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#$Date: 2023-08-05 12:04:12 +0300 (Sat, 05 Aug 2023) $
#$Revision: 285464 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/32/7713270.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7713270
loop_
_publ_author_name
'Li, Jiahe'
'Wang, Zhiyuan'
'Chen, Zhongting'
'Xue, Xingyong'
'Lin, Kejuan'
'Chen, Hailan'
'Pan, Lixia'
'Yuan, Yulin'
'Ma, Zhen'
_publ_section_title
;
 Silver complexes with substituted terpyridines as promising anticancer
 metallodrugs and their crystal structure, photoluminescence, and DNA
 interactions.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9607
_journal_page_last               9621
_journal_paper_doi               10.1039/d2dt03463h
_journal_volume                  52
_journal_year                    2023
_chemical_formula_moiety         'C23 H17 Ag Cl F6 N4 Sb'
_chemical_formula_sum            'C23 H17 Ag Cl F6 N4 Sb'
_chemical_formula_weight         728.48
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-01-15 deposited with the CCDC.	2023-06-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 99.079(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   7.8110(3)
_cell_length_b                   20.7327(7)
_cell_length_c                   15.6722(5)
_cell_measurement_reflns_used    15200
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.500
_cell_measurement_theta_min      2.928
_cell_volume                     2506.21(15)
_computing_cell_refinement       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_molecular_graphics    'Diamond 3.2 (2012)'
_computing_publication_material  'SHELXL2018 and PLATON (Spek, 2009)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.3818
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0260
_diffrn_reflns_av_unetI/netI     0.0292
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.982
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            15200
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.982
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.500
_diffrn_reflns_theta_min         2.928
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    2.030
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.51867
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.931
_exptl_crystal_description       prism
_exptl_crystal_F_000             1408
_exptl_crystal_size_max          0.46
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.316
_refine_diff_density_min         -0.797
_refine_diff_density_rms         0.084
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     326
_refine_ls_number_reflns         5653
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.049
_refine_ls_R_factor_all          0.0529
_refine_ls_R_factor_gt           0.0351
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0484P)²+0.3448P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0874
_refine_ls_wR_factor_ref         0.0981
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4254
_reflns_number_total             5653
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt03463h2.cif
_cod_data_source_block           D_CCDC1
_cod_depositor_comments
'Adding full bibliography for 7713268--7713273.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7713270
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.51034(4) 0.49338(2) 0.34117(2) 0.07056(12) Uani 1 1 d . . . . .
Sb1 Sb 0.05708(3) 0.33049(2) 0.85484(2) 0.06141(11) Uani 1 1 d . . . . .
Cl1 Cl 1.40322(15) 0.61031(6) 0.94812(8) 0.0956(4) Uani 1 1 d . . . . .
F1 F -0.0623(5) 0.40588(15) 0.8671(2) 0.1369(12) Uani 1 1 d . . . . .
F2 F 0.2645(4) 0.37389(15) 0.8847(2) 0.1191(10) Uani 1 1 d . . . . .
F3 F 0.1798(3) 0.25471(12) 0.8449(2) 0.1025(9) Uani 1 1 d . . . . .
F4 F -0.1485(3) 0.28545(17) 0.8253(2) 0.1259(11) Uani 1 1 d . . . . .
F5 F 0.0567(5) 0.31158(18) 0.97167(19) 0.1296(12) Uani 1 1 d . . . . .
F6 F 0.0566(4) 0.35102(15) 0.74028(16) 0.1024(9) Uani 1 1 d . . . . .
N1 N 0.5686(3) 0.60662(16) 0.35200(18) 0.0607(7) Uani 1 1 d . . . . .
N2 N 0.7113(3) 0.51743(12) 0.46539(15) 0.0445(6) Uani 1 1 d . . . . .
N3 N 0.5895(3) 0.39793(14) 0.42607(17) 0.0537(7) Uani 1 1 d . . . . .
