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#$Date: 2023-06-09 09:48:39 +0300 (Fri, 09 Jun 2023) $
#$Revision: 284423 $
#$URL: file:///home/coder/svn-repositories/cod/cif/8/10/73/8107328.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_8107328
loop_
_publ_author_name
'Sokol, Vesna'
'Brajica, Lara'
'Mišura, Ozana'
'Đaković, Marijana'
'Paut, Andrea'
'Prkić, Ante'
'Kukovec, Boris-Marko'
_publ_section_title
;
 The double polymeric chain of
 catena-poly[(\m2-6-bromopyridine-3-carboxylato-\k2 O,O′)
 (6-bromopyridine-3-carboxylato-κ2 O,O′)
 (μ2-1,2-bis(4-pyridyl)ethylene-κ2 N:N′)cobalt(II)],
 C24H16CoBr2N4O4
;
_journal_issue                   6
_journal_name_full
'Zeitschrift für Kristallographie - New Crystal Structures'
_journal_page_first              1181
_journal_page_last               1183
_journal_paper_doi               10.1515/ncrs-2022-0460
_journal_volume                  237
_journal_year                    2022
_chemical_formula_sum            'C24 H16 Br2 Co N4 O4'
_chemical_formula_weight         643.16
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_cell_angle_alpha                90
_cell_angle_beta                 105.363(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.1134(4)
_cell_length_b                   16.1731(6)
_cell_length_c                   13.7057(5)
_cell_measurement_reflns_used    7819
_cell_measurement_temperature    170(2)
_cell_measurement_theta_max      29.6050
_cell_measurement_theta_min      2.9490
_cell_volume                     2375.41(16)
_computing_cell_refinement
'CrysAlisPro 1.171.41.123a (Rigaku OD, 2022) [1]'
_computing_data_collection
'CrysAlisPro 1.171.41.123a (Rigaku OD, 2022) [1]'
_computing_data_reduction
'CrysAlisPro 1.171.41.123a (Rigaku OD, 2022) [1]'
_computing_molecular_graphics    'MERCURY (Macrae et al., 2020) [4]'
_computing_publication_material  'SHELXL-2018/3 (Sheldrick, 2018) [3]'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018) [3]'
_computing_structure_solution    'SHELXT (Sheldrick, 2015) [2]'
_diffrn_ambient_temperature      170(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.879
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0582
_diffrn_reflns_av_unetI/netI     0.0731
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.879
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            32374
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.879
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         33.416
_diffrn_reflns_theta_min         4.082
_exptl_absorpt_coefficient_mu    4.126
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.96730
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.123a (Rigaku Oxford Diffraction, 2022)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    1.798
_exptl_crystal_description       prism
_exptl_crystal_F_000             1268
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.04
_refine_diff_density_max         0.769
_refine_diff_density_min         -0.626
_refine_diff_density_rms         0.091
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     317
_refine_ls_number_reflns         8150
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.1127
_refine_ls_R_factor_gt           0.0588
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0384P)²+1.7473P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0978
_refine_ls_wR_factor_ref         0.1101
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5169
_reflns_number_total             8150
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            suppl_j_ncrs-2022-0460_suppl.cif
_cod_data_source_block           1
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               8107328
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.16732(3) 0.42379(2) 0.05212(3) 0.02422(10) Uani 1 1 d . . . . .
Br1 Br 0.50460(5) 0.88395(4) 0.09718(4) 0.0987(2) Uani 1 1 d . . . . .
Br2 Br 0.89474(3) 0.20186(2) 0.23329(3) 0.04373(11) Uani 1 1 d . . . . .
N1 N 0.2630(3) 0.82589(19) 0.0492(2) 0.0503(8) Uani 1 1 d . . . . .
N2 N 0.7286(3) 0.3350(2) 0.1967(2) 0.0437(7) Uani 0.5 1 d . . P A 1
C10A C 0.7286(3) 0.3350(2) 0.1967(2) 0.0437(7) Uani 0.5 1 d . . P A 2
H10A H 0.802165 0.367757 0.214353 0.052 Uiso 0.5 1 calc R U P A 2
N3 N 0.1675(2) 0.43226(15) 0.20922(17) 0.0308(5) Uani 1 1 d . . . . .
