#------------------------------------------------------------------------------
#$Date: 2018-09-26 06:29:44 +0300 (Wed, 26 Sep 2018) $
#$Revision: 211175 $
#$URL: file:///home/coder/svn-repositories/cod/cif/8/10/26/8102656.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8102656
loop_
_publ_author_name
'Mouhamad Awada'
'Catherine Jeunesse'
'Eric Brenner'
'Dominique Matt'
'Loïc Toupet'
_publ_section_title
;
 Crystal structure of bis[(m2-5,11-bis(diphenyl-
 phosphanyl)25,26-dipropyloxy-27,28-bis(2-
 propenyl)calix[4]arene-P:P']disilver(I) bis(tetrafluoroborate) ---
 dichloromethane (1:2), [Ag2(C64H62O4P2)2][BF4]2 · 2CH2Cl2
;
_journal_issue                   1
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              176
_journal_volume                  225
_journal_year                    2010
_chemical_formula_sum            'C65 H64 Ag B Cl2 F4 O4 P2'
_chemical_formula_weight         1236.68
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.197(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.6993(8)
_cell_length_b                   23.1203(9)
_cell_length_c                   17.0133(7)
_cell_measurement_temperature    150(2)
_cell_volume                     5943.7(5)
_computing_cell_refinement
'CrysAlis RED, Oxford Diffraction Ltd.,Version 1.171.26'
_computing_data_collection
'CrysAlis CCD, Oxford Diffraction Ltd.,Version 1.171.26'
_computing_data_reduction
'CrysAlis RED, Oxford Diffraction Ltd.,Version 1.171.26'
_computing_molecular_graphics    'PLATON_(Spek, 1998)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR-97_(Altomare & al., 1998)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 19.64
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD Saphire 3 Xcalibur'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1232
_diffrn_reflns_av_sigmaI/netI    0.1734
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            80761
_diffrn_reflns_theta_full        27.00
_diffrn_reflns_theta_max         27.00
_diffrn_reflns_theta_min         2.56
_exptl_absorpt_coefficient_mu    0.543
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.382
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2552
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.567
_refine_diff_density_min         -0.892
_refine_diff_density_rms         0.088
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.802
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     712
_refine_ls_number_reflns         12972
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.802
_refine_ls_R_factor_all          0.1441
_refine_ls_R_factor_gt           0.0602
_refine_ls_shift/su_max          0.601
_refine_ls_shift/su_mean         0.021
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0873P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1445
_refine_ls_wR_factor_ref         0.1637
_reflns_number_gt                5489
_reflns_number_total             12972
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            1267-2903.cff
_cod_data_source_block           dipagchelate
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_cell_volume        5943.7(4)
_cod_original_sg_symbol_H-M      P21/n
_cod_database_code               8102656
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.22301(3) 0.027749(19) 0.65178(2) 0.04150(15) Uani 1 1 d . . .
P1 P 0.24808(8) 0.07505(6) 0.78621(8) 0.0336(3) Uani 1 1 d . . .
P2 P 0.18971(9) 0.02732(6) 0.49886(8) 0.0358(3) Uani 1 1 d . . .
O1 O -0.0859(2) 0.15569(17) 0.7955(2) 0.0423(9) Uani 1 1 d . . .
O2 O -0.1378(2) 0.11949(15) 0.9455(2) 0.0351(8) Uani 1 1 d . . .
O3 O 0.2994(2) -0.14346(17) 0.2644(2) 0.0421(9) Uani 1 1 d . . .
O4 O 0.2427(2) -0.21093(14) 0.3976(2) 0.0345(8) Uani 1 1 d . . .
C1 C 0.1460(3) 0.0957(2) 0.7914(3) 0.0326(12) Uani 1 1 d . . .
C2 C 0.1282(3) 0.0845(2) 0.8632(3) 0.0368(13) Uani 1 1 d . . .
H2 H 0.1701 0.0637 0.9112 0.044 Uiso 1 1 calc R . .
C3 C 0.0497(3) 0.1035(2) 0.8650(3) 0.0380(13) Uani 1 1 d . . .
C4 C -0.0088(3) 0.1360(2) 0.7939(3) 0.0321(12) Uani 1 1 d . . .
C5 C 0.0060(3) 0.1455(2) 0.7199(3) 0.0293(11) Uani 1 1 d . . .
C6 C 0.0832(3) 0.1248(2) 0.7206(3) 0.0313(12) Uani 1 1 d . . .
H6 H 0.0941 0.1307 0.6707 0.038 Uiso 1 1 calc R . .
C7 C 0.0244(3) 0.0872(2) 0.9374(3) 0.0413(14) Uani 1 1 d . . .
H7A H 0.0136 0.1227 0.9640 0.050 Uiso 1 1 calc R . .
H7B H 0.0738 0.0658 0.9829 0.050 Uiso 1 1 calc R . .
C8 C -0.1322(5) -0.0360(3) 0.8277(4) 0.0582(18) Uani 1 1 d . . .
H8 H -0.1297 -0.0727 0.8037 0.070 Uiso 1 1 calc R . .
C9 C -0.0579(4) -0.0025(3) 0.8647(3) 0.0508(16) Uani 1 1 d . . .
H9 H -0.0045 -0.0158 0.8636 0.061 Uiso 1 1 calc R . .
C10 C -0.0578(3) 0.0500(2) 0.9035(3) 0.0363(13) Uani 1 1 d . . .
C11 C -0.1369(3) 0.0676(2) 0.9051(3) 0.0336(12) Uani 1 1 d . . .
C12 C -0.2145(3) 0.0365(2) 0.8631(3) 0.0382(13) Uani 1 1 d . . .
C13 C -0.2111(4) -0.0160(3) 0.8257(3) 0.0501(16) Uani 1 1 d . . .
H13 H -0.2634 -0.0384 0.7983 0.060 Uiso 1 1 calc R . .
C14 C -0.3021(3) 0.0596(3) 0.8553(3) 0.0500(16) Uani 1 1 d . . .