N4 N 0.3410(5) 0.4661(2) 0.2229(2) 0.0975(13) Uani 1 1 d . . . . .
C1 C 0.4949(5) 0.6498(2) 0.2938(3) 0.0752(11) Uani 1 1 d . . . . .
H1A H 0.414586 0.635260 0.247666 0.090 Uiso 1 1 calc R U . . .
C2 C 0.5321(6) 0.7141(2) 0.2991(3) 0.0780(12) Uani 1 1 d . . . . .
H2A H 0.476442 0.742602 0.257982 0.094 Uiso 1 1 calc R U . . .
C3 C 0.6516(6) 0.7358(2) 0.3651(3) 0.0789(12) Uani 1 1 d . . . . .
H3A H 0.681082 0.779302 0.369410 0.095 Uiso 1 1 calc R U . . .
C4 C 0.7283(5) 0.69226(18) 0.4258(2) 0.0649(9) Uani 1 1 d . . . . .
H4A H 0.809926 0.706192 0.471839 0.078 Uiso 1 1 calc R U . . .
C5 C 0.6837(4) 0.62807(16) 0.4181(2) 0.0491(7) Uani 1 1 d . . . . .
C6 C 0.7579(4) 0.57844(15) 0.48345(19) 0.0449(7) Uani 1 1 d . . . . .
C7 C 0.8687(4) 0.59477(15) 0.55861(19) 0.0454(7) Uani 1 1 d . . . . .
H7A H 0.902684 0.637422 0.568821 0.055 Uiso 1 1 calc R U . . .
C8 C 0.9287(3) 0.54726(15) 0.61857(19) 0.0433(6) Uani 1 1 d . . . . .
C9 C 0.8735(4) 0.48433(15) 0.6000(2) 0.0464(7) Uani 1 1 d . . . . .
H9A H 0.907217 0.451387 0.639389 0.056 Uiso 1 1 calc R U . . .
C10 C 0.7669(4) 0.47104(15) 0.52170(19) 0.0432(6) Uani 1 1 d . . . . .
C11 C 0.7114(4) 0.40373(15) 0.4956(2) 0.0462(7) Uani 1 1 d . . . . .
C12 C 0.7818(5) 0.35007(17) 0.5394(2) 0.0583(8) Uani 1 1 d . . . . .
H12A H 0.866706 0.354486 0.587755 0.070 Uiso 1 1 calc R U . . .
C13 C 0.7252(5) 0.28965(18) 0.5108(2) 0.0652(9) Uani 1 1 d . . . . .
H13A H 0.773836 0.252998 0.539061 0.078 Uiso 1 1 calc R U . . .
C14 C 0.5982(5) 0.28385(19) 0.4411(3) 0.0670(10) Uani 1 1 d . . . . .
H14A H 0.555897 0.243632 0.421773 0.080 Uiso 1 1 calc R U . . .
C15 C 0.5354(5) 0.33875(19) 0.4010(3) 0.0636(9) Uani 1 1 d . . . . .
H15A H 0.449274 0.335027 0.352939 0.076 Uiso 1 1 calc R U . . .
C16 C 1.0481(4) 0.56300(15) 0.6996(2) 0.0477(7) Uani 1 1 d . . . . .
C17 C 1.1459(4) 0.51558(16) 0.7471(2) 0.0506(7) Uani 1 1 d . . . . .
H17A H 1.137595 0.473231 0.727256 0.061 Uiso 1 1 calc R U . . .
C18 C 1.2554(4) 0.52958(17) 0.8229(2) 0.0557(8) Uani 1 1 d . . . . .
H18A H 1.319847 0.497112 0.853923 0.067 Uiso 1 1 calc R U . . .
C19 C 1.2677(5) 0.59220(19) 0.8519(2) 0.0650(9) Uani 1 1 d . . . . .
C20 C 1.1755(6) 0.6401(2) 0.8052(3) 0.0877(14) Uani 1 1 d . . . . .
