#------------------------------------------------------------------------------
#$Date: 2023-06-29 13:38:08 +0300 (Thu, 29 Jun 2023) $
#$Revision: 284602 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/32/7713233.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7713233
loop_
_publ_author_name
'Chen, Leyi'
'Sun, Fang'
'Shen, Quanli'
'Wang, Lei'
'Liu, Yonggang'
'Fan, Hao'
'Tang, Qing'
'Tang, Zhenghua'
_publ_section_title
;
 Structure, optical properties, and catalytic applications of
 alkynyl-protected M₄Rh₂ (M = Ag/Au) nanoclusters
 with atomic precision: a comparative study.
;
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_paper_doi               10.1039/d3dt01326j
_journal_year                    2023
_chemical_formula_sum            'C137 H78 Au4 F48 P2 Rh2'
_chemical_formula_weight         3691.62
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2022-10-08 deposited with the CCDC.	2023-06-09 downloaded from the CCDC.
;
_cell_angle_alpha                90.3557(8)
_cell_angle_beta                 103.8441(8)
_cell_angle_gamma                115.4022(10)
_cell_formula_units_Z            2
_cell_length_a                   17.16177(18)
_cell_length_b                   17.24053(19)
_cell_length_c                   24.4066(2)
_cell_measurement_reflns_used    63046
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      31.0730
_cell_measurement_theta_min      2.3180
_cell_volume                     6284.74(13)
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.838
_diffrn_measurement_device_type  'XtaLAB Synergy R, DW system, HyPix'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0541
_diffrn_reflns_av_unetI/netI     0.0469
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.838
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            183311
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.838
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         31.025
_diffrn_reflns_theta_min         2.241
_exptl_absorpt_coefficient_mu    5.057
_exptl_crystal_colour            'clear dark orange'
_exptl_crystal_density_diffrn    1.951
_exptl_crystal_description       needle
_exptl_crystal_F_000             3536
_exptl_crystal_size_max          0.100
_exptl_crystal_size_mid          0.030
_exptl_crystal_size_min          0.030
_refine_diff_density_max         1.872
_refine_diff_density_min         -2.887
_refine_diff_density_rms         0.167
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     2053
_refine_ls_number_reflns         33635
_refine_ls_number_restraints     2284
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0604
_refine_ls_R_factor_gt           0.0378
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0457P)²+17.2444P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0868
_refine_ls_wR_factor_ref         0.0951
_reflns_Friedel_coverage         0.000
_reflns_number_gt                26010
_reflns_number_total             33635
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3dt01326j2.cif
_cod_data_source_block           exp_2046_1_auto
_cod_original_cell_volume        6284.73(12)
_cod_database_code               7713233
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.632
_shelx_estimated_absorpt_t_max   0.863
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au6 Au 0.85952(2) 0.94092(2) -0.04772(2) 0.01661(4) Uani 1 1 d . . . . .
Au3 Au 0.51330(2) 0.50224(2) 0.41435(2) 0.01854(4) Uani 1 1 d . . . . .
Au2 Au 0.98047(2) 1.08786(2) 0.04643(2) 0.02175(4) Uani 1 1 d . . . . .
Au5 Au 0.60193(2) 0.62883(2) 0.52367(2) 0.02242(4) Uani 1 1 d . . . . .
Rh1 Rh 0.96544(2) 0.90355(2) 0.06552(2) 0.01252(6) Uani 1 1 d . . . . .
Rh4 Rh 0.60354(2) 0.44597(2) 0.52417(2) 0.01416(7) Uani 1 1 d . . . . .
P1 P 0.93280(7) 0.80738(7) 0.12843(4) 0.0148(2) Uani 1 1 d . . . . .
P2 P 0.71284(7) 0.40351(7) 0.54881(4) 0.0153(2) Uani 1 1 d . . . . .
F1 F 1.2183(2) 0.77248(19) -0.12045(14) 0.0354(7) Uani 1 1 d . U . . .
C1 C 0.8379(3) 0.8576(3) 0.01840(18) 0.0178(8) Uani 1 1 d . . . . .
F4 F 1.1009(2) 0.7654(2) 0.61957(14) 0.0372(7) Uani 1 1 d . . . . .
F6 F 1.0557(2) 0.7999(2) 0.53834(14) 0.0407(8) Uani 1 1 d . . . . .
C4 C 0.6921(3) 0.5700(3) 0.54636(18) 0.0178(8) Uani 1 1 d . . . . .
F8 F 1.2453(2) 0.6780(2) -0.07292(18) 0.0504(9) Uani 1 1 d . U . . .
F10 F 0.8794(2) 0.8738(3) 0.74773(14) 0.0503(10) Uani 1 1 d . . . . .
C6 C 1.0977(3) 0.9657(3) 0.10605(17) 0.0157(8) Uani 1 1 d . . . . .
C8 C 0.4997(3) 0.6739(3) 0.49756(18) 0.0194(9) Uani 1 1 d . . . . .
C10 C 0.6107(3) 0.4529(3) 0.44285(18) 0.0200(9) Uani 1 1 d . . . . .
C12 C 0.9878(3) 0.8239(3) 0.01663(18) 0.0167(8) Uani 1 1 d . . . . .
F12 F 0.5340(2) 0.6042(2) 0.06729(15) 0.0506(10) Uani 1 1 d . . . . .
F14 F 0.8442(3) 0.9426(2) 0.68187(16) 0.0539(10) Uani 1 1 d . . . . .
F16 F 0.9833(3) 0.9800(2) 0.72469(18) 0.0604(12) Uani 1 1 d . . . . .
C14 C 0.4152(3) 0.5520(3) 0.39760(18) 0.0178(9) Uani 1 1 d . . . . .
C16 C 0.9486(3) 0.9945(3) 0.10712(18) 0.0170(8) Uani 1 1 d . . . . .
F18 F 0.4766(3) 0.7846(3) -0.17989(15) 0.0708(14) Uani 1 1 d . . . . .
F20 F 0.8995(3) 0.9354(3) 0.54051(18) 0.0599(10) Uani 1 1 d . U . . .
C18 C 0.7604(3) 0.8348(3) -0.01116(18) 0.0189(9) Uani 1 1 d . . . . .
F22 F 1.1350(2) 0.8987(2) 0.61027(18) 0.0517(10) Uani 1 1 d . . . . .
F24 F 0.4158(2) 0.6231(2) 0.03772(14) 0.0456(9) Uani 1 1 d . . . . .
F26 F 0.4384(2) 0.5364(2) -0.01209(16) 0.0488(9) Uani 1 1 d . . . . .
F28 F 1.1626(3) 0.6406(2) -0.15881(17) 0.0561(11) Uani 1 1 d . U . . .
F30 F 0.7393(15) 1.1290(10) 0.2769(7) 0.050(3) Uani 0.380(13) 1 d D . P A 1
C20 C 0.4234(3) 0.5434(3) 0.34943(18) 0.0219(9) Uani 1 1 d . . . . .
C22 C 0.7451(3) 0.6471(3) 0.56543(19) 0.0214(9) Uani 1 1 d . . . . .
C24 C 0.5684(3) 0.7434(3) 0.51197(19) 0.0223(9) Uani 1 1 d . . . . .
F32 F 0.5153(3) 0.7124(3) 0.15485(17) 0.0606(11) Uani 1 1 d . . . . .
C26 C 1.0142(3) 0.7123(3) -0.04301(18) 0.0175(8) Uani 1 1 d . . . . .
C28 C 1.1774(3) 1.0077(3) 0.13105(18) 0.0187(9) Uani 1 1 d . . . . .
F34 F 1.1201(3) 1.3339(2) 0.2717(2) 0.0740(14) Uani 1 1 d . . . . .
C30 C 0.8708(3) 0.6935(3) 0.09991(19) 0.0183(9) Uani 1 1 d . . . . .
C32 C 0.8263(3) 0.7231(3) 0.59262(19) 0.0220(9) Uani 1 1 d . . . . .
F36 F 0.9309(3) 0.4132(2) -0.0777(3) 0.0804(15) Uani 1 1 d . U . . .
C34 C 0.8212(3) 0.6653(3) 0.04303(19) 0.0194(9) Uani 1 1 d . . . . .
H34 H 0.821216 0.706046 0.017026 0.023 Uiso 1 1 calc R U . . .
F38 F 1.3335(3) 1.2435(3) 0.2978(2) 0.0595(12) Uani 0.822(6) 1 d D U P B 1
C36 C 1.2631(3) 1.0413(3) 0.17400(18) 0.0207(9) Uani 1 1 d . . . . .
C38 C 1.0020(3) 0.7794(3) -0.01560(19) 0.0202(9) Uani 1 1 d . . . . .
C40 C 0.8330(3) 0.5228(3) 0.49672(19) 0.0224(9) Uani 1 1 d . . . . .
H40 H 0.781057 0.516594 0.468560 0.027 Uiso 1 1 calc R U . . .
F40 F 1.0495(3) 1.3834(2) 0.21211(16) 0.0680(13) Uani 1 1 d . . . . .
F42 F 0.3806(2) 0.7650(4) -0.1341(2) 0.0890(19) Uani 1 1 d . . . . .
C42 C 0.6108(3) 0.4597(3) 0.39273(18) 0.0205(9) Uani 1 1 d . . . . .
C44 C 0.6347(3) 0.2711(3) 0.4558(2) 0.0253(10) Uani 1 1 d . . . . .
H44 H 0.589290 0.289741 0.443770 0.030 Uiso 1 1 calc R U . . .
F44 F 0.7990(5) 0.3339(5) 0.3337(3) 0.0607(17) Uani 0.714(7) 1 d D U P C 1
C46 C 0.7233(3) 0.3750(3) 0.62038(19) 0.0217(9) Uani 1 1 d . . . . .
C48 C 0.7717(3) 0.5768(3) 0.0248(2) 0.0262(10) Uani 1 1 d . . . . .
H48 H 0.737157 0.557752 -0.013612 0.031 Uiso 1 1 calc R U . . .
F46 F 0.5752(12) 1.0593(12) 0.5426(8) 0.050(2) Uani 0.323(12) 1 d D U P D 1
C50 C 0.9424(3) 1.0542(3) 0.13015(18) 0.0196(9) Uani 1 1 d . . . . .
F48 F 0.8547(4) 0.4514(2) -0.0402(2) 0.0812(16) Uani 1 1 d . U . . .
C52 C 0.9056(3) 0.7364(3) 0.5808(2) 0.0236(10) Uani 1 1 d . . . . .
H52 H 0.905929 0.696717 0.553751 0.028 Uiso 1 1 calc R U . . .
C54 C 0.8270(3) 0.7828(3) 0.6323(2) 0.0233(10) Uani 1 1 d . . . . .
H54 H 0.772879 0.775413 0.640243 0.028 Uiso 1 1 calc R U . . .
F50 F 1.5372(3) 1.0309(4) 0.2581(3) 0.0623(14) Uani 0.779(6) 1 d D U P E 1
F52 F 1.0233(4) 1.3626(3) 0.2927(2) 0.0817(16) Uani 1 1 d . . . . .
F54 F 0.8361(3) 0.4472(3) -0.1286(2) 0.0955(19) Uani 1 1 d . U . . .
C56 C 0.8246(3) 0.4814(3) 0.54576(18) 0.0178(8) Uani 1 1 d . . . . .
C58 C 0.5941(4) 0.8897(3) 0.5442(2) 0.0304(11) Uani 1 1 d . . . . .
H58 H 0.532492 0.867727 0.542865 0.037 Uiso 1 1 calc R U . . .
C60 C 1.0884(3) 0.7328(3) -0.06469(19) 0.0216(9) Uani 1 1 d . . . . .