H14A H -0.2938 0.0991 0.8799 0.060 Uiso 1 1 calc R . .
H14B H -0.3244 0.0347 0.8891 0.060 Uiso 1 1 calc R . .
C15 C 0.4920(4) -0.0167(3) 0.3600(4) 0.0663(19) Uani 1 1 d . . .
H15 H 0.5390 0.0105 0.3811 0.080 Uiso 1 1 calc R . .
C16 C 0.4783(4) -0.0546(3) 0.4166(4) 0.0550(16) Uani 1 1 d . . .
H16 H 0.5147 -0.0514 0.4771 0.066 Uiso 1 1 calc R . .
C17 C 0.4130(3) -0.0971(2) 0.3872(3) 0.0399(14) Uani 1 1 d . . .
C18 C 0.3628(3) -0.1007(2) 0.2963(3) 0.0404(14) Uani 1 1 d . . .
C19 C 0.3696(3) -0.0610(3) 0.2394(4) 0.0510(16) Uani 1 1 d . . .
C20 C 0.4361(4) -0.0195(3) 0.2727(4) 0.0637(19) Uani 1 1 d . . .
H20 H 0.4431 0.0077 0.2343 0.076 Uiso 1 1 calc R . .
C21 C 0.3904(3) -0.1324(2) 0.4483(3) 0.0386(13) Uani 1 1 d . . .
H21A H 0.4363 -0.1268 0.5083 0.046 Uiso 1 1 calc R . .
H21B H 0.3897 -0.1739 0.4336 0.046 Uiso 1 1 calc R . .
C22 C 0.2049(3) -0.0412(2) 0.4567(3) 0.0310(12) Uani 1 1 d . . .
C23 C 0.1348(3) -0.0795(2) 0.4227(3) 0.0310(12) Uani 1 1 d . . .
H23 H 0.0777 -0.0667 0.4144 0.037 Uiso 1 1 calc R . .
C24 C 0.1443(3) -0.1355(2) 0.4003(3) 0.0287(12) Uani 1 1 d . . .
C25 C 0.2299(3) -0.1536(2) 0.4150(3) 0.0285(12) Uani 1 1 d . . .
C26 C 0.3004(3) -0.1154(2) 0.4436(3) 0.0292(12) Uani 1 1 d . . .
C27 C 0.2863(3) -0.0600(2) 0.4644(3) 0.0308(12) Uani 1 1 d . . .
H27 H 0.3345 -0.0336 0.4849 0.037 Uiso 1 1 calc R . .
C28 C 0.0640(3) -0.1742(2) 0.3591(3) 0.0328(12) Uani 1 1 d . . .
H28A H 0.0815 -0.2114 0.3421 0.039 Uiso 1 1 calc R . .
H28B H 0.0396 -0.1825 0.4018 0.039 Uiso 1 1 calc R . .
C29 C -0.0795(4) 0.2094(3) 0.8390(4) 0.0594(18) Uani 1 1 d . . .
H29A H -0.1348 0.2139 0.8466 0.071 Uiso 1 1 calc R . .
H29B H -0.0308 0.2054 0.8979 0.071 Uiso 1 1 calc R . .
C30 C -0.0668(9) 0.2572(5) 0.8077(9) 0.197(7) Uani 1 1 d . . .
H30 H -0.1215 0.2666 0.7605 0.236 Uiso 1 1 calc R . .
C31 C -0.0156(6) 0.2956(4) 0.8120(6) 0.109(3) Uani 1 1 d . . .
H31A H 0.0436 0.2945 0.8555 0.131 Uiso 1 1 calc R . .
H31B H -0.0347 0.3268 0.7719 0.131 Uiso 1 1 calc R . .
C32 C -0.1340(5) 0.1112(3) 1.0299(4) 0.0662(19) Uani 1 1 d . . .
H32A H -0.0779 0.0917 1.0676 0.079 Uiso 1 1 calc R . .
H32B H -0.1837 0.0862 1.0262 0.079 Uiso 1 1 calc R . .
C33A C -0.1394(7) 0.1678(4) 1.0676(6) 0.104(3) Uani 1 1 d . . .
H33A H -0.1842 0.1931 1.0239 0.125 Uiso 1 1 calc R . .
H33B H -0.1539 0.1632 1.1180 0.125 Uiso 1 1 calc R . .
C34A C -0.0573(14) 0.1890(6) 1.0922(8) 0.261(12) Uani 1 1 d . . .
H34A H -0.0530 0.2271 1.1189 0.392 Uiso 1 1 calc R . .
H34B H -0.0445 0.1926 1.0412 0.392 Uiso 1 1 calc R . .
H34C H -0.0143 0.1627 1.1343 0.392 Uiso 1 1 calc R . .
C35 C 0.3328(4) -0.2008(3) 0.2606(4) 0.076(2) Uani 1 1 d . . .
H35A H 0.2980 -0.2294 0.2765 0.091 Uiso 1 1 calc R . .
H35B H 0.3949 -0.2033 0.3048 0.091 Uiso 1 1 calc R . .
C36 C 0.3298(5) -0.2168(4) 0.1772(5) 0.099(3) Uani 1 1 d . . .
H36A H 0.3672 -0.1899 0.1622 0.119 Uiso 1 1 calc R . .
H36B H 0.2682 -0.2132 0.1321 0.119 Uiso 1 1 calc R . .
C37 C 0.3622(5) -0.2792(3) 0.1775(5) 0.089(2) Uani 1 1 d . . .
H37A H 0.3596 -0.2884 0.1203 0.134 Uiso 1 1 calc R . .
H37B H 0.3244 -0.3060 0.1909 0.134 Uiso 1 1 calc R . .
H37C H 0.4234 -0.2828 0.2217 0.134 Uiso 1 1 calc R . .
C38 C 0.2527(4) -0.2487(3) 0.4684(4) 0.0562(17) Uani 1 1 d . . .
H38A H 0.1961 -0.2527 0.4735 0.067 Uiso 1 1 calc R . .
