#------------------------------------------------------------------------------
#$Date: 2016-02-18 14:25:00 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176728 $
#$URL: svn://www.crystallography.net/cod/cif/8/10/22/8102236.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8102236
loop_
_publ_author_name
'Qiong-Hua Jin'
'Ke-Yi Hu'
'Li-Min Chen'
'Jing-Jing Sun'
'Liang Yang'
'Pei-Zhou Li'
_publ_section_title
;
 Crystal structure of
 tetrakis(μ-thiocyanato)bis(μ-(bis(diphenylphosphino)methane-P,P'))tetrasilver(I),
 Ag4(SCN)4(C25H22P2)2
;
_journal_issue                   1
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              79
_journal_volume                  223
_journal_year                    2008
_chemical_formula_structural     Ag4(SCN)4(C25H22P2)2
_chemical_formula_sum            'C54 H44 Ag4 N4 P4 S4'
_chemical_formula_weight         1432.57
_chemical_name_systematic
; 
tetrakis(μ-thiocyanato)bis(μ-(bis(diphenylphosphino)methane-P,P'))-
tetrasilver(I)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.722(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   12.4531(4)
_cell_length_b                   16.7286(5)
_cell_length_c                   13.6948(4)
_cell_measurement_reflns_used    7966
_cell_measurement_temperature    273(2)
_cell_measurement_theta_max      24.75
_cell_measurement_theta_min      2.69
_cell_volume                     2819.95(15)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      273(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker SMART CCD'
_diffrn_measurement_method       phi/omega
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0288
_diffrn_reflns_av_sigmaI/netI    0.0294
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            27238
_diffrn_reflns_theta_full        28.31
_diffrn_reflns_theta_max         28.31
_diffrn_reflns_theta_min         1.94
_exptl_absorpt_coefficient_mu    1.669
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.687
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1416
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.376
_refine_diff_density_min         -0.466
_refine_diff_density_rms         0.060
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.089
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     316
_refine_ls_number_reflns         7002
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.089
_refine_ls_R_factor_all          0.0491
_refine_ls_R_factor_gt           0.0307
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0246P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0571
_refine_ls_wR_factor_ref         0.0621
_reflns_number_gt                5308
_reflns_number_total             7002
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            1267-2180.cff
_cod_data_source_block           070628b_0m
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P12(1)/n1
_cod_database_code               8102236
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_Wyckoff_symbol
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag2 Ag 0.397106(16) 0.071673(11) 0.167146(14) 0.05432(7) Uani 1 4 e d . . .
Ag1 Ag 0.368539(17) 0.156944(12) -0.033087(14) 0.05669(7) Uani 1 4 e d . . .
P1 P 0.35099(5) 0.27356(3) 0.06396(4) 0.03710(13) Uani 1 4 e d . . .
P2 P 0.28903(5) 0.17190(3) 0.23293(4) 0.03934(14) Uani 1 4 e d . . .
C1 C 0.48311(18) 0.29699(13) 0.13400(16) 0.0416(5) Uani 1 4 e d . . .
C2 C 0.5734(2) 0.27184(17) 0.0956(2) 0.0652(7) Uani 1 4 e d . . .
H2 H 0.5651 0.2440 0.0362 0.078 Uiso 1 4 e calc R . .
C5 C 0.6014(3) 0.35104(19) 0.2728(2) 0.0779(9) Uani 1 4 e d . . .
H5 H 0.6108 0.3771 0.3335 0.094 Uiso 1 4 e calc R . .
C4 C 0.6894(3) 0.3271(2) 0.2327(3) 0.0886(11) Uani 1 4 e d . . .
H4 H 0.7589 0.3378 0.2654 0.106 Uiso 1 4 e calc R . .
C3 C 0.6763(2) 0.2879(2) 0.1453(3) 0.0937(11) Uani 1 4 e d . . .
H3 H 0.7370 0.2717 0.1183 0.112 Uiso 1 4 e calc R . .
