#------------------------------------------------------------------------------
#$Date: 2010-01-30 15:59:17 +0200 (Sat, 30 Jan 2010) $
#$Revision: 966 $
#$URL: file:///home/coder/svn-repositories/cod/cif/1/1100979.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1100979
_chemical_name_common             '[Zn2(Me2biim)3][NO3]4'
_chemical_formula_sum    'C24 H36 N16 O15 Zn2'
_chemical_formula_weight          919.43
loop_
 _atom_type_symbol
 _atom_type_description
 _atom_type_scat_dispersion_real
 _atom_type_scat_dispersion_imag
 _atom_type_scat_source
 'C'  'C'   0.0033   0.0016
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H'  'H'   0.0000   0.0000
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N'  'N'   0.0061   0.0033
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O'  'O'   0.0106   0.0060
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Zn'  'Zn'   0.2839   1.4301
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
_symmetry_cell_setting            ?
_symmetry_space_group_name_H-M    'P-1'
loop_
 _symmetry_equiv_pos_as_xyz
 'x, y, z'
 '-x, -y, -z'
_cell_length_a                    9.85700(10)
_cell_length_b                    12.1339(3)
_cell_length_c                    16.9110(4)
_cell_angle_alpha                 82.5350(10)
_cell_angle_beta                  86.4190(10)
_cell_angle_gamma                 68.4430(10)
_cell_volume                      1864.96(7)
_cell_formula_units_Z             2
_cell_measurement_temperature     273(2)
_cell_measurement_reflns_used     3960
_cell_measurement_theta_min       ?
_cell_measurement_theta_max       ?
_exptl_crystal_description        prism
_exptl_crystal_colour             colorless
_exptl_crystal_size_max           0.40
_exptl_crystal_size_mid           0.20
_exptl_crystal_size_min           0.16
_exptl_crystal_density_meas       ?
_exptl_crystal_density_diffrn     1.637
_exptl_crystal_density_method     'not measured'
_exptl_crystal_F_000              944
_exptl_absorpt_coefficient_mu     1.375
_exptl_absorpt_correction_type    SADABS
_exptl_absorpt_correction_T_min   0.170
_exptl_absorpt_correction_T_max   1.000
_exptl_absorpt_process_details    ?
_diffrn_ambient_temperature       273(2)
_diffrn_radiation_wavelength      0.71073
_diffrn_radiation_type            MoK\a
_diffrn_radiation_source          'fine-focus sealed tube'
_diffrn_radiation_monochromator   graphite
_diffrn_measurement_device_type   ?
_diffrn_measurement_method        ?
_diffrn_detector_area_resol_mean  ?
_diffrn_standards_number          ?
_diffrn_standards_interval_count  ?
_diffrn_standards_interval_time   ?
_diffrn_standards_decay_%         ?
_diffrn_reflns_number             9615
_diffrn_reflns_av_R_equivalents   0.0440
_diffrn_reflns_av_sigmaI/netI     0.0641
_diffrn_reflns_limit_h_min        -11
_diffrn_reflns_limit_h_max        11
_diffrn_reflns_limit_k_min        -9
_diffrn_reflns_limit_k_max        14
_diffrn_reflns_limit_l_min        -20
_diffrn_reflns_limit_l_max        19
_diffrn_reflns_theta_min          1.21
_diffrn_reflns_theta_max          24.99
_reflns_number_total              6455
_reflns_number_gt                 4846
_reflns_threshold_expression      >2sigma(I)
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_matrix_type            full
_refine_ls_weighting_scheme       calc
_refine_ls_weighting_details
 'calc w=1/[\s^2^(Fo^2^)+(0.0300P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary      direct
_atom_sites_solution_secondary    difmap
_atom_sites_solution_hydrogens    geom
_refine_ls_hydrogen_treatment     mixed
_refine_ls_extinction_method      none
_refine_ls_extinction_coef        ?