H38B H 0.2983 -0.2337 0.5239 0.067 Uiso 1 1 calc R . .
C39 C 0.2807(7) -0.3056(4) 0.4460(9) 0.147(6) Uani 1 1 d . . .
H39 H 0.3397 -0.3097 0.4522 0.176 Uiso 1 1 calc R . .
C40 C 0.2361(12) -0.3427(6) 0.4229(8) 0.206(8) Uani 1 1 d . . .
H40A H 0.1768 -0.3397 0.4163 0.247 Uiso 1 1 calc R . .
H40B H 0.2566 -0.3781 0.4095 0.247 Uiso 1 1 calc R . .
C41 C 0.3049(3) 0.1436(3) 0.7941(3) 0.0429(14) Uani 1 1 d . . .
C42 C 0.2798(4) 0.1948(3) 0.8186(4) 0.0507(16) Uani 1 1 d . . .
H42 H 0.2305 0.1954 0.8327 0.061 Uiso 1 1 calc R . .
C43 C 0.3256(5) 0.2450(3) 0.8226(4) 0.0679(19) Uani 1 1 d . . .
H43 H 0.3071 0.2802 0.8386 0.081 Uiso 1 1 calc R . .
C44 C 0.3972(5) 0.2449(4) 0.8039(5) 0.087(2) Uani 1 1 d . . .
H44 H 0.4299 0.2796 0.8096 0.104 Uiso 1 1 calc R . .
C45 C 0.4219(4) 0.1959(4) 0.7773(5) 0.083(2) Uani 1 1 d . . .
H45 H 0.4700 0.1967 0.7614 0.100 Uiso 1 1 calc R . .
C46 C 0.3769(4) 0.1432(3) 0.7728(4) 0.0592(17) Uani 1 1 d . . .
H46 H 0.3953 0.1084 0.7557 0.071 Uiso 1 1 calc R . .
C47 C 0.3168(3) 0.0388(2) 0.8875(3) 0.0339(13) Uani 1 1 d . . .
C48 C 0.3649(3) 0.0696(3) 0.9630(3) 0.0398(13) Uani 1 1 d . . .
H48 H 0.3605 0.1106 0.9633 0.048 Uiso 1 1 calc R . .
C49 C 0.4187(3) 0.0410(3) 1.0371(3) 0.0471(16) Uani 1 1 d . . .
H49 H 0.4512 0.0622 1.0889 0.056 Uiso 1 1 calc R . .
C50 C 0.4259(3) -0.0174(3) 1.0373(3) 0.0482(16) Uani 1 1 d . . .
H50 H 0.4647 -0.0366 1.0889 0.058 Uiso 1 1 calc R . .
C51 C 0.3784(4) -0.0491(3) 0.9645(4) 0.0502(15) Uani 1 1 d . . .
H51 H 0.3829 -0.0901 0.9656 0.060 Uiso 1 1 calc R . .
C52 C 0.3237(3) -0.0207(3) 0.8890(3) 0.0414(14) Uani 1 1 d . . .
H52 H 0.2908 -0.0424 0.8379 0.050 Uiso 1 1 calc R . .
C53 C 0.0768(3) 0.0490(2) 0.4275(3) 0.0360(13) Uani 1 1 d . . .
C54 C 0.0238(3) 0.0729(2) 0.4633(3) 0.0442(14) Uani 1 1 d . . .
H54 H 0.0466 0.0774 0.5245 0.053 Uiso 1 1 calc R . .
C55 C -0.0616(4) 0.0901(3) 0.4114(3) 0.0509(16) Uani 1 1 d . . .
H55 H -0.0970 0.1067 0.4368 0.061 Uiso 1 1 calc R . .
C56 C -0.0953(4) 0.0831(2) 0.3229(4) 0.0522(16) Uani 1 1 d . . .
H56 H -0.1544 0.0944 0.2869 0.063 Uiso 1 1 calc R . .
C57 C -0.0428(4) 0.0594(3) 0.2867(4) 0.0625(19) Uani 1 1 d . . .
H57 H -0.0654 0.0552 0.2254 0.075 Uiso 1 1 calc R . .
C58 C 0.0426(4) 0.0417(3) 0.3395(4) 0.0583(18) Uani 1 1 d . . .
H58 H 0.0777 0.0243 0.3144 0.070 Uiso 1 1 calc R . .
C59 C 0.2599(3) 0.0779(2) 0.4770(3) 0.0416(14) Uani 1 1 d . . .
C60 C 0.2782(4) 0.0749(3) 0.4046(3) 0.0483(15) Uani 1 1 d . . .
H60 H 0.2539 0.0444 0.3639 0.058 Uiso 1 1 calc R . .
C61 C 0.3315(4) 0.1160(3) 0.3915(4) 0.0519(16) Uani 1 1 d . . .
H61 H 0.3445 0.1133 0.3424 0.062 Uiso 1 1 calc R . .
C62 C 0.3658(4) 0.1611(3) 0.4497(5) 0.0618(18) Uani 1 1 d . . .
H62 H 0.4018 0.1897 0.4403 0.074 Uiso 1 1 calc R . .
C63 C 0.3478(4) 0.1646(3) 0.5211(4) 0.0637(18) Uani 1 1 d . . .
H63 H 0.3712 0.1955 0.5611 0.076 Uiso 1 1 calc R . .
C64 C 0.2965(4) 0.1237(3) 0.5347(4) 0.0522(16) Uani 1 1 d . . .
H64 H 0.2852 0.1263 0.5848 0.063 Uiso 1 1 calc R . .
C71 C 0.6032(4) 0.2287(3) 1.1118(4) 0.071(2) Uani 1 1 d . . .
H71A H 0.5924 0.2456 1.1599 0.085 Uiso 1 1 calc R . .
H71B H 0.6455 0.1963 1.1357 0.085 Uiso 1 1 calc R . .
Cl1 Cl 0.6492(2) 0.28021(12) 1.07122(17) 0.1453(12) Uani 1 1 d . . .