C7 C 0.29969(19) 0.36479(14) 0.00087(16) 0.0435(5) Uani 1 4 e d . . .
C8 C 0.2243(2) 0.35748(17) -0.08269(19) 0.0616(7) Uani 1 4 e d . . .
H8 H 0.2032 0.3069 -0.1063 0.074 Uiso 1 4 e calc R . .
C13 C 0.25867(18) 0.26108(13) 0.15452(16) 0.0429(5) Uani 1 4 e d . . .
H13A H 0.1848 0.2572 0.1200 0.052 Uiso 1 4 e calc R . .
H13B H 0.2629 0.3081 0.1963 0.052 Uiso 1 4 e calc R . .
C21 C 0.4147(2) 0.15848(16) 0.41454(19) 0.0566(7) Uani 1 4 e d . . .
H21 H 0.4325 0.1090 0.3905 0.068 Uiso 1 4 e calc R . .
C14 C 0.15343(18) 0.13453(14) 0.24293(16) 0.0428(5) Uani 1 4 e d . . .
C20 C 0.34396(18) 0.20812(14) 0.35571(16) 0.0444(5) Uani 1 4 e d . . .
C19 C 0.0890(2) 0.16602(19) 0.3058(2) 0.0716(9) Uani 1 4 e d . . .
H19 H 0.1154 0.2069 0.3489 0.086 Uiso 1 4 e calc R . .
C15 C 0.1116(2) 0.07470(17) 0.1804(2) 0.0684(8) Uani 1 4 e d . . .
H15 H 0.1545 0.0520 0.1377 0.082 Uiso 1 4 e calc R . .
C25 C 0.3193(2) 0.28210(16) 0.39370(19) 0.0597(7) Uani 1 4 e d . . .
H25 H 0.2708 0.3162 0.3557 0.072 Uiso 1 4 e calc R . .
C12 C 0.3312(3) 0.43992(17) 0.0330(2) 0.0883(11) Uani 1 4 e d . . .
H12 H 0.3829 0.4463 0.0891 0.106 Uiso 1 4 e calc R . .
C6 C 0.4981(2) 0.33659(16) 0.2236(2) 0.0620(7) Uani 1 4 e d . . .
H6 H 0.4381 0.3537 0.2509 0.074 Uiso 1 4 e calc R . .
C23 C 0.4362(2) 0.2546(2) 0.5446(2) 0.0732(9) Uani 1 4 e d . . .
H23 H 0.4677 0.2703 0.6077 0.088 Uiso 1 4 e calc R . .
C22 C 0.4596(2) 0.1815(2) 0.5091(2) 0.0711(8) Uani 1 4 e d . . .
H22 H 0.5059 0.1469 0.5485 0.085 Uiso 1 4 e calc R . .
C10 C 0.2098(3) 0.4982(2) -0.0987(3) 0.0964(12) Uani 1 4 e d . . .
H10 H 0.1784 0.5431 -0.1313 0.116 Uiso 1 4 e calc R . .
C9 C 0.1790(2) 0.4245(2) -0.1324(2) 0.0808(10) Uani 1 4 e d . . .
H9 H 0.1276 0.4188 -0.1888 0.097 Uiso 1 4 e calc R . .
C24 C 0.3662(2) 0.3051(2) 0.4871(2) 0.0738(8) Uani 1 4 e d . . .
H24 H 0.3504 0.3550 0.5112 0.089 Uiso 1 4 e calc R . .
C11 C 0.2860(4) 0.5069(2) -0.0181(3) 0.1231(16) Uani 1 4 e d . . .
H11 H 0.3083 0.5578 0.0035 0.148 Uiso 1 4 e calc R . .
C17 C -0.0555(3) 0.0778(2) 0.2425(3) 0.0847(10) Uani 1 4 e d . . .
H17 H -0.1254 0.0584 0.2431 0.102 Uiso 1 4 e calc R . .
C16 C 0.0066(3) 0.0472(2) 0.1793(3) 0.0842(10) Uani 1 4 e d . . .
