122.8(4) 1_465 . ?
N7 Ag4 N14 167.2(5) 1_465 . ?
N15 Ag4 N14 68.9(4) . . ?
N7 Ag4 N13 101.1(5) 1_465 . ?
N15 Ag4 N13 135.7(5) . . ?
N14 Ag4 N13 66.8(4) . . ?
C2 Au1 C1 175.6(7) . . ?
C3 Au2 C4 179.5(6) . . ?
C3 Au2 Ag1 85.7(5) . . ?
C4 Au2 Ag1 94.6(5) . . ?
C3 Au2 Au3 95.3(5) . . ?
C4 Au2 Au3 84.4(5) . . ?
Ag1 Au2 Au3 177.50(3) . . ?
C5 Au3 C6 177.8(6) . . ?
C5 Au3 Au2 92.7(5) . . ?
C6 Au3 Au2 88.1(4) . . ?
C7 Au4 C8 175.1(7) . . ?
C1 N1 Ag1 166.1(12) . . ?
C2 N2 Ag2 169.3(14) . 2_575 ?
C3 N3 Ag3 172.2(15) . . ?
C4 N4 Ag2 175.5(13) . . ?
C5 N5 Ag3 175.2(15) . 2_676 ?
C6 N6 Ag2 174.0(15) . 2_565 ?
C7 N7 Ag4 170.9(12) . 1_645 ?
C8 N8 Ag3 177.5(15) . . ?
C9 N9 C13 116.3(17) . . ?
C9 N9 Ag2 120.1(13) . . ?
C13 N9 Ag2 122.5(14) . . ?
C28 N10 C24 118.5(14) . . ?
C28 N10 Ag1 121.5(11) . . ?
C24 N10 Ag1 118.7(11) . . ?
C23 N11 C19 117.5(12) . . ?
C23 N11 Ag1 123.8(9) . . ?
C19 N11 Ag1 118.2(10) . . ?
C18 N12 C14 118.2(14) . . ?
C18 N12 Ag1 118.9(10) . . ?
C14 N12 Ag1 122.9(10) . . ?
C29 N13 C33 116.3(15) . . ?
C29 N13 Ag4 123.3(12) . . ?
C33 N13 Ag4 120.3(11) . . ?
C34 N14 C38 125.9(14) . . ?
C34 N14 Ag4 118.3(10) . . ?
C38 N14 Ag4 115.6(10) . . ?
C43 N15 C39 118.7(14) . . ?
C43 N15 Ag4 122.0(11) . . ?
C39 N15 Ag4 119.0(10) . . ?
N1 C1 Au1 178.6(14) . . ?
N2 C2 Au1 175.5(13) . . ?
N3 C3 Au2 178.4(16) . . ?
N4 C4 Au2 178.2(15) . . ?
N5 C5 Au3 178.4(17) . . ?
N6 C6 Au3 176.5(15) . . ?
N7 C7 Au4 177.7(15) . . ?
N8 C8 Au4 177.1(16) . . ?
N9 C9 C10 125(2) . . ?
N9 C9 H9 117.5 . . ?
C10 C9 H9 117.5 . . ?
C9 C10 C11 118(2) . . ?
C9 C10 H10 120.9 . . ?
C11 C10 H10 120.9 . . ?
C12 C11 C10 118(2) . . ?
C12 C11 H11 121.1 . . ?
C10 C11 H11 121.1 . . ?
C13 C12 C11 120(2) . . ?
C13 C12 H12 120.1 . . ?
C11 C12 H12 120.1 . . ?
C12 C13 N9 123(2) . . ?
C12 C13 H13 118.7 . . ?
N9 C13 H13 118.7 . . ?
N12 C14 C15 123.4(15) . . ?
N12 C14 H14 118.3 . . ?
C15 C14 H14 118.3 . . ?
C16 C15 C14 114.4(17) . . ?
C16 C15 H15 122.8 . . ?
C14 C15 H15 122.8 . . ?
C17 C16 C15 123.1(19) . . ?
C17 C16 H16 118.4 . . ?
C15 C16 H16 118.4 . . ?