H60 H 1.130580 0.791428 -0.062552 0.026 Uiso 1 1 calc R U . . .
C62 C 0.7018(3) 0.3099(3) 0.50604(19) 0.0203(9) Uani 1 1 d . . . . .
C64 C 0.6640(3) 0.7916(3) -0.02740(18) 0.0208(9) Uani 1 1 d . . . . .
C66 C 0.9251(3) 1.1065(3) 0.16745(18) 0.0208(9) Uani 1 1 d . . . . .
C68 C 0.6284(3) 0.8345(3) 0.5284(2) 0.0259(10) Uani 1 1 d . . . . .
C70 C 0.9875(3) 1.1918(3) 0.18895(19) 0.0232(10) Uani 1 1 d . . . . .
H70 H 1.041603 1.217446 0.177737 0.028 Uiso 1 1 calc R U . . .
C72 C 1.0398(3) 0.5814(3) -0.0934(2) 0.0241(10) Uani 1 1 d . . . . .
H72 H 1.048891 0.537149 -0.110076 0.029 Uiso 1 1 calc R U . . .
C74 C 1.3168(3) 0.9987(3) 0.1800(2) 0.0252(10) Uani 1 1 d . . . . .
H74 H 1.299248 0.948844 0.154381 0.030 Uiso 1 1 calc R U . . .
C76 C 1.0348(3) 0.8144(3) 0.17632(18) 0.0184(9) Uani 1 1 d . . . . .
C78 C 0.8642(3) 0.8162(3) 0.17266(19) 0.0210(9) Uani 1 1 d . . . . .
C80 C 0.6327(3) 0.4497(3) 0.34044(19) 0.0218(9) Uani 1 1 d . . . . .
C82 C 0.4114(3) 0.5414(3) 0.28829(19) 0.0233(10) Uani 1 1 d . . . . .
C84 C 0.6131(3) 0.8162(3) -0.0707(2) 0.0257(10) Uani 1 1 d . . . . .
H84 H 0.641734 0.860907 -0.091835 0.031 Uiso 1 1 calc R U . . .
F56 F 0.4952(3) 0.8880(4) -0.1240(2) 0.0778(14) Uani 1 1 d . . . . .
C86 C 1.0762(3) 0.7670(3) 0.1613(2) 0.0240(10) Uani 1 1 d . . . . .
H86 H 1.047658 0.726222 0.127982 0.029 Uiso 1 1 calc R U . . .
F58 F 1.4508(5) 1.2287(5) 0.3436(2) 0.0795(16) Uani 0.822(6) 1 d D U P B 1
C88 C 0.9520(3) 0.6253(3) -0.0476(2) 0.0233(9) Uani 1 1 d . . . . .
H88 H 0.900961 0.610346 -0.033507 0.028 Uiso 1 1 calc R U . . .
F60 F 0.9246(3) 1.0438(3) 0.5951(2) 0.0962(18) Uani 1 1 d . U . . .
C90 C 0.8461(3) 1.0704(3) 0.1848(2) 0.0264(10) Uani 1 1 d . . . . .
H90 H 0.803405 1.012308 0.170994 0.032 Uiso 1 1 calc R U . . .
C92 C 0.8916(4) 1.2041(3) 0.2435(2) 0.0310(11) Uani 1 1 d . . . . .
H92 H 0.879976 1.237206 0.268891 0.037 Uiso 1 1 calc R U . . .
C94 C 0.9928(4) 0.5839(3) 0.5310(2) 0.0331(12) Uani 1 1 d . . . . .
H94 H 1.050345 0.618923 0.525998 0.040 Uiso 1 1 calc R U . . .
C96 C 1.0787(3) 0.8761(3) 0.2245(2) 0.0236(10) Uani 1 1 d . . . . .
H96 H 1.052021 0.910529 0.234275 0.028 Uiso 1 1 calc R U . . .
C98 C 0.6756(4) 0.2902(3) 0.6294(2) 0.0275(10) Uani 1 1 d . . . . .
H98 H 0.644506 0.245722 0.598089 0.033 Uiso 1 1 calc R U . . .
C100 C 0.7675(3) 0.4403(3) 0.6668(2) 0.0265(10) Uani 1 1 d . . . . .
H100 H 0.797777 0.499034 0.660921 0.032 Uiso 1 1 calc R U . . .
C102 C 0.7185(4) 0.8683(3) 0.5291(2) 0.0313(11) Uani 1 1 d . . . . .
H102 H 0.741604 0.831431 0.517876 0.038 Uiso 1 1 calc R U . . .
F62 F 1.4570(5) 0.9527(5) 0.1810(2) 0.0668(15) Uani 0.779(6) 1 d D U P E 1
F64 F 0.5591(8) 0.5469(9) 0.1924(5) 0.066(2) Uani 0.434(7) 1 d D U P F 1
C104 C 0.7936(3) 0.8365(3) 0.1480(2) 0.0230(9) Uani 1 1 d . . . . .
H104 H 0.787017 0.852637 0.110648 0.028 Uiso 1 1 calc R U . . .
C106 C 1.1588(4) 0.7787(4) 0.1946(2) 0.0325(12) Uani 1 1 d . . . . .
H106 H 1.186881 0.746185 0.184135 0.039 Uiso 1 1 calc R U . . .
F66 F 0.8874(3) 1.0428(3) 0.5048(2) 0.0851(16) Uani 1 1 d . U . . .
F68 F 0.5837(13) 1.0039(8) 0.6222(6) 0.055(2) Uani 0.323(12) 1 d D U P D 1
C108 C 0.9172(4) 0.5726(3) 0.4894(2) 0.0299(11) Uani 1 1 d . . . . .
H108 H 0.922939 0.599124 0.455658 0.036 Uiso 1 1 calc R U . . .
F69 F 0.4850(5) 0.7696(3) 0.21880(19) 0.094(2) Uani 1 1 d . . . . .
C110 C 1.2907(3) 1.1156(3) 0.21126(19) 0.0246(10) Uani 1 1 d . . . . .
H110 H 1.255550 1.146411 0.207172 0.030 Uiso 1 1 calc R U . . .
C112 C 0.8689(3) 0.6319(3) 0.1371(2) 0.0258(10) Uani 1 1 d . . . . .
H112 H 0.901120 0.650113 0.176059 0.031 Uiso 1 1 calc R U . . .
C114 C 0.6765(3) 0.3982(3) 0.3388(2) 0.0259(10) Uani 1 1 d . . . . .
H114 H 0.693252 0.373911 0.371813 0.031 Uiso 1 1 calc R U . . .
F35 F 0.3850(3) 0.7033(3) 0.1408(2) 0.0784(15) Uani 1 1 d . . . . .
C116 C 1.1003(3) 0.6677(3) -0.08907(19) 0.0220(9) Uani 1 1 d . U . . .
C118 C 0.7667(4) 0.4186(4) 0.7216(2) 0.0355(13) Uani 1 1 d . . . . .
H118 H 0.798772 0.462460 0.753201 0.043 Uiso 1 1 calc R U . . .
C120 C 0.8199(3) 0.5438(3) 0.1174(2) 0.0272(10) Uani 1 1 d . . . . .
H120 H 0.819633 0.502239 0.142813 0.033 Uiso 1 1 calc R U . . .
C122 C 0.6348(4) 0.2041(3) 0.4229(2) 0.0349(12) Uani 1 1 d . . . . .
H122 H 0.588800 0.177238 0.388665 0.042 Uiso 1 1 calc R U . . .
C124 C 0.3648(4) 0.4633(3) 0.25303(19) 0.0279(11) Uani 1 1 d . . . . .
H124 H 0.345856 0.410300 0.268956 0.033 Uiso 1 1 calc R U . . .
C126 C 0.7676(3) 0.2815(3) 0.5229(2) 0.0255(10) Uani 1 1 d . . . . .
H126 H 0.813237 0.307537 0.557366 0.031 Uiso 1 1 calc R U . . .
C128 C 0.9654(3) 0.5613(3) -0.0726(2) 0.0239(9) Uani 1 1 d . U . . .
C130 C 0.6204(3) 0.7250(3) 0.0029(2) 0.0247(10) Uani 1 1 d . . . . .
H130 H 0.654463 0.707431 0.032342 0.030 Uiso 1 1 calc R U . . .
C132 C 0.4420(3) 0.6183(4) 0.2647(2) 0.0276(10) Uani 1 1 d . . . . .
H132 H 0.476375 0.671932 0.288574 0.033 Uiso 1 1 calc R U . . .
C134 C 0.9066(4) 0.8522(3) 0.6597(2) 0.0291(11) Uani 1 1 d . . . . .
C136 C 0.9843(3) 0.8071(3) 0.6081(2) 0.0252(10) Uani 1 1 d . . . . .
C138 C 1.4217(3) 1.1013(4) 0.2605(2) 0.0325(12) Uani 1 1 d . . . . .
H138 H 1.475351 1.121455 0.290485 0.039 Uiso 1 1 calc R U . . .
C140 C 0.9702(4) 1.2393(3) 0.2269(2) 0.0259(10) Uani 1 1 d . . . . .
C142 C 0.8724(4) 0.7930(3) 0.2273(2) 0.0295(11) Uani 1 1 d . . . . .
H142 H 0.919202 0.778089 0.244448 0.035 Uiso 1 1 calc R U . . .
C144 C 1.1811(4) 0.6902(3) -0.1100(2) 0.0322(10) Uani 1 1 d . U . . .
C9 C 0.9019(3) 0.4924(3) 0.5868(2) 0.0264(10) Uani 1 1 d . . . . .
H9 H 0.897169 0.463917 0.619899 0.032 Uiso 1 1 calc R U . . .
C73 C 0.9860(3) 0.8657(3) 0.6482(2) 0.0288(11) Uani 1 1 d . . . . .
H73 H 1.040565 0.913852 0.667356 0.035 Uiso 1 1 calc R U . . .
C37 C 0.6121(3) 0.4882(3) 0.2928(2) 0.0265(10) Uani 1 1 d . . . . .
H37 H 0.583850 0.524806 0.293920 0.032 Uiso 1 1 calc R U . . .
C75 C 1.3958(3) 1.0285(4) 0.2231(2) 0.0342(9) Uani 1 1 d D U . . .
C19 C 0.7670(4) 0.2152(3) 0.4896(2) 0.0316(11) Uani 1 1 d . . . . .
H19 H 0.812394 0.196546 0.501131 0.038 Uiso 1 1 calc R U . . .
C77 C 1.2006(4) 0.8380(4) 0.2434(2) 0.0339(12) Uani 1 1 d . . . . .
H77 H 1.256646 0.845109 0.266855 0.041 Uiso 1 1 calc R U . . .
C39 C 0.5197(3) 0.7747(4) -0.0830(2) 0.0305(12) Uani 1 1 d . . . . .
C79 C 0.4799(4) 0.6124(4) 0.0211(2) 0.0382(13) Uani 1 1 d . . . . .
C5 C 1.1606(3) 0.8868(3) 0.2577(2) 0.0299(11) Uani 1 1 d . . . . .
H5 H 1.189875 0.928152 0.290726 0.036 Uiso 1 1 calc R U . . .
C81 C 0.7720(3) 0.5170(3) 0.0611(2) 0.0277(10) Uani 1 1 d . . . . .
H81 H 0.739132 0.457034 0.047699 0.033 Uiso 1 1 calc R U . . .
C41 C 0.6332(4) 0.4728(4) 0.2434(2) 0.0366(10) Uani 1 1 d D U . . .
C83 C 0.6956(4) 0.3824(4) 0.2891(2) 0.0361(10) Uani 1 1 d D U . . .