H16 H -0.0211 0.0076 0.1348 0.101 Uiso 1 4 e calc R . .
C18 C -0.0154(3) 0.1372(2) 0.3054(3) 0.0938(11) Uani 1 4 e d . . .
H18 H -0.0585 0.1587 0.3486 0.113 Uiso 1 4 e calc R . .
S1 S 0.28147(5) 0.01815(4) -0.02771(5) 0.04858(15) Uani 1 4 e d . . .
S2 S 0.39265(6) -0.06270(4) 0.26263(5) 0.05556(17) Uani 1 4 e d . . .
C26 C 0.37956(18) -0.02959(13) -0.07418(16) 0.0397(5) Uani 1 4 e d . . .
C27 C 0.4727(2) -0.10946(14) 0.19619(17) 0.0465(6) Uani 1 4 e d . . .
N2 N 0.5291(2) -0.14215(13) 0.15059(18) 0.0665(6) Uani 1 4 e d . . .
N1 N 0.44691(16) -0.06251(12) -0.10639(14) 0.0493(5) Uani 1 4 e d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag2 P2 139.00(5) 3_655 . ?
N1 Ag2 S2 102.35(5) 3_655 . ?
P2 Ag2 S2 110.93(2) . . ?
N1 Ag2 Ag1 71.80(5) 3_655 . ?
P2 Ag2 Ag1 90.863(15) . . ?
S2 Ag2 Ag1 147.412(17) . . ?
N2 Ag1 P1 127.38(6) 3_655 . ?
N2 Ag1 S1 102.24(6) 3_655 . ?
P1 Ag1 S1 130.36(2) . . ?
N2 Ag1 Ag2 126.67(6) 3_655 . ?
P1 Ag1 Ag2 83.701(15) . . ?
S1 Ag1 Ag2 62.975(15) . . ?
C1 P1 C7 107.10(11) . . ?
C1 P1 C13 106.20(11) . . ?
C7 P1 C13 101.91(10) . . ?
C1 P1 Ag1 108.53(8) . . ?
C7 P1 Ag1 118.39(8) . . ?
C13 P1 Ag1 113.86(8) . . ?
C20 P2 C14 105.49(10) . . ?
C20 P2 C13 106.48(11) . . ?
C14 P2 C13 102.15(10) . . ?
C20 P2 Ag2 115.10(8) . . ?
C14 P2 Ag2 111.44(8) . . ?
C13 P2 Ag2 114.98(7) . . ?
C2 C1 C6 118.5(2) . . ?
C2 C1 P1 117.33(19) . . ?
C6 C1 P1 124.16(19) . . ?
C1 C2 C3 120.2(3) . . ?
C1 C2 H2 119.9 . . ?
C3 C2 H2 119.9 . . ?
C4 C5 C6 120.0(3) . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C3 C4 C5 120.3(3) . . ?
C3 C4 H4 119.8 . . ?
C5 C4 H4 119.8 . . ?
C4 C3 C2 120.5(3) . . ?
C4 C3 H3 119.8 . . ?
C2 C3 H3 119.8 . . ?
C12 C7 C8 118.5(2) . . ?
C12 C7 P1 123.6(2) . . ?
C8 C7 P1 117.89(19) . . ?
C7 C8 C9 120.9(3) . . ?
C7 C8 H8 119.5 . . ?
C9 C8 H8 119.5 . . ?
P1 C13 P2 113.17(11) . . ?
P1 C13 H13A 108.9 . . ?
P2 C13 H13A 108.9 . . ?
P1 C13 H13B 108.9 . . ?
P2 C13 H13B 108.9 . . ?
H13A C13 H13B 107.8 . . ?
C20 C21 C22 120.7(3) . . ?
C20 C21 H21 119.6 . . ?
C22 C21 H21 119.6 . . ?
C19 C14 C15 118.1(2) . . ?
C19 C14 P2 123.6(2) . . ?
C15 C14 P2 118.21(19) . . ?
