#------------------------------------------------------------------------------
#$Date: 2018-09-26 06:29:44 +0300 (Wed, 26 Sep 2018) $
#$Revision: 211175 $
#$URL: file:///home/coder/svn-repositories/cod/cif/8/10/32/8103264.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8103264
loop_
_publ_author_name
'You-Jun Di'
'Jun-Feng Wang'
_publ_section_title
;
 Crystal structure of caesium diaquamanganese(II) gallium phosphate,
 Cs[MnGa2(PO4)3(H2O)2]
;
_journal_issue                   4
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              435
_journal_volume                  226
_journal_year                    2011
_chemical_formula_sum            'Cs Ga2 H4 Mn O14 P3'
_chemical_formula_weight         648.23
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 109.125(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.482(5)
_cell_length_b                   10.407(3)
_cell_length_c                   8.913(3)
_cell_measurement_reflns_used    2291
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.14
_cell_measurement_theta_min      2.53
_cell_volume                     1181.5(7)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0163
_diffrn_reflns_av_sigmaI/netI    0.0176
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            2993
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.53
_exptl_absorpt_coefficient_mu    9.102
_exptl_absorpt_correction_T_max  0.5296
_exptl_absorpt_correction_T_min  0.3422
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    3.644
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1212
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.492
_refine_diff_density_min         -0.528
_refine_diff_density_rms         0.101
_refine_ls_extinction_coef       0.00074(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     106
_refine_ls_number_reflns         1040
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0180
_refine_ls_R_factor_gt           0.0169
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0297P)²+2.8175P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0468
_refine_ls_wR_factor_ref         0.0473
_reflns_number_gt                994
_reflns_number_total             1040
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            710069.cff
_cod_data_source_block           a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1181.6(7)
_cod_original_sg_symbol_H-M      'C2/c  '
_cod_database_code               8103264
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cs1 Cs 0.0000 0.63967(3) 0.2500 0.02133(13) Uani 1 2 d S
Ga1 Ga -0.17122(3) -0.07529(3) -0.07591(4) 0.00908(13) Uani 1 1 d .
Mn1 Mn 0.0000 -0.28166(7) -0.2500 0.01250(18) Uani 1 2 d S
P1 P -0.29044(6) 0.12834(8) -0.32946(10) 0.0095(2) Uani 1 1 d .
P2 P 0.0000 0.00394(11) 0.2500 0.0087(2) Uani 1 2 d S
O1 O -0.27250(17) -0.0501(2) 0.0354(3) 0.0129(5) Uani 1 1 d .
O2 O -0.20974(18) 0.0856(2) -0.1679(3) 0.0132(5) Uani 1 1 d .
O3 O -0.23615(17) -0.2285(2) -0.1597(3) 0.0129(5) Uani 1 1 d .
O4 O -0.05758(18) -0.0850(2) 0.1126(3) 0.0127(5) Uani 1 1 d .
O5 O -0.07368(17) -0.0972(2) -0.2028(3) 0.0128(5) Uani 1 1 d .
O6 O -0.09765(18) -0.3927(2) -0.1652(3) 0.0158(5) Uani 1 1 d .
O1W O 0.1199(2) -0.3019(3) -0.0120(3) 0.0237(6) Uani 1 1 d .
H2 H 0.152(4) -0.359(4) 0.000(5) 0.018(13) Uiso 1 1 d .