_refine_ls_number_reflns          6455
_refine_ls_number_parameters      514
_refine_ls_number_restraints      0
_refine_ls_R_factor_all           0.1371
_refine_ls_R_factor_gt            0.0999
_refine_ls_wR_factor_ref          0.1775
_refine_ls_wR_factor_gt           0.1650
_refine_ls_goodness_of_fit_ref    2.141
_refine_ls_restrained_S_all       2.141
_refine_ls_shift/su_max           0.003
_refine_ls_shift/su_mean          0.000
loop_
 _atom_site_label
 _atom_site_type_symbol
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_U_iso_or_equiv
 _atom_site_adp_type
 _atom_site_occupancy
 _atom_site_symmetry_multiplicity
 _atom_site_calc_flag
 _atom_site_refinement_flags
 _atom_site_disorder_assembly
 _atom_site_disorder_group
Zn1 Zn 0.01347(8) 0.68101(7) 0.34571(5) 0.0421(3) Uani 1 1 d . . .
Zn2 Zn 0.22038(8) 0.76933(7) 0.15182(5) 0.0394(3) Uani 1 1 d . . .
O1 O -0.1057(6) 0.6605(5) 0.4387(3) 0.0641(15) Uani 1 1 d . . .
O2 O 0.3605(5) 0.7870(4) 0.0689(3) 0.0532(14) Uani 1 1 d . . .
O11 O 0.4609(6) 0.9587(5) 0.0870(4) 0.0651(16) Uani 1 1 d . . .
O12 O 0.4053(8) 1.1479(6) 0.0771(4) 0.100(2) Uani 1 1 d . . .
O13 O 0.2369(7) 1.0728(7) 0.0934(4) 0.098(2) Uani 1 1 d . . .
O21 O -0.1976(7) 0.4751(6) 0.4650(4) 0.090(2) Uani 1 1 d . . .
O22 O -0.1317(8) 0.2964(6) 0.4311(5) 0.104(2) Uani 1 1 d . . .
O23 O -0.0544(7) 0.4269(7) 0.3640(4) 0.092(2) Uani 1 1 d . . .
O31 O 0.3623(6) 0.7034(6) -0.0678(4) 0.0757(18) Uani 1 1 d . . .
O32 O 0.2656(7) 0.6008(7) -0.1234(4) 0.104(3) Uani 1 1 d . . .
O33 O 0.1529(7) 0.6986(7) -0.0284(4) 0.096(2) Uani 1 1 d . . .
O41 O 0.7614(10) 0.8544(10) 0.5134(6) 0.131(3) Uani 1 1 d . . .
O42 O 0.6695(7) 0.9144(7) 0.3997(5) 0.105(2) Uani 1 1 d . . .
O43 O 0.6539(11) 1.0394(10) 0.4777(8) 0.204(7) Uani 1 1 d . . .
O1W O 0.6239(14) 0.8688(8) 0.6619(7) 0.203(6) Uani 1 1 d . . .
N1 N 0.3658(8) 1.0622(6) 0.0855(4) 0.0591(18) Uani 1 1 d . . .
N2 N -0.1266(8) 0.3979(7) 0.4201(5) 0.0642(19) Uani 1 1 d . . .
N3 N 0.2567(7) 0.6693(6) -0.0741(4) 0.0567(17) Uani 1 1 d . . .
N4 N 0.6881(11) 0.9479(14) 0.4608(7) 0.113(4) Uani 1 1 d . . .
N11 N 0.2173(6) 0.5623(5) 0.3445(3) 0.0433(14) Uani 1 1 d . . .
N12 N 0.4540(6) 0.4773(5) 0.3263(4) 0.0496(16) Uani 1 1 d . . .
N13 N 0.3171(6) 0.7768(5) 0.2525(3) 0.0386(14) Uani 1 1 d . . .
N14 N 0.4056(6) 0.7442(5) 0.3724(3) 0.0427(14) Uani 1 1 d . . .
N21 N 0.0089(6) 0.8494(5) 0.3416(3) 0.0388(14) Uani 1 1 d . . .
N22 N -0.0109(7) 1.0368(5) 0.3101(4) 0.0517(17) Uani 1 1 d . . .
N23 N 0.0153(6) 0.8843(5) 0.1453(3) 0.0390(14) Uani 1 1 d . . .
N24 N -0.2059(6) 1.0016(5) 0.1749(4) 0.0484(16) Uani 1 1 d . . .
N31 N -0.0902(5) 0.6762(5) 0.2486(3) 0.0385(14) Uani 1 1 d . . .