N4 N 0.1756(2) 0.41281(15) 0.89617(17) 0.0313(5) Uani 1 1 d . . . . .
O1 O 0.1325(2) 0.54574(13) 0.03763(17) 0.0430(5) Uani 1 1 d . . . . .
O2 O -0.00734(18) 0.64423(13) -0.01935(15) 0.0344(5) Uani 1 1 d . . . . .
O3 O 0.37004(19) 0.43728(13) 0.10074(17) 0.0389(5) Uani 1 1 d . . . . .
O4 O 0.28492(19) 0.31456(13) 0.09376(16) 0.0356(5) Uani 1 1 d . . . . .
C1 C 0.1758(3) 0.7660(2) 0.0312(2) 0.0368(7) Uani 1 1 d . . . . .
H1 H 0.090540 0.781934 0.011106 0.044 Uiso 1 1 calc R U . . .
C2 C 0.2037(3) 0.68259(18) 0.0403(2) 0.0279(6) Uani 1 1 d . . . . .
C3 C 0.3278(3) 0.6595(2) 0.0694(2) 0.0412(8) Uani 1 1 d . . . . .
H3 H 0.350199 0.602738 0.077083 0.049 Uiso 1 1 calc R U . . .
C4 C 0.4185(3) 0.7196(3) 0.0872(3) 0.0540(10) Uani 1 1 d . . . . .
H4 H 0.504596 0.705526 0.106796 0.065 Uiso 1 1 calc R U . . .
C5 C 0.3807(4) 0.7998(3) 0.0758(3) 0.0544(11) Uani 1 1 d . . . . .
C6 C 0.1015(3) 0.61920(17) 0.01812(19) 0.0257(6) Uani 1 1 d . . . . .
C7 C 0.6131(3) 0.3699(2) 0.1695(3) 0.0421(8) Uani 1 1 d . . . . .
H7 H 0.605662 0.428453 0.167706 0.050 Uiso 1 1 calc R U . A 1
C8 C 0.5064(3) 0.3219(2) 0.1443(2) 0.0334(7) Uani 1 1 d . . . . .
C9 C 0.5214(3) 0.2371(2) 0.1477(3) 0.0403(7) Uani 1 1 d . . . . .
H9 H 0.449249 0.202936 0.131095 0.048 Uiso 1 1 calc R U . B 1
C10 C 0.6356(3) 0.20084(18) 0.1741(2) 0.0377(7) Uani 0.5 1 d . . P A 1
H10 H 0.645151 0.142446 0.175798 0.045 Uiso 0.5 1 calc R U P A 1
N2A N 0.6356(3) 0.20084(18) 0.1741(2) 0.0377(7) Uani 0.5 1 d . . P A 2
C11 C 0.7334(3) 0.2514(2) 0.1975(2) 0.0340(7) Uani 1 1 d . . . . .
C12 C 0.3801(3) 0.3605(2) 0.1114(2) 0.0314(6) Uani 1 1 d . . . . .
C13 C 0.2208(3) 0.4954(2) 0.2668(2) 0.0401(8) Uani 1 1 d . . . . .
H13 H 0.257064 0.538129 0.236420 0.048 Uiso 1 1 calc R U . . .
C14 C 0.2262(3) 0.5022(2) 0.3679(2) 0.0429(8) Uani 1 1 d . . . . .
H14 H 0.264025 0.549233 0.405092 0.051 Uiso 1 1 calc R U . . .
C15 C 0.1766(3) 0.4406(2) 0.4152(2) 0.0369(7) Uani 1 1 d . . . . .
C16 C 0.1220(3) 0.3740(2) 0.3554(2) 0.0402(8) Uani 1 1 d . . . . .
H16 H 0.086848 0.329652 0.384129 0.048 Uiso 1 1 calc R U . . .
C17 C 0.1191(3) 0.3727(2) 0.2544(2) 0.0372(7) Uani 1 1 d . . . . .
H17 H 0.080553 0.326998 0.214716 0.045 Uiso 1 1 calc R U . . .
C18 C 0.1799(3) 0.4481(2) 0.5229(2) 0.0439(8) Uani 1 1 d . . . . .
H18 H 0.184282 0.502430 0.549961 0.053 Uiso 1 1 calc R U . . .
C19 C 0.1774(3) 0.3863(2) 0.5856(2) 0.0392(7) Uani 1 1 d . . . . .