Cl2 Cl 0.50503(13) 0.20242(9) 1.03356(15) 0.1071(8) Uani 1 1 d . . .
B1 B 0.3472(9) -0.1057(5) 0.7083(5) 0.101(4) Uani 1 1 d . . .
F1 F 0.3027(6) -0.0646(3) 0.6770(4) 0.250(5) Uani 1 1 d . . .
F2 F 0.4271(3) -0.1076(2) 0.7695(4) 0.133(2) Uani 1 1 d . . .
F3 F 0.3049(4) -0.1279(2) 0.7676(4) 0.1340(19) Uani 1 1 d . . .
F4 F 0.3282(4) -0.1545(3) 0.6540(3) 0.146(2) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Ag1 P2 153.14(5) . . ?
P1 Ag1 F1 111.55(16) . . ?
P2 Ag1 F1 92.50(14) . . ?
C1 P1 C47 107.7(2) . . ?
C1 P1 C41 103.8(2) . . ?
C47 P1 C41 103.4(2) . . ?
C1 P1 Ag1 112.36(15) . . ?
C47 P1 Ag1 118.44(17) . . ?
C41 P1 Ag1 109.83(18) . . ?
C59 P2 C22 105.9(2) . . ?
C59 P2 C53 105.2(2) . . ?
C22 P2 C53 105.0(2) . . ?
C59 P2 Ag1 110.34(18) . . ?
C22 P2 Ag1 115.18(15) . . ?
C53 P2 Ag1 114.44(17) . . ?
C4 O1 C29 115.8(4) . . ?
C11 O2 C32 112.2(4) . . ?
C18 O3 C35 115.4(4) . . ?
C25 O4 C38 112.0(4) . . ?
C6 C1 C2 119.0(4) . . ?
C6 C1 P1 117.7(4) . . ?
C2 C1 P1 123.3(4) . . ?
C3 C2 C1 120.8(4) . . ?
C3 C2 H2 119.6 . . ?
C1 C2 H2 119.6 . . ?
C2 C3 C4 117.6(4) . . ?
C2 C3 C7 122.1(4) . . ?
C4 C3 C7 120.1(4) . . ?
O1 C4 C5 119.4(4) . . ?
O1 C4 C3 118.2(4) . . ?
C5 C4 C3 122.3(4) . . ?
C6 C5 C4 117.7(4) . . ?
C6 C5 C28 121.9(4) . 3_556 ?
C4 C5 C28 120.3(4) . 3_556 ?
C5 C6 C1 122.4(4) . . ?
C5 C6 H6 118.8 . . ?
C1 C6 H6 118.8 . . ?
C3 C7 C10 110.8(4) . . ?
C3 C7 H7A 109.5 . . ?
C10 C7 H7A 109.5 . . ?
C3 C7 H7B 109.5 . . ?
C10 C7 H7B 109.5 . . ?
H7A C7 H7B 108.1 . . ?
C9 C8 C13 119.3(6) . . ?
C9 C8 H8 120.3 . . ?
C13 C8 H8 120.3 . . ?
C8 C9 C10 122.3(6) . . ?
C8 C9 H9 118.9 . . ?
C10 C9 H9 118.9 . . ?
C9 C10 C11 117.3(5) . . ?
C9 C10 C7 119.9(5) . . ?
C11 C10 C7 122.7(5) . . ?
O2 C11 C12 120.0(4) . . ?
O2 C11 C10 118.3(5) . . ?
C12 C11 C10 121.5(5) . . ?
C13 C12 C11 118.8(5) . . ?
C13 C12 C14 119.9(5) . . ?
C11 C12 C14 121.3(5) . . ?
C12 C13 C8 120.5(6) . . ?
C12 C13 H13 119.7 . . ?
C8 C13 H13 119.7 . . ?
C12 C14 C19 110.7(4) . 3_556 ?
C12 C14 H14A 109.5 . . ?
C19 C14 H14A 109.5 3_556 . ?
C12 C14 H14B 109.5 . . ?
C19 C14 H14B 109.5 3_556 . ?
H14A C14 H14B 108.1 . . ?
C20 C15 C16 118.8(6) . . ?
C20 C15 H15 120.6 . . ?
C16 C15 H15 120.6 . . ?
C17 C16 C15 122.0(5) . . ?
C17 C16 H16 119.0 . . ?
C15 C16 H16 119.0 . . ?
C16 C17 C18 116.3(5) . . ?
C16 C17 C21 121.8(5) . . ?
C18 C17 C21 121.5(5) . . ?
C19 C18 O3 118.7(5) . . ?
C19 C18 C17 122.9(5) . . ?
O3 C18 C17 118.1(5) . . ?
C18 C19 C20 117.7(5) . . ?
C18 C19 C14 120.9(5) . 3_556 ?
C20 C19 C14 121.3(5) . 3_556 ?
C15 C20 C19 121.8(6) . . ?
C15 C20 H20 119.1 . . ?
C19 C20 H20 119.1 . . ?
C17 C21 C26 111.0(4) . . ?
C17 C21 H21A 109.4 . . ?
C26 C21 H21A 109.4 . . ?
C17 C21 H21B 109.4 . . ?
C26 C21 H21B 109.4 . . ?
H21A C21 H21B 108.0 . . ?
C27 C22 C23 117.6(5) . . ?
C27 C22 P2 122.6(4) . . ?
C23 C22 P2 119.5(4) . . ?
C24 C23 C22 122.8(4) . . ?
C24 C23 H23 118.6 . . ?
C22 C23 H23 118.6 . . ?
C23 C24 C25 117.2(4) . . ?
C23 C24 C28 120.0(4) . . ?
C25 C24 C28 122.7(4) . . ?
C26 C25 O4 119.8(4) . . ?
C26 C25 C24 121.4(5) . . ?
O4 C25 C24 118.8(4) . . ?
C27 C26 C25 118.2(4) . . ?
C27 C26 C21 120.0(4) . . ?