C21 C20 C25 118.3(2) . . ?
C21 C20 P2 117.17(19) . . ?
C25 C20 P2 124.52(18) . . ?
C14 C19 C18 120.2(3) . . ?
C14 C19 H19 119.9 . . ?
C18 C19 H19 119.9 . . ?
C14 C15 C16 121.3(3) . . ?
C14 C15 H15 119.4 . . ?
C16 C15 H15 119.4 . . ?
C24 C25 C20 120.5(3) . . ?
C24 C25 H25 119.8 . . ?
C20 C25 H25 119.8 . . ?
C7 C12 C11 120.1(3) . . ?
C7 C12 H12 119.9 . . ?
C11 C12 H12 119.9 . . ?
C5 C6 C1 120.5(3) . . ?
C5 C6 H6 119.7 . . ?
C1 C6 H6 119.7 . . ?
C22 C23 C24 119.8(3) . . ?
C22 C23 H23 120.1 . . ?
C24 C23 H23 120.1 . . ?
C23 C22 C21 120.4(3) . . ?
C23 C22 H22 119.8 . . ?
C21 C22 H22 119.8 . . ?
C11 C10 C9 120.4(3) . . ?
C11 C10 H10 119.8 . . ?
C9 C10 H10 119.8 . . ?
C10 C9 C8 119.8(3) . . ?
C10 C9 H9 120.1 . . ?
C8 C9 H9 120.1 . . ?
C23 C24 C25 120.3(3) . . ?
C23 C24 H24 119.8 . . ?
C25 C24 H24 119.8 . . ?
C10 C11 C12 120.2(3) . . ?
C10 C11 H11 119.9 . . ?
C12 C11 H11 119.9 . . ?
C16 C17 C18 119.5(3) . . ?
C16 C17 H17 120.2 . . ?
C18 C17 H17 120.2 . . ?
C17 C16 C15 120.1(3) . . ?
C17 C16 H16 120.0 . . ?
C15 C16 H16 120.0 . . ?
C17 C18 C19 120.7(3) . . ?
C17 C18 H18 119.6 . . ?
C19 C18 H18 119.6 . . ?
C26 S1 Ag1 94.90(8) . . ?
C27 S2 Ag2 94.12(8) . . ?
N1 C26 S1 179.8(2) . . ?
N2 C27 S2 179.4(3) . . ?
C27 N2 Ag1 156.5(2) . 3_655 ?
C26 N1 Ag2 154.94(18) . 3_655 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag2 N1 2.231(2) 3_655 ?
Ag2 P2 2.4087(6) . ?
Ag2 S2 2.6054(6) . ?
Ag2 Ag1 3.0635(3) . ?
Ag1 N2 2.213(2) 3_655 ?
Ag1 P1 2.3891(6) . ?
Ag1 S1 2.5683(7) . ?
P1 C1 1.817(2) . ?
P1 C7 1.821(2) . ?
P1 C13 1.826(2) . ?
P2 C20 1.820(2) . ?
P2 C14 1.825(2) . ?
P2 C13 1.844(2) . ?
C1 C2 1.377(3) . ?
C1 C6 1.382(3) . ?
C2 C3 1.383(4) . ?
C2 H2 0.9300 . ?
C5 C4 1.358(5) . ?
C5 C6 1.381(4) . ?
C5 H5 0.9300 . ?
C4 C3 1.353(5) . ?
C4 H4 0.9300 . ?
C3 H3 0.9300 . ?
C7 C12 1.369(4) . ?
C7 C8 1.371(3) . ?
C8 C9 1.387(4) . ?
C8 H8 0.9300 . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C21 C20 1.378(3) . ?
C21 C22 1.384(4) . ?
C21 H21 0.9300 . ?
C14 C19 1.368(3) . ?
C14 C15 1.368(3) . ?
C20 C25 1.395(3) . ?
C19 C18 1.386(4) . ?
C19 H19 0.9300 . ?