C21 C 0.8957(4) 0.4689(3) -0.0802(2) 0.0351(11) Uani 1 1 d . U . . .
C85 C 0.4768(3) 0.7107(4) -0.0529(2) 0.0335(12) Uani 1 1 d . . . . .
H85 H 0.413367 0.684175 -0.060893 0.040 Uiso 1 1 calc R U . . .
C43 C 0.5279(3) 0.6849(3) -0.0099(2) 0.0265(10) Uani 1 1 d . . . . .
F9 F 1.4483(4) 1.2971(3) 0.2709(2) 0.0646(13) Uani 0.822(6) 1 d D U P B 1
C87 C 0.7433(4) 0.8113(4) 0.2326(2) 0.0375(13) Uani 1 1 d . . . . .
H87 H 0.702411 0.809916 0.253260 0.045 Uiso 1 1 calc R U . . .
C11 C 0.4219(4) 0.6163(4) 0.2055(2) 0.0316(12) Uani 1 1 d . . . . .
C89 C 1.0396(4) 1.3292(3) 0.2503(2) 0.0317(12) Uani 1 1 d . . . . .
C45 C 0.6740(4) 0.4190(4) 0.2408(2) 0.0310(11) Uani 1 1 d . . . . .
H45 H 0.686813 0.407639 0.206692 0.037 Uiso 1 1 calc R U . . .
C91 C 0.7336(4) 0.8331(3) 0.1781(2) 0.0312(11) Uani 1 1 d . . . . .
H91 H 0.685393 0.846003 0.160945 0.037 Uiso 1 1 calc R U . . .
C23 C 0.8300(4) 1.1192(4) 0.2221(2) 0.0338(10) Uani 1 1 d D . . . .
C93 C 0.9853(3) 0.5448(3) 0.5795(2) 0.0324(12) Uani 1 1 d . . . . .
H93 H 1.037744 0.553739 0.608209 0.039 Uiso 1 1 calc R U . . .
F37 F 0.6983(10) 1.1151(8) 0.6087(6) 0.048(2) Uani 0.323(12) 1 d D U P D 1
C47 C 0.7410(4) 1.0105(3) 0.5623(2) 0.0426(15) Uani 1 1 d . . . . .
H47 H 0.779412 1.070389 0.573626 0.051 Uiso 1 1 calc R U . . .
C95 C 0.3458(4) 0.4628(4) 0.1940(2) 0.0404(11) Uani 1 1 d D U . . .
C3 C 1.0692(3) 0.8182(3) 0.5944(2) 0.0329(12) Uani 1 1 d . . . . .
C97 C 1.3998(5) 1.2270(5) 0.2919(3) 0.0481(11) Uani 0.822(6) 1 d D U P B 1
C49 C 0.7742(4) 0.9557(3) 0.5461(2) 0.0393(13) Uani 1 1 d . U . . .
F19 F 0.7557(6) 0.3122(5) 0.2408(3) 0.0677(15) Uani 0.714(7) 1 d D U P C 1
C99 C 0.6998(4) 0.1766(3) 0.4394(2) 0.0357(13) Uani 1 1 d . . . . .
H99 H 0.698947 0.131274 0.416579 0.043 Uiso 1 1 calc R U . . .
C25 C 0.8120(4) 0.7915(4) 0.2571(2) 0.0400(14) Uani 1 1 d . . . . .
H25 H 0.818566 0.776519 0.294725 0.048 Uiso 1 1 calc R U . . .
C101 C 1.3694(3) 1.1441(4) 0.2540(2) 0.0325(10) Uani 1 1 d D U . . .
C51 C 0.7198(4) 0.3344(4) 0.7302(2) 0.0405(14) Uani 1 1 d . . . . .
H51 H 0.719363 0.319982 0.767626 0.049 Uiso 1 1 calc R U . . .
C103 C 0.6732(4) 0.2703(4) 0.6841(2) 0.0369(13) Uani 1 1 d . . . . .
H103 H 0.639320 0.212335 0.690006 0.044 Uiso 1 1 calc R U . . .
C13 C 0.9043(4) 0.9122(4) 0.7034(3) 0.0395(14) Uani 1 1 d . . . . .
C105 C 0.6519(4) 0.9771(3) 0.5619(2) 0.0398(10) Uani 1 1 d D U . . .
F39 F 0.6706(4) 0.2368(4) 0.2878(2) 0.0543(13) Uani 0.714(7) 1 d D U P C 1
C53 C 1.4543(5) 0.9833(5) 0.2307(4) 0.0431(10) Uani 0.779(6) 1 d D U P E 1
C107 C 0.3742(4) 0.5389(4) 0.1707(2) 0.0377(13) Uani 1 1 d . . . . .
H107 H 0.361098 0.538101 0.130545 0.045 Uiso 1 1 calc R U . . .
C27 C 1.0654(4) 0.6810(4) 0.3191(3) 0.0435(14) Uani 1 1 d . . . . .
H27 H 1.121562 0.691087 0.313135 0.052 Uiso 1 1 calc R U . . .
C109 C 1.0619(5) 0.7395(5) 0.3563(3) 0.0538(17) Uani 1 1 d . . . . .
H109 H 1.115457 0.789159 0.374747 0.065 Uiso 1 1 calc R U . . .
C55 C 0.4517(5) 0.7005(5) 0.1802(2) 0.0458(15) Uani 1 1 d . . . . .
C111 C 0.7492(10) 1.0735(9) 0.2438(7) 0.046(2) Uani 0.380(13) 1 d D . P A 1
C7 C 0.9907(5) 0.6093(4) 0.2907(3) 0.0478(16) Uani 1 1 d . . . . .
C113 C 0.6258(12) 1.0399(10) 0.5837(7) 0.0444(15) Uani 0.323(12) 1 d D U P D 1
C57 C 0.4680(4) 0.8039(5) -0.1293(3) 0.0500(18) Uani 1 1 d . . . . .
F5 F 1.4255(4) 0.9183(5) 0.2611(4) 0.0781(16) Uani 0.779(6) 1 d D U P E 1
C115 C 0.9838(5) 0.7275(5) 0.3670(3) 0.0545(18) Uani 1 1 d . . . . .
H115 H 0.981643 0.767210 0.393132 0.065 Uiso 1 1 calc R U . . .
C29 C 0.7303(6) 0.3165(6) 0.2876(4) 0.0427(11) Uani 0.714(7) 1 d D U P C 1
F41 F 0.3171(8) 0.3821(5) 0.1083(3) 0.082(2) Uani 0.594(7) 1 d D U P G 1
C117 C 0.2916(9) 0.3789(7) 0.1554(5) 0.0610(16) Uani 0.594(7) 1 d D U P G 1
C59 C 0.8703(5) 0.9936(4) 0.5462(3) 0.0548(15) Uani 1 1 d . U . . .
C119 C 0.9073(5) 0.6550(5) 0.3383(3) 0.0569(18) Uani 1 1 d . . . . .
H119 H 0.851720 0.645311 0.344933 0.068 Uiso 1 1 calc R U . . .
C15 C 0.9970(6) 0.5489(6) 0.2503(4) 0.074(3) Uani 1 1 d . . . . .
H15A H 1.022480 0.580386 0.220672 0.111 Uiso 1 1 calc R U . . .
H15B H 0.937065 0.502430 0.232674 0.111 Uiso 1 1 calc R U . . .
H15C H 1.035490 0.523881 0.270706 0.111 Uiso 1 1 calc R U . . .
C121 C 0.6164(11) 0.5180(10) 0.1931(5) 0.0497(15) Uani 0.434(7) 1 d D U P F 1
C61 C 0.9088(5) 0.5973(5) 0.3011(4) 0.061(2) Uani 1 1 d . . . . .
H61 H 0.854764 0.548639 0.282000 0.073 Uiso 1 1 calc R U . . .
F21 F 0.5952(9) 0.4680(7) 0.1449(3) 0.067(2) Uani 0.434(7) 1 d D U P F 1
F43 F 0.2908(8) 0.3129(5) 0.1799(3) 0.0742(19) Uani 0.594(7) 1 d D U P G 1
F11 F 0.6923(7) 0.5846(7) 0.1876(4) 0.0590(18) Uani 0.434(7) 1 d D U P F 1
F45 F 0.2054(6) 0.3630(6) 0.1391(4) 0.088(2) Uani 0.594(7) 1 d D U P G 1
F23 F 0.7485(10) 1.0073(7) 0.2714(7) 0.059(3) Uani 0.380(13) 1 d D . P A 1
F47 F 0.6780(7) 1.0417(11) 0.1992(5) 0.069(3) Uani 0.380(13) 1 d D . P A 1
C123 C 0.6591(6) 0.7402(5) 0.3952(3) 0.0621(14) Uani 1 1 d . U . . .
H123 H 0.598536 0.699058 0.389804 0.075 Uiso 1 1 calc R U . . .
C31 C 0.7198(18) 1.026(2) 0.0157(16) 0.038(5) Uani 0.179(19) 1 d D U P H 1
H31 H 0.754540 0.996156 0.029797 0.045 Uiso 0.179(19) 1 calc R U P H 1
C125 C 0.6777(6) 0.8230(5) 0.3838(3) 0.0666(14) Uani 1 1 d . U . . .
C63 C 0.7245(6) 0.7152(6) 0.4138(3) 0.0680(15) Uani 1 1 d . U . . .
H63 H 0.708749 0.657169 0.421420 0.082 Uiso 1 1 calc R U . . .
C127 C 0.7685(6) 0.8808(5) 0.3909(3) 0.0732(16) Uani 1 1 d . U . . .
H127 H 0.784917 0.938734 0.382882 0.088 Uiso 1 1 calc R U . . .
C2 C 0.604(2) 1.067(2) 0.0229(16) 0.041(5) Uani 0.179(19) 1 d D U P H 1
H2 H 0.555819 1.059982 0.038627 0.049 Uiso 0.179(19) 1 calc R U P H 1
C129 C 0.647(2) 1.015(2) 0.0348(19) 0.040(5) Uani 0.179(19) 1 d D U P H 1
C65 C 0.8121(6) 0.7710(6) 0.4220(3) 0.0737(15) Uani 1 1 d . U . . .
H65 H 0.857983 0.753550 0.435929 0.088 Uiso 1 1 calc R U . . .
C131 C 0.8317(7) 0.8535(6) 0.4092(4) 0.0800(17) Uani 1 1 d . U . . .
H131 H 0.892583 0.893104 0.413493 0.096 Uiso 1 1 calc R U . . .
C33 C 0.741(2) 1.082(2) -0.0246(18) 0.037(5) Uani 0.179(19) 1 d D U P H 1
H33 H 0.783679 1.083272 -0.043742 0.044 Uiso 0.179(19) 1 calc R U P H 1
C133 C 0.7005(19) 1.135(2) -0.0367(15) 0.037(5) Uani 0.179(19) 1 d D U P H 1
H133 H 0.719166 1.176993 -0.061846 0.045 Uiso 0.179(19) 1 calc R U P H 1
C67 C 0.610(3) 0.942(3) 0.0656(18) 0.048(6) Uani 0.179(19) 1 d D U P H 1
H67A H 0.556763 0.895211 0.040070 0.073 Uiso 0.179(19) 1 calc R U P H 1
H67B H 0.593818 0.959876 0.097554 0.073 Uiso 0.179(19) 1 calc R U P H 1
H67C H 0.654996 0.920644 0.080099 0.073 Uiso 0.179(19) 1 calc R U P H 1
C135 C 0.632(2) 1.129(2) -0.0128(17) 0.040(5) Uani 0.179(19) 1 d D U P H 1
H135 H 0.605643 1.167438 -0.020944 0.048 Uiso 0.179(19) 1 calc R U P H 1
C17 C 0.6024(8) 0.8494(7) 0.3658(5) 0.098(3) Uani 1 1 d . U . . .