C25 C26 C21 121.7(5) . . ?
C26 C27 C22 122.6(5) . . ?
C26 C27 H27 118.7 . . ?
C22 C27 H27 118.7 . . ?
C5 C28 C24 110.5(4) 3_556 . ?
C5 C28 H28A 109.6 3_556 . ?
C24 C28 H28A 109.6 . . ?
C5 C28 H28B 109.6 3_556 . ?
C24 C28 H28B 109.6 . . ?
H28A C28 H28B 108.1 . . ?
C30 C29 O1 121.5(6) . . ?
C30 C29 H29A 107.0 . . ?
O1 C29 H29A 107.0 . . ?
C30 C29 H29B 106.8 . . ?
O1 C29 H29B 106.9 . . ?
H29A C29 H29B 106.7 . . ?
C31 C30 C29 147.4(16) . . ?
C31 C30 H30 106.3 . . ?
C29 C30 H30 106.3 . . ?
C30 C31 H31A 119.8 . . ?
C30 C31 H31B 120.2 . . ?
H31A C31 H31B 120.0 . . ?
O2 C32 C33A 109.5(6) . . ?
O2 C32 H32A 109.8 . . ?
C33A C32 H32A 109.8 . . ?
O2 C32 H32B 109.8 . . ?
C33A C32 H32B 109.7 . . ?
H32A C32 H32B 108.2 . . ?
C34A C33A C32 102.4(10) . . ?
C34A C33A H33A 111.3 . . ?
C32 C33A H33A 111.3 . . ?
C34A C33A H33B 111.3 . . ?
C32 C33A H33B 111.3 . . ?
H33A C33A H33B 109.2 . . ?
C33A C34A H34A 109.4 . . ?
C33A C34A H34B 109.5 . . ?
H34A C34A H34B 109.5 . . ?
C33A C34A H34C 109.5 . . ?
H34A C34A H34C 109.5 . . ?
H34B C34A H34C 109.5 . . ?
O3 C35 C36 115.0(7) . . ?
O3 C35 H35A 108.5 . . ?
C36 C35 H35A 108.5 . . ?
O3 C35 H35B 108.5 . . ?
C36 C35 H35B 108.5 . . ?
H35A C35 H35B 107.5 . . ?
C35 C36 C37 111.8(7) . . ?
C35 C36 H36A 109.3 . . ?
C37 C36 H36A 109.3 . . ?
C35 C36 H36B 109.3 . . ?
C37 C36 H36B 109.3 . . ?
H36A C36 H36B 107.9 . . ?
C36 C37 H37A 109.5 . . ?
C36 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C36 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
O4 C38 C39 105.0(7) . . ?
O4 C38 H38A 110.7 . . ?
C39 C38 H38A 110.9 . . ?
O4 C38 H38B 110.7 . . ?
C39 C38 H38B 110.8 . . ?
H38A C38 H38B 108.8 . . ?
C40 C39 C38 122.8(15) . . ?
C40 C39 H39 118.8 . . ?
C38 C39 H39 118.4 . . ?
C39 C40 H40A 120.6 . . ?
C39 C40 H40B 119.4 . . ?
H40A C40 H40B 120.0 . . ?
C42 C41 C46 119.4(6) . . ?
C42 C41 P1 123.5(4) . . ?
C46 C41 P1 117.1(5) . . ?
C41 C42 C43 120.3(6) . . ?
C41 C42 H42 119.8 . . ?
C43 C42 H42 119.9 . . ?
C44 C43 C42 120.8(7) . . ?
C44 C43 H43 119.6 . . ?
C42 C43 H43 119.6 . . ?
C45 C44 C43 120.2(7) . . ?
C45 C44 H44 119.9 . . ?
C43 C44 H44 119.9 . . ?
C44 C45 C46 120.7(7) . . ?
C44 C45 H45 119.7 . . ?
C46 C45 H45 119.7 . . ?
C41 C46 C45 118.5(6) . . ?
C41 C46 H46 120.8 . . ?
C45 C46 H46 120.8 . . ?
C52 C47 C48 118.9(5) . . ?
C52 C47 P1 119.4(4) . . ?
C48 C47 P1 121.7(4) . . ?
C49 C48 C47 120.0(5) . . ?
C49 C48 H48 120.0 . . ?
C47 C48 H48 120.0 . . ?
C50 C49 C48 120.4(5) . . ?
C50 C49 H49 119.8 . . ?
C48 C49 H49 119.8 . . ?
C49 C50 C51 121.1(5) . . ?
C49 C50 H50 119.5 . . ?
C51 C50 H50 119.5 . . ?
C50 C51 C52 119.1(6) . . ?
C50 C51 H51 120.4 . . ?
C52 C51 H51 120.4 . . ?
C47 C52 C51 120.4(5) . . ?
C47 C52 H52 119.8 . . ?
C51 C52 H52 119.8 . . ?
C58 C53 C54 118.9(5) . . ?
C58 C53 P2 121.7(4) . . ?
C54 C53 P2 119.3(4) . . ?
C55 C54 C53 121.0(5) . . ?
C55 C54 H54 119.5 . . ?
C53 C54 H54 119.5 . . ?
C56 C55 C54 119.8(5) . . ?
C56 C55 H55 120.1 . . ?
C54 C55 H55 120.1 . . ?
C55 C56 C57 119.6(5) . . ?
C55 C56 H56 120.2 . . ?
C57 C56 H56 120.2 . . ?
C58 C57 C56 120.1(5) . . ?
C58 C57 H57 120.0 . . ?
C56 C57 H57 120.0 . . ?
C53 C58 C57 120.6(5) . . ?
C53 C58 H58 119.7 . . ?
C57 C58 H58 119.7 . . ?
C60 C59 C64 117.7(5) . . ?
C60 C59 P2 123.9(4) . . ?
C64 C59 P2 118.4(4) . . ?
C61 C60 C59 120.5(5) . . ?
C61 C60 H60 119.7 . . ?