H1 H 0.159(4) -0.251(5) 0.034(6) 0.035(15) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cs Cs -0.3680 2.1192 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O6 Cs1 O6 67.56(9) 6_556 5
O6 Cs1 O4 137.74(6) 6_556 2_565
O6 Cs1 O4 142.19(6) 5 2_565
O6 Cs1 O4 142.19(6) 6_556 1_565
O6 Cs1 O4 137.74(6) 5 1_565
O4 Cs1 O4 46.00(8) 2_565 1_565
O6 Cs1 O1W 68.53(8) 6_556 2_565
O6 Cs1 O1W 132.22(7) 5 2_565
O4 Cs1 O1W 70.68(7) 2_565 2_565
O4 Cs1 O1W 89.54(8) 1_565 2_565
O6 Cs1 O1W 132.22(7) 6_556 1_565
O6 Cs1 O1W 68.53(8) 5 1_565
O4 Cs1 O1W 89.54(8) 2_565 1_565
O4 Cs1 O1W 70.68(7) 1_565 1_565
O1W Cs1 O1W 158.79(13) 2_565 1_565
O6 Cs1 O1 66.71(6) 6_556 7_455
O6 Cs1 O1 86.64(6) 5 7_455
O4 Cs1 O1 126.32(6) 2_565 7_455
O4 Cs1 O1 84.87(6) 1_565 7_455
O1W Cs1 O1 92.80(7) 2_565 7_455
O1W Cs1 O1 92.96(7) 1_565 7_455
O6 Cs1 O1 86.64(6) 6_556 8_556
O6 Cs1 O1 66.71(6) 5 8_556
O4 Cs1 O1 84.87(6) 2_565 8_556
O4 Cs1 O1 126.32(6) 1_565 8_556
O1W Cs1 O1 92.96(7) 2_565 8_556
O1W Cs1 O1 92.80(7) 1_565 8_556
O1 Cs1 O1 148.30(8) 7_455 8_556
O6 Cs1 O3 130.13(6) 6_556 8_556
O6 Cs1 O3 78.11(6) 5 8_556
O4 Cs1 O3 64.11(5) 2_565 8_556
O4 Cs1 O3 87.20(6) 1_565 8_556
O1W Cs1 O3 118.96(6) 2_565 8_556
O1W Cs1 O3 54.46(6) 1_565 8_556
O1 Cs1 O3 147.18(5) 7_455 8_556
O1 Cs1 O3 45.87(5) 8_556 8_556
O6 Cs1 O3 78.11(6) 6_556 7_455
O6 Cs1 O3 130.13(6) 5 7_455
O4 Cs1 O3 87.20(6) 2_565 7_455
O4 Cs1 O3 64.11(5) 1_565 7_455
O1W Cs1 O3 54.46(6) 2_565 7_455
O1W Cs1 O3 118.96(6) 1_565 7_455
O1 Cs1 O3 45.87(5) 7_455 7_455
O1 Cs1 O3 147.18(5) 8_556 7_455
O3 Cs1 O3 149.41(7) 8_556 7_455
O6 Cs1 O6 97.77(5) 6_556 1_565
O6 Cs1 O6 72.88(7) 5 1_565
O4 Cs1 O6 117.49(6) 2_565 1_565
O4 Cs1 O6 73.43(6) 1_565 1_565
O1W Cs1 O6 131.37(6) 2_565 1_565
O1W Cs1 O6 51.27(6) 1_565 1_565
O1 Cs1 O6 41.69(5) 7_455 1_565
O1 Cs1 O6 133.98(5) 8_556 1_565
O3 Cs1 O6 105.60(5) 8_556 1_565
O3 Cs1 O6 77.39(5) 7_455 1_565
O6 Cs1 O6 72.88(7) 6_556 2_565
O6 Cs1 O6 97.77(5) 5 2_565
O4 Cs1 O6 73.43(6) 2_565 2_565
O4 Cs1 O6 117.49(6) 1_565 2_565
O1W Cs1 O6 51.27(6) 2_565 2_565
O1W Cs1 O6 131.37(6) 1_565 2_565
O1 Cs1 O6 133.98(5) 7_455 2_565
O1 Cs1 O6 41.69(5) 8_556 2_565
O3 Cs1 O6 77.39(5) 8_556 2_565
O3 Cs1 O6 105.60(5) 7_455 2_565
O6 Cs1 O6 169.01(8) 1_565 2_565
O3 Ga1 O2 124.69(10) . .
O3 Ga1 O4 117.09(10) . .
O2 Ga1 O4 118.21(10) . .