C15 C16 1.384(4) . ?
C15 H15 0.9300 . ?
C25 C24 1.378(3) . ?
C25 H25 0.9300 . ?
C12 C11 1.394(4) . ?
C12 H12 0.9300 . ?
C6 H6 0.9300 . ?
C23 C22 1.365(4) . ?
C23 C24 1.373(4) . ?
C23 H23 0.9300 . ?
C22 H22 0.9300 . ?
C10 C11 1.350(5) . ?
C10 C9 1.350(5) . ?
C10 H10 0.9300 . ?
C9 H9 0.9300 . ?
C24 H24 0.9300 . ?
C11 H11 0.9300 . ?
C17 C16 1.346(4) . ?
C17 C18 1.360(5) . ?
C17 H17 0.9300 . ?
C16 H16 0.9300 . ?
C18 H18 0.9300 . ?
S1 C26 1.664(2) . ?
S2 C27 1.646(3) . ?
C26 N1 1.146(3) . ?
C27 N2 1.147(3) . ?
N2 Ag1 2.213(2) 3_655 ?
N1 Ag2 2.231(2) 3_655 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Ag2 Ag1 N2 18.56(9) 3_655 . . 3_655 ?
P2 Ag2 Ag1 N2 160.71(8) . . . 3_655 ?
S2 Ag2 Ag1 N2 -65.91(8) . . . 3_655 ?
N1 Ag2 Ag1 P1 -114.23(5) 3_655 . . . ?
P2 Ag2 Ag1 P1 27.91(2) . . . . ?
S2 Ag2 Ag1 P1 161.29(3) . . . . ?
N1 Ag2 Ag1 S1 103.80(5) 3_655 . . . ?
P2 Ag2 Ag1 S1 -114.06(2) . . . . ?
S2 Ag2 Ag1 S1 19.32(3) . . . . ?
N2 Ag1 P1 C1 -61.42(11) 3_655 . . . ?
S1 Ag1 P1 C1 116.86(8) . . . . ?
Ag2 Ag1 P1 C1 70.79(8) . . . . ?
N2 Ag1 P1 C7 60.84(12) 3_655 . . . ?
S1 Ag1 P1 C7 -120.88(9) . . . . ?
Ag2 Ag1 P1 C7 -166.96(9) . . . . ?
N2 Ag1 P1 C13 -179.46(11) 3_655 . . . ?
S1 Ag1 P1 C13 -1.18(9) . . . . ?
Ag2 Ag1 P1 C13 -47.25(8) . . . . ?
N1 Ag2 P2 C20 -72.44(12) 3_655 . . . ?
S2 Ag2 P2 C20 69.64(9) . . . . ?
Ag1 Ag2 P2 C20 -135.14(8) . . . . ?
N1 Ag2 P2 C14 167.51(11) 3_655 . . . ?
S2 Ag2 P2 C14 -50.41(8) . . . . ?
Ag1 Ag2 P2 C14 104.81(8) . . . . ?
N1 Ag2 P2 C13 51.89(12) 3_655 . . . ?
S2 Ag2 P2 C13 -166.03(9) . . . . ?
Ag1 Ag2 P2 C13 -10.81(9) . . . . ?
C7 P1 C1 C2 -102.8(2) . . . . ?
C13 P1 C1 C2 148.90(19) . . . . ?
Ag1 P1 C1 C2 26.1(2) . . . . ?
C7 P1 C1 C6 78.7(2) . . . . ?
C13 P1 C1 C6 -29.6(2) . . . . ?
Ag1 P1 C1 C6 -152.44(19) . . . . ?
C6 C1 C2 C3 -1.5(4) . . . . ?
P1 C1 C2 C3 179.9(2) . . . . ?
C6 C5 C4 C3 -1.1(5) . . . . ?
C5 C4 C3 C2 0.1(6) . . . . ?
C1 C2 C3 C4 1.2(5) . . . . ?
C1 P1 C7 C12 -24.7(3) . . . . ?
