#------------------------------------------------------------------------------ #$Date: 2022-07-06 10:58:16 +0300 (Wed, 06 Jul 2022) $ #$Revision: 276600 $ #$URL: file:///home/coder/svn-repositories/cod/cif/1/56/69/1566976.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_1566976 loop_ _publ_author_name 'Zhang, Wei-Qiang' 'Morgan, Harry W. T.' 'McGrady, John E.' 'Sun, Zhong-Ming' _publ_section_title ; Synthesis and characterisation of the ternary intermetalloid clusters {M@[As8(ZnMes)4]}3- (M = Nb, Ta) from binary [M@As8]3- precursors. ; _journal_issue 22 _journal_name_full 'Chemical science' _journal_page_first 6744 _journal_page_last 6748 _journal_paper_doi 10.1039/d2sc01748b _journal_volume 13 _journal_year 2022 _chemical_formula_moiety 'C36 H44 As8 Nb Zn4, 3(C18 H36 K N2 O6), C2 H8 N2, C2 H7 N2, C7 H8' _chemical_formula_sum 'C101 H175 As8 K3 N10 Nb O18 Zn4' _chemical_formula_weight 2888.55 _space_group_crystal_system monoclinic _space_group_IT_number 14 _space_group_name_Hall '-P 2yn' _space_group_name_H-M_alt 'P 1 21/n 1' _atom_sites_solution_hydrogens geom _atom_sites_solution_primary iterative _audit_creation_date 2021-05-13 _audit_creation_method ; Olex2 1.3-beta (compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272) ; _audit_update_record ; 2021-07-01 deposited with the CCDC. 2022-05-16 downloaded from the CCDC. ; _cell_angle_alpha 90 _cell_angle_beta 104.5190(10) _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 16.9909(2) _cell_length_b 33.0617(4) _cell_length_c 22.6750(2) _cell_measurement_reflns_used 30150 _cell_measurement_temperature 100.00(10) _cell_measurement_theta_max 72.4250 _cell_measurement_theta_min 3.7280 _cell_volume 12330.9(2) _computing_cell_refinement 'CrysAlisPro 1.171.40.84a (Rigaku OD, 2020)' _computing_data_collection 'CrysAlisPro 1.171.40.84a (Rigaku OD, 2020)' _computing_data_reduction 'CrysAlisPro 1.171.40.84a (Rigaku OD, 2020)' _computing_molecular_graphics 'Olex2 1.3-beta (Dolomanov et al., 2009)' _computing_publication_material 'Olex2 1.3-beta (Dolomanov et al., 2009)' _computing_structure_refinement 'olex2.refine 1.3-beta (Bourhis et al., 2015)' _computing_structure_solution 'olex2.solve 1.3-beta (Bourhis et al., 2015)' _diffrn_ambient_environment N~2~ _diffrn_ambient_temperature 100.00(10) _diffrn_detector 'Hybrid Pixel Array Detector' _diffrn_detector_area_resol_mean 10.0000 _diffrn_measured_fraction_theta_full 0.981 _diffrn_measured_fraction_theta_max 0.997 _diffrn_measurement_details ; List of Runs (angles in degrees, time in seconds): # Type Start End Width t~exp~ \w \q \k \f Frames #-------------------------------------------------------------------------- 1 \w -36.00 5.00 0.50 1.74 -- -35.00 -82.00 120.00 82 2 \w -103.00 -77.00 0.50 1.74 -- -35.00 -77.00 150.00 52 3 \w -31.00 2.00 0.50 1.74 -- -35.00 -82.00-120.00 66 4 \w -69.00 44.00 0.50 1.74 -- -35.00 57.00 60.00 226 5 \w 84.00 133.00 0.50 1.74 -- 43.40 82.00 0.00 98 6 \w 11.00 37.00 0.50 1.74 -- 43.40 77.00 150.00 52 7 \w 22.00 48.00 0.50 1.74 -- 43.40 77.00 -30.00 52 8 \w 89.00 117.00 0.50 6.95 -- 104.50 82.00-120.00 56 9 \w 88.00 146.00 0.50 6.95 -- 104.50 82.00-150.00 116 10 \w 117.00 145.00 0.50 6.95 -- 104.50 -45.00 60.00 56 11 \w 18.00 100.00 0.50 6.95 -- 104.50 -45.00 60.00 164 12 \w 67.00 161.00 0.50 6.95 -- 104.50 45.00 -30.00 188 13 \w 163.00 192.00 0.50 6.95 -- 104.50 82.00 -90.00 58 14 \w 79.00 142.00 0.50 6.95 -- 104.50 61.00-180.00 126 15 \w 163.00 189.00 0.50 6.95 -- 104.50 61.00-180.00 52 16 \w 129.00 192.00 0.50 6.95 -- 104.50 82.00-120.00 126 17 \w 164.00 189.00 0.50 6.95 -- 104.50 82.00-150.00 50 18 \w 74.00 185.00 0.50 6.95 -- 104.50 45.00 -60.00 222 ; _diffrn_measurement_device 'four-circle diffractometer' _diffrn_measurement_device_type 'XtaLAB AFC12 (RINC): Kappa single' _diffrn_measurement_method '\w scans' _diffrn_orient_matrix_type 'CrysAlisPro convention (1999,Acta A55,543-557)' _diffrn_orient_matrix_UB_11 0.0717125000 _diffrn_orient_matrix_UB_12 0.0296105000 _diffrn_orient_matrix_UB_13 0.0066064000 _diffrn_orient_matrix_UB_21 0.0286333000 _diffrn_orient_matrix_UB_22 -0.0230917000 _diffrn_orient_matrix_UB_23 -0.0498459000 _diffrn_orient_matrix_UB_31 -0.0530875000 _diffrn_orient_matrix_UB_32 0.0275494000 _diffrn_orient_matrix_UB_33 -0.0489526000 _diffrn_radiation_monochromator mirror _diffrn_radiation_probe x-ray _diffrn_radiation_type 'Cu K\a' _diffrn_radiation_wavelength 1.54184 _diffrn_reflns_av_R_equivalents 0.0324 _diffrn_reflns_av_unetI/netI 0.0356 _diffrn_reflns_Laue_measured_fraction_full 0.981 _diffrn_reflns_Laue_measured_fraction_max 0.997 _diffrn_reflns_limit_h_max 20 _diffrn_reflns_limit_h_min -20 _diffrn_reflns_limit_k_max 27 _diffrn_reflns_limit_k_min -39 _diffrn_reflns_limit_l_max 20 _diffrn_reflns_limit_l_min -27 _diffrn_reflns_number 62745 _diffrn_reflns_point_group_measured_fraction_full 0.981 _diffrn_reflns_point_group_measured_fraction_max 0.997 _diffrn_reflns_theta_full 67.684 _diffrn_reflns_theta_max 66.993 _diffrn_reflns_theta_min 3.740 _diffrn_source 'Rotating-anode X-ray tube (dual wavelength)' _diffrn_source_type 'Rigaku (Cu) X-ray DW Source' _exptl_absorpt_coefficient_mu 5.397 _exptl_absorpt_correction_T_max 1.00000 _exptl_absorpt_correction_T_min 0.46202 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; CrysAlisPro 1.171.40.84a (Rigaku Oxford Diffraction, 2020) Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm. ; _exptl_crystal_colour green _exptl_crystal_density_diffrn 1.556 _exptl_crystal_description block _exptl_crystal_F_000 5908 _exptl_crystal_size_max 0.2 _exptl_crystal_size_mid 0.18 _exptl_crystal_size_min 0.16 _refine_diff_density_max 0.988 _refine_diff_density_min -0.930 _refine_diff_density_rms 0.091 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.097 _refine_ls_hydrogen_treatment constr _refine_ls_matrix_type full _refine_ls_number_parameters 1326 _refine_ls_number_reflns 21908 _refine_ls_number_restraints 1 _refine_ls_restrained_S_all 1.119 _refine_ls_R_factor_all 0.0452 _refine_ls_R_factor_gt 0.0406 _refine_ls_shift/su_max 0.004 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details ; w=1/[\s^2^(Fo^2^)+(0.0346P)^2^+38.3699P] where P=(Fo^2^+2Fc^2^)/3 ; _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.1011 _refine_ls_wR_factor_ref 0.1031 _reflns_Friedel_coverage 0.000 _reflns_number_gt 20269 _reflns_number_total 21908 _reflns_threshold_expression 'I > 2\s(I)' _cod_data_source_file d2sc01748b2.cif _cod_data_source_block 5 _cod_depositor_comments 'Adding full bibliography for 1566976--1566977.cif.' _cod_database_code 1566976 _shelxl_version_number 2013-2 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _reflns_odcompleteness_completeness 99.62 _reflns_odcompleteness_iscentric 1 _reflns_odcompleteness_theta 66.97 _olex2_refinement_description ; 1. Restrained distances H5B-H8D 2.38 with sigma of 0.01 2. Uiso/Uaniso restraints and constraints Uanis(C94) = Uanis(C94') Uanis(N10) = Uanis(N10') 3. Others Sof(N10')=Sof(H10E)=Sof(H10F)=Sof(H93A)=Sof(C94')=Sof(H94C)=Sof(H94D)=1-FVAR(1) Sof(N10)=Sof(H10C)=Sof(H10D)=Sof(H93)=Sof(C94)=Sof(H94A)=Sof(H94B)=FVAR(1) 4.a Secondary CH2 refined with riding coordinates: C1(H1A,H1B), C2(H2A,H2B), C3(H3A,H3B), C4(H4A,H4B), C5(H5A,H5B), C6(H6A,H6B), C7(H7A,H7B), C8(H8A,H8B), C9(H9A,H9B), C10(H10A,H10B), C11(H11A,H11B), C12(H12A,H12B), C13(H13A,H13B), C14(H14A,H14B), C15(H15A,H15B), C16(H16A,H16B), C17(H17A,H17B), C18(H18A,H18B), C19(H19A,H19B), C20(H20A,H20B), C21(H21A, H21B), C22(H22A,H22B), C23(H23A,H23B), C24(H24A,H24B), C25(H25A,H25B), C26(H26A,H26B), C27(H27A,H27B), C28(H28A,H28B), C29(H29A,H29B), C30(H30A,H30B), C31(H31A,H31B), C32(H32A,H32B), C33(H33A,H33B), C34(H34A,H34B), C35(H35A, H35B), C36(H36A,H36B), C37(H37A,H37B), C38(H38A,H38B), C39(H39A,H39B), C40(H40A,H40B), C41(H41A,H41B), C42(H42A,H42B), C43(H43A,H43B), C44(H44A,H44B), C45(H45A,H45B), C46(H46A,H46B), C47(H47A,H47B), C48(H48A,H48B), C49(H49A, H49B), C50(H50A,H50B), C51(H51A,H51B), C52(H52A,H52B), C53(H53A,H53B), C54(H54A,H54B), C91(H91A,H91B), C92(H92A,H92B), C94(H94A,H94B), C94'(H94C,H94D) 4.b Aromatic/amide H refined with riding coordinates: C58(H58), C61(H61), C67(H67), C70(H70), C76(H76), C79(H79), C85(H85), C88(H88), C93(H93), C93(H93A), C95(H95), C96(H96), C97(H97), C98(H98), C101(H101) 4.c X=CH2 refined with riding coordinates: N7(H7C,H7D), N8(H8C,H8D), N9(H9C,H9D), N10(H10C,H10D), N10'(H10E,H10F) 4.d Idealised Me refined as rotating group: C57(H57A,H57B,H57C), C60(H60A,H60B,H60C), C63(H63A,H63B,H63C), C66(H66A,H66B, H66C), C69(H69A,H69B,H69C), C72(H72A,H72B,H72C), C75(H75A,H75B,H75C), C78(H78A, H78B,H78C), C81(H81A,H81B,H81C), C84(H84A,H84B,H84C), C87(H87A,H87B,H87C), C90(H90A,H90B,H90C), C100(H10G,H10H,H10I) ; _smtbx_masks_void_probe_radius 1.2 _smtbx_masks_void_truncation_radius 1.2 _shelx_res_file ; TITL zwq_a.res in P2(1)/n CELL 1.54184 16.9909 33.0617 22.675 90 104.519 90 ZERR 4 0.0002 0.0004 0.0002 0 0.001 0 LATT 1 SYMM 0.5-X,0.5+Y,0.5-Z SFAC C H N O K Nb Zn As UNIT 404 700 40 72 12 4 16 32 EADP C94 C94' EADP N10 N10' DFIX 2.38 0.01 H5b H8d L.S. 5 PLAN 43 CONF BOND $H LIST 4 MORE -1 ABIN fmap 2 acta OMIT -3 134 REM REM REM WGHT 0.034600 38.369900 FVAR 0.14091 0.72008 NB1 6 0.058773 0.839429 0.290690 11.00000 0.01793 0.02039 = 0.01491 -0.00036 0.00337 0.00195 AS1 8 -0.000220 0.817107 0.387263 11.00000 0.02206 0.02197 = 0.01657 -0.00103 0.00455 0.00033 AS2 8 -0.085730 0.862096 0.312484 11.00000 0.02021 0.02310 = 0.02080 -0.00010 0.00578 0.00311 AS3 8 -0.092570 0.814748 0.230003 11.00000 0.02048 0.02385 = 0.01840 -0.00018 0.00162 0.00154 AS4 8 -0.023299 0.859562 0.175326 11.00000 0.02487 0.02524 = 0.01578 0.00093 0.00364 0.00281 AS5 8 0.127885 0.768251 0.269065 11.00000 0.02469 0.02328 = 0.01979 -0.00029 0.00651 0.00485 AS6 8 0.209719 0.811426 0.347169 11.00000 0.01962 0.02872 = 0.02076 0.00026 0.00362 0.00443 AS7 8 0.203825 0.867134 0.276559 11.00000 0.02124 0.02929 = 0.02246 -0.00054 0.00718 -0.00007 AS8 8 0.129698 0.910358 0.330457 11.00000 0.02196 0.02187 = 0.02073 -0.00071 0.00408 -0.00030 ZN1 7 0.131392 0.854757 0.413412 11.00000 0.02240 0.02484 = 0.01782 -0.00168 0.00165 -0.00003 ZN2 7 -0.001924 0.762381 0.304629 11.00000 0.02274 0.02168 = 0.01801 -0.00044 0.00331 0.00125 ZN3 7 0.111765 0.824393 0.185704 11.00000 0.02731 0.02801 = 0.01913 -0.00055 0.00917 0.00254 ZN4 7 -0.007522 0.915392 0.257523 11.00000 0.02377 0.02272 = 0.02067 0.00163 0.00465 0.00381 K1 5 0.242320 0.597477 0.087311 11.00000 0.02556 0.03018 = 0.03150 -0.00032 0.00799 0.00285 K2 5 0.532260 0.734045 0.232523 11.00000 0.02146 0.03061 = 0.02299 0.00056 0.00620 0.00216 K3 5 0.765743 0.889139 0.004998 11.00000 0.03976 0.03079 = 0.02919 0.00357 -0.00159 -0.01096 O1 4 0.076110 0.590831 0.073816 11.00000 0.03045 0.06331 = 0.06372 -0.01396 0.01681 0.00100 O2 4 0.138132 0.596464 -0.031756 11.00000 0.02807 0.06057 = 0.04216 -0.01371 0.00083 -0.00432 O3 4 0.312817 0.555890 0.199785 11.00000 0.04034 0.02454 = 0.03485 0.00336 0.01719 0.00689 O4 4 0.358244 0.537455 0.091171 11.00000 0.03054 0.03107 = 0.03083 0.00301 0.01180 0.00500 O5 4 0.246424 0.671801 0.144384 11.00000 0.04099 0.03065 = 0.03516 -0.00455 0.01919 -0.00027 O6 4 0.332387 0.663536 0.052945 11.00000 0.03417 0.02824 = 0.02492 0.00303 0.00832 0.00580 O7 4 0.437087 0.690284 0.298266 11.00000 0.03887 0.04645 = 0.02815 0.00880 0.01477 0.00672 O8 4 0.524785 0.647602 0.228063 11.00000 0.03427 0.03006 = 0.02927 0.00321 0.01246 -0.00358 O9 4 0.634212 0.776673 0.330638 11.00000 0.02333 0.04744 = 0.03131 -0.00692 0.00691 -0.00156 O10 4 0.694791 0.744751 0.234787 11.00000 0.02051 0.03598 = 0.02559 0.00092 0.00526 0.00315 O11 4 0.427579 0.800809 0.193726 11.00000 0.02863 0.03775 = 0.02990 -0.00057 0.00746 0.00678 O12 4 0.472045 0.750548 0.107344 11.00000 0.03218 0.02695 = 0.02653 0.00549 0.00927 0.00548 O13 4 0.640099 0.844143 -0.077979 11.00000 0.03564 0.03299 = 0.01946 0.00046 0.00240 -0.00518 O14 4 0.653671 0.929509 -0.096090 11.00000 0.05151 0.03642 = 0.04678 0.01007 -0.01764 -0.01507 O15 4 0.742806 0.852508 0.106030 11.00000 0.03069 0.02662 = 0.02624 -0.00167 0.00751 -0.00246 O16 4 0.722640 0.936579 0.099733 11.00000 0.04698 0.02437 = 0.04657 -0.00409 -0.01323 -0.00156 O17 4 0.899872 0.847047 -0.019209 11.00000 0.02968 0.05512 = 0.02664 0.00232 0.00572 -0.01564 O18 4 0.903510 0.932600 -0.005869 11.00000 0.07193 0.05508 = 0.02934 0.01060 -0.00018 -0.03631 N1 3 0.170411 0.607367 0.197202 11.00000 0.04293 0.03957 = 0.04881 0.00564 0.02549 0.01037 N2 3 0.311559 0.588665 -0.020937 11.00000 0.03123 0.03430 = 0.02360 -0.00230 0.00477 -0.00075 N3 3 0.460097 0.778182 0.323145 11.00000 0.02906 0.05267 = 0.02996 -0.00559 0.00904 0.00799 N4 3 0.600486 0.688543 0.142952 11.00000 0.02554 0.02345 = 0.02558 0.00318 0.00979 0.00114 N5 3 0.766967 0.798908 0.009725 11.00000 0.02308 0.03013 = 0.02050 -0.00187 0.00492 -0.00486 N6 3 0.756815 0.982023 -0.004195 11.00000 0.08647 0.03367 = 0.05667 0.01466 -0.03216 -0.01937 N7 3 0.148974 0.409284 0.084555 11.00000 0.04314 0.04681 = 0.03926 0.00008 -0.00106 -0.00133 AFIX 93 H7C 2 0.144240 0.406697 0.046083 11.00000 -1.20000 H7D 2 0.156218 0.388273 0.107648 11.00000 -1.20000 AFIX 0 N8 3 0.195757 0.482946 0.030429 11.00000 0.04799 0.06125 = 0.06331 0.00189 0.01843 -0.00108 AFIX 93 H8C 2 0.236585 0.466796 0.040719 11.00000 -1.20000 H8D 2 0.193335 0.500218 0.001670 11.00000 -1.20000 AFIX 0 N9 3 0.548605 0.871766 0.024435 11.00000 0.09047 0.14954 = 0.07303 -0.01860 0.01427 0.03122 AFIX 93 H9C 2 0.589422 0.874707 0.055414 11.00000 -1.20000 H9D 2 0.553614 0.857698 -0.006319 11.00000 -1.20000 AFIX 0 PART 1 N10 3 0.520896 0.949702 0.084099 21.00000 0.07656 0.13985 = 0.20748 -0.10364 -0.01814 0.03288 AFIX 93 H10C 2 0.548256 0.955475 0.058035 21.00000 -1.20000 H10D 2 0.523473 0.965246 0.114936 21.00000 -1.20000 AFIX 0 PART 2 N10' 3 0.491344 0.961444 0.016595 -21.00000 0.07656 0.13985 = 0.20748 -0.10364 -0.01814 0.03288 AFIX 93 H10E 2 0.538990 0.963853 0.040763 -21.00000 -1.20000 H10F 2 0.466615 0.982388 -0.001621 -21.00000 -1.20000 AFIX 0 PART 0 C1 1 0.091929 0.586681 0.181514 11.00000 0.05665 0.06124 = 0.07702 0.00191 0.04345 0.00160 AFIX 23 H1A 2 0.064215 0.592106 0.213230 11.00000 -1.20000 H1B 2 0.101664 0.557777 0.181340 11.00000 -1.20000 AFIX 0 C2 1 0.036958 0.598127 0.121896 11.00000 0.03793 0.06998 = 0.08706 -0.01489 0.03185 -0.00065 AFIX 23 H2A 2 -0.012768 0.582434 0.114859 11.00000 -1.20000 H2B 2 0.022819 0.626527 0.122431 11.00000 -1.20000 AFIX 0 C3 1 0.030274 0.606034 0.016926 11.00000 0.03138 0.08995 = 0.06489 -0.01725 0.00270 0.00734 AFIX 23 H3A 2 0.038579 0.634977 0.014903 11.00000 -1.20000 H3B 2 -0.027164 0.601187 0.012773 11.00000 -1.20000 AFIX 0 C4 1 0.056793 0.585362 -0.033624 11.00000 0.03252 0.09926 = 0.05890 -0.02198 0.00520 -0.01191 AFIX 23 H4A 2 0.053243 0.556274 -0.029345 11.00000 -1.20000 H4B 2 0.021282 0.593104 -0.072528 11.00000 -1.20000 AFIX 0 C5 1 0.168079 0.574196 -0.074976 11.00000 0.04048 0.06472 = 0.03853 -0.01688 0.00265 -0.00879 AFIX 23 H5A 2 0.130037 0.576261 -0.114671 11.00000 -1.20000 H5B 2 0.172830 0.545887 -0.063389 11.00000 -1.20000 AFIX 0 C6 1 0.248040 0.589607 -0.078579 11.00000 0.04387 0.05106 = 0.02739 -0.00457 0.00353 -0.00448 AFIX 23 H6A 2 0.266488 0.573785 -0.108562 11.00000 -1.20000 H6B 2 0.241525 0.617305 -0.093092 11.00000 -1.20000 AFIX 0 C7 1 0.223966 0.588788 0.251124 11.00000 0.06717 0.04404 = 0.04620 0.01176 0.03719 0.02191 AFIX 23 H7A 2 0.193193 0.584362 0.281260 11.00000 -1.20000 H7B 2 0.267447 0.607593 0.268422 11.00000 -1.20000 AFIX 0 C8 1 0.261059 0.549135 0.239085 11.00000 0.06187 0.03779 = 0.05160 0.01343 0.03385 0.01202 AFIX 23 H8A 2 0.291967 0.537558 0.277177 11.00000 -1.20000 H8B 2 0.218444 0.530230 0.220373 11.00000 -1.20000 AFIX 0 C9 1 0.351697 0.518660 0.191055 11.00000 0.03726 0.02326 = 0.03306 0.00158 0.01013 0.00638 AFIX 23 H9A 2 0.310941 0.498581 0.173457 11.00000 -1.20000 H9B 2 0.383194 0.508553 0.229999 11.00000 -1.20000 AFIX 0 C10 1 0.406170 0.525617 0.149658 11.00000 0.02903 0.02553 = 0.03525 -0.00030 0.00597 0.00434 AFIX 23 H10A 2 0.445288 0.546642 0.166229 11.00000 -1.20000 H10B 2 0.435772 0.501026 0.146092 11.00000 -1.20000 AFIX 0 C11 1 0.406837 0.541051 0.048518 11.00000 0.03263 0.02968 = 0.04188 0.00243 0.01947 0.00600 AFIX 23 H11A 2 0.437207 0.516272 0.047949 11.00000 -1.20000 H11B 2 0.445313 0.563057 0.060382 11.00000 -1.20000 AFIX 0 C12 1 0.352178 0.549164 -0.014345 11.00000 0.04044 0.03208 = 0.03356 -0.00746 0.01749 -0.00023 AFIX 23 H12A 2 0.384494 0.547297 -0.043954 11.00000 -1.20000 H12B 2 0.311034 0.528181 -0.023852 11.00000 -1.20000 AFIX 0 C13 1 0.160584 0.650835 0.206237 11.00000 0.04553 0.04476 = 0.04198 0.01086 0.02433 0.02001 AFIX 23 H13A 2 0.148790 0.654897 0.245515 11.00000 -1.20000 H13B 2 0.114139 0.660470 0.175206 11.00000 -1.20000 AFIX 0 C14 1 0.233626 0.675861 0.203733 11.00000 0.04286 0.03663 = 0.03306 -0.00067 0.01201 0.01391 AFIX 23 H14A 2 0.224299 0.704007 0.211982 11.00000 -1.20000 H14B 2 0.281059 0.666492 0.234079 11.00000 -1.20000 AFIX 0 C15 1 0.297073 0.702829 0.130702 11.00000 0.03843 0.02778 = 0.03894 -0.00460 0.01447 -0.00011 AFIX 23 H15A 2 0.352340 0.699357 0.155124 11.00000 -1.20000 H15B 2 0.277697 0.729099 0.139919 11.00000 -1.20000 AFIX 0 C16 1 0.295024 0.700327 0.064609 11.00000 0.02933 0.02584 = 0.03593 0.00298 0.00604 0.00172 AFIX 23 H16A 2 0.239162 0.701191 0.040463 11.00000 -1.20000 H16B 2 0.323743 0.723208 0.053183 11.00000 -1.20000 AFIX 0 C17 1 0.337815 0.662239 -0.008791 11.00000 0.03546 0.03472 = 0.02363 0.00587 0.00420 0.00227 AFIX 23 H17A 2 0.374059 0.683343 -0.015834 11.00000 -1.20000 H17B 2 0.284585 0.666758 -0.035985 11.00000 -1.20000 AFIX 0 C18 1 0.369673 0.621457 -0.021321 11.00000 0.03255 0.03397 = 0.02516 0.00291 0.00960 -0.00178 AFIX 23 H18A 2 0.382286 0.622118 -0.060729 11.00000 -1.20000 H18B 2 0.419698 0.615911 0.009238 11.00000 -1.20000 AFIX 0 C19 1 0.525165 0.788974 0.376876 11.00000 0.03397 0.07971 = 0.02923 -0.01951 0.00537 0.00888 AFIX 23 H19A 2 0.540775 0.764986 0.401681 11.00000 -1.20000 H19B 2 0.504132 0.808500 0.400971 11.00000 -1.20000 AFIX 0 C20 1 0.599895 0.806495 0.361760 11.00000 0.02992 0.06512 = 0.04305 -0.02529 -0.00249 0.00710 AFIX 23 H20A 2 0.585271 0.830246 0.336249 11.00000 -1.20000 H20B 2 0.639136 0.814476 0.398870 11.00000 -1.20000 AFIX 0 C21 1 0.708639 0.789905 0.318954 11.00000 0.02668 0.05004 = 0.03154 -0.00802 0.00417 -0.00744 AFIX 23 H21A 2 0.745362 0.799117 0.356512 11.00000 -1.20000 H21B 2 0.698374 0.812336 0.290476 11.00000 -1.20000 AFIX 0 C22 1 0.746516 0.755693 0.292893 11.00000 0.02364 0.05003 = 0.02689 0.00269 0.00512 -0.00178 AFIX 23 H22A 2 0.799490 0.763746 0.288164 11.00000 -1.20000 H22B 2 0.753759 0.732667 0.320238 11.00000 -1.20000 AFIX 0 C23 1 0.732787 0.714626 0.206792 11.00000 0.02419 0.03454 = 0.03820 0.00443 0.01161 0.00573 AFIX 23 H23A 2 0.739870 0.690116 0.231067 11.00000 -1.20000 H23B 2 0.786020 0.723934 0.204354 11.00000 -1.20000 AFIX 0 C24 1 0.680923 0.705863 0.143649 11.00000 0.02784 0.03670 = 0.03155 0.00108 0.01408 0.00107 AFIX 23 H24A 2 0.673048 0.730777 0.120312 11.00000 -1.20000 H24B 2 0.709799 0.687141 0.123657 11.00000 -1.20000 AFIX 0 C25 1 0.400575 0.751468 0.340991 11.00000 0.03574 0.06576 = 0.03692 -0.00313 0.01964 0.00618 AFIX 23 H25A 2 0.350743 0.751463 0.308753 11.00000 -1.20000 H25B 2 0.388035 0.762354 0.377305 11.00000 -1.20000 AFIX 0 C26 1 0.429501 0.708500 0.353368 11.00000 0.04456 0.06532 = 0.03375 0.00619 0.02323 0.00681 AFIX 23 H26A 2 0.481653 0.708177 0.383130 11.00000 -1.20000 H26B 2 0.390998 0.693357 0.369851 11.00000 -1.20000 AFIX 0 C27 1 0.456543 0.648438 0.307291 11.00000 0.03999 0.04887 = 0.04261 0.02033 0.02023 0.00485 AFIX 23 H27A 2 0.415550 0.634979 0.323267 11.00000 -1.20000 H27B 2 0.508564 0.645441 0.336734 11.00000 -1.20000 AFIX 0 C28 1 0.460303 0.629491 0.248737 11.00000 0.03623 0.03483 = 0.04295 0.01214 0.01495 -0.00182 AFIX 23 H28A 2 0.469767 0.600653 0.254368 11.00000 -1.20000 H28B 2 0.409107 0.633419 0.218675 11.00000 -1.20000 AFIX 0 C29 1 0.537142 0.627175 0.175824 11.00000 0.04478 0.02452 = 0.03126 0.00179 0.01099 -0.00148 AFIX 23 H29A 2 0.489470 0.630115 0.142054 11.00000 -1.20000 H29B 2 0.546009 0.598573 0.184518 11.00000 -1.20000 AFIX 0 C30 1 0.610459 0.645296 0.159257 11.00000 0.03728 0.02443 = 0.03465 0.00130 0.01151 0.00662 AFIX 23 H30A 2 0.657515 0.642151 0.193471 11.00000 -1.20000 H30B 2 0.620903 0.630415 0.125138 11.00000 -1.20000 AFIX 0 C31 1 0.418370 0.815186 0.295287 11.00000 0.03031 0.05013 = 0.03839 -0.01449 0.00924 0.00466 AFIX 23 H31A 2 0.458389 0.836399 0.297265 11.00000 -1.20000 H31B 2 0.381066 0.823999 0.318818 11.00000 -1.20000 AFIX 0 C32 1 0.371697 0.809545 0.229762 11.00000 0.02200 0.04369 = 0.03819 -0.00420 0.00559 0.00955 AFIX 23 H32A 2 0.333298 0.787467 0.226777 11.00000 -1.20000 H32B 2 0.341499 0.833953 0.214946 11.00000 -1.20000 AFIX 0 C33 1 0.389608 0.804339 0.130667 11.00000 0.03420 0.02811 = 0.03366 0.00457 0.00725 0.00601 AFIX 23 H33A 2 0.372345 0.832049 0.121037 11.00000 -1.20000 H33B 2 0.341980 0.787071 0.120145 11.00000 -1.20000 AFIX 0 C34 1 0.449053 0.792040 0.094818 11.00000 0.04062 0.02842 = 0.03431 0.00883 0.01131 0.00764 AFIX 23 H34A 2 0.424485 0.795435 0.051630 11.00000 -1.20000 H34B 2 0.496897 0.809140 0.105786 11.00000 -1.20000 AFIX 0 C35 1 0.517226 0.735889 0.066044 11.00000 0.03250 0.03412 = 0.02322 0.00358 0.00888 0.00087 AFIX 23 H35A 2 0.564450 0.752898 0.068471 11.00000 -1.20000 H35B 2 0.483569 0.736964 0.024629 11.00000 -1.20000 AFIX 0 C36 1 0.543996 0.692924 0.082108 11.00000 0.03285 0.03168 = 0.02074 0.00001 0.00833 0.00073 AFIX 23 H36A 2 0.496294 0.676415 0.080443 11.00000 -1.20000 H36B 2 0.570208 0.682670 0.051749 11.00000 -1.20000 AFIX 0 C37 1 0.690024 0.782345 -0.027408 11.00000 0.02613 0.03276 = 0.02637 -0.00677 0.00633 -0.00646 AFIX 23 H37A 2 0.648618 0.784758 -0.004929 11.00000 -1.20000 H37B 2 0.697224 0.753811 -0.034524 11.00000 -1.20000 AFIX 0 C38 1 0.661107 0.803534 -0.087938 11.00000 0.03184 0.03831 = 0.02369 -0.00920 0.00451 -0.00477 AFIX 23 H38A 2 0.703756 0.803226 -0.109466 11.00000 -1.20000 H38B 2 0.614148 0.789565 -0.112722 11.00000 -1.20000 AFIX 0 C39 1 0.611152 0.864354 -0.135012 11.00000 0.04078 0.04550 = 0.01983 0.00563 -0.00273 -0.01465 AFIX 23 H39A 2 0.566019 0.849378 -0.160264 11.00000 -1.20000 H39B 2 0.654127 0.865650 -0.156173 11.00000 -1.20000 AFIX 0 C40 1 0.584307 0.905910 -0.124565 11.00000 0.03987 0.04337 = 0.03756 0.00900 -0.00910 -0.01257 AFIX 23 H40A 2 0.556593 0.918101 -0.163086 11.00000 -1.20000 H40B 2 0.546702 0.904906 -0.098709 11.00000 -1.20000 AFIX 0 C41 1 0.630306 0.969806 -0.085098 11.00000 0.08199 0.03607 = 0.06895 0.01255 -0.03427 -0.00434 AFIX 23 H41A 2 0.600294 0.969737 -0.053911 11.00000 -1.20000 H41B 2 0.595818 0.981179 -0.122059 11.00000 -1.20000 AFIX 0 C42 1 0.706539 0.994503 -0.064519 11.00000 0.11097 0.03330 = 0.07124 0.02067 -0.04267 -0.02020 AFIX 23 H42A 2 0.738465 0.991968 -0.094298 11.00000 -1.20000 H42B 2 0.691887 1.022754 -0.062776 11.00000 -1.20000 AFIX 0 C43 1 0.778181 0.788072 0.073901 11.00000 0.02609 0.02532 = 0.02279 0.00068 0.00828 -0.00210 AFIX 23 H43A 2 0.834319 0.793166 0.095241 11.00000 -1.20000 H43B 2 0.768350 0.759308 0.076554 11.00000 -1.20000 AFIX 0 C44 1 0.723616 0.810698 0.105826 11.00000 0.02720 0.02448 = 0.02634 -0.00133 0.00844 -0.00078 AFIX 23 H44A 2 0.667091 0.806404 0.084740 11.00000 -1.20000 H44B 2 0.731959 0.800962 0.147292 11.00000 -1.20000 AFIX 0 C45 1 0.716861 0.874325 0.151611 11.00000 0.02618 0.03577 = 0.03314 -0.00690 0.00599 0.00427 AFIX 23 H45A 2 0.734292 0.860530 0.190460 11.00000 -1.20000 H45B 2 0.658017 0.876228 0.141063 11.00000 -1.20000 AFIX 0 C46 1 0.753480 0.915715 0.155970 11.00000 0.03579 0.03518 = 0.03857 -0.00779 -0.00406 0.00567 AFIX 23 H46A 2 0.739956 0.930579 0.188982 11.00000 -1.20000 H46B 2 0.812203 0.913667 0.164440 11.00000 -1.20000 AFIX 0 C47 1 0.752952 0.976954 0.104992 11.00000 0.07864 0.02961 = 0.05971 -0.00458 -0.01611 -0.01129 AFIX 23 H47A 2 0.811915 0.976685 0.116731 11.00000 -1.20000 H47B 2 0.733926 0.991349 0.136045 11.00000 -1.20000 AFIX 0 C48 1 0.723127 0.997900 0.044129 11.00000 0.09559 0.02559 = 0.07862 0.00302 -0.02936 -0.00386 AFIX 23 H48A 2 0.664373 0.995636 0.031466 11.00000 -1.20000 H48B 2 0.736411 1.026424 0.049349 11.00000 -1.20000 AFIX 0 C49 1 0.835279 0.783319 -0.012447 11.00000 0.02970 0.03984 = 0.02384 -0.00444 0.00899 -0.00087 AFIX 23 H49A 2 0.819524 0.782789 -0.056623 11.00000 -1.20000 H49B 2 0.846383 0.755706 0.001647 11.00000 -1.20000 AFIX 0 C50 1 0.911776 0.807751 0.008041 11.00000 0.02803 0.05385 = 0.02119 0.00255 0.00857 -0.00101 AFIX 23 H50A 2 0.925974 0.810289 0.052063 11.00000 -1.20000 H50B 2 0.956121 0.794159 -0.003691 11.00000 -1.20000 AFIX 0 C51 1 0.973486 0.869755 -0.002188 11.00000 0.03615 0.08267 = 0.02764 -0.00462 0.00858 -0.03040 AFIX 23 H51A 2 1.016261 0.855879 -0.015549 11.00000 -1.20000 H51B 2 0.990347 0.872559 0.041768 11.00000 -1.20000 AFIX 0 C52 1 0.959165 0.910256 -0.031115 11.00000 0.06817 0.08802 = 0.02729 0.00045 0.01176 -0.04895 AFIX 23 H52A 2 1.010231 0.924799 -0.024386 11.00000 -1.20000 H52B 2 0.937173 0.907256 -0.074698 11.00000 -1.20000 AFIX 0 C53 1 0.888015 0.972201 -0.031135 11.00000 0.09862 0.07016 = 0.04111 0.02323 -0.01860 -0.05924 AFIX 23 H53A 2 0.857966 0.970253 -0.073478 11.00000 -1.20000 H53B 2 0.939160 0.985720 -0.029590 11.00000 -1.20000 AFIX 0 C54 1 0.840108 0.996403 0.003553 11.00000 0.10330 0.04253 = 0.05347 0.01747 -0.03391 -0.04021 AFIX 23 H54A 2 0.867770 0.995624 0.046512 11.00000 -1.20000 H54B 2 0.838590 1.024361 -0.009652 11.00000 -1.20000 AFIX 0 C55 1 0.186475 0.879939 0.493439 11.00000 0.02451 0.02388 = 0.01959 0.00120 0.00459 -0.00221 C56 1 0.262781 0.869517 0.529988 11.00000 