H19 H 0.174347 0.331542 0.559872 0.047 Uiso 1 1 calc R U . . .
C20 C 0.1792(3) 0.39696(19) 0.6921(2) 0.0326(7) Uani 1 1 d . . . . .
C21 C 0.2222(3) 0.3346(2) 0.7624(2) 0.0402(8) Uani 1 1 d . . . . .
H21 H 0.254078 0.284831 0.742227 0.048 Uiso 1 1 calc R U . . .
C22 C 0.2186(3) 0.3448(2) 0.8612(2) 0.0413(8) Uani 1 1 d . . . . .
H22 H 0.248515 0.300953 0.907345 0.050 Uiso 1 1 calc R U . . .
C23 C 0.1321(4) 0.4716(2) 0.8285(2) 0.0497(9) Uani 1 1 d . . . . .
H23 H 0.099111 0.520273 0.850384 0.060 Uiso 1 1 calc R U . . .
C24 C 0.1322(4) 0.4661(2) 0.7279(2) 0.0543(10) Uani 1 1 d . . . . .
H24 H 0.099535 0.510271 0.683062 0.065 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Co1 O2 111.98(9) . 3_565
O1 Co1 N3 89.18(9) . .
O2 Co1 N3 91.40(9) 3_565 .
O1 Co1 N4 92.31(9) . 1_554
O2 Co1 N4 90.06(9) 3_565 1_554
N3 Co1 N4 177.37(9) . 1_554
O1 Co1 O4 155.08(9) . .
O2 Co1 O4 92.73(8) 3_565 .
N3 Co1 O4 87.03(8) . .
N4 Co1 O4 90.71(9) 1_554 .
O1 Co1 O3 95.06(9) . .
O2 Co1 O3 152.94(8) 3_565 .
N3 Co1 O3 87.76(9) . .
N4 Co1 O3 89.94(9) 1_554 .
O4 Co1 O3 60.20(8) . .
O1 Co1 C12 124.98(10) . .
O2 Co1 C12 122.98(10) 3_565 .
N3 Co1 C12 87.20(9) . .
N4 Co1 C12 90.17(9) 1_554 .
O4 Co1 C12 30.25(9) . .
O3 Co1 C12 29.96(9) . .
C5 N1 C1 115.4(3) . .
C11 N2 C7 116.7(3) . .
C11 C10A C7 116.7(3) . .
C11 C10A H10A 121.7 . .
C7 C10A H10A 121.7 . .
C13 N3 C17 116.8(3) . .
C13 N3 Co1 121.6(2) . .
C17 N3 Co1 121.6(2) . .
C23 N4 C22 115.9(3) . .
C23 N4 Co1 121.8(2) . 1_556
C22 N4 Co1 122.2(2) . 1_556
C6 O1 Co1 172.7(2) . .
C6 O2 Co1 127.51(19) . 3_565
C12 O3 Co1 89.39(18) . .
C12 O4 Co1 89.24(18) . .
N1 C1 C2 123.5(3) . .
N1 C1 H1 118.2 . .
C2 C1 H1 118.2 . .
C3 C2 C1 118.2(3) . .
C3 C2 C6 121.2(3) . .
C1 C2 C6 120.6(3) . .
C4 C3 C2 119.3(3) . .
C4 C3 H3 120.3 . .
C2 C3 H3 120.3 . .
C5 C4 C3 117.6(3) . .
C5 C4 H4 121.2 . .
C3 C4 H4 121.2 . .
N1 C5 C4 125.9(3) . .
N1 C5 Br1 115.7(3) . .
C4 C5 Br1 118.4(3) . .
O1 C6 O2 125.4(3) . .
O1 C6 C2 117.2(3) . .
O2 C6 C2 117.4(3) . .
C10A C7 C8 121.3(3) . .
N2 C7 C8 121.3(3) . .
N2 C7 H7 119.3 . .
C8 C7 H7 119.3 . .
C9 C8 C7 117.5(3) . .
C9 C8 C12 121.4(3) . .
C7 C8 C12 121.1(3) . .
N2A C9 C8 122.2(3) . .
C10 C9 C8 122.2(3) . .
C10 C9 H9 118.9 . .
C8 C9 H9 118.9 . .
C11 C10 C9 116.5(3) . .
