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#$Date: 2023-08-05 12:04:12 +0300 (Sat, 05 Aug 2023) $
#$Revision: 285464 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/71/32/7713271.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7713271
loop_
_publ_author_name
'Li, Jiahe'
'Wang, Zhiyuan'
'Chen, Zhongting'
'Xue, Xingyong'
'Lin, Kejuan'
'Chen, Hailan'
'Pan, Lixia'
'Yuan, Yulin'
'Ma, Zhen'
_publ_section_title
;
 Silver complexes with substituted terpyridines as promising anticancer
 metallodrugs and their crystal structure, photoluminescence, and DNA
 interactions.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9607
_journal_page_last               9621
_journal_paper_doi               10.1039/d2dt03463h
_journal_volume                  52
_journal_year                    2023
_chemical_formula_moiety         'C23 H17 Ag F6 I N4 Sb'
_chemical_formula_sum            'C23 H17 Ag F6 I N4 Sb'
_chemical_formula_weight         819.93
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2020-01-15 deposited with the CCDC.	2023-06-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 98.44(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.0272(16)
_cell_length_b                   20.981(4)
_cell_length_c                   15.281(3)
_cell_measurement_reflns_used    17692
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.797
_cell_measurement_theta_min      3.322
_cell_volume                     2545.7(9)
_computing_cell_refinement       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.46 (Rigaku OD, 2015)'
_computing_molecular_graphics    'Diamond 3.2 (2012)'
_computing_publication_material  'SHELXL2018 and PLATON (Spek, 2009)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.3818
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.891
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0303
_diffrn_reflns_av_unetI/netI     0.0380
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.891
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            17692
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.891
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.797
_diffrn_reflns_theta_min         3.322
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    3.107
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.73033
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.46 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.139
_exptl_crystal_description       prism
_exptl_crystal_F_000             1552
_exptl_crystal_size_max          0.46
_exptl_crystal_size_mid          0.41
_exptl_crystal_size_min          0.33
_refine_diff_density_max         0.489
_refine_diff_density_min         -0.599
_refine_diff_density_rms         0.090
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     326
_refine_ls_number_reflns         5914
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.014
_refine_ls_R_factor_all          0.0617
_refine_ls_R_factor_gt           0.0354
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0358P)²+1.0531P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0744
_refine_ls_wR_factor_ref         0.0896
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4084
_reflns_number_total             5914
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2dt03463h2.cif
_cod_data_source_block           D_CCDC2
_cod_depositor_comments
'Adding full bibliography for 7713268--7713273.cif.'
_cod_original_cell_volume        2545.8(9)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7713271
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.50917(5) 0.50127(2) 1.33985(2) 0.06553(13) Uani 1 1 d . . . . .
I1 I 2.42629(4) 0.39238(2) 1.97252(2) 0.06453(12) Uani 1 1 d . . . . .
Sb1 Sb 0.05330(4) 0.67178(2) 0.84881(2) 0.05437(11) Uani 1 1 d . . . . .
F1 F -0.0602(6) 0.59661(19) 0.8605(3) 0.1362(17) Uani 1 1 d . . . . .
F2 F 0.2558(5) 0.62936(19) 0.8749(3) 0.1164(14) Uani 1 1 d . . . . .
F3 F 0.0553(6) 0.6879(2) 0.9696(2) 0.1270(15) Uani 1 1 d . . . . .
F4 F -0.1474(4) 0.7150(2) 0.8226(3) 0.1267(16) Uani 1 1 d . . . . .
F5 F 0.0529(5) 0.65255(19) 0.7316(2) 0.1010(11) Uani 1 1 d . . . . .
F6 F 0.1706(4) 0.74695(15) 0.8401(3) 0.1023(12) Uani 1 1 d . . . . .
N1 N 1.5661(5) 0.38946(19) 1.3539(2) 0.0576(10) Uani 1 1 d . . . . .
N2 N 1.7114(4) 0.47991(16) 1.4639(2) 0.0401(8) Uani 1 1 d . . . . .