0.02932 0.02470 = 0.02118 0.00288 0.00587 -0.00007 C57 1 0.306576 0.832190 0.516665 11.00000 0.03488 0.03183 = 0.02677 -0.00001 -0.00074 0.00537 AFIX 137 H57A 2 0.331784 0.837795 0.484100 11.00000 -1.50000 H57B 2 0.268344 0.810470 0.504966 11.00000 -1.50000 H57C 2 0.347439 0.824576 0.552459 11.00000 -1.50000 AFIX 0 C58 1 0.301092 0.893792 0.579433 11.00000 0.02909 0.03406 = 0.01802 0.00120 -0.00228 -0.00118 AFIX 43 H58 2 0.352065 0.886227 0.602911 11.00000 -1.20000 AFIX 0 C59 1 0.265677 0.928603 0.594489 11.00000 0.03807 0.03069 = 0.01890 -0.00048 0.00264 -0.00541 C60 1 0.310826 0.956537 0.644641 11.00000 0.05678 0.03806 = 0.02869 -0.00842 -0.00353 -0.00469 AFIX 137 H60A 2 0.319899 0.982101 0.627377 11.00000 -1.50000 H60B 2 0.362128 0.944645 0.664616 11.00000 -1.50000 H60C 2 0.279047 0.960559 0.673695 11.00000 -1.50000 AFIX 0 C61 1 0.187949 0.938384 0.560155 11.00000 0.03443 0.02583 = 0.02293 -0.00143 0.01049 -0.00068 AFIX 43 H61 2 0.161708 0.960975 0.570551 11.00000 -1.20000 AFIX 0 C62 1 0.148963 0.914866 0.510536 11.00000 0.02671 0.02712 = 0.02076 0.00274 0.00866 -0.00111 C63 1 0.067172 0.927856 0.472854 11.00000 0.02973 0.03062 = 0.03305 -0.00484 0.01015 0.00316 AFIX 137 H63A 2 0.072106 0.937019 0.433767 11.00000 -1.50000 H63B 2 0.046829 0.949462 0.493163 11.00000 -1.50000 H63C 2 0.030238 0.905400 0.467519 11.00000 -1.50000 AFIX 0 C64 1 -0.051855 0.707282 0.304891 11.00000 0.01710 0.02712 = 0.02236 -0.00235 0.00048 0.00453 C65 1 -0.065108 0.683190 0.251674 11.00000 0.01715 0.03060 = 0.02245 -0.00280 0.00025 0.00422 C66 1 -0.047654 0.700088 0.194692 11.00000 0.02826 0.03483 = 0.02168 -0.00732 0.00285 0.00233 AFIX 137 H66A 2 -0.079133 0.724195 0.182820 11.00000 -1.50000 H66B 2 -0.061829 0.680429 0.162617 11.00000 -1.50000 H66C 2 0.009143 0.706427 0.202265 11.00000 -1.50000 AFIX 0 C67 1 -0.094657 0.643776 0.251188 11.00000 0.02885 0.03235 = 0.02767 -0.01149 0.00246 -0.00165 AFIX 43 H67 2 -0.102051 0.628524 0.215757 11.00000 -1.20000 AFIX 0 C68 1 -0.113476 0.626496 0.302119 11.00000 0.03321 0.03105 = 0.03744 -0.00766 0.00901 -0.00870 C69 1 -0.142574 0.583259 0.302125 11.00000 0.06380 0.03942 = 0.05762 -0.01159 0.02618 -0.01954 AFIX 137 H69A 2 -0.195582 0.580814 0.274810 11.00000 -1.50000 H69B 2 -0.145237 0.575897 0.342533 11.00000 -1.50000 H69C 2 -0.105372 0.565626 0.289034 11.00000 -1.50000 AFIX 0 C70 1 -0.102597 0.650486 0.354005 11.00000 0.02812 0.03312 = 0.03040 -0.00230 0.00850 -0.00372 AFIX 43 H70 2 -0.115836 0.639993 0.388340 11.00000 -1.20000 AFIX 0 C71 1 -0.072327 0.689907 0.355919 11.00000 0.02483 0.02689 = 0.02390 -0.00109 0.00237 -0.00142 C72 1 -0.061474 0.712804 0.414823 11.00000 0.03976 0.03053 = 0.02418 -0.00130 0.01087 -0.00569 AFIX 137 H72A 2 -0.082543 0.697034 0.442961 11.00000 -1.50000 H72B 2 -0.090249 0.738020 0.407203 11.00000 -1.50000 H72C 2 -0.004710 0.717954 0.431858 11.00000 -1.50000 AFIX 0 C73 1 0.144870 0.818822 0.107102 11.00000 0.02489 0.03108 = 0.02260 0.00212 0.00604 0.00683 C74 1 0.180115 0.851004 0.081975 11.00000 0.03196 0.02897 = 0.02483 0.00238 0.00914 0.00498 C75 1 0.194268 0.891683 0.113640 11.00000 0.05915 0.03218 = 0.03248 -0.00015 0.01912 -0.00537 AFIX 137 H75A 2 0.143125 0.902906 0.116212 11.00000 -1.50000 H75B 2 0.219897 0.909636 0.090857 11.00000 -1.50000 H75C 2 0.228751 0.888283 0.153914 11.00000 -1.50000 AFIX 0 C76 1 0.200681 0.846979 0.026162 11.00000 0.02989 0.03946 = 0.02548 0.00641 0.01078 0.00029 AFIX 43 H76 2 0.224208 0.868736 0.010972 11.00000 -1.20000 AFIX 0 C77 1 0.186673 0.811098 -0.007110 11.00000 0.03021 0.04516 = 0.02209 0.00200 0.00689 0.01171 C78 1 0.209654 0.806823 -0.067021 11.00000 0.05231 0.05786 = 0.02935 -0.00050 0.01976 0.00972 AFIX 137 H78A 2 0.162395 0.799635 -0.098424 11.00000 -1.50000 H78B 2 0.250126 0.786091 -0.063509 11.00000 -1.50000 H78C 2 0.231040 0.832028 -0.077187 11.00000 -1.50000 AFIX 0 C79 1 0.150287 0.779750 0.016716 11.00000 0.03218 0.03500 = 0.02272 -0.00147 0.00512 0.01108 AFIX 43 H79 2 0.139283 0.755716 -0.005111 11.00000 -1.20000 AFIX 0 C80 1 0.129390 0.782924 0.072647 11.00000 0.02758 0.03294 = 0.01895 -0.00040 0.00621 0.00646 C81 1 0.087779 0.747794 0.094070 11.00000 0.04081 0.03272 = 0.02457 -0.00182 0.00763 0.00021 AFIX 137 H81A 2 0.116129 0.740908 0.135015 11.00000 -1.50000 H81B 2 0.087896 0.724983 0.067895 11.00000 -1.50000 H81C 2 0.032723 0.755041 0.092989 11.00000 -1.50000 AFIX 0 C82 1 -0.049012 0.970822 0.230559 11.00000 0.02556 0.02351 = 0.02294 0.00008 0.00200 -0.00057 C83 1 -0.102223 0.993150 0.256841 11.00000 0.02293 0.02457 = 0.02437 -0.00063 0.00327 0.00298 C84 1 -0.128061 0.976830 0.311278 11.00000 0.03347 0.03132 = 0.03317 -0.00040 0.01329 0.00799 AFIX 137 H84A 2 -0.164056 0.954297 0.298923 11.00000 -1.50000 H84B 2 -0.155594 0.997652 0.327825 11.00000 -1.50000 H84C 2 -0.080962 0.968161 0.341700 11.00000 -1.50000 AFIX 0 C85 1 -0.131680 1.030928 0.233289 11.00000 0.02514 0.02545 = 0.03552 -0.00381 0.00341 0.00222 AFIX 43 H85 2 -0.167373 1.044902 0.251010 11.00000 -1.20000 AFIX 0 C86 1 -0.108741 1.048156 0.183773 11.00000 0.02862 0.02259 = 0.03215 0.00494 -0.00457 -0.00245 C87 1 -0.145526 1.087540 0.156052 11.00000 0.04107 0.02714 = 0.04963 0.00829 -0.00311 0.00175 AFIX 137 H87A 2 -0.202773 1.083955 0.138920 11.00000 -1.50000 H87B 2 -0.120076 1.095656 0.124617 11.00000 -1.50000 H87C 2 -0.137093 1.108025 0.187012 11.00000 -1.50000 AFIX 0 C88 1 -0.052625 1.027251 0.160151 11.00000 0.03371 0.02853 = 0.02590 0.00330 -0.00027 -0.00819 AFIX 43 H88 2 -0.033944 1.038860 0.128846 11.00000 -1.20000 AFIX 0 C89 1 -0.023534 0.989195 0.182264 11.00000 0.02725 0.02585 = 0.02536 0.00166 0.00358 -0.00373 C90 1 0.035555 0.967273 0.153241 11.00000 0.04469 0.03257 = 0.03049 0.00395 0.01812 -0.00163 AFIX 137 H90A 2 0.006859 0.947224 0.125387 11.00000 -1.50000 H90B 2 0.076740 0.954380 0.184356 11.00000 -1.50000 H90C 2 0.060491 0.986332 0.131599 11.00000 -1.50000 AFIX 0 C91 1 0.144726 0.449221 0.110579 11.00000 0.03724 0.05510 = 0.05496 -0.01560 0.01194 -0.00721 AFIX 23 H91A 2 0.194807 0.454736 0.141096 11.00000 -1.20000 H91B 2 0.100247 0.450050 0.130286 11.00000 -1.20000 AFIX 0 C92 1 0.131786 0.481075 0.061190 11.00000 0.04327 0.04484 = 0.07833 -0.01227 0.01525 -0.00035 AFIX 23 H92A 2 0.080954 0.475573 0.031491 11.00000 -1.20000 H92B 2 0.126853 0.507276 0.079178 11.00000 -1.20000 AFIX 0 C93 1 0.470891 0.890633 0.024054 11.00000 0.07927 0.10156 = 0.12628 -0.02784 0.02277 0.01863 PART 1 AFIX 43 H93 2 0.425577 0.888053 -0.008699 21.00000 -1.20000 AFIX 43 PART 2 H93A 2 0.429325 0.875916 0.033925 -21.00000 -1.20000 AFIX 0 PART 1 C94 1 0.468959 0.912721 0.075819 21.00000 0.09354 0.11795 = 0.08872 -0.02354 0.02797 0.01946 AFIX 23 H94A 2 0.486881 0.895514 0.111304 21.00000 -1.20000 H94B 2 0.413273 0.920648 0.073401 21.00000 -1.20000 AFIX 0 PART 2 C94' 1 0.461087 0.930613 0.008736 -21.00000 0.09354 0.11795 = 0.08872 -0.02354 0.02797 0.01946 AFIX 23 H94C 2 0.447897 0.928982 -0.035369 -21.00000 -1.20000 H94D 2 0.409554 0.936280 0.018142 -21.00000 -1.20000 AFIX 0 PART 0 C95 1 0.544692 0.891553 0.235071 11.00000 0.11159 0.07268 = 0.12731 -0.01530 0.05265 -0.02544 AFIX 43 H95 2 0.550815 0.863909 0.230063 11.00000 -1.20000 AFIX 0 C96 1 0.611687 0.915943 0.252641 11.00000 0.10592 0.08954 = 0.08744 -0.02223 0.04601 -0.01769 AFIX 43 H96 2 0.663812 0.905127 0.260497 11.00000 -1.20000 AFIX 0 C97 1 0.599656 0.958407 0.258626 11.00000 0.12824 0.08810 = 0.09799 -0.04106 0.05044 -0.03987 AFIX 43 H97 2 0.644113 0.975752 0.268586 11.00000 -1.20000 AFIX 0 C98 1 0.522667 0.973402 0.249669 11.00000 0.09566 0.06292 = 0.09142 -0.01969 0.01258 -0.01249 AFIX 43 H98 2 0.515699 1.000996 0.254512 11.00000 -1.20000 AFIX 0 C99 1 0.455498 0.949132 0.233805 11.00000 0.11695 0.07492 = 0.08015 0.01089 0.05315 0.02409 C100 1 0.372430 0.964440 0.223861 11.00000 0.12945 0.13507 = 0.10007 0.00067 0.04825 -0.00609 AFIX 137 H10G 2 0.338993 0.952763 0.187343 11.00000 -1.50000 H10H 2 0.372596 0.993342 0.219826 11.00000 -1.50000 H10I 2 0.351182 0.957262 0.257887 11.00000 -1.50000 AFIX 0 C101 1 0.465101 0.908954 0.224467 11.00000 0.10773 0.08412 = 0.13073 -0.01106 0.05848 -0.02679 AFIX 43 H101 2 0.419545 0.892627 0.211067 11.00000 -1.20000 AFIX 0 HKLF 4 REM zwq_a.res in P2(1)/n REM R1 = 0.0406 for 20269 Fo > 4sig(Fo) and 0.0452 for all 21908 data REM 1326 parameters refined using 1 restraints END WGHT 0.0346 38.4392 REM Highest difference peak 0.988, deepest hole -0.930, 1-sigma level 0.091 Q1 1 0.5476 0.9569 0.1740 11.00000 0.05 0.99 Q2 1 0.1892 0.4906 0.0204 11.00000 0.05 0.88 Q3 1 0.1705 0.5630 -0.0626 11.00000 0.05 0.87 Q4 1 0.4122 0.9250 0.1590 11.00000 0.05 0.78 Q5 1 0.0026 0.8405 0.2288 11.00000 0.05 0.69 Q6 1 0.4805 0.9332 0.1381 11.00000 0.05 0.68 Q7 1 0.1136 0.8373 0.3572 11.00000 0.05 0.63 Q8 1 0.1235 0.8880 0.2778 11.00000 0.05 0.62 Q9 1 0.0163 0.8216 0.1864 11.00000 0.05 0.61 Q10 1 0.0007 0.8626 0.3220 11.00000 0.05 0.60 Q11 1 0.0581 0.9109 0.2965 11.00000 0.05 0.59 Q12 1 0.0257 0.7961 0.2935 11.00000 0.05 0.58 Q13 1 -0.0811 0.8312 0.2710 11.00000 0.05 0.56 Q14 1 0.1387 0.8286 0.3196 11.00000 0.05 0.54 Q15 1 0.1692 0.8600 0.2208 11.00000 0.05 0.54 Q16 1 -0.1876 0.8289 0.2277 11.00000 0.05 0.53 Q17 1 -0.1336 0.8503 0.2427 11.00000 0.05 0.53 Q18 1 -0.0174 0.8162 0.2494 11.00000 0.05 0.53 Q19 1 0.5597 0.9903 0.0983 11.00000 0.05 0.51 Q20 1 0.0935 0.8014 0.2834 11.00000 0.05 0.51 Q21 1 0.4757 0.9300 0.0244 11.00000 0.05 0.51 Q22 1 -0.1117 0.8458 0.3305 11.00000 0.05 0.50 Q23 1 0.5101 0.9416 0.0886 11.00000 0.05 0.50 Q24 1 -0.0288 0.8372 0.2786 11.00000 0.05 0.50 Q25 1 -0.0529 0.8819 0.2694 11.00000 0.05 0.50 Q26 1 0.0860 0.8202 0.4030 11.00000 0.05 0.49 Q27 1 0.0980 0.7486 0.2778 11.00000 0.05 0.48 Q28 1 0.1307 0.5671 -0.0086 11.00000 0.05 0.48 Q29 1 0.2331 0.8393 0.2523 11.00000 0.05 0.48 Q30 1 -0.0436 0.8300 0.3304 11.00000 0.05 0.48 Q31 1 0.1578 0.8136 0.2884 11.00000 0.05 0.48 Q32 1 0.0966 0.8899 0.3687 11.00000 0.05 0.47 Q33 1 0.1889 0.8241 0.2093 11.00000 0.05 0.47 Q34 1 0.0591 0.8539 0.1977 11.00000 0.05 0.47 Q35 1 0.0257 0.8779 0.2812 11.00000 0.05 0.46 Q36 1 0.1448 0.7894 0.3206 11.00000 0.05 0.46 Q37 1 0.1811 0.7908 0.3520 11.00000 0.05 0.46 Q38 1 0.2898 0.8111 0.3721 11.00000 0.05 0.46 Q39 1 -0.0443 0.7377 0.3118 11.00000 0.05 0.45 Q40 1 0.0122 0.8901 0.2153 11.00000 0.05 0.45 Q41 1 0.0738 0.7697 0.3278 11.00000 0.05 0.44 Q42 1 0.1985 0.4594 -0.0037 11.00000 0.05 0.44 Q43 1 -0.0685 0.8370 0.3705 11.00000 0.05 0.44 ; _shelx_res_checksum 3787 _shelx_hkl_file ; 0 0 -2 9999.00 408.15 0 0 -3 1.72 0.63 0 0 3 0.79 0.64 0 0 -4 3180.69 130.40 0 0 4 3194.52 130.61 0 0 -5 0.07 0.92 0 0 5 -0.05 0.97 0 0 -6 58.33 3.17 0 0 6 62.99 3.51 0 0 7 1.39 1.10 0 0 -7 0.05 1.08 0 0 -8 4.25 1.25 0 0 8 4.64 1.42 0 0 -9 0.46 1.28 0 0 -10 2899.15 119.44 0 0 -11 -0.86 1.55 0 0 -12 2954.76 122.03 0 0 -13 0.66 1.46 0 0 -14 38.81 3.33 0 0 -15 0.79 2.16 0 0 -15 0.52 1.70 0 0 15 1.53 2.68 0 0 -16 9.47 2.62 0 0 -16 10.36 2.17 0 0 16 10.39 3.69 0 0 -17 0.90 2.70 0 0 -17 2.33 2.16 0 0 17 1.62 3.23 0 0 -18 22.91 3.38 0 0 -18 20.71 2.78 0 0 18 18.51 4.42 0 0 -19 2.03 2.99 0 0 -19 0.82 2.43 0 0 19 0.76 3.71 0 0 -20 68.83 5.03 0 0 -20 61.10 4.57 0 0 -21 4.87 2.95 0 0 -21 -0.64 2.50 0 0 -22 168.80 8.41 0 0 -22 151.60 8.36 0 0 -22 174.53 9.18 0 0 -23 3.05 2.80 0 0 -23 3.53 3.93 0 0 -23 1.32 2.56 0 0 -24 184.03 8.71 0 0 -24 174.81 8.80 0 0 -24 187.36 9.35 0 0 -25 -1.24 2.04 0 0 -25 0.47 1.88 0 0 -25 1.37 2.43 0 0 -26 236.63 10.50 0 0 -26 242.52 10.67 0 0 -26 244.39 10.97 0 1 -2 647.44 26.54 0 1 -2 642.65 26.61 0 -1 2 668.22 26.61 0 -1 2 627.14 26.54 0 -1 3 1044.83 42.45 0 1 -3 1019.13 42.32 0 1 -4 2078.82 86.18 0 -1 4 2136.30 86.37 0 -1 5 25.31 1.91 0 -1 -5 25.72 1.75 0 1 -5 26.15 1.73 0 1 5 24.13 1.94 0 1 6 221.88 10.28 0 -1 6 230.92 10.22 0 1 -6 228.77 9.94 0 -1 -6 226.84 9.94 0 -1 7 1718.79 72.20 0 -1 -7 1753.24 71.82 0 1 7 1741.78 72.25 0 1 -7 1744.82 71.80 0 -1 8 6.44 1.46 0 1 -8 9.97 1.48 0 -1 -8 8.81 1.46 0 1 -9 29.91 2.39 0 -1 -9 30.72 2.38 0 -1 -10 79.31 4.34 0 1 -10 71.04 4.25 0 1 -11 98.86 5.32 0 -1 -11 94.25 5.24 0 -1 -12 41.97 3.27 0 1 -12 55.34 3.59 0 -1 -13 24.62 2.56 0 1 -13 19.27 2.43 0 1 -14 17.95 2.50 0 1 14 20.64 3.33 0 -1 -14 21.38 2.44 0 1 -15 46.27 3.47 0 -1 -15 43.75 3.42 0 1 15 46.19 4.93 0 1 -15 40.97 3.14 0 -1 -15 44.54 3.20 0 -1 -15 42.71 3.21 0 1 -16 310.34 14.23 0 -1 -16 313.15 14.22 0 1 16 356.99 17.21 0 -1 16 371.87 17.61 0 1 -16 323.69 14.17 0 -1 -16 323.70 14.23 0 -1 -16 286.28 13.95 0 -1 -17 241.66 11.24 0 1 -17 233.31 11.24 0 -1 -17 225.34 10.94 0 1 -17 235.98 11.09 0 -1 -17 235.04 11.16 0 -1 17 274.74 14.65 0 1 17 255.55 14.14 0 -1 -18 470.44 20.56 0 1 -18 460.73 20.55 0 -1 -18 461.46 20.50 0 1 -18 436.96 20.36 0 1 18 505.56 24.08 0 1 -19 11.91 3.35 0 -1 -19 12.09 3.19 0 1 -19 9.32 2.63 0 -1 -19 9.92 2.66 0 -1 19 9.04 4.45 0 1 19 9.91 4.19 0 1 -20 128.06 7.16 0 -1 -20 129.15 7.20 0 -1 -20 119.96 6.99 0 1 -20 128.50 6.98 0 1 -21 36.15 3.77 0 -1 -21 40.19 3.92 0 1 -21 30.53 3.44 0 -1 -21 35.34 3.57 0 1 -22 14.50 2.81 0 -1 -22 11.33 2.93 0 -1 -22 9.03 2.74 0 1 -22 4.98 2.51 0 -1 -22 5.00 3.52 0 -1 -23 2.22 2.70 0 1 -23 2.10 2.56 0 -1 -23 3.75 3.18 0 1 -23 4.19 2.32 0 -1 -23 5.89 2.53 0 -1 -24 186.09 8.89 0 1 -24 187.72 8.83 0 1 -24 184.33 8.93 0 -1 -24 184.06 9.05 0 -1 -24 186.74 9.45 0 1 -25 24.29 2.49 0 -1 -25 20.69 2.58 0 -1 -25 24.04 3.03 0 -1 -25 24.12 2.61 0 1 -25 24.55 2.51 0 -1 -26 44.74 2.92 0 1 -26 45.96 2.85 0 -1 -26 53.84 3.11 0 1 -26 44.00 2.94 0 -1 -26 48.31 3.40 0 -2 2 4724.80 202.92 0 2 -2 4974.13 202.93 0 2 2 5079.68 203.00 0 -2 2 4988.12 202.93 0 -2 -2 5068.22 202.86 0 -2 3 1209.38 49.24 0 2 -3 1185.69 49.18 0 2 -4 210.22 9.04 0 -2 4 208.39 9.15 0 -2 5 15.16 1.49 0 2 -5 15.26 1.42 0 2 -6 11.67 1.35 0 -2 6 11.88 1.45 0 -2 7 136.98 6.75 0 2 -7 134.98 6.42 0 -2 -7 139.86 6.46 0 -2 -8 34.38 2.37 0 -2 8 30.88 1.63 0 -2 8 36.42 2.72 0 2 -8 33.65 2.40 0 -2 -9 216.82 9.78 0 2 -9 214.67 9.78 0 -2 9 206.69 10.20 0 2 -10 746.62 31.37 0 -2 -10 732.22 31.33 0 -2 -11 216.81 10.35 0 2 -11 227.41 10.44 0 -2 -12 484.08 21.57 0 2 -12 502.80 21.65 0 -2 -13 1146.03 49.13 0 2 -13 1186.12 49.22 0 2 13 1160.29 50.29 0 -2 -14 291.14 13.44 0 2 -14 281.70 13.48 0 2 14 282.19 14.63 0 2 -15 60.25 4.06 0 -2 -15 57.70 3.93 0 2 15 61.46 5.58 0 -2 -15 68.19 4.00 0 2 -15 62.82 3.80 0 2 -15 56.82 3.89 0 -2 -15 56.87 3.79 0 -2 -16 7.70 2.54 0 2 -16 6.70 2.61 0 -2 16 3.10 3.16 0 2 16 6.79 3.19 0 -2 -16 5.67 2.17 0 2 -16 8.20 1.97 0 2 -16 13.43 2.56 0 -2 -16 8.04 2.25 0 -2 -17 311.02 14.10 0 2 -17 313.30 14.16 0 2 17 316.30 16.84 0 -2 -17 305.06 14.09 0 2 -17 304.05 13.95 0 2 -17 296.51 13.95 0 2 -18 13.52 3.17 0 -2 -18 13.13 3.15 0 2 18 14.88 4.19 0 -2 18 9.82 4.41 0 -2 -18 14.94 2.73 0 2 -18 14.35 2.55 0 2 -18 10.73 3.07 0 -2 -19 719.75 30.64 0 2 -19 726.16 30.64 0 -2 -19 692.56 30.66 0 2 -19 679.53 30.49 0 -2 19 812.06 35.32 0 2 19 726.12 34.06 0 2 -20 8.79 3.05 0 -2 -20 11.01 3.16 0 2 -20 12.61 2.68 0 -2 -20 8.70 2.76 0 -2 -21 145.46 7.56 0 2 -21 138.62 7.43 0 -2 -21 135.65 7.52 0 2 -21 128.42 7.27 0 2 -22 14.75 2.87 0 -2 -22 13.02 2.96 0 2 -22 10.60 2.66 0 -2 -22 9.06 3.55 0 -2 -22 9.84 2.83 0 2 -23 20.38 2.88 0 -2 -23 21.97 3.19 0 2 -23 21.37 2.80 0 -2 -23 21.23 3.69 0 -2 -23 19.99 3.03 0 2 -24 292.01 13.13 0 -2 -24 308.34 13.32 0 2 -24 291.81 13.28 0 -2 -24 281.28 13.45 0 -2 -24 306.25 13.86 0 -2 -25 14.91 2.40 0 2 -25 15.91 2.20 0 -2 -25 18.13 2.43 0 2 -25 21.83 2.26 0 -2 -25 18.63 2.84 0 -2 -26 224.54 9.74 0 2 -26 220.00 9.57 0 2 -26 208.48 9.70 0 -2 -26 218.52 9.90 0 -2 -26 231.84 10.12 0 3 0 0.24 0.50 0 -3 0 0.34 0.54 0 -3 -1 474.10 18.72 0 -3 -1 431.82 18.65 0 3 1 469.31 18.66 0 -3 1 427.30 18.64 0 3 2 169.68 7.04 0 3 -2 156.42 6.94 0 -3 -2 159.19 6.95 0 -3 -3 2430.74 96.90 0 3 3 2385.98 97.29 0 3 -3 2282.08 97.16 0 -3 3 2276.40 97.17 0 -3 4 395.04 17.07 0 3 4 410.20 17.18 0 3 -4 408.59 17.04 0 -3 5 48.58 2.66 0 3 -5 41.45 2.54 0 -3 6 321.70 14.33 0 3 -6 334.87 14.15 0 3 -7 636.04 27.05 0 -3 7 653.26 27.38 0 -3 8 6.23 0.93 0 3 -8 7.63 1.42 0 -3 8 7.21 1.41 0 -3 -8 6.57 1.41 0 -3 -9 443.51 17.85 0 3 -9 436.89 17.86 0 -3 9 390.72 16.98 0 -3 9 440.10 18.35 0 -3 -10 211.63 9.82 0 3 -10 211.38 9.85 0 -3 10 207.66 10.34 0 3 11 551.14 25.19 0 3 -11 572.65 24.52 0 -3 -11 570.72 24.47 0 -3 -12 79.25 4.85 0 3 12 81.77 5.67 0 3 -12 88.16 5.00 0 3 -13 42.46 3.31 0 -3 -13 42.60 3.29 0 3 13 38.26 3.94 0 -3 -14 217.17 10.63 0 3 14 213.23 11.77 0 3 -14 220.68 10.77 0 -3 -15 8.01 2.23 0 3 -15 10.75 2.46 0 3 15 8.96 2.79 0 3 -15 9.41 1.90 0 -3 -15 10.54 2.07 0 -3 -15 9.81 2.12 0 3 -15 8.76 2.30 0 -3 -16 108.92 6.08 0 3 -16 121.44 6.27 0 3 16 110.53 8.02 0 3 16 108.18 7.25 0 -3 -16 116.51 6.16 0 -3 -16 108.64 5.90 0 3 -16 114.62 5.89 0 3 -16 109.26 6.08 0 3 -17 613.55 25.95 0 -3 -17 586.28 25.85 0 -3 17 662.24 30.02 0 3 17 591.10 28.62 0 -3 -17 627.12 26.07 0 3 -17 594.38 25.80 0 3 -17 574.98 25.81 0 3 -18 225.33 10.70 0 -3 -18 217.82 10.63 0 3 -18 215.50 10.41 0 -3 -18 226.98 10.77 0 3 -18 204.60 10.57 0 3 18 210.05 13.03 0 -3 -19 559.26 24.44 0 3 -19 571.39 24.40 0 3 -19 520.42 24.22 0 -3 -19 565.03 24.54 0 3 19 585.02 27.73 0 -3 19 626.41 29.00 0 -3 -20 27.39 3.65 0 3 -20 23.32 3.39 0 -3 -20 25.01 3.36 0 3 -20 18.71 2.91 0 3 -21 117.00 6.39 0 -3 -21 114.50 6.54 0 3 -21 115.71 7.19 0 -3 -21 102.07 6.51 0 3 -21 108.56 6.22 0 3 -22 44.98 3.78 0 -3 -22 53.49 4.24 0 3 -22 44.70 4.53 0 -3 -22 50.08 4.71 0 -3 -22 44.07 3.98 0 3 -22 45.69 3.70 0 -3 -23 1.17 2.80 0 3 -23 0.07 2.40 0 3 -23 -0.12 3.19 0 3 -23 2.09 2.08 0 -3 -23 0.58 3.19 0 -3 -23 -1.70 2.74 0 3 -24 5.22 2.15 0 -3 -24 4.48 2.48 0 3 -24 7.61 2.07 0 -3 -24 1.92 2.33 0 3 -24 6.35 3.02 0 -3 -24 8.80 2.89 0 3 -25 53.98 3.30 0 -3 -25 53.63 3.57 0 3 -25 50.84 3.35 0 3 -25 59.14 4.12 0 -3 -25 56.14 3.99 0 -3 -25 53.07 3.71 0 -3 -26 0.86 1.72 0 -3 -26 3.36 1.68 0 3 -26 2.42 2.10 0 -3 -26 3.33 2.00 0 3 -26 0.29 1.43 0 4 0 5249.11 214.63 0 4 1 3698.53 148.57 0 4 1 3599.57 148.47 0 -4 -1 3553.54 148.51 0 -4 1 3658.35 148.38 0 -4 -2 2.30 1.14 0 4 -2 1.93 0.95 0 4 -3 6.29 1.20 0 -4 3 7.50 1.10 0 4 3 7.83 1.31 0 -4 -3 7.83 1.25 0 4 -4 16.74 1.53 0 -4 4 17.07 1.49 0 4 4 18.38 1.67 0 -4 -4 19.29 1.02 0 -4 5 883.58 36.78 0 4 -5 882.84 36.69 0 4 -6 836.13 34.33 0 -4 6 806.60 34.44 0 4 7 17.58 1.98 0 4 -7 18.61 1.81 0 -4 7 16.56 1.74 0 4 -8 142.80 6.66 0 -4 8 130.09 6.17 0 4 8 140.86 6.99 0 -4 8 143.65 6.92 0 -4 9 2118.93 86.60 0 -4 9 2002.30 85.46 0 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5.78 0 4 19 42.67 5.43 0 -4 -20 152.60 8.18 0 4 -20 162.94 8.06 0 4 -20 140.53 7.84 0 -4 -20 164.99 8.40 0 4 -21 20.94 3.14 0 -4 -21 23.85 3.41 0 -4 -21 20.46 3.83 0 4 -21 19.06 2.77 0 -4 -21 16.08 3.14 0 4 -21 21.08 3.86 0 4 -22 23.61 3.03 0 -4 -22 29.78 3.44 0 4 -22 22.14 2.79 0 -4 -22 26.72 3.86 0 -4 -22 21.81 3.36 0 4 -22 20.23 3.77 0 4 -23 102.84 5.70 0 -4 -23 116.79 6.17 0 4 -23 116.25 6.68 0 -4 -23 103.45 6.25 0 -4 -23 107.07 6.57 0 4 -23 103.34 5.73 0 4 -24 288.25 13.05 0 -4 -24 323.97 13.46 0 -4 -24 291.95 13.58 0 4 -24 314.65 13.88 0 -4 -24 303.74 13.79 0 4 -24 277.98 13.17 0 -4 -25 166.17 7.55 0 4 -25 153.68 7.17 0 -4 -25 177.77 7.96 0 4 -25 168.02 7.99 0 -4 -25 153.49 7.67 0 4 -25 141.13 7.28 0 -4 -26 162.84 7.53 0 4 -26 169.67 7.92 0 -4 -26 161.59 7.77 0 -4 -26 164.66 7.68 0 5 0 0.24 1.13 0 -5 -1 1318.68 55.36 0 5 1 1372.37 55.40 0 5 1 1334.72 55.31 0 5 -2 133.08 6.15 0 -5 -2 137.10 6.28 0 5 -3 1874.10 79.61 0 -5 -3 2002.82 79.64 0 5 -4 532.59 22.59 0 -5 -4 535.77 22.20 0 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6.44 0 5 -17 107.60 6.04 0 5 -17 112.05 6.51 0 -5 -18 730.21 32.42 0 5 -18 780.06 32.45 0 5 18 737.32 35.15 0 -5 18 865.16 37.27 0 5 -18 730.08 32.36 0 -5 -18 806.67 32.84 0 5 -18 754.83 32.56 0 5 -19 946.68 39.08 0 -5 -19 909.91 39.15 0 -5 -19 941.98 39.48 0 5 -19 886.81 39.03 0 -5 19 1050.92 44.16 0 5 19 876.42 41.95 0 5 -20 99.75 5.85 0 5 -20 90.84 5.68 0 -5 -20 101.87 6.28 0 -5 -21 16.03 3.17 0 5 -21 9.76 2.65 0 5 -21 11.00 3.52 0 -5 -21 15.92 3.58 0 -5 -21 11.13 2.98 0 5 -21 12.63 2.46 0 5 -22 8.31 2.45 0 -5 -22 12.75 2.92 0 5 -22 3.35 3.18 0 5 -22 8.94 2.25 0 -5 -22 10.85 3.30 0 -5 -22 5.51 2.81 0 5 -23 103.87 5.69 0 -5 -23 118.77 6.26 0 5 -23 108.11 5.77 0 -5 -23 101.32 6.29 0 5 -23 119.10 6.69 0 -5 -23 116.68 6.64 0 -5 -24 8.93 2.61 0 5 -24 8.30 2.02 0 -5 -24 5.78 2.55 0 -5 -24 7.57 2.71 0 5 -24 8.69 2.90 0 5 -24 9.20 1.92 0 -5 -25 22.46 2.62 0 -5 -25 22.84 2.66 0 -5 -25 26.10 2.91 0 5 -25 22.92 2.98 0 -5 -26 -1.44 1.75 0 -5 -26 -1.61 1.65 0 5 -26 0.58 2.02 0 -5 -26 -0.34 1.75 0 6 0 991.31 41.20 0 6 1 21.81 2.08 0 6 1 24.51 2.17 0 6 2 299.83 13.23 0 6 -2 294.17 13.03 0 -6 -2 317.73 13.21 0 -6 -3 150.31 6.81 0 6 -3 143.33 6.69 0 -6 4 449.43 19.24 0 -6 -4 456.99 19.34 0 6 -4 445.52 19.39 0 6 4 481.07 19.56 0 -6 5 77.61 4.06 0 6 -5 76.28 4.15 0 -6 -5 82.47 3.60 0 6 -6 788.29 33.40 0 -6 6 805.12 33.45 0 -6 7 902.54 37.05 0 -6 7 833.18 36.71 0 6 7 895.47 37.19 0 6 -7 907.62 36.94 0 6 8 277.94 12.44 0 -6 8 264.36 12.21 0 6 -8 278.04 12.08 0 -6 8 255.88 11.74 0 6 -9 634.74 26.29 0 -6 9 581.87 25.76 0 6 9 635.97 26.73 0 -6 9 630.12 26.60 0 -6 10 312.74 14.53 0 6 -10 311.28 14.11 0 6 10 311.67 14.61 0 6 -11 2.14 1.60 0 6 11 3.16 1.90 0 -6 -11 2.81 1.62 0 6 12 1047.98 46.20 0 -6 -12 1078.37 45.48 0 6 -12 1087.61 45.55 0 6 13 6.59 2.22 0 6 -13 10.10 2.16 0 -6 -13 5.67 1.87 0 6 14 238.25 13.23 0 -6 -14 277.50 12.76 0 6 -14 268.48 12.79 0 6 14 268.33 13.69 0 6 15 89.03 6.24 0 6 15 83.51 6.48 0 6 -15 89.49 4.69 0 6 -15 82.38 5.09 0 6 -16 33.12 3.05 0 6 16 22.43 3.88 0 6 16 26.96 4.07 0 -6 -16 40.17 3.37 0 6 -16 32.58 2.68 0 6 -16 30.29 3.39 0 6 -17 16.47 2.79 0 6 17 11.81 3.55 0 6 17 11.36 3.42 0 6 -17 15.25 2.40 0 -6 -17 17.12 2.97 0 6 -17 12.02 3.11 0 6 -18 23.99 3.09 0 -6 -18 21.53 3.18 0 6 18 22.01 4.29 0 -6 18 21.93 4.93 0 6 -18 14.95 2.56 0 -6 -18 23.17 3.30 0 6 -18 21.94 3.65 0 -6 -19 5.05 2.82 0 6 -19 1.90 2.56 0 -6 -19 3.96 2.81 0 6 -19 4.94 2.19 0 -6 19 6.86 4.17 0 6 19 0.91 3.09 0 6 -20 21.45 3.00 0 -6 -20 22.50 3.56 0 6 -20 13.93 2.55 0 -6 -20 19.28 3.59 0 6 -20 15.28 3.67 0 -6 -21 157.88 8.05 0 6 -21 154.97 7.64 0 -6 -21 163.96 8.54 0 6 -21 133.57 7.56 0 -6 -21 160.43 8.34 0 6 -21 160.14 8.59 0 -6 -22 5.49 2.70 0 6 -22 2.44 2.17 0 -6 -22 1.66 2.73 0 6 -22 5.01 2.04 0 6 -22 2.88 3.01 0 -6 -22 3.50 3.02 0 -6 -23 18.16 2.96 0 6 -23 14.15 2.28 0 6 -23 14.14 2.16 0 -6 -23 17.88 3.12 0 6 -23 21.20 3.27 0 -6 -24 40.51 3.41 0 6 -24 40.17 3.72 0 -6 -24 42.64 3.61 0 6 -24 36.28 2.73 0 -6 -24 35.01 3.40 0 -6 -25 224.65 9.70 0 -6 -25 211.21 9.83 0 -6 -25 190.34 9.73 0 6 -25 218.62 10.00 0 -6 -26 -1.25 1.78 0 -6 -26 2.56 1.71 0 6 -26 -0.43 1.99 0 -6 -26 3.07 1.70 0 7 0 0.84 1.43 0 7 1 297.97 13.20 0 7 1 304.65 13.22 0 7 -2 13.84 1.74 0 7 2 13.37 1.81 0 7 -3 420.58 18.45 0 -7 -3 447.95 18.59 0 7 -4 2665.75 112.90 0 -7 -4 2801.69 112.95 0 -7 4 2770.83 112.74 0 -7 5 5.84 1.28 0 7 -5 6.15 1.44 0 -7 -5 7.38 0.88 0 7 6 1921.01 78.15 0 -7 6 1858.63 77.87 0 7 -6 1885.81 77.94 0 -7 7 1083.75 44.97 0 -7 7 1055.04 44.80 0 7 -7 1069.61 44.91 0 7 7 1095.57 45.20 0 7 8 4.39 1.70 0 7 -8 5.53 1.69 0 -7 8 2.46 1.38 0 -7 8 4.41 1.49 0 7 9 1257.31 51.54 0 7 -9 1256.50 51.13 0 -7 9 1242.92 51.35 0 -7 9 1163.99 50.67 0 -7 10 8.72 1.39 0 -7 10 11.74 2.13 0 7 10 11.73 2.17 0 7 -10 12.38 2.02 0 7 -11 2.25 1.67 0 7 11 2.34 1.84 0 7 12 70.87 5.21 0 7 -12 76.23 4.79 0 -7 -12 73.69 4.71 0 7 -13 15.41 2.44 0 7 13 11.64 2.61 0 -7 -13 14.51 2.25 0 7 -14 4.84 2.11 0 -7 -14 3.66 1.88 0 7 14 4.22 2.43 0 7 14 3.70 2.42 0 -7 -14 3.09 1.76 0 7 15 382.39 18.63 0 7 15 360.21 18.22 0 7 -15 384.86 16.37 0 7 -15 367.41 16.62 0 7 -16 502.68 20.94 0 7 16 445.98 22.82 0 7 16 465.04 23.17 0 7 -16 477.92 20.88 0 7 -16 494.72 21.20 0 7 -17 829.42 33.79 0 7 17 772.20 36.28 0 7 17 724.87 35.78 0 7 -17 793.01 33.76 0 7 -17 809.42 34.05 0 7 -18 567.49 24.31 0 7 -18 534.01 24.27 0 7 -18 604.66 24.75 0 7 -19 113.36 6.23 0 -7 -19 127.08 6.92 0 7 -19 114.30 6.18 0 -7 19 111.57 9.63 0 -7 -20 835.81 35.91 0 7 -20 863.19 35.63 0 7 -20 782.15 35.65 0 7 -20 869.59 36.45 0 -7 -20 901.14 36.41 0 7 -21 1.02 2.19 0 -7 -21 5.00 2.76 0 7 -21 2.55 2.04 0 7 -21 4.54 3.05 0 -7 -21 -1.07 2.92 0 -7 -21 0.12 2.87 0 -7 -22 49.14 4.13 0 7 -22 47.33 3.41 0 -7 -22 50.42 4.29 0 7 -22 57.75 4.52 0 -7 -22 50.47 4.26 0 -7 -23 67.79 4.24 0 -7 -23 49.52 4.20 0 7 -23 58.22 4.35 0 7 -23 44.46 3.33 0 -7 -23 60.95 4.34 0 -7 -24 29.06 3.02 0 -7 -24 24.34 3.08 0 7 -24 31.20 3.26 0 -7 -24 28.27 3.03 0 -7 -25 17.08 2.40 0 -7 -25 22.22 2.51 0 7 -25 22.68 2.74 0 -7 -25 20.07 2.47 0 -7 -26 11.66 1.89 0 -7 -26 8.05 1.80 0 7 -26 12.12 2.09 0 -7 -26 9.86 1.78 0 8 0 830.38 34.88 0 8 1 191.26 8.97 0 8 1 197.60 9.02 0 8 2 36.56 2.74 0 8 -2 36.91 2.59 0 8 2 32.46 2.68 0 8 3 108.71 5.58 0 8 -3 106.05 5.36 0 8 -4 2453.53 102.45 0 -8 4 2513.52 102.21 0 -8 -5 5.27 0.95 0 -8 5 5.45 1.20 0 8 -5 4.56 1.42 0 -8 6 104.23 5.40 0 -8 6 102.31 5.56 0 -8 -6 112.35 4.86 0 8 -6 108.46 5.58 0 -8 7 60.75 3.60 0 8 7 57.63 3.85 0 -8 7 55.53 3.59 0 8 -7 59.70 3.70 0 -8 8 471.16 20.46 0 8 8 470.15 20.71 0 -8 8 457.42 20.21 0 8 -8 478.14 20.47 0 8 -9 2512.51 101.37 0 -8 9 2440.88 101.46 0 8 9 2521.42 101.74 0 -8 9 2367.28 100.96 0 -8 10 176.27 9.15 0 -8 10 172.36 8.42 0 8 -10 192.99 9.05 0 8 10 192.54 9.45 0 8 -11 1194.44 50.11 0 8 11 1172.23 50.58 0 -8 11 1187.08 50.47 0 8 12 52.26 4.43 0 -8 -12 56.96 3.95 0 8 -12 51.34 4.01 0 -8 -13 166.09 8.31 0 8 13 137.89 8.60 0 8 -13 156.39 8.29 0 8 13 152.14 8.89 0 -8 -14 22.56 2.82 0 8 -14 26.12 3.12 0 8 14 28.29 3.59 0 8 14 23.02 3.49 0 -8 -14 26.82 2.47 0 8 -14 25.43 2.86 0 -8 -15 59.13 3.89 0 8 15 57.41 5.27 0 8 15 60.15 5.42 0 8 -15 61.71 3.67 0 8 -15 64.36 4.38 0 -8 -16 12.93 2.43 0 8 16 8.37 3.32 0 8 16 10.00 3.24 0 8 -16 10.99 1.96 0 8 -16 9.61 2.81 0 8 17 0.74 3.22 0 