#------------------------------------------------------------------------------
#$Date: 2023-02-02 10:29:13 +0200 (Thu, 02 Feb 2023) $
#$Revision: 280748 $
#$URL: file:///home/coder/svn-repositories/cod/cif/8/10/66/8106658.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8106658
loop_
_publ_author_name
'Su, Qiong'
'Wang, Yan-Bin'
_publ_section_title
;
 Crystal structure of
 bis(pyridine)-bis(2-formyl-4,6-dichlorophenolato)cobalt(II),
 C24H16Cl4CoN2O4
;
_journal_issue                   5
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              729
_journal_page_last               730
_journal_paper_doi               10.1515/ncrs-2016-0386
_journal_volume                  232
_journal_year                    2017
_chemical_formula_moiety         'C24 H16 Cl4 Co N2 O4'
_chemical_formula_sum            'C24 H16 Cl4 Co N2 O4'
_chemical_formula_weight         597.12
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                115.198(12)
_cell_angle_beta                 101.596(11)
_cell_angle_gamma                96.518(12)
_cell_formula_units_Z            2
_cell_length_a                   8.6148(13)
_cell_length_b                   12.2201(16)
_cell_length_c                   13.4807(16)
_cell_measurement_reflns_used    1582
_cell_measurement_temperature    173.00(10)
_cell_measurement_theta_max      24.2040
_cell_measurement_theta_min      3.6640
_cell_volume                     1225.8(3)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_diffrn_ambient_temperature      173.00(10)
_diffrn_detector_area_resol_mean 16.0733
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details
;
#__ type_ start__ end____ width___ exp.time_
  1 omega   -7.00   23.00   1.5000    1.5000
omega____ theta____ kappa____ phi______ frames
    -      -16.1227  -99.0000    0.0000 20

#__ type_ start__ end____ width___ exp.time_
  2 omega  -18.00   24.00   1.5000    1.5000
omega____ theta____ kappa____ phi______ frames
    -      -16.1227  -99.0000 -120.0000 28

#__ type_ start__ end____ width___ exp.time_
  3 omega  -52.00   23.00   1.5000    1.5000
omega____ theta____ kappa____ phi______ frames
    -       20.7321  -19.0000 -150.0000 50

#__ type_ start__ end____ width___ exp.time_
  4 omega  -46.00   42.50   1.5000    1.5000
omega____ theta____ kappa____ phi______ frames
    -       20.7321  -57.0000  -30.0000 59

#__ type_ start__ end____ width___ exp.time_
  5 omega  -41.00   37.00   1.5000    1.5000
omega____ theta____ kappa____ phi______ frames
    -       20.7321  -57.0000   90.0000 52

#__ type_ start__ end____ width___ exp.time_
  6 omega  -18.00   48.00   1.5000    1.5000
omega____ theta____ kappa____ phi______ frames
    -       20.7321  -99.0000 -150.0000 44
;
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0833164000
_diffrn_orient_matrix_UB_12      -0.0013974000
_diffrn_orient_matrix_UB_13      0.0056910000
_diffrn_orient_matrix_UB_21      -0.0068233000
_diffrn_orient_matrix_UB_22      -0.0391204000
_diffrn_orient_matrix_UB_23      0.0262412000
_diffrn_orient_matrix_UB_31      -0.0212530000
_diffrn_orient_matrix_UB_32      -0.0529263000
_diffrn_orient_matrix_UB_33      -0.0542415000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0439
_diffrn_reflns_av_unetI/netI     0.0910
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            8572
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         26.02
_diffrn_reflns_theta_min         3.40
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    1.171
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.77656
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28 (release 01-02-2013 CrysAlis171 .NET)
(compiled Feb  1 2013,16:14:44)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear light violet'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    violet
_exptl_crystal_density_diffrn    1.618
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             602
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.21
_refine_diff_density_max         0.537
_refine_diff_density_min         -0.601
_refine_diff_density_rms         0.087
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     316
_refine_ls_number_reflns         4822
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.0859
_refine_ls_R_factor_gt           0.0524
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0259P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0874
_refine_ls_wR_factor_ref         0.1109
_reflns_number_gt                3276
_reflns_number_total             4822
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            suppl_ncrs-2016-0386_suppl.cif
_cod_data_source_block           1
_cod_database_code               8106658
_reflns_odcompleteness_completeness 99.76
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C15(H15), C7(H7), C5(H5), C8(H8), C19(H19), C3(H3), C12(H12), C18(H18),
 C16(H16), C24(H24), C10(H10), C22(H22), C23(H23), C17(H17), C20(H20), C21(H21)
;
_olex2_date_sample_data_collection 2015-02-02
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_refinement_flags_posn
Co1 Co 0.32944(7) 0.47584(4) 0.24647(4) 0.02622(16) Uani 1 d . . .