O3 Ga1 O1 90.21(10) . .
O2 Ga1 O1 87.85(10) . .
O4 Ga1 O1 93.10(10) . .
O3 Ga1 O5 89.15(9) . .
O2 Ga1 O5 89.65(9) . .
O4 Ga1 O5 90.29(10) . .
O1 Ga1 O5 176.46(9) . .
O3 Ga1 Cs1 54.41(7) . 7_455
O2 Ga1 Cs1 82.74(7) . 7_455
O4 Ga1 Cs1 140.42(7) . 7_455
O1 Ga1 Cs1 52.10(7) . 7_455
O5 Ga1 Cs1 125.05(7) . 7_455
O3 Ga1 Cs1 75.82(7) . 1_545
O2 Ga1 Cs1 159.47(7) . 1_545
O4 Ga1 Cs1 41.28(7) . 1_545
O1 Ga1 Cs1 93.42(7) . 1_545
O5 Ga1 Cs1 89.80(7) . 1_545
Cs1 Ga1 Cs1 114.014(15) 7_455 1_545
O6 Mn1 O6 112.21(13) . 2_554
O6 Mn1 O1W 86.83(11) . 2_554
O6 Mn1 O1W 87.09(11) 2_554 2_554
O6 Mn1 O1W 87.09(11) . .
O6 Mn1 O1W 86.83(11) 2_554 .
O1W Mn1 O1W 169.08(19) 2_554 .
O6 Mn1 O5 155.63(9) . 2_554
O6 Mn1 O5 92.01(9) 2_554 2_554
O1W Mn1 O5 97.46(11) 2_554 2_554
O1W Mn1 O5 91.81(11) . 2_554
O6 Mn1 O5 92.01(9) . .
O6 Mn1 O5 155.63(9) 2_554 .
O1W Mn1 O5 91.81(11) 2_554 .
O1W Mn1 O5 97.46(11) . .
O5 Mn1 O5 63.97(11) 2_554 .
O6 Mn1 P2 123.90(7) . 5
O6 Mn1 P2 123.90(7) 2_554 5
O1W Mn1 P2 95.46(9) 2_554 5
O1W Mn1 P2 95.46(9) . 5
O5 Mn1 P2 31.99(6) 2_554 5
O5 Mn1 P2 31.99(6) . 5
O6 Mn1 Cs1 56.10(7) . 5
O6 Mn1 Cs1 56.10(7) 2_554 5
O1W Mn1 Cs1 84.54(9) 2_554 5
O1W Mn1 Cs1 84.54(9) . 5
O5 Mn1 Cs1 148.01(6) 2_554 5
O5 Mn1 Cs1 148.01(6) . 5
P2 Mn1 Cs1 180.0 5 5
O6 P1 O1 108.10(13) 4_454 6
O6 P1 O3 112.84(13) 4_454 4_454
O1 P1 O3 111.28(13) 6 4_454
O6 P1 O2 112.07(13) 4_454 .
O1 P1 O2 109.37(13) 6 .
O3 P1 O2 103.13(13) 4_454 .
O6 P1 Cs1 64.58(10) 4_454 3_444
O1 P1 Cs1 60.77(9) 6 3_444
O3 P1 Cs1 91.19(9) 4_454 3_444
O2 P1 Cs1 165.16(10) . 3_444
O6 P1 Cs1 35.62(10) 4_454 7_455
O1 P1 Cs1 93.89(9) 6 7_455
O3 P1 Cs1 146.75(9) 4_454 7_455
O2 P1 Cs1 87.65(9) . 7_455
Cs1 P1 Cs1 82.30(2) 3_444 7_455
O4 P2 O4 105.46(18) . 2
O4 P2 O5 111.47(12) . 5
O4 P2 O5 113.33(12) 2 5
O4 P2 O5 113.33(12) . 6_556
O4 P2 O5 111.47(12) 2 6_556
O5 P2 O5 102.01(18) 5 6_556
O4 P2 Mn1 127.27(9) . 5
O4 P2 Mn1 127.27(9) 2 5
O5 P2 Mn1 51.00(9) 5 5
O5 P2 Mn1 51.00(9) 6_556 5
O4 P2 Cs1 52.73(9) . 1_545
O4 P2 Cs1 52.73(9) 2 1_545
O5 P2 Cs1 129.00(9) 5 1_545
O5 P2 Cs1 129.00(9) 6_556 1_545
Mn1 P2 Cs1 180.0 5 1_545
P1 O1 Ga1 130.07(14) 6_556 .
