#------------------------------------------------------------------------------
#$Date: 2016-02-18 14:25:00 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176728 $
#$URL: svn://www.crystallography.net/cod/cif/8/10/22/8102212.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8102212
loop_
_publ_author_name
'Hamid R. Khavasi'
'Vahid Amani'
'Nasser Safari'
_publ_section_title
;
 Refinement of the crystal structure of 1,10-phenanthrolinium
 tetrachloro(1,10-phenanthroline)ferrate(III),
 (C12H9N2)[FeCl4(C12H8N2)]
;
_journal_issue                   1
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              41
_journal_volume                  223
_journal_year                    2008
_chemical_formula_structural     (C12H9N2)[FeCl4(C12H8N2)]
_chemical_formula_sum            'C24 H17 Cl4 Fe N4'
_chemical_formula_weight         559.07
_chemical_name_systematic
;
1,10-phenanthrolinium tetrachloro-1,10-phenanthroline-ferrate(III)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                111.08(2)
_cell_angle_beta                 96.22(2)
_cell_angle_gamma                93.68(3)
_cell_formula_units_Z            2
_cell_length_a                   8.694(3)
_cell_length_b                   11.306(4)
_cell_length_c                   12.802(4)
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.96
_cell_measurement_theta_min      1.72
_cell_volume                     1160.0(7)
_computing_cell_refinement       'X-Area 1.31 (Stoe & Cie GmbH, 2005)'
_computing_data_collection       'X-Area 1.31 (Stoe & Cie GmbH, 2005)'
_computing_data_reduction        'X-Area 1.31 (Stoe & Cie GmbH, 2005)'
_computing_molecular_graphics    'X-Step32 1.07e (Stoe & Cie GmbH, 2000)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean '0.15 mm'
_diffrn_measured_fraction_theta_full 0.98
_diffrn_measured_fraction_theta_max 0.908
_diffrn_measurement_device_type  'Stoe IPDS II'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0167
_diffrn_reflns_av_sigmaI/netI    0.0161
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            8633
_diffrn_reflns_theta_full        27.96
_diffrn_reflns_theta_max         27.96
_diffrn_reflns_theta_min         1.72
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.132
_exptl_absorpt_correction_T_max  0.800
_exptl_absorpt_correction_T_min  0.638
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'shape of crystal determined optically'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.601
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             566
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.236
_refine_diff_density_min         -0.222
_refine_diff_density_rms         0.039
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     366
_refine_ls_number_reflns         5583
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0310
_refine_ls_R_factor_gt           0.0268
_refine_ls_shift/su_max          0.013
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0345P)²+0.4038P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0682
_refine_ls_wR_factor_ref         0.0702
_reflns_number_gt                4582
_reflns_number_total             5583
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            1267-2141.cff
_cod_data_source_block           kh50-abs1
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_cell_volume        1159.9(6)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               8102212
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Fe1 Fe 0.77764(3) 0.83592(2) 0.203781(18) 0.03018(7) Uani 1 2 i d . . .
C1 C 1.0613(2) 0.97387(16) 0.13885(14) 0.0356(3) Uani 1 2 i d . . .
H1 H 1.054(2) 1.0426(19) 0.2071(16) 0.036(5) Uiso 1 2 i d . . .
C2 C 1.1729(2) 0.98730(19) 0.07164(16) 0.0403(4) Uani 1 2 i d . . .
H2 H 1.237(3) 1.065(2) 0.0951(17) 0.046(5) Uiso 1 2 i d . . .
C3 C 1.1838(2) 0.88894(19) -0.02654(16) 0.0417(4) Uani 1 2 i d . . .
H3 H 1.256(3) 0.899(2) -0.0734(18) 0.053(6) Uiso 1 2 i d . . .
C4 C 1.0849(2) 0.77475(17) -0.05743(14) 0.0374(3) Uani 1 2 i d . . .
C5 C 1.0871(2) 0.6657(2) -0.15906(16) 0.0467(4) Uani 1 2 i d . . .
H5 H 1.158(3) 0.675(2) -0.2078(19) 0.054(6) Uiso 1 2 i d . . .
C6 C 0.9950(2) 0.55636(19) -0.18207(15) 0.0470(4) Uani 1 2 i d . . .
H6 H 0.997(3) 0.486(2) -0.2463(19) 0.052(6) Uiso 1 2 i d . . .
C7 C 0.8902(2) 0.54456(16) -0.10563(14) 0.0375(3) Uani 1 2 i d . . .