H17A H 0.576040 0.834280 0.324579 0.147 Uiso 1 1 calc R U . . .
H17B H 0.626159 0.911931 0.375591 0.147 Uiso 1 1 calc R U . . .
H17C H 0.556372 0.818870 0.385469 0.147 Uiso 1 1 calc R U . . .
F3 F 1.4848(14) 0.9707(14) 0.2827(7) 0.061(2) Uani 0.221(6) 1 d D U P E 2
F49 F 1.4980(13) 0.9847(14) 0.1975(9) 0.057(2) Uani 0.221(6) 1 d D U P E 2
C137 C 1.4431(14) 0.9714(13) 0.2305(9) 0.0484(16) Uani 0.221(6) 1 d D U P E 2
F25 F 1.3937(10) 0.8850(10) 0.2191(8) 0.049(2) Uani 0.221(6) 1 d D U P E 2
F51 F 1.3465(13) 1.1949(13) 0.3337(8) 0.050(2) Uani 0.178(6) 1 d D U P B 2
F13 F 1.4827(12) 1.2459(17) 0.3293(9) 0.052(3) Uani 0.178(6) 1 d D U P B 2
F53 F 1.3863(16) 1.2802(12) 0.2761(8) 0.053(2) Uani 0.178(6) 1 d D U P B 2
C69 C 1.3974(15) 1.2161(13) 0.2991(8) 0.047(2) Uani 0.178(6) 1 d D U P B 2
F27 F 0.2489(10) 0.3802(8) 0.1073(4) 0.081(3) Uani 0.406(7) 1 d D U P G 2
C139 C 0.2930(12) 0.3753(9) 0.1580(7) 0.0633(19) Uani 0.406(7) 1 d D U P G 2
F55 F 0.3401(9) 0.3321(8) 0.1600(6) 0.077(2) Uani 0.406(7) 1 d D U P G 2
F7 F 0.2271(9) 0.3179(7) 0.1785(5) 0.077(2) Uani 0.406(7) 1 d D U P G 2
C35 C 0.6025(8) 0.5072(9) 0.1899(4) 0.0476(14) Uani 0.566(7) 1 d D U P F 2
F57 F 0.6570(7) 0.5250(8) 0.1572(4) 0.0746(19) Uani 0.566(7) 1 d D U P F 2
F29 F 0.5968(6) 0.5815(6) 0.2033(4) 0.0562(17) Uani 0.566(7) 1 d D U P F 2
F59 F 0.5246(6) 0.4552(6) 0.1581(3) 0.0700(19) Uani 0.566(7) 1 d D U P F 2
F15 F 0.7420(8) 1.1124(7) 0.2854(4) 0.0470(17) Uani 0.620(13) 1 d D . P A 2
C141 C 0.7397(6) 1.0832(7) 0.2338(4) 0.0414(14) Uani 0.620(13) 1 d D . P A 2
F61 F 0.7047(6) 0.9968(4) 0.2333(5) 0.065(2) Uani 0.620(13) 1 d D . P A 2
F31 F 0.6778(4) 1.0975(7) 0.1967(3) 0.060(2) Uani 0.620(13) 1 d D . P A 2
F63 F 0.5919(6) 1.0778(6) 0.5368(4) 0.0520(15) Uani 0.677(12) 1 d D U P D 2
F2 F 0.5351(6) 0.9919(4) 0.5939(4) 0.0574(16) Uani 0.677(12) 1 d D U P D 2
F65 F 0.6681(7) 1.0938(5) 0.6229(3) 0.068(2) Uani 0.677(12) 1 d D U P D 2
C71 C 0.6103(7) 1.0332(6) 0.5775(4) 0.0449(12) Uani 0.677(12) 1 d D U P D 2
F33 F 0.8372(8) 0.3846(8) 0.2820(6) 0.051(2) Uani 0.286(7) 1 d D U P C 2
F67 F 0.7181(11) 0.2718(10) 0.2502(7) 0.061(2) Uani 0.286(7) 1 d D U P C 2
F17 F 0.7759(12) 0.3074(13) 0.3397(7) 0.052(2) Uani 0.286(7) 1 d D U P C 2
C143 C 0.7569(11) 0.3390(12) 0.2914(7) 0.0436(16) Uani 0.286(7) 1 d D U P C 2
C67A C 0.6441(10) 0.9781(10) 0.0515(5) 0.086(4) Uani 0.821(19) 1 d D U P H 2
H67D H 0.586984 0.928688 0.032726 0.129 Uiso 0.821(19) 1 calc R U P H 2
H67E H 0.639275 1.001699 0.086539 0.129 Uiso 0.821(19) 1 calc R U P H 2
H67F H 0.691476 0.959152 0.060839 0.129 Uiso 0.821(19) 1 calc R U P H 2
C31A C 0.7356(5) 1.0605(7) -0.0109(4) 0.063(3) Uani 0.821(19) 1 d DG U P H 2
H31A H 0.767962 1.027041 -0.003498 0.076 Uiso 0.821(19) 1 calc R U P H 2
C33A C 0.7581(5) 1.1252(7) -0.0461(4) 0.071(3) Uani 0.821(19) 1 d DG U P H 2
H33A H 0.805891 1.135899 -0.062779 0.085 Uiso 0.821(19) 1 calc R U P H 2
C1A C 0.7108(5) 1.1742(7) -0.0569(3) 0.075(3) Uani 0.821(19) 1 d DG U P H 2
H1A H 0.726175 1.218358 -0.080968 0.090 Uiso 0.821(19) 1 calc R U P H 2
C1B C 0.6409(6) 1.1585(7) -0.0325(4) 0.080(3) Uani 0.821(19) 1 d DG U P H 2
H1B H 0.608530 1.191960 -0.039878 0.096 Uiso 0.821(19) 1 calc R U P H 2
C2A C 0.6184(5) 1.0938(7) 0.0027(4) 0.070(3) Uani 0.821(19) 1 d DG U P H 2
H2A H 0.570600 1.083104 0.019402 0.084 Uiso 0.821(19) 1 calc R U P H 2
C145 C 0.6657(5) 1.0448(6) 0.0135(4) 0.068(3) Uani 0.821(19) 1 d DG U P H 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au6 C6 171.17(16) . 2_775 ?
C1 Au6 C18 32.43(16) . . ?
C6 Au6 C18 156.27(16) 2_775 . ?
C1 Au6 C28 156.87(16) . 2_775 ?
C6 Au6 C28 31.96(16) 2_775 2_775 ?
C18 Au6 C28 124.60(16) . 2_775 ?
C1 Au6 Au2 87.28(12) . 2_775 ?
C6 Au6 Au2 86.83(11) 2_775 2_775 ?
C18 Au6 Au2 111.84(12) . 2_775 ?
C28 Au6 Au2 107.81(11) 2_775 2_775 ?
C1 Au6 Au2 86.66(11) . . ?
C6 Au6 Au2 86.48(11) 2_775 . ?
C18 Au6 Au2 108.19(11) . . ?
C28 Au6 Au2 110.94(11) 2_775 . ?
Au2 Au6 Au2 87.119(7) 2_775 . ?
C1 Au6 Rh1 38.97(11) . . ?
C6 Au6 Rh1 132.24(11) 2_775 . ?
C18 Au6 Rh1 71.38(11) . . ?
C28 Au6 Rh1 163.91(11) 2_775 . ?
Au2 Au6 Rh1 59.956(7) 2_775 . ?
Au2 Au6 Rh1 60.635(7) . . ?
C1 Au6 Rh1 132.21(11) . 2_775 ?
C6 Au6 Rh1 38.98(11) 2_775 2_775 ?
C18 Au6 Rh1 164.24(11) . 2_775 ?
C28 Au6 Rh1 70.90(11) 2_775 2_775 ?
Au2 Au6 Rh1 60.729(7) 2_775 2_775 ?
Au2 Au6 Rh1 59.318(7) . 2_775 ?
Rh1 Au6 Rh1 93.271(9) . 2_775 ?
C14 Au3 C10 172.28(17) . . ?
C14 Au3 C42 155.43(16) . . ?
C10 Au3 C42 32.26(16) . . ?
C14 Au3 C20 32.16(17) . . ?
C10 Au3 C20 155.55(17) . . ?
C42 Au3 C20 123.40(16) . . ?
C14 Au3 Au5 87.60(11) . 2_666 ?
C10 Au3 Au5 87.25(12) . 2_666 ?
C42 Au3 Au5 110.00(12) . 2_666 ?
C20 Au3 Au5 107.64(12) . 2_666 ?
C14 Au3 Au5 86.06(11) . . ?
C10 Au3 Au5 88.12(11) . . ?
C42 Au3 Au5 110.46(11) . . ?
C20 Au3 Au5 110.85(11) . . ?
Au5 Au3 Au5 89.050(7) 2_666 . ?
C14 Au3 Rh4 132.68(12) . . ?
C10 Au3 Rh4 39.61(12) . . ?
C42 Au3 Rh4 71.87(11) . . ?
C20 Au3 Rh4 164.45(12) . . ?
Au5 Au3 Rh4 60.552(8) 2_666 . ?
Au5 Au3 Rh4 61.422(7) . . ?
C14 Au3 Rh4 38.92(12) . 2_666 ?
C10 Au3 Rh4 133.37(12) . 2_666 ?
C42 Au3 Rh4 165.59(11) . 2_666 ?
C20 Au3 Rh4 71.00(12) . 2_666 ?
Au5 Au3 Rh4 61.769(8) 2_666 2_666 ?
Au5 Au3 Rh4 59.597(7) . 2_666 ?
Rh4 Au3 Rh4 93.763(9) . 2_666 ?
C12 Au2 C16 177.28(16) 2_775 . ?
C12 Au2 C50 151.05(16) 2_775 . ?
C16 Au2 C50 31.65(16) . . ?
C12 Au2 C38 31.47(16) 2_775 2_775 ?
C16 Au2 C38 151.22(16) . 2_775 ?
C50 Au2 C38 119.59(16) . 2_775 ?
C12 Au2 Au6 89.82(12) 2_775 2_775 ?
C16 Au2 Au6 88.63(11) . 2_775 ?
C50 Au2 Au6 108.98(12) . 2_775 ?
C38 Au2 Au6 110.83(11) 2_775 2_775 ?
C12 Au2 Au6 89.72(11) 2_775 . ?
C16 Au2 Au6 88.12(11) . . ?
C50 Au2 Au6 110.40(11) . . ?
C38 Au2 Au6 110.92(11) 2_775 . ?
Au6 Au2 Au6 92.883(7) 2_775 . ?
C12 Au2 Rh1 41.10(12) 2_775 2_775 ?
C16 Au2 Rh1 136.22(11) . 2_775 ?
C50 Au2 Rh1 167.80(11) . 2_775 ?
C38 Au2 Rh1 72.56(11) 2_775 2_775 ?
Au6 Au2 Rh1 62.821(8) 2_775 2_775 ?
Au6 Au2 Rh1 62.928(8) . 2_775 ?
C12 Au2 Rh1 137.23(12) 2_775 . ?
C16 Au2 Rh1 40.07(11) . . ?
C50 Au2 Rh1 71.71(11) . . ?
C38 Au2 Rh1 168.70(11) 2_775 . ?
Au6 Au2 Rh1 62.755(7) 2_775 . ?
Au6 Au2 Rh1 61.835(7) . . ?
Rh1 Au2 Rh1 96.145(9) 2_775 . ?