Cl4 Cl 0.19575(14) 0.13685(9) -0.13505(8) 0.0397(3) Uani 1 d . . .
Cl1 Cl 0.39082(16) 0.79832(9) 0.62842(8) 0.0492(3) Uani 1 d . . .
Cl2 Cl 0.86342(15) 1.09512(9) 0.59419(10) 0.0528(3) Uani 1 d . . .
Cl3 Cl 0.78793(17) 0.03394(10) -0.06078(10) 0.0600(4) Uani 1 d . . .
O4 O 0.3144(3) 0.3253(2) 0.10052(19) 0.0306(7) Uani 1 d . . .
O1 O 0.3618(3) 0.6353(2) 0.38993(18) 0.0265(6) Uani 1 d . . .
O2 O 0.4366(3) 0.5898(2) 0.18370(19) 0.0306(7) Uani 1 d . . .
O3 O 0.5678(3) 0.4619(2) 0.3077(2) 0.0346(7) Uani 1 d . . .
N2 N 0.2276(4) 0.3698(3) 0.3190(2) 0.0301(8) Uani 1 d . . .
N1 N 0.0886(4) 0.4832(3) 0.1736(2) 0.0277(8) Uani 1 d . . .
C15 C 0.0240(5) 0.5759(4) 0.2328(3) 0.0373(11) Uani 1 d . . .
H15 H 0.0841 0.6336 0.3064 0.045 Uiso 1 calc . . R
C6 C 0.5571(5) 0.7703(3) 0.3643(3) 0.0240(9) Uani 1 d . . .
C7 C 0.5249(5) 0.6946(3) 0.2438(3) 0.0301(9) Uani 1 d . . .
H7 H 0.5771 0.7288 0.2061 0.036 Uiso 1 calc . . R
C5 C 0.6773(5) 0.8816(3) 0.4152(3) 0.0324(10) Uani 1 d . . .
H5 H 0.7343 0.9016 0.3712 0.039 Uiso 1 calc . . R
C14 C 0.4209(5) 0.2647(3) 0.0697(3) 0.0254(9) Uani 1 d . . .
C9 C 0.5801(5) 0.2850(3) 0.1405(3) 0.0266(9) Uani 1 d . . .
C8 C 0.6380(5) 0.3844(3) 0.2559(3) 0.0330(10) Uani 1 d . . .
H8 H 0.7425 0.3901 0.2959 0.040 Uiso 1 calc . . R
C19 C -0.0022(5) 0.3995(3) 0.0678(3) 0.0291(9) Uani 1 d . . .
H19 H 0.0392 0.3330 0.0255 0.035 Uiso 1 calc . . R
C2 C 0.5037(5) 0.8271(3) 0.5460(3) 0.0283(9) Uani 1 d . . .
C1 C 0.4686(5) 0.7362(3) 0.4293(3) 0.0240(9) Uani 1 d . . .
C13 C 0.3870(5) 0.1653(3) -0.0440(3) 0.0306(10) Uani 1 d . . .
C11 C 0.6469(6) 0.1195(3) -0.0104(3) 0.0357(10) Uani 1 d . . .
C4 C 0.7097(5) 0.9594(3) 0.5281(3) 0.0313(10) Uani 1 d . . .
C3 C 0.6222(5) 0.9339(3) 0.5943(3) 0.0327(10) Uani 1 d . . .
H3 H 0.6438 0.9891 0.6713 0.039 Uiso 1 calc . . R
C12 C 0.4947(6) 0.0964(3) -0.0827(3) 0.0357(11) Uani 1 d . . .
H12 H 0.4664 0.0337 -0.1575 0.043 Uiso 1 calc . . R
C18 C -0.1538(5) 0.4091(3) 0.0201(3) 0.0327(10) Uani 1 d . . .
H18 H -0.2128 0.3503 -0.0535 0.039 Uiso 1 calc . . R
C16 C -0.1261(6) 0.5899(4) 0.1904(4) 0.0452(12) Uani 1 d . . .
