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#$Date: 2023-08-05 12:04:12 +0300 (Sat, 05 Aug 2023) $
#$Revision: 285464 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/32/7713268.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7713268
loop_
_publ_author_name
'Li, Jiahe'
'Wang, Zhiyuan'
'Chen, Zhongting'
'Xue, Xingyong'
'Lin, Kejuan'
'Chen, Hailan'
'Pan, Lixia'
'Yuan, Yulin'
'Ma, Zhen'
_publ_section_title
;
 Silver complexes with substituted terpyridines as promising anticancer
 metallodrugs and their crystal structure, photoluminescence, and DNA
 interactions.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9607
_journal_page_last               9621
_journal_paper_doi               10.1039/d2dt03463h
_journal_volume                  52
_journal_year                    2023
_chemical_formula_moiety         'C25 H21 Ag F6 N5 Sb'
_chemical_formula_sum            'C25 H21 Ag F6 N5 Sb'
_chemical_formula_weight         735.09
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-01-15 deposited with the CCDC.	2023-06-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90.6790(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   16.9108(5)
_cell_length_b                   7.8655(2)
_cell_length_c                   19.3503(6)
_cell_measurement_reflns_used    36539
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      30.568
_cell_measurement_theta_min      1.590
_cell_volume                     2573.64(13)
_computing_cell_refinement       'Bruker BREEZE'
_computing_data_collection       'Bruker BREEZE'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Breeze CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0265
_diffrn_reflns_av_unetI/netI     0.0205
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            36539
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.568
_diffrn_reflns_theta_min         1.590
_exptl_absorpt_coefficient_mu    1.879
_exptl_absorpt_correction_T_max  0.559
_exptl_absorpt_correction_T_min  0.495
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.897
_exptl_crystal_description       prism
_exptl_crystal_F_000             1432
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.31
_refine_diff_density_max         1.325
_refine_diff_density_min         -0.746
_refine_diff_density_rms         0.141
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     345
_refine_ls_number_reflns         7815
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.050
_refine_ls_R_factor_all          0.0448
_refine_ls_R_factor_gt           0.0398
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0704P)²+12.9333P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1363
_refine_ls_wR_factor_ref         0.1403
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6994
_reflns_number_total             7815
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt03463h2.cif
_cod_data_source_block           M
_cod_depositor_comments
'Adding full bibliography for 7713268--7713273.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7713268
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.64368(2) 1.47543(5) -0.04529(2) 0.03121(10) Uani 1 1 d . . . . .
Sb1 Sb -0.00546(2) 0.68772(4) 0.12269(2) 0.02576(8) Uani 1 1 d . . . . .
F1 F -0.0258(4) 0.5141(10) 0.1822(5) 0.151(4) Uani 1 1 d . . . . .
F2 F -0.0614(3) 0.5743(10) 0.0545(4) 0.115(2) Uani 1 1 d . . . . .
F3 F 0.0135(3) 0.8708(7) 0.0649(3) 0.096(2) Uani 1 1 d . . . . .
F4 F 0.0899(2) 0.5926(5) 0.0979(3) 0.0767(15) Uani 1 1 d . . . . .
F5 F -0.1001(2) 0.7883(6) 0.1492(2) 0.0661(12) Uani 1 1 d . . . . .
F6 F 0.0485(3) 0.8018(9) 0.1928(3) 0.101(2) Uani 1 1 d . . . . .
C03 C 0.8727(4) 0.1680(9) 0.0741(4) 0.0521(14) Uani 1 1 d . . . . .
H03A H 0.917113 0.092188 0.076288 0.078 Uiso 1 1 calc R U . . .
H03B H 0.878107 0.253061 0.109433 0.078 Uiso 1 1 calc R U . . .
H03C H 0.870587 0.221819 0.029611 0.078 Uiso 1 1 calc R U . . .
N4 N 0.7488(2) 1.6281(5) -0.0708(3) 0.0377(9) Uani 1 1 d . . . . .
C01 C 0.8047(3) 1.7021(6) -0.0796(3) 0.0346(9) Uani 1 1 d . . . . .
N5 N 0.7438(3) -0.0009(7) 0.0937(3) 0.0514(12) Uani 1 1 d . . . . .