C8 C 0.7966(2) 0.43178(17) -0.12174(16) 0.0436(4) Uani 1 2 i d . . .
H8 H 0.794(2) 0.359(2) -0.1856(18) 0.047(6) Uiso 1 2 i d . . .
C9 C 0.7037(2) 0.42885(17) -0.04322(17) 0.0435(4) Uani 1 2 i d . . .
H9 H 0.637(3) 0.357(2) -0.0518(19) 0.055(6) Uiso 1 2 i d . . .
C10 C 0.7028(2) 0.54000(16) 0.05292(16) 0.0386(4) Uani 1 2 i d . . .
H10 H 0.640(2) 0.545(2) 0.1116(18) 0.046(5) Uiso 1 2 i d . . .
C11 C 0.88240(18) 0.65128(15) -0.00697(13) 0.0317(3) Uani 1 2 i d . . .
C12 C 0.97888(18) 0.76778(15) 0.01631(13) 0.0310(3) Uani 1 2 i d . . .
C13 C 0.7715(2) 0.93163(18) 0.54233(16) 0.0447(4) Uani 1 2 i d . . .
H13 H 0.828(3) 0.961(2) 0.498(2) 0.058(6) Uiso 1 2 i d . . .
C14 C 0.6807(2) 1.0055(2) 0.61699(17) 0.0493(4) Uani 1 2 i d . . .
H14 H 0.676(3) 1.093(2) 0.627(2) 0.060(7) Uiso 1 2 i d . . .
C15 C 0.6011(2) 0.9536(2) 0.67925(17) 0.0489(4) Uani 1 2 i d . . .
H15 H 0.542(3) 1.002(2) 0.7298(19) 0.055(6) Uiso 1 2 i d . . .
C16 C 0.6102(2) 0.82544(19) 0.66723(15) 0.0424(4) Uani 1 2 i d . . .
C17 C 0.5323(3) 0.7650(3) 0.73142(19) 0.0578(5) Uani 1 2 i d . . .
H17 H 0.474(3) 0.814(2) 0.785(2) 0.065(7) Uiso 1 2 i d . . .
C18 C 0.5431(3) 0.6422(3) 0.7149(2) 0.0615(6) Uani 1 2 i d . . .
H18 H 0.493(3) 0.600(3) 0.754(2) 0.084(9) Uiso 1 2 i d . . .
C19 C 0.6323(2) 0.5653(2) 0.63302(17) 0.0486(4) Uani 1 2 i d . . .
C20 C 0.6438(3) 0.4340(2) 0.6096(2) 0.0636(6) Uani 1 2 i d . . .
H20 H 0.592(4) 0.399(3) 0.650(3) 0.091(9) Uiso 1 2 i d . . .
C21 C 0.7317(3) 0.3695(2) 0.5313(2) 0.0649(6) Uani 1 2 i d . . .
H21 H 0.747(3) 0.280(3) 0.514(2) 0.084(9) Uiso 1 2 i d . . .
C22 C 0.8096(3) 0.4347(2) 0.4746(2) 0.0599(5) Uani 1 2 i d . . .
H22 H 0.878(3) 0.392(3) 0.420(2) 0.080(8) Uiso 1 2 i d . . .
C23 C 0.7134(2) 0.62100(18) 0.57006(14) 0.0406(4) Uani 1 2 i d . . .
C24 C 0.70112(19) 0.75314(17) 0.58923(13) 0.0363(3) Uani 1 2 i d . . .
N1 N 0.96620(15) 0.86769(12) 0.11261(11) 0.0302(3) Uani 1 2 i d . . .
N2 N 0.78828(16) 0.64851(12) 0.07041(11) 0.0322(3) Uani 1 2 i d . . .
N3 N 0.77900(18) 0.81084(14) 0.53055(12) 0.0391(3) Uani 1 2 i d . . .
H3A H 0.826(3) 0.767(2) 0.484(2) 0.057(7) Uiso 1 2 i d . . .
N4 N 0.8014(2) 0.55702(16) 0.49134(14) 0.0503(4) Uani 1 2 i d . . .
Cl1 Cl 0.58345(5) 0.75830(4) 0.27977(4) 0.04280(10) Uani 1 2 i d . . .
Cl2 Cl 0.80834(5) 1.05072(4) 0.31996(4) 0.04356(11) Uani 1 2 i d . . .
Cl3 Cl 0.59560(5) 0.86293(4) 0.06586(4) 0.04140(10) Uani 1 2 i d . . .