P1 O1 Cs1 96.08(10) 6_556 7_455
Ga1 O1 Cs1 101.07(9) . 7_455
P1 O2 Ga1 132.30(15) . .
P1 O3 Ga1 140.07(15) 4_444 .
P1 O3 Cs1 118.66(11) 4_444 7_455
Ga1 O3 Cs1 100.10(8) . 7_455
P2 O4 Ga1 137.65(14) . .
P2 O4 Cs1 104.27(11) . 1_545
Ga1 O4 Cs1 115.39(9) . 1_545
P2 O5 Ga1 132.91(14) 5 .
P2 O5 Mn1 97.01(11) 5 .
Ga1 O5 Mn1 127.52(11) . .
P1 O6 Mn1 130.97(14) 4_444 .
P1 O6 Cs1 127.86(13) 4_444 5
Mn1 O6 Cs1 90.11(8) . 5
P1 O6 Cs1 92.59(10) 4_444 1_545
Mn1 O6 Cs1 105.50(9) . 1_545
Cs1 O6 Cs1 107.12(7) 5 1_545
Mn1 O1W Cs1 108.77(11) . 1_545
Mn1 O1W H2 116(3) . .
Cs1 O1W H2 99(3) 1_545 .
Mn1 O1W H1 127(4) . .
Cs1 O1W H1 99(3) 1_545 .
H2 O1W H1 103(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cs1 O6 3.093(2) 6_556
Cs1 O6 3.093(2) 5
Cs1 O4 3.113(2) 2_565
Cs1 O4 3.113(2) 1_565
Cs1 O1W 3.303(3) 2_565
Cs1 O1W 3.303(3) 1_565
Cs1 O1 3.411(2) 7_455
Cs1 O1 3.411(2) 8_556
Cs1 O3 3.504(2) 8_556
Cs1 O3 3.504(2) 7_455
Cs1 O6 3.514(3) 1_565
Cs1 O6 3.514(3) 2_565
Ga1 O3 1.854(2) .
Ga1 O2 1.862(2) .
Ga1 O4 1.869(2) .
Ga1 O1 1.951(2) .
Ga1 O5 2.009(2) .
Ga1 Cs1 4.2424(14) 7_455
Ga1 Cs1 4.2630(10) 1_545
Mn1 O6 2.072(2) .
Mn1 O6 2.072(2) 2_554
Mn1 O1W 2.216(3) 2_554
Mn1 O1W 2.216(3) .
Mn1 O5 2.263(2) 2_554
Mn1 O5 2.263(2) .
Mn1 P2 2.8903(17) 5
Mn1 Cs1 3.7258(14) 5
P1 O6 1.510(2) 4_454
P1 O1 1.537(2) 6
P1 O3 1.543(2) 4_454
P1 O2 1.559(2) .
P1 Cs1 3.8868(13) 3_444
P1 Cs1 4.1921(12) 7_455
P2 O4 1.529(2) .
P2 O4 1.529(2) 2
P2 O5 1.542(2) 5
P2 O5 1.542(2) 6_556
P2 Mn1 2.8903(17) 5
P2 Cs1 3.7910(17) 1_545
O1 P1 1.537(2) 6_556
O1 Cs1 3.411(2) 7_455
O3 P1 1.543(2) 4_444
O3 Cs1 3.504(2) 7_455
O4 Cs1 3.113(2) 1_545
O5 P2 1.542(2) 5
O6 P1 1.510(2) 4_444
O6 Cs1 3.093(2) 5
O6 Cs1 3.514(3) 1_545
O1W Cs1 3.303(3) 1_545
O1W H2 0.72(5) .