N3 N 1.5870(4) 0.59717(17) 1.4226(2) 0.0495(9) Uani 1 1 d . . . . .
N4 N 1.3406(5) 0.5286(3) 1.2227(3) 0.0889(16) Uani 1 1 d . . . . .
C1 C 1.4919(7) 0.3461(3) 1.2976(3) 0.0722(15) Uani 1 1 d . . . . .
H1A H 1.410836 0.359791 1.251604 0.087 Uiso 1 1 calc R U . . .
C2 C 1.5287(7) 0.2831(3) 1.3039(4) 0.0738(16) Uani 1 1 d . . . . .
H2A H 1.470929 0.254101 1.264488 0.089 Uiso 1 1 calc R U . . .
C3 C 1.6514(7) 0.2629(3) 1.3688(4) 0.0751(16) Uani 1 1 d . . . . .
H3A H 1.682538 0.220212 1.373055 0.090 Uiso 1 1 calc R U . . .
C4 C 1.7287(7) 0.3068(2) 1.4278(3) 0.0607(13) Uani 1 1 d . . . . .
H4A H 1.811800 0.293898 1.473258 0.073 Uiso 1 1 calc R U . . .
C5 C 1.6835(5) 0.3695(2) 1.4199(3) 0.0449(10) Uani 1 1 d . . . . .
C6 C 1.7570(5) 0.41992(19) 1.4839(3) 0.0392(9) Uani 1 1 d . . . . .
C7 C 1.8688(5) 0.40498(19) 1.5591(3) 0.0413(9) Uani 1 1 d . . . . .
H7A H 1.903013 0.363010 1.569915 0.050 Uiso 1 1 calc R U . . .
C8 C 1.9299(5) 0.45295(19) 1.6185(3) 0.0389(9) Uani 1 1 d . . . . .
C9 C 1.8736(5) 0.51505(19) 1.5974(3) 0.0418(9) Uani 1 1 d . . . . .
H9A H 1.908037 0.548382 1.635924 0.050 Uiso 1 1 calc R U . . .
C10 C 1.7669(5) 0.52708(19) 1.5195(2) 0.0386(9) Uani 1 1 d . . . . .
C11 C 1.7105(5) 0.59289(19) 1.4918(3) 0.0400(9) Uani 1 1 d . . . . .
C12 C 1.7810(6) 0.6466(2) 1.5338(3) 0.0524(11) Uani 1 1 d . . . . .
H12A H 1.866029 0.642976 1.581956 0.063 Uiso 1 1 calc R U . . .
C13 C 1.7237(7) 0.7060(2) 1.5035(3) 0.0614(13) Uani 1 1 d . . . . .
H13A H 1.771947 0.742796 1.530022 0.074 Uiso 1 1 calc R U . . .
C14 C 1.5958(6) 0.7099(2) 1.4346(3) 0.0612(13) Uani 1 1 d . . . . .
H14A H 1.552247 0.749238 1.414813 0.073 Uiso 1 1 calc R U . . .
C15 C 1.5332(6) 0.6551(2) 1.3952(3) 0.0585(12) Uani 1 1 d . . . . .
H15A H 1.448703 0.658078 1.346776 0.070 Uiso 1 1 calc R U . . .
C16 C 2.0485(5) 0.43838(19) 1.6995(3) 0.0405(9) Uani 1 1 d . . . . .
C17 C 2.1477(5) 0.48633(19) 1.7442(3) 0.0423(9) Uani 1 1 d . . . . .
H17A H 2.140547 0.527655 1.721990 0.051 Uiso 1 1 calc R U . . .
C18 C 2.2564(5) 0.4733(2) 1.8210(3) 0.0442(10) Uani 1 1 d . . . . .
H18A H 2.322196 0.505583 1.849952 0.053 Uiso 1 1 calc R U . . .
C19 C 2.2665(5) 0.4123(2) 1.8544(3) 0.0485(11) Uani 1 1 d . . . . .