C04 C 0.8004(3) 0.0727(7) 0.0847(3) 0.0398(10) Uani 1 1 d . . . . .
C05 C 0.8760(3) 1.7995(7) -0.0921(4) 0.0550(17) Uani 1 1 d . . . . .
H05A H 0.920287 1.744638 -0.070063 0.083 Uiso 1 1 calc R U . . .
H05B H 0.870071 1.912013 -0.073612 0.083 Uiso 1 1 calc R U . . .
H05C H 0.884821 1.806403 -0.140947 0.083 Uiso 1 1 calc R U . . .
N1 N 0.54905(18) 1.3049(4) 0.01356(17) 0.0207(6) Uani 1 1 d . . . . .
C7 C 0.7070(3) 1.3918(6) 0.2191(2) 0.0329(9) Uani 1 1 d . . . . .
H7A H 0.717356 1.376748 0.266005 0.039 Uiso 1 1 calc R U . . .
C8 C 0.5557(2) 1.2713(5) 0.08090(19) 0.0200(6) Uani 1 1 d . . . . .
N2 N 0.54332(19) 1.3873(4) -0.12184(18) 0.0250(6) Uani 1 1 d . . . . .
C10 C 0.4238(2) 1.1642(5) 0.0101(2) 0.0228(7) Uani 1 1 d . . . . .
H10A H 0.378864 1.133476 -0.015070 0.027 Uiso 1 1 calc R U . . .
C11 C 0.4854(2) 1.2524(4) -0.02155(19) 0.0198(6) Uani 1 1 d . . . . .
C12 C 0.3159(2) 0.9214(5) 0.0780(2) 0.0261(7) Uani 1 1 d . . . . .
H12A H 0.320043 0.915293 0.030178 0.031 Uiso 1 1 calc R U . . .
C13 C 0.6406(2) 1.3183(6) 0.1875(2) 0.0295(8) Uani 1 1 d . . . . .
H13A H 0.605652 1.253463 0.213360 0.035 Uiso 1 1 calc R U . . .
C14 C 0.3686(2) 1.0233(5) 0.1157(2) 0.0229(7) Uani 1 1 d . . . . .
N3 N 0.6761(2) 1.4353(5) 0.0789(2) 0.0278(7) Uani 1 1 d . . . . .
C16 C 0.4845(2) 1.2885(5) -0.0974(2) 0.0216(7) Uani 1 1 d . . . . .
C19 C 0.7571(3) 1.4874(6) 0.1785(3) 0.0335(9) Uani 1 1 d . . . . .
H19A H 0.801746 1.538585 0.197763 0.040 Uiso 1 1 calc R U . . .
C21 C 0.2573(3) 0.8290(6) 0.1112(3) 0.0335(9) Uani 1 1 d . . . . .
H21A H 0.222888 0.761014 0.085535 0.040 Uiso 1 1 calc R U . . .
C23 C 0.6271(2) 1.3429(5) 0.1173(2) 0.0217(6) Uani 1 1 d . . . . .
C24 C 0.4266(3) 1.2223(5) -0.1418(2) 0.0278(8) Uani 1 1 d . . . . .
H24A H 0.386225 1.154637 -0.124601 0.033 Uiso 1 1 calc R U . . .
C25 C 0.4308(2) 1.1229(5) 0.0803(2) 0.0209(6) Uani 1 1 d . . . . .
C29 C 0.4906(3) 1.3579(6) -0.2367(2) 0.0337(9) Uani 1 1 d . . . . .
H29A H 0.494250 1.382849 -0.283564 0.040 Uiso 1 1 calc R U . . .
C30 C 0.3607(3) 1.0305(6) 0.1873(2) 0.0330(9) Uani 1 1 d . . . . .
H30A H 0.395124 1.097435 0.213402 0.040 Uiso 1 1 calc R U . . .
C31 C 0.4988(2) 1.1765(5) 0.1160(2) 0.0222(7) Uani 1 1 d . . . . .
H31A H 0.506075 1.149384 0.162381 0.027 Uiso 1 1 calc R U . . .
C33 C 0.7395(2) 1.5058(6) 0.1088(3) 0.0325(9) Uani 1 1 d . . . . .
H33A H 0.773393 1.570038 0.081697 0.039 Uiso 1 1 calc R U . . .