C59 C60 H60 119.7 . . ?
C62 C61 C60 120.1(6) . . ?
C62 C61 H61 120.0 . . ?
C60 C61 H61 120.0 . . ?
C63 C62 C61 119.8(6) . . ?
C63 C62 H62 120.1 . . ?
C61 C62 H62 120.1 . . ?
C64 C63 C62 120.1(6) . . ?
C64 C63 H63 120.0 . . ?
C62 C63 H63 120.0 . . ?
C63 C64 C59 121.8(6) . . ?
C63 C64 H64 119.1 . . ?
C59 C64 H64 119.1 . . ?
Cl1 C71 Cl2 112.1(4) . . ?
Cl1 C71 H71A 109.2 . . ?
Cl2 C71 H71A 109.2 . . ?
Cl1 C71 H71B 109.2 . . ?
Cl2 C71 H71B 109.2 . . ?
H71A C71 H71B 107.9 . . ?
F1 B1 F2 128.5(13) . . ?
F1 B1 F4 115.2(9) . . ?
F2 B1 F4 111.6(7) . . ?
F1 B1 F3 100.7(8) . . ?
F2 B1 F3 93.7(6) . . ?
F4 B1 F3 97.1(9) . . ?
B1 F1 Ag1 165.1(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 P1 2.4056(13) . ?
Ag1 P2 2.4179(13) . ?
Ag1 F1 2.455(5) . ?
P1 C1 1.808(5) . ?
P1 C47 1.818(5) . ?
P1 C41 1.822(6) . ?
P2 C59 1.803(6) . ?
P2 C22 1.801(5) . ?
P2 C53 1.826(5) . ?
O1 C4 1.376(5) . ?
O1 C29 1.427(7) . ?
O2 C11 1.384(6) . ?
O2 C32 1.424(6) . ?
O3 C18 1.380(6) . ?
O3 C35 1.450(8) . ?
O4 C25 1.394(6) . ?
O4 C38 1.438(6) . ?
C1 C6 1.389(6) . ?
C1 C2 1.398(6) . ?
C2 C3 1.396(6) . ?
C2 H2 0.9500 . ?
C3 C4 1.406(6) . ?
C3 C7 1.510(7) . ?
C4 C5 1.399(6) . ?
C5 C6 1.371(6) . ?
C5 C28 1.509(6) 3_556 ?
C6 H6 0.9500 . ?
C7 C10 1.511(7) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 C9 1.368(9) . ?
C8 C13 1.383(9) . ?
C8 H8 0.9500 . ?
C9 C10 1.382(8) . ?
C9 H9 0.9500 . ?
C10 C11 1.395(7) . ?
C11 C12 1.385(7) . ?
C12 C13 1.382(7) . ?
C12 C14 1.509(7) . ?
C13 H13 0.9500 . ?
C14 C19 1.524(7) 3_556 ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 C20 1.378(8) . ?
C15 C16 1.390(8) . ?
C15 H15 0.9500 . ?
C16 C17 1.394(7) . ?
C16 H16 0.9500 . ?
C17 C18 1.413(7) . ?
C17 C21 1.491(7) . ?
C18 C19 1.374(7) . ?
C19 C20 1.393(8) . ?
C19 C14 1.524(7) 3_556 ?
C20 H20 0.9500 . ?
C21 C26 1.524(6) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C22 C27 1.378(6) . ?
C22 C23 1.383(6) . ?
C23 C24 1.377(6) . ?
C23 H23 0.9500 . ?
C24 C25 1.406(6) . ?
C24 C28 1.513(6) . ?
C25 C26 1.384(6) . ?
C26 C27 1.375(7) . ?
C27 H27 0.9500 . ?
C28 C5 1.509(6) 3_556 ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 C30 1.282(12) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 C31 1.214(10) . ?
C30 H30 0.9500 . ?
C31 H31A 0.9500 . ?
C31 H31B 0.9500 . ?
C32 C33A 1.478(11) . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C33A C34A 1.35(2) . ?
C33A H33A 0.9900 . ?
C33A H33B 0.9900 . ?
C34A H34A 0.9800 . ?
C34A H34B 0.9800 . ?
C34A H34C 0.9800 . ?
C35 C36 1.446(9) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 C37 1.540(10) . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
C37 H37A 0.9800 . ?
C37 H37B 0.9800 . ?
C37 H37C 0.9800 . ?
C38 C39 1.498(13) . ?
C38 H38A 0.9900 . ?
C38 H38B 0.9900 . ?
C39 C40 1.095(18) . ?
C39 H39 0.9500 . ?
C40 H40A 0.9500 . ?
C40 H40B 0.9500 . ?
C41 C42 1.379(7) . ?
C41 C46 1.395(7) . ?
C42 C43 1.377(8) . ?
C42 H42 0.9500 . ?
C43 C44 1.361(10) . ?
C43 H43 0.9500 . ?
C44 C45 1.349(10) . ?
C44 H44 0.9500 . ?
C45 C46 1.416(9) . ?
C45 H45 0.9500 . ?
C46 H46 0.9500 . ?
C47 C52 1.382(7) . ?
C47 C48 1.387(7) . ?
C48 C49 1.367(7) . ?
C48 H48 0.9500 . ?
C49 C50 1.356(8) . ?
C49 H49 0.9500 . ?
C50 C51 1.365(8) . ?
C50 H50 0.9500 . ?
C51 C52 1.383(7) . ?
C51 H51 0.9500 . ?
C52 H52 0.9500 . ?
C53 C58 1.367(7) . ?
C53 C54 1.384(7) . ?
C54 C55 1.377(7) . ?
C54 H54 0.9500 . ?
C55 C56 1.375(7) . ?
C55 H55 0.9500 . ?
C56 C57 1.382(8) . ?
C56 H56 0.9500 . ?
C57 C58 1.385(8) . ?
C57 H57 0.9500 . ?
C58 H58 0.9500 . ?
C59 C60 1.391(7) . ?
C59 C64 1.395(8) . ?