C4 Au5 C8 173.80(16) . . ?
C4 Au5 C24 154.03(17) . . ?
C8 Au5 C24 32.13(17) . . ?
C4 Au5 C22 32.29(16) . . ?
C8 Au5 C22 153.89(16) . . ?
C24 Au5 C22 122.04(17) . . ?
C4 Au5 Au3 86.22(12) . 2_666 ?
C8 Au5 Au3 89.78(12) . 2_666 ?
C24 Au5 Au3 112.27(12) . 2_666 ?
C22 Au5 Au3 104.92(12) . 2_666 ?
C4 Au5 Au3 86.97(11) . . ?
C8 Au5 Au3 88.37(11) . . ?
C24 Au5 Au3 109.82(11) . . ?
C22 Au5 Au3 112.37(11) . . ?
Au3 Au5 Au3 90.947(7) 2_666 . ?
C4 Au5 Rh4 133.20(12) . 2_666 ?
C8 Au5 Rh4 40.63(12) . 2_666 ?
C24 Au5 Rh4 72.75(12) . 2_666 ?
C22 Au5 Rh4 164.46(12) . 2_666 ?
Au3 Au5 Rh4 62.102(8) 2_666 2_666 ?
Au3 Au5 Rh4 61.998(8) . 2_666 ?
C4 Au5 Rh4 38.51(12) . . ?
C8 Au5 Rh4 135.30(12) . . ?
C24 Au5 Rh4 167.24(12) . . ?
C22 Au5 Rh4 70.67(11) . . ?
Au3 Au5 Rh4 61.851(8) 2_666 . ?
Au3 Au5 Rh4 60.605(7) . . ?
Rh4 Au5 Rh4 94.709(10) 2_666 . ?
C1 Rh1 C16 89.06(17) . . ?
C1 Rh1 C12 91.03(17) . . ?
C16 Rh1 C12 172.42(17) . . ?
C1 Rh1 C6 171.10(17) . . ?
C16 Rh1 C6 88.13(17) . . ?
C12 Rh1 C6 90.65(17) . . ?
C1 Rh1 P1 94.17(12) . . ?
C16 Rh1 P1 95.94(12) . . ?
C12 Rh1 P1 91.61(12) . . ?
C6 Rh1 P1 94.52(12) . . ?
C1 Rh1 Au2 87.58(12) . 2_775 ?
C16 Rh1 Au2 127.77(12) . 2_775 ?
C12 Rh1 Au2 44.68(12) . 2_775 ?
C6 Rh1 Au2 87.48(12) . 2_775 ?
P1 Rh1 Au2 136.29(3) . 2_775 ?
C1 Rh1 Au2 86.58(12) . . ?
C16 Rh1 Au2 43.91(12) . . ?
C12 Rh1 Au2 128.53(12) . . ?
C6 Rh1 Au2 85.53(12) . . ?
P1 Rh1 Au2 139.85(3) . . ?
Au2 Rh1 Au2 83.856(9) 2_775 . ?
C1 Rh1 Au6 42.52(12) . . ?
C16 Rh1 Au6 87.24(12) . . ?
C12 Rh1 Au6 87.71(12) . . ?
C6 Rh1 Au6 128.85(12) . . ?
P1 Rh1 Au6 136.62(3) . . ?
Au2 Rh1 Au6 57.225(7) 2_775 . ?
Au2 Rh1 Au6 57.530(7) . . ?
C1 Rh1 Au6 129.22(12) . 2_775 ?
C16 Rh1 Au6 86.13(12) . 2_775 ?
C12 Rh1 Au6 87.95(12) . 2_775 ?
C6 Rh1 Au6 42.13(12) . 2_775 ?
P1 Rh1 Au6 136.62(3) . 2_775 ?
Au2 Rh1 Au6 57.756(7) 2_775 2_775 ?
Au2 Rh1 Au6 56.515(7) . 2_775 ?
Au6 Rh1 Au6 86.729(9) . 2_775 ?
C4 Rh4 C14 86.96(17) . 2_666 ?
C4 Rh4 C10 91.29(17) . . ?
C14 Rh4 C10 171.53(18) 2_666 . ?
C4 Rh4 C8 171.70(18) . 2_666 ?
C14 Rh4 C8 89.72(17) 2_666 2_666 ?
C10 Rh4 C8 90.89(17) . 2_666 ?
C4 Rh4 P2 91.27(13) . . ?
C14 Rh4 P2 95.21(13) 2_666 . ?
C10 Rh4 P2 93.11(14) . . ?
C8 Rh4 P2 96.61(13) 2_666 . ?
C4 Rh4 Au5 127.69(13) . 2_666 ?
C14 Rh4 Au5 87.50(12) 2_666 2_666 ?
C10 Rh4 Au5 87.02(13) . 2_666 ?
C8 Rh4 Au5 44.46(13) 2_666 2_666 ?
P2 Rh4 Au5 141.04(3) . 2_666 ?
C4 Rh4 Au3 87.57(12) . . ?
C14 Rh4 Au3 128.55(12) 2_666 . ?
C10 Rh4 Au3 43.04(13) . . ?
C8 Rh4 Au3 88.56(13) 2_666 . ?
P2 Rh4 Au3 136.04(3) . . ?
Au5 Rh4 Au3 57.344(7) 2_666 . ?
C4 Rh4 Au5 42.42(13) . . ?
C14 Rh4 Au5 85.45(12) 2_666 . ?
C10 Rh4 Au5 87.67(12) . . ?
C8 Rh4 Au5 129.71(13) 2_666 . ?
P2 Rh4 Au5 133.67(3) . . ?
Au5 Rh4 Au5 85.289(10) 2_666 . ?
Au3 Rh4 Au5 57.972(7) . . ?
C4 Rh4 Au3 84.35(13) . 2_666 ?
C14 Rh4 Au3 42.31(12) 2_666 2_666 ?
C10 Rh4 Au3 129.27(13) . 2_666 ?
C8 Rh4 Au3 88.07(13) 2_666 2_666 ?
P2 Rh4 Au3 137.38(3) . 2_666 ?
Au5 Rh4 Au3 58.401(8) 2_666 2_666 ?
Au3 Rh4 Au3 86.235(9) . 2_666 ?
Au5 Rh4 Au3 56.378(7) . 2_666 ?
C76 P1 C30 103.7(2) . . ?
C76 P1 C78 106.9(2) . . ?
C30 P1 C78 100.9(2) . . ?
C76 P1 Rh1 110.25(14) . . ?
C30 P1 Rh1 117.06(15) . . ?
C78 P1 Rh1 116.75(15) . . ?
C46 P2 C56 106.9(2) . . ?
C46 P2 C62 104.8(2) . . ?
C56 P2 C62 99.2(2) . . ?
C46 P2 Rh4 110.12(15) . . ?
C56 P2 Rh4 116.58(15) . . ?
C62 P2 Rh4 118.03(16) . . ?
C18 C1 Rh1 175.9(4) . . ?
C18 C1 Au6 78.3(3) . . ?
Rh1 C1 Au6 98.51(18) . . ?
C22 C4 Rh4 173.5(4) . . ?
C22 C4 Au5 80.1(3) . . ?
Rh4 C4 Au5 99.06(19) . . ?
C28 C6 Rh1 176.3(4) . . ?
C28 C6 Au6 79.5(3) . 2_775 ?
Rh1 C6 Au6 98.89(17) . 2_775 ?
C24 C8 Rh4 173.7(4) . 2_666 ?
C24 C8 Au5 78.8(3) . . ?
Rh4 C8 Au5 94.91(18) 2_666 . ?
C42 C10 Rh4 175.4(4) . . ?
C42 C10 Au3 78.1(3) . . ?
Rh4 C10 Au3 97.3(2) . . ?
C38 C12 Rh1 175.8(4) . . ?
C38 C12 Au2 81.6(3) . 2_775 ?
Rh1 C12 Au2 94.23(17) . 2_775 ?
C20 C14 Rh4 174.6(4) . 2_666 ?
C20 C14 Au3 79.2(3) . . ?
Rh4 C14 Au3 98.76(18) 2_666 . ?
C50 C16 Rh1 175.1(4) . . ?
C50 C16 Au2 79.4(3) . . ?
Rh1 C16 Au2 96.02(17) . . ?
C1 C18 C64 158.5(4) . . ?
C1 C18 Au6 69.2(3) . . ?
C64 C18 Au6 131.8(3) . . ?
C14 C20 C82 162.4(5) . . ?
C14 C20 Au3 68.6(3) . . ?
C82 C20 Au3 128.8(3) . . ?
C4 C22 C32 160.9(5) . . ?
C4 C22 Au5 67.6(3) . . ?
C32 C22 Au5 131.5(3) . . ?
C8 C24 C68 162.3(5) . . ?
C8 C24 Au5 69.0(3) . . ?
C68 C24 Au5 127.9(3) . . ?
C60 C26 C88 119.0(4) . . ?
C60 C26 C38 120.9(4) . . ?
C88 C26 C38 120.1(4) . . ?
C6 C28 C36 162.6(5) . . ?
C6 C28 Au6 68.6(3) . 2_775 ?
C36 C28 Au6 128.6(3) . 2_775 ?
C112 C30 C34 118.9(4) . . ?
C112 C30 P1 118.4(3) . . ?
C34 C30 P1 122.7(3) . . ?
C52 C32 C54 119.1(4) . . ?
C52 C32 C22 119.6(4) . . ?
C54 C32 C22 121.2(4) . . ?
C48 C34 C30 119.5(4) . . ?
C48 C34 H34 120.3 . . ?
C30 C34 H34 120.3 . . ?
C74 C36 C110 119.1(4) . . ?
C74 C36 C28 121.0(4) . . ?
C110 C36 C28 119.9(4) . . ?
C12 C38 C26 165.7(5) . . ?
C12 C38 Au2 66.9(3) . 2_775 ?
C26 C38 Au2 127.3(3) . 2_775 ?
C108 C40 C56 119.8(5) . . ?
C108 C40 H40 120.1 . . ?
C56 C40 H40 120.1 . . ?
C10 C42 C80 157.0(5) . . ?
C10 C42 Au3 69.6(3) . . ?
C80 C42 Au3 133.0(3) . . ?
C62 C44 C122 119.2(5) . . ?
C62 C44 H44 120.4 . . ?
C122 C44 H44 120.4 . . ?
C98 C46 C100 119.5(4) . . ?
C98 C46 P2 119.8(4) . . ?
C100 C46 P2 119.9(4) . . ?
C81 C48 C34 121.3(4) . . ?
C81 C48 H48 119.4 . . ?
C34 C48 H48 119.4 . . ?
C16 C50 C66 163.9(5) . . ?
C16 C50 Au2 68.9(3) . . ?
C66 C50 Au2 127.0(3) . . ?
C136 C52 C32 120.2(4) . . ?
C136 C52 H52 119.9 . . ?
C32 C52 H52 119.9 . . ?
C134 C54 C32 119.7(5) . . ?
C134 C54 H54 120.2 . . ?
C32 C54 H54 120.2 . . ?
C9 C56 C40 119.0(4) . . ?
C9 C56 P2 122.2(4) . . ?
C40 C56 P2 118.3(3) . . ?
C105 C58 C68 119.1(5) . . ?
C105 C58 H58 120.4 . . ?
C68 C58 H58 120.4 . . ?
C116 C60 C26 120.0(4) . . ?
C116 C60 H60 120.0 . . ?
C26 C60 H60 120.0 . . ?
C44 C62 C126 119.5(4) . . ?
C44 C62 P2 122.5(4) . . ?
C126 C62 P2 117.9(4) . . ?
C84 C64 C130 119.3(4) . . ?