H16 H -0.1665 0.6558 0.2347 0.054 Uiso 1 calc . . R
C24 C 0.1448(6) 0.2527(3) 0.2521(3) 0.0418(11) Uani 1 d . . .
H24 H 0.1445 0.2168 0.1758 0.050 Uiso 1 calc . . R
C10 C 0.6901(5) 0.2114(3) 0.0999(3) 0.0352(10) Uani 1 d . . .
H10 H 0.7920 0.2254 0.1482 0.042 Uiso 1 calc . . R
C22 C 0.0597(6) 0.2312(4) 0.3980(4) 0.0465(13) Uani 1 d . . .
H22 H 0.0013 0.1860 0.4246 0.056 Uiso 1 calc . . R
C23 C 0.0604(6) 0.1820(4) 0.2882(4) 0.0508(13) Uani 1 d . . .
H23 H 0.0043 0.1009 0.2373 0.061 Uiso 1 calc . . R
C17 C -0.2173(5) 0.5059(4) 0.0817(3) 0.0421(11) Uani 1 d . . .
H17 H -0.3192 0.5145 0.0509 0.051 Uiso 1 calc . . R
C20 C 0.2281(7) 0.4136(4) 0.4261(3) 0.0648(17) Uani 1 d . . .
H20 H 0.2876 0.4939 0.4765 0.078 Uiso 1 calc . . R
C21 C 0.1461(8) 0.3485(4) 0.4691(4) 0.077(2) Uani 1 d . . .
H21 H 0.1502 0.3848 0.5460 0.093 Uiso 1 calc . . R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Co1 O1 174.57(11) . .
O4 Co1 O2 89.42(10) . .
O4 Co1 O3 87.46(10) . .
O4 Co1 N2 93.61(11) . .
O4 Co1 N1 89.15(11) . .
O1 Co1 O2 85.60(9) . .
O1 Co1 O3 90.03(10) . .
O1 Co1 N2 91.33(10) . .
O1 Co1 N1 93.24(11) . .
O2 Co1 N2 176.77(10) . .
O2 Co1 N1 92.46(10) . .
O3 Co1 O2 86.19(10) . .
O3 Co1 N2 92.82(11) . .
O3 Co1 N1 176.35(11) . .
N2 Co1 N1 88.71(12) . .
C14 O4 Co1 130.3(2) . .
C1 O1 Co1 128.3(2) . .
C7 O2 Co1 125.0(2) . .
C8 O3 Co1 126.5(2) . .
C24 N2 Co1 120.1(3) . .
C20 N2 Co1 124.8(3) . .
C20 N2 C24 114.9(4) . .
C15 N1 Co1 119.6(2) . .
C15 N1 C19 117.3(3) . .
C19 N1 Co1 123.1(3) . .
N1 C15 H15 118.5 . .
N1 C15 C16 123.1(4) . .
C16 C15 H15 118.5 . .
C5 C6 C7 117.0(3) . .
C5 C6 C1 121.5(3) . .
C1 C6 C7 121.4(3) . .
O2 C7 C6 128.1(4) . .
O2 C7 H7 115.9 . .
C6 C7 H7 115.9 . .
C6 C5 H5 120.0 . .
C4 C5 C6 120.0(4) . .
C4 C5 H5 120.0 . .
O4 C14 C9 125.3(3) . .
O4 C14 C13 120.7(3) . .
C9 C14 C13 113.9(3) . .
C14 C9 C8 121.6(3) . .
C10 C9 C14 121.7(3) . .
C10 C9 C8 116.7(4) . .
O3 C8 C9 128.5(4) . .
O3 C8 H8 115.7 . .
C9 C8 H8 115.7 . .
N1 C19 H19 118.8 . .
N1 C19 C18 122.3(4) . .
C18 C19 H19 118.8 . .
C1 C2 Cl1 117.7(3) . .
C3 C2 Cl1 119.4(3) . .
C3 C2 C1 122.9(3) . .
O1 C1 C6 125.0(3) . .
O1 C1 C2 120.3(3) . .
C6 C1 C2 114.6(3) . .
C14 C13 Cl4 116.2(3) . .
C12 C13 Cl4 119.9(3) . .
C12 C13 C14 123.9(4) . .
C12 C11 Cl3 120.0(3) . .
C10 C11 Cl3 119.3(4) . .
C10 C11 C12 120.6(4) . .
C5 C4 Cl2 120.8(3) . .
C5 C4 C3 121.0(3) . .