8 -17 -0.30 1.82 0 8 -17 1.65 2.99 0 8 -18 6.87 2.11 0 8 -18 4.52 3.19 0 8 -19 33.36 3.86 0 8 -19 28.97 2.86 0 8 -20 249.17 11.87 0 8 -20 283.95 12.83 0 -8 -21 71.35 4.96 0 8 -21 60.00 3.96 0 -8 -21 62.01 4.91 0 8 -21 70.86 5.02 0 -8 -22 339.00 16.63 0 -8 -22 384.45 16.71 0 8 -22 376.59 16.76 0 -8 -23 9.17 2.73 0 8 -23 8.32 2.71 0 -8 -23 7.65 2.73 0 -8 -23 7.09 2.64 0 -8 -24 10.96 2.49 0 -8 -24 8.30 2.42 0 8 -24 9.18 2.54 0 -8 -24 3.78 2.44 0 -8 -25 11.26 2.21 0 -8 -25 12.75 2.14 0 8 -25 11.78 2.38 0 -8 -25 9.90 2.12 0 -8 -26 3.40 1.67 0 -8 -26 2.75 1.53 0 9 0 1.68 1.79 0 9 1 379.58 16.47 0 9 1 369.46 16.42 0 9 -2 74.31 4.13 0 9 2 73.35 4.26 0 9 2 76.50 4.34 0 9 3 1539.05 64.77 0 -9 3 1590.20 64.72 0 9 -3 1543.60 64.57 0 -9 4 95.23 5.25 0 9 -4 99.30 5.14 0 -9 4 98.90 4.78 0 -9 5 322.23 14.14 0 9 -5 324.11 14.42 0 -9 5 332.03 14.54 0 -9 6 2620.49 107.53 0 9 -6 2607.92 107.74 0 -9 -6 2618.81 107.06 0 -9 6 2587.21 107.77 0 9 -7 801.42 33.90 0 -9 7 805.09 33.76 0 -9 7 789.94 33.83 0 -9 8 3182.33 130.58 0 -9 8 3102.63 130.45 0 9 -8 3228.82 130.66 0 9 -9 74.64 4.73 0 9 9 80.82 5.00 0 -9 9 77.31 4.50 0 -9 9 78.87 4.75 0 9 10 47.74 3.92 0 -9 10 48.26 3.26 0 -9 10 45.57 3.67 0 9 11 20.74 2.72 0 -9 11 12.10 2.28 0 9 -11 16.38 2.38 0 9 11 18.46 2.69 0 9 12 -0.17 1.99 0 9 12 0.35 1.99 0 9 -12 2.87 1.80 0 9 13 34.51 3.82 0 9 -13 38.46 3.51 0 9 13 37.20 3.85 0 -9 -13 35.10 3.31 0 -9 -14 170.99 8.82 0 9 14 160.40 9.46 0 9 -14 174.33 8.94 0 9 14 158.88 9.44 0 -9 -14 160.66 7.67 0 9 -14 156.02 7.95 0 9 15 803.01 36.59 0 -9 -15 799.82 34.39 0 9 -15 846.87 34.71 0 -9 -16 901.08 39.84 0 9 16 870.34 41.99 0 9 -16 974.09 40.18 0 -9 -17 520.03 23.56 0 9 17 472.43 25.49 0 -9 -17 579.94 24.27 0 9 -17 597.07 23.98 0 -9 -18 33.58 3.58 0 9 -18 39.04 4.08 0 9 -19 1392.31 58.61 0 -9 -20 487.38 21.52 0 9 -20 481.72 21.61 0 9 -21 215.08 10.71 0 -9 -21 216.29 10.59 0 -9 -22 50.01 4.06 0 9 -22 55.53 4.33 0 -9 -23 2.31 2.63 0 9 -23 7.24 2.55 0 -9 -23 5.13 2.42 0 9 -24 108.89 5.88 0 -9 -24 99.45 5.82 0 -9 -24 109.57 5.70 0 -9 -25 17.49 2.39 0 -9 -25 16.24 2.27 0 9 -25 13.39 2.31 0 -9 -25 19.95 2.16 0 -9 -26 0.12 1.57 0 -9 -26 1.61 1.47 0 10 1 249.88 11.69 0 10 1 258.99 11.67 0 10 2 2192.00 88.83 0 -10 -2 2162.99 88.71 0 10 -2 2067.19 88.62 0 10 2 2167.56 88.76 0 10 3 4.67 1.59 0 10 -3 7.65 1.79 0 -10 -3 6.64 1.72 0 -10 3 5.14 1.74 0 10 -4 469.69 20.38 0 -10 4 485.56 20.55 0 10 4 440.93 20.56 0 -10 -4 480.23 20.42 0 -10 5 43.28 2.66 0 -10 -5 41.98 3.13 0 -10 5 39.23 3.16 0 10 -5 39.55 3.02 0 -10 -6 232.19 10.50 0 -10 6 245.36 11.30 0 -10 6 256.83 10.95 0 10 -6 242.08 11.22 0 -10 7 309.67 14.81 0 10 7 313.48 15.18 0 -10 -7 340.14 13.97 0 10 -7 320.06 14.86 0 -10 7 342.38 14.67 0 -10 8 1301.07 53.80 0 -10 8 1275.74 53.83 0 10 8 1264.30 54.41 0 10 -8 1295.23 53.97 0 -10 9 353.39 15.90 0 10 9 331.39 16.33 0 10 -9 361.78 16.01 0 -10 9 353.33 15.73 0 10 -10 785.65 31.82 0 -10 10 709.17 31.26 0 -10 10 750.11 31.77 0 10 10 695.62 32.17 0 10 11 4.25 2.16 0 10 -11 6.33 2.06 0 10 12 304.62 15.34 0 10 -12 317.12 14.79 0 10 -13 6.12 2.22 0 -10 -13 9.45 2.25 0 10 13 4.21 2.28 0 10 14 8.43 2.78 0 10 -14 5.79 2.35 0 -10 -14 4.95 1.93 0 10 -14 6.12 2.46 0 10 15 20.40 3.63 0 -10 -15 23.19 2.58 0 10 -15 22.14 3.09 0 -10 -16 49.40 3.77 0 10 16 46.29 5.15 0 -10 -16 63.10 4.35 0 10 -16 60.44 4.38 0 -10 -17 78.92 5.02 0 10 17 69.03 6.67 0 -10 -17 90.90 5.56 0 10 -17 95.53 5.58 0 -10 -18 17.34 2.88 0 -10 -18 16.02 3.08 0 10 -18 15.78 3.03 0 10 -18 17.33 3.34 0 -10 -19 7.58 2.80 0 -10 -19 8.81 2.97 0 10 -19 8.40 2.91 0 -10 -20 22.52 3.20 0 10 -20 22.89 3.33 0 -10 -20 23.94 3.19 0 -10 -21 181.32 8.70 0 -10 -21 164.36 8.67 0 10 -21 172.78 8.91 0 10 -22 87.30 5.48 0 -10 -22 87.24 5.26 0 -10 -23 265.30 12.01 0 10 -23 256.68 12.10 0 -10 -24 11.78 2.14 0 10 -24 9.73 2.40 0 -10 -25 4.77 1.65 0 10 -25 6.05 1.98 0 -10 -25 4.02 1.91 0 -10 -26 45.00 2.83 0 11 1 310.24 13.94 0 11 1 302.92 13.85 0 11 -2 243.09 11.46 0 11 2 249.00 11.62 0 -11 2 257.05 11.67 0 11 2 256.10 11.66 0 -11 -2 248.38 11.54 0 11 3 220.48 10.70 0 -11 -3 234.23 10.66 0 11 -3 223.15 10.55 0 -11 3 230.84 10.74 0 -11 -4 150.36 7.38 0 11 4 145.37 7.50 0 11 -4 142.88 7.34 0 -11 4 141.88 7.44 0 -11 5 2842.90 114.54 0 11 5 2522.38 114.57 0 11 -5 2743.09 114.39 0 -11 -5 2829.54 114.45 0 -11 5 2849.76 113.92 0 -11 6 482.91 20.45 0 -11 6 479.84 20.98 0 11 -6 466.19 20.86 0 -11 -6 474.99 20.21 0 -11 -7 3828.94 155.58 0 -11 7 3777.89 156.45 0 -11 7 3765.16 156.10 0 11 -7 3786.31 156.48 0 -11 8 744.46 31.56 0 11 -8 750.82 31.89 0 -11 8 748.59 31.78 0 11 8 713.31 32.27 0 -11 9 1686.85 68.38 0 11 -9 1680.42 68.60 0 11 9 1545.12 68.98 0 -11 9 1617.00 68.30 0 11 -10 75.39 4.95 0 -11 10 79.08 4.88 0 -11 10 77.11 4.64 0 11 10 75.49 5.39 0 11 -11 374.75 17.05 0 11 11 358.15 17.51 0 11 -12 18.20 2.75 0 11 12 15.52 2.86 0 11 -13 16.66 2.83 0 11 13 16.11 3.12 0 -11 -13 14.17 2.66 0 -11 -13 16.15 2.20 0 -11 -14 4.42 1.91 0 11 -14 2.03 2.41 0 11 14 2.24 2.54 0 -11 -14 1.01 1.59 0 11 -14 3.44 2.41 0 -11 -15 22.44 2.65 0 11 15 25.20 3.91 0 -11 -15 32.94 2.48 0 11 -15 23.98 3.16 0 -11 -16 560.43 25.34 0 11 16 536.92 27.53 0 -11 -16 634.22 26.04 0 11 -16 632.03 25.73 0 -11 -17 156.23 8.18 0 -11 -17 172.58 8.84 0 11 -17 179.86 8.70 0 -11 -18 26.37 3.07 0 11 -18 19.10 3.10 0 -11 -18 26.34 3.43 0 11 -18 25.97 3.53 0 -11 -19 433.65 19.33 0 -11 -19 459.15 19.95 0 11 -19 432.46 19.64 0 -11 -20 3.00 2.64 0 11 -20 6.96 2.70 0 -11 -20 3.66 2.99 0 -11 -20 4.30 2.42 0 -11 -21 802.10 32.58 0 -11 -21 763.43 33.00 0 -11 -21 741.23 32.60 0 11 -21 753.13 32.78 0 -11 -22 9.43 2.70 0 11 -22 9.95 2.63 0 -11 -22 10.59 2.40 0 -11 -23 1.74 2.37 0 -11 -23 5.16 2.01 0 11 -23 7.61 2.36 0 11 -24 -1.13 2.03 0 -11 -24 3.37 1.75 0 -12 -1 35.89 2.93 0 12 1 42.57 3.21 0 12 1 34.84 3.04 0 12 -2 386.37 17.95 0 -12 2 417.22 18.11 0 12 2 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6.71 2.15 -1 -13 6 4.21 2.13 1 -13 -6 5.21 1.95 -1 -13 5 64.20 3.11 -1 13 5 59.18 4.45 1 13 -5 69.42 4.49 1 -13 -5 63.17 3.95 -1 -13 5 66.20 4.54 1 -13 -5 67.73 4.32 1 -13 -4 2355.76 91.59 -1 13 4 2368.68 92.12 -1 -13 4 2098.93 90.29 1 13 -4 2372.50 91.75 -1 -13 4 2460.47 91.89 -1 -13 3 99.46 5.53 -1 13 3 99.29 5.65 1 -13 -3 88.61 5.19 -1 -13 3 88.25 3.99 1 -13 -2 1566.85 67.02 -1 -13 2 1653.77 67.27 1 -13 -1 173.63 8.63 1 13 -1 175.85 8.68 1 13 0 1985.03 79.92 1 13 0 1860.53 79.81 1 13 1 1948.63 81.06 1 13 1 1988.87 81.10 -1 13 -1 1911.46 81.05 -1 -13 -1 1947.66 81.13 -1 -13 -2 1632.98 68.92 1 13 2 1624.73 68.87 1 13 2 1686.27 68.90 -1 13 -2 1652.38 68.83 1 13 3 282.08 13.38 -1 13 -3 292.18 13.31 -1 13 -4 1072.12 44.91 1 13 4 1047.53 45.05 -1 13 -5 371.76 16.82 1 13 5 368.92 17.08 -1 13 -6 14.78 2.58 1 -13 6 13.85 2.16 1 -13 6 18.19 2.65 1 13 6 12.86 2.28 1 -13 7 865.13 34.85 -1 13 -7 843.30 35.21 1 -13 7 852.59 35.24 1 -13 8 691.53 30.34 -1 13 -8 715.01 30.76 1 -13 8 713.42 30.68 1 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-18 11.63 2.89 1 14 -18 18.08 3.07 1 -14 -17 59.25 4.08 1 -14 -17 53.22 3.64 1 14 -17 54.14 4.02 1 -14 -17 63.14 4.61 1 14 -17 64.81 4.40 1 -14 -16 56.82 3.78 1 -14 -16 50.92 3.50 1 14 -16 49.31 4.05 1 -14 -15 409.88 18.04 1 14 -15 443.78 20.19 -1 14 15 373.27 20.27 1 -14 -15 414.63 18.06 1 14 -15 422.55 18.23 1 -14 -14 2.80 1.97 1 14 -14 1.82 2.76 -1 14 14 2.92 2.65 1 -14 -14 3.20 1.81 1 14 -14 -0.86 2.40 1 -14 -13 365.90 16.01 -1 14 13 328.42 18.00 1 14 -13 358.95 17.75 1 -14 -13 386.96 16.13 1 14 -13 368.18 16.11 1 -14 -12 26.22 2.47 1 -14 -12 27.00 2.37 -1 14 12 20.87 3.52 1 14 -12 25.98 3.55 -1 14 11 91.28 6.59 1 14 -11 101.15 6.35 -1 14 10 200.91 11.31 1 14 -10 222.91 11.05 -1 14 9 64.46 5.07 1 14 -9 72.51 4.95 -1 -14 9 60.39 4.56 1 14 -8 294.23 14.12 -1 -14 8 294.00 13.93 1 -14 -7 65.92 3.82 1 14 -7 65.88 4.62 -1 -14 7 57.21 4.37 1 -14 -6 600.44 24.89 1 -14 -6 557.83 24.36 -1 14 6 498.81 25.09 -1 -14 6 583.66 25.03 1 14 -6 584.93 25.07 1 -14 -5 509.08 22.45 -1 -14 5 522.94 22.72 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15 13 33.76 4.51 1 15 -13 45.50 4.61 1 -15 -13 48.35 3.22 1 15 -13 41.39 3.29 1 -15 -12 559.70 24.57 1 -15 -12 606.05 24.82 1 -15 -12 606.70 24.72 1 15 -12 545.86 26.31 -1 15 12 540.48 26.79 1 15 -11 15.61 3.08 -1 15 11 12.89 2.84 1 15 -10 284.61 13.80 -1 15 10 264.77 13.99 -1 15 9 225.63 12.15 -1 -15 9 233.76 11.54 1 15 -9 235.45 11.86 -1 -15 8 19.65 2.91 1 15 -8 26.69 3.17 1 15 -7 58.14 4.42 -1 -15 7 60.10 4.44 1 -15 -7 57.42 3.65 -1 15 6 85.55 5.86 1 -15 -6 90.52 5.16 -1 -15 6 92.38 5.83 1 -15 -6 93.44 5.59 1 15 -6 92.62 5.82 1 -15 -5 36.02 3.11 1 15 -5 36.23 3.59 1 -15 -5 34.83 3.27 -1 -15 5 42.32 3.63 -1 15 5 35.30 3.53 1 15 -4 241.36 11.76 -1 15 4 246.23 12.03 1 -15 -4 229.48 11.47 -1 -15 4 244.29 11.79 1 -15 -3 111.30 6.51 -1 -15 3 127.53 6.95 1 -15 -2 1020.96 44.53 -1 -15 2 1085.27 44.84 1 15 -1 726.74 31.07 1 -15 -1 708.11 31.01 1 15 0 364.17 16.64 -1 15 -1 171.04 8.71 1 15 1 159.52 8.62 1 15 1 169.07 8.70 -1 -15 -1 171.56 8.75 1 -15 2 444.17 20.28 -1 -15 -2 442.68 20.17 1 15 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69.33 4.11 1 -21 -20 75.49 4.02 1 -21 -20 73.55 4.37 1 -21 -20 69.52 3.82 1 -21 -19 56.51 3.52 1 -21 -19 59.05 3.87 1 -21 -19 55.72 3.43 1 -21 -18 13.70 2.26 1 -21 -18 9.97 2.29 1 -21 -18 14.77 2.17 1 -21 -17 35.22 2.99 1 -21 -17 41.63 3.29 1 -21 -17 39.10 3.13 1 -21 -16 179.82 8.13 1 -21 -16 167.10 8.35 1 -21 -16 161.09 8.29 1 -21 -15 1492.37 60.73 1 -21 -15 1446.44 60.98 1 -21 -15 1532.80 61.05 1 -21 -15 1407.89 60.62 1 -21 -14 2063.03 84.28 1 -21 -14 2015.37 83.97 1 -21 -13 701.21 30.15 1 -21 -13 715.83 29.91 1 -21 -12 506.01 21.87 1 -21 -12 508.00 21.64 1 21 -11 748.40 33.99 1 -21 -11 758.51 31.63 1 -21 -11 740.13 31.42 1 -21 -10 189.66 8.72 1 -21 -10 189.12 8.70 1 21 -10 200.75 11.16 1 -21 -9 168.62 7.80 1 21 -9 174.41 10.23 1 -21 -8 65.46 3.64 1 -21 -8 67.46 3.80 1 21 -8 65.79 5.62 1 -21 -7 176.38 8.21 1 21 -7 182.25 10.31 1 -21 -6 6.31 1.54 1 21 -6 6.83 2.69 1 -21 -5 3.50 1.40 1 -21 -5 5.51 2.25 1 21 -5 3.91 2.66 1 -21 -4 10.96 2.45 1 -21 -4 8.56 2.36 1 -21 -3 511.38 23.43 1 -21 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50.26 3.37 -2 12 -1 46.77 3.58 2 12 1 47.36 3.51 2 12 2 584.78 24.79 2 12 2 567.14 24.77 -2 12 -2 561.73 24.79 -2 12 -3 6.67 2.20 -2 12 -4 309.61 14.16 -2 12 -5 904.72 38.48 -2 12 -6 150.14 7.96 2 -12 6 161.70 8.14 -2 12 -7 5851.85 242.08 2 -12 7 5934.13 242.20 -2 12 -8 626.26 27.46 2 -12 8 630.33 27.58 2 -12 9 435.10 19.92 -2 12 -9 439.92 19.81 -2 12 -10 8.29 2.21 2 -12 10 7.71 2.03 2 -12 10 8.09 2.30 2 -12 11 37.18 3.66 -2 12 -11 33.16 3.43 -2 -12 -12 176.55 8.49 2 -12 12 174.60 9.88 -2 -12 -12 183.19 8.49 -2 -12 -12 190.26 8.80 -2 -12 -13 40.21 3.08 2 -12 13 36.51 4.17 2 12 13 34.49 4.31 -2 -12 -13 39.69 2.89 -2 -12 -13 42.88 3.36 -2 12 -13 38.29 3.11 -2 12 -13 43.07 3.30 -2 -12 -14 27.48 2.73 -2 12 -14 28.88 2.87 -2 -12 -14 29.61 2.63 -2 -12 -14 31.23 3.04 2 12 14 25.50 4.11 -2 -12 -15 24.38 2.86 -2 -12 -15 23.66 2.62 -2 12 -15 26.35 2.94 -2 -12 -15 31.50 2.60 -2 -12 -15 24.95 3.17 2 12 15 19.32 4.16 -2 -12 -16 1.03 2.39 -2 12 -16 2.10 2.32 -2 -12 -16 1.32 2.66 -2 -12 -16 2.08 2.04 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-20 97.43 5.72 2 -13 -19 284.96 13.09 2 -13 -19 281.42 13.53 2 13 -19 290.56 13.29 2 -13 -18 8.79 2.65 2 13 -18 12.49 3.07 2 -13 -17 98.29 5.26 2 -13 -17 83.30 4.83 2 13 -17 96.37 5.65 2 -13 -16 64.13 3.96 -2 13 16 50.54 5.74 2 13 -16 61.90 5.63 2 -13 -16 54.93 3.62 2 13 -16 61.46 4.35 2 -13 -15 279.19 12.83 2 13 -15 305.57 14.91 2 -13 -15 295.45 14.99 -2 13 15 268.89 15.07 2 -13 -15 290.20 12.84 2 13 -15 290.39 13.12 2 -13 -14 200.50 9.59 2 -13 -14 225.19 10.09 2 13 -14 228.87 11.60 -2 13 14 192.73 11.63 2 -13 -14 213.67 9.68 2 13 -14 205.43 9.85 2 -13 -13 154.37 7.45 2 -13 -13 161.34 7.77 2 -13 -13 166.34 7.56 2 13 -13 155.45 9.08 -2 13 13 145.75 9.38 2 13 -12 54.67 4.68 -2 13 12 52.02 4.76 2 13 -11 1190.43 50.46 -2 13 11 1161.62 51.01 -2 13 10 437.65 20.54 2 13 -10 433.18 19.96 2 13 -9 17.56 2.58 -2 13 9 15.66 2.78 -2 13 8 1678.39 73.51 2 13 -8 1726.07 72.96 2 -13 -8 1791.07 72.64 2 13 -7 487.31 21.94 2 -13 -7 497.20 21.70 2 -13 -7 489.31 21.31 -2 13 7 495.08 22.45 2 -13 -6 2105.91 85.45 2 13 -6 2078.21 85.66 2 -13 -6 1998.65 85.15 2 -13 -5 3.86 1.94 -2 -13 5 5.20 2.11 2 -13 -5 4.05 1.58 -2 -13 4 670.87 28.69 2 -13 -4 636.22 28.32 2 -13 -4 670.93 28.45 -2 -13 3 263.79 12.56 2 13 -3 263.74 12.42 2 13 -2 206.65 10.07 2 13 -1 287.55 13.81 2 13 -1 315.49 13.74 -2 13 0 690.84 30.12 2 13 0 693.00 30.00 2 13 0 707.72 29.92 2 13 1 907.71 39.44 2 13 1 943.56 39.50 -2 13 -1 940.60 39.58 2 13 2 1473.42 61.63 2 13 2 1444.00 61.65 -2 13 -2 1498.80 61.70 -2 13 -3 2430.47 98.79 2 13 3 2330.39 98.82 2 13 4 20.40 2.53 -2 13 -4 19.90 2.62 -2 13 -5 3493.19 144.21 -2 13 -6 922.99 39.38 2 -13 6 921.69 39.40 -2 13 -7 1230.16 53.00 2 -13 7 1279.02 53.05 -2 13 -8 32.77 3.28 2 -13 8 37.64 3.31 -2 13 -9 0.82 1.86 2 -13 9 1.32 1.90 2 -13 9 1.26 1.76 2 -13 10 24.70 2.95 2 -13 10 28.17 3.16 -2 13 -10 24.53 3.01 2 13 11 259.03 14.22 2 -13 11 280.72 13.75 -2 13 -11 293.40 13.71 -2 -13 -12 4.67 1.97 -2 -13 -12 3.14 1.94 -2 -13 -12 2.72 1.74 -2 13 -12 3.36 1.74 2 13 12 0.45 2.32 2 -13 12 1.07 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97.28 4.26 -2 -13 -25 76.14 4.24 2 -14 -26 23.31 1.88 2 -14 -25 97.68 4.86 2 -14 -24 6.07 2.03 2 -14 -24 4.48 1.99 2 14 -24 4.58 1.61 2 -14 -23 2.68 2.18 2 -14 -23 0.66 2.14 2 14 -23 4.59 1.85 2 -14 -22 334.11 15.22 2 14 -22 315.08 15.24 2 -14 -22 354.20 15.67 2 -14 -21 15.77 2.74 2 -14 -21 13.39 2.90 2 14 -21 14.43 2.50 2 -14 -21 10.39 2.40 2 -14 -20 38.86 3.41 2 14 -20 32.44 3.31 2 -14 -20 38.54 3.74 2 14 -20 43.20 3.73 2 -14 -19 228.76 10.67 2 14 -19 203.26 10.67 2 -14 -19 240.24 11.19 2 14 -19 239.27 10.88 2 -14 -18 25.50 3.01 2 -14 -18 21.30 2.28 2 14 -18 29.36 3.41 2 -14 -17 12.59 2.51 2 -14 -17 14.81 2.12 2 14 -17 19.47 3.09 2 -14 -16 28.63 2.91 -2 14 16 24.74 4.14 2 14 -16 28.00 4.31 2 -14 -16 24.35 2.48 2 14 -16 31.54 3.31 2 -14 -15 3.98 2.16 2 -14 -15 2.58 2.88 2 14 -15 6.82 3.24 -2 14 15 4.09 2.87 2 -14 -15 3.89 1.89 2 14 -15 5.76 2.50 2 -14 -14 20.29 2.46 2 -14 -14 24.06 2.75 2 14 -14 21.93 3.63 -2 14 14 21.27 3.81 2 -14 -14 20.05 2.30 2 14 -14 20.97 2.75 2 -14 -13 164.86 7.71 2 -14 -13 149.36 7.32 2 -14 -13 161.37 7.46 -2 14 13 134.90 9.17 2 14 -13 150.08 9.05 2 -14 -12 169.66 8.09 -2 14 12 166.58 9.91 2 14 -12 173.29 9.58 2 14 -11 53.82 4.45 -2 14 11 43.12 4.50 2 14 -10 64.06 4.78 -2 14 10 58.07 4.96 2 14 -9 20.84 2.84 -2 14 9 22.47 3.17 2 -14 -8 1.95 1.39 2 14 -8 5.50 2.11 2 -14 -8 2.75 1.90 -2 14 8 4.12 2.24 2 -14 -7 177.48 8.88 2 14 -7 168.13 9.10 2 -14 -7 174.53 8.46 2 14 -6 1552.54 65.13 2 -14 -6 1597.19 64.92 2 -14 -6 1505.86 64.61 2 -14 -5 267.58 12.90 2 -14 -5 272.02 12.84 -2 -14 5 294.34 13.37 2 -14 -4 6.77 1.99 2 -14 -4 5.74 1.98 -2 -14 4 3.01 2.27 2 14 -3 2158.18 86.83 -2 -14 3 2112.17 86.97 2 -14 -3 1995.95 86.57 2 14 -2 286.66 13.45 2 14 -1 1333.67 58.90 2 14 -1 1471.64 58.85 2 14 0 6.45 2.15 -2 14 0 5.53 2.11 2 14 0 7.14 1.93 2 14 1 929.66 40.05 2 14 1 975.20 40.15 -2 14 -1 921.05 40.14 -2 14 -2 10.74 2.33 2 14 2 8.09 2.26 2 14 2 6.77 2.02 -2 14 -3 373.43 16.68 2 14 3 355.51 16.66 -2 14 -4 153.57 7.87 2 14 4 140.93 7.85 -2 14 -5 221.24 10.39 2 14 5 192.92 10.36 -2 14 -6 563.43 24.77 2 14 6 524.63 25.02 2 -14 6 588.55 24.73 2 -14 7 226.62 10.89 -2 14 -7 229.92 11.07 2 14 7 206.56 11.27 2 -14 8 337.14 15.86 2 14 8 300.41 16.12 2 -14 8 355.63 15.79 -2 14 -8 352.40 15.92 -2 14 -9 92.60 5.91 2 -14 9 95.86 5.91 2 -14 9 92.02 5.71 2 -14 10 521.72 23.93 2 -14 10 534.15 24.07 -2 14 -10 557.77 24.27 -2 -14 -11 49.16 3.27 -2 -14 -11 45.69 3.23 -2 14 -11 49.60 4.30 2 14 11 41.58 4.51 -2 -14 -12 1379.12 55.26 -2 14 -12 1234.42 55.20 -2 -14 -12 1354.68 55.36 -2 -14 -12 1399.11 55.53 2 14 12 1248.35 57.55 -2 -14 -13 8.41 2.23 -2 14 -13 6.47 1.87 -2 -14 -13 6.70 1.91 -2 -14 -13 8.21 2.25 2 14 13 5.82 2.92 -2 -14 -14 6.84 2.30 -2 14 -14 11.17 2.22 -2 -14 -14 12.75 2.19 -2 -14 -14 13.38 2.37 2 14 14 9.10 3.35 -2 -14 -15 469.18 20.33 -2 14 -15 443.26 20.43 -2 -14 -15 499.26 20.81 -2 -14 -15 473.67 20.38 -2 -14 -16 88.12 5.04 -2 14 -16 83.29 5.07 -2 -14 -16 83.63 4.89 -2 -14 -16 88.16 5.53 -2 -14 -17 -0.22 2.40 -2 14 -17 2.20 2.35 -2 -14 -17 3.12 2.60 -2 -14 -17 2.05 1.85 -2 -14 -18 134.34 6.95 -2 -14 -18 138.12 7.44 -2 14 -18 134.96 7.12 -2 -14 -18 136.63 6.74 -2 -14 -19 239.25 11.17 -2 14 -19 233.64 11.36 -2 -14 -19 262.33 11.82 -2 -14 -20 1.83 2.31 -2 -14 -20 0.62 2.58 -2 14 -20 4.23 2.29 -2 -14 -21 414.68 18.10 -2 -14 -21 418.76 18.54 -2 -14 -22 4.07 2.23 -2 -14 -22 3.65 2.30 -2 -14 -23 80.46 4.36 -2 -14 -23 74.36 4.51 -2 -14 -24 139.35 6.16 -2 -14 -24 120.08 6.17 2 -15 -25 0.15 1.55 2 -15 -25 1.14 1.57 2 -15 -24 107.77 5.33 2 -15 -24 104.76 5.53 2 -15 -23 28.87 2.63 2 -15 -23 24.31 2.71 2 -15 -22 9.92 2.40 2 -15 -22 11.60 2.58 2 15 -22 12.10 2.04 2 -15 -21 4.29 2.31 2 -15 -21 -0.20 2.52 2 15 -21 3.01 2.03 2 -15 -20 324.24 14.14 2 -15 -20 329.48 14.64 2 15 -20 347.27 14.30 2 -15 -19 9.76 2.53 2 -15 -19 12.73 2.91 2 15 -19 9.21 2.33 2 15 -19 11.81 2.87 2 -15 -18 5.55 2.41 2 -15 -18 4.21 1.75 2 15 -18 2.28 2.14 2 15 -18 6.30 2.73 2 -15 -17 21.88 2.81 2 -15 -17 21.82 2.37 2 15 -17 18.69 3.06 2 -15 -16 141.37 7.01 2 -15 -16 133.58 6.89 2 15 -16 136.73 7.21 2 -15 -15 271.09 12.42 2 -15 -15 276.06 14.79 2 15 -15 289.55 14.66 -2 15 15 264.92 14.85 2 -15 -15 277.74 12.46 2 15 -15 278.33 12.60 2 -15 -14 579.59 25.48 2 -15 -14 643.61 25.91 2 15 -14 596.13 27.64 -2 15 14 553.50 27.84 2 -15 -14 625.41 25.63 2 15 -14 579.01 25.58 2 -15 -13 30.84 2.88 2 -15 -13 33.05 2.76 2 -15 -13 31.18 2.63 2 15 -13 31.58 4.07 -2 15 13 31.47 4.27 2 -15 -12 173.09 8.03 2 -15 -12 170.45 7.85 2 15 -12 161.37 9.44 -2 15 11 162.44 9.68 2 15 -11 166.74 9.38 2 15 -10 45.58 4.11 -2 15 10 42.03 4.29 2 15 -9 390.80 18.20 -2 15 9 384.96 18.73 2 15 -8 32.94 3.49 2 -15 -8 35.28 3.24 -2 15 8 30.97 3.68 2 -15 -8 37.07 2.91 2 15 -7 1286.95 54.01 2 -15 -7 1348.43 53.75 2 -15 -7 1199.94 53.20 2 -15 -6 155.64 8.07 2 15 -6 157.56 8.34 2 -15 -6 143.88 7.74 2 -15 -5 1799.88 75.69 2 -15 -5 1824.88 75.72 2 -15 -4 34.16 3.31 2 -15 -4 34.75 3.17 2 -15 -3 137.19 7.51 2 15 -3 145.04 7.76 2 15 -2 19.85 2.77 2 -15 -2 14.58 2.34 2 15 -1 413.99 18.69 2 15 0 599.41 26.02 2 15 0 590.85 26.03 -2 15 -1 1040.68 44.66 2 15 1 1045.35 44.56 2 15 1 1060.40 44.61 -2 15 -2 64.61 4.55 2 15 2 65.28 4.51 2 15 2 65.39 4.41 2 15 3 1326.74 57.45 -2 15 -3 1391.14 57.38 -2 15 -4 135.50 7.72 2 15 4 149.24 7.94 -2 15 -5 1083.47 45.60 2 15 5 1053.61 45.88 -2 15 -6 908.79 38.55 2 15 6 846.01 38.77 2 -15 6 919.56 38.29 2 -15 7 81.57 5.07 -2 15 -7 84.91 5.45 2 15 7 79.33 5.57 2 -15 7 79.43 5.42 2 15 8 27.71 3.44 2 -15 8 33.64 3.38 -2 15 -8 27.65 3.18 2 -15 8 27.96 3.02 2 -15 9 18.01 2.77 -2 15 -9 19.30 2.88 2 15 9 16.98 2.90 2 -15 9 18.55 2.70 -2 -15 -10 38.48 2.75 2 -15 10 31.17 3.48 -2 15 -10 33.86 3.67 -2 -15 -11 30.26 2.74 -2 -15 -11 29.01 2.61 -2 -15 -11 28.75 2.67 -2 15 -11 25.02 3.43 -2 -15 -12 662.07 27.80 -2 -15 -12 658.62 28.00 -2 -15 -12 657.58 27.94 2 15 12 627.62 30.29 -2 -15 -13 75.31 4.42 -2 -15 -13 74.36 4.55 -2 15 -13 70.23 4.26 -2 -15 -13 73.24 4.44 2 15 13 64.99 6.02 -2 -15 -14 2.43 2.15 -2 15 -14 4.43 1.88 -2 -15 -14 3.45 2.00 -2 -15 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22 9 646.88 30.73 -2 -22 -9 659.69 27.89 -2 22 -10 177.41 10.33 2 -22 10 170.99 10.02 -2 -22 -10 177.03 8.22 -2 -22 -11 80.95 4.59 -2 -22 -11 73.74 4.31 -2 -22 -12 104.81 5.86 -2 -22 -12 116.82 5.74 -2 -22 -13 239.14 10.76 -2 -22 -13 232.86 10.97 -2 -22 -13 237.51 10.74 -2 -22 -14 24.73 2.69 -2 -22 -14 21.53 2.30 -2 -22 -14 26.08 2.83 -2 -22 -14 28.69 2.43 -2 -22 -15 5.05 2.15 -2 -22 -15 6.45 2.08 -2 -22 -15 2.78 1.67 -2 -22 -16 16.56 2.36 -2 -22 -16 19.71 2.49 -2 -22 -16 13.01 2.02 -2 -22 -17 15.57 2.24 -2 -22 -17 11.87 1.93 -2 -22 -17 17.31 2.26 -2 -22 -18 130.11 5.97 -2 -22 -18 124.67 6.05 -2 -22 -19 148.74 6.50 -2 -22 -19 131.51 6.46 -2 -22 -19 131.21 6.47 -2 -22 -20 29.56 2.16 -2 -22 -20 22.69 1.84 -2 -22 -20 26.87 2.09 -2 -22 -21 232.63 9.95 2 -23 -22 57.06 3.11 2 -23 -21 13.04 1.82 2 -23 -20 10.34 1.51 2 -23 -20 7.90 1.79 2 -23 -19 87.42 4.63 2 -23 -19 92.15 4.88 2 -23 -18 0.80 1.80 2 -23 -18 -0.19 1.68 2 -23 -17 54.69 3.74 2 -23 -17 56.49 3.71 2 -23 -16 84.80 4.92 2 -23 -16 92.15 5.07 2 -23 -16 83.67 4.48 2 -23 -15 7.02 2.30 2 -23 -15 9.74 1.93 2 -23 -14 253.86 11.64 2 -23 -14 250.95 11.31 2 -23 -13 37.65 3.23 2 -23 -13 36.31 2.83 2 -23 -12 1216.81 51.59 2 -23 -12 1252.82 51.42 2 -23 -11 6.26 1.80 2 -23 -10 157.31 7.45 2 -23 -9 154.88 7.53 2 23 -9 169.00 10.09 2 -23 -9 163.74 7.69 2 23 -8 24.86 4.34 2 -23 -8 22.22 2.34 2 23 -7 1.40 2.99 2 -23 -7 1.57 1.67 2 23 -6 506.27 24.04 2 -23 -6 505.64 21.59 2 -23 -5 130.89 8.19 2 -23 -5 137.49 8.17 2 -23 -5 130.44 6.39 2 -23 -4 47.03 4.62 2 -23 -4 42.08 4.40 2 -23 -4 46.82 2.96 -2 -23 4 43.51 2.70 2 -23 -3 30.19 3.91 2 23 -3 19.52 3.64 2 -23 -3 20.01 3.41 2 -23 -3 25.18 2.09 -2 -23 3 24.54 2.01 2 -23 -2 170.06 9.64 2 -23 -2 149.79 9.09 2 23 -2 159.63 9.34 2 -23 -2 151.28 7.13 -2 -23 2 151.06 7.07 2 23 -1 314.16 16.12 2 -23 -1 315.13 16.26 -2 -23 1 329.08 14.06 2 -23 0 25.86 3.91 -2 -23 0 28.69 2.26 -2 -23 -1 6.73 1.59 -2 -23 -1 7.71 1.57 2 -23 2 446.64 22.09 -2 -23 -2 462.07 19.77 -2 -23 -2 469.23 19.79 2 -23 3 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24 -2 68.82 5.89 2 -24 -2 66.11 3.76 -2 -24 2 67.33 3.73 2 24 -1 2.38 2.98 2 -24 -1 5.03 2.77 2 -24 -1 1.55 2.70 2 -24 -1 2.62 1.44 -2 -24 1 3.94 1.54 2 -24 0 16.48 3.61 -2 -24 0 18.86 1.98 -2 -24 -1 60.75 3.56 -2 -24 -1 64.83 3.66 2 -24 2 17.62 3.78 -2 -24 -2 18.79 1.91 -2 -24 -2 17.74 2.09 2 -24 3 9.62 1.49 2 -24 3 9.54 3.26 -2 -24 -3 12.61 1.90 -2 -24 -3 10.94 1.82 2 -24 4 24.67 3.96 -2 -24 -4 25.37 2.46 -2 -24 -4 29.99 2.43 2 -24 5 65.39 5.81 -2 -24 -5 69.06 3.98 2 -24 6 49.82 5.25 -2 -24 -6 59.90 3.61 -2 -24 -6 54.71 3.38 2 -24 7 7.32 3.05 -2 -24 -7 12.43 2.00 -2 -24 -7 13.41 1.97 2 -24 8 146.15 9.31 -2 -24 -8 157.23 7.42 -2 -24 -8 148.87 7.24 2 -24 9 121.85 8.11 -2 -24 -9 120.45 6.18 -2 -24 -9 121.73 6.05 -2 -24 -10 18.66 2.21 -2 -24 -11 17.30 2.17 -2 -24 -12 284.63 13.14 -2 -24 -12 300.72 13.04 -2 -24 -13 13.36 2.25 -2 -24 -13 15.62 2.08 -2 -24 -14 204.21 9.53 -2 -24 -14 202.26 9.30 -2 -24 -15 14.11 2.32 -2 -24 -15 13.62 1.82 -2 -24 -16 6.58 2.06 -2 -24 -17 0.57 1.77 -2 -24 -18 205.40 9.32 -2 -24 -19 -0.97 1.38 -2 -24 -20 436.58 18.27 2 -25 -20 176.71 7.65 2 -25 -20 166.15 7.70 2 -25 -19 36.99 2.67 2 -25 -19 43.58 2.69 2 -25 -18 87.48 4.38 2 -25 -18 72.12 4.19 2 -25 -17 3.87 1.86 2 -25 -17 4.72 1.64 2 -25 -16 40.98 3.00 2 -25 -16 47.77 3.37 2 -25 -16 44.87 2.81 2 -25 -15 8.49 1.87 2 -25 -15 6.02 2.20 2 -25 -15 4.64 1.69 2 -25 -14 20.95 2.70 2 -25 -14 23.60 2.31 2 -25 -13 580.82 25.52 2 -25 -13 608.48 25.32 2 -25 -12 546.79 23.30 2 -25 -11 58.38 3.64 2 -25 -10 5.09 1.70 2 -25 -10 4.51 2.08 2 -25 -9 3.31 1.67 2 -25 -9 1.07 1.81 2 -25 -8 16.02 2.15 2 -25 -8 17.93 2.34 2 -25 -7 953.19 40.11 2 25 -7 982.61 42.98 2 -25 -7 960.78 40.20 2 25 -6 335.22 17.31 2 -25 -6 338.84 14.87 2 -25 -5 763.50 32.14 2 -25 -4 11.86 3.25 2 -25 -4 6.83 2.93 2 25 -4 10.45 3.70 2 -25 -4 10.33 1.88 -2 -25 4 8.24 1.57 2 -25 -3 26.43 3.93 2 -25 -3 22.04 3.65 2 25 -3 20.13 4.11 2 -25 -3 21.56 2.13 -2 -25 3 21.59 2.00 2 -25 -2 110.70 7.48 2 25 -2 105.35 7.41 2 -25 -2 98.48 6.98 2 -25 -2 93.58 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9.19 2 -27 2 206.30 11.98 -2 -27 -2 203.51 9.32 -2 -27 -2 211.82 9.45 2 -27 3 1482.82 63.88 -2 -27 -3 1476.38 60.99 2 -27 3 1391.43 60.72 -2 -27 -3 1583.12 61.07 2 -27 4 488.79 23.37 -2 -27 -4 483.41 20.71 -2 -27 -4 477.89 20.70 2 -27 5 253.10 14.17 -2 -27 -5 264.71 11.84 2 -27 6 92.15 7.09 -2 -27 -6 89.86 4.95 -2 -27 -7 7.68 2.13 -2 -27 -7 5.96 1.81 -2 -27 -8 7.54 2.05 -2 -27 -8 5.84 1.88 -2 -27 -9 147.59 7.31 -2 -27 -9 150.64 7.21 -2 -27 -10 34.63 2.92 -2 -27 -10 32.80 2.76 -2 -27 -11 8.81 1.89 -2 -27 -12 9.89 1.91 -2 -27 -13 4.19 1.84 -2 -27 -13 3.25 1.61 -2 -27 -14 14.42 2.12 -2 -27 -14 17.33 1.92 -2 -27 -15 11.18 2.04 -2 -27 -15 8.33 1.54 -2 -27 -16 2.23 1.68 -2 -27 -17 316.38 13.74 -2 -27 -18 42.55 2.66 -2 -27 -19 73.62 3.56 2 -28 -19 36.77 2.30 2 -28 -18 101.58 4.96 2 -28 -17 37.31 2.68 2 -28 -16 21.47 2.23 2 -28 -16 20.44 1.83 2 -28 -15 11.71 2.08 2 -28 -15 11.76 1.70 2 -28 -14 384.37 16.56 2 -28 -14 374.52 16.31 2 -28 -13 2.74 1.61 2 -28 -12 46.24 3.12 2 -28 -11 27.39 2.78 2 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204.22 9.13 -2 -29 0 195.51 9.18 -2 -29 -1 128.63 6.37 2 -29 1 136.75 6.43 -2 -29 -1 138.34 6.64 -2 -29 -2 506.99 22.11 2 -29 2 516.42 22.02 -2 -29 -2 539.63 22.29 -2 -29 -3 63.15 3.87 -2 -29 -3 71.23 4.07 2 -29 3 63.35 3.60 -2 -29 -4 461.00 20.01 -2 -29 -4 469.78 20.08 -2 -29 -5 300.88 13.31 -2 -29 -5 297.27 13.30 -2 -29 -6 209.02 9.70 -2 -29 -7 34.66 2.87 -2 -29 -7 33.55 2.80 -2 -29 -8 15.52 2.31 -2 -29 -8 12.79 2.14 -2 -29 -9 4.57 1.85 -2 -29 -9 6.07 1.76 -2 -29 -10 9.60 2.11 -2 -29 -10 11.35 1.90 -2 -29 -11 4.59 1.83 -2 -29 -11 2.90 1.68 -2 -29 -12 27.74 2.38 -2 -29 -13 15.43 1.90 -2 -29 -14 72.85 3.94 -2 -29 -14 66.10 3.68 -2 -29 -15 80.77 4.16 -2 -29 -15 72.15 3.77 -2 -29 -16 237.25 10.47 -2 -29 -17 2.82 1.34 -2 -29 -18 324.51 13.72 2 -30 -18 27.47 1.93 2 -30 -17 15.44 1.72 2 -30 -16 -0.05 1.53 2 -30 -16 0.50 1.06 2 -30 -15 20.57 2.21 2 -30 -15 22.88 1.90 2 -30 -14 36.41 2.53 2 -30 -13 158.38 7.37 2 -30 -12 12.35 2.17 2 -30 -12 13.89 1.91 2 -30 -11 9.97 2.16 2 -30 -11 10.64 1.90 2 -30 -10 74.29 4.48 2 -30 -10 80.19 4.31 2 -30 -9 -0.25 1.81 2 -30 -9 1.63 1.98 2 -30 -8 70.25 4.22 2 -30 -8 65.04 4.06 2 -30 -7 262.70 11.90 2 -30 -6 314.68 14.24 2 -30 -6 328.18 14.21 2 -30 -5 1451.45 62.21 2 -30 -5 1553.45 62.28 2 -30 -4 1.63 1.87 2 -30 -4 4.09 1.78 -2 -30 4 2.94 1.53 2 -30 -3 596.97 26.57 -2 -30 3 622.22 26.53 2 -30 -3 678.10 26.76 2 -30 -2 11.57 2.04 2 -30 -2 6.15 1.68 -2 -30 2 7.63 1.74 -2 -30 1 44.80 3.13 2 -30 -1 49.97 3.15 2 -30 0 8.84 1.74 -2 -30 0 8.07 1.83 -2 -30 -1 214.90 9.73 2 -30 1 208.67 9.52 2 -30 2 1.50 1.45 -2 -30 -2 0.81 1.52 -2 -30 -2 1.86 1.87 -2 -30 -3 233.83 10.66 2 -30 3 230.89 10.45 -2 -30 -3 249.82 10.86 -2 -30 -4 33.97 2.69 -2 -30 -4 30.65 2.74 -2 -30 -5 0.20 1.76 -2 -30 -5 0.60 1.84 -2 -30 -6 777.00 32.76 -2 -30 -7 60.70 4.01 -2 -30 -7 66.77 3.89 -2 -30 -8 369.88 16.10 -2 -30 -8 365.11 16.00 -2 -30 -9 16.05 2.31 -2 -30 -9 15.35 2.05 -2 -30 -10 272.89 12.07 -2 -30 -10 267.41 11.97 -2 -30 -11 71.65 4.13 -2 -30 -11 71.87 3.99 -2 -30 -12 15.24 2.08 -2 -30 -12 13.04 1.84 -2 -30 -13 26.00 2.15 -2 -30 -14 47.35 2.80 -2 -30 -15 44.36 2.91 -2 -30 -15 48.22 2.60 -2 -30 -16 33.98 2.34 -2 -30 -17 33.32 2.16 2 -31 -18 6.17 1.09 2 -31 -17 20.66 1.76 2 -31 -16 64.88 3.35 2 -31 -16 56.60 2.97 2 -31 -15 4.74 1.60 2 -31 -15 3.24 1.24 2 -31 -14 28.30 2.16 2 -31 -13 1.86 1.46 2 -31 -12 83.57 4.72 2 -31 -12 90.85 4.58 2 -31 -11 5.06 1.92 2 -31 -11 4.60 1.69 2 -31 -10 50.51 3.55 2 -31 -10 56.28 3.39 2 -31 -9 209.97 9.91 2 -31 -9 219.59 9.83 2 -31 -8 582.40 24.86 2 -31 -7 114.92 5.96 2 -31 -6 381.60 16.92 2 -31 -6 395.94 16.93 2 -31 -5 17.92 2.28 2 -31 -5 17.27 2.31 2 -31 -4 245.81 11.38 -2 -31 4 243.83 11.20 2 -31 -3 52.93 3.45 -2 -31 3 60.39 3.47 2 -31 -3 65.20 3.71 2 -31 -2 103.56 5.53 -2 -31 2 115.57 5.68 2 -31 -1 200.06 8.95 -2 -31 1 191.33 8.95 2 -31 0 8.44 1.67 -2 -31 0 8.97 1.79 2 -31 1 1.81 1.49 -2 -31 -1 2.43 1.73 -2 -31 -2 49.50 3.15 -2 -31 -2 57.95 3.45 2 -31 2 50.75 3.08 -2 -31 -3 285.83 12.94 2 -31 3 291.07 12.78 -2 -31 -3 311.22 13.14 -2 -31 -4 288.73 12.82 -2 -31 -4 290.83 12.94 -2 -31 -5 35.87 2.82 -2 -31 -5 36.91 2.93 -2 -31 -6 432.60 18.69 -2 -31 -7 1.43 1.88 -2 -31 -8 31.75 2.72 -2 -31 -8 30.36 2.56 -2 -31 -9 0.31 1.77 -2 -31 -9 0.82 1.73 -2 -31 -10 5.50 1.79 -2 -31 -10 2.86 1.67 -2 -31 -11 40.90 2.94 -2 -31 -11 42.63 2.81 -2 -31 -12 61.74 3.57 -2 -31 -12 59.22 3.41 -2 -31 -13 226.22 9.95 -2 -31 -14 25.25 1.90 -2 -31 -15 44.25 2.75 -2 -31 -15 44.60 2.35 -2 -31 -16 309.43 13.21 2 -32 -17 -0.65 1.03 2 -32 -16 6.71 1.34 2 -32 -15 148.31 6.59 2 -32 -14 107.96 5.12 2 -32 -13 15.22 1.97 2 -32 -13 14.08 1.74 2 -32 -12 91.08 4.72 2 -32 -12 87.67 4.54 2 -32 -11 100.90 5.14 2 -32 -11 95.94 4.96 2 -32 -10 49.49 3.39 2 -32 -10 54.12 3.30 2 -32 -9 5.64 2.01 2 -32 -9 10.01 1.87 2 -32 -8 173.75 8.22 2 -32 -7 50.47 3.42 2 -32 -6 240.25 11.12 2 -32 -6 254.06 11.16 2 -32 -5 27.36 2.47 2 -32 -5 30.93 2.69 2 -32 -4 316.37 14.56 2 -32 -4 359.58 14.77 2 -32 -3 48.14 3.24 -2 -32 3 55.54 3.28 2 -32 -2 2.40 1.59 -2 -32 2 4.98 1.56 2 -32 -1 160.95 7.43 -2 -32 1 157.17 7.45 2 -32 0 58.78 3.42 -2 -32 0 60.11 3.56 -2 -32 -1 7.66 1.85 2 -32 1 5.92 1.51 -2 -32 -2 180.74 8.58 2 -32 2 189.40 8.58 -2 -32 -2 207.50 8.92 -2 -32 -3 180.43 8.69 -2 -32 -3 207.84 9.00 -2 -32 -4 236.35 10.97 -2 -32 -4 259.14 11.17 -2 -32 -5 136.57 6.83 -2 -32 -5 150.44 6.99 -2 -32 -6 2.14 1.76 -2 -32 -7 197.84 9.09 -2 -32 -8 280.44 12.65 -2 -32 -8 291.56 12.66 -2 -32 -9 319.86 13.80 -2 -32 -9 309.15 13.71 -2 -32 -10 15.58 2.04 -2 -32 -10 16.00 1.91 -2 -32 -11 85.01 4.42 -2 -32 -11 81.21 4.29 -2 -32 -12 63.55 3.53 -2 -32 -12 60.36 3.40 -2 -32 -13 6.20 1.58 -2 -32 -13 3.36 1.31 -2 -32 -14 28.07 1.90 -2 -32 -15 16.98 1.65 -2 -32 -16 27.68 1.82 2 -33 -16 4.56 1.12 2 -33 -15 8.77 1.13 2 -33 -14 18.02 1.64 2 -33 -13 249.30 11.01 2 -33 -13 252.62 10.90 2 -33 -12 18.00 1.98 2 -33 -12 15.36 1.79 2 -33 -11 -1.19 1.65 2 -33 -11 -1.27 1.57 2 -33 -10 1.32 1.66 2 -33 -10 2.78 1.60 2 -33 -9 113.80 5.80 2 -33 -9 118.56 5.77 2 -33 -8 96.23 5.06 2 -33 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-13 -15 40.71 3.35 4 -13 -15 50.71 3.25 4 13 -15 46.41 4.94 4 -13 -15 47.39 5.00 4 -13 -14 153.30 7.46 4 -13 -14 141.28 7.17 4 -13 -14 148.07 7.17 4 13 -14 147.64 8.94 4 -13 -13 66.47 4.12 4 -13 -13 68.97 3.94 4 13 -13 66.74 5.50 4 -13 -12 593.23 24.90 4 13 -12 558.19 26.41 4 13 -11 89.26 6.07 4 13 -10 285.41 14.01 4 -13 -9 8.27 2.12 4 13 -9 9.68 2.40 4 -13 -8 1581.68 66.29 4 -13 -7 108.21 6.05 4 13 -6 577.69 25.22 4 -13 -6 564.14 24.97 4 13 -5 144.34 7.64 4 -13 -5 139.52 7.50 4 13 -4 106.93 6.09 4 -13 -4 103.12 6.05 4 13 -3 1349.87 55.81 4 13 -3 1334.18 55.07 4 -13 -3 1280.53 55.85 4 13 -2 186.63 8.93 4 13 -2 197.00 9.48 4 -13 -2 184.30 9.56 4 13 -1 526.55 22.85 4 13 -1 538.50 23.18 4 -13 -1 514.52 23.38 4 13 0 2143.32 87.04 4 -13 0 2035.74 87.30 4 13 1 16.06 2.37 4 13 2 1325.22 52.80 4 -13 2 1173.58 53.07 4 -13 3 835.26 36.05 -4 13 -4 415.48 18.31 4 -13 4 393.95 18.46 -4 13 -5 50.90 3.77 4 -13 5 47.63 3.91 -4 13 -6 5.18 1.93 4 -13 6 2.58 1.77 -4 13 -7 40.34 3.32 4 -13 7 30.94 3.29 4 -13 7 34.94 3.68 -4 13 -8 190.90 9.36 4 -13 8 184.42 10.04 4 -13 8 169.34 9.56 4 -13 9 88.90 6.02 4 -13 9 72.35 5.38 -4 -13 -10 636.73 26.87 -4 -13 -10 644.39 26.95 4 -13 10 637.85 28.86 4 -13 10 600.35 28.27 -4 -13 -11 141.39 6.90 -4 13 -11 130.77 6.80 -4 -13 -11 141.18 7.06 -4 -13 -11 138.45 6.84 -4 13 -11 140.65 6.83 4 -13 11 135.60 8.51 4 -13 11 138.95 8.18 -4 -13 -12 626.17 26.28 -4 13 -12 584.15 26.32 -4 -13 -12 639.78 26.58 -4 -13 -12 623.88 26.34 -4 13 -12 606.34 26.27 4 -13 12 600.06 28.73 4 -13 12 653.07 28.61 -4 -13 -13 423.72 18.55 -4 -13 -13 455.31 18.95 -4 13 -13 417.51 18.56 -4 -13 -13 431.39 18.60 -4 13 -13 405.36 18.66 4 -13 13 431.46 20.83 4 -13 13 419.68 21.28 -4 -13 -14 143.72 7.34 -4 -13 -14 154.57 7.76 -4 -13 -14 151.13 7.32 -4 13 -14 139.89 7.28 -4 13 -14 140.78 7.49 4 -13 14 149.24 10.02 -4 -13 -15 1995.20 84.88 -4 13 -15 1994.24 85.16 -4 13 -15 1994.48 84.98 -4 -13 -15 2173.59 85.45 -4 -13 -15 2134.78 85.02 4 -13 15 2073.12 88.65 -4 -13 -16 32.07 3.17 -4 -13 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-7 -20 1086.08 43.96 5 -7 -19 98.81 5.97 5 7 -19 87.16 5.82 5 -7 -19 94.57 5.39 5 7 -19 88.80 5.86 5 -7 -18 986.39 45.23 5 -7 -18 1056.74 43.52 5 7 -18 1047.23 43.51 5 7 -18 980.84 43.23 5 -7 -18 1042.15 43.02 5 7 -17 402.77 19.48 5 -7 -17 385.42 19.51 5 7 -17 401.18 17.87 5 -7 -17 408.37 17.96 5 -7 -17 398.36 17.72 5 -7 -17 399.05 17.48 5 7 -16 0.41 2.52 5 -7 -16 0.87 2.62 5 7 -16 4.01 2.37 5 -7 -16 2.85 1.97 5 -7 -16 0.37 2.42 5 -7 -16 0.25 2.09 5 7 -15 2.10 2.67 5 -7 -15 3.26 2.69 5 -7 -15 4.91 2.26 5 -7 -15 6.44 1.96 5 7 -15 3.89 2.17 5 -7 -15 3.67 1.96 5 -7 -14 31.02 2.62 5 7 -14 27.40 3.44 5 -7 -14 28.36 3.65 5 7 -13 0.33 2.17 5 -7 -13 0.35 2.04 -5 7 12 278.05 12.95 5 -7 -12 287.99 13.90 5 7 -12 276.80 13.62 -5 7 11 12.70 1.79 5 7 -11 12.39 2.38 -5 7 10 239.22 10.98 -5 7 9 1931.31 80.00 -5 7 8 371.27 16.42 5 7 -8 373.46 16.83 -5 7 7 1725.82 68.62 -5 7 7 1595.74 67.82 5 7 -7 1760.15 68.95 -5 7 6 116.57 5.19 5 7 -6 113.07 5.35 -5 7 5 597.45 25.67 5 7 -5 602.16 25.73 -5 7 4 2459.36 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184.62 8.57 -5 -26 -12 250.32 11.17 -5 -26 -13 28.49 2.70 -5 -26 -13 35.26 2.51 -5 -26 -14 77.33 4.47 -5 -26 -14 85.52 4.22 -5 -26 -15 52.26 3.32 -5 -26 -16 75.52 4.09 -5 -26 -17 27.05 2.08 5 -27 -20 3.31 0.97 5 -27 -19 67.62 3.44 5 -27 -19 63.35 3.38 5 -27 -18 2.70 1.52 5 -27 -18 4.16 1.41 5 -27 -17 -0.17 1.64 5 -27 -17 0.57 1.40 5 -27 -17 0.36 1.14 5 -27 -16 185.78 8.75 5 -27 -16 190.86 8.44 5 -27 -15 2.99 1.43 5 -27 -15 2.19 1.92 5 -27 -14 114.43 5.96 5 -27 -14 114.88 5.64 5 -27 -13 8.06 1.79 5 -27 -12 44.84 3.05 5 -27 -12 38.54 2.92 5 -27 -11 4.10 1.80 5 -27 -11 5.43 1.73 5 -27 -11 2.32 2.11 5 -27 -10 3.54 2.11 5 -27 -9 2.57 2.11 5 -27 -8 88.97 5.04 5 -27 -7 2.32 2.07 5 -27 -6 332.53 17.75 5 -27 -6 363.55 15.72 5 -27 -5 31.07 4.66 5 -27 -5 28.11 2.68 -5 -27 5 23.85 2.27 5 -27 -4 197.43 11.57 5 -27 -4 197.22 9.06 -5 -27 4 189.26 8.87 5 -27 -3 10.20 3.65 5 -27 -3 11.51 1.92 -5 -27 3 13.83 1.95 5 -27 -2 10.46 3.74 5 -27 -2 8.48 1.76 -5 -27 2 8.09 1.89 5 -27 -1 169.83 10.29 5 -27 -1 149.95 7.19 -5 -27 1 154.72 7.43 5 -27 0 72.65 6.66 -5 -27 0 68.62 3.96 -5 -27 0 76.23 4.30 -5 -27 -1 0.06 1.53 -5 -27 -1 1.00 1.94 5 -27 2 177.28 10.97 -5 -27 -2 170.34 8.28 -5 -27 -2 182.00 8.42 -5 -27 -3 1.32 1.82 -5 -27 -3 3.86 2.04 -5 -27 -4 772.03 32.62 -5 -27 -5 20.04 2.57 -5 -27 -6 298.14 12.99 -5 -27 -6 278.11 12.87 -5 -27 -7 123.06 6.17 -5 -27 -7 112.64 5.96 -5 -27 -8 304.92 13.24 -5 -27 -8 285.39 13.04 -5 -27 -9 104.91 5.67 -5 -27 -9 111.82 5.62 -5 -27 -10 29.89 2.72 -5 -27 -10 23.78 2.39 -5 -27 -11 2.87 1.68 -5 -27 -12 32.78 2.50 -5 -27 -13 53.34 3.52 -5 -27 -13 58.90 3.31 -5 -27 -14 19.10 2.22 -5 -27 -14 21.67 1.86 -5 -27 -15 304.64 13.26 -5 -27 -16 121.69 5.78 -5 -27 -17 841.40 34.87 5 -28 -19 -1.24 1.12 5 -28 -18 1.46 1.14 5 -28 -18 0.85 1.40 5 -28 -17 85.91 4.46 5 -28 -17 100.99 4.76 5 -28 -17 91.11 4.31 5 -28 -16 74.02 4.07 5 -28 -16 78.15 4.01 5 -28 -15 0.68 1.77 5 -28 -15 1.80 1.40 5 -28 -14 10.86 1.74 5 -28 -14 10.90 2.15 5 -28 -13 38.49 2.72 5 -28 -12 35.78 2.73 5 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17.17 1.86 -5 -30 -1 14.73 1.87 -5 -30 -1 16.80 2.26 5 -30 2 129.39 6.01 -5 -30 -2 119.13 6.14 -5 -30 -2 130.50 6.44 -5 -30 -3 259.32 11.81 -5 -30 -3 270.77 11.96 -5 -30 -4 3.35 1.78 -5 -30 -4 1.78 1.87 -5 -30 -5 0.74 1.74 -5 -30 -6 250.92 11.33 -5 -30 -7 7.37 1.98 -5 -30 -7 4.70 1.87 -5 -30 -8 178.08 8.33 -5 -30 -8 175.24 8.18 -5 -30 -9 210.17 9.61 -5 -30 -9 210.21 9.48 -5 -30 -10 85.42 4.73 -5 -30 -10 91.33 4.57 -5 -30 -11 18.26 2.10 -5 -30 -11 20.28 1.92 -5 -30 -12 -1.06 1.57 -5 -30 -12 2.76 1.30 -5 -30 -13 1.57 1.14 -5 -30 -14 14.08 1.64 -5 -30 -15 169.73 7.50 5 -31 -18 74.17 3.51 5 -31 -17 1.45 1.16 5 -31 -16 193.97 8.32 5 -31 -16 182.19 8.07 5 -31 -15 4.75 1.54 5 -31 -15 4.13 1.23 5 -31 -14 36.21 2.37 5 -31 -13 0.39 1.67 5 -31 -13 2.89 1.43 5 -31 -12 2.25 1.52 5 -31 -12 2.56 1.82 5 -31 -11 87.57 4.90 5 -31 -11 94.67 4.77 5 -31 -10 29.59 2.69 5 -31 -10 28.52 2.55 5 -31 -9 416.85 17.36 5 -31 -9 382.46 17.20 5 -31 -8 30.04 2.76 5 -31 -7 122.87 6.19 5 -31 -7 121.94 6.18 5 -31 -6 1.04 1.89 5 -31 -6 0.85 1.76 5 -31 -5 -2.52 1.86 5 -31 -5 -0.31 1.68 5 -31 -4 57.05 3.47 5 -31 -4 55.03 3.34 -5 -31 4 50.02 3.18 5 -31 -3 6.20 1.78 5 -31 -3 7.12 1.57 -5 -31 3 5.81 1.65 5 -31 -2 14.24 1.96 5 -31 -2 13.72 1.69 -5 -31 2 16.20 2.03 5 -31 -1 15.17 1.89 -5 -31 1 17.05 2.08 5 -31 0 23.46 2.09 -5 -31 0 24.01 2.41 5 -31 1 4.14 1.45 -5 -31 -1 5.06 1.95 -5 -31 -2 74.78 4.16 5 -31 2 79.62 4.02 -5 -31 -2 77.19 4.45 -5 -31 -3 62.59 3.73 -5 -31 -3 64.94 3.94 -5 -31 -4 11.65 1.98 -5 -31 -4 11.82 2.10 -5 -31 -5 11.42 2.01 -5 -31 -6 83.98 4.59 -5 -31 -7 3.04 1.76 -5 -31 -7 2.71 1.69 -5 -31 -8 359.15 15.57 -5 -31 -8 356.40 15.47 -5 -31 -9 7.39 1.88 -5 -31 -9 7.09 1.70 -5 -31 -10 0.49 1.63 -5 -31 -10 2.02 1.42 -5 -31 -11 35.26 2.59 -5 -31 -11 37.00 2.40 -5 -31 -12 1.96 1.48 -5 -31 -12 3.95 1.21 -5 -31 -13 7.75 1.21 -5 -31 -15 40.86 2.29 5 -32 -17 21.25 1.55 5 -32 -16 2.11 1.17 5 -32 -16 -0.90 0.83 5 -32 -15 107.16 4.92 5 -32 -14 144.19 6.51 5 -32 -13 37.47 2.67 5 -32 -13 39.88 2.48 5 -32 -12 25.70 2.41 5 -32 -12 29.93 2.22 5 -32 -11 33.49 2.74 5 -32 -11 38.13 2.60 5 -32 -10 4.83 1.72 5 -32 -10 7.67 1.91 5 -32 -9 152.74 7.32 5 -32 -8 -1.01 1.81 5 -32 -7 1.41 1.76 5 -32 -7 -1.06 1.84 5 -32 -6 -3.64 1.82 5 -32 -6 0.24 1.70 5 -32 -5 3.49 1.77 5 -32 -5 3.68 1.69 5 -32 -4 13.81 2.04 5 -32 -4 11.69 1.79 -5 -32 4 13.79 1.73 5 -32 -3 3.17 1.68 5 -32 -3 0.31 1.38 -5 -32 3 1.92 1.44 5 -32 -2 40.70 2.77 -5 -32 2 39.39 2.78 5 -32 -1 14.41 1.87 -5 -32 1 17.23 2.04 -5 -32 0 327.82 13.56 5 -32 0 291.12 13.25 -5 -32 -1 707.71 28.92 5 -32 1 667.67 28.60 5 -32 2 5.31 1.38 -5 -32 -2 3.57 1.49 -5 -32 -2 4.40 1.83 -5 -32 -3 153.31 7.46 -5 -32 -3 170.33 7.69 -5 -32 -4 93.51 5.01 -5 -32 -4 103.95 5.20 -5 -32 -5 12.49 1.91 -5 -32 -6 8.93 1.85 -5 -32 -7 11.63 1.84 -5 -32 -7 9.50 1.80 -5 -32 -8 75.13 4.20 -5 -32 -8 79.36 4.13 -5 -32 -9 2.42 1.62 -5 -32 -9 4.56 1.51 -5 -32 -10 60.87 3.51 -5 -32 -10 62.70 3.36 -5 -32 -11 8.64 1.64 -5 -32 -11 12.26 1.48 -5 -32 -12 50.39 2.96 -5 -32 -12 53.21 2.82 -5 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540.72 23.29 -10 -4 10 492.08 23.15 10 -4 -10 524.14 23.19 10 4 -10 551.65 23.24 -10 4 10 523.11 21.39 -10 -4 10 451.95 21.32 10 4 -10 543.14 22.07 -10 4 9 12.37 2.56 -10 -4 9 11.04 2.56 10 -4 -9 12.67 2.50 10 4 -9 9.80 2.42 -10 4 8 1.30 2.13 -10 -4 8 3.67 2.33 10 -4 -8 0.97 1.81 10 4 -8 1.81 2.02 -10 4 7 107.55 6.83 10 -4 -7 108.33 6.37 10 4 -7 120.39 6.59 -10 4 6 86.58 5.82 10 -4 -6 88.98 5.33 10 4 -6 84.52 5.34 -10 -4 5 1016.31 42.81 10 -4 -5 950.81 41.92 10 4 -5 1014.10 42.07 -10 -4 4 266.95 13.23 10 -4 -4 263.63 12.36 10 4 -4 272.79 12.47 -10 4 3 36.45 3.56 -10 -4 3 35.16 3.66 10 -4 -3 31.50 2.66 -10 4 2 981.38 42.14 -10 -4 2 966.10 42.06 -10 4 1 896.99 38.89 -10 -4 1 890.11 38.79 -10 4 0 5.02 2.41 -10 -4 0 4.29 2.26 -10 -4 -1 390.32 18.29 10 4 1 388.25 18.34 -10 -4 -2 3.02 2.23 10 4 2 2.07 1.92 -10 -4 -3 6.96 2.23 10 4 3 4.90 2.35 -10 -4 -3 6.16 2.39 -10 -4 -3 6.97 1.63 -10 4 -3 5.76 1.95 -10 -4 -4 12.49 2.42 10 4 4 14.87 2.85 -10 -4 -4 14.68 2.75 -10 -4 -4 14.84 1.96 -10 4 -4 12.15 1.73 -10 4 -4 13.52 2.19 -10 -4 -4 16.33 1.81 -10 4 -5 28.39 2.45 -10 -4 -5 31.49 3.05 10 4 5 26.37 3.63 10 -4 5 22.86 3.79 -10 -4 -5 30.49 2.52 -10 -4 -5 33.17 3.19 -10 4 -5 28.76 2.32 -10 4 -5 27.78 2.85 -10 -4 -5 29.09 2.37 -10 4 -6 10.38 1.98 -10 -4 -6 11.95 2.62 10 -4 6 11.58 3.25 10 4 6 10.75 2.92 -10 -4 -6 11.54 1.99 -10 4 -6 10.76 2.57 -10 -4 -6 15.53 2.63 -10 4 -6 11.07 1.82 -10 4 -6 12.23 2.34 -10 -4 -6 12.81 1.84 -10 4 -7 137.93 6.96 -10 -4 -7 142.03 7.39 10 -4 7 132.10 9.13 10 4 7 140.60 8.98 -10 -4 -7 151.70 7.16 -10 4 -7 138.46 7.67 -10 -4 -7 154.29 7.82 -10 4 -7 144.77 6.95 -10 -4 -7 156.13 6.96 -10 -4 -8 465.88 21.38 -10 4 -8 479.50 21.02 10 4 8 475.30 23.49 -10 -4 -8 517.41 21.26 -10 4 -8 520.64 21.86 -10 -4 -8 518.11 21.86 -10 4 -8 506.02 21.08 -10 4 -9 3.44 2.04 -10 -4 -9 3.61 2.73 10 4 9 4.36 3.18 -10 -4 -9 4.45 1.88 -10 -4 -9 4.29 2.73 -10 4 -9 -0.18 2.49 -10 4 -10 901.49 38.73 -10 -4 -10 904.58 39.17 -10 -4 -10 916.16 38.88 -10 -4 -10 956.02 39.75 -10 4 -10 974.96 39.26 -10 4 -11 7.35 2.25 -10 -4 -11 7.77 3.05 -10 -4 -11 9.54 3.23 -10 -4 -11 7.04 2.07 -10 4 -11 6.58 2.85 -10 4 -12 237.88 10.85 -10 -4 -12 240.73 11.49 -10 -4 -12 223.27 10.86 -10 -4 -12 245.96 12.05 -10 4 -12 254.44 11.52 -10 4 -13 107.77 5.80 -10 -4 -13 119.29 6.61 -10 -4 -13 123.86 7.30 -10 -4 -13 104.12 5.74 -10 4 -13 123.72 6.56 -10 -4 -14 15.03 3.19 -10 -4 -14 10.12 3.57 -10 4 -14 11.47 2.75 -10 -4 -15 5.86 2.78 -10 4 -15 8.53 3.09 -10 -4 -15 5.46 3.34 -10 -4 -15 4.54 2.73 -10 4 -15 7.32 2.73 -10 -4 -16 1.92 2.52 -10 -4 -16 2.70 3.17 -10 -4 -16 3.21 2.74 -10 4 -16 2.73 2.58 -10 -4 -17 13.30 2.59 -10 -4 -17 11.35 3.21 -10 -4 -17 12.05 2.70 -10 4 -17 16.18 2.62 -10 -4 -18 189.77 8.76 -10 -4 -18 178.93 9.26 -10 4 -18 186.34 8.77 -10 -4 -18 193.83 9.03 -10 -4 -19 100.08 4.93 -10 -4 -19 91.57 5.16 -10 -4 -20 126.34 6.05 10 5 -26 25.76 2.40 10 5 -25 167.53 7.06 10 5 -25 160.26 7.08 10 -5 -24 44.20 3.66 10 -5 -24 45.87 3.34 10 -5 -24 43.08 3.03 10 5 -24 41.05 3.66 10 5 -23 170.44 8.16 10 -5 -23 149.86 7.91 10 -5 -23 142.51 7.51 10 5 -23 150.51 7.88 10 -5 -23 162.76 7.35 10 5 -22 36.80 3.50 10 -5 -22 24.52 3.21 10 -5 -22 28.42 2.78 10 5 -22 27.66 3.46 10 5 -21 57.15 4.31 10 -5 -21 46.95 4.03 10 5 -21 53.09 4.21 10 -5 -21 50.12 3.65 10 5 -20 274.86 12.51 10 -5 -20 249.56 12.31 10 -5 -20 258.65 11.82 10 -5 -19 199.32 9.41 10 5 -19 193.68 9.72 10 -5 -19 170.42 9.56 10 -5 -19 201.55 9.17 10 -5 -18 247.14 11.03 10 5 -18 231.07 11.27 10 -5 -18 214.58 11.19 10 -5 -18 233.38 10.70 10 -5 -17 284.69 12.64 10 5 -17 274.42 12.88 10 -5 -17 258.19 12.83 -10 -5 16 58.39 5.14 10 -5 -16 68.11 4.27 10 5 -16 65.20 4.62 10 -5 -16 61.86 4.58 -10 -5 15 -0.19 2.50 10 -5 -15 -2.92 3.12 10 -5 -15 2.63 1.95 10 5 -15 0.70 3.00 10 -5 -15 3.21 2.49 10 5 -15 1.65 2.49 10 5 -15 0.88 2.52 -10 5 14 12.08 2.72 -10 -5 14 10.87 2.92 10 -5 -14 7.57 2.98 10 -5 -14 10.00 2.16 10 5 -14 4.18 2.83 10 5 -14 10.00 2.59 10 -5 -14 8.43 2.52 10 5 -14 11.88 2.79 -10 5 13 285.04 13.88 -10 -5 13 267.42 13.93 10 -5 -13 290.79 14.48 10 5 -13 281.21 14.25 10 5 -13 287.86 12.80 10 -5 -13 272.72 12.78 10 5 -13 264.32 12.70 -10 5 12 5.91 2.44 -10 -5 12 6.46 2.48 10 -5 -12 6.53 2.79 10 5 -12 3.06 2.45 10 5 -12 7.39 2.33 10 -5 -12 7.33 2.51 10 5 -12 5.48 2.64 -10 5 11 202.33 10.39 -10 -5 11 209.15 10.61 10 -5 -11 216.02 10.75 10 5 -11 220.45 10.70 10 5 -11 206.36 9.30 10 -5 -11 204.08 9.40 10 5 -11 198.58 9.43 -10 5 10 180.49 9.28 -10 -5 10 174.66 9.35 10 -5 -10 170.42 9.14 10 5 -10 184.68 9.28 10 5 -10 181.77 8.37 -10 5 9 562.54 25.54 -10 -5 9 560.04 25.63 10 -5 -9 559.49 25.38 10 5 -9 580.18 25.44 -10 5 8 35.09 3.64 -10 -5 8 30.94 3.55 10 -5 -8 35.46 3.40 10 5 -8 33.97 3.34 -10 5 7 1384.48 58.01 10 -5 -7 1322.45 57.44 10 5 -7 1381.36 57.55 -10 5 6 798.79 34.77 10 -5 -6 780.92 34.12 10 5 -6 799.45 34.18 -10 5 5 1350.13 57.87 -10 -5 5 1344.34 57.89 10 -5 -5 1320.27 57.11 10 5 -5 1420.36 57.24 -10 -5 4 35.86 3.73 10 -5 -4 33.87 2.97 10 5 -4 44.18 3.26 -10 5 3 4.07 2.28 -10 -5 3 4.47 2.32 10 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-6 -26 135.01 6.40 10 6 -26 130.26 6.30 10 6 -26 144.64 6.55 10 -6 -25 30.69 2.69 10 6 -25 33.86 2.76 10 -6 -25 24.80 2.22 10 6 -25 33.33 3.04 10 -6 -24 164.62 8.20 10 -6 -24 173.51 7.89 10 -6 -24 147.72 7.74 10 6 -24 179.31 8.21 10 6 -23 342.34 14.95 10 -6 -23 327.03 14.83 10 -6 -23 310.42 14.58 10 6 -23 338.29 14.80 10 6 -22 131.99 6.86 10 -6 -22 112.27 6.59 10 6 -22 122.27 6.76 10 -6 -22 123.70 6.09 10 6 -21 23.08 3.12 10 -6 -21 16.52 2.97 10 6 -21 18.12 3.26 10 -6 -21 17.83 2.46 10 6 -20 38.08 3.68 10 -6 -20 35.65 3.63 10 -6 -20 39.11 3.41 10 -6 -20 37.20 3.15 10 6 -19 3.10 2.57 10 -6 -19 2.93 2.29 10 -6 -19 0.94 2.60 10 -6 -19 1.46 2.26 10 -6 -18 215.12 10.22 10 6 -18 217.31 10.45 10 -6 -18 195.57 10.29 10 -6 -18 216.75 9.84 10 6 -17 44.08 3.87 10 -6 -17 44.74 3.57 10 -6 -17 35.11 3.67 -10 -6 16 325.71 16.74 10 -6 -16 374.55 15.58 10 6 -16 344.20 15.69 10 -6 -16 325.15 15.63 10 6 -15 9.93 3.38 -10 -6 15 4.70 2.65 10 -6 -15 4.43 3.30 10 -6 -15 7.35 2.21 10 6 -15 9.25 2.66 10 -6 -15 6.45 2.52 10 6 -15 6.93 2.67 -10 6 14 107.45 6.99 -10 -6 14 112.50 7.33 10 -6 -14 115.62 7.94 10 6 -14 113.21 7.70 10 -6 -14 114.73 6.30 10 -6 -14 112.34 6.09 10 6 -14 114.47 6.29 10 6 -14 116.41 6.40 -10 6 13 134.57 7.98 -10 -6 13 121.07 8.15 10 -6 -13 132.32 8.56 10 6 -13 139.36 8.63 10 -6 -13 134.85 7.13 10 6 -13 137.61 7.07 10 6 -13 140.52 7.27 -10 6 12 95.31 6.27 -10 -6 12 94.34 6.46 10 -6 -12 94.72 6.71 10 6 -12 87.20 6.46 10 6 -12 97.38 5.40 10 -6 -12 90.24 5.39 10 6 -12 94.34 5.64 -10 6 11 930.76 37.22 -10 -6 11 863.95 37.21 10 -6 -11 898.56 37.37 10 6 -11 930.81 37.33 10 6 -11 928.49 35.70 10 -6 -11 910.02 35.82 10 6 -11 895.55 35.88 -10 6 10 -0.52 2.09 -10 -6 10 -1.47 2.47 10 -6 -10 1.56 2.27 10 6 -10 -1.53 2.39 -10 -6 10 0.82 1.50 10 6 -10 1.50 2.07 10 6 -10 2.71 2.66 -10 6 9 102.62 6.54 -10 -6 9 95.53 6.53 10 -6 -9 101.78 6.36 10 6 -9 107.46 6.47 -10 -6 9 87.43 4.90 10 6 -9 116.34 6.08 -10 6 8 148.78 8.46 -10 -6 8 145.57 8.54 10 -6 -8 152.00 8.25 10 6 -8 146.11 8.18 10 6 -7 6.49 2.28 -10 6 7 1.66 2.06 10 -6 -7 3.11 1.91 -10 6 6 727.57 31.23 -10 -6 6 675.01 31.13 10 -6 -6 696.30 30.54 10 6 -6 714.64 30.60 -10 6 5 179.70 9.46 -10 -6 5 169.24 9.36 10 -6 -5 159.93 8.64 10 6 -5 181.40 8.83 -10 -6 4 834.65 36.25 10 -6 -4 770.71 35.26 10 6 -4 893.99 35.57 -10 6 3 309.24 15.33 -10 -6 3 323.21 15.38 10 -6 -3 318.90 14.37 -10 6 2 198.16 10.72 -10 -6 2 209.58 10.75 -10 -6 1 136.33 7.88 10 6 0 360.58 17.16 -10 -6 0 385.78 17.61 10 6 1 751.44 33.22 -10 -6 -1 773.83 33.53 10 6 2 60.97 4.61 -10 -6 -2 62.59 4.89 -10 -6 -2 65.90 4.14 -10 -6 -3 49.74 3.65 -10 -6 -3 48.68 4.30 10 6 3 51.31 4.30 -10 -6 -3 52.23 3.30 -10 -6 -3 50.79 3.22 -10 6 -3 53.22 3.62 -10 -6 -4 6.91 2.37 10 6 4 3.00 2.19 -10 -6 -4 6.33 1.82 -10 6 -4 7.97 2.27 -10 -6 -4 6.98 1.62 -10 -6 -5 17.99 2.76 10 6 5 11.92 2.71 -10 -6 -5 15.81 2.11 -10 -6 -5 20.64 2.76 -10 6 -5 13.20 2.49 -10 -6 -5 12.98 1.94 -10 -6 -6 12.86 2.66 10 6 6 10.76 2.76 -10 -6 -6 11.54 2.12 -10 -6 -6 12.86 2.55 -10 -6 -6 11.55 1.89 -10 -6 -7 147.56 7.79 10 6 7 153.01 9.22 -10 -6 -7 162.07 7.63 -10 -6 -7 149.16 8.03 -10 -6 -7 160.56 7.40 -10 -6 -8 100.17 6.07 10 6 8 101.98 7.41 -10 -6 -8 109.47 5.79 -10 -6 -8 113.13 6.36 -10 -6 -8 112.25 5.51 -10 6 -8 106.81 6.09 -10 -6 -9 56.24 4.43 -10 -6 -9 57.81 3.80 -10 -6 -9 59.05 4.58 -10 6 -9 56.90 4.37 -10 -6 -10 280.10 13.41 -10 -6 -10 287.60 13.05 -10 6 -10 285.71 13.72 -10 -6 -10 288.05 13.83 -10 6 -10 306.70 13.52 -10 -6 -11 673.77 29.81 -10 -6 -11 674.16 29.47 -10 6 -11 691.56 30.13 -10 -6 -11 701.70 30.32 -10 6 -11 738.15 29.95 -10 -6 -12 103.63 6.48 -10 -6 -12 108.81 5.86 -10 6 -12 117.46 6.82 -10 -6 -12 108.33 6.84 -10 6 -12 118.88 6.51 -10 -6 -13 11.92 3.17 -10 -6 -13 9.66 2.09 -10 6 -13 11.40 3.20 -10 -6 -13 14.89 3.60 -10 6 -13 11.23 2.80 -10 -6 -14 65.61 4.62 -10 -6 -14 63.31 5.08 -10 6 -14 71.77 4.51 -10 -6 -15 5.33 2.79 -10 -6 -15 4.76 3.04 -10 6 -15 5.18 2.46 -10 -6 -16 5.80 2.61 -10 -6 -16 6.33 3.00 -10 -6 -16 1.62 2.77 -10 6 -16 3.50 2.36 -10 -6 -17 44.60 3.56 -10 -6 -17 47.71 4.08 -10 -6 -17 45.28 3.85 -10 6 -17 46.01 3.40 -10 -6 -18 100.61 5.28 -10 -6 -18 92.61 5.60 -10 -6 -18 103.36 5.57 -10 -6 -19 161.70 7.48 -10 -6 -19 161.19 7.72 -10 -6 -20 368.42 15.78 10 -7 -26 3.08 1.66 10 7 -26 1.14 2.02 10 -7 -25 4.84 1.97 10 7 -25 3.99 1.91 10 -7 -25 2.37 1.56 10 7 -25 5.23 2.39 10 -7 -24 195.96 8.99 10 -7 -24 187.65 9.02 10 7 -24 200.47 9.32 10 -7 -23 36.26 3.38 10 7 -23 35.10 3.63 10 7 -22 36.32 3.51 10 -7 -22 37.47 3.45 10 7 -22 37.28 3.86 10 7 -21 28.54 3.32 10 -7 -21 25.05 3.21 10 -7 -21 27.78 2.68 10 7 -21 35.83 3.67 10 7 -20 755.49 31.91 10 -7 -20 688.80 31.80 10 -7 -20 772.52 31.88 10 -7 -20 754.11 31.32 10 7 -19 133.56 7.10 10 -7 -19 123.30 7.00 10 -7 -19 129.03 6.95 10 -7 -18 337.14 15.32 10 7 -18 350.71 15.46 10 -7 -18 323.22 15.39 10 -7 -17 3.57 2.32 10 -7 -17 2.13 2.59 10 7 -17 3.43 2.50 -10 -7 16 14.93 3.27 10 -7 -16 16.96 2.90 10 7 -16 19.01 2.89 10 -7 -16 17.32 2.52 -10 -7 15 258.16 14.17 10 -7 -15 300.14 13.04 10 7 -15 281.67 13.05 10 -7 -15 276.93 13.07 10 7 -15 282.31 13.15 10 7 -14 1.58 2.59 -10 -7 14 1.60 2.55 10 -7 -14 4.25 3.11 10 7 -14 2.61 2.22 10 -7 -14 6.11 2.36 10 7 -14 3.24 2.69 -10 7 13 102.54 6.65 -10 -7 13 101.09 6.85 10 -7 -13 106.13 7.27 10 7 -13 95.96 6.92 10 7 -13 103.90 5.66 10 -7 -13 101.45 5.81 10 7 -13 103.96 6.00 10 7 -12 6.18 2.85 -10 7 12 9.75 2.64 -10 -7 12 7.26 2.80 10 -7 -12 7.48 2.93 10 7 -12 7.41 2.29 10 -7 -12 8.55 2.41 10 7 -12 8.58 2.85 -10 7 11 80.18 5.73 -10 -7 11 89.32 6.11 10 -7 -11 89.33 6.08 10 7 -11 88.86 5.95 10 7 -11 86.67 4.73 10 -7 -11 84.37 4.87 -10 -7 11 67.94 4.10 10 7 -11 77.18 5.18 10 7 -10 8.55 2.65 -10 7 10 12.96 2.81 -10 -7 10 11.36 2.89 10 -7 -10 11.11 2.62 -10 -7 10 12.79 1.76 10 7 -10 15.21 2.36 10 7 -10 12.50 3.08 -10 7 9 104.84 6.45 -10 -7 9 103.49 6.59 10 -7 -9 94.67 6.18 10 7 -9 102.29 6.29 -10 -7 9 81.50 4.73 10 7 -9 107.43 5.96 -10 7 8 435.77 20.65 -10 -7 8 428.17 20.75 10 -7 -8 456.41 20.49 10 7 -8 457.67 20.44 -10 7 7 121.29 7.30 10 -7 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8.18 10 9 -22 64.80 4.20 10 -9 -22 62.15 4.23 10 9 -21 33.16 3.20 10 -9 -21 27.69 3.18 10 9 -20 263.65 11.72 10 -9 -20 236.77 11.64 10 -9 -20 246.24 11.70 10 9 -19 26.05 3.01 10 -9 -19 22.56 3.10 10 -9 -19 17.70 2.88 10 -9 -18 18.16 2.83 10 9 -18 16.29 2.86 10 -9 -18 14.31 3.04 10 -9 -17 6.87 2.43 10 9 -17 7.75 2.59 10 -9 -17 6.15 2.74 -10 -9 16 1.68 2.69 10 -9 -16 4.30 2.52 10 -9 -16 7.45 2.28 10 9 -16 6.36 2.53 -10 -9 15 152.29 9.40 10 -9 -15 162.57 8.08 10 9 -15 155.07 7.95 10 -9 -15 158.65 8.02 10 9 -14 12.75 3.49 -10 -9 14 10.30 3.10 10 -9 -14 11.01 3.60 10 9 -14 11.20 2.43 10 -9 -14 14.03 2.63 -10 -9 13 256.75 13.84 10 -9 -13 296.16 14.44 10 9 -13 261.98 13.99 10 -9 -13 266.75 12.34 10 9 -13 264.12 12.18 10 9 -12 2.71 2.79 -10 -9 12 5.47 2.82 10 -9 -12 5.04 2.74 10 9 -12 6.85 2.15 10 -9 -12 8.07 2.37 10 9 -11 6.08 2.86 -10 -9 11 3.32 2.62 10 -9 -11 6.16 2.79 10 9 -11 8.88 2.14 10 -9 -11 10.99 2.46 -10 -9 11 6.85 1.75 10 9 -10 4.23 2.53 -10 -9 10 4.08 2.63 10 -9 -10 2.29 2.52 -10 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3.70 10 11 -14 44.32 4.22 10 11 -13 43.02 4.99 -10 -11 13 46.18 4.92 10 -11 -13 43.24 5.06 10 -11 -13 47.82 3.60 10 11 -13 42.05 3.30 10 11 -13 50.87 4.34 10 11 -12 22.47 3.99 -10 -11 12 29.93 4.05 10 -11 -12 32.25 4.17 10 11 -12 26.90 2.68 10 -11 -12 31.70 2.99 10 11 -12 32.16 3.75 10 11 -11 7.09 3.04 -10 -11 11 12.00 3.13 10 -11 -11 2.63 2.63 10 -11 -11 8.24 2.29 -10 -11 11 3.08 1.54 10 11 -11 7.33 3.17 10 11 -10 3.53 2.72 10 -11 -10 4.14 2.71 10 -11 -10 7.24 2.20 -10 -11 10 5.20 1.69 10 11 -10 5.20 3.22 10 11 -9 0.92 2.45 -10 -11 9 1.68 1.63 10 11 -9 4.84 3.12 -10 -11 9 2.40 1.40 10 11 -8 310.08 15.23 -10 -11 8 293.21 13.62 10 11 -8 343.85 14.76 -10 -11 8 318.79 13.62 10 11 -7 6.42 2.47 -10 -11 7 8.23 2.02 10 11 -7 9.86 3.29 -10 -11 7 4.41 1.47 10 11 -6 169.18 9.18 -10 -11 6 171.86 9.98 -10 -11 6 170.43 8.06 10 11 -6 176.32 8.95 -10 -11 6 166.46 7.86 10 11 -5 28.73 3.38 -10 -11 5 20.21 3.59 10 11 -5 29.88 3.67 -10 -11 5 26.80 2.28 10 11 -4 142.43 7.59 -10 -11 4 137.90 8.26 -10 -11 4 136.90 6.29 -10 -11 3 65.60 5.34 10 11 -3 55.92 3.62 -10 -11 3 67.43 3.71 -10 -11 2 6.85 3.02 -10 -11 2 7.97 2.11 -10 -11 1 20.46 3.21 -10 -11 1 24.18 3.84 -10 -11 1 20.24 2.84 -10 -11 1 19.05 2.76 -10 -11 0 2.51 2.65 -10 -11 0 4.55 3.02 -10 -11 -1 48.02 3.55 -10 -11 -1 49.73 4.52 -10 -11 -1 46.75 3.23 -10 -11 -1 48.64 3.27 -10 -11 -2 555.59 23.69 -10 -11 -2 525.46 24.93 -10 -11 -2 547.76 23.61 -10 -11 -2 562.42 23.57 -10 -11 -3 86.38 4.91 -10 -11 -3 83.13 4.68 -10 -11 -3 74.78 4.52 -10 -11 -4 44.38 3.60 -10 -11 -4 42.63 3.13 -10 -11 -5 2255.87 94.50 -10 -11 -5 2198.67 94.53 -10 -11 -5 2305.73 94.42 -10 11 -5 2396.64 94.65 -10 -11 -6 112.42 5.26 -10 -11 -6 119.92 5.28 -10 -11 -6 112.20 4.84 -10 11 -6 126.70 5.32 -10 -11 -7 2478.96 104.05 -10 -11 -7 2544.96 104.16 -10 -11 -7 2441.47 103.86 -10 11 -7 2633.85 104.14 -10 -11 -8 18.48 3.27 -10 -11 -8 21.69 3.07 -10 -11 -8 20.17 3.02 -10 -11 -8 21.56 2.58 -10 11 -8 25.07 3.23 -10 -11 -9 6.43 2.60 -10 -11 -9 4.98 2.62 -10 -11 -9 5.02 1.91 -10 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610.14 26.39 10 12 -18 43.01 3.32 10 -12 -18 43.52 3.46 10 -12 -18 39.52 3.65 10 -12 -18 39.36 2.88 10 12 -17 789.24 33.26 10 -12 -17 804.31 33.52 10 -12 -17 809.23 33.57 10 -12 -17 756.36 33.06 10 -12 -16 406.60 17.07 10 12 -16 365.24 16.67 10 -12 -16 373.72 16.95 -10 -12 15 349.31 18.44 10 -12 -15 376.39 16.70 10 12 -15 367.38 16.40 10 -12 -15 367.21 16.64 10 12 -15 400.12 17.10 -10 -12 14 1009.30 45.90 10 12 -14 980.64 43.56 10 -12 -14 1102.10 43.97 10 -12 -14 1037.13 43.83 10 12 -14 1094.76 44.23 10 12 -13 2.86 2.92 -10 -12 13 0.96 3.20 10 -12 -13 3.76 3.09 10 -12 -13 4.64 2.25 10 12 -13 2.50 2.91 10 12 -12 307.49 15.69 10 -12 -12 312.94 15.97 10 -12 -12 298.53 13.78 10 12 -12 311.30 14.33 10 12 -11 0.22 2.67 10 -12 -11 1.60 3.07 10 -12 -11 -0.31 2.01 -10 -12 11 -1.50 1.59 10 12 -11 -0.21 3.20 10 12 -10 6.47 2.95 10 -12 -10 3.88 2.75 10 -12 -10 5.00 2.19 -10 -12 10 5.66 1.66 10 12 -10 6.60 3.22 10 12 -9 50.30 4.68 -10 -12 9 49.83 3.18 10 12 -9 49.90 4.53 -10 -12 9 53.67 3.11 10 12 -8 9.04 2.81 -10 -12 8 13.62 2.00 10 12 -8 14.70 3.52 -10 -12 8 8.76 1.71 10 12 -7 219.82 11.49 -10 -12 7 213.61 10.04 10 12 -7 241.65 11.10 -10 -12 7 222.79 10.00 10 12 -6 55.16 4.56 -10 -12 6 55.84 3.58 10 12 -6 53.70 4.46 -10 -12 6 56.10 3.34 10 12 -5 309.21 14.34 10 12 -5 273.60 13.45 -10 -12 5 296.53 12.88 10 12 -4 16.67 3.06 -10 -12 4 19.11 3.51 10 12 -4 12.12 2.74 -10 -12 4 21.59 2.12 -10 -12 3 978.99 37.88 -10 -12 3 1015.72 35.51 -10 -12 2 72.54 5.84 -10 -12 2 77.48 4.30 10 12 -2 77.02 3.88 -10 -12 2 79.10 4.28 -10 -12 1 395.95 14.79 -10 -12 1 369.12 16.53 -10 -12 1 364.94 14.56 -10 -12 1 360.79 14.54 -10 -12 0 31.63 4.45 -10 -12 0 29.52 4.94 -10 -12 0 36.03 4.23 -10 -12 -1 514.72 21.78 -10 -12 -1 485.88 23.20 -10 -12 -1 490.44 21.68 -10 -12 -1 516.85 21.67 -10 -12 -2 26.03 2.86 -10 -12 -2 25.23 3.41 -10 -12 -2 19.82 2.44 -10 -12 -2 23.48 2.51 -10 -12 -3 143.79 7.11 -10 -12 -3 132.42 7.02 -10 -12 -3 143.39 6.97 -10 -12 -4 200.17 9.60 -10 -12 -4 205.86 9.55 -10 -12 -5 95.46 5.54 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100.00 5.19 10 13 -23 107.75 5.77 10 -13 -22 54.44 3.61 10 -13 -22 52.95 3.48 10 13 -22 55.92 4.23 10 -13 -21 399.55 18.27 10 -13 -21 422.22 18.14 10 13 -21 446.41 18.67 10 -13 -20 34.79 3.09 10 -13 -20 28.92 3.06 10 -13 -19 605.64 25.74 10 13 -19 586.66 25.35 10 -13 -19 595.92 25.59 10 -13 -18 17.06 2.66 10 13 -18 17.88 2.44 10 -13 -18 20.28 2.78 10 -13 -18 13.99 2.04 10 -13 -17 117.68 6.48 10 -13 -17 128.38 6.59 10 -13 -17 113.62 6.00 10 -13 -16 7.59 2.34 10 -13 -16 7.22 2.43 10 -13 -16 7.03 1.98 -10 -13 15 19.83 4.10 10 -13 -15 22.47 2.94 10 -13 -15 18.96 2.94 10 13 -15 27.51 3.86 -10 -13 14 157.14 10.20 10 -13 -14 166.80 8.46 10 -13 -14 171.81 8.43 10 13 -14 181.79 9.02 -10 -13 13 253.14 14.11 10 -13 -13 260.11 12.01 10 13 -13 265.21 12.51 10 13 -12 385.32 18.88 10 -13 -12 386.88 19.12 10 -13 -12 375.16 16.77 10 13 -12 380.34 17.27 10 13 -11 39.89 4.63 10 -13 -11 38.71 4.40 10 -13 -11 37.22 3.00 10 13 -11 33.30 3.83 10 13 -10 430.56 19.24 10 -13 -10 408.18 17.24 -10 -13 10 361.88 16.73 10 13 -10 420.30 17.88 10 13 -9 4.88 2.78 -10 -13 9 5.43 1.67 10 13 -9 7.50 3.29 10 13 -8 29.01 3.71 -10 -13 8 32.65 2.56 10 13 -8 31.21 3.88 -10 -13 8 29.31 2.44 10 13 -7 56.81 4.90 -10 -13 7 60.69 3.67 10 13 -7 68.43 4.87 -10 -13 7 56.53 3.50 10 13 -6 179.35 9.73 -10 -13 6 176.19 8.33 10 13 -6 182.89 9.17 -10 -13 6 176.03 8.30 10 13 -5 8.44 2.79 10 13 -5 5.70 2.99 -10 -13 5 8.81 1.73 -10 -13 4 545.49 24.74 -10 -13 4 534.31 22.27 10 13 -4 480.02 22.59 -10 -13 4 535.52 22.31 -10 -13 3 9.36 3.22 -10 -13 3 14.32 1.88 -10 -13 3 10.63 1.98 10 13 -3 8.04 2.29 -10 -13 2 7.37 2.89 -10 -13 2 6.31 1.73 -10 -13 2 7.96 1.81 -10 -13 1 43.39 5.12 -10 -13 1 39.45 3.84 -10 -13 1 43.33 3.94 -10 -13 0 23.61 3.98 -10 -13 0 17.15 4.47 -10 -13 0 26.91 3.87 -10 -13 -1 472.78 19.81 -10 -13 -1 436.10 21.30 -10 -13 -1 439.63 19.71 -10 -13 -1 466.23 19.73 -10 -13 -2 6.71 2.34 -10 -13 -2 7.49 2.05 -10 -13 -2 7.23 2.08 -10 -13 -3 226.63 10.37 -10 -13 -3 205.58 10.26 -10 -13 -3 233.93 10.33 -10 -13 -4 483.50 20.33 -10 -13 -4 451.61 20.35 -10 -13 -4 463.86 20.28 -10 -13 -5 46.83 3.72 -10 -13 -5 41.46 3.50 -10 -13 -6 1669.56 68.74 -10 -13 -6 1625.87 68.90 -10 -13 -6 1663.16 68.72 -10 -13 -7 206.77 9.75 -10 -13 -7 198.45 9.91 -10 -13 -7 195.85 9.56 -10 -13 -8 51.96 4.13 -10 -13 -8 45.81 4.04 -10 -13 -8 48.06 3.56 -10 -13 -9 16.30 3.12 -10 -13 -9 17.16 3.04 -10 -13 -9 18.78 2.49 -10 -13 -10 92.97 5.60 -10 -13 -10 96.18 5.70 -10 -13 -10 90.06 5.11 -10 -13 -11 51.98 3.97 -10 -13 -11 45.81 3.78 -10 -13 -11 43.50 3.65 -10 -13 -12 41.20 3.57 -10 -13 -12 34.80 3.32 -10 -13 -12 37.51 3.31 -10 -13 -13 5.54 2.48 -10 -13 -13 6.77 2.29 -10 -13 -13 5.54 2.22 -10 -13 -14 19.34 2.46 -10 -13 -14 20.59 2.51 -10 -13 -15 3.15 1.80 -10 -13 -15 2.27 1.83 -10 -13 -16 2.32 1.50 -10 -13 -16 4.13 1.75 -10 -13 -16 5.43 2.59 -10 -13 -17 99.47 5.43 -10 -13 -19 136.14 6.16 10 -14 -25 1.44 1.32 10 14 -25 1.17 1.63 10 -14 -24 25.23 2.08 10 -14 -24 24.34 2.30 10 14 -24 27.26 2.68 10 -14 -23 3.73 1.79 10 14 -23 3.33 2.45 10 -14 -22 66.89 4.15 10 -14 -22 76.13 4.14 10 14 -22 78.09 4.83 10 -14 -21 19.45 2.49 10 -14 -21 20.31 2.40 10 14 -21 21.42 3.25 10 -14 -20 125.33 6.32 10 -14 -20 117.23 6.40 10 -14 -19 481.48 20.14 10 -14 -19 468.87 19.94 10 -14 -19 437.58 19.51 10 -14 -18 281.24 12.65 10 -14 -18 279.18 12.55 10 -14 -18 265.02 12.14 10 -14 -17 1094.06 45.61 10 -14 -17 1116.31 45.74 10 -14 -17 1058.33 45.32 10 -14 -16 24.74 2.92 10 -14 -16 20.94 2.93 10 -14 -16 22.61 2.45 10 -14 -15 1578.86 64.69 10 -14 -15 1526.27 64.58 -10 -14 14 9.87 3.46 10 -14 -14 13.56 2.62 10 -14 -14 17.09 2.73 10 14 -14 15.91 3.54 10 -14 -13 491.30 21.75 10 14 -13 517.09 22.26 10 -14 -12 71.21 4.46 10 14 -12 70.38 5.35 10 14 -11 184.03 9.99 10 -14 -11 187.94 7.91 10 14 -11 199.68 8.75 10 14 -10 160.62 9.27 10 -14 -10 142.38 7.32 -10 -14 10 145.60 6.91 10 14 -10 152.75 8.12 10 14 -9 6.66 3.06 -10 -14 9 5.55 1.75 10 -14 -9 2.06 2.14 10 14 -9 7.00 3.09 10 14 -8 6.30 2.91 -10 -14 8 8.13 1.88 10 14 -8 7.51 3.16 -10 -14 8 6.53 1.69 10 14 -7 6.93 2.73 -10 -14 7 7.49 1.94 10 14 -7 7.05 3.08 -10 -14 7 5.67 1.69 10 14 -6 106.83 6.92 -10 -14 6 106.26 5.48 10 14 -6 109.28 6.43 -10 -14 6 104.88 5.46 10 14 -5 -0.18 2.58 10 14 -5 -2.27 3.21 -10 -14 5 1.98 1.64 -10 -14 4 762.91 30.77 10 14 -4 666.69 31.07 -10 -14 4 743.03 30.79 -10 -14 3 48.10 4.90 -10 -14 3 50.00 3.16 -10 -14 3 44.29 3.11 -10 -14 2 421.83 17.96 -10 -14 2 416.32 15.50 -10 -14 2 410.75 15.45 -10 -14 1 145.71 9.02 -10 -14 1 155.69 7.33 10 14 -1 147.81 6.70 -10 -14 1 147.65 7.27 -10 -14 0 177.07 10.06 -10 -14 0 158.64 11.29 -10 -14 0 161.09 9.93 -10 -14 -1 730.53 26.20 -10 -14 -1 689.86 28.10 -10 -14 -1 678.48 26.15 -10 -14 -2 313.49 13.65 -10 -14 -2 287.57 13.55 -10 -14 -2 308.57 13.63 -10 -14 -3 29.30 3.02 -10 -14 -3 24.82 2.80 -10 -14 -3 31.25 2.91 -10 -14 -4 22.80 2.90 -10 -14 -4 22.53 2.84 -10 -14 -4 19.47 2.68 -10 -14 -5 65.11 4.26 -10 -14 -5 56.96 4.08 -10 -14 -6 55.75 4.14 -10 -14 -6 54.11 3.98 -10 -14 -7 -0.49 2.56 -10 -14 -7 -0.98 2.81 -10 -14 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62.52 4.96 -10 -20 2 67.44 4.29 -10 -20 1 2660.60 120.59 -10 -20 1 2956.00 118.40 10 20 -1 2817.10 118.55 -10 -20 1 2917.79 118.48 -10 -20 0 157.84 7.43 -10 -20 0 150.26 7.47 -10 -20 -1 839.39 30.38 -10 -20 -1 770.69 30.30 -10 -20 -2 272.29 10.69 10 20 2 194.27 9.78 -10 -20 -3 65.21 4.79 -10 -20 -3 52.38 4.87 -10 -20 -3 62.78 4.92 -10 -20 -4 15.27 3.27 -10 -20 -4 10.84 3.37 -10 -20 -4 12.71 3.42 -10 -20 -5 39.20 5.38 -10 -20 -5 41.08 5.54 -10 -20 -5 47.80 5.61 -10 -20 -6 73.69 7.55 -10 -20 -6 67.18 7.71 -10 -20 -6 69.19 7.60 -10 -20 -7 31.91 5.34 -10 -20 -7 37.15 5.54 -10 -20 -8 40.90 7.14 -10 -20 -8 37.97 7.12 -10 -20 -9 60.03 8.56 -10 -20 -9 52.02 8.52 -10 -20 -10 645.11 25.56 -10 -20 -10 578.68 25.70 -10 -20 -10 569.90 25.51 -10 -20 -11 40.46 5.61 -10 -20 -11 35.32 5.46 -10 -20 -12 71.87 9.39 -10 -20 -12 66.91 9.43 -10 -20 -13 76.43 8.98 -10 -20 -13 67.82 9.00 -10 -20 -14 5.82 3.58 -10 -20 -14 5.17 3.58 -10 -20 -15 148.34 7.86 -10 -20 -15 127.79 7.86 -10 -20 -15 135.02 7.91 -10 -20 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34.72 2.79 10 -22 -18 40.58 2.64 10 -22 -17 0.96 1.20 10 -22 -17 -1.23 1.75 10 -22 -17 1.27 1.61 10 -22 -16 69.54 4.28 10 -22 -16 77.66 4.27 10 -22 -15 41.12 3.18 10 -22 -15 44.28 3.22 10 -22 -14 14.14 2.20 10 -22 -14 12.61 2.29 10 -22 -13 65.34 4.20 10 -22 -13 74.83 4.41 10 -22 -12 243.14 11.14 10 -22 -12 240.63 11.10 10 22 -12 240.94 11.18 10 22 -11 156.67 7.82 10 22 -10 606.98 26.04 10 22 -9 18.38 2.90 10 22 -8 34.35 3.52 -10 -22 8 37.92 2.93 10 22 -7 13.55 2.86 -10 -22 7 13.67 2.28 10 22 -6 277.28 13.22 -10 -22 6 298.07 13.04 10 22 -5 9.28 2.90 -10 -22 5 12.27 2.36 10 22 -4 1066.39 43.96 -10 -22 4 1022.42 43.75 10 22 -3 61.06 4.57 -10 -22 3 58.21 4.04 -10 -22 2 1700.11 79.75 -10 -22 2 1864.09 77.46 10 22 -2 1950.91 77.84 -10 -22 2 1878.87 77.62 -10 -22 1 346.39 15.05 10 22 -1 333.97 15.44 -10 -22 1 334.43 15.19 -10 -22 0 1155.68 48.29 10 22 0 1126.81 48.43 -10 -22 0 1177.58 48.41 -10 -22 -1 88.90 5.02 -10 -22 -1 97.86 5.39 -10 -22 -2 91.98 5.17 10 22 2 81.41 5.08 -10 -22 -3 46.12 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6.28 10 -26 -7 13.32 2.26 -10 -26 7 9.63 1.95 10 -26 -6 19.72 2.51 -10 -26 6 21.38 2.34 -10 -26 5 36.92 2.93 -10 -26 4 197.30 9.27 -10 -26 3 2.24 1.91 -10 -26 2 177.97 8.54 -10 -26 1 192.89 9.11 -10 -26 1 208.08 9.49 -10 -26 0 6.22 1.88 -10 -26 0 7.76 2.29 -10 -26 -1 21.57 2.37 -10 -26 -1 24.16 2.69 -10 -26 -2 28.69 2.75 -10 -26 -2 34.08 3.03 -10 -26 -3 45.93 3.33 -10 -26 -4 3.32 1.95 -10 -26 -4 4.55 2.03 -10 -26 -5 79.98 4.56 -10 -26 -5 77.32 4.51 -10 -26 -6 12.22 2.23 -10 -26 -6 9.71 2.07 -10 -26 -7 2.07 1.79 -10 -26 -7 2.73 1.73 -10 -26 -8 9.12 1.95 -10 -26 -8 5.59 1.70 -10 -26 -9 28.05 2.44 -10 -26 -9 29.44 2.30 -10 -26 -10 31.00 2.27 -10 -26 -11 6.80 1.27 -10 -26 -12 -0.11 1.25 -10 -26 -13 18.51 1.57 10 -27 -18 270.11 11.52 10 -27 -17 2.05 0.94 10 -27 -17 2.41 1.33 10 -27 -16 54.48 3.09 10 -27 -16 51.04 2.79 10 -27 -15 7.38 1.56 10 -27 -15 7.82 1.39 10 -27 -15 8.60 1.71 10 -27 -14 -0.14 1.36 10 -27 -14 -0.78 1.51 10 -27 -14 -0.27 1.61 10 -27 -13 -1.53 1.51 10 -27 -12 21.96 2.15 10 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86.04 4.49 -11 -20 3 63.25 6.60 -11 -20 3 81.48 4.67 11 20 -3 84.48 5.51 -11 -20 3 66.93 4.81 -11 -20 2 263.59 14.19 -11 -20 2 266.73 11.96 11 20 -2 253.77 12.43 -11 -20 2 260.73 12.12 -11 -20 1 32.17 2.97 -11 -20 1 33.43 3.28 11 20 -1 28.19 3.81 -11 -20 0 503.76 21.25 11 20 0 466.23 21.33 -11 -20 0 493.48 21.38 -11 -20 -1 481.91 19.24 11 20 1 396.99 18.92 -11 -20 -2 507.36 18.56 11 20 2 360.80 17.81 -11 -20 -3 124.84 6.09 -11 -20 -3 126.08 6.17 -11 -20 -4 23.56 3.70 -11 -20 -4 22.51 3.67 -11 -20 -5 85.98 6.23 -11 -20 -5 74.03 6.38 -11 -20 -5 81.29 6.43 -11 -20 -6 83.36 6.97 -11 -20 -6 80.03 7.20 -11 -20 -6 77.25 7.08 -11 -20 -7 12.77 3.64 -11 -20 -7 14.22 3.88 -11 -20 -7 13.65 3.70 -11 -20 -8 11.26 4.29 -11 -20 -8 13.39 4.22 -11 -20 -9 99.15 8.07 -11 -20 -9 81.38 8.10 -11 -20 -9 85.36 8.00 -11 -20 -10 1.97 2.97 -11 -20 -10 1.40 2.61 -11 -20 -11 22.37 3.76 -11 -20 -11 24.34 3.85 -11 -20 -12 598.58 20.27 -11 -20 -12 531.86 20.36 -11 -20 -13 4.96 2.22 -11 -20 -13 4.25 2.21 -11 -20 -13 4.55 2.16 -11 -20 -14 868.28 28.40 -11 -20 -14 842.14 28.26 11 -21 -22 -0.83 1.20 11 21 -21 16.41 1.74 11 -21 -20 0.09 0.94 11 21 -20 1.56 1.64 11 -21 -19 46.70 2.77 11 21 -19 52.13 3.22 11 -21 -18 5.59 1.76 11 -21 -18 5.35 1.50 11 -21 -17 77.25 4.55 11 -21 -17 86.83 4.42 11 -21 -16 193.56 9.07 11 -21 -16 194.68 8.96 11 -21 -15 54.05 3.58 11 -21 -15 52.49 3.52 11 -21 -14 13.69 2.19 11 -21 -14 11.32 2.28 11 -21 -13 146.78 7.31 11 -21 -13 148.72 7.35 11 21 -13 145.22 7.47 11 -21 -12 444.46 18.96 11 21 -12 421.54 18.97 11 21 -11 1.49 2.60 11 21 -10 609.64 26.26 11 21 -9 67.56 4.71 11 21 -8 104.75 6.19 -11 -21 8 111.05 5.78 11 21 -7 49.94 4.26 -11 -21 7 56.29 3.76 11 21 -6 105.23 6.20 -11 -21 6 103.30 5.72 11 21 -5 215.53 10.37 -11 -21 5 205.86 9.97 11 21 -4 1240.23 50.35 -11 -21 4 1159.39 50.06 -11 -21 3 199.27 8.78 -11 -21 3 185.33 8.88 11 21 -3 189.86 9.56 -11 -21 3 176.83 9.10 -11 -21 2 605.13 25.83 11 21 -2 629.00 26.35 -11 -21 2 583.38 25.99 -11 -21 1 568.48 23.89 11 21 -1 547.17 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-18 47.82 3.02 11 -22 -18 41.89 2.74 11 -22 -17 27.23 2.46 11 -22 -17 29.16 2.34 11 -22 -16 41.04 3.05 11 -22 -16 46.24 3.07 11 -22 -15 15.57 2.14 11 -22 -15 12.73 2.14 11 -22 -14 79.11 4.58 11 -22 -14 82.41 4.62 11 -22 -13 342.39 15.09 11 -22 -13 338.82 15.07 11 -22 -12 263.60 11.53 11 -22 -12 247.90 11.48 11 22 -12 241.74 11.50 11 22 -11 16.88 2.81 11 22 -10 65.75 4.46 11 22 -9 95.27 5.60 11 22 -8 386.60 17.49 -11 -22 8 400.86 17.24 11 22 -7 131.23 7.16 -11 -22 7 138.49 6.89 11 22 -6 60.36 4.55 -11 -22 6 65.72 4.13 11 22 -5 94.38 5.87 -11 -22 5 103.02 5.55 11 22 -4 25.62 3.51 -11 -22 4 24.00 2.90 -11 -22 3 68.54 4.10 11 22 -3 72.99 5.01 -11 -22 3 62.64 4.34 -11 -22 2 8.02 2.09 11 22 -2 12.53 3.21 -11 -22 2 7.07 2.42 -11 -22 1 154.43 7.65 11 22 -1 154.85 8.20 -11 -22 1 158.07 7.91 -11 -22 0 115.69 5.93 11 22 0 112.56 6.36 -11 -22 0 98.33 5.95 -11 -22 -1 351.67 15.46 11 22 1 349.31 15.58 -11 -22 -1 335.36 15.56 -11 -22 -2 68.38 4.36 11 22 2 62.83 4.41 -11 -22 -3 270.14 11.94 11 22 3 234.07 11.56 -11 -22 -3 269.15 11.99 -11 -22 -4 76.33 4.56 -11 -22 -4 74.96 4.61 -11 -22 -5 48.85 3.64 -11 -22 -5 49.21 3.55 -11 -22 -6 160.24 6.87 -11 -22 -6 158.67 6.88 -11 -22 -7 3.04 2.29 -11 -22 -7 4.28 2.12 -11 -22 -8 5.88 2.37 -11 -22 -8 4.30 2.15 11 22 9 28.32 1.72 -11 -22 -9 2.60 2.02 -11 -22 -10 6.99 2.05 -11 -22 -10 2.14 1.70 -11 -22 -11 137.63 5.80 -11 -22 -11 132.13 5.51 -11 -22 -11 132.08 5.47 -11 -22 -12 19.21 2.05 -11 -22 -12 19.88 1.85 11 22 12 14.75 1.60 -11 -22 -13 926.17 33.12 -11 -22 -13 854.13 32.87 -11 -22 -14 269.24 11.52 11 -23 -21 2.98 1.10 11 -23 -19 7.18 1.26 11 23 -19 8.34 1.58 11 -23 -18 14.19 1.86 11 -23 -18 14.56 1.70 11 23 -18 15.05 1.98 11 -23 -17 -0.58 1.55 11 -23 -17 0.74 1.13 11 -23 -17 -2.23 1.56 11 -23 -16 9.79 1.91 11 -23 -16 8.28 1.82 11 -23 -15 360.02 15.96 11 -23 -15 372.01 15.95 11 -23 -14 7.08 1.84 11 -23 -14 5.57 1.99 11 -23 -13 10.93 2.01 11 -23 -13 11.13 2.27 11 -23 -12 3.74 1.85 11 -23 -12 2.46 2.13 11 23 -12 2.61 2.22 11 -23 -11 176.74 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2.70 11 23 10 32.82 2.42 -11 -23 -11 199.26 8.35 -11 -23 -11 188.77 8.04 -11 -23 -11 196.89 8.09 -11 -23 -12 6.13 1.56 -11 -23 -12 5.85 1.24 -11 -23 -13 141.62 6.48 11 -24 -19 333.47 14.09 11 -24 -18 3.95 1.33 11 24 -18 6.17 1.49 11 -24 -17 20.48 2.05 11 -24 -17 18.83 1.57 11 -24 -17 20.26 1.96 11 -24 -16 29.05 2.41 11 -24 -16 30.56 2.43 11 -24 -15 37.06 2.68 11 -24 -15 32.28 2.65 11 -24 -14 8.24 1.88 11 -24 -14 10.08 1.99 11 -24 -13 367.41 16.16 11 -24 -13 374.00 16.21 11 -24 -12 67.22 4.00 11 -24 -11 252.97 11.01 11 24 -11 229.88 10.90 11 -24 -10 245.10 10.95 11 24 -10 230.35 10.83 11 24 -9 356.50 15.71 11 24 -8 325.41 15.00 -11 -24 8 350.01 14.86 11 24 -7 218.60 10.58 -11 -24 7 236.41 10.48 11 24 -6 6.07 2.50 -11 -24 6 4.98 2.01 11 24 -5 1.32 2.47 -11 -24 5 -1.61 2.11 11 24 -4 8.57 2.67 -11 -24 4 7.28 2.21 11 24 -3 55.12 4.16 -11 -24 3 56.54 3.94 -11 -24 2 38.88 2.92 11 24 -2 39.09 3.56 -11 -24 2 37.80 3.35 -11 -24 1 4.27 1.89 11 24 -1 -1.94 2.52 -11 -24 1 1.17 2.18 -11 -24 0 47.05 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6.87 2.99 13 7 -13 9.73 2.62 13 -7 -13 10.28 2.87 13 7 -13 10.83 3.33 -13 -7 12 21.62 4.26 13 7 -12 27.01 3.00 13 -7 -12 24.06 3.39 -13 -7 12 22.42 2.80 13 7 -12 20.54 3.73 -13 -7 11 37.73 4.90 13 7 -11 48.87 3.67 -13 -7 11 43.95 3.49 13 -7 -11 46.65 4.13 13 7 -11 48.03 4.49 -13 -7 10 109.99 7.76 13 7 -10 107.62 5.93 -13 -7 10 102.90 5.74 13 7 -10 104.28 6.58 -13 -7 9 699.01 30.31 13 7 -9 738.87 31.00 -13 -7 8 1010.14 47.14 -13 7 8 1095.13 44.45 -13 -7 8 1051.24 44.83 -13 -7 8 1052.31 44.63 13 7 -8 1106.23 45.52 -13 -7 7 846.09 38.07 -13 -7 7 824.61 35.66 -13 7 7 835.93 35.22 -13 -7 7 851.22 35.48 13 7 -7 882.58 36.33 -13 -7 6 291.76 15.68 -13 -7 6 301.04 13.63 -13 7 6 297.96 13.07 -13 -7 6 303.35 13.37 13 7 -6 307.59 14.28 -13 7 5 3.26 1.62 -13 -7 5 2.41 2.87 -13 -7 5 3.30 1.96 -13 -7 5 3.40 1.73 13 7 -5 1.73 3.43 -13 7 4 54.63 3.31 -13 -7 4 53.99 5.38 -13 -7 4 55.60 3.80 -13 -7 4 61.23 3.69 13 7 -4 52.02 4.63 -13 7 3 119.04 5.82 -13 -7 3 107.36 8.03 -13 -7 3 130.66 6.30 -13 -7 3 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13 -8 -13 4.11 2.68 13 8 -13 3.02 3.34 -13 -8 12 771.58 36.09 13 8 -12 808.63 33.86 13 -8 -12 821.64 34.20 -13 -8 12 776.72 33.66 13 8 -12 801.96 34.33 -13 -8 11 173.49 11.33 13 8 -11 198.89 9.48 13 -8 -11 207.31 9.93 -13 -8 11 193.38 9.35 13 8 -11 203.54 10.24 -13 -8 10 97.65 7.59 13 8 -10 105.40 5.75 -13 -8 10 99.61 5.63 13 8 -10 98.55 6.58 13 8 -9 1639.94 67.50 -13 -8 9 1602.69 67.39 -13 -8 9 1584.64 67.18 13 8 -9 1708.77 68.12 -13 -8 8 394.89 20.08 -13 -8 8 402.13 17.76 -13 -8 8 400.03 17.52 13 8 -8 418.60 18.55 -13 -8 7 63.13 6.44 -13 -8 7 72.85 4.97 -13 8 7 85.50 4.24 -13 -8 7 68.29 4.50 13 8 -7 89.30 6.08 -13 -8 6 11.78 3.80 -13 -8 6 3.71 2.50 -13 8 6 9.35 1.78 -13 -8 6 11.45 2.10 13 8 -6 10.04 3.62 -13 -8 5 157.79 8.04 -13 8 5 155.42 7.33 -13 -8 5 164.46 9.96 -13 -8 5 160.38 7.83 -13 -8 5 165.68 7.74 13 8 -5 162.16 8.73 -13 8 4 95.51 4.80 -13 -8 4 94.88 7.12 -13 -8 4 98.91 5.36 -13 -8 4 100.55 5.23 13 8 -4 85.55 5.98 -13 -8 3 83.26 6.85 -13 -8 3 94.67 5.18 -13 -8 3 95.77 5.12 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86.99 5.42 -13 -8 -14 14.71 2.47 -13 -8 -14 17.79 2.87 -13 -8 -15 314.14 13.93 13 8 16 370.20 7.76 -13 -8 -16 22.70 7.70 13 -9 -24 2.67 1.40 13 9 -24 2.88 1.35 13 9 -24 4.15 1.96 13 -9 -23 1.69 1.88 13 -9 -23 1.94 1.59 13 9 -23 -0.51 2.31 13 9 -22 30.45 2.65 13 -9 -22 34.01 2.89 13 9 -22 32.10 3.18 13 9 -21 31.25 2.75 13 -9 -21 35.87 3.07 13 9 -20 2.43 1.95 13 -9 -20 2.95 1.89 13 -9 -20 0.57 2.13 13 -9 -19 17.33 2.45 13 9 -19 19.12 2.44 13 -9 -19 15.31 2.73 13 9 -18 8.81 2.28 13 -9 -18 8.30 2.25 13 -9 -18 7.96 2.56 13 -9 -17 185.88 8.99 13 9 -17 181.19 8.89 13 -9 -17 184.50 9.16 13 9 -16 79.48 4.97 13 -9 -16 84.89 5.06 13 -9 -16 87.67 5.31 13 -9 -15 207.38 9.89 13 -9 -15 199.24 9.68 13 9 -15 187.82 9.49 13 9 -15 207.33 10.16 13 -9 -14 61.44 4.40 13 9 -14 55.31 4.03 13 9 -14 55.27 4.81 13 9 -13 5.33 2.32 13 -9 -13 5.96 2.67 13 9 -13 2.96 3.43 -13 -9 12 224.07 13.28 13 9 -12 247.49 11.19 13 -9 -12 240.93 11.52 -13 -9 12 239.34 11.08 13 9 -12 239.66 11.89 -13 -9 11 542.72 25.34 13 9 -11 522.74 22.75 13 -9 -11 539.23 23.13 -13 -9 11 528.53 22.67 13 9 -11 510.71 23.35 -13 -9 10 526.60 24.97 13 9 -10 506.70 22.35 -13 -9 10 516.47 22.32 13 9 -10 534.67 23.11 13 9 -9 1940.69 80.72 -13 -9 9 1936.70 80.67 -13 -9 9 1932.08 80.51 13 9 -9 2017.85 81.39 -13 -9 8 337.92 17.20 -13 -9 8 314.02 14.52 -13 -9 8 322.49 14.31 13 9 -8 336.59 15.34 -13 -9 7 3841.66 165.43 -13 -9 7 3945.59 162.84 -13 9 7 3939.41 162.37 -13 -9 7 3972.70 162.69 13 9 -7 4087.70 163.47 -13 -9 6 358.86 16.62 -13 9 6 380.06 16.07 -13 -9 6 370.59 18.95 -13 -9 6 377.43 16.52 -13 -9 6 379.54 16.42 13 9 -6 377.54 17.31 -13 -9 5 210.89 10.43 -13 -9 5 217.80 12.53 -13 -9 5 223.48 10.32 -13 -9 5 228.60 10.22 13 9 -5 211.75 11.01 -13 -9 4 6.24 3.35 -13 -9 4 4.92 2.09 -13 -9 4 3.51 1.79 13 9 -4 -0.21 3.38 -13 -9 3 253.02 13.43 -13 -9 3 248.88 11.16 -13 -9 3 257.70 11.10 -13 -9 2 -0.49 3.08 -13 -9 2 3.31 2.01 13 9 -2 -0.78 2.51 -13 -9 1 6.77 3.28 -13 -9 1 15.21 2.52 -13 -9 0 3.09 3.35 -13 -9 0 9.84 2.73 -13 -9 0 4.23 2.37 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40.27 2.87 13 -10 -23 2.73 1.77 13 -10 -23 5.09 1.57 13 10 -23 3.35 2.20 13 -10 -22 202.80 9.66 13 10 -22 224.03 9.93 13 10 -21 78.80 4.33 13 -10 -21 77.31 4.54 13 10 -20 17.91 2.30 13 -10 -20 20.85 2.50 13 -10 -20 18.46 2.59 13 -10 -19 38.46 3.20 13 10 -19 39.94 3.09 13 -10 -19 41.71 3.43 13 10 -18 3.33 2.07 13 -10 -18 4.32 2.11 13 -10 -18 4.53 2.41 13 -10 -17 1.11 2.39 13 -10 -17 3.08 2.13 13 10 -17 2.20 2.15 13 -10 -16 3.90 2.14 13 -10 -16 2.08 2.42 13 10 -16 2.27 2.15 13 -10 -15 157.44 8.24 13 -10 -15 160.86 8.18 13 10 -15 160.00 7.96 13 10 -15 173.51 8.73 13 10 -14 22.63 2.73 13 -10 -14 26.16 3.06 13 10 -14 24.99 3.81 13 10 -13 5.64 2.37 13 -10 -13 8.73 2.65 13 10 -13 7.72 3.50 13 10 -12 18.71 2.66 13 -10 -12 23.85 3.19 -13 -10 12 18.93 2.73 13 10 -12 19.18 3.88 -13 -10 11 1237.23 55.82 13 10 -11 1254.39 53.13 13 -10 -11 1282.57 53.50 -13 -10 11 1291.48 53.11 13 10 -11 1285.02 53.80 13 10 -10 420.01 18.14 -13 -10 10 439.56 18.18 -13 -10 10 383.42 17.84 13 10 -10 432.88 18.99 13 10 -9 1889.99 80.00 -13 -10 9 1992.24 80.05 -13 -10 9 1882.64 79.86 13 10 -9 2011.73 80.76 -13 -10 8 375.72 20.46 13 10 -8 400.02 17.98 -13 -10 8 421.38 18.15 -13 -10 8 413.77 17.91 13 10 -8 431.77 18.95 -13 -10 7 70.46 4.78 -13 -10 7 68.58 4.40 13 10 -7 80.42 5.96 -13 -10 6 95.95 5.75 -13 -10 6 92.90 7.65 -13 -10 6 100.72 5.46 -13 -10 6 103.85 5.46 13 10 -6 100.20 6.61 -13 -10 5 651.59 27.98 -13 -10 5 673.14 30.56 -13 -10 5 662.19 27.92 -13 -10 5 676.77 27.87 13 10 -5 604.83 28.39 -13 -10 4 51.90 5.51 -13 -10 4 57.03 3.86 -13 -10 4 62.26 3.83 -13 -10 3 9.84 3.47 -13 -10 3 11.77 2.22 -13 -10 3 13.37 2.28 13 10 -3 4.50 3.30 -13 -10 2 43.05 5.05 -13 -10 2 41.99 3.37 -13 -10 2 39.46 3.21 13 10 -2 28.87 3.43 -13 -10 1 463.07 19.13 -13 -10 1 488.80 16.61 -13 -10 0 55.31 6.37 -13 -10 0 62.81 5.12 -13 -10 -1 18.55 3.92 -13 -10 -1 16.87 3.87 -13 -10 -2 8.50 3.84 -13 -10 -2 6.94 3.68 -13 -10 -3 4.04 3.43 -13 -10 -3 2.11 3.31 -13 -10 -4 39.30 3.29 -13 -10 -4 36.85 3.43 -13 -10 -5 4.54 2.69 -13 -10 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47.82 3.53 13 16 -7 42.30 4.32 -13 -16 6 127.51 6.61 13 16 -6 135.93 7.51 -13 -16 6 133.58 6.90 -13 -16 5 82.76 4.92 -13 -16 5 87.61 5.04 13 16 -5 95.90 5.96 -13 -16 5 88.87 5.16 -13 -16 4 157.01 7.68 -13 -16 4 149.24 7.78 13 16 -4 154.53 8.46 -13 -16 4 166.24 8.01 -13 -16 3 32.21 3.32 -13 -16 3 35.87 3.41 13 16 -3 34.97 4.11 -13 -16 2 2.04 2.38 13 16 -2 2.82 3.13 -13 -16 2 1.37 2.51 -13 -16 1 25.61 3.05 13 16 -1 29.62 3.60 -13 -16 1 26.09 3.20 -13 -16 0 216.30 9.79 13 16 0 183.42 9.51 -13 -16 -1 15.43 2.84 13 16 1 13.85 2.60 -13 -16 -1 12.02 2.92 -13 -16 -2 33.33 3.53 13 16 2 30.28 2.71 -13 -16 -2 30.66 3.48 -13 -16 -3 12.02 3.20 -13 -16 -3 9.60 3.10 -13 -16 -4 28.12 4.62 -13 -16 -4 26.61 4.50 -13 -16 -5 81.11 7.99 -13 -16 -5 89.40 7.91 -13 -16 -6 53.30 8.60 13 16 6 366.42 8.74 -13 -16 -7 10.50 3.13 -13 -16 -7 7.80 3.13 -13 -16 -8 10.99 3.40 -13 -16 -8 10.21 3.51 -13 -16 -8 12.68 3.21 -13 -16 -8 13.50 3.10 -13 -16 -9 227.86 12.46 -13 -16 -9 214.08 12.59 -13 -16 -9 186.25 12.12 -13 -16 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2.22 -13 -17 7 333.21 14.55 13 17 -7 326.98 15.32 -13 -17 7 332.52 14.85 -13 -17 6 12.68 2.26 13 17 -6 17.00 3.56 -13 -17 6 14.75 2.55 -13 -17 5 72.26 4.37 -13 -17 5 69.71 4.40 13 17 -5 78.85 5.38 -13 -17 5 77.71 4.71 -13 -17 4 232.71 10.87 -13 -17 4 237.16 11.07 13 17 -4 250.52 11.71 -13 -17 4 237.16 11.24 -13 -17 3 1.70 2.34 13 17 -3 4.44 3.37 -13 -17 3 4.60 2.47 -13 -17 2 48.14 3.85 -13 -17 2 51.47 3.98 13 17 -2 49.00 4.58 -13 -17 1 47.44 3.64 -13 -17 1 46.02 3.73 13 17 -1 42.14 4.11 -13 -17 0 4.64 2.39 13 17 0 3.17 2.85 -13 -17 -1 46.96 3.77 13 17 1 35.17 3.58 -13 -17 -2 289.03 11.82 -13 -17 -2 302.67 12.06 -13 -17 -3 56.84 4.28 -13 -17 -3 63.65 4.33 -13 -17 -4 117.81 6.46 -13 -17 -4 120.18 6.42 13 17 4 107.31 5.45 -13 -17 -5 47.74 4.93 -13 -17 -5 42.30 4.67 -13 -17 -6 27.35 5.29 13 17 6 206.95 5.44 -13 -17 -7 57.12 7.03 13 17 7 271.83 7.16 -13 -17 -8 51.30 5.15 -13 -17 -8 42.67 4.69 -13 -17 -8 48.61 4.75 -13 -17 -9 5.55 2.99 -13 -17 -9 10.13 2.76 -13 -17 -9 9.90 2.57 -13 -17 -10 21.47 3.28 -13 -17 -10 17.51 2.68 -13 -17 -10 26.45 3.03 -13 -17 -11 11.41 3.01 -13 -17 -11 14.54 2.85 -13 -17 -12 1.66 1.84 -13 -17 -12 1.35 1.77 -13 -17 -13 19.47 1.78 13 17 13 19.68 1.50 13 18 -21 1.00 1.58 13 18 -20 2.25 1.84 13 -18 -19 -0.34 1.61 13 -18 -19 -0.93 1.10 13 -18 -18 3.27 1.76 13 -18 -18 7.79 1.44 13 -18 -17 38.64 3.00 13 -18 -17 44.55 2.81 13 -18 -16 4.69 1.75 13 -18 -15 3.53 1.85 13 -18 -15 5.65 1.85 13 -18 -14 307.91 13.83 13 18 -14 321.91 14.23 13 -18 -13 113.01 5.92 13 18 -13 120.61 6.48 13 -18 -12 357.23 16.33 13 18 -12 402.58 16.89 13 -18 -11 122.39 6.22 13 18 -11 119.70 6.81 13 -18 -10 100.55 5.52 -13 -18 10 115.22 5.33 -13 -18 10 95.66 5.33 13 18 -10 103.41 6.12 13 -18 -9 8.12 2.19 -13 -18 9 11.50 1.96 13 18 -9 8.32 3.11 -13 -18 9 8.85 2.09 13 -18 -8 212.03 10.29 -13 -18 8 231.24 10.11 13 18 -8 223.93 10.87 -13 -18 8 224.97 10.39 -13 -18 7 171.29 7.89 13 18 -7 157.18 8.60 -13 -18 7 169.96 8.24 -13 -18 6 19.58 2.29 13 18 -6 18.21 3.52 -13 -18 6 14.96 2.53 -13 -18 5 9.65 2.13 13 18 -5 11.78 3.32 -13 -18 5 9.39 2.39 -13 -18 4 163.14 7.70 -13 -18 4 152.48 7.78 13 18 -4 162.08 8.51 -13 -18 4 161.20 8.03 -13 -18 3 2.59 2.09 -13 -18 3 2.31 2.13 13 18 -3 3.98 3.19 -13 -18 3 1.17 2.39 -13 -18 2 532.23 23.30 13 18 -2 547.19 23.69 -13 -18 2 537.52 23.44 -13 -18 1 449.70 19.68 13 18 -1 443.32 19.91 -13 -18 1 450.38 19.83 -13 -18 0 7.21 2.52 13 18 0 1.38 3.03 -13 -18 -1 421.66 18.01 13 18 1 387.79 17.78 -13 -18 -2 9.75 2.65 13 18 2 4.63 2.60 -13 -18 -2 4.58 2.57 -13 -18 -3 0.19 2.50 13 18 3 -0.46 2.17 -13 -18 -3 -0.10 2.53 -13 -18 -4 17.47 2.90 -13 -18 -4 20.98 2.96 13 18 4 16.11 2.32 -13 -18 -5 154.51 7.25 -13 -18 -5 157.29 7.11 -13 -18 -6 18.40 3.25 -13 -18 -6 14.22 2.91 -13 -18 -7 40.07 4.21 13 18 7 103.57 3.94 -13 -18 -8 112.82 6.92 -13 -18 -8 120.41 6.62 -13 -18 -9 7.12 2.44 -13 -18 -9 7.24 2.01 -13 -18 -9 3.53 1.87 -13 -18 -10 246.74 9.97 -13 -18 -10 208.00 9.37 13 18 10 190.03 9.16 -13 -18 -10 244.47 9.61 -13 -18 -11 203.73 7.86 -13 -18 -11 199.02 7.55 -13 -18 -12 130.16 5.36 -13 -18 -12 121.09 5.11 -13 -18 -13 252.32 10.00 13 18 13 214.08 9.85 13 19 -21 16.84 1.75 13 19 -20 5.55 1.75 13 -19 -19 4.57 1.66 13 -19 -19 6.94 1.18 13 -19 -18 3.65 1.35 13 -19 -17 214.31 9.56 13 -19 -16 29.04 2.44 13 -19 -15 15.45 2.14 13 -19 -13 16.66 2.31 13 19 -13 20.33 3.09 13 19 -12 225.28 10.69 13 19 -11 157.24 8.07 13 19 -10 17.97 3.17 -13 -19 9 4.86 1.73 13 19 -9 3.20 2.82 -13 -19 9 4.28 1.85 -13 -19 8 7.30 1.87 13 19 -8 8.34 3.01 -13 -19 8 6.95 2.03 -13 -19 7 8.57 1.93 13 19 -7 9.41 3.13 -13 -19 7 5.82 2.19 -13 -19 6 33.50 2.67 -13 -19 6 32.18 3.04 13 19 -6 27.47 3.74 -13 -19 5 167.02 7.74 13 19 -5 168.63 8.61 -13 -19 5 154.34 8.10 -13 -19 4 199.68 9.03 -13 -19 4 182.60 9.14 13 19 -4 207.23 9.92 -13 -19 4 194.33 9.48 -13 -19 3 15.09 2.35 -13 -19 3 12.43 2.41 13 19 -3 19.74 3.50 -13 -19 3 15.21 2.76 -13 -19 2 84.03 4.62 -13 -19 2 81.16 4.85 13 19 -2 82.07 5.59 -13 -19 2 75.04 4.98 -13 -19 1 3.20 2.38 13 19 -1 1.65 3.22 -13 -19 1 4.38 2.42 -13 -19 0 9.58 2.45 13 19 0 2.97 3.05 -13 -19 -1 178.65 8.57 13 19 1 164.32 8.55 -13 -19 -2 78.65 4.75 -13 -19 -2 75.41 4.87 -13 -19 -3 94.10 5.34 -13 -19 -3 98.93 5.40 -13 -19 -4 119.05 6.12 -13 -19 -4 117.98 6.07 -13 -19 -5 7.11 2.46 -13 -19 -5 6.03 2.46 13 19 5 1.20 1.95 -13 -19 -6 2.03 2.34 -13 -19 -6 1.33 2.10 13 19 6 3.70 1.80 -13 -19 -7 0.07 1.92 13 19 7 9.50 1.63 -13 -19 -8 96.94 4.52 13 19 8 69.93 3.91 -13 -19 -9 28.16 2.68 -13 -19 -9 25.55 2.14 13 19 9 22.93 1.93 -13 -19 -10 104.30 4.89 -13 -19 -10 93.22 4.33 -13 -19 -11 112.65 5.11 -13 -19 -11 106.78 4.76 -13 -19 -12 4.12 1.54 13 19 12 8.08 1.50 13 20 -20 51.68 2.97 13 -20 -19 11.56 1.28 13 -20 -18 1.68 1.21 13 -20 -17 7.70 1.59 13 -20 -16 3.25 1.59 13 -20 -15 2.84 1.76 13 -20 -15 2.53 1.74 13 -20 -14 2.64 1.72 13 -20 -14 3.45 1.86 13 -20 -13 35.86 2.91 13 20 -13 37.18 3.40 13 20 -12 85.51 5.12 13 20 -11 84.94 5.21 13 20 -10 58.42 4.31 -13 -20 9 5.87 1.68 13 20 -9 3.12 2.80 -13 -20 9 2.07 1.77 -13 -20 8 15.84 1.98 13 20 -8 18.29 3.06 -13 -20 8 16.74 2.30 -13 -20 7 66.09 3.69 13 20 -7 59.25 4.64 -13 -20 7 62.36 4.09 -13 -20 6 23.13 2.27 13 20 -6 19.68 3.34 -13 -20 6 20.43 2.69 -13 -20 5 52.75 3.36 13 20 -5 53.17 4.42 -13 -20 5 55.19 3.91 -13 -20 4 4.25 1.92 -13 -20 4 2.61 1.85 13 20 -4 0.48 3.05 -13 -20 4 7.91 2.48 -13 -20 3 109.80 5.46 -13 -20 3 101.53 5.59 13 20 -3 111.25 6.41 -13 -20 3 97.46 5.85 -13 -20 2 728.42 29.87 -13 -20 2 676.39 30.07 13 20 -2 736.73 30.54 -13 -20 2 694.23 30.29 -13 -20 1 6.07 2.30 13 20 -1 4.43 3.13 -13 -20 1 7.85 2.55 -13 -20 0 784.13 33.14 13 20 0 751.35 33.28 -13 -20 0 806.21 33.34 -13 -20 -1 78.92 4.81 13 20 1 70.13 4.98 -13 -20 -2 117.51 6.19 13 20 2 102.87 6.11 -13 -20 -2 116.36 6.36 -13 -20 -3 1.37 2.33 13 20 3 -1.33 2.52 -13 -20 -3 -0.09 2.40 -13 -20 -4 60.08 4.12 -13 -20 -4 64.35 4.19 -13 -20 -5 303.57 12.63 -13 -20 -5 315.95 12.63 -13 -20 -6 16.55 2.59 -13 -20 -6 17.72 2.43 -13 -20 -7 108.56 5.44 -13 -20 -7 111.77 5.20 -13 -20 -8 15.74 2.00 13 20 8 12.40 1.95 -13 -20 -9 25.11 2.43 -13 -20 -9 23.08 2.00 13 20 9 18.31 2.00 -13 -20 -10 227.28 9.32 13 20 10 189.55 8.95 -13 -20 -11 9.92 1.65 13 20 11 9.14 1.65 -13 -20 -12 648.11 26.99 13 21 -20 0.66 1.28 13 -21 -19 0.68 0.87 13 21 -19 3.01 1.52 13 -21 -18 7.93 1.32 13 -21 -17 76.82 4.12 13 -21 -17 74.46 3.92 13 -21 -16 93.47 4.87 13 -21 -16 92.67 4.74 13 -21 -15 33.49 2.61 13 -21 -15 29.64 2.58 13 -21 -14 4.27 1.76 13 -21 -14 0.81 1.82 13 -21 -13 2.14 1.71 13 -21 -13 0.86 1.90 13 21 -13 1.24 2.29 13 -21 -12 297.70 13.33 13 21 -12 298.76 13.42 13 21 -11 10.39 2.63 13 21 -10 1.74 2.48 13 21 -9 77.24 4.95 -13 -21 9 76.27 4.24 13 21 -8 18.26 3.06 -13 -21 8 20.75 2.34 -13 -21 7 344.15 14.32 13 21 -7 314.66 14.97 -13 -21 7 325.47 14.69 -13 -21 6 41.10 2.76 13 21 -6 37.66 3.88 -13 -21 6 42.27 3.27 -13 -21 5 24.25 2.30 13 21 -5 24.55 3.46 -13 -21 5 26.50 2.82 -13 -21 4 29.76 2.45 13 21 -4 27.20 3.53 -13 -21 4 26.49 2.92 -13 -21 3 17.15 2.14 -13 -21 3 14.59 2.22 13 21 -3 16.63 3.32 -13 -21 3 13.95 2.62 -13 -21 2 36.31 2.82 -13 -21 2 30.57 2.97 13 21 -2 39.05 3.95 -13 -21 2 40.20 3.47 -13 -21 1 8.76 2.06 -13 -21 1 9.49 2.26 13 21 -1 10.73 3.12 -13 -21 1 10.81 2.55 -13 -21 0 38.62 3.31 -13 -21 0 33.61 3.54 13 21 0 38.84 3.87 -13 -21 -1 6.73 2.40 13 21 1 6.68 2.93 -13 -21 -2 122.60 6.30 13 21 2 111.93 6.37 -13 -21 -2 118.93 6.49 -13 -21 -3 7.52 2.43 13 21 3 3.29 2.47 -13 -21 -3 4.60 2.34 -13 -21 -4 30.84 3.03 -13 -21 -4 34.17 3.14 13 21 4 31.50 3.04 -13 -21 -5 30.14 2.94 13 21 5 22.78 2.65 -13 -21 -5 25.40 2.80 -13 -21 -6 154.92 7.03 -13 -21 -6 139.73 6.82 -13 -21 -7 6.50 2.07 -13 -21 -7 5.85 1.82 13 21 7 4.83 1.92 -13 -21 -8 97.02 4.62 13 21 8 82.20 4.56 -13 -21 -9 4.05 1.37 13 21 9 1.94 1.72 -13 -21 -10 116.34 5.27 13 21 10 98.52 5.09 -13 -21 -11 3.92 1.40 13 21 11 -0.48 1.53 13 22 -19 110.89 5.11 13 -22 -18 -1.38 1.42 13 -22 -18 0.43 1.13 13 -22 -17 6.24 1.56 13 -22 -17 4.64 1.36 13 -22 -16 51.00 3.05 13 -22 -16 43.59 2.85 13 -22 -15 14.15 1.91 13 -22 -15 12.47 1.89 13 -22 -14 1.42 1.61 13 -22 -14 3.29 1.75 13 -22 -13 8.18 1.81 13 -22 -13 8.05 2.00 13 -22 -12 38.41 2.83 13 -22 -12 36.03 2.94 13 22 -12 31.20 3.05 13 22 -11 20.16 2.71 13 22 -10 26.19 2.99 -13 -22 9 31.30 2.46 13 22 -9 30.95 3.22 13 22 -8 1.11 2.63 -13 -22 8 1.57 1.72 13 22 -7 96.63 5.87 -13 -22 7 109.45 5.53 13 22 -6 1.34 2.77 -13 -22 6 1.26 1.92 13 22 -5 8.27 2.84 -13 -22 5 8.77 2.18 -13 -22 4 35.86 2.61 13 22 -4 35.73 3.64 -13 -22 4 38.68 3.23 -13 -22 3 215.41 9.24 -13 -22 3 187.99 9.37 13 22 -3 210.75 10.03 -13 -22 3 209.35 9.79 -13 -22 2 13.54 2.02 -13 -22 2 14.30 2.15 13 22 -2 11.16 3.08 -13 -22 2 18.23 2.68 -13 -22 1 874.19 36.04 -13 -22 1 824.69 36.30 13 22 -1 891.31 36.64 -13 -22 1 869.25 36.59 -13 -22 0 149.73 7.04 -13 -22 0 147.75 7.37 13 22 0 151.97 7.73 -13 -22 0 148.21 7.62 -13 -22 -1 353.13 15.43 13 22 1 342.48 15.55 -13 -22 -2 8.66 2.33 13 22 2 7.27 2.61 -13 -22 -3 54.47 3.67 13 22 3 45.90 3.66 -13 -22 -3 48.50 3.69 -13 -22 -4 31.25 3.00 -13 -22 -4 38.08 3.11 13 22 4 28.80 3.03 -13 -22 -5 1.21 1.98 13 22 5 0.24 2.16 -13 -22 -5 0.07 1.93 -13 -22 -6 32.62 2.80 -13 -22 -6 30.48 2.63 13 22 6 25.94 2.65 -13 -22 -7 54.22 3.40 -13 -22 -7 52.19 3.13 13 22 7 43.38 3.18 -13 -22 -8 44.21 2.58 13 22 8 30.94 2.70 -13 -22 -9 28.10 1.93 13 22 9 21.64 2.21 -13 -22 -10 5.58 1.47 13 22 10 0.56 1.69 -13 -22 -11 431.37 18.12 13 -23 -18 30.75 2.13 13 -23 -18 24.83 1.83 13 23 -18 31.86 2.04 13 -23 -17 52.00 2.73 13 -23 -17 54.28 3.00 13 -23 -16 83.40 4.35 13 -23 -16 83.97 4.25 13 -23 -15 1.83 1.51 13 -23 -15 0.84 1.58 13 -23 -14 1.26 1.54 13 -23 -14 0.82 1.61 13 -23 -13 49.57 3.12 13 -23 -13 44.13 3.12 13 -23 -12 91.98 4.78 13 23 -12 85.84 4.88 13 -23 -11 -0.40 1.75 13 23 -11 0.83 2.08 13 23 -10 99.55 5.45 13 23 -9 13.12 2.55 13 23 -8 102.82 5.76 -13 -23 8 106.12 5.30 13 23 -7 15.90 2.84 -13 -23 7 17.10 2.21 13 23 -6 100.32 5.92 -13 -23 6 112.52 5.66 13 23 -5 69.52 4.70 -13 -23 5 73.86 4.36 13 23 -4 71.01 4.77 -13 -23 4 76.70 4.54 13 23 -3 12.75 2.92 -13 -23 3 15.13 2.55 -13 -23 2 1.19 1.72 13 23 -2 0.71 2.66 -13 -23 2 0.32 2.10 -13 -23 1 13.23 1.89 -13 -23 1 10.84 2.11 13 23 -1 16.85 2.99 -13 -23 1 13.90 2.52 -13 -23 0 4.63 1.67 -13 -23 0 0.07 1.82 13 23 0 7.19 2.62 -13 -23 0 2.75 2.27 -13 -23 -1 64.87 3.61 -13 -23 -1 66.79 4.04 13 23 1 60.04 4.21 -13 -23 -2 0.56 1.90 13 23 2 1.57 2.28 -13 -23 -3 3.14 2.00 13 23 3 1.47 2.22 -13 -23 -3 4.72 2.15 -13 -23 -4 12.82 2.24 13 23 4 12.90 2.35 -13 -23 -4 11.53 2.27 -13 -23 -5 150.00 7.01 -13 -23 -5 150.94 6.96 -13 -23 -6 163.02 7.24 -13 -23 -6 151.70 7.09 -13 -23 -7 27.64 2.41 -13 -23 -7 31.10 2.26 -13 -23 -8 57.25 3.31 -13 -23 -8 59.93 3.08 13 23 8 48.91 3.20 -13 -23 -9 49.06 2.60 13 23 9 46.16 2.84 13 -24 -17 11.18 1.50 13 24 -17 11.70 1.47 13 -24 -16 19.82 1.80 13 -24 -16 12.15 1.62 13 -24 -15 10.90 1.64 13 -24 -15 8.96 1.65 13 -24 -14 19.42 2.02 13 -24 -14 26.44 2.22 13 -24 -13 72.26 3.97 13 -24 -13 71.81 4.00 13 -24 -12 14.23 1.95 13 -24 -11 -0.55 1.56 13 24 -11 2.56 1.94 13 -24 -10 17.77 2.11 13 -24 -10 14.80 2.13 13 24 -10 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73.53 4.53 14 15 -11 72.38 5.19 14 -15 -10 103.95 5.65 -14 -15 10 109.14 5.34 -14 -15 10 90.82 5.20 14 15 -10 97.59 6.17 14 -15 -9 2.65 2.29 -14 -15 9 1.53 1.96 -14 -15 9 0.36 1.85 14 15 -9 2.50 3.08 -14 -15 8 66.95 4.09 -14 -15 8 63.98 4.13 14 15 -8 64.52 5.09 -14 -15 7 152.35 7.54 -14 -15 7 161.91 7.77 14 15 -7 152.62 8.35 -14 -15 6 2.01 2.18 14 15 -6 2.08 3.14 -14 -15 6 4.41 2.17 -14 -15 5 179.11 8.43 -14 -15 5 170.89 8.52 -14 -15 5 176.91 8.62 14 15 -5 176.88 9.20 -14 -15 4 81.66 4.76 -14 -15 4 75.06 4.83 -14 -15 4 84.62 4.97 14 15 -4 86.04 5.75 -14 -15 3 16.25 2.62 -14 -15 3 14.39 2.52 14 15 -3 18.62 3.63 -14 -15 3 14.59 2.63 -14 -15 2 -0.45 2.30 -14 -15 2 -1.72 2.41 14 15 -2 -0.62 3.33 -14 -15 1 -0.37 2.34 14 15 -1 0.39 3.19 -14 -15 0 95.13 5.57 14 15 0 90.61 5.64 -14 -15 -1 -1.14 2.43 -14 -15 -1 1.80 2.44 14 15 1 -1.07 2.66 -14 -15 -2 120.58 6.41 -14 -15 -2 131.83 6.48 -14 -15 -3 8.03 2.82 -14 -15 -3 12.58 2.70 14 15 3 10.55 2.20 -14 -15 -4 34.49 3.77 -14 -15 -4 37.76 3.46 -14 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264.52 12.05 14 17 -9 261.14 12.59 -14 -17 8 20.27 2.30 14 -17 -8 22.09 2.64 14 17 -8 21.39 3.53 -14 -17 8 17.94 2.41 -14 -17 7 110.62 5.55 -14 -17 7 106.57 5.80 14 17 -7 102.26 6.39 -14 -17 6 22.43 2.42 14 17 -6 19.47 3.56 -14 -17 6 20.78 2.63 -14 -17 5 95.84 5.06 -14 -17 5 90.68 5.10 -14 -17 5 89.21 5.32 14 17 -5 94.75 5.95 -14 -17 4 17.19 2.44 -14 -17 4 13.13 2.31 14 17 -4 21.99 3.73 -14 -17 4 17.34 2.72 -14 -17 3 249.32 10.96 -14 -17 3 226.54 11.08 -14 -17 3 239.03 11.25 14 17 -3 244.09 11.68 -14 -17 2 377.64 15.84 -14 -17 2 355.70 16.08 -14 -17 2 355.59 16.17 14 17 -2 345.55 16.43 -14 -17 1 32.16 3.17 14 17 -1 26.65 3.87 -14 -17 1 35.23 3.40 -14 -17 0 111.79 6.19 14 17 0 108.07 6.39 -14 -17 -1 13.70 2.72 -14 -17 -1 17.89 2.98 14 17 1 15.16 3.09 -14 -17 -2 -0.36 2.46 -14 -17 -2 -1.30 2.45 14 17 2 -4.40 2.72 -14 -17 -3 16.21 2.80 -14 -17 -3 14.01 2.69 14 17 3 15.03 2.68 -14 -17 -4 41.36 3.57 -14 -17 -4 40.16 3.49 14 17 4 34.95 3.13 -14 -17 -5 44.60 3.66 -14 -17 -5 47.62 3.39 -14 -17 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45.16 3.87 -14 -20 8 151.48 6.78 -14 -20 8 144.30 7.02 14 20 -8 133.09 7.46 -14 -20 7 101.44 5.10 -14 -20 7 103.61 5.47 14 20 -7 104.04 6.02 -14 -20 6 24.39 2.24 -14 -20 6 26.80 2.69 -14 -20 5 42.23 2.91 -14 -20 5 44.53 3.41 14 20 -5 43.95 4.03 -14 -20 4 21.86 2.31 -14 -20 4 21.10 2.27 14 20 -4 18.96 3.40 -14 -20 4 21.12 2.77 -14 -20 3 19.31 2.26 -14 -20 3 13.32 2.25 14 20 -3 15.20 3.44 -14 -20 3 17.56 2.78 -14 -20 2 93.93 4.90 -14 -20 2 92.89 5.17 14 20 -2 95.80 5.80 -14 -20 2 89.57 5.39 -14 -20 1 97.34 5.06 -14 -20 1 94.71 5.36 14 20 -1 98.87 5.90 -14 -20 1 96.39 5.58 -14 -20 0 38.11 2.90 -14 -20 0 38.06 3.22 14 20 0 35.77 3.81 -14 -20 -1 451.41 19.24 14 20 1 427.93 19.28 -14 -20 -2 47.60 3.58 -14 -20 -2 44.63 3.71 14 20 2 43.30 3.77 -14 -20 -3 10.43 2.39 -14 -20 -3 10.80 2.44 14 20 3 11.97 2.62 -14 -20 -4 10.68 2.43 -14 -20 -4 10.30 2.29 14 20 4 11.54 2.50 -14 -20 -5 0.07 2.09 -14 -20 -5 2.04 1.87 14 20 5 0.18 2.13 -14 -20 -6 39.22 3.09 -14 -20 -6 37.42 2.74 14 20 6 31.75 2.87 -14 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9.96 1.72 20 10 -6 6.51 1.54 20 -10 -5 8.88 1.65 20 10 -5 5.18 1.51 20 -10 -4 248.68 9.65 20 10 -4 197.93 9.42 20 -10 -3 18.02 1.70 20 10 -3 13.41 1.58 20 -10 -2 2.26 1.25 -20 -10 2 1.60 1.12 -20 -10 1 17.82 1.49 20 -11 -10 53.26 2.99 20 -11 -9 84.32 3.85 20 11 -9 64.59 3.65 20 -11 -8 80.53 3.69 20 11 -8 60.00 3.47 20 -11 -7 6.71 1.53 20 11 -7 4.15 1.48 20 -11 -6 30.16 2.05 20 11 -6 18.17 1.86 20 -11 -5 90.24 4.05 20 11 -5 70.81 3.89 20 -11 -4 7.41 1.42 20 11 -4 5.12 1.36 20 -11 -3 1.94 1.25 20 -12 -8 22.16 1.75 20 12 -8 16.42 1.70 20 -12 -7 2.54 1.28 20 12 -7 -0.28 1.32 20 -12 -6 -0.78 1.24 20 12 -6 0.82 1.31 20 -12 -5 71.08 3.33 20 12 -5 59.24 3.26 21 -1 -7 48.20 2.68 21 -2 -8 28.93 2.04 21 -2 -7 16.53 1.63 21 -2 -6 25.87 1.92 21 -3 -9 130.00 5.92 21 -3 -8 101.81 4.81 21 -3 -7 119.70 5.52 21 -3 -6 122.34 5.60 21 -4 -8 15.81 1.65 21 -4 -7 10.76 1.54 21 -4 -6 13.60 1.54 0 0 0 0.00 0.00 TITL ZWQ in P2(1)/n REM P2(1)/n (#14 in standard setting) CELL 1.54184 16.990920 33.061699 22.675034 90.0000 104.5194 90.0000 ZERR 53.00 0.000187 0.000386 0.000220 0.0000 0.0010 0.0000 LATT 1 SYMM -x+1/2, y+1/2,-z+1/2 SFAC C H N O UNIT 583.00 530.00 53.00 53.00 TREF HKLF 4 END _computing_structure_solution 'SHELXT 2014/5 (Sheldrick, 2014)' ; _shelx_hkl_checksum 21846 _shelx_fab_file ; -20 0 6 -0.2626 0.0441 -20 0 8 -0.5937 -0.0109 -20 0 10 -0.4064 -0.0093 -20 1 4 0.2560 -0.1371 -20 1 5 -0.1097 0.0025 -20 1 6 0.3492 0.0658 -20 1 7 0.1211 -0.0230 -20 1 8 0.4270 0.2096 -20 1 9 0.1884 0.1072 -20 1 10 0.3045 -0.1185 -20 1 11 -0.1308 0.0304 -20 2 3 -0.3703 -0.0454 -20 2 4 0.2293 -0.0327 -20 2 5 -0.2757 0.0511 -20 2 6 0.3808 0.0547 -20 2 7 -0.5218 -0.1988 -20 2 8 0.4046 -0.0360 -20 2 9 -0.3767 -0.0453 -20 2 10 0.5360 -0.0746 -20 3 3 -0.1290 0.0135 -20 3 4 -0.2192 -0.1140 -20 3 5 -0.2797 -0.0242 -20 3 6 0.0006 0.0185 -20 3 7 -0.4071 -0.0565 -20 3 8 0.2533 0.1350 -20 3 9 -0.4197 0.0371 -20 3 10 -0.2228 -0.1753 -20 4 4 0.2171 -0.0468 -20 4 5 0.8566 0.1625 -20 4 6 -0.0107 0.0573 -20 4 7 0.1511 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0.0787 11 12 12 2.6086 0.0325 11 12 13 1.3707 0.0904 11 12 14 -0.7191 0.2501 11 12 15 1.2686 -0.0617 11 12 16 0.3410 0.2319 11 13 11 -2.4215 0.1118 11 13 12 -1.3350 -0.0441 11 13 13 1.0821 -0.0538 11 13 14 -2.6511 0.1004 11 13 15 3.0733 -0.1989 11 13 16 -0.4169 0.2165 11 14 11 1.0274 0.0248 11 14 12 0.6122 -0.1605 11 14 13 2.4601 -0.0670 11 14 14 -3.3163 0.0363 11 14 15 2.4371 -0.2898 11 14 16 -2.9288 0.0018 11 15 11 -2.5799 0.1559 11 15 12 -0.8016 -0.1286 11 15 13 0.1470 0.0267 11 15 14 -2.4760 0.1184 11 15 15 1.7869 -0.1236 11 16 11 -0.9307 0.2321 11 16 12 2.3098 -0.0519 11 16 13 0.5312 0.1062 11 16 14 0.1173 0.2315 11 16 15 1.1892 -0.1227 11 17 11 -2.1552 0.1485 11 17 12 1.1652 -0.1379 11 17 13 -0.4766 -0.0553 11 17 14 -0.6393 0.1314 11 17 15 0.5150 -0.3377 11 18 11 -0.7501 0.0761 11 18 12 0.3452 -0.2359 11 18 13 0.2677 -0.1230 11 18 14 -1.8510 0.0908 11 19 11 -0.8872 0.2842 11 19 12 -0.5111 -0.0720 11 19 13 0.9757 0.1418 11 19 14 -1.6924 0.2484 11 20 11 0.7112 0.2653 11 20 12 0.7911 -0.1853 11 20 13 1.1085 0.0438 11 21 11 -1.1676 0.1508 11 21 12 0.2350 -0.1839 11 21 13 -0.7509 0.0084 11 22 11 -0.7779 0.1087 11 22 12 0.4140 -0.2485 11 23 11 -0.0155 0.3196 11 23 12 0.8272 0.0102 11 24 11 0.2587 0.1487 12 0 12 -0.2823 -0.2750 12 0 14 -5.2707 -0.1079 12 0 16 -5.5466 0.1381 12 1 12 -0.6971 0.0337 12 1 13 -0.6464 0.4400 12 1 14 -0.4480 -0.0514 12 1 15 3.3947 0.1391 12 1 16 -0.7384 -0.0044 12 1 17 1.6390 0.1351 12 2 12 8.6485 -0.3054 12 2 13 0.4664 -0.0257 12 2 14 3.2708 -0.1010 12 2 15 -0.1030 0.0456 12 2 16 1.1374 0.0624 12 2 17 0.8473 -0.0611 12 3 12 -1.1245 0.0747 12 3 13 -6.4546 -0.0273 12 3 14 1.3229 -0.0321 12 3 15 -1.9127 -0.3187 12 3 16 1.0885 -0.0134 12 3 17 -1.7466 -0.2155 12 4 12 3.5708 -0.0715 12 4 13 -0.4414 -0.0231 12 4 14 -0.5844 0.1789 12 4 15 -2.5324 0.0527 12 4 16 -1.9926 0.2667 12 5 12 -2.2569 0.0687 12 5 13 1.5540 0.2019 12 5 14 1.3605 -0.0174 12 5 15 4.2451 -0.0009 12 5 16 1.1096 0.0490 12 6 12 1.7879 -0.3074 12 6 13 1.2284 -0.0143 12 6 14 -0.8554 -0.1458 12 6 15 -0.6851 0.0225 12 6 16 -2.2218 -0.1614 12 7 12 -2.8981 0.0022 12 7 13 -4.6071 0.0302 12 7 14 0.8780 -0.1192 12 7 15 -1.9751 -0.0613 12 7 16 0.0379 -0.0701 12 8 12 5.8750 0.0398 12 8 13 -0.4724 0.0898 12 8 14 4.2906 0.1884 12 8 15 -3.1879 0.1756 12 8 16 1.7408 0.1002 12 9 12 -2.0573 0.0611 12 9 13 -2.8055 -0.0334 12 9 14 3.3799 -0.0722 12 9 15 -1.2233 -0.0454 12 9 16 3.1106 -0.0146 12 10 12 0.3683 -0.1008 12 10 13 0.4618 -0.0611 12 10 14 0.4584 -0.0792 12 10 15 -2.5431 -0.0067 12 10 16 -1.2518 -0.2136 12 11 12 -4.0121 0.0621 12 11 13 -0.7980 0.0001 12 11 14 0.2804 -0.0993 12 11 15 -0.5337 0.1264 12 12 12 1.4111 0.1279 12 12 13 0.9271 0.1317 12 12 14 2.7005 0.0569 12 12 15 -1.3355 0.2880 12 13 12 -1.6075 0.0568 12 13 13 -3.0797 -0.0884 12 13 14 3.0569 -0.1938 12 13 15 -3.1149 0.0885 12 14 12 1.7026 0.0535 12 14 13 -1.2278 -0.1023 12 14 14 3.2513 -0.1188 12 15 12 -2.5496 0.2242 12 15 13 -1.4783 -0.0257 12 15 14 1.3738 -0.0118 12 16 12 -0.6411 0.2376 12 16 13 1.6045 0.0232 12 16 14 1.4318 -0.0286 12 17 12 -2.0775 0.1010 12 17 13 -0.2114 -0.1086 12 18 12 -0.2170 0.1153 12 18 13 -0.9419 -0.1159 12 19 12 -0.3525 0.3724 12 20 12 0.4291 0.2337 13 0 15 -6.7059 0.0184 13 1 13 0.4576 -0.0029 13 1 14 1.4648 0.3449 13 1 15 0.4792 -0.0604 13 2 13 7.9357 -0.2818 13 2 14 -0.6441 -0.0671 13 2 15 1.8075 0.0056 13 3 13 -0.6787 0.0701 13 3 14 -4.7827 -0.1944 13 4 13 2.7129 0.0308 13 4 14 -0.8097 0.0940 13 5 13 -0.9420 -0.0305 13 5 14 3.1760 0.0847 13 5 15 1.6898 -0.0823 13 6 13 1.4600 -0.3045 13 6 14 -0.8378 -0.0124 13 6 15 -1.9184 -0.1393 13 7 13 -0.7897 0.0159 13 7 14 -4.1787 -0.0190 13 7 15 1.7041 -0.0397 13 8 13 6.5083 0.1455 13 8 14 -2.1007 0.1481 13 8 15 3.7136 0.2316 13 9 13 -0.3774 -0.0549 13 9 14 -2.4205 -0.1438 13 10 13 0.4917 -0.0819 13 10 14 -1.2890 -0.0025 13 11 13 -2.0425 0.0502 13 11 14 -1.1225 0.0758 13 12 13 2.9393 0.1214 13 12 14 -1.0739 0.1838 13 13 13 0.4978 -0.0709 13 14 13 2.5072 0.0726 13 15 13 -1.1559 0.1857 14 0 14 -4.1541 -0.1762 14 1 14 1.6236 -0.0378 14 2 14 4.9105 -0.1445 14 3 14 -0.3154 0.0901 14 4 14 0.4894 0.1709 0 0 0 0.0 0.0 ; _shelx_fab_checksum 56334 _olex2_submission_special_instructions 'No special instructions were received' _oxdiff_exptl_absorpt_empirical_details ; Empirical correction (ABSPACK) includes: - Absorption correction using spherical harmonics - Frame scaling ; _oxdiff_exptl_absorpt_empirical_full_max 1.698 _oxdiff_exptl_absorpt_empirical_full_min 0.302 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_site_symmetry_order _atom_site_calc_flag _atom_site_refinement_flags_posn _atom_site_refinement_flags_adp _atom_site_refinement_flags_occupancy _atom_site_disorder_assembly _atom_site_disorder_group Nb1 Nb 0.05877(2) 0.83943(2) 0.29069(2) 0.01787(7) Uani 1 1 d . . . . . As1 As -0.00022(2) 0.81711(2) 0.38726(2) 0.02025(9) Uani 1 1 d . . . . . As2 As -0.08573(2) 0.86210(2) 0.31248(2) 0.02126(9) Uani 1 1 d . . . . . As3 As -0.09257(2) 0.81475(2) 0.23000(2) 0.02149(9) Uani 1 1 d . . . . . As4 As -0.02330(2) 0.85956(2) 0.17533(2) 0.02222(9) Uani 1 1 d . . . . . As5 As 0.12789(2) 0.76825(2) 0.26906(2) 0.02242(9) Uani 1 1 d . . . . . As6 As 0.20972(2) 0.81143(2) 0.34717(2) 0.02329(9) Uani 1 1 d . . . . . As7 As 0.20382(2) 0.86713(2) 0.27656(2) 0.02402(9) Uani 1 1 d . . . . . As8 As 0.12970(2) 0.91036(2) 0.33046(2) 0.02175(9) Uani 1 1 d . . . . . Zn1 Zn 0.13139(3) 0.85476(2) 0.41341(2) 0.02229(11) Uani 1 1 d . . . . . Zn2 Zn -0.00192(3) 0.76238(2) 0.30463(2) 0.02113(11) Uani 1 1 d . . . . . Zn3 Zn 0.11177(3) 0.82439(2) 0.18570(2) 0.02422(11) Uani 1 1 d . . . . . Zn4 Zn -0.00752(3) 0.91539(2) 0.25752(2) 0.02255(11) Uani 1 1 d . . . . . K1 K 0.24232(5) 0.59748(3) 0.08731(4) 0.02893(18) Uani 1 1 d . . . . . K2 K 0.53226(5) 0.73405(3) 0.23252(4) 0.02491(17) Uani 1 1 d . . . . . K3 K 0.76574(6) 0.88914(3) 0.00500(4) 0.0351(2) Uani 1 1 d . . . . . O1 O 0.0761(2) 0.59083(12) 0.07382(17) 0.0516(9) Uani 1 1 d . . . . . O2 O 0.13813(19) 0.59646(11) -0.03176(15) 0.0450(8) Uani 1 1 d . . . . . O3 O 0.31282(18) 0.55589(8) 0.19978(13) 0.0319(6) Uani 1 1 d . . . . . O4 O 0.35824(17) 0.53745(8) 0.09117(12) 0.0301(6) Uani 1 1 d . . . . . O5 O 0.24642(19) 0.67180(9) 0.14438(13) 0.0339(6) Uani 1 1 d . . . . . O6 O 0.33239(17) 0.66354(8) 0.05294(12) 0.0289(6) Uani 1 1 d . . . . . O7 O 0.43709(19) 0.69028(10) 0.29827(13) 0.0367(7) Uani 1 1 d . . . . . O8 O 0.52479(17) 0.64760(8) 0.22806(12) 0.0304(6) Uani 1 1 d . . . . . O9 O 0.63421(17) 0.77667(10) 0.33064(13) 0.0340(7) Uani 1 1 d . . . . . O10 O 0.69479(16) 0.74475(9) 0.23479(12) 0.0275(6) Uani 1 1 d . . . . . O11 O 0.42758(17) 0.80081(9) 0.19373(13) 0.0321(6) Uani 1 1 d . . . . . O12 O 0.47205(17) 0.75055(8) 0.10734(12) 0.0282(6) Uani 1 1 d . . . . . O13 O 0.64010(17) 0.84414(9) -0.07798(12) 0.0302(6) Uani 1 1 d . . . . . O14 O 0.6537(2) 0.92951(10) -0.09609(15) 0.0502(9) Uani 1 1 d . . . . . O15 O 0.74281(17) 0.85251(8) 0.10603(12) 0.0278(6) Uani 1 1 d . . . . . O16 O 0.7226(2) 0.93658(9) 0.09973(15) 0.0438(8) Uani 1 1 d . . . . . O17 O 0.89987(18) 0.84705(10) -0.01921(13) 0.0374(7) Uani 1 1 d . . . . . O18 O 0.9035(2) 0.93260(11) -0.00587(14) 0.0544(10) Uani 1 1 d . . . . . N1 N 0.1704(2) 0.60737(12) 0.19720(19) 0.0413(9) Uani 1 1 d . . . . . N2 N 0.3116(2) 0.58867(11) -0.02094(15) 0.0301(7) Uani 1 1 d . . . . . N3 N 0.4601(2) 0.77818(12) 0.32315(16) 0.0369(8) Uani 1 1 d . . . . . N4 N 0.60049(19) 0.68854(10) 0.14295(14) 0.0243(7) Uani 1 1 d . . . . . N5 N 0.76697(19) 0.79891(10) 0.00972(14) 0.0247(7) Uani 1 1 d . . . . . N6 N 0.7568(3) 0.98202(13) -0.0042(2) 0.0679(16) Uani 1 1 d . . . . . N7 N 0.1490(2) 0.40928(13) 0.08455(19) 0.0451(10) Uani 1 1 d . . . . . H7C H 0.1442 0.4067 0.0461 0.054 Uiso 1 1 calc R U . . . H7D H 0.1562 0.3883 0.1076 0.054 Uiso 1 1 calc R U . . . N8 N 0.1958(3) 0.48295(14) 0.0304(2) 0.0567(12) Uani 1 1 d . . . . . H8C H 0.2366 0.4668 0.0407 0.068 Uiso 1 1 calc R U . . . H8D H 0.1933 0.5002 0.0017 0.068 Uiso 1 1 calc DR U . . . N9 N 0.5486(4) 0.8718(2) 0.0244(3) 0.105(2) Uani 1 1 d . . . . . H9C H 0.5894 0.8747 0.0554 0.127 Uiso 1 1 calc R U . . . H9D H 0.5536 0.8577 -0.0063 0.127 Uiso 1 1 calc R U . . . N10 N 0.5209(6) 0.9497(4) 0.0841(7) 0.151(6) Uani 0.720(8) 1 d . . P A 1 H10C H 0.5483 0.9555 0.0580 0.181 Uiso 0.720(8) 1 calc R U P A 1 H10D H 0.5235 0.9652 0.1149 0.181 Uiso 0.720(8) 1 calc R U P A 1 N10' N 0.4913(17) 0.9614(10) 0.0166(18) 0.151(6) Uani 0.280(8) 1 d . . P A 2 H10E H 0.5390 0.9639 0.0408 0.181 Uiso 0.280(8) 1 calc R U P A 2 H10F H 0.4666 0.9824 -0.0016 0.181 Uiso 0.280(8) 1 calc R U P A 2 C1 C 0.0919(4) 0.58668(19) 0.1815(3) 0.0602(15) Uani 1 1 d . . . . . H1A H 0.0642 0.5921 0.2132 0.072 Uiso 1 1 calc R U . . . H1B H 0.1017 0.5578 0.1813 0.072 Uiso 1 1 calc R U . . . C2 C 0.0370(3) 0.5981(2) 0.1219(3) 0.0621(16) Uani 1 1 d . . . . . H2A H -0.0128 0.5824 0.1149 0.075 Uiso 1 1 calc R U . . . H2B H 0.0228 0.6265 0.1224 0.075 Uiso 1 1 calc R U . . . C3 C 0.0303(3) 0.6060(2) 0.0169(3) 0.0637(17) Uani 1 1 d . . . . . H3A H 0.0386 0.6350 0.0149 0.076 Uiso 1 1 calc R U . . . H3B H -0.0272 0.6012 0.0128 0.076 Uiso 1 1 calc R U . . . C4 C 0.0568(3) 0.5854(2) -0.0336(3) 0.0647(17) Uani 1 1 d . . . . . H4A H 0.0532 0.5563 -0.0293 0.078 Uiso 1 1 calc R U . . . H4B H 0.0213 0.5931 -0.0725 0.078 Uiso 1 1 calc R U . . . C5 C 0.1681(3) 0.57420(17) -0.0750(2) 0.0492(13) Uani 1 1 d . . . . . H5A H 0.1300 0.5763 -0.1147 0.059 Uiso 1 1 calc R U . . . H5B H 0.1728 0.5459 -0.0634 0.059 Uiso 1 1 calc DR U . . . C6 C 0.2480(3) 0.58961(16) -0.0786(2) 0.0417(11) Uani 1 1 d . . . . . H6A H 0.2665 0.5738 -0.1086 0.050 Uiso 1 1 calc R U . . . H6B H 0.2415 0.6173 -0.0931 0.050 Uiso 1 1 calc R U . . . C7 C 0.2240(3) 0.58879(15) 0.2511(2) 0.0484(13) Uani 1 1 d . . . . . H7A H 0.1932 0.5844 0.2813 0.058 Uiso 1 1 calc R U . . . H7B H 0.2674 0.6076 0.2684 0.058 Uiso 1 1 calc R U . . . C8 C 0.2611(3) 0.54913(15) 0.2391(2) 0.0469(12) Uani 1 1 d . . . . . H8A H 0.2920 0.5376 0.2772 0.056 Uiso 1 1 calc R U . . . H8B H 0.2184 0.5302 0.2204 0.056 Uiso 1 1 calc R U . . . C9 C 0.3517(3) 0.51866(12) 0.19105(19) 0.0310(9) Uani 1 1 d . . . . . H9A H 0.3109 0.4986 0.1735 0.037 Uiso 1 1 calc R U . . . H9B H 0.3832 0.5086 0.2300 0.037 Uiso 1 1 calc R U . . . C10 C 0.4062(3) 0.52562(12) 0.14966(19) 0.0303(9) Uani 1 1 d . . . . . H10A H 0.4453 0.5466 0.1662 0.036 Uiso 1 1 calc R U . . . H10B H 0.4358 0.5010 0.1461 0.036 Uiso 1 1 calc R U . . . C11 C 0.4068(3) 0.54105(13) 0.0485(2) 0.0329(9) Uani 1 1 d . . . . . H11A H 0.4372 0.5163 0.0479 0.040 Uiso 1 1 calc R U . . . H11B H 0.4453 0.5631 0.0604 0.040 Uiso 1 1 calc R U . . . C12 C 0.3522(3) 0.54916(13) -0.01434(19) 0.0339(9) Uani 1 1 d . . . . . H12A H 0.3845 0.5473 -0.0440 0.041 Uiso 1 1 calc R U . . . H12B H 0.3110 0.5282 -0.0239 0.041 Uiso 1 1 calc R U . . . C13 C 0.1606(3) 0.65083(15) 0.2062(2) 0.0417(11) Uani 1 1 d . . . . . H13A H 0.1488 0.6549 0.2455 0.050 Uiso 1 1 calc R U . . . H13B H 0.1141 0.6605 0.1752 0.050 Uiso 1 1 calc R U . . . C14 C 0.2336(3) 0.67586(14) 0.2037(2) 0.0371(10) Uani 1 1 d . . . . . H14A H 0.2243 0.7040 0.2120 0.044 Uiso 1 1 calc R U . . . H14B H 0.2811 0.6665 0.2341 0.044 Uiso 1 1 calc R U . . . C15 C 0.2971(3) 0.70283(13) 0.1307(2) 0.0342(9) Uani 1 1 d . . . . . H15A H 0.3523 0.6994 0.1551 0.041 Uiso 1 1 calc R U . . . H15B H 0.2777 0.7291 0.1399 0.041 Uiso 1 1 calc R U . . . C16 C 0.2950(3) 0.70033(12) 0.06461(19) 0.0307(9) Uani 1 1 d . . . . . H16A H 0.2392 0.7012 0.0405 0.037 Uiso 1 1 calc R U . . . H16B H 0.3237 0.7232 0.0532 0.037 Uiso 1 1 calc R U . . . C17 C 0.3378(3) 0.66224(13) -0.00879(18) 