C11 C10 H10 121.8 . .
C9 C10 H10 121.8 . .
C11 N2A C9 116.5(3) . .
C10 C11 N2 125.7(3) . .
N2A C11 C10A 125.7(3) . .
N2A C11 Br2 117.2(2) . .
C10 C11 Br2 117.2(2) . .
N2 C11 Br2 117.1(2) . .
C10A C11 Br2 117.1(2) . .
O3 C12 O4 121.2(3) . .
O3 C12 C8 119.9(3) . .
O4 C12 C8 119.0(3) . .
O3 C12 Co1 60.65(15) . .
O4 C12 Co1 60.52(15) . .
C8 C12 Co1 178.6(2) . .
N3 C13 C14 123.6(3) . .
N3 C13 H13 118.2 . .
C14 C13 H13 118.2 . .
C13 C14 C15 120.0(3) . .
C13 C14 H14 120.0 . .
C15 C14 H14 120.0 . .
C14 C15 C16 116.6(3) . .
C14 C15 C18 120.3(3) . .
C16 C15 C18 123.1(3) . .
C17 C16 C15 119.6(3) . .
C17 C16 H16 120.2 . .
C15 C16 H16 120.2 . .
N3 C17 C16 123.5(3) . .
N3 C17 H17 118.3 . .
C16 C17 H17 118.3 . .
C19 C18 C15 126.1(3) . .
C19 C18 H18 117.0 . .
C15 C18 H18 117.0 . .
C18 C19 C20 124.1(3) . .
C18 C19 H19 117.9 . .
C20 C19 H19 117.9 . .
C24 C20 C21 115.8(3) . .
C24 C20 C19 123.0(3) . .
C21 C20 C19 121.1(3) . .
C22 C21 C20 120.1(3) . .
C22 C21 H21 120.0 . .
C20 C21 H21 120.0 . .
N4 C22 C21 123.9(3) . .
N4 C22 H22 118.0 . .
C21 C22 H22 118.0 . .
N4 C23 C24 123.7(3) . .
N4 C23 H23 118.2 . .
C24 C23 H23 118.2 . .
C20 C24 C23 120.6(3) . .
C20 C24 H24 119.7 . .
C23 C24 H24 119.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 O1 2.010(2) .
Co1 O2 2.037(2) 3_565
Co1 N3 2.157(2) .
Co1 N4 2.171(2) 1_554
Co1 O4 2.182(2) .
Co1 O3 2.184(2) .
Co1 C12 2.506(3) .
Br1 C5 1.903(3) .
Br2 C11 1.905(3) .
N1 C5 1.330(5) .
N1 C1 1.346(4) .
N2 C11 1.354(4) .
N2 C7 1.360(4) .
C10A C11 1.354(4) .
C10A C7 1.360(4) .
C10A H10A 0.9500 .
N3 C13 1.330(4) .
N3 C17 1.332(4) .
N4 C23 1.328(4) .
N4 C22 1.338(4) .
O1 C6 1.246(3) .
O2 C6 1.250(3) .
O3 C12 1.251(4) .
O4 C12 1.262(4) .
C1 C2 1.382(4) .
C1 H1 0.9500 .
C2 C3 1.382(4) .
C2 C6 1.500(4) .
C3 C4 1.374(5) .
C3 H3 0.9500 .
C4 C5 1.360(6) .
C4 H4 0.9500 .
C7 C8 1.383(4) .
C7 H7 0.9500 .
C8 C9 1.381(5) .
C8 C12 1.493(4) .
C9 N2A 1.357(4) .
C9 C10 1.357(4) .
C9 H9 0.9500 .
C10 C11 1.330(4) .
C10 H10 0.9500 .
N2A C11 1.330(4) .
C13 C14 1.375(4) .
C13 H13 0.9500 .
C14 C15 1.381(5) .
C14 H14 0.9500 .
C15 C16 1.392(5) .
C15 C18 1.471(4) .
C16 C17 1.377(4) .
C16 H16 0.9500 .
C17 H17 0.9500 .
C18 C19 1.323(5) .
C18 H18 0.9500 .
C19 C20 1.466(4) .
C19 H19 0.9500 .
C20 C24 1.378(5) .
C20 C21 1.389(4) .
C21 C22 1.374(4) .
C21 H21 0.9500 .