C60 C61 1.384(8) . ?
C60 H60 0.9500 . ?
C61 C62 1.383(8) . ?
C61 H61 0.9500 . ?
C62 C63 1.373(9) . ?
C62 H62 0.9500 . ?
C63 C64 1.360(8) . ?
C63 H63 0.9500 . ?
C64 H64 0.9500 . ?
C71 Cl1 1.714(7) . ?
C71 Cl2 1.723(7) . ?
C71 H71A 0.9900 . ?
C71 H71B 0.9900 . ?
B1 F1 1.183(9) . ?
B1 F2 1.298(11) . ?
B1 F4 1.408(11) . ?
B1 F3 1.547(12) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P2 Ag1 P1 C1 79.6(2) . . . . ?
F1 Ag1 P1 C1 -128.4(3) . . . . ?
P2 Ag1 P1 C47 -153.88(18) . . . . ?
F1 Ag1 P1 C47 -1.8(3) . . . . ?
P2 Ag1 P1 C41 -35.5(2) . . . . ?
F1 Ag1 P1 C41 116.6(3) . . . . ?
P1 Ag1 P2 C59 49.7(2) . . . . ?
F1 Ag1 P2 C59 -104.4(3) . . . . ?
P1 Ag1 P2 C22 169.53(19) . . . . ?
F1 Ag1 P2 C22 15.4(3) . . . . ?
P1 Ag1 P2 C53 -68.7(2) . . . . ?
F1 Ag1 P2 C53 137.2(3) . . . . ?
C47 P1 C1 C6 179.4(4) . . . . ?
C41 P1 C1 C6 70.2(4) . . . . ?
Ag1 P1 C1 C6 -48.4(4) . . . . ?
C47 P1 C1 C2 0.3(5) . . . . ?
C41 P1 C1 C2 -109.0(4) . . . . ?
Ag1 P1 C1 C2 132.4(4) . . . . ?
C6 C1 C2 C3 -1.7(7) . . . . ?
P1 C1 C2 C3 177.4(4) . . . . ?
C1 C2 C3 C4 -2.3(8) . . . . ?
C1 C2 C3 C7 173.9(5) . . . . ?
C29 O1 C4 C5 -98.4(5) . . . . ?
C29 O1 C4 C3 85.8(6) . . . . ?
C2 C3 C4 O1 -179.0(4) . . . . ?
C7 C3 C4 O1 4.7(7) . . . . ?
C2 C3 C4 C5 5.2(8) . . . . ?
C7 C3 C4 C5 -171.1(5) . . . . ?
O1 C4 C5 C6 -179.6(4) . . . . ?
C3 C4 C5 C6 -3.9(7) . . . . ?
O1 C4 C5 C28 -3.3(7) . . . 3_556 ?
C3 C4 C5 C28 172.4(5) . . . 3_556 ?
C4 C5 C6 C1 -0.4(7) . . . . ?
C28 C5 C6 C1 -176.7(4) 3_556 . . . ?
C2 C1 C6 C5 3.1(7) . . . . ?
P1 C1 C6 C5 -176.0(4) . . . . ?
C2 C3 C7 C10 -114.9(5) . . . . ?
C4 C3 C7 C10 61.2(7) . . . . ?
C13 C8 C9 C10 2.7(8) . . . . ?
C8 C9 C10 C11 1.1(7) . . . . ?
C8 C9 C10 C7 -175.5(5) . . . . ?
C3 C7 C10 C9 60.2(6) . . . . ?
C3 C7 C10 C11 -116.2(5) . . . . ?
C32 O2 C11 C12 82.3(6) . . . . ?
C32 O2 C11 C10 -101.7(5) . . . . ?
C9 C10 C11 O2 178.5(4) . . . . ?
C7 C10 C11 O2 -5.0(7) . . . . ?
C9 C10 C11 C12 -5.5(7) . . . . ?
C7 C10 C11 C12 170.9(4) . . . . ?
O2 C11 C12 C13 -178.0(4) . . . . ?
C10 C11 C12 C13 6.1(7) . . . . ?
O2 C11 C12 C14 3.7(7) . . . . ?
C10 C11 C12 C14 -172.2(4) . . . . ?
C11 C12 C13 C8 -2.2(7) . . . . ?
C14 C12 C13 C8 176.1(5) . . . . ?
C9 C8 C13 C12 -2.1(8) . . . . ?
C13 C12 C14 C19 -53.1(7) . . . 3_556 ?
C11 C12 C14 C19 125.2(5) . . . 3_556 ?
C20 C15 C16 C17 3.5(10) . . . . ?
C15 C16 C17 C18 1.7(8) . . . . ?
C15 C16 C17 C21 -171.8(5) . . . . ?
C35 O3 C18 C19 106.5(6) . . . . ?
C35 O3 C18 C17 -78.4(6) . . . . ?
C16 C17 C18 C19 -7.2(8) . . . . ?
C21 C17 C18 C19 166.2(5) . . . . ?
C16 C17 C18 O3 177.8(5) . . . . ?
C21 C17 C18 O3 -8.8(7) . . . . ?
O3 C18 C19 C20 -177.8(5) . . . . ?
C17 C18 C19 C20 7.3(9) . . . . ?
O3 C18 C19 C14 7.1(8) . . . 3_556 ?
C17 C18 C19 C14 -167.8(5) . . . 3_556 ?
C16 C15 C20 C19 -3.5(10) . . . . ?
C18 C19 C20 C15 -1.8(10) . . . . ?
C14 C19 C20 C15 173.3(6) 3_556 . . . ?
C16 C17 C21 C26 108.5(5) . . . . ?
C18 C17 C21 C26 -64.5(6) . . . . ?
C59 P2 C22 C27 39.5(4) . . . . ?
C53 P2 C22 C27 150.5(4) . . . . ?
Ag1 P2 C22 C27 -82.7(4) . . . . ?
C59 P2 C22 C23 -147.1(4) . . . . ?