N32 N -0.1540(6) 0.6548(5) 0.1311(4) 0.0435(14) Uani 1 1 d . . .
N33 N 0.2195(6) 0.6043(5) 0.1489(3) 0.0370(13) Uani 1 1 d . . .
N34 N 0.1631(6) 0.4450(4) 0.1507(3) 0.0377(13) Uani 1 1 d . . .
C11 C 0.3404(8) 0.5819(6) 0.3292(4) 0.0437(18) Uani 1 1 d . . .
C12 C 0.2562(9) 0.4400(6) 0.3523(5) 0.054(2) Uani 1 1 d . . .
H12A H 0.1920 0.3997 0.3640 0.065 Uiso 1 1 calc R . .
C13 C 0.4007(9) 0.3881(7) 0.3404(5) 0.061(2) Uani 1 1 d . . .
H13A H 0.4538 0.3067 0.3415 0.073 Uiso 1 1 calc R . .
C14 C 0.6047(8) 0.4623(8) 0.3026(6) 0.076(3) Uani 1 1 d . . .
H14A H 0.6153 0.5385 0.2963 0.115 Uiso 1 1 calc R . .
H14B H 0.6279 0.4284 0.2529 0.115 Uiso 1 1 calc R . .
H14C H 0.6697 0.4101 0.3429 0.115 Uiso 1 1 calc R . .
C15 C 0.3547(7) 0.6989(6) 0.3173(4) 0.0413(17) Uani 1 1 d . . .
C16 C 0.3450(7) 0.8753(7) 0.2686(5) 0.0473(19) Uani 1 1 d . . .
H16A H 0.3293 0.9448 0.2340 0.057 Uiso 1 1 calc R . .
C17 C 0.3986(8) 0.8543(7) 0.3424(5) 0.054(2) Uani 1 1 d . . .
H17A H 0.4257 0.9062 0.3680 0.065 Uiso 1 1 calc R . .
C18 C 0.4538(9) 0.6856(8) 0.4540(5) 0.068(2) Uani 1 1 d . . .
H18A H 0.4501 0.6069 0.4606 0.102 Uiso 1 1 calc R . .
H18B H 0.3905 0.7318 0.4928 0.102 Uiso 1 1 calc R . .
H18C H 0.5520 0.6802 0.4613 0.102 Uiso 1 1 calc R . .
C21 C -0.0240(7) 0.9394(6) 0.2840(4) 0.0417(18) Uani 1 1 d . . .
C22 C 0.0332(9) 1.0055(7) 0.3860(5) 0.058(2) Uani 1 1 d . . .
H22A H 0.0509 1.0547 0.4186 0.069 Uiso 1 1 calc R . .
C23 C 0.0480(7) 0.8892(7) 0.4071(4) 0.0478(19) Uani 1 1 d . . .
H23A H 0.0785 0.8447 0.4561 0.057 Uiso 1 1 calc R . .
C24 C -0.0286(11) 1.1498(7) 0.2621(5) 0.085(3) Uani 1 1 d . . .
H24A H -0.0155 1.2038 0.2950 0.127 Uiso 1 1 calc R . .
H24B H -0.1246 1.1834 0.2401 0.127 Uiso 1 1 calc R . .
H24C H 0.0428 1.1365 0.2196 0.127 Uiso 1 1 calc R . .
C25 C -0.0705(7) 0.9416(6) 0.2030(4) 0.0381(16) Uani 1 1 d . . .
C26 C -0.2068(8) 0.9821(6) 0.0972(5) 0.0507(19) Uani 1 1 d . . .
H26A H -0.2861 1.0128 0.0633 0.061 Uiso 1 1 calc R . .
C27 C -0.0722(7) 0.9105(6) 0.0793(4) 0.0424(17) Uani 1 1 d . . .
H27A H -0.0418 0.8825 0.0301 0.051 Uiso 1 1 calc R . .
C28 C -0.3347(9) 1.0713(8) 0.2204(5) 0.077(3) Uani 1 1 d . . .
H28A H -0.4173 1.1051 0.1861 0.116 Uiso 1 1 calc R . .