C20 C 2.1736(6) 0.3639(2) 1.8106(3) 0.0685(15) Uani 1 1 d . . . . .
H20A H 2.183960 0.322390 1.832218 0.082 Uiso 1 1 calc R U . . .
C21 C 2.0642(6) 0.3775(2) 1.7338(3) 0.0626(14) Uani 1 1 d . . . . .
H21A H 1.999956 0.344773 1.704901 0.075 Uiso 1 1 calc R U . . .
C22 C 1.2529(6) 0.5361(3) 1.1599(3) 0.0662(14) Uani 1 1 d . . . . .
C23 C 1.1402(6) 0.5444(3) 1.0778(4) 0.089(2) Uani 1 1 d . . . . .
H23A H 1.181557 0.520572 1.031804 0.133 Uiso 1 1 calc R U . . .
H23B H 1.134198 0.588717 1.062284 0.133 Uiso 1 1 calc R U . . .
H23C H 1.030018 0.529271 1.084790 0.133 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ag1 N2 174.08(17) . . ?
N4 Ag1 N1 115.03(18) . . ?
N2 Ag1 N1 68.95(12) . . ?
N4 Ag1 N3 107.25(18) . . ?
N2 Ag1 N3 68.95(12) . . ?
N1 Ag1 N3 137.72(12) . . ?
F5 Sb1 F4 91.14(19) . . ?
F5 Sb1 F1 88.64(19) . . ?
F4 Sb1 F1 90.8(2) . . ?
F5 Sb1 F2 88.85(18) . . ?
F4 Sb1 F2 179.3(2) . . ?
F1 Sb1 F2 89.9(2) . . ?
F5 Sb1 F6 92.57(17) . . ?
F4 Sb1 F6 90.14(18) . . ?
F1 Sb1 F6 178.5(2) . . ?
F2 Sb1 F6 89.15(18) . . ?
F5 Sb1 F3 177.68(18) . . ?
F4 Sb1 F3 90.3(2) . . ?
F1 Sb1 F3 89.6(2) . . ?
F2 Sb1 F3 89.7(2) . . ?
F6 Sb1 F3 89.21(19) . . ?
C1 N1 C5 118.1(4) . . ?
C1 N1 Ag1 123.4(4) . . ?
C5 N1 Ag1 118.5(3) . . ?
C6 N2 C10 119.9(3) . . ?
C6 N2 Ag1 119.9(2) . . ?
C10 N2 Ag1 119.8(3) . . ?
C15 N3 C11 118.4(4) . . ?
C15 N3 Ag1 123.2(3) . . ?
C11 N3 Ag1 117.5(3) . . ?
C22 N4 Ag1 172.6(6) . . ?
N1 C1 C2 123.3(5) . . ?
N1 C1 H1A 118.4 . . ?
C2 C1 H1A 118.4 . . ?
C1 C2 C3 118.8(5) . . ?
C1 C2 H2A 120.6 . . ?
C3 C2 H2A 120.6 . . ?
C2 C3 C4 118.7(5) . . ?
C2 C3 H3A 120.6 . . ?
C4 C3 H3A 120.6 . . ?
C5 C4 C3 120.0(5) . . ?
C5 C4 H4A 120.0 . . ?
C3 C4 H4A 120.0 . . ?
N1 C5 C4 121.0(4) . . ?
N1 C5 C6 115.8(4) . . ?
C4 C5 C6 123.2(4) . . ?
N2 C6 C7 121.7(4) . . ?
N2 C6 C5 116.6(3) . . ?
C7 C6 C5 121.7(4) . . ?
C6 C7 C8 120.0(4) . . ?
C6 C7 H7A 120.0 . . ?
C8 C7 H7A 120.0 . . ?
C7 C8 C9 116.7(4) . . ?
C7 C8 C16 121.2(4) . . ?
C9 C8 C16 122.1(3) . . ?
C10 C9 C8 120.4(4) . . ?
C10 C9 H9A 119.8 . . ?