0.0318(9) Uani 1 1 d . . . . . H17A H 0.3741 0.6833 -0.0158 0.038 Uiso 1 1 calc R U . . . H17B H 0.2846 0.6668 -0.0360 0.038 Uiso 1 1 calc R U . . . C18 C 0.3697(3) 0.62146(13) -0.02132(18) 0.0301(9) Uani 1 1 d . . . . . H18A H 0.3823 0.6221 -0.0607 0.036 Uiso 1 1 calc R U . . . H18B H 0.4197 0.6159 0.0092 0.036 Uiso 1 1 calc R U . . . C19 C 0.5252(3) 0.78897(19) 0.3769(2) 0.0481(13) Uani 1 1 d . . . . . H19A H 0.5408 0.7650 0.4017 0.058 Uiso 1 1 calc R U . . . H19B H 0.5041 0.8085 0.4010 0.058 Uiso 1 1 calc R U . . . C20 C 0.5999(3) 0.80650(17) 0.3618(2) 0.0481(13) Uani 1 1 d . . . . . H20A H 0.5853 0.8302 0.3362 0.058 Uiso 1 1 calc R U . . . H20B H 0.6391 0.8145 0.3989 0.058 Uiso 1 1 calc R U . . . C21 C 0.7086(3) 0.78991(15) 0.3190(2) 0.0366(10) Uani 1 1 d . . . . . H21A H 0.7454 0.7991 0.3565 0.044 Uiso 1 1 calc R U . . . H21B H 0.6984 0.8123 0.2905 0.044 Uiso 1 1 calc R U . . . C22 C 0.7465(2) 0.75569(14) 0.29289(18) 0.0337(9) Uani 1 1 d . . . . . H22A H 0.7995 0.7637 0.2882 0.040 Uiso 1 1 calc R U . . . H22B H 0.7538 0.7327 0.3202 0.040 Uiso 1 1 calc R U . . . C23 C 0.7328(2) 0.71463(13) 0.20679(19) 0.0316(9) Uani 1 1 d . . . . . H23A H 0.7399 0.6901 0.2311 0.038 Uiso 1 1 calc R U . . . H23B H 0.7860 0.7239 0.2044 0.038 Uiso 1 1 calc R U . . . C24 C 0.6809(2) 0.70586(13) 0.14365(19) 0.0309(9) Uani 1 1 d . . . . . H24A H 0.6730 0.7308 0.1203 0.037 Uiso 1 1 calc R U . . . H24B H 0.7098 0.6871 0.1237 0.037 Uiso 1 1 calc R U . . . C25 C 0.4006(3) 0.75147(17) 0.3410(2) 0.0443(12) Uani 1 1 d . . . . . H25A H 0.3507 0.7515 0.3088 0.053 Uiso 1 1 calc R U . . . H25B H 0.3880 0.7624 0.3773 0.053 Uiso 1 1 calc R U . . . C26 C 0.4295(3) 0.70850(17) 0.3534(2) 0.0455(12) Uani 1 1 d . . . . . H26A H 0.4817 0.7082 0.3831 0.055 Uiso 1 1 calc R U . . . H26B H 0.3910 0.6934 0.3699 0.055 Uiso 1 1 calc R U . . . C27 C 0.4565(3) 0.64844(15) 0.3073(2) 0.0421(11) Uani 1 1 d . . . . . H27A H 0.4155 0.6350 0.3233 0.050 Uiso 1 1 calc R U . . . H27B H 0.5086 0.6454 0.3367 0.050 Uiso 1 1 calc R U . . . C28 C 0.4603(3) 0.62949(14) 0.2487(2) 0.0371(10) Uani 1 1 d . . . . . H28A H 0.4698 0.6007 0.2544 0.045 Uiso 1 1 calc R U . . . H28B H 0.4091 0.6334 0.2187 0.045 Uiso 1 1 calc R U . . . C29 C 0.5371(3) 0.62718(13) 0.17582(19) 0.0333(9) Uani 1 1 d . . . . . H29A H 0.4895 0.6301 0.1421 0.040 Uiso 1 1 calc R U . . . H29B H 0.5460 0.5986 0.1845 0.040 Uiso 1 1 calc R U . . . C30 C 0.6105(3) 0.64530(12) 0.1593(2) 0.0317(9) Uani 1 1 d . . . . . H30A H 0.6575 0.6422 0.1935 0.038 Uiso 1 1 calc R U . . . H30B H 0.6209 0.6304 0.1251 0.038 Uiso 1 1 calc R U . . . C31 C 0.4184(3) 0.81519(15) 0.2953(2) 0.0395(11) Uani 1 1 d . . . . . H31A H 0.4584 0.8364 0.2973 0.047 Uiso 1 1 calc R U . . . H31B H 0.3811 0.8240 0.3188 0.047 Uiso 1 1 calc R U . . . C32 C 0.3717(3) 0.80954(14) 0.2298(2) 0.0350(10) Uani 1 1 d . . . . . H32A H 0.3333 0.7875 0.2268 0.042 Uiso 1 1 calc R U . . . H32B H 0.3415 0.8340 0.2149 0.042 Uiso 1 1 calc R U . . . C33 C 0.3896(3) 0.80434(13) 0.13067(19) 0.0322(9) Uani 1 1 d . . . . . H33A H 0.3723 0.8320 0.1210 0.039 Uiso 1 1 calc R U . . . H33B H 0.3420 0.7871 0.1201 0.039 Uiso 1 1 calc R U . . . C34 C 0.4491(3) 0.79204(13) 0.0948(2) 0.0341(9) Uani 1 1 d . . . . . H34A H 0.4245 0.7954 0.0516 0.041 Uiso 1 1 calc R U . . . H34B H 0.4969 0.8091 0.1058 0.041 Uiso 1 1 calc R U . . . C35 C 0.5172(3) 0.73589(13) 0.06604(18) 0.0296(9) Uani 1 1 d . . . . . H35A H 0.5644 0.7529 0.0685 0.036 Uiso 1 1 calc R U . . . H35B H 0.4836 0.7370 0.0246 0.036 Uiso 1 1 calc R U . . . C36 C 0.5440(3) 0.69292(12) 0.08211(17) 0.0281(8) Uani 1 1 d . . . . . H36A H 0.4963 0.6764 0.0804 0.034 Uiso 1 1 calc R U . . . H36B H 0.5702 0.6827 0.0517 0.034 Uiso 1 1 calc R U . . . C37 C 0.6900(2) 0.78234(13) -0.02741(17) 0.0285(8) Uani 1 1 d . . . . . H37A H 0.6486 0.7848 -0.0049 0.034 Uiso 1 1 calc R U . . . H37B H 0.6972 0.7538 -0.0345 0.034 Uiso 1 1 calc R U . . . C38 C 0.6611(3) 0.80353(13) -0.08794(18) 0.0317(9) Uani 1 1 d . . . . . H38A H 0.7038 0.8032 -0.1095 0.038 Uiso 1 1 calc R U . . . H38B H 0.6141 0.7896 -0.1127 0.038 Uiso 1 1 calc R U . . . C39 C 0.6112(3) 0.86435(14) -0.13501(18) 0.0372(10) Uani 1 1 d . . . . . H39A H 0.5660 0.8494 -0.1603 0.045 Uiso 1 1 calc R U . . . H39B H 0.6541 0.8657 -0.1562 0.045 Uiso 1 1 calc R U . . . C40 C 0.5843(3) 0.90591(15) -0.1246(2) 0.0436(12) Uani 1 1 d . . . . . H40A H 0.5566 0.9181 -0.1631 0.052 Uiso 1 1 calc R U . . . H40B H 0.5467 0.9049 -0.0987 0.052 Uiso 1 1 calc R U . . . C41 C 0.6303(4) 0.96981(16) -0.0851(3) 0.072(2) Uani 1 1 d . . . . . H41A H 0.6003 0.9697 -0.0539 0.086 Uiso 1 1 calc R U . . . H41B H 0.5958 0.9812 -0.1221 0.086 Uiso 1 1 calc R U . . . C42 C 0.7065(5) 0.99450(17) -0.0645(3) 0.084(3) Uani 1 1 d . . . . . H42A H 0.7385 0.9920 -0.0943 0.100 Uiso 1 1 calc R U . . . H42B H 0.6919 1.0228 -0.0628 0.100 Uiso 1 1 calc R U . . . C43 C 0.7782(2) 0.78807(12) 0.07390(17) 0.0243(8) Uani 1 1 d . . . . . H43A H 0.8343 0.7932 0.0952 0.029 Uiso 1 1 calc R U . . . H43B H 0.7684 0.7593 0.0766 0.029 Uiso 1 1 calc R U . . . C44 C 0.7236(2) 0.81070(11) 0.10583(18) 0.0257(8) Uani 1 1 d . . . . . H44A H 0.6671 0.8064 0.0847 0.031 Uiso 1 1 calc R U . . . H44B H 0.7320 0.8010 0.1473 0.031 Uiso 1 1 calc R U . . . C45 C 0.7169(3) 0.87432(13) 0.15161(19) 0.0320(9) Uani 1 1 d . . . . . H45A H 0.7343 0.8605 0.1905 0.038 Uiso 1 1 calc R U . . . H45B H 0.6580 0.8762 0.1411 0.038 Uiso 1 1 calc R U . . . C46 C 0.7535(3) 0.91571(14) 0.1560(2) 0.0389(10) Uani 1 1 d . . . . . H46A H 0.7400 0.9306 0.1890 0.047 Uiso 1 1 calc R U . . . H46B H 0.8122 0.9137 0.1644 0.047 Uiso 1 1 calc R U . . . C47 C 0.7530(4) 0.97695(15) 0.1050(3) 0.0620(17) Uani 1 1 d . . . . . H47A H 0.8119 0.9767 0.1167 0.074 Uiso 1 1 calc R U . . . H47B H 0.7339 0.9913 0.1360 0.074 Uiso 1 1 calc R U . . . C48 C 0.7231(5) 0.99790(16) 0.0441(3) 0.076(2) Uani 1 1 d . . . . . H48A H 0.6644 0.9956 0.0315 0.091 Uiso 1 1 calc R U . . . H48B H 0.7364 1.0264 0.0493 0.091 Uiso 1 1 calc R U . . . C49 C 0.8353(2) 0.78332(14) -0.01245(18) 0.0307(9) Uani 1 1 d . . . . . H49A H 0.8195 0.7828 -0.0566 0.037 Uiso 1 1 calc R U . . . H49B H 0.8464 0.7557 0.0016 0.037 Uiso 1 1 calc R U . . . C50 C 0.9118(3) 0.80775(14) 0.00804(18) 0.0339(10) Uani 1 1 d . . . . . H50A H 0.9260 0.8103 0.0521 0.041 Uiso 1 1 calc R U . . . H50B H 0.9561 0.7942 -0.0037 0.041 Uiso 1 1 calc R U . . . C51 C 0.9735(3) 0.86976(18) -0.0022(2) 0.0487(14) Uani 1 1 d . . . . . H51A H 1.0163 0.8559 -0.0155 0.058 Uiso 1 1 calc R U . . . H51B H 0.9903 0.8726 0.0418 0.058 Uiso 1 1 calc R U . . . C52 C 0.9592(4) 0.9103(2) -0.0311(2) 0.0612(18) Uani 1 1 d . . . . . H52A H 1.0102 0.9248 -0.0244 0.073 Uiso 1 1 calc R U . . . H52B H 0.9372 0.9073 -0.0747 0.073 Uiso 1 1 calc R U . . . C53 C 0.8880(4) 0.9722(2) -0.0311(3) 0.076(2) Uani 1 1 d . . . . . H53A H 0.8580 0.9703 -0.0735 0.092 Uiso 1 1 calc R U . . . H53B H 0.9392 0.9857 -0.0296 0.092 Uiso 1 1 calc R U . . . C54 C 0.8401(4) 0.99640(18) 0.0036(3) 0.076(2) Uani 1 1 d . . . . . H54A H 0.8678 0.9956 0.0465 0.091 Uiso 1 1 calc R U . . . H54B H 0.8386 1.0244 -0.0097 0.091 Uiso 1 1 calc R U . . . C55 C 0.1865(2) 0.87994(11) 0.49344(16) 0.0228(8) Uani 1 1 d . . . . . C56 C 0.2628(2) 0.86952(12) 0.52999(17) 0.0251(8) Uani 1 1 d . . . . . C57 C 0.3066(3) 0.83219(13) 0.51666(19) 0.0327(9) Uani 1 1 d . . . . . H57A H 0.3318 0.8378 0.4841 0.049 Uiso 1 1 calc R U . . . H57B H 0.2683 0.8105 0.5050 0.049 Uiso 1 1 calc R U . . . H57C H 0.3474 0.8246 0.5525 0.049 Uiso 1 1 calc R U . . . C58 C 0.3011(3) 0.89379(13) 0.57943(17) 0.0285(9) Uani 1 1 d . . . . . H58 H 0.3521 0.8862 0.6029 0.034 Uiso 1 1 calc R U . . . C59 C 0.2657(3) 0.92860(13) 0.59449(17) 0.0300(9) Uani 1 1 d . . . . . C60 C 0.3108(3) 0.95654(15) 0.6446(2) 0.0437(11) Uani 1 1 d . . . . . H60A H 0.3199 0.9821 0.6274 0.066 Uiso 1 1 calc R U . . . H60B H 0.3621 0.9446 0.6646 0.066 Uiso 1 1 calc R U . . . H60C H 0.2790 0.9606 0.6737 0.066 Uiso 1 1 calc R U . . . C61 C 0.1879(2) 0.93838(12) 0.56016(17) 0.0271(8) Uani 1 1 d . . . . . H61 H 0.1617 0.9610 0.5706 0.033 Uiso 1 1 calc R U . . . C62 C 0.1490(2) 0.91487(12) 0.51054(17) 0.0244(8) Uani 1 1 d . . . . . C63 C 0.0672(2) 0.92786(13) 0.47285(19) 0.0307(9) Uani 1 1 d . . . . . H63A H 0.0721 0.9370 0.4338 0.046 Uiso 1 1 calc R U . . . H63B H 0.0468 0.9495 0.4932 0.046 Uiso 1 1 calc R U . . . H63C H 0.0302 0.9054 0.4675 0.046 Uiso 1 1 calc R U . . . C64 C -0.0519(2) 0.70728(12) 0.30489(16) 0.0230(8) Uani 1 1 d . . . . . C65 C -0.0651(2) 0.68319(12) 0.25167(17) 0.0242(8) Uani 1 1 d . . . . . C66 C -0.0477(2) 0.70009(13) 0.19469(17) 0.0289(9) Uani 1 1 d . . . . . H66A H -0.0791 0.7242 0.1828 0.043 Uiso 1 1 calc R U . . . H66B H -0.0618 0.6804 0.1626 0.043 Uiso 1 1 calc R U . . . H66C H 0.0091 0.7064 0.2023 0.043 Uiso 1 1 calc R U . . . C67 C -0.0947(2) 0.64378(13) 0.25119(18) 0.0304(9) Uani 1 1 d . . . . . H67 H -0.1021 0.6285 0.2158 0.037 Uiso 1 1 calc R U . . . C68 C -0.1135(3) 0.62650(13) 0.3021(2) 0.0339(9) Uani 1 1 d . . . . . C69 C -0.1426(4) 0.58326(15) 0.3021(3) 0.0517(13) Uani 1 1 d . . . . . H69A H -0.1956 0.5808 0.2748 0.077 Uiso 1 1 calc R U . . . H69B H -0.1452 0.5759 0.3425 0.077 Uiso 1 1 calc R U . . . H69C H -0.1054 0.5656 0.2890 0.077 Uiso 1 1 calc R U . . . C70 C -0.1026(2) 0.65049(13) 0.35400(19) 0.0303(9) Uani 1 1 d . . . . . H70 H -0.1158 0.6400 0.3883 0.036 Uiso 1 1 calc R U . . . C71 C -0.0723(2) 0.68991(12) 0.35592(17) 0.0259(8) Uani 1 1 d . . . . . C72 C -0.0615(3) 0.71280(13) 0.41482(18) 0.0310(9) Uani 1 1 d . . . . . H72A H -0.0825 0.6970 0.4430 0.046 Uiso 1 1 calc R U . . . H72B H -0.0902 0.7380 0.4072 0.046 Uiso 1 1 calc R U . . . H72C H -0.0047 0.7180 0.4319 0.046 Uiso 1 1 calc R U . . . C73 C 0.1449(2) 0.81882(12) 0.10710(17) 0.0262(8) Uani 1 1 d . . . . . C74 C 0.1801(2) 0.85100(12) 0.08197(18) 0.0282(8) Uani 1 1 d . . . . . C75 C 0.1943(3) 0.89168(14) 0.1136(2) 0.0399(11) Uani 1 1 d . . . . . H75A H 0.1431 0.9029 0.1162 0.060 Uiso 1 1 calc R U . . . H75B H 0.2199 0.9096 0.0909 0.060 Uiso 1 1 calc R U . . . H75C H 0.2288 0.8883 0.1539 0.060 Uiso 1 1 calc R U . . . C76 C 0.2007(3) 0.84698(13) 0.02616(18) 0.0309(9) Uani 1 1 d . . . . . H76 H 0.2242 0.8687 0.0110 0.037 Uiso 1 1 calc R U . . . C77 C 0.1867(3) 0.81110(14) -0.00711(18) 0.0324(9) Uani 1 1 d . . . . . C78 C 0.2097(3) 0.80682(17) -0.0670(2) 0.0448(12) Uani 1 1 d . . . . . H78A H 0.1624 0.7996 -0.0984 0.067 Uiso 1 1 calc R U . . . H78B H 0.2501 0.7861 -0.0635 0.067 Uiso 1 1 calc R U . . . H78C H 0.2310 0.8320 -0.0772 0.067 Uiso 1 1 calc R U . . . C79 C 0.1503(3) 0.77975(13) 0.01672(18) 0.0303(9) Uani 1 1 d . . . . . H79 H 0.1393 0.7557 -0.0051 0.036 Uiso 1 1 calc R U . . . C80 C 0.1294(2) 0.78292(12) 0.07265(17) 0.0264(8) Uani 1 1 d . . . . . C81 C 0.0878(3) 0.74779(13) 0.09407(18) 0.0328(9) Uani 1 1 d . . . . . H81A H 0.1161 0.7409 0.1350 0.049 Uiso 1 1 calc R U . . . H81B H 0.0879 0.7250 0.0679 0.049 Uiso 1 1 calc R U . . . H81C H 0.0327 0.7550 0.0930 0.049 Uiso 1 1 calc R U . . . C82 C -0.0490(2) 0.97082(12) 0.23056(17) 0.0247(8) Uani 1 1 d . . . . . C83 C -0.1022(2) 0.99315(12) 0.25684(17) 0.0244(8) Uani 1 1 d . . . . . C84 C -0.1281(3) 0.97683(13) 0.31128(19) 0.0318(9) Uani 1 1 d . . . . . H84A H -0.1641 0.9543 0.2989 0.048 Uiso 1 1 calc R U . . . H84B H -0.1556 0.9977 0.3278 0.048 Uiso 1 1 calc R U . . . H84C H -0.0810 0.9682 0.3417 0.048 Uiso 1 1 calc R U . . . C85 C -0.1317(2) 1.03093(12) 0.23329(19) 0.0295(9) Uani 1 1 d . . . . . H85 H -0.1674 1.0449 0.2510 0.035 Uiso 1 1 calc R U . . . C86 C -0.1087(2) 1.04816(12) 0.18377(19) 0.0300(9) Uani 1 1 d . . . . . C87 C -0.1455(3) 1.08754(13) 0.1561(2) 0.0419(11) Uani 1 1 d . . . . . H87A H -0.2028 1.0840 0.1389 0.063 Uiso 1 1 calc R U . . . H87B H -0.1201 1.0957 0.1246 0.063 Uiso 1 1 calc R U . . . H87C H -0.1371 1.1080 0.1870 0.063 Uiso 1 1 calc R U . . . C88 C -0.0526(3) 1.02725(12) 0.16015(18) 0.0308(9) Uani 1 1 d . . . . . H88 H -0.0339 1.0389 0.1288 0.037 Uiso 1 1 calc R U . . . C89 C -0.0235(2) 0.98919(12) 0.18226(17) 0.0267(8) Uani 1 1 d . . . . . C90 C 0.0356(3) 0.96727(13) 0.15324(19) 0.0344(9) Uani 1 1 d . . . . . H90A H 0.0069 0.9472 0.1254 0.052 Uiso 1 1 calc R U . . . H90B H 0.0767 0.9544 0.1844 0.052 Uiso 1 1 calc R U . . . H90C H 0.0605 0.9863 0.1316 0.052 Uiso 1 1 calc R U . . . C91 C 0.1447(3) 0.44922(16) 0.1106(2) 0.0490(12) Uani 1 1 d . . . . . H91A H 0.1948 0.4547 0.1411 0.059 Uiso 1 1 calc R U . . . H91B H 0.1002 0.4500 0.1303 0.059 Uiso 1 1 calc R U . . . C92 C 0.1318(3) 0.48107(17) 0.0612(3) 0.0555(14) Uani 1 1 d . . . . . H92A H 0.0810 0.4756 0.0315 0.067 Uiso 1 1 calc R U . . . H92B H 0.1269 0.5073 0.0792 0.067 Uiso 1 1 calc R U . . . C93 C 0.4709(5) 0.8906(3) 0.0241(5) 0.103(3) Uani 1 1 d . . . . . H93 H 0.4256 0.8881 -0.0087 0.123 Uiso 0.720(8) 1 calc R U P A 1 H93A H 0.4293 0.8759 0.0339 0.123 Uiso 0.280(8) 1 calc R U P A 2 C94 C 0.4690(8) 0.9127(4) 0.0758(6) 0.099(4) Uani 0.720(8) 1 d . . P A 1 H94A H 0.4869 0.8955 0.1113 0.119 Uiso 0.720(8) 1 calc R U P A 1 H94B H 0.4133 0.9206 0.0734 0.119 Uiso 0.720(8) 1 calc R U P A 1 C94' C 0.461(2) 0.9306(11) 0.0087(15) 0.099(4) Uani 0.280(8) 1 d . . P A 2 H94C H 0.4479 0.9290 -0.0354 0.119 Uiso 0.280(8) 1 calc R U P A 2 H94D H 0.4096 0.9363 0.0181 0.119 Uiso 0.280(8) 1 calc R U P A 2 C95 C 0.5447(6) 0.8916(3) 0.2351(4) 0.100(3) Uani 1 1 d . . . . . H95 H 0.5508 0.8639 0.2301 0.120 Uiso 1 1 calc R U . . . C96 C 0.6117(6) 0.9159(3) 0.2526(4) 0.090(2) Uani 1 1 d . . . . . H96 H 0.6638 0.9051 0.2605 0.109 Uiso 1 1 calc R U . . . C97 C 0.5997(7) 0.9584(3) 0.2586(4) 0.101(3) Uani 1 1 d . . . . . H97 H 0.6441 0.9758 0.2686 0.121 Uiso 1 1 calc R U . . . C98 C 0.5227(6) 0.9734(2) 0.2497(4) 0.085(2) Uani 1 1 d . . . . . H98 H 0.5157 1.0010 0.2545 0.102 Uiso 1 1 calc R U . . . C99 C 0.4555(6) 0.9491(2) 0.2338(4) 0.086(2) Uani 1 1 d . . . . . C100 C 0.3724(6) 0.9644(3) 0.2239(4) 0.118(3) Uani 1 1 d . . . . . H10G H 0.3390 0.9528 0.1873 0.177 Uiso 1 1 calc R U . . . H10H H 0.3726 0.9933 0.2198 0.177 Uiso 1 1 calc R U . . . H10I H 0.3512 0.9573 0.2579 0.177 Uiso 1 1 calc R U . . . C101 C 0.4651(6) 0.9090(3) 0.2245(5) 0.102(3) Uani 1 1 d . . . . . H101 H 0.4195 0.8926 0.2111 0.123 Uiso 1 1 calc R U . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Nb1 0.01793(14) 0.02039(15) 0.01491(14) -0.00036(10) 0.00337(11) 0.00195(11) As1 0.0221(2) 0.0220(2) 0.01657(18) -0.00103(15) 0.00455(15) 0.00033(15) As2 0.0202(2) 0.0231(2) 0.02080(19) -0.00010(15) 0.00578(16) 0.00311(16) As3 0.0205(2) 0.0239(2) 0.01840(19) -0.00018(15) 0.00162(15) 0.00154(16) As4 0.0249(2) 0.0252(2) 0.01578(18) 0.00093(15) 0.00364(16) 0.00281(16) As5 0.0247(2) 0.0233(2) 0.01979(19) -0.00029(15) 0.00651(16) 0.00485(16) As6 0.0196(2) 0.0287(2) 0.02076(19) 0.00026(16) 0.00362(16) 0.00443(16) As7 0.0212(2) 0.0293(2) 0.0225(2) -0.00054(16) 0.00718(16) -0.00007(17) As8 0.0220(2) 0.0219(2) 0.02073(19) -0.00071(15) 0.00408(16) -0.00030(16) Zn1 0.0224(2) 0.0248(3) 0.0178(2) -0.00168(19) 0.00165(19) 0.0000(2) Zn2 0.0227(2) 0.0217(2) 0.0180(2) -0.00044(18) 0.00331(19) 0.00125(19) Zn3 0.0273(3) 0.0280(3) 0.0191(2) -0.0005(2) 0.0092(2) 0.0025(2) Zn4 0.0238(3) 0.0227(2) 0.0207(2) 0.00163(19) 0.0047(2) 0.0038(2) K1 0.0256(4) 0.0302(4) 0.0315(4) -0.0003(3) 0.0080(3) 0.0028(3) K2 0.0215(4) 0.0306(4) 0.0230(4) 0.0006(3) 0.0062(3) 0.0022(3) K3 0.0398(5) 0.0308(5) 0.0292(4) 0.0036(4) -0.0016(4) -0.0110(4) O1 0.0304(17) 0.063(2) 0.064(2) -0.0140(18) 0.0168(16) 0.0010(16) O2 0.0281(16) 0.061(2) 0.0422(18) -0.0137(16) 0.0008(14) -0.0043(15) O3 0.0403(17) 0.0245(14) 0.0348(15) 0.0034(12) 0.0172(13) 0.0069(12) O4 0.0305(15) 0.0311(15) 0.0308(14) 0.0030(12) 0.0118(12) 0.0050(12) O5 0.0410(17) 0.0307(15) 0.0352(15) -0.0045(12) 0.0192(13) -0.0003(13) O6 0.0342(15) 0.0282(14) 0.0249(14) 0.0030(11) 0.0083(12) 0.0058(12) O7 0.0389(17) 0.0464(18) 0.0281(15) 0.0088(13) 0.0148(13) 0.0067(14) O8 0.0343(16) 0.0301(15) 0.0293(14) 0.0032(12) 0.0125(12) -0.0036(12) O9 0.0233(14) 0.0474(18) 0.0313(15) -0.0069(13) 0.0069(12) -0.0016(13) O10 0.0205(13) 0.0360(15) 0.0256(13) 0.0009(11) 0.0053(11) 0.0031(11) O11 0.0286(15) 0.0377(16) 0.0299(14) -0.0006(12) 0.0075(12) 0.0068(12) O12 0.0322(15) 0.0270(14) 0.0265(14) 0.0055(11) 0.0093(11) 0.0055(12) O13 0.0356(16) 0.0330(15) 0.0195(13) 0.0005(11) 0.0024(11) -0.0052(12) O14 0.052(2) 0.0364(18) 0.0468(19) 0.0101(15) -0.0176(16) -0.0151(16) O15 0.0307(15) 0.0266(14) 0.0262(14) -0.0017(11) 0.0075(11) -0.0025(11) O16 0.0470(19) 0.0244(15) 0.0466(18) -0.0041(13) -0.0132(15) -0.0016(14) O17 0.0297(16) 0.0551(19) 0.0266(15) 0.0023(13) 0.0057(12) -0.0156(14) O18 0.072(3) 0.055(2) 0.0293(16) 0.0106(15) -0.0002(17) -0.0363(19) N1 0.043(2) 0.040(2) 0.049(2) 0.0056(18) 0.0255(19) 0.0104(18) N2 0.0312(18) 0.0343(19) 0.0236(16) -0.0023(14) 0.0048(14) -0.0008(15) N3 0.0291(19) 0.053(2) 0.0300(18) -0.0056(17) 0.0090(15) 0.0080(17) N4 0.0255(17) 0.0235(16) 0.0256(16) 0.0032(13) 0.0098(13) 0.0011(13) N5 0.0231(16) 0.0301(17) 0.0205(15) -0.0019(13) 0.0049(13) -0.0049(13) N6 0.086(4) 0.034(2) 0.057(3) 0.015(2) -0.032(3) -0.019(2) N7 0.043(2) 0.047(2) 0.039(2) 0.0001(18) -0.0011(18) -0.0013(19) N8 0.048(3) 0.061(3) 0.063(3) 0.002(2) 0.018(2) -0.001(2) N9 0.090(5) 0.150(7) 0.073(4) -0.019(4) 0.014(4) 0.031(5) N10 0.077(7) 0.140(10) 0.207(14) -0.104(10) -0.018(7) 0.033(6) N10' 0.077(7) 0.140(10) 0.207(14) -0.104(10) -0.018(7) 0.033(6) C1 0.057(3) 0.061(4) 0.077(4) 0.002(3) 0.043(3) 0.002(3) C2 0.038(3) 0.070(4) 0.087(4) -0.015(3) 0.032(3) -0.001(3) C3 0.031(3) 0.090(5) 0.065(4) -0.017(3) 0.003(3) 0.007(3) C4 0.033(3) 0.099(5) 0.059(3) -0.022(3) 0.005(2) -0.012(3) C5 0.040(3) 0.065(3) 0.039(3) -0.017(2) 0.003(2) -0.009(2) C6 0.044(3) 0.051(3) 0.027(2) -0.005(2) 0.0035(19) -0.004(2) C7 0.067(3) 0.044(3) 0.046(3) 0.012(2) 0.037(3) 0.022(2) C8 0.062(3) 0.038(3) 0.052(3) 0.013(2) 0.034(3) 0.012(2) C9 0.037(2) 0.023(2) 0.033(2) 0.0016(16) 0.0101(18) 0.0064(17) C10 0.029(2) 0.026(2) 0.035(2) -0.0003(17) 0.0060(17) 0.0043(17) C11 0.033(2) 0.030(2) 0.042(2) 0.0024(18) 0.0195(19) 0.0060(18) C12 0.040(2) 0.032(2) 0.034(2) -0.0075(18) 0.0175(19) -0.0002(19) C13 0.046(3) 0.045(3) 0.042(3) 0.011(2) 0.024(2) 0.020(2) C14 0.043(3) 0.037(2) 0.033(2) -0.0007(18) 0.0120(19) 0.014(2) C15 0.038(2) 0.028(2) 0.039(2) -0.0046(18) 0.0145(19) -0.0001(18) C16 0.029(2) 0.026(2) 0.036(2) 0.0030(17) 0.0060(17) 0.0017(17) C17 0.035(2) 0.035(2) 0.024(2) 0.0059(17) 0.0042(17) 0.0023(18) C18 0.033(2) 0.034(2) 0.0252(19) 0.0029(17) 0.0096(17) -0.0018(18) C19 0.034(2) 0.080(4) 0.029(2) -0.020(2) 0.0054(19) 0.009(2) C20 0.030(2) 0.065(3) 0.043(3) -0.025(2) -0.002(2) 0.007(2) C21 0.027(2) 0.050(3) 0.032(2) -0.008(2) 0.0042(18) -0.0074(19) C22 0.024(2) 0.050(3) 0.027(2) 0.0027(19) 0.0051(17) -0.0018(19) C23 0.024(2) 0.035(2) 0.038(2) 0.0044(18) 0.0116(17) 0.0057(17) C24 0.028(2) 0.037(2) 0.032(2) 0.0011(17) 0.0141(17) 0.0011(17) C25 0.036(2) 0.066(3) 0.037(2) -0.003(2) 0.020(2) 0.006(2) C26 0.045(3) 0.065(3) 0.034(2) 0.006(2) 0.023(2) 0.007(2) C27 0.040(3) 0.049(3) 0.043(3) 0.020(2) 0.020(2) 0.005(2) C28 0.036(2) 0.035(2) 0.043(2) 0.0121(19) 0.015(2) -0.0018(19) C29 0.045(3) 0.025(2) 0.031(2) 0.0018(17) 0.0110(19) -0.0015(18) C30 0.037(2) 0.024(2) 0.035(2) 0.0013(17) 0.0115(18) 0.0066(17) C31 0.030(2) 0.050(3) 0.038(2) -0.014(2) 0.0092(19) 0.005(2) C32 0.022(2) 0.044(2) 0.038(2) -0.0042(19) 0.0056(18) 0.0096(18) C33 0.034(2) 0.028(2) 0.034(2) 0.0046(17) 0.0072(18) 0.0060(17) C34 0.041(2) 0.028(2) 0.034(2) 0.0088(17) 0.0113(19) 0.0076(18) C35 0.033(2) 0.034(2) 0.0232(19) 0.0036(16) 0.0089(17) 0.0009(17) C36 0.033(2) 0.032(2) 0.0207(18) 0.0000(16) 0.0083(16) 0.0007(17) C37 0.026(2) 0.033(2) 0.026(2) -0.0068(16) 0.0063(16) -0.0065(17) C38 0.032(2) 0.038(2) 0.0237(19) -0.0092(17) 0.0045(17) -0.0048(18) C39 0.041(3) 0.046(3) 0.0198(19) 0.0056(18) -0.0027(18) -0.015(2) C40 0.040(3) 0.043(3) 0.038(2) 0.009(2) -0.009(2) -0.013(2) C41 0.082(4) 0.036(3) 0.069(4) 0.013(3) -0.034(3) -0.004(3) C42 0.111(6) 0.033(3) 0.071(4) 0.021(3) -0.043(4) -0.020(3) C43 0.026(2) 0.0253(19) 0.0228(18) 0.0007(15) 0.0083(15) -0.0021(15) C44 0.027(2) 0.0245(19) 0.0263(19) -0.0013(15) 0.0084(16) -0.0008(16) C45 0.026(2) 0.036(2) 0.033(2) -0.0069(18) 0.0060(17) 0.0043(17) C46 0.036(2) 0.035(2) 0.039(2) -0.0078(19) -0.0041(19) 0.0057(19) C47 0.079(4) 0.030(3) 0.060(3) -0.005(2) -0.016(3) -0.011(3) C48 0.096(5) 0.026(3) 0.079(4) 0.003(3) -0.029(4) -0.004(3) C49 0.030(2) 0.040(2) 0.0238(19) -0.0044(17) 0.0090(17) -0.0009(18) C50 0.028(2) 0.054(3) 0.0212(19) 0.0025(18) 0.0086(16) -0.0010(19) C51 0.036(3) 0.083(4) 0.028(2) -0.005(2) 0.009(2) -0.030(3) C52 0.068(4) 0.088(4) 0.027(2) 0.000(3) 0.012(2) -0.049(3) C53 0.099(5) 0.070(4) 0.041(3) 0.023(3) -0.019(3) -0.059(4) C54 0.103(5) 0.043(3) 0.053(3) 0.017(3) -0.034(4) -0.040(3) C55 0.0245(19) 0.0239(18) 0.0196(17) 0.0012(14) 0.0046(15) -0.0022(15) C56 0.029(2) 0.0247(19) 0.0212(18) 0.0029(15) 0.0059(16) -0.0001(16) C57 0.035(2) 0.032(2) 0.027(2) 0.0000(17) -0.0007(17) 0.0054(18) C58 0.029(2) 0.034(2) 0.0180(18) 0.0012(16) -0.0023(15) -0.0012(17) C59 0.038(2) 0.031(2) 0.0189(18) -0.0005(16) 0.0026(17) -0.0054(18) C60 0.057(3) 0.038(3) 0.029(2) -0.0084(19) -0.004(2) -0.005(2) C61 0.034(2) 0.0258(19) 0.0229(19) -0.0014(15) 0.0105(16) -0.0007(17) C62 0.027(2) 0.0271(19) 0.0208(18) 0.0027(15) 0.0087(15) -0.0011(16) C63 0.030(2) 0.031(2) 0.033(2) -0.0048(17) 0.0101(17) 0.0032(17) C64 0.0171(17) 0.0271(19) 0.0224(18) -0.0024(15) 0.0005(14) 0.0045(15) C65 0.0172(18) 0.031(2) 0.0224(18) -0.0028(15) 0.0002(14) 0.0042(15) C66 0.028(2) 0.035(2) 0.0217(18) -0.0073(16) 0.0028(16) 0.0023(17) C67 0.029(2) 0.032(2) 0.028(2) -0.0115(17) 0.0025(17) -0.0017(17) C68 0.033(2) 0.031(2) 0.037(2) -0.0077(18) 0.0090(19) -0.0087(18) C69 0.064(3) 0.039(3) 0.058(3) -0.012(2) 0.026(3) -0.020(2) C70 0.028(2) 0.033(2) 0.030(2) -0.0023(17) 0.0085(17) -0.0037(17) C71 0.025(2) 0.027(2) 0.0239(19) -0.0011(15) 0.0024(15) -0.0014(16) C72 0.040(2) 0.031(2) 0.0242(19) -0.0013(16) 0.0109(17) -0.0057(18) C73 0.025(2) 0.031(2) 0.0226(18) 0.0021(16) 0.0060(15) 0.0068(16) C74 0.032(2) 0.029(2) 0.0248(19) 0.0024(16) 0.0091(16) 0.0050(17) C75 0.059(3) 0.032(2) 0.032(2) -0.0001(18) 0.019(2) -0.005(2) C76 0.030(2) 0.039(2) 0.025(2) 0.0064(17) 0.0108(17) 0.0003(18) C77 0.030(2) 0.045(2) 0.0221(19) 0.0020(17) 0.0069(17) 0.0117(19) C78 0.052(3) 0.058(3) 0.029(2) -0.001(2) 0.020(2) 0.010(2) C79 0.032(2) 0.035(2) 0.0227(19) -0.0015(16) 0.0051(16) 0.0111(18) C80 0.028(2) 0.033(2) 0.0190(18) -0.0004(15) 0.0062(15) 0.0065(17) C81 0.041(2) 0.033(2) 0.025(2) -0.0018(17) 0.0076(18) 0.0002(19) C82 0.0256(19) 0.0235(19) 0.0229(18) 0.0001(15) 0.0020(15) -0.0006(15) C83 0.0229(19) 0.0246(19) 0.0244(19) -0.0006(15) 0.0033(15) 0.0030(15) C84 0.033(2) 0.031(2) 0.033(2) -0.0004(17) 0.0133(18) 0.0080(18) C85 0.025(2) 0.025(2) 0.036(2) -0.0038(17) 0.0034(17) 0.0022(16) C86 0.029(2) 0.0226(19) 0.032(2) 0.0049(16) -0.0046(17) -0.0025(16) C87 0.041(3) 0.027(2) 0.050(3) 0.008(2) -0.003(2) 0.0017(19) C88 0.034(2) 0.029(2) 0.026(2) 0.0033(16) -0.0003(17) -0.0082(17) C89 0.027(2) 0.0259(19) 0.0254(19) 0.0017(15) 0.0036(16) -0.0037(16) C90 0.045(3) 0.033(2) 0.030(2) 0.0039(17) 0.0181(19) -0.0016(19) C91 0.037(3) 0.055(3) 0.055(3) -0.016(2) 0.012(2) -0.007(2) C92 0.043(3) 0.045(3) 0.078(4) -0.012(3) 0.015(3) 0.000(2) C93 0.079(5) 0.102(7) 0.126(7) -0.028(6) 0.023(5) 0.019(5) C94 0.094(8) 0.118(10) 0.089(7) -0.024(7) 0.028(6) 0.019(7) C94' 0.094(8) 0.118(10) 0.089(7) -0.024(7) 0.028(6) 0.019(7) C95 0.112(7) 0.073(5) 0.127(7) -0.015(5) 0.053(6) -0.025(5) C96 0.106(6) 0.090(6) 0.087(5) -0.022(4) 0.046(5) -0.018(5) C97 0.128(8) 0.088(6) 0.098(6) -0.041(5) 0.050(6) -0.040(6) C98 0.096(6) 0.063(4) 0.091(5) -0.020(4) 0.013(5) -0.012(4) C99 0.117(7) 0.075(5) 0.080(5) 0.011(4) 0.053(5) 0.024(5) C100 0.129(9) 0.135(9) 0.100(7) 0.001(6) 0.048(6) -0.006(7) C101 0.108(7) 0.084(6) 0.131(8) -0.011(5) 0.058(6) -0.027(5) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' K K 0.3868 1.0657 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Nb Nb -0.1121 2.4826 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Zn Zn -1.5491 0.6778 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' As As -0.9300 1.0051 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag As1 Nb1 As5 99.915(15) . . ? As1 Nb1 Zn1 53.766(14) . . ? As1 Nb1 Zn2 56.130(14) . . ? As1 Nb1 Zn3 153.863(18) . . ? As1 Nb1 Zn4 104.844(16) . . ? As2 Nb1 As1 53.169(13) . . ? As2 Nb1 As5 135.794(17) . . ? As2 Nb1 Zn1 87.853(15) . . ? As2 Nb1 Zn2 81.695(15) . . ? As2 Nb1 Zn3 134.461(17) . . ? As2 Nb1 Zn4 58.563(14) . . ? As3 Nb1 As1 80.442(14) . . ? As3 Nb1 As2 52.727(13) . . ? As3 Nb1 As4 52.789(13) . . ? As3 Nb1 As5 92.592(15) . . ? As3 Nb1 As6 142.633(17) . . ? As3 Nb1 As7 144.130(16) . . ? As3 Nb1 Zn1 133.155(17) . . ? As3 Nb1 Zn2 56.980(14) . . ? As3 Nb1 Zn3 88.928(16) . . ? As3 Nb1 Zn4 82.328(15) . . ? As4 Nb1 As1 129.417(16) . . ? As4 Nb1 As2 80.754(14) . . ? As4 Nb1 As5 100.262(15) . . ? As4 Nb1 As6 136.890(16) . . ? As4 Nb1 As7 93.752(15) . . ? As4 Nb1 Zn1 154.889(18) . . ? As4 Nb1 Zn2 102.530(16) . . ? As4 Nb1 Zn3 54.621(14) . . ? As4 Nb1 Zn4 56.164(14) . . ? As5 Nb1 Zn1 103.473(16) . . ? As5 Nb1 Zn2 54.696(14) . . ? As5 Nb1 Zn3 56.501(14) . . ? As5 Nb1 Zn4 153.454(17) . . ? As6 Nb1 As1 91.304(14) . . ? As6 Nb1 As2 142.356(16) . . ? As6 Nb1 As5 52.759(13) . . ? As6 Nb1 Zn1 57.647(14) . . ? As6 Nb1 Zn2 88.149(16) . . ? As6 Nb1 Zn3 82.737(15) . . ? As6 Nb1 Zn4 134.769(18) . . ? As7 Nb1 As1 135.316(16) . . ? As7 Nb1 As2 144.223(17) . . ? As7 Nb1 As5 79.977(15) . . ? As7 Nb1 As6 52.886(13) . . ? As7 Nb1 Zn1 82.495(15) . . ? As7 Nb1 Zn2 133.659(17) . . ? As7 Nb1 Zn3 57.638(15) . . ? As7 Nb1 Zn4 88.943(16) . . ? As8 Nb1 As1 101.000(15) . . ? As8 Nb1 As2 