H28B H -0.3155 1.1342 0.2410 0.116 Uiso 1 1 calc R . .
H28C H -0.3549 1.0200 0.2639 0.116 Uiso 1 1 calc R . .
C31 C -0.0415(7) 0.6310(6) 0.1809(4) 0.0358(16) Uani 1 1 d . . .
C32 C -0.2394(7) 0.7307(7) 0.2415(5) 0.050(2) Uani 1 1 d . . .
H32A H -0.3030 0.7706 0.2802 0.060 Uiso 1 1 calc R . .
C33 C -0.2779(8) 0.7172(7) 0.1707(5) 0.058(2) Uani 1 1 d . . .
H33A H -0.3724 0.7452 0.1514 0.070 Uiso 1 1 calc R . .
C34 C -0.1440(8) 0.6288(7) 0.0472(4) 0.060(2) Uani 1 1 d . . .
H34A H -0.2403 0.6549 0.0260 0.090 Uiso 1 1 calc R . .
H34B H -0.0965 0.5445 0.0452 0.090 Uiso 1 1 calc R . .
H34C H -0.0887 0.6702 0.0161 0.090 Uiso 1 1 calc R . .
C35 C 0.1123(7) 0.5625(6) 0.1601(4) 0.0341(15) Uani 1 1 d . . .
C36 C 0.3078(7) 0.4124(6) 0.1328(4) 0.0456(18) Uani 1 1 d . . .
H36A H 0.3710 0.3368 0.1230 0.055 Uiso 1 1 calc R . .
C37 C 0.3432(7) 0.5102(6) 0.1320(4) 0.0423(18) Uani 1 1 d . . .
H37A H 0.4356 0.5133 0.1218 0.051 Uiso 1 1 calc R . .
C38 C 0.0832(8) 0.3625(6) 0.1686(5) 0.057(2) Uani 1 1 d . . .
H38A H -0.0175 0.4072 0.1795 0.086 Uiso 1 1 calc R . .
H38B H 0.1249 0.3069 0.2143 0.086 Uiso 1 1 calc R . .
H38C H 0.0904 0.3198 0.1235 0.086 Uiso 1 1 calc R . .
loop_
 _atom_site_aniso_label
 _atom_site_aniso_U_11
 _atom_site_aniso_U_22
 _atom_site_aniso_U_33
 _atom_site_aniso_U_23
 _atom_site_aniso_U_13
 _atom_site_aniso_U_12
Zn1 0.0415(5) 0.0387(5) 0.0457(5) -0.0096(4) 0.0070(4) -0.0139(4)
Zn2 0.0388(5) 0.0347(5) 0.0468(5) -0.0098(4) 0.0050(4) -0.0150(4)
O1 0.072(4) 0.067(4) 0.061(4) -0.013(3) 0.024(3) -0.036(3)
O2 0.060(3) 0.057(3) 0.056(3) -0.019(3) 0.024(3) -0.036(3)
O11 0.058(3) 0.039(3) 0.095(5) -0.005(3) -0.001(3) -0.015(3)
O12 0.129(6) 0.048(4) 0.132(7) -0.023(4) -0.017(5) -0.036(4)
O13 0.054(4) 0.110(6) 0.114(6) -0.031(4) -0.003(4) -0.005(4)
O21 0.096(5) 0.094(5) 0.090(5) -0.035(4) 0.031(4) -0.044(4)
O22 0.134(7) 0.063(5) 0.121(6) 0.005(4) -0.016(5) -0.045(5)
O23 0.092(5) 0.123(6) 0.066(5) -0.009(4) 0.020(4) -0.050(5)
O31 0.069(4) 0.101(5) 0.080(4) -0.035(4) 0.023(3) -0.052(4)
O32 0.095(5) 0.142(7) 0.111(6) -0.079(5) 0.024(4) -0.069(5)
O33 0.061(4) 0.138(6) 0.095(5) -0.045(5) 0.028(4) -0.038(4)
O41 0.107(7) 0.172(10) 0.100(7) -0.044(6) 0.006(5) -0.027(7)
O42 0.081(5) 0.135(7) 0.110(6) -0.053(5) 0.006(4) -0.039(5)
O43 0.178(10) 0.169(10) 0.317(16) -0.199(12) 0.093(10) -0.082(8)
O1W 0.331(15) 0.096(7) 0.191(10) -0.041(7) 0.113(10) -0.099(9)
N1 0.072(5) 0.052(5) 0.051(4) -0.014(3) -0.007(4) -0.017(4)
N2 0.051(4) 0.070(6) 0.069(5) -0.001(4) -0.014(4) -0.018(4)