C53 P2 C22 C23 -36.1(4) . . . . ?
Ag1 P2 C22 C23 90.7(4) . . . . ?
C27 C22 C23 C24 2.9(7) . . . . ?
P2 C22 C23 C24 -170.8(3) . . . . ?
C22 C23 C24 C25 1.2(6) . . . . ?
C22 C23 C24 C28 -176.9(4) . . . . ?
C38 O4 C25 C26 99.2(5) . . . . ?
C38 O4 C25 C24 -82.7(5) . . . . ?
C23 C24 C25 C26 -5.4(6) . . . . ?
C28 C24 C25 C26 172.6(4) . . . . ?
C23 C24 C25 O4 176.5(4) . . . . ?
C28 C24 C25 O4 -5.5(6) . . . . ?
O4 C25 C26 C27 -176.7(4) . . . . ?
C24 C25 C26 C27 5.3(7) . . . . ?
O4 C25 C26 C21 6.2(6) . . . . ?
C24 C25 C26 C21 -171.8(4) . . . . ?
C17 C21 C26 C27 -61.3(6) . . . . ?
C17 C21 C26 C25 115.8(5) . . . . ?
C25 C26 C27 C22 -0.9(7) . . . . ?
C21 C26 C27 C22 176.3(4) . . . . ?
C23 C22 C27 C26 -3.1(7) . . . . ?
P2 C22 C27 C26 170.4(4) . . . . ?
C23 C24 C28 C5 53.8(6) . . . 3_556 ?
C25 C24 C28 C5 -124.2(5) . . . 3_556 ?
C4 O1 C29 C30 69.2(11) . . . . ?
O1 C29 C30 C31 -105.5(15) . . . . ?
C11 O2 C32 C33A -177.4(6) . . . . ?
O2 C32 C33A C34A -77.1(11) . . . . ?
C18 O3 C35 C36 -96.3(6) . . . . ?
O3 C35 C36 C37 -177.4(5) . . . . ?
C25 O4 C38 C39 -170.8(5) . . . . ?
O4 C38 C39 C40 -105.5(16) . . . . ?
C1 P1 C41 C42 13.0(5) . . . . ?
C47 P1 C41 C42 -99.3(5) . . . . ?
Ag1 P1 C41 C42 133.4(4) . . . . ?
C1 P1 C41 C46 -166.2(4) . . . . ?
C47 P1 C41 C46 81.5(4) . . . . ?
Ag1 P1 C41 C46 -45.8(4) . . . . ?
C46 C41 C42 C43 -0.4(8) . . . . ?
P1 C41 C42 C43 -179.6(4) . . . . ?
C41 C42 C43 C44 -1.1(9) . . . . ?
C42 C43 C44 C45 3.0(11) . . . . ?
C43 C44 C45 C46 -3.4(12) . . . . ?
C42 C41 C46 C45 0.1(8) . . . . ?
P1 C41 C46 C45 179.3(5) . . . . ?
C44 C45 C46 C41 1.9(10) . . . . ?
C1 P1 C47 C52 103.0(4) . . . . ?
C41 P1 C47 C52 -147.4(4) . . . . ?
Ag1 P1 C47 C52 -25.7(4) . . . . ?
C1 P1 C47 C48 -79.1(4) . . . . ?
C41 P1 C47 C48 30.4(4) . . . . ?
Ag1 P1 C47 C48 152.1(3) . . . . ?
C52 C47 C48 C49 0.6(7) . . . . ?
P1 C47 C48 C49 -177.3(4) . . . . ?
C47 C48 C49 C50 0.5(8) . . . . ?
C48 C49 C50 C51 -1.6(8) . . . . ?
C49 C50 C51 C52 1.5(8) . . . . ?
C48 C47 C52 C51 -0.6(7) . . . . ?
P1 C47 C52 C51 177.4(4) . . . . ?
C50 C51 C52 C47 -0.5(8) . . . . ?
C59 P2 C53 C58 70.2(5) . . . . ?
C22 P2 C53 C58 -41.3(5) . . . . ?
Ag1 P2 C53 C58 -168.5(4) . . . . ?
C59 P2 C53 C54 -110.8(5) . . . . ?
C22 P2 C53 C54 137.8(4) . . . . ?
Ag1 P2 C53 C54 10.5(5) . . . . ?
C58 C53 C54 C55 -1.3(9) . . . . ?
P2 C53 C54 C55 179.6(4) . . . . ?
C53 C54 C55 C56 0.7(9) . . . . ?
C54 C55 C56 C57 -0.7(9) . . . . ?
C55 C56 C57 C58 1.4(10) . . . . ?
C54 C53 C58 C57 1.9(9) . . . . ?
P2 C53 C58 C57 -179.0(5) . . . . ?
C56 C57 C58 C53 -2.0(10) . . . . ?
C22 P2 C59 C60 32.9(5) . . . . ?
C53 P2 C59 C60 -77.9(5) . . . . ?
Ag1 P2 C59 C60 158.1(4) . . . . ?
C22 P2 C59 C64 -148.8(4) . . . . ?
C53 P2 C59 C64 100.4(4) . . . . ?
Ag1 P2 C59 C64 -23.5(5) . . . . ?
C64 C59 C60 C61 0.4(8) . . . . ?
P2 C59 C60 C61 178.8(4) . . . . ?
C59 C60 C61 C62 -1.1(8) . . . . ?
C60 C61 C62 C63 0.8(9) . . . . ?
C61 C62 C63 C64 0.2(10) . . . . ?
C62 C63 C64 C59 -0.8(9) . . . . ?
C60 C59 C64 C63 0.5(8) . . . . ?
P2 C59 C64 C63 -177.9(5) . . . . ?
F2 B1 F1 Ag1 -48(5) . . . . ?
F4 B1 F1 Ag1 159(3) . . . . ?
F3 B1 F1 Ag1 56(4) . . . . ?
P1 Ag1 F1 B1 0(4) . . . . ?
P2 Ag1 F1 B1 168(4) . . . . ?