C84 C64 C18 122.0(4) . . ?
C130 C64 C18 118.6(4) . . ?
C70 C66 C90 118.8(4) . . ?
C70 C66 C50 121.4(4) . . ?
C90 C66 C50 119.7(4) . . ?
C102 C68 C58 119.8(5) . . ?
C102 C68 C24 121.7(5) . . ?
C58 C68 C24 118.5(5) . . ?
C140 C70 C66 119.8(5) . . ?
C140 C70 H70 120.1 . . ?
C66 C70 H70 120.1 . . ?
C116 C72 C128 118.4(4) . . ?
C116 C72 H72 120.8 . . ?
C128 C72 H72 120.8 . . ?
C36 C74 C75 120.5(5) . . ?
C36 C74 H74 119.8 . . ?
C75 C74 H74 119.8 . . ?
C86 C76 C96 119.4(4) . . ?
C86 C76 P1 120.0(3) . . ?
C96 C76 P1 120.0(4) . . ?
C142 C78 C104 118.9(4) . . ?
C142 C78 P1 122.0(4) . . ?
C104 C78 P1 118.6(3) . . ?
C37 C80 C114 119.6(4) . . ?
C37 C80 C42 123.5(4) . . ?
C114 C80 C42 116.9(4) . . ?
C124 C82 C132 119.6(4) . . ?
C124 C82 C20 120.5(4) . . ?
C132 C82 C20 119.7(4) . . ?
C64 C84 C39 119.7(5) . . ?
C64 C84 H84 120.1 . . ?
C39 C84 H84 120.1 . . ?
C106 C86 C76 120.3(5) . . ?
C106 C86 H86 119.8 . . ?
C76 C86 H86 119.8 . . ?
C128 C88 C26 119.7(4) . . ?
C128 C88 H88 120.1 . . ?
C26 C88 H88 120.1 . . ?
C23 C90 C66 120.2(5) . . ?
C23 C90 H90 119.9 . . ?
C66 C90 H90 119.9 . . ?
C140 C92 C23 118.5(5) . . ?
C140 C92 H92 120.8 . . ?
C23 C92 H92 120.8 . . ?
C93 C94 C108 120.4(5) . . ?
C93 C94 H94 119.8 . . ?
C108 C94 H94 119.8 . . ?
C5 C96 C76 119.8(5) . . ?
C5 C96 H96 120.1 . . ?
C76 C96 H96 120.1 . . ?
C46 C98 C103 119.9(5) . . ?
C46 C98 H98 120.0 . . ?
C103 C98 H98 120.0 . . ?
C118 C100 C46 119.7(5) . . ?
C118 C100 H100 120.2 . . ?
C46 C100 H100 120.2 . . ?
C49 C102 C68 120.0(5) . . ?
C49 C102 H102 120.0 . . ?
C68 C102 H102 120.0 . . ?
C91 C104 C78 120.1(5) . . ?
C91 C104 H104 120.0 . . ?
C78 C104 H104 120.0 . . ?
C86 C106 C77 120.0(5) . . ?
C86 C106 H106 120.0 . . ?
C77 C106 H106 120.0 . . ?
C94 C108 C40 120.2(5) . . ?
C94 C108 H108 119.9 . . ?
C40 C108 H108 119.9 . . ?
C101 C110 C36 119.6(5) . . ?
C101 C110 H110 120.2 . . ?
C36 C110 H110 120.2 . . ?
C120 C112 C30 120.3(4) . . ?
C120 C112 H112 119.9 . . ?
C30 C112 H112 119.9 . . ?
C83 C114 C80 119.9(5) . . ?
C83 C114 H114 120.0 . . ?
C80 C114 H114 120.0 . . ?
C60 C116 C72 121.6(4) . . ?
C60 C116 C144 119.3(4) . . ?
C72 C116 C144 119.1(4) . . ?
C51 C118 C100 120.4(5) . . ?
C51 C118 H118 119.8 . . ?
C100 C118 H118 119.8 . . ?
C81 C120 C112 120.1(5) . . ?
C81 C120 H120 119.9 . . ?
C112 C120 H120 119.9 . . ?
C99 C122 C44 121.2(5) . . ?
C99 C122 H122 119.4 . . ?
C44 C122 H122 119.4 . . ?
C82 C124 C95 119.9(5) . . ?
C82 C124 H124 120.1 . . ?
C95 C124 H124 120.1 . . ?
C62 C126 C19 120.6(5) . . ?
C62 C126 H126 119.7 . . ?
C19 C126 H126 119.7 . . ?
C88 C128 C72 121.3(4) . . ?
C88 C128 C21 119.2(5) . . ?
C72 C128 C21 119.5(4) . . ?
C43 C130 C64 120.0(4) . . ?
C43 C130 H130 120.0 . . ?
C64 C130 H130 120.0 . . ?
C82 C132 C11 119.5(5) . . ?
C82 C132 H132 120.3 . . ?
C11 C132 H132 120.3 . . ?
C54 C134 C73 121.5(5) . . ?
C54 C134 C13 117.5(5) . . ?
C73 C134 C13 120.9(5) . . ?
C52 C136 C73 121.1(5) . . ?
C52 C136 C3 118.3(4) . . ?
C73 C136 C3 120.6(4) . . ?
C101 C138 C75 119.5(5) . . ?
C101 C138 H138 120.2 . . ?
C75 C138 H138 120.2 . . ?
C92 C140 C70 121.3(5) . . ?
C92 C140 C89 120.4(4) . . ?
C70 C140 C89 118.2(5) . . ?
C78 C142 C25 119.9(5) . . ?
C78 C142 H142 120.0 . . ?
C25 C142 H142 120.0 . . ?
F1 C144 F8 106.8(4) . . ?
F1 C144 F28 106.5(4) . . ?
F8 C144 F28 105.5(4) . . ?
F1 C144 C116 113.2(4) . . ?
F8 C144 C116 112.2(4) . . ?
F28 C144 C116 112.1(5) . . ?
C93 C9 C56 120.2(5) . . ?
C93 C9 H9 119.9 . . ?
C56 C9 H9 119.9 . . ?
C134 C73 C136 118.3(4) . . ?
C134 C73 H73 120.8 . . ?
C136 C73 H73 120.8 . . ?
C80 C37 C41 119.6(5) . . ?
C80 C37 H37 120.2 . . ?
C41 C37 H37 120.2 . . ?
C138 C75 C74 119.9(5) . . ?
C138 C75 C53 118.6(5) . . ?
C74 C75 C53 121.4(6) . . ?
C138 C75 C137 123.5(10) . . ?
C74 C75 C137 116.2(10) . . ?
C99 C19 C126 119.8(5) . . ?
C99 C19 H19 120.1 . . ?
C126 C19 H19 120.1 . . ?
C5 C77 C106 119.8(5) . . ?
C5 C77 H77 120.1 . . ?
C106 C77 H77 120.1 . . ?
C85 C39 C84 121.2(5) . . ?
C85 C39 C57 120.9(5) . . ?
C84 C39 C57 117.8(5) . . ?
F12 C79 F26 107.3(5) . . ?
F12 C79 F24 107.1(5) . . ?
F26 C79 F24 105.8(4) . . ?
F12 C79 C43 113.0(4) . . ?
F26 C79 C43 111.6(5) . . ?
F24 C79 C43 111.7(5) . . ?
C96 C5 C77 120.6(5) . . ?
C96 C5 H5 119.7 . . ?
C77 C5 H5 119.7 . . ?
C48 C81 C120 119.9(4) . . ?
C48 C81 H81 120.0 . . ?
C120 C81 H81 120.0 . . ?
C45 C41 C37 121.2(5) . . ?
C45 C41 C121 118.8(8) . . ?
C37 C41 C121 120.0(8) . . ?
C45 C41 C35 119.0(7) . . ?
C37 C41 C35 119.5(7) . . ?
C114 C83 C45 121.1(5) . . ?
C114 C83 C29 117.2(6) . . ?
C45 C83 C29 121.4(6) . . ?
C114 C83 C143 118.4(8) . . ?
C45 C83 C143 119.4(8) . . ?
F54 C21 F48 108.2(6) . . ?
F54 C21 F36 106.2(5) . . ?
F48 C21 F36 103.8(5) . . ?
F54 C21 C128 112.8(5) . . ?
F48 C21 C128 113.0(4) . . ?
F36 C21 C128 112.3(5) . . ?
C39 C85 C43 119.0(4) . . ?
C39 C85 H85 120.5 . . ?
C43 C85 H85 120.5 . . ?
C130 C43 C85 120.6(5) . . ?
C130 C43 C79 121.0(5) . . ?
C85 C43 C79 118.4(4) . . ?
C25 C87 C91 119.9(5) . . ?
C25 C87 H87 120.1 . . ?
C91 C87 H87 120.1 . . ?
C107 C11 C132 120.6(5) . . ?
C107 C11 C55 120.2(5) . . ?
C132 C11 C55 119.2(5) . . ?
F40 C89 F34 105.1(5) . . ?
F40 C89 F52 107.1(5) . . ?
F34 C89 F52 104.7(5) . . ?
F40 C89 C140 113.3(4) . . ?
F34 C89 C140 113.0(4) . . ?
F52 C89 C140 113.0(5) . . ?
C83 C45 C41 118.5(5) . . ?
C83 C45 H45 120.7 . . ?
C41 C45 H45 120.7 . . ?
C87 C91 C104 120.5(5) . . ?
C87 C91 H91 119.7 . . ?
C104 C91 H91 119.7 . . ?
C90 C23 C92 121.2(5) . . ?
C90 C23 C111 117.2(7) . . ?
C92 C23 C111 121.2(7) . . ?
C90 C23 C141 119.0(6) . . ?
C92 C23 C141 119.3(6) . . ?
C94 C93 C9 120.3(5) . . ?
C94 C93 H93 119.8 . . ?
C9 C93 H93 119.8 . . ?
C105 C47 C49 119.6(5) . . ?
C105 C47 H47 120.2 . . ?
C49 C47 H47 120.2 . . ?
C107 C95 C124 120.5(5) . . ?
C107 C95 C117 119.1(7) . . ?
C124 C95 C117 120.4(7) . . ?
C107 C95 C139 122.4(8) . . ?
C124 C95 C139 117.1(8) . . ?
F4 C3 F22 106.8(4) . . ?
F4 C3 F6 106.0(4) . . ?
F22 C3 F6 107.3(4) . . ?
F4 C3 C136 112.4(4) . . ?
F22 C3 C136 112.7(4) . . ?
F6 C3 C136 111.3(4) . . ?
F38 C97 F9 101.8(7) . . ?
F38 C97 F58 109.3(7) . . ?
F9 C97 F58 106.3(7) . . ?
F38 C97 C101 114.0(6) . . ?
F9 C97 C101 112.9(6) . . ?
F58 C97 C101 111.9(7) . . ?
C102 C49 C47 120.6(6) . . ?
C102 C49 C59 121.0(6) . . ?
C47 C49 C59 118.4(5) . . ?
C122 C99 C19 119.8(5) . . ?
C122 C99 H99 120.1 . . ?
C19 C99 H99 120.1 . . ?
C87 C25 C142 120.8(5) . . ?
C87 C25 H25 119.6 . . ?
C142 C25 H25 119.6 . . ?
C138 C101 C110 121.3(5) . . ?
C138 C101 C69 115.9(10) . . ?
C110 C101 C69 122.5(10) . . ?
C138 C101 C97 120.2(5) . . ?
C110 C101 C97 118.4(6) . . ?
C118 C51 C103 119.9(5) . . ?
C118 C51 H51 120.1 . . ?
C103 C51 H51 120.1 . . ?