N3 0.047(4) 0.062(5) 0.058(5) -0.016(4) 0.004(3) -0.013(4)
N4 0.072(7) 0.185(13) 0.101(8) -0.080(9) 0.020(6) -0.050(8)
N11 0.039(3) 0.037(4) 0.050(4) -0.004(3) 0.000(3) -0.010(3)
N12 0.042(4) 0.043(4) 0.062(4) -0.016(3) -0.003(3) -0.009(3)
N13 0.035(3) 0.039(3) 0.046(4) -0.006(3) 0.004(3) -0.018(3)
N14 0.039(3) 0.046(4) 0.046(4) -0.012(3) -0.003(3) -0.015(3)
N21 0.043(3) 0.031(3) 0.039(3) -0.009(3) 0.009(3) -0.008(3)
N22 0.075(5) 0.034(4) 0.051(4) -0.017(3) 0.020(3) -0.025(3)
N23 0.035(3) 0.036(3) 0.048(4) -0.007(3) 0.006(3) -0.016(3)
N24 0.044(4) 0.039(4) 0.046(4) 0.002(3) 0.006(3) 0.001(3)
N31 0.036(3) 0.036(3) 0.044(4) -0.009(3) 0.007(3) -0.015(3)
N32 0.040(3) 0.038(3) 0.053(4) -0.006(3) -0.003(3) -0.013(3)
N33 0.033(3) 0.033(3) 0.045(4) -0.011(3) 0.003(3) -0.010(3)
N34 0.040(3) 0.028(3) 0.048(4) -0.018(3) 0.006(3) -0.013(3)
C11 0.043(4) 0.040(4) 0.045(4) -0.011(3) 0.001(3) -0.010(4)
C12 0.059(5) 0.033(4) 0.064(5) -0.003(4) -0.004(4) -0.010(4)
C13 0.064(6) 0.032(4) 0.079(6) -0.010(4) -0.004(5) -0.007(4)
C14 0.040(5) 0.082(7) 0.104(8) -0.031(6) -0.004(5) -0.011(5)
C15 0.037(4) 0.029(4) 0.057(5) -0.014(4) 0.008(3) -0.009(3)
C16 0.051(5) 0.052(5) 0.054(5) -0.019(4) 0.013(4) -0.035(4)
C17 0.055(5) 0.063(6) 0.060(5) -0.028(4) 0.006(4) -0.033(4)
C18 0.071(6) 0.081(7) 0.054(5) -0.021(5) -0.017(4) -0.024(5)
C21 0.037(4) 0.033(4) 0.056(5) -0.014(4) 0.018(3) -0.014(3)
C22 0.070(6) 0.056(5) 0.056(6) -0.027(4) 0.022(4) -0.030(5)
C23 0.052(5) 0.046(5) 0.041(4) -0.019(4) 0.007(3) -0.009(4)
C24 0.147(9) 0.038(5) 0.073(7) -0.009(4) 0.026(6) -0.041(6)
C25 0.039(4) 0.028(4) 0.047(4) -0.008(3) 0.008(3) -0.012(3)
C26 0.041(4) 0.047(5) 0.055(5) 0.003(4) -0.006(4) -0.007(4)
C27 0.041(4) 0.042(4) 0.043(4) -0.005(3) -0.002(3) -0.014(4)
C28 0.054(5) 0.077(7) 0.076(7) -0.013(5) 0.015(5) 0.004(5)
C31 0.037(4) 0.035(4) 0.043(4) -0.009(3) 0.004(3) -0.021(3)
C32 0.036(4) 0.052(5) 0.063(5) -0.015(4) 0.014(4) -0.017(4)
C33 0.026(4) 0.061(5) 0.083(6) -0.009(5) -0.004(4) -0.010(4)
C34 0.063(5) 0.066(6) 0.055(5) -0.017(4) -0.005(4) -0.024(5)
C35 0.038(4) 0.029(4) 0.034(4) -0.010(3) 0.003(3) -0.009(3)
C36 0.037(4) 0.041(4) 0.054(5) -0.015(4) 0.003(3) -0.006(4)
C37 0.028(4) 0.046(5) 0.054(5) -0.016(4) 0.005(3) -0.012(3)
C38 0.066(5) 0.037(4) 0.080(6) -0.016(4) 0.013(4) -0.030(4)
_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
 _geom_bond_atom_site_label_1
 _geom_bond_atom_site_label_2
 _geom_bond_distance
 _geom_bond_site_symmetry_2
 _geom_bond_publ_flag
Zn1 O1 1.948(5) . ?