O1W H1 0.77(5) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H2 O1 0.72(5) 2.21(5) 2.925(4) 171(5) 3_545
O1W H1 O2 0.77(5) 2.08(6) 2.799(4) 157(5) 5
O1W H1 O3 0.77(5) 2.64(5) 3.120(4) 122(4) 8_546
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O3 Ga1 O1 P1 65.56(19) . 6_556
O2 Ga1 O1 P1 -169.73(19) . 6_556
O4 Ga1 O1 P1 -51.59(19) . 6_556
O5 Ga1 O1 P1 145.1(14) . 6_556
Cs1 Ga1 O1 P1 107.80(19) 7_455 6_556
Cs1 Ga1 O1 P1 -10.24(18) 1_545 6_556
O3 Ga1 O1 Cs1 -42.24(9) . 7_455
O2 Ga1 O1 Cs1 82.47(9) . 7_455
O4 Ga1 O1 Cs1 -159.39(8) . 7_455
O5 Ga1 O1 Cs1 37.3(16) . 7_455
Cs1 Ga1 O1 Cs1 -118.04(5) 1_545 7_455
O6 P1 O2 Ga1 69.7(2) 4_454 .
O1 P1 O2 Ga1 -50.1(2) 6 .
O3 P1 O2 Ga1 -168.62(17) 4_454 .
Cs1 P1 O2 Ga1 -4.1(5) 3_444 .
Cs1 P1 O2 Ga1 43.18(17) 7_455 .
O3 Ga1 O2 P1 -6.2(2) . .
O4 Ga1 O2 P1 172.65(16) . .
O1 Ga1 O2 P1 -94.98(19) . .
O5 Ga1 O2 P1 82.51(19) . .
Cs1 Ga1 O2 P1 -42.93(17) 7_455 .
Cs1 Ga1 O2 P1 171.01(6) 1_545 .
O2 Ga1 O3 P1 146.80(19) . 4_444
O4 Ga1 O3 P1 -32.1(3) . 4_444
O1 Ga1 O3 P1 -125.7(2) . 4_444
O5 Ga1 O3 P1 57.8(2) . 4_444
Cs1 Ga1 O3 P1 -166.4(3) 7_455 4_444
Cs1 Ga1 O3 P1 -32.2(2) 1_545 4_444
O2 Ga1 O3 Cs1 -46.82(12) . 7_455
O4 Ga1 O3 Cs1 134.30(9) . 7_455
O1 Ga1 O3 Cs1 40.71(8) . 7_455
O5 Ga1 O3 Cs1 -135.80(8) . 7_455
Cs1 Ga1 O3 Cs1 134.19(6) 1_545 7_455
O4 P2 O4 Ga1 159.3(3) 2 .
O5 P2 O4 Ga1 -77.3(2) 5 .
O5 P2 O4 Ga1 37.1(2) 6_556 .
Mn1 P2 O4 Ga1 -20.7(3) 5 .
Cs1 P2 O4 Ga1 159.3(3) 1_545 .
O4 P2 O4 Cs1 0.0 2 1_545
O5 P2 O4 Cs1 123.40(11) 5 1_545
O5 P2 O4 Cs1 -122.21(11) 6_556 1_545
Mn1 P2 O4 Cs1 180.0 5 1_545
O3 Ga1 O4 P2 -157.93(19) . .
O2 Ga1 O4 P2 23.1(2) . .
O1 Ga1 O4 P2 -66.1(2) . .
O5 Ga1 O4 P2 112.9(2) . .
Cs1 Ga1 O4 P2 -92.0(2) 7_455 .
Cs1 Ga1 O4 P2 -157.8(3) 1_545 .