C13 P1 C7 C12 86.6(3) . . . . ?
Ag1 P1 C7 C12 -147.7(2) . . . . ?
C1 P1 C7 C8 156.2(2) . . . . ?
C13 P1 C7 C8 -92.5(2) . . . . ?
Ag1 P1 C7 C8 33.2(2) . . . . ?
C12 C7 C8 C9 -1.4(4) . . . . ?
P1 C7 C8 C9 177.7(2) . . . . ?
C1 P1 C13 P2 -67.91(15) . . . . ?
C7 P1 C13 P2 -179.89(13) . . . . ?
Ag1 P1 C13 P2 51.46(14) . . . . ?
C20 P2 C13 P1 109.24(13) . . . . ?
C14 P2 C13 P1 -140.35(13) . . . . ?
Ag2 P2 C13 P1 -19.51(15) . . . . ?
C20 P2 C14 C19 31.7(3) . . . . ?
C13 P2 C14 C19 -79.4(2) . . . . ?
Ag2 P2 C14 C19 157.3(2) . . . . ?
C20 P2 C14 C15 -152.0(2) . . . . ?
C13 P2 C14 C15 96.8(2) . . . . ?
Ag2 P2 C14 C15 -26.4(2) . . . . ?
C22 C21 C20 C25 0.3(4) . . . . ?
C22 C21 C20 P2 -179.7(2) . . . . ?
C14 P2 C20 C21 99.7(2) . . . . ?
C13 P2 C20 C21 -152.25(19) . . . . ?
Ag2 P2 C20 C21 -23.6(2) . . . . ?
C14 P2 C20 C25 -80.3(2) . . . . ?
C13 P2 C20 C25 27.8(2) . . . . ?
Ag2 P2 C20 C25 156.46(19) . . . . ?
C15 C14 C19 C18 0.3(4) . . . . ?
P2 C14 C19 C18 176.5(3) . . . . ?
C19 C14 C15 C16 0.9(4) . . . . ?
P2 C14 C15 C16 -175.6(2) . . . . ?
C21 C20 C25 C24 1.1(4) . . . . ?
P2 C20 C25 C24 -178.9(2) . . . . ?
C8 C7 C12 C11 0.8(5) . . . . ?
P1 C7 C12 C11 -178.3(3) . . . . ?
C4 C5 C6 C1 0.8(5) . . . . ?
C2 C1 C6 C5 0.5(4) . . . . ?
P1 C1 C6 C5 179.0(2) . . . . ?
C24 C23 C22 C21 1.3(5) . . . . ?
C20 C21 C22 C23 -1.5(4) . . . . ?
C11 C10 C9 C8 1.3(6) . . . . ?
C7 C8 C9 C10 0.4(5) . . . . ?
C22 C23 C24 C25 0.1(5) . . . . ?
C20 C25 C24 C23 -1.3(4) . . . . ?
C9 C10 C11 C12 -2.0(7) . . . . ?
C7 C12 C11 C10 0.9(7) . . . . ?
C18 C17 C16 C15 1.7(6) . . . . ?
C14 C15 C16 C17 -1.9(5) . . . . ?
C16 C17 C18 C19 -0.6(6) . . . . ?
C14 C19 C18 C17 -0.4(5) . . . . ?
N2 Ag1 S1 C26 24.40(10) 3_655 . . . ?
P1 Ag1 S1 C26 -154.20(8) . . . . ?
Ag2 Ag1 S1 C26 -100.73(8) . . . . ?
N1 Ag2 S2 C27 -24.20(10) 3_655 . . . ?
P2 Ag2 S2 C27 -179.82(8) . . . . ?
Ag1 Ag2 S2 C27 51.26(9) . . . . ?
Ag1 S1 C26 N1 -111(100) . . . . ?
Ag2 S2 C27 N2 122(26) . . . . ?
S2 C27 N2 Ag1 -124(25) . . . 3_655 ?
S1 C26 N1 Ag2 111(100) . . . 3_655 ?