H20A H 1.187647 0.682665 0.823970 0.105 Uiso 1 1 calc R U . . .
C21 C 1.0656(6) 0.62542(19) 0.7309(3) 0.0791(12) Uani 1 1 d . . . . .
H21A H 1.001135 0.658198 0.700627 0.095 Uiso 1 1 calc R U . . .
C22 C 0.2616(5) 0.4602(3) 0.1584(3) 0.0797(12) Uani 1 1 d . . . . .
C23 C 0.1585(6) 0.4537(3) 0.0739(3) 0.116(2) Uani 1 1 d . . . . .
H23A H 0.141566 0.408822 0.060108 0.174 Uiso 1 1 calc R U . . .
H23B H 0.217214 0.474018 0.031689 0.174 Uiso 1 1 calc R U . . .
H23C H 0.047963 0.474033 0.073761 0.174 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ag1 N2 175.25(13) . . ?
N4 Ag1 N1 113.52(15) . . ?
N2 Ag1 N1 68.82(9) . . ?
N4 Ag1 N3 108.99(14) . . ?
N2 Ag1 N3 68.76(9) . . ?
N1 Ag1 N3 137.49(9) . . ?
F6 Sb1 F1 89.02(15) . . ?
F6 Sb1 F2 90.06(14) . . ?
F1 Sb1 F2 89.90(16) . . ?
F6 Sb1 F4 90.29(15) . . ?
F1 Sb1 F4 91.18(17) . . ?
F2 Sb1 F4 178.87(15) . . ?
F6 Sb1 F3 92.00(14) . . ?
F1 Sb1 F3 178.78(15) . . ?
F2 Sb1 F3 89.41(13) . . ?
F4 Sb1 F3 89.50(14) . . ?
F6 Sb1 F5 178.73(15) . . ?
F1 Sb1 F5 89.80(16) . . ?
F2 Sb1 F5 89.48(16) . . ?
F4 Sb1 F5 90.20(17) . . ?
F3 Sb1 F5 89.18(15) . . ?
C5 N1 C1 118.0(3) . . ?
C5 N1 Ag1 118.6(2) . . ?
C1 N1 Ag1 123.4(3) . . ?
C10 N2 C6 119.7(3) . . ?
C10 N2 Ag1 120.0(2) . . ?
C6 N2 Ag1 120.0(2) . . ?
C11 N3 C15 118.3(3) . . ?
C11 N3 Ag1 117.7(2) . . ?
C15 N3 Ag1 123.3(2) . . ?
C22 N4 Ag1 170.2(5) . . ?
N1 C1 C2 123.2(4) . . ?
N1 C1 H1A 118.4 . . ?
C2 C1 H1A 118.4 . . ?
C3 C2 C1 119.0(4) . . ?
C3 C2 H2A 120.5 . . ?
C1 C2 H2A 120.5 . . ?
C2 C3 C4 118.7(4) . . ?
C2 C3 H3A 120.6 . . ?
C4 C3 H3A 120.6 . . ?
C5 C4 C3 119.8(4) . . ?
C5 C4 H4A 120.1 . . ?
C3 C4 H4A 120.1 . . ?
N1 C5 C4 121.3(3) . . ?
N1 C5 C6 116.1(3) . . ?
C4 C5 C6 122.5(3) . . ?
N2 C6 C7 121.6(3) . . ?
N2 C6 C5 116.2(3) . . ?
C7 C6 C5 122.2(3) . . ?
C6 C7 C8 119.9(3) . . ?
C6 C7 H7A 120.0 . . ?
C8 C7 H7A 120.0 . . ?
C9 C8 C7 117.6(3) . . ?
C9 C8 C16 121.1(3) . . ?
C7 C8 C16 121.4(3) . . ?
C8 C9 C10 119.4(3) . . ?
C8 C9 H9A 120.3 . . ?
C10 C9 H9A 120.3 . . ?
N2 C10 C9 121.8(3) . . ?