C3 C4 Cl2 118.2(3) . .
C2 C3 C4 119.8(3) . .
C2 C3 H3 120.1 . .
C4 C3 H3 120.1 . .
C13 C12 C11 119.9(4) . .
C13 C12 H12 120.1 . .
C11 C12 H12 120.1 . .
C19 C18 H18 120.2 . .
C17 C18 C19 119.5(4) . .
C17 C18 H18 120.2 . .
C15 C16 H16 120.2 . .
C15 C16 C17 119.6(4) . .
C17 C16 H16 120.2 . .
N2 C24 H24 117.8 . .
N2 C24 C23 124.4(4) . .
C23 C24 H24 117.8 . .
C9 C10 H10 120.0 . .
C11 C10 C9 120.0(4) . .
C11 C10 H10 120.0 . .
C23 C22 H22 120.9 . .
C23 C22 C21 118.2(4) . .
C21 C22 H22 120.9 . .
C24 C23 H23 120.5 . .
C22 C23 C24 119.0(4) . .
C22 C23 H23 120.5 . .
C18 C17 C16 118.1(4) . .
C18 C17 H17 121.0 . .
C16 C17 H17 121.0 . .
N2 C20 H20 117.9 . .
N2 C20 C21 124.2(4) . .
C21 C20 H20 117.9 . .
C22 C21 C20 119.2(4) . .
C22 C21 H21 120.4 . .
C20 C21 H21 120.4 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 O4 2.008(2) .
Co1 O1 2.016(2) .
Co1 O2 2.130(3) .
Co1 O3 2.109(3) .
Co1 N2 2.137(3) .
Co1 N1 2.140(3) .
Cl4 C13 1.742(4) .
Cl1 C2 1.729(4) .
Cl2 C4 1.751(4) .
Cl3 C11 1.745(4) .
O4 C14 1.268(4) .
O1 C1 1.280(4) .
O2 C7 1.234(4) .
O3 C8 1.219(4) .
N2 C24 1.334(4) .
N2 C20 1.308(5) .
N1 C15 1.334(5) .
N1 C19 1.349(4) .
C15 H15 0.9300 .
C15 C16 1.366(6) .
C6 C7 1.433(5) .
C6 C5 1.412(5) .
C6 C1 1.424(5) .
C7 H7 0.9300 .
C5 H5 0.9300 .
C5 C4 1.354(5) .
C14 C9 1.432(5) .
C14 C13 1.437(5) .
C9 C8 1.444(5) .
C9 C10 1.410(5) .
C8 H8 0.9300 .
C19 H19 0.9300 .
C19 C18 1.376(5) .
C2 C1 1.431(4) .
C2 C3 1.370(5) .
C13 C12 1.356(5) .
C11 C12 1.384(6) .
C11 C10 1.369(5) .
C4 C3 1.385(5) .
C3 H3 0.9300 .
C12 H12 0.9300 .
C18 H18 0.9300 .
C18 C17 1.372(6) .
C16 H16 0.9300 .
C16 C17 1.375(5) .
C24 H24 0.9300 .
C24 C23 1.368(6) .
C10 H10 0.9300 .
C22 H22 0.9300 .
C22 C23 1.342(6) .
C22 C21 1.352(5) .
C23 H23 0.9300 .
C17 H17 0.9300 .
C20 H20 0.9300 .
C20 C21 1.377(6) .
C21 H21 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
Co1 O4 C14 C9 6.4(6) . . . .
Co1 O4 C14 C13 -174.3(2) . . . .
Co1 O1 C1 C6 19.6(5) . . . .
Co1 O1 C1 C2 -162.4(3) . . . .
Co1 O2 C7 C6 -9.7(6) . . . .
Co1 O3 C8 C9 1.3(6) . . . .
Co1 N2 C24 C23 -172.5(4) . . . .
Co1 N2 C20 C21 172.2(5) . . . .
Co1 N1 C15 C16 177.2(3) . . . .
Co1 N1 C19 C18 -176.7(3) . . . .
Cl4 C13 C12 C11 179.7(3) . . . .
Cl1 C2 C1 O1 -2.9(5) . . . .
Cl1 C2 C1 C6 175.4(3) . . . .
Cl1 C2 C3 C4 -178.0(3) . . . .
Cl2 C4 C3 C2 -178.5(3) . . . .
Cl3 C11 C12 C13 -178.2(3) . . . .
Cl3 C11 C10 C9 177.2(3) . . . .