Cl4 Cl 0.97423(5) 0.78315(4) 0.32216(3) 0.03781(10) Uani 1 2 i d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Fe1 N2 75.04(6) . . ?
N1 Fe1 Cl1 168.12(4) . . ?
N2 Fe1 Cl1 93.39(5) . . ?
N1 Fe1 Cl2 91.02(5) . . ?
N2 Fe1 Cl2 165.86(4) . . ?
Cl1 Fe1 Cl2 100.64(3) . . ?
N1 Fe1 Cl3 89.45(4) . . ?
N2 Fe1 Cl3 83.70(5) . . ?
Cl1 Fe1 Cl3 92.00(3) . . ?
Cl2 Fe1 Cl3 93.98(3) . . ?
N1 Fe1 Cl4 86.28(4) . . ?
N2 Fe1 Cl4 88.27(5) . . ?
Cl1 Fe1 Cl4 90.74(3) . . ?
Cl2 Fe1 Cl4 93.26(3) . . ?
Cl3 Fe1 Cl4 171.655(17) . . ?
N1 C1 C2 122.86(16) . . ?
N1 C1 H1 117.8(12) . . ?
C2 C1 H1 119.3(12) . . ?
C3 C2 C1 119.44(18) . . ?
C3 C2 H2 121.9(12) . . ?
C1 C2 H2 118.7(12) . . ?
C2 C3 C4 119.44(15) . . ?
C2 C3 H3 119.4(14) . . ?
C4 C3 H3 121.1(14) . . ?
C3 C4 C12 117.56(16) . . ?
C3 C4 C5 123.73(16) . . ?
C12 C4 C5 118.70(17) . . ?
C6 C5 C4 121.38(17) . . ?
C6 C5 H5 122.2(14) . . ?
C4 C5 H5 116.4(14) . . ?
C5 C6 C7 121.12(17) . . ?
C5 C6 H6 121.6(14) . . ?
C7 C6 H6 117.3(14) . . ?
C8 C7 C11 117.27(16) . . ?
C8 C7 C6 124.05(16) . . ?
C11 C7 C6 118.67(17) . . ?
C9 C8 C7 119.86(16) . . ?
C9 C8 H8 118.3(13) . . ?
C7 C8 H8 121.8(13) . . ?
C8 C9 C10 119.16(18) . . ?
C8 C9 H9 122.8(14) . . ?
C10 C9 H9 118.0(14) . . ?
N2 C10 C9 122.69(17) . . ?
N2 C10 H10 113.7(13) . . ?
C9 C10 H10 123.7(13) . . ?
N2 C11 C7 122.73(15) . . ?
N2 C11 C12 117.27(13) . . ?
C7 C11 C12 119.99(14) . . ?
N1 C12 C4 122.49(15) . . ?
N1 C12 C11 117.44(13) . . ?
C4 C12 C11 120.04(14) . . ?
N3 C13 C14 119.94(18) . . ?
N3 C13 H13 116.3(15) . . ?
C14 C13 H13 123.8(15) . . ?
C15 C14 C13 119.45(19) . . ?
C15 C14 H14 120.3(14) . . ?
C13 C14 H14 120.2(14) . . ?
C14 C15 C16 120.50(17) . . ?
C14 C15 H15 120.2(14) . . ?
C16 C15 H15 119.3(14) . . ?
C24 C16 C15 118.30(16) . . ?
C24 C16 C17 118.05(19) . . ?
C15 C16 C17 123.66(18) . . ?
C18 C17 C16 121.0(2) . . ?
C18 C17 H17 121.5(15) . . ?
C16 C17 H17 117.6(16) . . ?
C17 C18 C19 121.87(18) . . ?
C17 C18 H18 123.2(17) . . ?
C19 C18 H18 114.9(18) . . ?
C23 C19 C20 116.6(2) . . ?
C23 C19 C18 119.23(19) . . ?
C20 C19 C18 124.2(2) . . ?
C21 C20 C19 120.0(2) . . ?
C21 C20 H20 124(2) . . ?
C19 C20 H20 116(2) . . ?
C20 C21 C22 118.7(2) . . ?
C20 C21 H21 123.3(17) . . ?
C22 C21 H21 117.9(17) . . ?
N4 C22 C21 124.2(2) . . ?
N4 C22 H22 114.9(17) . . ?
C21 C22 H22 120.9(17) . . ?
N4 C23 C19 123.83(18) . . ?