C36 C 0.3019(3) 0.9387(7) 0.2200(3) 0.0414(11) Uani 1 1 d . . . . .
H36A H 0.297201 0.944570 0.267745 0.050 Uiso 1 1 calc R U . . .
C38 C 0.4297(3) 1.2583(6) -0.2118(2) 0.0319(8) Uani 1 1 d . . . . .
H38A H 0.391124 1.215981 -0.241803 0.038 Uiso 1 1 calc R U . . .
C40 C 0.5457(3) 1.4188(6) -0.1895(2) 0.0303(8) Uani 1 1 d . . . . .
H40A H 0.586775 1.485590 -0.205932 0.036 Uiso 1 1 calc R U . . .
C42 C 0.2502(3) 0.8380(7) 0.1817(3) 0.0405(11) Uani 1 1 d . . . . .
H42A H 0.210758 0.776752 0.203707 0.049 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ag1 N2 126.78(15) . . ?
N4 Ag1 N1 163.54(15) . . ?
N2 Ag1 N1 69.58(12) . . ?
N4 Ag1 N3 96.70(15) . . ?
N2 Ag1 N3 136.49(12) . . ?
N1 Ag1 N3 66.91(11) . . ?
F1 Sb1 F2 89.5(4) . . ?
F1 Sb1 F4 91.8(3) . . ?
F2 Sb1 F4 93.5(3) . . ?
F1 Sb1 F3 177.5(4) . . ?
F2 Sb1 F3 92.0(4) . . ?
F4 Sb1 F3 90.0(2) . . ?
F1 Sb1 F6 89.7(4) . . ?
F2 Sb1 F6 178.5(3) . . ?
F4 Sb1 F6 87.8(2) . . ?
F3 Sb1 F6 88.8(3) . . ?
F1 Sb1 F5 88.6(3) . . ?
F2 Sb1 F5 88.1(3) . . ?
F4 Sb1 F5 178.3(2) . . ?
F3 Sb1 F5 89.5(2) . . ?
F6 Sb1 F5 90.5(2) . . ?
C04 C03 H03A 109.5 . . ?
C04 C03 H03B 109.5 . . ?
H03A C03 H03B 109.5 . . ?
C04 C03 H03C 109.5 . . ?
H03A C03 H03C 109.5 . . ?
H03B C03 H03C 109.5 . . ?
C01 N4 Ag1 175.1(5) . . ?
N4 C01 C05 178.8(6) . . ?
N5 C04 C03 179.3(7) . . ?
C01 C05 H05A 109.5 . . ?
C01 C05 H05B 109.5 . . ?
H05A C05 H05B 109.5 . . ?
C01 C05 H05C 109.5 . . ?
H05A C05 H05C 109.5 . . ?
H05B C05 H05C 109.5 . . ?
C11 N1 C8 119.7(3) . . ?
C11 N1 Ag1 118.2(2) . . ?
C8 N1 Ag1 121.9(2) . . ?
C19 C7 C13 118.1(4) . . ?
C19 C7 H7A 120.9 . . ?
C13 C7 H7A 120.9 . . ?
N1 C8 C31 121.9(3) . . ?
N1 C8 C23 116.3(3) . . ?
C31 C8 C23 121.8(3) . . ?
C40 N2 C16 118.8(4) . . ?
C40 N2 Ag1 122.4(3) . . ?
C16 N2 Ag1 118.6(3) . . ?
C25 C10 C11 119.0(3) . . ?
C25 C10 H10A 120.5 . . ?
C11 C10 H10A 120.5 . . ?
N1 C11 C10 122.1(3) . . ?
N1 C11 C16 116.1(3) . . ?
C10 C11 C16 121.7(3) . . ?
C21 C12 C14 120.7(4) . . ?
C21 C12 H12A 119.6 . . ?
C14 C12 H12A 119.6 . . ?
C23 C13 C7 119.4(4) . . ?
C23 C13 H13A 120.3 . . ?
C7 C13 H13A 120.3 . . ?
C30 C14 C12 118.3(4) . . ?
C30 C14 C25 121.0(4) . . ?
C12 C14 C25 120.7(4) . . ?
C33 N3 C23 119.2(4) . . ?