O4 Co1 O2 C7 -156.1(3) . . . .
O4 Co1 O3 C8 0.6(3) . . . .
O4 Co1 N2 C24 -17.8(3) . . . .
O4 Co1 N2 C20 167.9(4) . . . .
O4 Co1 N1 C15 -176.8(3) . . . .
O4 Co1 N1 C19 1.4(3) . . . .
O4 C14 C9 C8 -3.4(6) . . . .
O4 C14 C9 C10 178.7(4) . . . .
O4 C14 C13 Cl4 1.2(5) . . . .
O4 C14 C13 C12 -179.7(4) . . . .
O1 Co1 O2 C7 21.7(3) . . . .
O1 Co1 O3 C8 -174.6(3) . . . .
O1 Co1 N2 C24 164.5(3) . . . .
O1 Co1 N2 C20 -9.8(4) . . . .
O1 Co1 N1 C15 -1.7(3) . . . .
O1 Co1 N1 C19 176.5(3) . . . .
O2 Co1 O4 C14 81.8(3) . . . .
O2 Co1 O1 C1 -26.9(3) . . . .
O2 Co1 O3 C8 -89.0(3) . . . .
O2 Co1 N1 C15 -87.5(3) . . . .
O2 Co1 N1 C19 90.8(3) . . . .
O3 Co1 O4 C14 -4.4(3) . . . .
O3 Co1 O1 C1 59.3(3) . . . .
O3 Co1 O2 C7 -68.6(3) . . . .
O3 Co1 N2 C24 -105.4(3) . . . .
O3 Co1 N2 C20 80.3(4) . . . .
N2 Co1 O4 C14 -97.1(3) . . . .
N2 Co1 O1 C1 152.1(3) . . . .
N2 Co1 O3 C8 94.1(3) . . . .
N2 Co1 N1 C15 89.5(3) . . . .
N2 Co1 N1 C19 -92.3(3) . . . .
N2 C24 C23 C22 -0.4(8) . . . .
N2 C20 C21 C22 0.6(10) . . . .
N1 Co1 O4 C14 174.2(3) . . . .
N1 Co1 O1 C1 -119.1(3) . . . .
N1 Co1 O2 C7 114.8(3) . . . .
N1 Co1 N2 C24 71.3(3) . . . .
N1 Co1 N2 C20 -103.0(4) . . . .
N1 C15 C16 C17 -0.1(7) . . . .
N1 C19 C18 C17 -0.7(6) . . . .
C15 N1 C19 C18 1.5(5) . . . .
C15 C16 C17 C18 0.9(6) . . . .
C6 C5 C4 Cl2 177.6(3) . . . .
C6 C5 C4 C3 -2.5(6) . . . .
C7 C6 C5 C4 177.7(4) . . . .
C7 C6 C1 O1 4.1(6) . . . .
C7 C6 C1 C2 -174.1(3) . . . .
C5 C6 C7 O2 173.1(4) . . . .
C5 C6 C1 O1 -177.7(3) . . . .
C5 C6 C1 C2 4.1(5) . . . .
C5 C4 C3 C2 1.6(6) . . . .
C14 C9 C8 O3 -0.6(6) . . . .
C14 C9 C10 C11 1.3(5) . . . .
C14 C13 C12 C11 0.7(6) . . . .
C9 C14 C13 Cl4 -179.4(3) . . . .
C9 C14 C13 C12 -0.4(5) . . . .
C8 C9 C10 C11 -176.7(3) . . . .
C19 N1 C15 C16 -1.1(6) . . . .
C19 C18 C17 C16 -0.5(6) . . . .
C1 C6 C7 O2 -8.6(6) . . . .
C1 C6 C5 C4 -0.6(6) . . . .
C1 C2 C3 C4 2.4(6) . . . .
C13 C14 C9 C8 177.3(3) . . . .
C13 C14 C9 C10 -0.6(5) . . . .
C3 C2 C1 O1 176.6(4) . . . .
C3 C2 C1 C6 -5.1(5) . . . .
C12 C11 C10 C9 -0.9(6) . . . .
C24 N2 C20 C21 -2.4(8) . . . .
C10 C9 C8 O3 177.4(4) . . . .
C10 C11 C12 C13 -0.1(6) . . . .
C23 C22 C21 C20 1.4(9) . . . .
C20 N2 C24 C23 2.3(7) . . . .
C21 C22 C23 C24 -1.5(8) . . . .