N4 C23 C24 117.98(15) . . ?
C19 C23 C24 118.18(17) . . ?
N3 C24 C16 118.39(16) . . ?
N3 C24 C23 119.94(15) . . ?
C16 C24 C23 121.67(16) . . ?
C1 N1 C12 118.17(14) . . ?
C1 N1 Fe1 127.06(11) . . ?
C12 N1 Fe1 114.70(11) . . ?
C10 N2 C11 118.28(14) . . ?
C10 N2 Fe1 126.98(11) . . ?
C11 N2 Fe1 114.37(10) . . ?
C13 N3 C24 123.41(16) . . ?
C13 N3 H3A 119.8(17) . . ?
C24 N3 H3A 116.7(17) . . ?
C22 N4 C23 116.71(19) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Fe1 N1 2.1954(14) . ?
Fe1 N2 2.2069(15) . ?
Fe1 Cl1 2.3123(7) . ?
Fe1 Cl2 2.3266(10) . ?
Fe1 Cl3 2.3578(8) . ?
Fe1 Cl4 2.4069(8) . ?
C1 N1 1.327(2) . ?
C1 C2 1.400(2) . ?
C1 H1 0.950(19) . ?
C2 C3 1.364(3) . ?
C2 H2 0.94(2) . ?
C3 C4 1.407(3) . ?
C3 H3 0.94(2) . ?
C4 C12 1.407(2) . ?
C4 C5 1.438(3) . ?
C5 C6 1.347(3) . ?
C5 H5 0.95(2) . ?
C6 C7 1.441(3) . ?
C6 H6 0.92(2) . ?
C7 C8 1.404(3) . ?
C7 C11 1.410(2) . ?
C8 C9 1.364(3) . ?
C8 H8 0.93(2) . ?
C9 C10 1.409(3) . ?
C9 H9 0.93(2) . ?
C10 N2 1.325(2) . ?
C10 H10 0.96(2) . ?
C11 N2 1.3588(19) . ?
C11 C12 1.431(2) . ?
C12 N1 1.361(2) . ?
C13 N3 1.326(2) . ?
C13 C14 1.381(3) . ?
C13 H13 0.91(2) . ?
C14 C15 1.365(3) . ?
C14 H14 0.96(2) . ?
C15 C16 1.409(3) . ?
C15 H15 0.92(2) . ?
C16 C24 1.399(2) . ?
C16 C17 1.438(3) . ?
C17 C18 1.337(4) . ?
C17 H17 0.93(2) . ?
C18 C19 1.436(3) . ?
C18 H18 0.93(3) . ?
C19 C23 1.405(2) . ?
C19 C20 1.417(3) . ?
C20 C21 1.354(4) . ?
C20 H20 0.89(3) . ?
C21 C22 1.399(4) . ?
C21 H21 0.98(3) . ?
C22 N4 1.328(3) . ?
C22 H22 0.97(3) . ?
C23 N4 1.356(2) . ?
C23 C24 1.437(3) . ?
C24 N3 1.362(2) . ?
N3 H3A 0.80(2) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C3 1.4(3) . . . . ?
C1 C2 C3 C4 -1.3(3) . . . . ?
C2 C3 C4 C12 -0.4(3) . . . . ?
C2 C3 C4 C5 179.97(17) . . . . ?
C3 C4 C5 C6 176.78(18) . . . . ?
C12 C4 C5 C6 -2.8(3) . . . . ?
C4 C5 C6 C7 0.1(3) . . . . ?
C5 C6 C7 C8 -176.86(18) . . . . ?
C5 C6 C7 C11 1.7(3) . . . . ?
C11 C7 C8 C9 -0.2(3) . . . . ?
C6 C7 C8 C9 178.38(17) . . . . ?
C7 C8 C9 C10 0.4(3) . . . . ?
C8 C9 C10 N2 0.4(3) . . . . ?
C8 C7 C11 N2 -0.6(2) . . . . ?
C6 C7 C11 N2 -179.29(15) . . . . ?
C8 C7 C11 C12 177.86(15) . . . . ?
C6 C7 C11 C12 -0.8(2) . . . . ?
C3 C4 C12 N1 2.2(2) . . . . ?
C5 C4 C12 N1 -178.18(15) . . . . ?
C3 C4 C12 C11 -175.96(15) . . . . ?
C5 C4 C12 C11 3.7(2) . . . . ?
N2 C11 C12 N1 -1.6(2) . . . . ?