C16 C17 C18 120.4(17) . . ?
C16 C17 H17 119.8 . . ?
C18 C17 H17 119.8 . . ?
N12 C18 C17 120.3(16) . . ?
N12 C18 C19 117.9(13) . . ?
C17 C18 C19 121.8(15) . . ?
C20 C19 N11 120.9(16) . . ?
C20 C19 C18 123.6(15) . . ?
N11 C19 C18 115.4(12) . . ?
C19 C20 C21 120.6(17) . . ?
C19 C20 H20 119.7 . . ?
C21 C20 H20 119.7 . . ?
C22 C21 C20 115.9(16) . . ?
C22 C21 H21 122.0 . . ?
C20 C21 H21 122.0 . . ?
C21 C22 C23 119.9(17) . . ?
C21 C22 H22 120.1 . . ?
C23 C22 H22 120.1 . . ?
N11 C23 C22 125.1(16) . . ?
N11 C23 C24 115.8(12) . . ?
C22 C23 C24 119.1(16) . . ?
N10 C24 C25 121.7(15) . . ?
N10 C24 C23 114.0(13) . . ?
C25 C24 C23 124.2(14) . . ?
C26 C25 C24 119.8(15) . . ?
C26 C25 H25 120.1 . . ?
C24 C25 H25 120.1 . . ?
C25 C26 C27 120.0(16) . . ?
C25 C26 H26 120.0 . . ?
C27 C26 H26 120.0 . . ?
C28 C27 C26 116.5(16) . . ?
C28 C27 H27 121.8 . . ?
C26 C27 H27 121.8 . . ?
N10 C28 C27 123.3(17) . . ?
N10 C28 H28 118.3 . . ?
C27 C28 H28 118.3 . . ?
C30 C29 N13 125.6(19) . . ?
C30 C29 H29 117.2 . . ?
N13 C29 H29 117.2 . . ?
C29 C30 C31 115(2) . . ?
C29 C30 H30 122.3 . . ?
C31 C30 H30 122.3 . . ?
C30 C31 C32 125(2) . . ?
C30 C31 H31 117.3 . . ?
C32 C31 H31 117.3 . . ?
C31 C32 C33 114.7(17) . . ?
C31 C32 H32 122.7 . . ?
C33 C32 H32 122.7 . . ?
N13 C33 C32 122.5(15) . . ?
N13 C33 C34 113.1(14) . . ?
C32 C33 C34 124.4(16) . . ?
N14 C34 C35 117.8(15) . . ?
N14 C34 C33 121.2(14) . . ?
C35 C34 C33 121.0(16) . . ?
C36 C35 C34 120.9(16) . . ?
C36 C35 H35 119.5 . . ?
C34 C35 H35 119.5 . . ?
C35 C36 C37 116.2(17) . . ?
C35 C36 H36 121.9 . . ?
C37 C36 H36 121.9 . . ?
C38 C37 C36 121.0(16) . . ?
C38 C37 H37 119.5 . . ?
C36 C37 H37 119.5 . . ?
N14 C38 C37 116.8(16) . . ?
N14 C38 C39 119.4(13) . . ?
C37 C38 C39 123.7(15) . . ?
N15 C39 C40 120.4(14) . . ?
N15 C39 C38 116.4(13) . . ?
C40 C39 C38 123.2(14) . . ?
C41 C40 C39 123.4(17) . . ?
C41 C40 H40 118.3 . . ?
C39 C40 H40 118.3 . . ?
C40 C41 C42 115.6(17) . . ?
C40 C41 H41 122.2 . . ?
C42 C41 H41 122.2 . . ?
C43 C42 C41 120.2(19) . . ?
C43 C42 H42 119.9 . . ?
C41 C42 H42 119.9 . . ?
N15 C43 C42 121.7(17) . . ?
N15 C43 H43 119.2 . . ?
C42 C43 H43 119.2 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.160(13) . ?
Ag1 N11 2.341(10) . ?
Ag1 N12 2.374(12) . ?
Ag1 N10 2.454(12) . ?
Ag1 Au2 3.1796(16) . ?
Ag2 N2 2.204(12) 2_575 ?