N2 C10 C11 116.2(3) . . ?
C9 C10 C11 122.0(3) . . ?
N3 C11 C12 120.8(3) . . ?
N3 C11 C10 116.4(3) . . ?
C12 C11 C10 122.8(3) . . ?
C11 C12 C13 119.4(3) . . ?
C11 C12 H12A 120.3 . . ?
C13 C12 H12A 120.3 . . ?
C14 C13 C12 119.8(4) . . ?
C14 C13 H13A 120.1 . . ?
C12 C13 H13A 120.1 . . ?
C15 C14 C13 117.6(4) . . ?
C15 C14 H14A 121.2 . . ?
C13 C14 H14A 121.2 . . ?
N3 C15 C14 124.1(3) . . ?
N3 C15 H15A 118.0 . . ?
C14 C15 H15A 118.0 . . ?
C21 C16 C17 117.3(3) . . ?
C21 C16 C8 121.4(3) . . ?
C17 C16 C8 121.3(3) . . ?
C18 C17 C16 121.8(3) . . ?
C18 C17 H17A 119.1 . . ?
C16 C17 H17A 119.1 . . ?
C19 C18 C17 119.0(3) . . ?
C19 C18 H18A 120.5 . . ?
C17 C18 H18A 120.5 . . ?
C20 C19 C18 120.4(3) . . ?
C20 C19 Cl1 120.2(3) . . ?
C18 C19 Cl1 119.4(3) . . ?
C21 C20 C19 120.0(4) . . ?
C21 C20 H20A 120.0 . . ?
C19 C20 H20A 120.0 . . ?
C20 C21 C16 121.6(4) . . ?
C20 C21 H21A 119.2 . . ?
C16 C21 H21A 119.2 . . ?
N4 C22 C23 178.9(6) . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N4 2.176(4) . ?
Ag1 N2 2.353(2) . ?
Ag1 N1 2.393(3) . ?
Ag1 N3 2.410(3) . ?
Sb1 F6 1.845(3) . ?
Sb1 F1 1.846(3) . ?
Sb1 F2 1.848(3) . ?
Sb1 F4 1.852(3) . ?
Sb1 F3 1.860(2) . ?
Sb1 F5 1.873(3) . ?
Cl1 C19 1.741(3) . ?
N1 C5 1.336(4) . ?
N1 C1 1.342(5) . ?
N2 C10 1.331(4) . ?
N2 C6 1.334(4) . ?
N3 C11 1.334(4) . ?
N3 C15 1.337(4) . ?
N4 C22 1.106(5) . ?
C1 C2 1.363(6) . ?
C1 H1A 0.9300 . ?
C2 C3 1.357(6) . ?
C2 H2A 0.9300 . ?
C3 C4 1.378(5) . ?
C3 H3A 0.9300 . ?
C4 C5 1.376(5) . ?
C4 H4A 0.9300 . ?
C5 C6 1.502(4) . ?
C6 C7 1.389(4) . ?
C7 C8 1.391(4) . ?
C7 H7A 0.9300 . ?
C8 C9 1.390(4) . ?
C8 C16 1.489(4) . ?
C9 C10 1.398(4) . ?
C9 H9A 0.9300 . ?
C10 C11 1.499(4) . ?
C11 C12 1.375(5) . ?
C12 C13 1.379(5) . ?
C12 H12A 0.9300 . ?
C13 C14 1.360(5) . ?
C13 H13A 0.9300 . ?
C14 C15 1.355(5) . ?
C14 H14A 0.9300 . ?
C15 H15A 0.9300 . ?
C16 C21 1.383(5) . ?
C16 C17 1.387(4) . ?
C17 C18 1.382(4) . ?
C17 H17A 0.9300 . ?
C18 C19 1.374(5) . ?
C18 H18A 0.9300 . ?
C19 C20 1.369(5) . ?
C20 C21 1.367(5) . ?
C20 H20A 0.9300 . ?
C21 H21A 0.9300 . ?