C7 C11 C12 N1 179.88(14) . . . . ?
N2 C11 C12 C4 176.65(14) . . . . ?
C7 C11 C12 C4 -1.9(2) . . . . ?
N3 C13 C14 C15 0.9(3) . . . . ?
C13 C14 C15 C16 -0.4(3) . . . . ?
C14 C15 C16 C24 -0.7(3) . . . . ?
C14 C15 C16 C17 178.7(2) . . . . ?
C24 C16 C17 C18 -1.7(3) . . . . ?
C15 C16 C17 C18 178.8(2) . . . . ?
C16 C17 C18 C19 0.0(4) . . . . ?
C17 C18 C19 C23 1.4(3) . . . . ?
C17 C18 C19 C20 -178.0(2) . . . . ?
C23 C19 C20 C21 1.1(3) . . . . ?
C18 C19 C20 C21 -179.6(2) . . . . ?
C19 C20 C21 C22 -0.2(4) . . . . ?
C20 C21 C22 N4 -1.0(4) . . . . ?
C20 C19 C23 N4 -1.0(3) . . . . ?
C18 C19 C23 N4 179.62(19) . . . . ?
C20 C19 C23 C24 178.36(18) . . . . ?
C18 C19 C23 C24 -1.1(3) . . . . ?
C15 C16 C24 N3 1.4(3) . . . . ?
C17 C16 C24 N3 -178.07(18) . . . . ?
C15 C16 C24 C23 -178.48(18) . . . . ?
C17 C16 C24 C23 2.0(3) . . . . ?
N4 C23 C24 N3 -1.2(3) . . . . ?
C19 C23 C24 N3 179.45(17) . . . . ?
N4 C23 C24 C16 178.71(17) . . . . ?
C19 C23 C24 C16 -0.7(3) . . . . ?
C2 C1 N1 C12 0.3(2) . . . . ?
C2 C1 N1 Fe1 -176.28(12) . . . . ?
C4 C12 N1 C1 -2.1(2) . . . . ?
C11 C12 N1 C1 176.06(14) . . . . ?
C4 C12 N1 Fe1 174.88(12) . . . . ?
C11 C12 N1 Fe1 -6.93(17) . . . . ?
N2 Fe1 N1 C1 -174.66(14) . . . . ?
Cl1 Fe1 N1 C1 -161.19(14) . . . . ?
Cl2 Fe1 N1 C1 7.74(13) . . . . ?
Cl3 Fe1 N1 C1 101.71(13) . . . . ?
Cl4 Fe1 N1 C1 -85.46(13) . . . . ?
N2 Fe1 N1 C12 8.64(10) . . . . ?
Cl1 Fe1 N1 C12 22.1(3) . . . . ?
Cl2 Fe1 N1 C12 -168.95(10) . . . . ?
Cl3 Fe1 N1 C12 -74.99(11) . . . . ?
Cl4 Fe1 N1 C12 97.84(11) . . . . ?
C9 C10 N2 C11 -1.2(3) . . . . ?
C9 C10 N2 Fe1 171.51(13) . . . . ?
C7 C11 N2 C10 1.3(2) . . . . ?
C12 C11 N2 C10 -177.21(14) . . . . ?
C7 C11 N2 Fe1 -172.29(12) . . . . ?
C12 C11 N2 Fe1 9.21(17) . . . . ?
N1 Fe1 N2 C10 177.62(15) . . . . ?
Cl1 Fe1 N2 C10 0.38(14) . . . . ?
Cl2 Fe1 N2 C10 -172.49(12) . . . . ?
Cl3 Fe1 N2 C10 -91.26(14) . . . . ?
Cl4 Fe1 N2 C10 91.02(14) . . . . ?
N1 Fe1 N2 C11 -9.46(10) . . . . ?
Cl1 Fe1 N2 C11 173.30(10) . . . . ?
Cl2 Fe1 N2 C11 0.4(2) . . . . ?
Cl3 Fe1 N2 C11 81.66(11) . . . . ?
Cl4 Fe1 N2 C11 -96.07(11) . . . . ?
C14 C13 N3 C24 -0.2(3) . . . . ?
C16 C24 N3 C13 -1.0(3) . . . . ?
C23 C24 N3 C13 178.93(18) . . . . ?
C21 C22 N4 C23 1.1(4) . . . . ?
C19 C23 N4 C22 -0.1(3) . . . . ?
C24 C23 N4 C22 -179.41(19) . . . . ?