C8 C9 H9A 119.8 . . ?
N2 C10 C9 121.2(4) . . ?
N2 C10 C11 116.4(3) . . ?
C9 C10 C11 122.4(4) . . ?
N3 C11 C12 121.2(4) . . ?
N3 C11 C10 116.3(4) . . ?
C12 C11 C10 122.5(4) . . ?
C11 C12 C13 119.1(4) . . ?
C11 C12 H12A 120.4 . . ?
C13 C12 H12A 120.4 . . ?
C14 C13 C12 119.3(4) . . ?
C14 C13 H13A 120.4 . . ?
C12 C13 H13A 120.4 . . ?
C15 C14 C13 118.7(4) . . ?
C15 C14 H14A 120.7 . . ?
C13 C14 H14A 120.7 . . ?
N3 C15 C14 123.3(4) . . ?
N3 C15 H15A 118.4 . . ?
C14 C15 H15A 118.4 . . ?
C21 C16 C17 117.8(4) . . ?
C21 C16 C8 121.4(4) . . ?
C17 C16 C8 120.8(4) . . ?
C18 C17 C16 121.1(4) . . ?
C18 C17 H17A 119.5 . . ?
C16 C17 H17A 119.5 . . ?
C19 C18 C17 119.6(4) . . ?
C19 C18 H18A 120.2 . . ?
C17 C18 H18A 120.2 . . ?
C20 C19 C18 120.6(4) . . ?
C20 C19 I1 119.4(3) . . ?
C18 C19 I1 120.0(3) . . ?
C19 C20 C21 119.3(4) . . ?
C19 C20 H20A 120.3 . . ?
C21 C20 H20A 120.3 . . ?
C16 C21 C20 121.5(4) . . ?
C16 C21 H21A 119.2 . . ?
C20 C21 H21A 119.2 . . ?
N4 C22 C23 178.7(7) . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N4 2.158(4) . ?
Ag1 N2 2.350(3) . ?
Ag1 N1 2.394(4) . ?
Ag1 N3 2.410(4) . ?
I1 C19 2.097(4) . ?
Sb1 F5 1.836(3) . ?
Sb1 F4 1.841(3) . ?
Sb1 F1 1.843(4) . ?
Sb1 F2 1.845(3) . ?
Sb1 F6 1.852(3) . ?
Sb1 F3 1.874(4) . ?
N1 C1 1.331(6) . ?
N1 C5 1.342(5) . ?
N2 C6 1.334(5) . ?
N2 C10 1.338(5) . ?
N3 C15 1.336(5) . ?
N3 C11 1.341(5) . ?
N4 C22 1.114(6) . ?
C1 C2 1.356(8) . ?
C1 H1A 0.9300 . ?
C2 C3 1.358(7) . ?
C2 H2A 0.9300 . ?
C3 C4 1.373(6) . ?
C3 H3A 0.9300 . ?
C4 C5 1.365(6) . ?
C4 H4A 0.9300 . ?
C5 C6 1.501(5) . ?
C6 C7 1.386(5) . ?
C7 C8 1.396(5) . ?
C7 H7A 0.9300 . ?
C8 C9 1.401(5) . ?
C8 C16 1.478(5) . ?
C9 C10 1.384(5) . ?
C9 H9A 0.9300 . ?
C10 C11 1.495(5) . ?
C11 C12 1.377(6) . ?
C12 C13 1.385(6) . ?
C12 H12A 0.9300 . ?
C13 C14 1.361(7) . ?
C13 H13A 0.9300 . ?
C14 C15 1.359(7) . ?
C14 H14A 0.9300 . ?
C15 H15A 0.9300 . ?
C16 C21 1.381(6) . ?
C16 C17 1.398(5) . ?
C17 C18 1.383(5) . ?
C17 H17A 0.9300 . ?
C18 C19 1.376(6) . ?
C18 H18A 0.9300 . ?
C19 C20 1.375(6) . ?
C20 C21 1.388(6) . ?