Zn1 N11 1.997(5) . ?
Zn1 N31 2.005(5) . ?
Zn1 N21 2.019(5) . ?
Zn2 O2 1.954(4) . ?
Zn2 N23 1.990(5) . ?
Zn2 N33 2.013(5) . ?
Zn2 N13 2.031(6) . ?
O11 N1 1.259(8) . ?
O12 N1 1.227(8) . ?
O13 N1 1.230(8) . ?
O21 N2 1.257(9) . ?
O22 N2 1.240(9) . ?
O23 N2 1.242(8) . ?
O31 N3 1.267(8) . ?
O32 N3 1.230(8) . ?
O33 N3 1.215(7) . ?
O41 N4 1.348(14) . ?
O42 N4 1.206(10) . ?
O43 N4 1.105(13) . ?
N11 C11 1.324(8) . ?
N11 C12 1.380(9) . ?
N12 C11 1.354(8) . ?
N12 C13 1.357(9) . ?
N12 C14 1.465(9) . ?
N13 C15 1.324(9) . ?
N13 C16 1.384(8) . ?
N14 C17 1.345(9) . ?
N14 C15 1.347(8) . ?
N14 C18 1.488(9) . ?
N21 C21 1.323(9) . ?
N21 C23 1.391(8) . ?
N22 C22 1.342(10) . ?
N22 C21 1.364(8) . ?
N22 C24 1.457(9) . ?
N23 C25 1.338(8) . ?
N23 C27 1.384(8) . ?
N24 C25 1.347(8) . ?
N24 C26 1.366(9) . ?
N24 C28 1.476(8) . ?
N31 C31 1.320(8) . ?
N31 C32 1.379(8) . ?
N32 C31 1.357(8) . ?
N32 C33 1.365(8) . ?
N32 C34 1.483(9) . ?
N33 C35 1.324(8) . ?
N33 C37 1.374(8) . ?
N34 C35 1.355(7) . ?
N34 C36 1.358(8) . ?
N34 C38 1.478(8) . ?
C11 C15 1.464(9) . ?
C12 C13 1.343(10) . ?
C16 C17 1.342(10) . ?
C21 C25 1.466(10) . ?
C22 C23 1.366(10) . ?
C26 C27 1.333(9) . ?
C31 C35 1.482(9) . ?
C32 C33 1.325(10) . ?
C36 C37 1.352(9) . ?
loop_
 _geom_angle_atom_site_label_1
 _geom_angle_atom_site_label_2
 _geom_angle_atom_site_label_3
 _geom_angle
 _geom_angle_site_symmetry_1
 _geom_angle_site_symmetry_3
 _geom_angle_publ_flag
O1 Zn1 N11 115.8(2) . . ?
O1 Zn1 N31 107.7(2) . . ?
N11 Zn1 N31 109.5(2) . . ?
O1 Zn1 N21 105.1(2) . . ?
N11 Zn1 N21 111.8(2) . . ?
N31 Zn1 N21 106.5(2) . . ?
O2 Zn2 N23 118.9(2) . . ?
O2 Zn2 N33 105.2(2) . . ?
N23 Zn2 N33 108.3(2) . . ?
O2 Zn2 N13 102.2(2) . . ?
N23 Zn2 N13 111.5(2) . . ?
N33 Zn2 N13 110.4(2) . . ?
O12 N1 O13 122.7(8) . . ?
O12 N1 O11 118.9(8) . . ?