O3 Ga1 O4 Cs1 -0.17(14) . 1_545
O2 Ga1 O4 Cs1 -179.13(9) . 1_545
O1 Ga1 O4 Cs1 91.65(10) . 1_545
O5 Ga1 O4 Cs1 -89.36(10) . 1_545
Cs1 Ga1 O4 Cs1 65.81(14) 7_455 1_545
O3 Ga1 O5 P2 163.60(19) . 5
O2 Ga1 O5 P2 38.89(19) . 5
O4 Ga1 O5 P2 -79.31(19) . 5
O1 Ga1 O5 P2 84.0(16) . 5
Cs1 Ga1 O5 P2 119.77(16) 7_455 5
Cs1 Ga1 O5 P2 -120.59(18) 1_545 5
O3 Ga1 O5 Mn1 -38.91(14) . .
O2 Ga1 O5 Mn1 -163.61(14) . .
O4 Ga1 O5 Mn1 78.19(14) . .
O1 Ga1 O5 Mn1 -118.5(15) . .
Cs1 Ga1 O5 Mn1 -82.74(14) 7_455 .
Cs1 Ga1 O5 Mn1 36.91(12) 1_545 .
O6 Mn1 O5 P2 175.69(11) . 5
O6 Mn1 O5 P2 -10.5(3) 2_554 5
O1W Mn1 O5 P2 -97.42(12) 2_554 5
O1W Mn1 O5 P2 88.36(12) . 5
O5 Mn1 O5 P2 0.0 2_554 5
Cs1 Mn1 O5 P2 180.0 5 5
O6 Mn1 O5 Ga1 12.09(14) . .
O6 Mn1 O5 Ga1 -174.09(16) 2_554 .
O1W Mn1 O5 Ga1 98.98(16) 2_554 .
O1W Mn1 O5 Ga1 -75.23(15) . .
O5 Mn1 O5 Ga1 -163.6(2) 2_554 .
P2 Mn1 O5 Ga1 -163.6(2) 5 .
Cs1 Mn1 O5 Ga1 16.4(2) 5 .
O6 Mn1 O6 P1 -144.5(2) 2_554 4_444
O1W Mn1 O6 P1 -59.0(2) 2_554 4_444
O1W Mn1 O6 P1 130.1(2) . 4_444
O5 Mn1 O6 P1 42.1(3) 2_554 4_444
O5 Mn1 O6 P1 32.71(19) . 4_444
P2 Mn1 O6 P1 35.5(2) 5 4_444
Cs1 Mn1 O6 P1 -144.5(2) 5 4_444
O6 Mn1 O6 Cs1 0.0 2_554 5
O1W Mn1 O6 Cs1 85.55(10) 2_554 5
O1W Mn1 O6 Cs1 -85.38(10) . 5
O5 Mn1 O6 Cs1 -173.32(17) 2_554 5
O5 Mn1 O6 Cs1 177.25(7) . 5
P2 Mn1 O6 Cs1 180.0 5 5
O6 Mn1 O6 Cs1 107.83(8) 2_554 1_545
O1W Mn1 O6 Cs1 -166.62(11) 2_554 1_545
O1W Mn1 O6 Cs1 22.45(11) . 1_545
O5 Mn1 O6 Cs1 -65.5(2) 2_554 1_545
O5 Mn1 O6 Cs1 -74.93(8) . 1_545
P2 Mn1 O6 Cs1 -72.17(8) 5 1_545
Cs1 Mn1 O6 Cs1 107.83(8) 5 1_545
O6 Mn1 O1W Cs1 -24.42(11) . 1_545
O6 Mn1 O1W Cs1 -136.87(12) 2_554 1_545
O1W Mn1 O1W Cs1 -80.63(10) 2_554 1_545
O5 Mn1 O1W Cs1 131.22(11) 2_554 1_545
O5 Mn1 O1W Cs1 67.24(12) . 1_545
P2 Mn1 O1W Cs1 99.37(10) 5 1_545
Cs1 Mn1 O1W Cs1 -80.63(10) 5 1_545