C98 C103 C51 120.6(5) . . ?
C98 C103 H103 119.7 . . ?
C51 C103 H103 119.7 . . ?
F16 C13 F10 106.1(5) . . ?
F16 C13 F14 107.7(5) . . ?
F10 C13 F14 105.0(5) . . ?
F16 C13 C134 112.8(5) . . ?
F10 C13 C134 113.0(5) . . ?
F14 C13 C134 111.7(5) . . ?
C47 C105 C58 121.0(6) . . ?
C47 C105 C113 114.7(8) . . ?
C58 C105 C113 124.3(9) . . ?
C47 C105 C71 122.6(6) . . ?
C58 C105 C71 116.4(6) . . ?
F50 C53 F5 104.8(7) . . ?
F50 C53 F62 105.3(7) . . ?
F5 C53 F62 109.0(8) . . ?
F50 C53 C75 114.8(7) . . ?
F5 C53 C75 110.0(6) . . ?
F62 C53 C75 112.4(6) . . ?
C95 C107 C11 119.8(5) . . ?
C95 C107 H107 120.1 . . ?
C11 C107 H107 120.1 . . ?
C7 C27 C109 121.9(7) . . ?
C7 C27 H27 119.1 . . ?
C109 C27 H27 119.1 . . ?
C115 C109 C27 121.5(7) . . ?
C115 C109 H109 119.2 . . ?
C27 C109 H109 119.2 . . ?
F32 C55 F35 106.1(5) . . ?
F32 C55 F69 105.8(6) . . ?
F35 C55 F69 107.5(6) . . ?
F32 C55 C11 112.4(6) . . ?
F35 C55 C11 111.6(6) . . ?
F69 C55 C11 113.0(5) . . ?
F23 C111 F47 106.8(13) . . ?
F23 C111 F30 109.4(13) . . ?
F47 C111 F30 107.5(15) . . ?
F23 C111 C23 114.5(11) . . ?
F47 C111 C23 107.6(11) . . ?
F30 C111 C23 110.8(13) . . ?
C27 C7 C61 116.8(7) . . ?
C27 C7 C15 120.3(7) . . ?
C61 C7 C15 122.9(7) . . ?
F46 C113 F68 111.5(15) . . ?
F46 C113 F37 107.1(15) . . ?
F68 C113 F37 108.7(14) . . ?
F46 C113 C105 111.2(14) . . ?
F68 C113 C105 106.6(12) . . ?
F37 C113 C105 111.8(13) . . ?
F56 C57 F42 108.8(6) . . ?
F56 C57 F18 105.1(5) . . ?
F42 C57 F18 105.4(6) . . ?
F56 C57 C39 113.6(6) . . ?
F42 C57 C39 112.4(5) . . ?
F18 C57 C39 111.0(6) . . ?
C109 C115 C119 117.1(7) . . ?
C109 C115 H115 121.4 . . ?
C119 C115 H115 121.4 . . ?
F39 C29 F19 103.8(8) . . ?
F39 C29 F44 106.5(8) . . ?
F19 C29 F44 109.8(8) . . ?
F39 C29 C83 113.6(7) . . ?
F19 C29 C83 113.0(7) . . ?
F44 C29 C83 109.7(7) . . ?
F43 C117 F41 111.4(11) . . ?
F43 C117 F45 104.1(12) . . ?
F41 C117 F45 106.0(11) . . ?
F43 C117 C95 113.2(9) . . ?
F41 C117 C95 111.5(10) . . ?
F45 C117 C95 110.1(9) . . ?
F20 C59 F66 106.5(7) . . ?
F20 C59 F60 104.9(6) . . ?
F66 C59 F60 106.5(5) . . ?
F20 C59 C49 113.8(5) . . ?
F66 C59 C49 112.4(6) . . ?
F60 C59 C49 112.1(6) . . ?
C61 C119 C115 122.5(7) . . ?
C61 C119 H119 118.7 . . ?
C115 C119 H119 118.7 . . ?
C7 C15 H15A 109.5 . . ?
C7 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C7 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
F64 C121 F21 111.2(13) . . ?
F64 C121 F11 107.8(13) . . ?
F21 C121 F11 99.0(12) . . ?
F64 C121 C41 114.7(12) . . ?
F21 C121 C41 110.6(11) . . ?
F11 C121 C41 112.5(11) . . ?
C119 C61 C7 120.2(7) . . ?
C119 C61 H61 119.9 . . ?
C7 C61 H61 119.9 . . ?
C63 C123 C125 121.9(8) . . ?
C63 C123 H123 119.0 . . ?
C125 C123 H123 119.0 . . ?
C129 C31 C33 118(2) . . ?
C129 C31 H31 121.0 . . ?
C33 C31 H31 121.0 . . ?
C123 C125 C127 116.8(9) . . ?
C123 C125 C17 120.1(8) . . ?
C127 C125 C17 123.1(9) . . ?
C123 C63 C65 121.6(9) . . ?
C123 C63 H63 119.2 . . ?
C65 C63 H63 119.2 . . ?
C131 C127 C125 119.6(9) . . ?
C131 C127 H127 120.2 . . ?
C125 C127 H127 120.2 . . ?
C129 C2 C135 118(2) . . ?
C129 C2 H2 121.1 . . ?
C135 C2 H2 121.1 . . ?
C31 C129 C2 122.7(19) . . ?
C31 C129 C67 119(2) . . ?
C2 C129 C67 119(2) . . ?
C63 C65 C131 117.3(10) . . ?
C63 C65 H65 121.3 . . ?
C131 C65 H65 121.3 . . ?
C127 C131 C65 122.7(9) . . ?
C127 C131 H131 118.6 . . ?
C65 C131 H131 118.6 . . ?
C133 C33 C31 120(2) . . ?
C133 C33 H33 120.2 . . ?
C31 C33 H33 120.2 . . ?
C33 C133 C135 121(2) . . ?
C33 C133 H133 119.4 . . ?
C135 C133 H133 119.4 . . ?
C129 C67 H67A 109.5 . . ?
C129 C67 H67B 109.5 . . ?
H67A C67 H67B 109.5 . . ?
C129 C67 H67C 109.5 . . ?
H67A C67 H67C 109.5 . . ?
H67B C67 H67C 109.5 . . ?
C2 C135 C133 119(2) . . ?
C2 C135 H135 120.3 . . ?
C133 C135 H135 120.3 . . ?
C125 C17 H17A 109.5 . . ?
C125 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C125 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
F3 C137 F49 109.2(18) . . ?
F3 C137 F25 95.6(16) . . ?
F49 C137 F25 101.0(17) . . ?
F3 C137 C75 115.8(15) . . ?
F49 C137 C75 114.2(15) . . ?
F25 C137 C75 118.8(16) . . ?
F51 C69 F53 104.1(19) . . ?
F51 C69 F13 109.0(19) . . ?
F53 C69 F13 108(2) . . ?
F51 C69 C101 112.1(16) . . ?
F53 C69 C101 109.4(16) . . ?
F13 C69 C101 113.4(18) . . ?
F55 C139 F27 116.4(15) . . ?
F55 C139 F7 98.2(14) . . ?
F27 C139 F7 102.4(14) . . ?
F55 C139 C95 112.6(12) . . ?
F27 C139 C95 112.2(12) . . ?
F7 C139 C95 113.9(13) . . ?
F59 C35 F57 105.5(11) . . ?
F59 C35 F29 105.8(10) . . ?
F57 C35 F29 107.7(11) . . ?
F59 C35 C41 114.4(9) . . ?
F57 C35 C41 112.6(9) . . ?
F29 C35 C41 110.3(9) . . ?
F31 C141 F15 106.4(9) . . ?
F31 C141 F61 105.3(9) . . ?
F15 C141 F61 104.1(9) . . ?
F31 C141 C23 115.1(8) . . ?
F15 C141 C23 113.5(9) . . ?
F61 C141 C23 111.6(8) . . ?
F63 C71 F2 106.0(8) . . ?
F63 C71 F65 105.2(8) . . ?
F2 C71 F65 104.2(8) . . ?
F63 C71 C105 114.2(8) . . ?
F2 C71 C105 115.9(7) . . ?
F65 C71 C105 110.3(8) . . ?
F17 C143 F33 103.5(14) . . ?
F17 C143 F67 106.0(17) . . ?
F33 C143 F67 102.6(15) . . ?
F17 C143 C83 115.4(14) . . ?
F33 C143 C83 118.6(13) . . ?
F67 C143 C83 109.3(12) . . ?
C145 C67A H67D 109.5 . . ?
C145 C67A H67E 109.5 . . ?
H67D C67A H67E 109.5 . . ?
C145 C67A H67F 109.5 . . ?
H67D C67A H67F 109.5 . . ?
H67E C67A H67F 109.5 . . ?
C33A C31A C145 120.0 . . ?
C33A C31A H31A 120.0 . . ?
C145 C31A H31A 120.0 . . ?
C1A C33A C31A 120.0 . . ?
C1A C33A H33A 120.0 . . ?
C31A C33A H33A 120.0 . . ?
C1B C1A C33A 120.0 . . ?
C1B C1A H1A 120.0 . . ?
C33A C1A H1A 120.0 . . ?
C1A C1B C2A 120.0 . . ?
C1A C1B H1B 120.0 . . ?
C2A C1B H1B 120.0 . . ?
C145 C2A C1B 120.0 . . ?
C145 C2A H2A 120.0 . . ?
C1B C2A H2A 120.0 . . ?
C2A C145 C31A 120.0 . . ?
C2A C145 C67A 120.5(7) . . ?
C31A C145 C67A 119.5(7) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au6 C1 2.159(4) . ?
Au6 C6 2.161(4) 2_775 ?
Au6 C18 2.261(4) . ?
Au6 C28 2.282(4) 2_775 ?
Au6 Au2 2.9860(3) 2_775 ?
Au6 Au2 3.0233(2) . ?
Au6 Rh1 3.1592(3) . ?
Au6 Rh1 3.1830(4) 2_775 ?
Au3 C14 2.157(4) . ?
Au3 C10 2.161(5) . ?
Au3 C42 2.255(5) . ?
Au3 C20 2.275(5) . ?
Au3 Au5 2.9910(3) 2_666 ?
Au3 Au5 3.0552(2) . ?
Au3 Rh4 3.1398(4) . ?
Au3 Rh4 3.1670(4) 2_666 ?
Au2 C12 2.167(4) 2_775 ?
Au2 C16 2.178(4) . ?
Au2 C50 2.295(4) . ?
Au2 C38 2.331(4) 2_775 ?
Au2 Rh1 3.0742(4) 2_775 ?
Au2 Rh1 3.1231(4) . ?
Au5 C4 2.162(4) . ?
Au5 C8 2.175(5) . ?
Au5 C24 2.285(5) . ?
Au5 C22 2.304(5) . ?
Au5 Rh4 3.0936(4) 2_666 ?
Au5 Rh4 3.1646(4) . ?
Rh1 C1 2.009(4) . ?
Rh1 C16 2.022(4) . ?
Rh1 C12 2.026(4) . ?
Rh1 C6 2.027(4) . ?
Rh1 P1 2.2510(11) . ?
Rh4 C4 1.995(4) . ?
Rh4 C14 2.013(4) 2_666 ?
Rh4 C10 2.018(5) . ?
Rh4 C8 2.022(4) 2_666 ?
Rh4 P2 2.2494(12) . ?
P1 C76 1.813(4) . ?
P1 C30 1.819(4) . ?
P1 C78 1.827(5) . ?
P2 C46 1.806(5) . ?
P2 C56 1.829(5) . ?
P2 C62 1.831(4) . ?