Ag2 N4 2.252(13) . ?
Ag2 N6 2.256(14) 2_565 ?
Ag2 N9 2.411(15) . ?
Ag3 N8 2.118(12) . ?
Ag3 N5 2.190(14) 2_676 ?
Ag3 N3 2.191(14) . ?
Ag4 N7 2.097(15) 1_465 ?
Ag4 N15 2.376(12) . ?
Ag4 N14 2.441(12) . ?
Ag4 N13 2.443(14) . ?
Au1 C2 1.979(14) . ?
Au1 C1 2.009(14) . ?
Au2 C3 1.933(15) . ?
Au2 C4 1.978(16) . ?
Au2 Au3 3.2122(9) . ?
Au3 C5 1.987(18) . ?
Au3 C6 1.991(16) . ?
Au4 C7 1.965(14) . ?
Au4 C8 2.009(17) . ?
N1 C1 1.115(15) . ?
N2 C2 1.099(15) . ?
N3 C3 1.161(17) . ?
N4 C4 1.123(16) . ?
N5 C5 1.115(19) . ?
N6 C6 1.099(18) . ?
N7 C7 1.229(17) . ?
N8 C8 1.130(17) . ?
N9 C9 1.32(2) . ?
N9 C13 1.349(18) . ?
N10 C28 1.33(2) . ?
N10 C24 1.347(16) . ?
N11 C23 1.300(18) . ?
N11 C19 1.392(17) . ?
N12 C18 1.312(17) . ?
N12 C14 1.35(2) . ?
N13 C29 1.34(2) . ?
N13 C33 1.357(19) . ?
N14 C34 1.293(18) . ?
N14 C38 1.364(18) . ?
N15 C43 1.334(19) . ?
N15 C39 1.371(17) . ?
C9 C10 1.34(3) . ?
C9 H9 0.9300 . ?
C10 C11 1.39(3) . ?
C10 H10 0.9300 . ?
C11 C12 1.37(3) . ?
C11 H11 0.9300 . ?
C12 C13 1.35(3) . ?
C12 H12 0.9300 . ?
C13 H13 0.9300 . ?
C14 C15 1.40(2) . ?
C14 H14 0.9300 . ?
C15 C16 1.37(2) . ?
C15 H15 0.9300 . ?
C16 C17 1.27(3) . ?
C16 H16 0.9300 . ?
C17 C18 1.41(2) . ?
C17 H17 0.9300 . ?
C18 C19 1.47(2) . ?
C19 C20 1.37(2) . ?
C20 C21 1.45(2) . ?
C20 H20 0.9300 . ?
C21 C22 1.37(2) . ?
C21 H21 0.9300 . ?
C22 C23 1.391(19) . ?
C22 H22 0.9300 . ?
C23 C24 1.52(2) . ?
C24 C25 1.39(2) . ?
C25 C26 1.35(2) . ?
C25 H25 0.9300 . ?
C26 C27 1.41(2) . ?
C26 H26 0.9300 . ?
C27 C28 1.41(2) . ?
C27 H27 0.9300 . ?
C28 H28 0.9300 . ?
C29 C30 1.33(3) . ?
C29 H29 0.9300 . ?
C30 C31 1.35(3) . ?
C30 H30 0.9300 . ?
C31 C32 1.35(3) . ?
C31 H31 0.9300 . ?
C32 C33 1.40(2) . ?
C32 H32 0.9300 . ?
C33 C34 1.48(2) . ?
C34 C35 1.45(2) . ?
C35 C36 1.38(2) . ?
C35 H35 0.9300 . ?
C36 C37 1.43(2) . ?
C36 H36 0.9300 . ?
C37 C38 1.402(19) . ?
C37 H37 0.9300 . ?
C38 C39 1.44(2) . ?
C39 C40 1.38(2) . ?
C40 C41 1.32(2) . ?
C40 H40 0.9300 . ?
C41 C42 1.45(3) . ?
C41 H41 0.9300 . ?
C42 C43 1.37(2) . ?
C42 H42 0.9300 . ?
C43 H43 0.9300 . ?