C33 N3 Ag1 122.3(3) . . ?
C23 N3 Ag1 118.5(3) . . ?
N2 C16 C24 120.8(4) . . ?
N2 C16 C11 117.0(3) . . ?
C24 C16 C11 122.2(3) . . ?
C7 C19 C33 119.0(4) . . ?
C7 C19 H19A 120.5 . . ?
C33 C19 H19A 120.5 . . ?
C42 C21 C12 120.2(4) . . ?
C42 C21 H21A 119.9 . . ?
C12 C21 H21A 119.9 . . ?
N3 C23 C13 121.6(4) . . ?
N3 C23 C8 116.4(3) . . ?
C13 C23 C8 122.0(3) . . ?
C38 C24 C16 119.4(4) . . ?
C38 C24 H24A 120.3 . . ?
C16 C24 H24A 120.3 . . ?
C10 C25 C31 117.9(3) . . ?
C10 C25 C14 121.2(3) . . ?
C31 C25 C14 120.9(3) . . ?
C40 C29 C38 117.6(4) . . ?
C40 C29 H29A 121.2 . . ?
C38 C29 H29A 121.2 . . ?
C36 C30 C14 120.6(5) . . ?
C36 C30 H30A 119.7 . . ?
C14 C30 H30A 119.7 . . ?
C8 C31 C25 119.2(3) . . ?
C8 C31 H31A 120.4 . . ?
C25 C31 H31A 120.4 . . ?
N3 C33 C19 122.7(4) . . ?
N3 C33 H33A 118.7 . . ?
C19 C33 H33A 118.7 . . ?
C30 C36 C42 120.3(5) . . ?
C30 C36 H36A 119.9 . . ?
C42 C36 H36A 119.9 . . ?
C24 C38 C29 119.6(4) . . ?
C24 C38 H38A 120.2 . . ?
C29 C38 H38A 120.2 . . ?
N2 C40 C29 123.8(4) . . ?
N2 C40 H40A 118.1 . . ?
C29 C40 H40A 118.1 . . ?
C21 C42 C36 119.8(4) . . ?
C21 C42 H42A 120.1 . . ?
C36 C42 H42A 120.1 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N4 2.206(4) . ?
Ag1 N2 2.344(4) . ?
Ag1 N1 2.387(3) . ?
Ag1 N3 2.479(4) . ?
Sb1 F1 1.822(5) . ?
Sb1 F2 1.844(5) . ?
Sb1 F4 1.845(3) . ?
Sb1 F3 1.853(4) . ?
Sb1 F6 1.858(4) . ?
Sb1 F5 1.862(3) . ?
C03 C04 1.450(8) . ?
C03 H03A 0.9600 . ?
C03 H03B 0.9600 . ?
C03 H03C 0.9600 . ?
N4 C01 1.125(6) . ?
C01 C05 1.451(7) . ?
N5 C04 1.134(8) . ?
C05 H05A 0.9600 . ?
C05 H05B 0.9600 . ?
C05 H05C 0.9600 . ?
N1 C11 1.331(5) . ?
N1 C8 1.333(5) . ?
C7 C19 1.383(7) . ?
C7 C13 1.398(6) . ?
C7 H7A 0.9300 . ?
C8 C31 1.400(5) . ?
C8 C23 1.499(5) . ?
N2 C40 1.334(5) . ?
N2 C16 1.352(5) . ?
C10 C25 1.399(5) . ?
C10 C11 1.399(5) . ?
C10 H10A 0.9300 . ?
C11 C16 1.494(5) . ?
C12 C21 1.392(6) . ?
C12 C14 1.398(6) . ?
C12 H12A 0.9300 . ?
C13 C23 1.389(6) . ?
C13 H13A 0.9300 . ?
C14 C30 1.394(6) . ?
C14 C25 1.486(5) . ?
N3 C33 1.333(5) . ?
N3 C23 1.335(5) . ?
C16 C24 1.398(6) . ?
C19 C33 1.386(7) . ?
C19 H19A 0.9300 . ?
C21 C42 1.372(8) . ?
C21 H21A 0.9300 . ?
C24 C38 1.384(6) . ?
C24 H24A 0.9300 . ?
C25 C31 1.400(5) . ?