C22 H22 0.9500 .
C23 C24 1.381(5) .
C23 H23 0.9500 .
C24 H24 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C5 N1 C1 C2 0.8(5) . . . .
N1 C1 C2 C3 0.0(5) . . . .
N1 C1 C2 C6 -179.5(3) . . . .
C1 C2 C3 C4 -0.6(5) . . . .
C6 C2 C3 C4 178.8(3) . . . .
C2 C3 C4 C5 0.5(5) . . . .
C1 N1 C5 C4 -0.9(5) . . . .
C1 N1 C5 Br1 178.1(2) . . . .
C3 C4 C5 N1 0.3(6) . . . .
C3 C4 C5 Br1 -178.7(3) . . . .
Co1 O2 C6 O1 4.0(4) 3_565 . . .
Co1 O2 C6 C2 -176.84(17) 3_565 . . .
C3 C2 C6 O1 7.6(4) . . . .
C1 C2 C6 O1 -172.9(3) . . . .
C3 C2 C6 O2 -171.6(3) . . . .
C1 C2 C6 O2 7.8(4) . . . .
C11 C10A C7 C8 0.3(5) . . . .
C11 N2 C7 C8 0.3(5) . . . .
C10A C7 C8 C9 -0.1(5) . . . .
N2 C7 C8 C9 -0.1(5) . . . .
C10A C7 C8 C12 -178.1(3) . . . .
N2 C7 C8 C12 -178.1(3) . . . .
C7 C8 C9 N2A -0.3(5) . . . .
C12 C8 C9 N2A 177.7(3) . . . .
C7 C8 C9 C10 -0.3(5) . . . .
C12 C8 C9 C10 177.7(3) . . . .
C8 C9 C10 C11 0.5(5) . . . .
C8 C9 N2A C11 0.5(5) . . . .
C9 N2A C11 C10A -0.3(5) . . . .
C9 N2A C11 Br2 -179.3(2) . . . .
C9 C10 C11 N2 -0.3(5) . . . .
C9 C10 C11 Br2 -179.3(2) . . . .
C7 N2 C11 C10 -0.1(5) . . . .
C7 N2 C11 Br2 178.9(2) . . . .
C7 C10A C11 N2A -0.1(5) . . . .
C7 C10A C11 Br2 178.9(2) . . . .
Co1 O3 C12 O4 -0.7(3) . . . .
Co1 O3 C12 C8 178.6(2) . . . .
Co1 O4 C12 O3 0.7(3) . . . .
Co1 O4 C12 C8 -178.6(2) . . . .
C9 C8 C12 O3 -173.9(3) . . . .
C7 C8 C12 O3 4.1(4) . . . .
C9 C8 C12 O4 5.4(4) . . . .
C7 C8 C12 O4 -176.6(3) . . . .
C17 N3 C13 C14 -1.0(5) . . . .
Co1 N3 C13 C14 -178.1(3) . . . .
N3 C13 C14 C15 1.2(5) . . . .
C13 C14 C15 C16 -0.5(5) . . . .
C13 C14 C15 C18 -178.9(3) . . . .
C14 C15 C16 C17 -0.4(5) . . . .
C18 C15 C16 C17 177.9(3) . . . .
C13 N3 C17 C16 0.0(5) . . . .
Co1 N3 C17 C16 177.2(2) . . . .
C15 C16 C17 N3 0.7(5) . . . .
C14 C15 C18 C19 -155.1(4) . . . .
C16 C15 C18 C19 26.7(6) . . . .
C15 C18 C19 C20 -179.1(3) . . . .
C18 C19 C20 C24 28.2(5) . . . .
C18 C19 C20 C21 -155.8(4) . . . .
C24 C20 C21 C22 -1.3(5) . . . .
C19 C20 C21 C22 -177.6(3) . . . .
C23 N4 C22 C21 1.6(5) . . . .
Co1 N4 C22 C21 178.1(3) 1_556 . . .
C20 C21 C22 N4 -0.2(5) . . . .
C22 N4 C23 C24 -1.4(6) . . . .
Co1 N4 C23 C24 -178.0(3) 1_556 . . .
C21 C20 C24 C23 1.5(6) . . . .
C19 C20 C24 C23 177.7(4) . . . .
N4 C23 C24 C20 -0.1(6) . . . .