O13 N1 O11 118.3(7) . . ?
O22 N2 O23 121.4(8) . . ?
O22 N2 O21 120.3(8) . . ?
O23 N2 O21 118.2(8) . . ?
O33 N3 O32 121.0(7) . . ?
O33 N3 O31 119.8(7) . . ?
O32 N3 O31 119.0(7) . . ?
O43 N4 O42 129.8(17) . . ?
O43 N4 O41 119.6(13) . . ?
O42 N4 O41 110.6(13) . . ?
C11 N11 C12 105.6(6) . . ?
C11 N11 Zn1 128.6(5) . . ?
C12 N11 Zn1 125.5(5) . . ?
C11 N12 C13 107.7(6) . . ?
C11 N12 C14 126.6(7) . . ?
C13 N12 C14 125.3(7) . . ?
C15 N13 C16 105.8(6) . . ?
C15 N13 Zn2 129.8(5) . . ?
C16 N13 Zn2 124.1(5) . . ?
C17 N14 C15 108.2(6) . . ?
C17 N14 C18 125.6(6) . . ?
C15 N14 C18 126.1(6) . . ?
C21 N21 C23 106.7(6) . . ?
C21 N21 Zn1 132.1(5) . . ?
C23 N21 Zn1 121.2(5) . . ?
C22 N22 C21 107.2(6) . . ?
C22 N22 C24 126.4(7) . . ?
C21 N22 C24 126.1(7) . . ?
C25 N23 C27 106.0(6) . . ?
C25 N23 Zn2 128.8(5) . . ?
C27 N23 Zn2 124.8(4) . . ?
C25 N24 C26 108.3(6) . . ?
C25 N24 C28 126.6(7) . . ?
C26 N24 C28 125.1(7) . . ?
C31 N31 C32 106.1(6) . . ?
C31 N31 Zn1 131.8(4) . . ?
C32 N31 Zn1 122.0(5) . . ?
C31 N32 C33 106.7(6) . . ?
C31 N32 C34 126.9(6) . . ?
C33 N32 C34 126.2(6) . . ?
C35 N33 C37 106.7(5) . . ?
C35 N33 Zn2 131.1(4) . . ?
C37 N33 Zn2 122.2(4) . . ?
C35 N34 C36 107.3(5) . . ?
C35 N34 C38 126.6(5) . . ?
C36 N34 C38 125.5(6) . . ?
N11 C11 N12 110.3(6) . . ?
N11 C11 C15 125.8(6) . . ?
N12 C11 C15 123.9(6) . . ?
C13 C12 N11 109.7(7) . . ?
C12 C13 N12 106.7(7) . . ?
N13 C15 N14 109.9(6) . . ?
N13 C15 C11 125.8(7) . . ?
N14 C15 C11 124.3(7) . . ?
C17 C16 N13 108.9(7) . . ?
C16 C17 N14 107.1(6) . . ?
N21 C21 N22 110.3(7) . . ?
N21 C21 C25 127.5(6) . . ?
N22 C21 C25 122.1(6) . . ?
N22 C22 C23 108.4(7) . . ?
C22 C23 N21 107.3(7) . . ?
N23 C25 N24 109.3(6) . . ?
N23 C25 C21 125.3(6) . . ?
N24 C25 C21 125.4(6) . . ?
C27 C26 N24 106.8(7) . . ?
C26 C27 N23 109.5(6) . . ?
N31 C31 N32 110.2(6) . . ?
N31 C31 C35 126.6(6) . . ?
N32 C31 C35 123.2(6) . . ?
C33 C32 N31 109.3(6) . . ?
C32 C33 N32 107.7(6) . . ?
N33 C35 N34 110.0(5) . . ?
N33 C35 C31 126.4(6) . . ?
N34 C35 C31 123.6(6) . . ?
C37 C36 N34 107.4(6) . . ?
C36 C37 N33 108.5(6) . . ?
_diffrn_measured_fraction_theta_max    0.983
_diffrn_reflns_theta_full              24.99
_diffrn_measured_fraction_theta_full   0.983
_refine_diff_density_max    0.668
_refine_diff_density_min   -0.678
_refine_diff_density_rms    0.115
_cod_database_code 1100979