C29 C40 1.383(7) . ?
C29 C38 1.385(7) . ?
C29 H29A 0.9300 . ?
C30 C36 1.386(6) . ?
C30 H30A 0.9300 . ?
C31 H31A 0.9300 . ?
C33 H33A 0.9300 . ?
C36 C42 1.389(8) . ?
C36 H36A 0.9300 . ?
C38 H38A 0.9300 . ?
C40 H40A 0.9300 . ?
C42 H42A 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C11 N1 C8 C31 2.2(5) . . . . ?
Ag1 N1 C8 C31 177.7(3) . . . . ?
C11 N1 C8 C23 -176.9(3) . . . . ?
Ag1 N1 C8 C23 -1.5(4) . . . . ?
C8 N1 C11 C10 1.0(5) . . . . ?
Ag1 N1 C11 C10 -174.5(3) . . . . ?
C8 N1 C11 C16 -177.3(3) . . . . ?
Ag1 N1 C11 C16 7.2(4) . . . . ?
C25 C10 C11 N1 -3.0(5) . . . . ?
C25 C10 C11 C16 175.2(3) . . . . ?
C19 C7 C13 C23 0.2(7) . . . . ?
C21 C12 C14 C30 -0.2(6) . . . . ?
C21 C12 C14 C25 -179.6(4) . . . . ?
C40 N2 C16 C24 -0.9(6) . . . . ?
Ag1 N2 C16 C24 -175.3(3) . . . . ?
C40 N2 C16 C11 178.3(3) . . . . ?
Ag1 N2 C16 C11 4.0(4) . . . . ?
N1 C11 C16 N2 -7.4(5) . . . . ?
C10 C11 C16 N2 174.3(3) . . . . ?
N1 C11 C16 C24 171.8(4) . . . . ?
C10 C11 C16 C24 -6.5(6) . . . . ?
C13 C7 C19 C33 -0.2(7) . . . . ?
C14 C12 C21 C42 0.5(7) . . . . ?
C33 N3 C23 C13 -0.1(6) . . . . ?
Ag1 N3 C23 C13 -178.5(3) . . . . ?
C33 N3 C23 C8 178.4(4) . . . . ?
Ag1 N3 C23 C8 -0.1(4) . . . . ?
C7 C13 C23 N3 0.0(6) . . . . ?
C7 C13 C23 C8 -178.4(4) . . . . ?
N1 C8 C23 N3 1.0(5) . . . . ?
C31 C8 C23 N3 -178.1(4) . . . . ?
N1 C8 C23 C13 179.4(4) . . . . ?
C31 C8 C23 C13 0.3(6) . . . . ?
N2 C16 C24 C38 0.2(6) . . . . ?
C11 C16 C24 C38 -179.0(4) . . . . ?
C11 C10 C25 C31 1.7(5) . . . . ?
C11 C10 C25 C14 -177.5(3) . . . . ?
C30 C14 C25 C10 -158.0(4) . . . . ?
C12 C14 C25 C10 21.3(5) . . . . ?
C30 C14 C25 C31 22.9(6) . . . . ?
C12 C14 C25 C31 -157.8(4) . . . . ?
C12 C14 C30 C36 0.0(7) . . . . ?
C25 C14 C30 C36 179.3(4) . . . . ?
N1 C8 C31 C25 -3.5(6) . . . . ?
C23 C8 C31 C25 175.6(3) . . . . ?
C10 C25 C31 C8 1.4(5) . . . . ?
C14 C25 C31 C8 -179.5(3) . . . . ?
C23 N3 C33 C19 0.0(7) . . . . ?
Ag1 N3 C33 C19 178.4(4) . . . . ?
C7 C19 C33 N3 0.2(8) . . . . ?
C14 C30 C36 C42 0.1(8) . . . . ?
C16 C24 C38 C29 0.6(7) . . . . ?
C40 C29 C38 C24 -0.7(7) . . . . ?
C16 N2 C40 C29 0.9(7) . . . . ?
Ag1 N2 C40 C29 175.0(4) . . . . ?
C38 C29 C40 N2 -0.1(7) . . . . ?
C12 C21 C42 C36 -0.4(8) . . . . ?
C30 C36 C42 C21 0.1(8) . . . . ?