C20 H20A 0.9300 . ?
C21 H21A 0.9300 . ?
C22 C23 1.446(7) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 0.3(8) . . . . ?
Ag1 N1 C1 C2 177.6(4) . . . . ?
N1 C1 C2 C3 -2.5(9) . . . . ?
C1 C2 C3 C4 2.7(9) . . . . ?
C2 C3 C4 C5 -1.0(8) . . . . ?
C1 N1 C5 C4 1.6(7) . . . . ?
Ag1 N1 C5 C4 -175.9(3) . . . . ?
C1 N1 C5 C6 -177.2(4) . . . . ?
Ag1 N1 C5 C6 5.3(5) . . . . ?
C3 C4 C5 N1 -1.2(7) . . . . ?
C3 C4 C5 C6 177.5(5) . . . . ?
C10 N2 C6 C7 -3.6(6) . . . . ?
Ag1 N2 C6 C7 -176.4(3) . . . . ?
C10 N2 C6 C5 177.5(3) . . . . ?
Ag1 N2 C6 C5 4.7(5) . . . . ?
N1 C5 C6 N2 -6.6(6) . . . . ?
C4 C5 C6 N2 174.6(4) . . . . ?
N1 C5 C6 C7 174.5(4) . . . . ?
C4 C5 C6 C7 -4.3(7) . . . . ?
N2 C6 C7 C8 3.3(6) . . . . ?
C5 C6 C7 C8 -177.8(4) . . . . ?
C6 C7 C8 C9 -0.5(6) . . . . ?
C6 C7 C8 C16 179.7(4) . . . . ?
C7 C8 C9 C10 -2.0(6) . . . . ?
C16 C8 C9 C10 177.8(4) . . . . ?
C6 N2 C10 C9 1.0(6) . . . . ?
Ag1 N2 C10 C9 173.8(3) . . . . ?
C6 N2 C10 C11 179.7(3) . . . . ?
Ag1 N2 C10 C11 -7.5(5) . . . . ?
C8 C9 C10 N2 1.9(6) . . . . ?
C8 C9 C10 C11 -176.8(4) . . . . ?
C15 N3 C11 C12 0.0(6) . . . . ?
Ag1 N3 C11 C12 169.6(3) . . . . ?
C15 N3 C11 C10 -179.6(4) . . . . ?
Ag1 N3 C11 C10 -10.0(5) . . . . ?
N2 C10 C11 N3 11.6(5) . . . . ?
C9 C10 C11 N3 -169.7(4) . . . . ?
N2 C10 C11 C12 -168.0(4) . . . . ?
C9 C10 C11 C12 10.8(6) . . . . ?
N3 C11 C12 C13 -0.5(7) . . . . ?
C10 C11 C12 C13 179.1(4) . . . . ?
C11 C12 C13 C14 1.9(7) . . . . ?
C12 C13 C14 C15 -2.7(8) . . . . ?
C11 N3 C15 C14 -0.9(7) . . . . ?
Ag1 N3 C15 C14 -169.9(4) . . . . ?
C13 C14 C15 N3 2.3(8) . . . . ?
C7 C8 C16 C21 -20.1(7) . . . . ?
C9 C8 C16 C21 160.1(4) . . . . ?
C7 C8 C16 C17 160.5(4) . . . . ?
C9 C8 C16 C17 -19.3(6) . . . . ?
C21 C16 C17 C18 -0.8(6) . . . . ?
C8 C16 C17 C18 178.6(4) . . . . ?
C16 C17 C18 C19 -0.4(7) . . . . ?
C17 C18 C19 C20 2.0(7) . . . . ?
C17 C18 C19 I1 -178.5(3) . . . . ?
C18 C19 C20 C21 -2.4(8) . . . . ?
I1 C19 C20 C21 178.1(4) . . . . ?
C17 C16 C21 C20 0.4(8) . . . . ?
C8 C16 C21 C20 -179.0(5) . . . . ?
C19 C20 C21 C16 1.1(9) . . . . ?