C22 C23 1.444(5) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 0.1(6) . . . . ?
Ag1 N1 C1 C2 -178.2(3) . . . . ?
N1 C1 C2 C3 1.3(7) . . . . ?
C1 C2 C3 C4 -1.5(7) . . . . ?
C2 C3 C4 C5 0.4(6) . . . . ?
C1 N1 C5 C4 -1.2(5) . . . . ?
Ag1 N1 C5 C4 177.2(3) . . . . ?
C1 N1 C5 C6 177.8(3) . . . . ?
Ag1 N1 C5 C6 -3.9(4) . . . . ?
C3 C4 C5 N1 1.0(5) . . . . ?
C3 C4 C5 C6 -177.9(3) . . . . ?
C10 N2 C6 C7 2.3(4) . . . . ?
Ag1 N2 C6 C7 176.4(2) . . . . ?
C10 N2 C6 C5 -177.6(2) . . . . ?
Ag1 N2 C6 C5 -3.6(3) . . . . ?
N1 C5 C6 N2 4.9(4) . . . . ?
C4 C5 C6 N2 -176.2(3) . . . . ?
N1 C5 C6 C7 -175.1(3) . . . . ?
C4 C5 C6 C7 3.9(5) . . . . ?
N2 C6 C7 C8 -2.3(4) . . . . ?
C5 C6 C7 C8 177.6(3) . . . . ?
C6 C7 C8 C9 -0.1(4) . . . . ?
C6 C7 C8 C16 179.7(3) . . . . ?
C7 C8 C9 C10 2.3(4) . . . . ?
C16 C8 C9 C10 -177.5(3) . . . . ?
C6 N2 C10 C9 0.0(4) . . . . ?
Ag1 N2 C10 C9 -174.0(2) . . . . ?
C6 N2 C10 C11 -178.8(3) . . . . ?
Ag1 N2 C10 C11 7.2(3) . . . . ?
C8 C9 C10 N2 -2.4(4) . . . . ?
C8 C9 C10 C11 176.4(3) . . . . ?
C15 N3 C11 C12 1.1(5) . . . . ?
Ag1 N3 C11 C12 -170.0(2) . . . . ?
C15 N3 C11 C10 -179.5(3) . . . . ?
Ag1 N3 C11 C10 9.4(3) . . . . ?
N2 C10 C11 N3 -10.9(4) . . . . ?
C9 C10 C11 N3 170.2(3) . . . . ?
N2 C10 C11 C12 168.5(3) . . . . ?
C9 C10 C11 C12 -10.4(5) . . . . ?
N3 C11 C12 C13 0.0(5) . . . . ?
C10 C11 C12 C13 -179.3(3) . . . . ?
C11 C12 C13 C14 -1.5(6) . . . . ?
C12 C13 C14 C15 1.8(6) . . . . ?
C11 N3 C15 C14 -0.8(6) . . . . ?
Ag1 N3 C15 C14 169.8(3) . . . . ?
C13 C14 C15 N3 -0.6(6) . . . . ?
C9 C8 C16 C21 -161.5(4) . . . . ?
C7 C8 C16 C21 18.6(5) . . . . ?
C9 C8 C16 C17 18.2(5) . . . . ?
C7 C8 C16 C17 -161.6(3) . . . . ?
C21 C16 C17 C18 0.6(5) . . . . ?
C8 C16 C17 C18 -179.1(3) . . . . ?
C16 C17 C18 C19 -0.1(5) . . . . ?
C17 C18 C19 C20 -1.4(6) . . . . ?
C17 C18 C19 Cl1 179.2(3) . . . . ?
C18 C19 C20 C21 2.4(7) . . . . ?
Cl1 C19 C20 C21 -178.2(4) . . . . ?
C19 C20 C21 C16 -1.9(8) . . . . ?
C17 C16 C21 C20 0.4(7) . . . . ?
C8 C16 C21 C20 -179.8(4) . . . . ?