F1 C144 1.338(6) . ?
C1 C18 1.238(6) . ?
F4 C3 1.331(7) . ?
F6 C3 1.343(6) . ?
C4 C22 1.249(6) . ?
F8 C144 1.343(7) . ?
F10 C13 1.334(8) . ?
C6 C28 1.229(6) . ?
C8 C24 1.239(7) . ?
C10 C42 1.230(6) . ?
C12 C38 1.230(6) . ?
F12 C79 1.330(7) . ?
F14 C13 1.350(7) . ?
F16 C13 1.331(6) . ?
C14 C20 1.233(6) . ?
C16 C50 1.225(6) . ?
F18 C57 1.335(8) . ?
F20 C59 1.320(9) . ?
C18 C64 1.441(6) . ?
F22 C3 1.338(6) . ?
F24 C79 1.341(7) . ?
F26 C79 1.339(7) . ?
F28 C144 1.350(6) . ?
F30 C111 1.339(14) . ?
C20 C82 1.455(6) . ?
C22 C32 1.443(6) . ?
C24 C68 1.448(6) . ?
F32 C55 1.321(7) . ?
C26 C60 1.403(6) . ?
C26 C88 1.404(6) . ?
C26 C38 1.446(6) . ?
C28 C36 1.457(6) . ?
F34 C89 1.320(7) . ?
C30 C112 1.396(6) . ?
C30 C34 1.400(6) . ?
C32 C52 1.382(7) . ?
C32 C54 1.403(6) . ?
F36 C21 1.331(7) . ?
C34 C48 1.395(6) . ?
C34 H34 0.9500 . ?
F38 C97 1.323(9) . ?
C36 C74 1.388(7) . ?
C36 C110 1.397(7) . ?
C40 C108 1.385(7) . ?
C40 C56 1.402(6) . ?
C40 H40 0.9500 . ?
F40 C89 1.313(6) . ?
F42 C57 1.328(7) . ?
C42 C80 1.442(6) . ?
C44 C62 1.391(7) . ?
C44 C122 1.402(7) . ?
C44 H44 0.9500 . ?
F44 C29 1.344(11) . ?
C46 C98 1.385(7) . ?
C46 C100 1.403(7) . ?
C48 C81 1.364(7) . ?
C48 H48 0.9500 . ?
F46 C113 1.306(15) . ?
C50 C66 1.442(6) . ?
F48 C21 1.299(7) . ?
C52 C136 1.378(7) . ?
C52 H52 0.9500 . ?
C54 C134 1.376(7) . ?
C54 H54 0.9500 . ?
F50 C53 1.297(9) . ?
F52 C89 1.324(6) . ?
F54 C21 1.292(7) . ?
C56 C9 1.395(6) . ?
C58 C105 1.394(7) . ?
C58 C68 1.410(7) . ?
C58 H58 0.9500 . ?
C60 C116 1.378(6) . ?
C60 H60 0.9500 . ?
C62 C126 1.391(7) . ?
C64 C84 1.394(6) . ?
C64 C130 1.401(6) . ?
C66 C70 1.399(7) . ?
C66 C90 1.400(7) . ?
C68 C102 1.394(8) . ?
C70 C140 1.397(7) . ?
C70 H70 0.9500 . ?
C72 C116 1.385(7) . ?
C72 C128 1.393(7) . ?
C72 H72 0.9500 . ?
C74 C75 1.387(7) . ?
C74 H74 0.9500 . ?
C76 C86 1.387(6) . ?
C76 C96 1.398(6) . ?
C78 C142 1.388(7) . ?
C78 C104 1.403(7) . ?
C80 C37 1.389(7) . ?
C80 C114 1.395(7) . ?
C82 C124 1.387(7) . ?
C82 C132 1.387(7) . ?
C84 C39 1.398(6) . ?
C84 H84 0.9500 . ?
F56 C57 1.313(9) . ?
C86 C106 1.382(7) . ?
C86 H86 0.9500 . ?
F58 C97 1.345(9) . ?
C88 C128 1.386(6) . ?
C88 H88 0.9500 . ?
F60 C59 1.343(8) . ?
C90 C23 1.386(7) . ?
C90 H90 0.9500 . ?
C92 C140 1.382(8) . ?
C92 C23 1.390(8) . ?
C92 H92 0.9500 . ?
C94 C93 1.371(8) . ?
C94 C108 1.378(8) . ?
C94 H94 0.9500 . ?
C96 C5 1.378(7) . ?
C96 H96 0.9500 . ?
C98 C103 1.386(7) . ?
C98 H98 0.9500 . ?
C100 C118 1.391(7) . ?
C100 H100 0.9500 . ?
C102 C49 1.387(7) . ?
C102 H102 0.9500 . ?
F62 C53 1.338(10) . ?
F64 C121 1.275(17) . ?
C104 C91 1.381(7) . ?
C104 H104 0.9500 . ?
C106 C77 1.387(8) . ?
C106 H106 0.9500 . ?
F66 C59 1.327(8) . ?
F68 C113 1.320(16) . ?
C108 H108 0.9500 . ?
F69 C55 1.334(8) . ?
C110 C101 1.380(7) . ?
C110 H110 0.9500 . ?
C112 C120 1.395(7) . ?
C112 H112 0.9500 . ?
C114 C83 1.385(7) . ?
C114 H114 0.9500 . ?
F35 C55 1.326(7) . ?
C116 C144 1.488(7) . ?
C118 C51 1.372(9) . ?
C118 H118 0.9500 . ?
C120 C81 1.379(7) . ?
C120 H120 0.9500 . ?
C122 C99 1.368(8) . ?
C122 H122 0.9500 . ?
C124 C95 1.397(7) . ?
C124 H124 0.9500 . ?
C126 C19 1.393(7) . ?
C126 H126 0.9500 . ?
C128 C21 1.503(7) . ?
C130 C43 1.383(6) . ?
C130 H130 0.9500 . ?
C132 C11 1.401(7) . ?
C132 H132 0.9500 . ?
C134 C73 1.378(8) . ?
C134 C13 1.501(7) . ?
C136 C73 1.390(7) . ?
C136 C3 1.506(7) . ?
C138 C101 1.369(8) . ?
C138 C75 1.387(8) . ?
C138 H138 0.9500 . ?
C140 C89 1.492(7) . ?
C142 C25 1.392(7) . ?
C142 H142 0.9500 . ?
C9 C93 1.384(7) . ?
C9 H9 0.9500 . ?
C73 H73 0.9500 . ?
C37 C41 1.394(7) . ?
C37 H37 0.9500 . ?
C75 C53 1.493(9) . ?
C75 C137 1.510(16) . ?
C19 C99 1.388(8) . ?
C19 H19 0.9500 . ?
C77 C5 1.381(8) . ?
C77 H77 0.9500 . ?
C39 C85 1.369(7) . ?
C39 C57 1.492(8) . ?
C79 C43 1.497(7) . ?
C5 H5 0.9500 . ?
C81 H81 0.9500 . ?
C41 C45 1.389(8) . ?
C41 C121 1.495(13) . ?
C41 C35 1.511(11) . ?
C83 C45 1.388(8) . ?
C83 C29 1.495(9) . ?
C83 C143 1.523(15) . ?
C85 C43 1.403(7) . ?
C85 H85 0.9500 . ?
F9 C97 1.329(10) . ?
C87 C25 1.369(9) . ?
C87 C91 1.378(8) . ?
C87 H87 0.9500 . ?
C11 C107 1.375(8) . ?
C11 C55 1.508(8) . ?
C45 H45 0.9500 . ?
C91 H91 0.9500 . ?
C23 C111 1.498(14) . ?
C23 C141 1.502(10) . ?
C93 H93 0.9500 . ?
F37 C113 1.358(15) . ?
C47 C105 1.382(9) . ?
C47 C49 1.392(9) . ?
C47 H47 0.9500 . ?
C95 C107 1.369(9) . ?
C95 C117 1.503(12) . ?
C95 C139 1.516(14) . ?
C97 C101 1.511(9) . ?
C49 C59 1.490(10) . ?
F19 C29 1.328(9) . ?
C99 H99 0.9500 . ?
C25 H25 0.9500 . ?
C101 C69 1.484(17) . ?
C51 C103 1.386(9) . ?
C51 H51 0.9500 . ?
C103 H103 0.9500 . ?
C105 C113 1.475(15) . ?
C105 C71 1.518(10) . ?
F39 C29 1.316(11) . ?
C53 F5 1.327(9) . ?
C107 H107 0.9500 . ?
C27 C7 1.362(9) . ?
C27 C109 1.383(10) . ?
C27 H27 0.9500 . ?
C109 C115 1.357(10) . ?
C109 H109 0.9500 . ?
C111 F23 1.326(15) . ?
C111 F47 1.327(16) . ?
C7 C61 1.416(10) . ?
C7 C15 1.486(10) . ?
C115 C119 1.385(11) . ?
C115 H115 0.9500 . ?
F41 C117 1.316(13) . ?
C117 F43 1.285(13) . ?
C117 F45 1.338(15) . ?
C119 C61 1.354(11) . ?
C119 H119 0.9500 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C121 F21 1.331(15) . ?
C121 F11 1.355(16) . ?
C61 H61 0.9500 . ?
C123 C63 1.350(12) . ?
C123 C125 1.370(11) . ?
C123 H123 0.9500 . ?
C31 C129 1.378(17) . ?
C31 C33 1.383(18) . ?
C31 H31 0.9500 . ?
C125 C127 1.410(11) . ?
C125 C17 1.517(14) . ?
C63 C65 1.356(12) . ?
C63 H63 0.9500 . ?
C127 C131 1.344(14) . ?
C127 H127 0.9500 . ?
C2 C129 1.383(17) . ?
C2 C135 1.385(18) . ?
C2 H2 0.9500 . ?
C129 C67 1.45(2) . ?
C65 C131 1.371(13) . ?
C65 H65 0.9500 . ?
C131 H131 0.9500 . ?
C33 C133 1.367(18) . ?
C33 H33 0.9500 . ?
C133 C135 1.395(18) . ?
C133 H133 0.9500 . ?
C67 H67A 0.9800 . ?
C67 H67B 0.9800 . ?
C67 H67C 0.9800 . ?
C135 H135 0.9500 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
F3 C137 1.306(18) . ?
F49 C137 1.329(18) . ?
C137 F25 1.346(18) . ?
F51 C69 1.300(18) . ?
F13 C69 1.336(18) . ?
F53 C69 1.308(19) . ?
F27 C139 1.312(16) . ?
C139 F55 1.306(16) . ?
C139 F7 1.353(17) . ?
C35 F59 1.289(14) . ?
C35 F57 1.313(12) . ?
C35 F29 1.371(15) . ?
F15 C141 1.339(11) . ?
C141 F31 1.333(11) . ?
C141 F61 1.345(11) . ?
F63 C71 1.321(10) . ?
F2 C71 1.340(11) . ?
F65 C71 1.369(9) . ?
F33 C143 1.338(18) . ?
F67 C143 1.341(16) . ?
F17 C143 1.332(18) . ?
C67A C145 1.461(15) . ?
C67A H67D 0.9800 . ?
C67A H67E 0.9800 . ?
C67A H67F 0.9800 . ?
C31A C33A 1.3900 . ?
C31A C145 1.3900 . ?
C31A H31A 0.9500 . ?
C33A C1A 1.3900 . ?
C33A H33A 0.9500 . ?
C1A C1B 1.3900 . ?
C1A H1A 0.9500 . ?
C1B C2A 1.3900 . ?
C1B H1B 0.9500 . ?
C2A C145 1.3900 . ?
C2A H2A 0.9500 . ?