92.737(15) . . ? As8 Nb1 As3 135.990(16) . . ? As8 Nb1 As4 100.824(15) . . ? As8 Nb1 As5 129.492(16) . . ? As8 Nb1 As6 81.300(15) . . ? As8 Nb1 As7 53.328(13) . . ? As8 Nb1 Zn1 57.205(14) . . ? As8 Nb1 Zn2 154.744(17) . . ? As8 Nb1 Zn3 103.185(17) . . ? As8 Nb1 Zn4 54.488(14) . . ? Zn1 Nb1 Zn2 97.818(16) . . ? Zn3 Nb1 Zn1 136.489(18) . . ? Zn3 Nb1 Zn2 98.110(17) . . ? Zn4 Nb1 Zn1 98.833(17) . . ? Zn4 Nb1 Zn2 135.917(18) . . ? Zn4 Nb1 Zn3 97.219(17) . . ? As2 As1 Nb1 63.405(14) . . ? As2 As1 Zn1 101.70(2) . . ? As2 As1 Zn2 91.505(18) . . ? Zn1 As1 Nb1 64.437(15) . . ? Zn1 As1 Zn2 111.44(2) . . ? Zn2 As1 Nb1 63.241(15) . . ? As1 As2 Nb1 63.426(14) . . ? As1 As2 Zn4 116.30(2) . . ? As3 As2 Nb1 63.462(14) . . ? As3 As2 As1 92.728(18) . . ? As3 As2 Zn4 89.958(19) . . ? Zn4 As2 Nb1 61.645(15) . . ? As2 As3 Nb1 63.810(14) . . ? As2 As3 Zn2 91.241(18) . . ? As4 As3 Nb1 63.621(15) . . ? As4 As3 As2 93.708(19) . . ? As4 As3 Zn2 116.81(2) . . ? Zn2 As3 Nb1 62.961(15) . . ? As3 As4 Nb1 63.591(14) . . ? As3 As4 Zn3 102.55(2) . . ? As3 As4 Zn4 92.499(19) . . ? Zn3 As4 Nb1 64.142(15) . . ? Zn3 As4 Zn4 109.44(2) . . ? Zn4 As4 Nb1 63.038(15) . . ? As6 As5 Nb1 63.551(15) . . ? As6 As5 Zn2 101.41(2) . . ? As6 As5 Zn3 92.70(2) . . ? Zn2 As5 Nb1 63.994(15) . . ? Zn2 As5 Zn3 110.00(2) . . ? Zn3 As5 Nb1 62.986(15) . . ? As5 As6 Nb1 63.690(15) . . ? As5 As6 As7 92.504(19) . . ? As5 As6 Zn1 116.94(2) . . ? As7 As6 Nb1 63.493(15) . . ? As7 As6 Zn1 91.150(19) . . ? Zn1 As6 Nb1 62.452(15) . . ? As6 As7 Nb1 63.621(15) . . ? As6 As7 As8 93.179(19) . . ? As6 As7 Zn3 91.54(2) . . ? As8 As7 Nb1 62.587(15) . . ? As8 As7 Zn3 115.10(2) . . ? Zn3 As7 Nb1 62.508(15) . . ? As7 As8 Nb1 64.085(15) . . ? As7 As8 Zn1 91.985(19) . . ? As7 As8 Zn4 102.79(2) . . ? Zn1 As8 Nb1 63.431(15) . . ? Zn4 As8 Nb1 64.609(16) . . ? Zn4 As8 Zn1 111.16(2) . . ? As1 Zn1 Nb1 61.798(15) . . ? As1 Zn1 As6 98.19(2) . . ? As1 Zn1 As8 109.31(2) . . ? As6 Zn1 Nb1 59.902(14) . . ? As8 Zn1 Nb1 59.364(14) . . ? As8 Zn1 As6 83.669(19) . . ? C55 Zn1 Nb1 165.37(11) . . ? C55 Zn1 As1 127.56(11) . . ? C55 Zn1 As6 123.30(11) . . ? C55 Zn1 As8 106.07(11) . . ? As1 Zn2 Nb1 60.630(14) . . ? As1 Zn2 As3 84.522(18) . . ? As3 Zn2 Nb1 60.059(15) . . ? As5 Zn2 Nb1 61.310(15) . . ? As5 Zn2 As1 108.79(2) . . ? As5 Zn2 As3 99.23(2) . . ? C64 Zn2 Nb1 173.71(11) . . ? C64 Zn2 As1 123.85(11) . . ? C64 Zn2 As3 114.75(10) . . ? C64 Zn2 As5 118.11(11) . . ? As4 Zn3 Nb1 61.236(15) . . ? As4 Zn3 As5 108.77(2) . . ? As4 Zn3 As7 99.87(2) . . ? As5 Zn3 Nb1 60.513(14) . . ? As5 Zn3 As7 83.252(19) . . ? As7 Zn3 Nb1 59.853(14) . . ? C73 Zn3 Nb1 174.35(11) . . ? C73 Zn3 As4 114.15(11) . . ? C73 Zn3 As5 125.10(11) . . ? C73 Zn3 As7 119.69(12) . . ? As2 Zn4 Nb1 59.793(14) . . ? As4 Zn4 Nb1 60.797(15) . . ? As4 Zn4 As2 83.835(19) . . ? As8 Zn4 Nb1 60.903(15) . . ? As8 Zn4 As2 97.86(2) . . ? As8 Zn4 As4 109.84(2) . . ? C82 Zn4 Nb1 175.91(12) . . ? C82 Zn4 As2 124.27(12) . . ? C82 Zn4 As4 117.87(11) . . ? C82 Zn4 As8 117.43(11) . . ? O1 K1 O2 61.18(11) . . ? O1 K1 O3 104.23(11) . . ? O1 K1 O4 129.84(10) . . ? O1 K1 O6 128.69(10) . . ? O1 K1 N1 59.59(11) . . ? O1 K1 N2 120.08(11) . . ? O2 K1 O3 149.29(10) . . ? O2 K1 O6 89.92(9) . . ? O2 K1 N1 119.76(11) . . ? O2 K1 N2 59.81(10) . . ? O3 K1 O6 118.01(9) . . ? O3 K1 N1 59.44(9) . . ? O3 K1 N2 121.23(9) . . ? O4 K1 O2 106.85(9) . . ? O4 K1 O3 59.85(8) . . ? O4 K1 O6 97.43(8) . . ? O4 K1 N1 118.39(10) . . ? O4 K1 N2 62.30(9) . . ? O5 K1 O1 91.58(10) . . ? O5 K1 O2 113.09(10) . . ? O5 K1 O3 93.07(9) . . ? O5 K1 O4 133.11(9) . . ? O5 K1 O6 60.10(8) . . ? O5 K1 N1 59.50(10) . . ? O5 K1 N2 120.06(9) . . ? O6 K1 N1 119.15(10) . . ? O6 K1 N2 60.49(9) . . ? N2 K1 N1 179.31(11) . . ? O7 K2 O8 59.07(9) . . ? O7 K2 N3 60.62(10) . . ? O7 K2 N4 117.88(9) . . ? O8 K2 N3 118.99(10) . . ? O8 K2 N4 59.60(8) . . ? O9 K2 O7 99.05(9) . . ? O9 K2 O8 122.57(9) . . ? O9 K2 O11 93.96(9) . . ? O9 K2 N3 59.81(9) . . ? O9 K2 N4 121.36(9) . . ? O10 K2 O7 138.39(9) . . ? O10 K2 O8 99.40(9) . . ? O10 K2 O9 60.73(8) . . ? O10 K2 O11 116.83(9) . . ? O10 K2 O12 95.88(8) . . ? O10 K2 N3 119.89(10) . . ? O10 K2 N4 61.44(9) . . ? O11 K2 O7 99.41(9) . . ? O11 K2 O8 138.45(9) . . ? O11 K2 N3 60.29(9) . . ? O11 K2 N4 120.13(9) . . ? O12 K2 O7 120.94(9) . . ? O12 K2 O8 98.98(8) . . ? O12 K2 O9 133.75(9) . . ? O12 K2 O11 59.69(8) . . ? O12 K2 N3 119.01(9) . . ? O12 K2 N4 61.14(8) . . ? N4 K2 N3 178.44(10) . . ? O13 K3 O14 59.40(9) . . ? O13 K3 O16 118.69(9) . . ? O13 K3 N5 60.31(8) . . ? O13 K3 N6 117.07(10) . . ? O14 K3 N5 118.93(9) . . ? O14 K3 N6 58.53(10) . . ? O15 K3 O13 94.67(8) . . ? O15 K3 O14 131.88(11) . . ? O15 K3 O16 59.85(9) . . ? O15 K3 O17 103.73(9) . . ? O15 K3 O18 127.12(9) . . ? O15 K3 N5 61.53(8) . . ? O15 K3 N6 119.26(13) . . ? O16 K3 O14 95.65(10) . . ? O16 K3 N5 121.00(9) . . ? O16 K3 N6 59.54(14) . . ? O17 K3 O13 96.89(9) . . ? O17 K3 O14 118.09(11) . . ? O17 K3 O16 140.61(9) . . ? O17 K3 N5 61.20(9) . . ? O17 K3 N6 120.27(14) . . ? O18 K3 O13 134.76(9) . . ? O18 K3 O14 95.24(10) . . ? O18 K3 O16 99.16(11) . . ? O18 K3 O17 60.45(11) . . ? O18 K3 N5 121.05(12) . . ? O18 K3 N6 60.79(15) . . ? N5 K3 N6 177.36(11) . . ? C2 O1 K1 123.9(3) . . ? C3 O1 K1 112.5(3) . . ? C3 O1 C2 112.2(4) . . ? C4 O2 K1 113.7(3) . . ? C5 O2 K1 114.7(3) . . ? C5 O2 C4 111.1(4) . . ? C8 O3 K1 116.5(3) . . ? C8 O3 C9 109.4(3) . . ? C9 O3 K1 113.0(2) . . ? C10 O4 K1 117.4(2) . . ? C11 O4 K1 116.4(2) . . ? C11 O4 C10 111.2(3) . . ? C14 O5 K1 122.3(2) . . ? C15 O5 K1 118.9(2) . . ? C15 O5 C14 112.5(3) . . ? C16 O6 K1 107.7(2) . . ? C17 O6 K1 114.3(2) . . ? C17 O6 C16 110.4(3) . . ? C26 O7 K2 115.6(3) . . ? C26 O7 C27 110.7(3) . . ? C27 O7 K2 115.2(2) . . ? C28 O8 K2 116.0(2) . . ? C29 O8 K2 119.2(2) . . ? C29 O8 C28 111.1(3) . . ? C20 O9 K2 119.3(2) . . ? C20 O9 C21 111.9(4) . . ? C21 O9 K2 113.8(2) . . ? C22 O10 K2 115.3(2) . . ? C23 O10 K2 117.7(2) . . ? C23 O10 C22 110.2(3) . . ? C32 O11 K2 115.8(2) . . ? C33 O11 K2 117.9(2) . . ? C33 O11 C32 111.1(3) . . ? C34 O12 K2 113.4(2) . . ? C34 O12 C35 110.9(3) . . ? C35 O12 K2 118.2(2) . . ? C38 O13 K3 114.6(2) . . ? C38 O13 C39 109.9(3) . . ? C39 O13 K3 112.3(2) . . ? C40 O14 K3 114.1(3) . . ? C40 O14 C41 110.8(4) . . ? C41 O14 K3 116.4(3) . . ? C44 O15 K3 121.0(2) . . ? C45 O15 K3 121.8(2) . . ? C45 O15 C44 112.6(3) . . ? C46 O16 K3 107.2(2) . . ? C47 O16 K3 114.6(4) . . ? C47 O16 C46 109.5(3) . . ? C50 O17 K3 113.3(2) . . ? C51 O17 K3 112.4(3) . . ? C51 O17 C50 110.0(4) . . ? C52 O18 K3 114.9(3) . . ? C53 O18 K3 115.5(4) . . ? C53 O18 C52 112.8(5) . . ? C1 N1 K1 106.2(3) . . ? C1 N1 C7 110.2(4) . . ? C1 N1 C13 111.3(4) . . ? C7 N1 K1 110.1(3) . . ? C7 N1 C13 111.3(4) . . ? C13 N1 K1 107.5(3) . . ? C6 N2 K1 112.0(3) . . ? C12 N2 K1 106.0(2) . . ? C12 N2 C6 109.3(3) . . ? C12 N2 C18 111.0(3) . . ? C18 N2 K1 109.7(2) . . ? C18 N2 C6 108.9(3) . . ? C19 N3 K2 109.4(2) . . ? C19 N3 C25 110.1(4) . . ? C19 N3 C31 109.6(4) . . ? C25 N3 K2 108.7(3) . . ? C25 N3 C31 109.0(4) . . ? C31 N3 K2 110.1(2) . . ? C24 N4 K2 108.3(2) . . ? C30 N4 K2 110.9(2) . . ? C30 N4 C24 109.0(3) . . ? C30 N4 C36 109.6(3) . . ? C36 N4 K2 108.3(2) . . ? C36 N4 C24 110.8(3) . . ? C37 N5 K3 110.7(2) . . ? C43 N5 K3 106.2(2) . . ? C43 N5 C37 110.7(3) . . ? C43 N5 C49 109.7(3) . . ? C49 N5 K3 109.7(2) . . ? C49 N5 C37 109.8(3) . . ? C42 N6 K3 110.4(3) . . ? C48 N6 K3 109.3(3) . . ? C48 N6 C42 110.5(6) . . ? C48 N6 C54 110.1(5) . . ? C54 N6 K3 106.7(4) . . ? C54 N6 C42 109.8(5) . . ? H7C N7 H7D 120.0 . . ? C91 N7 H7C 120.0 . . ? C91 N7 H7D 120.0 . . ? H8C N8 H8D 120.0 . . ? C92 N8 H8C 120.0 . . ? C92 N8 H8D 120.0 . . ? H9C N9 H9D 120.0 . . ? C93 N9 H9C 120.0 . . ? C93 N9 H9D 120.0 . . ? H10C N10 H10D 120.0 . . ? C94 N10 H10C 120.0 . . ? C94 N10 H10D 120.0 . . ? H10E N10' H10F 120.0 . . ? C94' N10' H10E 120.0 . . ? C94' N10' H10F 120.0 . . ? N1 C1 H1A 108.4 . . ? N1 C1 H1B 108.4 . . ? N1 C1 C2 115.4(5) . . ? H1A C1 H1B 107.5 . . ? C2 C1 H1A 108.4 . . ? C2 C1 H1B 108.4 . . ? O1 C2 C1 110.1(4) . . ? O1 C2 H2A 109.6 . . ? O1 C2 H2B 109.6 . . ? C1 C2 H2A 109.6 . . ? C1 C2 H2B 109.6 . . ? H2A C2 H2B 108.2 . . ? O1 C3 H3A 109.8 . . ? O1 C3 H3B 109.8 . . ? O1 C3 C4 109.4(5) . . ? H3A C3 H3B 108.2 . . ? C4 C3 H3A 109.8 . . ? C4 C3 H3B 109.8 . . ? O2 C4 C3 109.7(5) . . ? O2 C4 H4A 109.7 . . ? O2 C4 H4B 109.7 . . ? C3 C4 H4A 109.7 . . ? C3 C4 H4B 109.7 . . ? H4A C4 H4B 108.2 . . ? O2 C5 H5A 109.5 . . ? O2 C5 H5B 109.5 . . ? O2 C5 C6 110.8(4) . . ? H5A C5 H5B 108.1 . . ? C6 C5 H5A 109.5 . . ? C6 C5 H5B 109.5 . . ? N2 C6 C5 115.1(4) . . ? N2 C6 H6A 108.5 . . ? N2 C6 H6B 108.5 . . ? C5 C6 H6A 108.5 . . ? C5 C6 H6B 108.5 . . ? H6A C6 H6B 107.5 . . ? N1 C7 H7A 108.6 . . ? N1 C7 H7B 108.6 . . ? N1 C7 C8 114.4(4) . . ? H7A C7 H7B 107.6 . . ? C8 C7 H7A 108.6 . . ? C8 C7 H7B 108.6 . . ? O3 C8 C7 109.3(4) . . ? O3 C8 H8A 109.8 . . ? O3 C8 H8B 109.8 . . ? C7 C8 H8A 109.8 . . ? C7 C8 H8B 109.8 . . ? H8A C8 H8B 108.3 . . ? O3 C9 H9A 109.8 . . ? O3 C9 H9B 109.8 . . ? O3 C9 C10 109.5(3) . . ? H9A C9 H9B 108.2 . . ? C10 C9 H9A 109.8 . . ? C10 C9 H9B 109.8 . . ? O4 C10 C9 109.1(3) . . ? O4 C10 H10A 109.9 . . ? O4 C10 H10B 109.9 . . ? C9 C10 H10A 109.9 . . ? C9 C10 H10B 109.9 . . ? H10A C10 H10B 108.3 . . ? O4 C11 H11A 109.8 . . ? O4 C11 H11B 109.8 . . ? O4 C11 C12 109.3(3) . . ? H11A C11 H11B 108.3 . . ? C12 C11 H11A 109.8 . . ? C12 C11 H11B 109.8 . . ? N2 C12 C11 114.5(3) . . ? N2 C12 H12A 108.6 . . ? N2 C12 H12B 108.6 . . ? C11 C12 H12A 108.6 . . ? C11 C12 H12B 108.6 . . ? H12A C12 H12B 107.6 . . ? N1 C13 H13A 108.7 . . ? N1 C13 H13B 108.7 . . ? N1 C13 C14 114.2(4) . . ? H13A C13 H13B 107.6 . . ? C14 C13 H13A 108.7 . . ? C14 C13 H13B 108.7 . . ? O5 C14 C13 107.9(4) . . ? O5 C14 H14A 110.1 . . ? O5 C14 H14B 110.1 . . ? C13 C14 H14A 110.1 . . ? C13 C14 H14B 110.1 . . ? H14A C14 H14B 108.4 . . ? O5 C15 H15A 110.0 . . ? O5 C15 H15B 110.0 . . ? O5 C15 C16 108.4(3) . . ? H15A C15 H15B 108.4 . . ? C16 C15 H15A 110.0 . . ? C16 C15 H15B 110.0 . . ? O6 C16 C15 109.5(3) . . ? O6 C16 H16A 109.8 . . ? O6 C16 H16B 109.8 . . ? C15 C16 H16A 109.8 . . ? C15 C16 H16B 109.8 . . ? H16A C16 H16B 108.2 . . ? O6 C17 H17A 109.9 . . ? O6 C17 H17B 109.9 . . ? O6 C17 C18 109.1(3) . . ? H17A C17 H17B 108.3 . . ? C18 C17 H17A 109.9 . . ? C18 C17 H17B 109.9 . . ? N2 C18 C17 112.7(3) . . ? N2 C18 H18A 109.1 . . ? N2 C18 H18B 109.1 . . ? C17 C18 H18A 109.1 . . ? C17 C18 H18B 109.1 . . ? H18A C18 H18B 107.8 . . ? N3 C19 H19A 108.8 . . ? N3 C19 H19B 108.8 . . ? N3 C19 C20 113.9(4) . . ? H19A C19 H19B 107.7 . . ? C20 C19 H19A 108.8 . . ? C20 C19 H19B 108.8 . . ? O9 C20 C19 108.6(4) . . ? O9 C20 H20A 110.0 . . ? O9 C20 H20B 110.0 . . ? C19 C20 H20A 110.0 . . ? C19 C20 H20B 110.0 . . ? H20A C20 H20B 108.3 . . ? O9 C21 H21A 109.8 . . ? O9 C21 H21B 109.8 . . ? O9 C21 C22 109.4(4) . . ? H21A C21 H21B 108.3 . . ? C22 C21 H21A 109.8 . . ? C22 C21 H21B 109.8 . . ? O10 C22 C21 109.2(3) . . ? O10 C22 H22A 109.8 . . ? O10 C22 H22B 109.8 . . ? C21 C22 H22A 109.8 . . ? C21 C22 H22B 109.8 . . ? H22A C22 H22B 108.3 . . ? O10 C23 H23A 109.7 . . ? O10 C23 H23B 109.7 . . ? O10 C23 C24 109.6(3) . . ? H23A C23 H23B 108.2 . . ? C24 C23 H23A 109.7 . . ? C24 C23 H23B 109.7 . . ? N4 C24 C23 113.8(3) . . ? N4 C24 H24A 108.8 . . ? N4 C24 H24B 108.8 . . ? C23 C24 H24A 108.8 . . ? C23 C24 H24B 108.8 . . ? H24A C24 H24B 107.7 . . ? N3 C25 H25A 108.8 . . ? N3 C25 H25B 108.8 . . ? N3 C25 C26 113.7(4) . . ? H25A C25 H25B 107.7 . . ? C26 C25 H25A 108.8 . . ? C26 C25 H25B 108.8 . . ? O7 C26 C25 109.5(4) . . ? O7 C26 H26A 109.8 . . ? O7 C26 H26B 109.8 . . ? C25 C26 H26A 109.8 . . ? C25 C26 H26B 109.8 . . ? H26A C26 H26B 108.2 . . ? O7 C27 H27A 109.7 . . ? O7 C27 H27B 109.7 . . ? O7 C27 C28 110.0(4) . . ? H27A C27 H27B 108.2 . . ? C28 C27 H27A 109.7 . . ? C28 C27 H27B 109.7 . . ? O8 C28 C27 109.0(4) . . ? O8 C28 H28A 109.9 . . ? O8 C28 H28B 109.9 . . ? C27 C28 H28A 109.9 . . ? C27 C28 H28B 109.9 . . ? H28A C28 H28B 108.3 . . ? O8 C29 H29A 109.9 . . ? O8 C29 H29B 109.9 . . ? O8 C29 C30 108.7(3) . . ? H29A C29 H29B 108.3 . . ? C30 C29 H29A 109.9 . . ? C30 C29 H29B 109.9 . . ? N4 C30 C29 113.3(3) . . ? N4 C30 H30A 108.9 . . ? N4 C30 H30B 108.9 . . ? C29 C30 H30A 108.9 . . ? C29 C30 H30B 108.9 . . ? H30A C30 H30B 107.7 . . ? N3 C31 H31A 108.9 . . ? N3 C31 H31B 108.9 . . ? N3 C31 C32 113.4(4) . . ? H31A C31 H31B 107.7 . . ? C32 C31 H31A 108.9 . . ? C32 C31 H31B 108.9 . . ? O11 C32 C31 109.1(3) . . ? O11 C32 H32A 109.9 . . ? O11 C32 H32B 109.9 . . ? C31 C32 H32A 109.9 . . ? C31 C32 H32B 109.9 . . ? H32A C32 H32B 108.3 . . ? O11 C33 H33A 109.9 . . ? O11 C33 H33B 109.9 . . ? O11 C33 C34 109.0(3) . . ? H33A C33 H33B 108.3 . . ? C34 C33 H33A 109.9 . . ? C34 C33 H33B 109.9 . . ? O12 C34 C33 109.8(3) . . ? O12 C34 H34A 109.7 . . ? O12 C34 H34B 109.7 . . ? C33 C34 H34A 109.7 . . ? C33 C34 H34B 109.7 . . ? H34A C34 H34B 108.2 . . ? O12 C35 H35A 109.7 . . ? O12 C35 H35B 109.7 . . ? O12 C35 C36 109.8(3) . . ? H35A C35 H35B 108.2 . . ? C36 C35 H35A 109.7 . . ? C36 C35 H35B 109.7 . . ? N4 C36 C35 113.8(3) . . ? N4 C36 H36A 108.8 . . ? N4 C36 H36B 108.8 . . ? C35 C36 H36A 108.8 . . ? C35 C36 H36B 108.8 . . ? H36A C36 H36B 107.7 . . ? N5 C37 H37A 109.0 . . ? N5 C37 H37B 109.0 . . ? N5 C37 C38 112.8(3) . . ? H37A C37 H37B 107.8 . . ? C38 C37 H37A 109.0 . . ? C38 C37 H37B 109.0 . . ? O13 C38 C37 109.4(3) . . ? O13 C38 H38A 109.8 . . ? O13 C38 H38B 109.8 . . ? C37 C38 H38A 109.8 . . ? C37 C38 H38B 109.8 . . ? H38A C38 H38B 108.3 . . ? O13 C39 H39A 109.7 . . ? O13 C39 H39B 109.7 . . ? O13 C39 C40 109.8(4) . . ? H39A C39 H39B 108.2 . . ? C40 C39 H39A 109.7 . . ? C40 C39 H39B 109.7 . . ? O14 C40 C39 109.0(4) . . ? O14 C40 H40A 109.9 . . ? O14 C40 H40B 109.9 . . ? C39 C40 H40A 109.9 . . ? C39 C40 H40B 109.9 . . ? H40A C40 H40B 108.3 . . ? O14 C41 H41A 110.2 . . ? O14 C41 H41B 110.2 . . ? O14 C41 C42 107.8(6) . . ? H41A C41 H41B 108.5 . . ? C42 C41 H41A 110.2 . . ? C42 C41 H41B 110.2 . . ? N6 C42 C41 112.9(5) . . ? N6 C42 H42A 109.0 . . ? N6 C42 H42B 109.0 . . ? C41 C42 H42A 109.0 . . ? C41 C42 H42B 109.0 . . ? H42A C42 H42B 107.8 . . ? N5 C43 H43A 108.7 . . ? N5 C43 H43B 108.7 . . ? N5 C43 C44 114.4(3) . . ? H43A C43 H43B 107.6 . . ? C44 C43 H43A 108.7 . . ? C44 C43 H43B 108.7 . . ? O15 C44 C43 108.4(3) . . ? O15 C44 H44A 110.0 . . ? O15 C44 H44B 110.0 . . ? C43 C44 H44A 110.0 . . ? C43 C44 H44B 110.0 . . ? H44A C44 H44B 108.4 . . ? O15 C45 H45A 110.0 . . ? O15 C45 H45B 110.0 . . ? O15 C45 C46 108.3(4) . . ? H45A C45 H45B 108.4 . . ? C46 C45 H45A 110.0 . . ? C46 C45 H45B 110.0 . . ? O16 C46 C45 109.2(3) . . ? O16 C46 H46A 109.8 . . ? O16 C46 H46B 109.8 . . ? C45 C46 H46A 109.8 . . ? C45 C46 H46B 109.8 . . ? H46A C46 H46B 108.3 . . ? O16 C47 H47A 109.9 . . ? O16 C47 H47B 109.9 . . ? O16 C47 C48 108.7(4) . . ? H47A C47 H47B 108.3 . . ? C48 C47 H47A 109.9 . . ? C48 C47 H47B 109.9 . . ? N6 C48 C47 114.6(5) . . ? N6 C48 H48A 108.6 . . ? N6 C48 H48B 108.6 . . ? C47 C48 H48A 108.6 . . ? C47 C48 H48B 108.6 . . ? H48A C48 H48B 107.6 . . ? N5 C49 H49A 108.8 . . ? N5 C49 H49B 108.8 . . ? N5 C49 C50 113.7(3) . . ? H49A C49 H49B 107.7 . . ? C50 C49 H49A 108.8 . . ? C50 C49 H49B 108.8 . . ? O17 C50 C49 109.7(3) . . ? O17 C50 H50A 109.7 . . ? O17 C50 H50B 109.7 . . ? C49 C50 H50A 109.7 . . ? C49 C50 H50B 109.7 . . ? H50A C50 H50B 108.2 . . ? O17 C51 H51A 110.0 . . ? O17 C51 H51B 110.0 . . ? O17 C51 C52 108.7(4) . . ? H51A C51 H51B 108.3 . . ? C52 C51 H51A 110.0 . . ? C52 C51 H51B 110.0 . . ? O18 C52 C51 110.0(4) . . ? O18 C52 H52A 109.7 . . ? O18 C52 H52B 109.7 . . ? C51 C52 H52A 109.7 . . ? C51 C52 H52B 109.7 . . ? H52A C52 H52B 108.2 . . ? O18 C53 H53A 109.6 . . ? O18 C53 H53B 109.6 . . ? O18 C53 C54 110.4(5) . . ? H53A C53 H53B 108.1 . . ? C54 C53 H53A 109.6 . . ? C54 C53 H53B 109.6 . . ? N6 C54 C53 113.6(5) . . ? N6 C54 H54A 108.8 . . ? N6 C54 H54B 108.8 . . ? C53 C54 H54A 108.8 . . ? C53 C54 H54B 108.8 . . ? H54A C54 H54B 107.7 . . ? C56 C55 Zn1 126.1(3) . . ? C56 C55 C62 116.9(3) . . ? C62 C55 Zn1 116.5(3) . . ? C55 C56 C57 120.9(3) . . ? C55 C56 C58 120.7(4) . . ? C58 C56 C57 118.4(4) . . ? C56 C57 H57A 109.5 . . ? C56 C57 H57B 109.5 . . ? C56 C57 H57C 109.5 . . ? H57A C57 H57B 109.5 . . ? H57A C57 H57C 109.5 . . ? H57B C57 H57C 109.5 . . ? C56 C58 H58 118.9 . . ? C59 C58 C56 122.1(4) . . ? C59 C58 H58 118.9 . . ? C58 C59 C60 121.6(4) . . ? C58 C59 C61 117.8(4) . . ? C61 C59 C60 120.6(4) . . ? C59 C60 H60A 109.5 . . ? C59 C60 H60B 109.5 . . ? C59 C60 H60C 109.5 . . ? H60A C60 H60B 109.5 . . ? H60A C60 H60C 109.5 . . ? H60B C60 H60C 109.5 . . ? C59 C61 H61 119.5 . . ? C62 C61 C59 121.0(4) . . ? C62 C61 H61 119.5 . . ? C55 C62 C63 119.5(3) . . ? C61 C62 C55 121.4(4) . . ? C61 C62 C63 119.1(4) . . ? C62 C63 H63A 109.5 . . ? C62 C63 H63B 109.5 . . ? C62 C63 H63C 109.5 . . ? H63A C63 H63B 109.5 . . ? H63A C63 H63C 109.5 . . ? H63B C63 H63C 109.5 . . ? C65 C64 Zn2 119.0(3) . . ? C71 C64 Zn2 124.2(3) . . ? C71 C64 C65 116.8(4) . . ? C64 C65 C66 120.0(4) . . ? C67 C65 C64 120.8(4) . . ? C67 C65 C66 119.2(3) . . ? C65 C66 H66A 109.5 . . ? C65 C66 H66B 109.5 . . ? C65 C66 H66C 109.5 . . ? H66A C66 H66B 109.5 . . ? H66A C66 H66C 109.5 . . ? H66B C66 H66C 109.5 . . ? C65 C67 H67 118.9 . . ? C65 C67 C68 122.2(4) . . ? C68 C67 H67 118.9 . . ? C67 C68 C69 122.0(4) . . ? C70 C68 C67 117.2(4) . . ? C70 C68 C69 120.8(4) . . ? C68 C69 H69A 109.5 . . ? C68 C69 H69B 109.5 . . ? C68 C69 H69C 109.5 . . ? H69A C69 H69B 109.5 . . ? H69A C69 H69C 109.5 . . ? H69B C69 H69C 109.5 . . ? C68 C70 H70 119.1 . . ? C68 C70 C71 121.8(4) . . ? C71 C70 H70 119.1 . . ? C64 C71 C72 121.5(3) . . ? C70 C71 C64 121.2(4) . . ? C70 C71 C72 117.3(4) . . ? C71 C72 H72A 109.5 . . ? C71 C72 H72B 109.5 . . ? C71 C72 H72C 109.5 . . ? H72A C72 H72B 109.5 . . ? H72A C72 H72C 109.5 . . ? H72B C72 H72C 109.5 . . ? C74 C73 Zn3 122.1(3) . . ? C80 C73 Zn3 121.0(3) . . ? C80 C73 C74 116.8(3) . . ? C73 C74 C75 120.8(4) . . ? C76 C74 C73 121.4(4) . . ? C76 C74 C75 117.8(4) . . ? C74 C75 H75A 109.5 . . ? C74 C75 H75B 109.5 . . ? C74 C75 H75C 109.5 . . ? H75A C75 H75B 109.5 . . ? H75A C75 H75C 109.5 . . ? H75B C75 H75C 109.5 . . ? C74 C76 H76 119.3 . . ? C77 C76 C74 121.5(4) . . ? C77 C76 H76 119.3 . . ? C76 C77 C78 121.2(4) . . ? C79 C77 C76 117.3(4) . . ? C79 C77 C78 121.5(4) . . ? C77 C78 H78A 109.5 . . ? C77 C78 H78B 109.5 . . ? C77 C78 H78C 109.5 . . ? H78A C78 H78B 109.5 . . ? H78A C78 H78C 109.5 . . ? H78B C78 H78C 109.5 . . ? C77 C79 H79 118.8 . . ? C77 C79 C80 122.4(4) . . ? C80 C79 H79 118.8 . . ? C73 C80 C81 120.6(3) . . ? C79 C80 C73 120.6(4) . . ? C79 C80 C81 118.7(4) . . ? C80 C81 H81A 109.5 . . ? C80 C81 H81B 109.5 . . ? C80 C81 H81C 109.5 . . ? H81A C81 H81B 109.5 . . ? H81A C81 H81C 109.5 . . ? H81B C81 H81C 109.5 . . ? C83 C82 Zn4 124.3(3) . . ? C83 C82 C89 117.2(4) . . ? C89 C82 Zn4 118.5(3) . . ? C82 C83 C84 120.5(3) . . ? C85 C83 C82 120.8(4) . . ? C85 C83 C84 118.8(4) . . ? C83 C84 H84A 109.5 . . ? C83 C84 H84B 109.5 . . ? C83 C84 H84C 109.5 . . ? H84A C84 H84B 109.5 . . ? H84A C84 H84C 109.5 . . ? H84B C84 H84C 109.5 . . ? C83 C85 H85 119.2 . . ? C86 C85 C83 121.6(4) . . ? C86 C85 H85 119.2 . . ? C85 C86 C87 121.0(4) . . ? C88 C86 C85 117.6(4) . . ? C88 C86 C87 121.4(4) . . ? C86 C87 H87A 109.5 . . ? C86 C87 H87B 109.5 . . ? C86 C87 H87C 109.5 . . ? H87A C87 H87B 109.5 . . ? H87A C87 H87C 109.5 . . ? H87B C87 H87C 109.5 . . ? C86 C88 H88 119.2 . . ? C86 C88 C89 121.6(4) . . ? C89 C88 H88 119.2 . . ? C82 C89 C90 119.8(4) . . ? C88 C89 C82 121.1(4) . . ? C88 C89 C90 119.2(4) . . ? C89 C90 H90A 109.5 . . ? C89 C90 H90B 109.5 . . ? C89 C90 H90C 109.5 . . ? H90A C90 H90B 109.5 . . ? H90A C90 H90C 109.5 . . ? H90B C90 H90C 109.5 . . ? N7 C91 H91A 109.6 . . ? N7 C91 H91B 109.6 . . ? N7 C91 C92 110.1(4) . . ? H91A C91 H91B 108.1 . . ? C92 C91 H91A 109.6 . . ? C92 C91 H91B 109.6 . . ? N8 C92 C91 113.8(5) . . ? N8 C92 H92A 108.8 . . ? N8 C92 H92B 108.8 . . ? C91 C92 H92A 108.8 . . ? C91 C92 H92B 108.8 . . ? H92A C92 H92B 107.7 . . ? N9 C93 H93 122.2 . . ? N9 C93 H93A 121.1 . . ? C94 C93 N9 115.6(9) . . ? C94 C93 H93 122.2 . . ? C94' C93 N9 117.9(16) . . ? C94' C93 H93A 121.1 . . ? N10 C94 H94A 108.9 . . ? N10 C94 H94B 108.9 . . ? C93 C94 N10 113.5(11) . . ? C93 C94 H94A 108.9 . . ? C93 C94 H94B 108.9 . . ? H94A C94 H94B 107.7 . . ? N10' C94' C93 144(4) . . ? N10' C94' H94C 101.0 . . ? N10' C94' H94D 101.0 . . ? C93 C94' H94C 101.0 . . ? C93 C94' H94D 101.0 . . ? H94C C94' H94D 104.4 . . ? C96 C95 H95 120.2 . . ? C96 C95 C101 119.5(8) . . ? C101 C95 H95 120.2 . . ? C95 C96 H96 120.7 . . ? C95 C96 C97 118.5(9) . . ? C97 C96 H96 120.7 . . ? C96 C97 H97 120.1 . . ? C98 C97 C96 119.8(8) . . ? C98 C97 H97 120.1 . . ? C97 C98 H98 119.0 . . ? C97 C98 C99 122.1(8) . . ? C99 C98 H98 119.0 . . ? C98 C99 C100 123.2(8) . . ? C101 C99 C98 119.3(8) . . ? C101 C99 C100 117.5(10) . . ? C99 C100 H10G 109.5 . . ? C99 C100 H10H 109.5 . . ? C99 C100 H10I 109.5 . . ? H10G C100 H10H 109.5 . . ? H10G C100 H10I 109.5 . . ? H10H C100 H10I 109.5 . . ? C95 C101 H101 119.7 . . ? C99 C101 C95 120.7(9) . . ? C99 C101 H101 119.7 . . ? loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Nb1 As1 2.7286(5) . ? Nb1 As2 2.7281(5) . ? Nb1 As3 2.7199(5) . ? Nb1 As4 2.7206(5) . ? Nb1 As5 2.7287(5) . ? Nb1 As6 2.7255(5) . ? Nb1 As7 2.7224(5) . ? Nb1 As8 2.6869(5) . ? Nb1 Zn1 2.7930(5) . ? Nb1 Zn2 2.7957(6) . ? Nb1 Zn3 2.7928(5) . ? Nb1 Zn4 2.7780(6) . ? As1 As2 2.4419(5) . ? As1 Zn1 2.4974(6) . ? As1 Zn2 2.5997(6) . ? As2 As3 2.4193(5) . ? As2 Zn4 2.6933(6) . ? As3 As4 2.4185(6) . ? As3 Zn2 2.6318(6) . ? As4 Zn3 2.5304(6) . ? As4 Zn4 2.5889(6) . ? As5 As6 2.4234(6) . ? As5 Zn2 2.5386(6) . ? As5 Zn3 2.6141(6) . ? As6 As7 2.4260(6) . ? As6 Zn1 2.6612(6) . ? As7 As8 2.4277(6) . ? As7 Zn3 2.6593(6) . ? As8 Zn1 2.6251(6) . ? As8 Zn4 2.5030(6) . ? Zn1 C55 2.003(4) . ? Zn2 C64 2.010(4) . ? Zn3 C73 2.007(4) . ? Zn4 C82 2.003(4) . ? K1 O1 2.772(3) . ? K1 O2 2.833(3) . ? K1 O3 2.881(3) . ? K1 O4 2.782(3) . ? K1 O5 2.770(3) . ? K1 O6 2.884(3) . ? K1 N1 3.055(4) . ? K1 N2 2.990(3) . ? K2 O7 2.853(3) . ? K2 O8 2.861(3) . ? K2 O9 2.829(3) . ? K2 O10 2.772(3) . ? K2 O11 2.833(3) . ? K2 O12 2.819(3) . ? K2 N3 3.020(4) . ? K2 N4 2.985(3) . ? K3 O13 2.880(3) . ? K3 O14 2.911(3) . ? K3 O15 2.705(3) . ? K3 O16 2.898(4) . ? K3 O17 2.839(3) . ? K3 O18 2.810(4) . ? K3 N5 2.985(3) . ? K3 N6 3.079(5) . ? O1 C2 1.433(7) . ? O1 C3 1.421(7) . ? O2 C4 1.420(6) . ? O2 C5 1.418(6) . ? O3 C8 1.418(5) . ? O3 C9 1.434(5) . ? O4 C10 1.426(5) . ? O4 C11 1.425(5) . ? O5 C14 1.422(5) . ? O5 C15 1.422(5) . ? O6 C16 1.427(5) . ? O6 C17 1.426(5) . ? O7 C26 1.422(5) . ? O7 C27 1.425(6) . ? O8 C28 1.427(5) . ? O8 C29 1.424(5) . ? O9 C20 1.420(5) . ? O9 C21 1.424(5) . ? O10 C22 1.435(5) . ? O10 C23 1.420(5) . ? O11 C32 1.429(5) . ? O11 C33 1.418(5) . ? O12 C34 1.435(5) . ? O12 C35 1.436(5) . ? O13 C38 1.422(5) . ? O13 C39 1.429(5) . ? O14 C40 1.426(5) . ? O14 C41 1.430(7) . ? O15 C44 1.420(5) . ? O15 C45 1.418(5) . ? O16 C46 1.429(5) . ? O16 C47 1.425(6) . ? O17 C50 1.431(6) . ? O17 C51 1.427(5) . ? O18 C52 1.428(8) . ? O18 C53 1.427(7) . ? N1 C1 1.461(7) . ? N1 C7 1.464(6) . ? N1 C13 1.467(6) . ? N2 C6 1.472(5) . ? N2 C12 1.467(5) . ? N2 C18 1.468(5) . ? N3 C19 1.469(6) . ? N3 C25 1.474(6) . ? N3 C31 1.474(6) . ? N4 C24 1.478(5) . ? N4 C30 1.476(5) . ? N4 C36 1.477(5) . ? N5 C37 1.472(5) . ? N5 C43 1.464(5) . ? N5 C49 1.469(5) . ? N6 C42 1.478(7) . ? N6 C48 1.455(10) . ? N6 C54 1.461(9) . ? N7 H7C 0.8600 . ? N7 H7D 0.8600 . ? N7 C91 1.455(6) . ? N8 H8C 0.8600 . ? N8 H8D 0.8600 . ? N8 C92 1.432(7) . ? N9 H9C 0.8600 . ? N9 H9D 0.8600 . ? N9 C93 1.458(10) . ? N10 H10C 0.8600 . ? N10 H10D 0.8600 . ? N10 C94 1.492(17) . ? N10' H10E 0.8600 . ? N10' H10F 0.8600 . ? N10' C94' 1.14(4) . ? C1 H1A 0.9700 . ? C1 H1B 0.9700 . ? C1 C2 1.487(9) . ? C2 H2A 0.9700 . ? C2 H2B 0.9700 . ? C3 H3A 0.9700 . ? C3 H3B 0.9700 . ? C3 C4 1.498(8) . ? C4 H4A 0.9700 . ? C4 H4B 0.9700 . ? C5 H5A 0.9700 . ? C5 H5B 0.9700 . ? C5 C6 1.472(7) . ? C6 H6A 0.9700 . ? C6 H6B 0.9700 . ? C7 H7A 0.9700 . ? C7 H7B 0.9700 . ? C7 C8 1.509(6) . ? C8 H8A 0.9700 . ? C8 H8B 0.9700 . ? C9 H9A 0.9700 . ? C9 H9B 0.9700 . ? C9 C10 1.492(6) . ? C10 H10A 0.9700 . ? C10 H10B 0.9700 . ? C11 H11A 0.9700 . ? C11 H11B 0.9700 . ? C11 C12 1.517(6) . ? C12 H12A 0.9700 . ? C12 H12B 0.9700 . ? C13 H13A 0.9700 . ? C13 H13B 0.9700 . ? C13 C14 1.504(7) . ? C14 H14A 0.9700 . ? C14 H14B 0.9700 . ? C15 H15A 0.9700 . ? C15 H15B 0.9700 . ? C15 C16 1.493(6) . ? C16 H16A 0.9700 . ? C16 H16B 0.9700 . ? C17 H17A 0.9700 . ? C17 H17B 0.9700 . ? C17 C18 1.506(6) . ? C18 H18A 0.9700 . ? C18 H18B 0.9700 . ? C19 H19A 0.9700 . ? C19 H19B 0.9700 . ? C19 C20 1.511(7) . ? C20 H20A 0.9700 . ? C20 H20B 0.9700 . ? C21 H21A 0.9700 . ? C21 H21B 0.9700 . ? C21 C22 1.494(6) . ? C22 H22A 0.9700 . ? C22 H22B 0.9700 . ? C23 H23A 0.9700 . ? C23 H23B 0.9700 . ? C23 C24 1.509(6) . ? C24 H24A 0.9700 . ? C24 H24B 0.9700 . ? C25 H25A 0.9700 . ? C25 H25B 0.9700 . ? C25 C26 1.506(7) . ? C26 H26A 0.9700 . ? C26 H26B 0.9700 . ? C27 H27A 0.9700 . ? C27 H27B 0.9700 . ? C27 C28 1.484(7) . ? C28 H28A 0.9700 . ? C28 H28B 0.9700 . ? C29 H29A 0.9700 . ? C29 H29B 0.9700 . ? C29 C30 1.512(6) . ? C30 H30A 0.9700 . ? C30 H30B 0.9700 . ? C31 H31A 0.9700 . ? C31 H31B 0.9700 . ? C31 C32 1.510(6) . ? C32 H32A 0.9700 . ? C32 H32B 0.9700 . ? C33 H33A 0.9700 . ? C33 H33B 0.9700 . ? C33 C34 1.503(6) . ? C34 H34A 0.9700 . ? C34 H34B 0.9700 . ? C35 H35A 0.9700 . ? C35 H35B 0.9700 . ? C35 C36 1.508(6) . ? C36 H36A 0.9700 . ? C36 H36B 0.9700 . ? C37 H37A 0.9700 . ? C37 H37B 0.9700 . ? C37 C38 1.509(6) . ? C38 H38A 0.9700 . ? C38 H38B 0.9700 . ? C39 H39A 0.9700 . ? C39 H39B 0.9700 . ? C39 C40 1.485(7) . ? C40 H40A 0.9700 . ? C40 H40B 0.9700 . ? C41 H41A 0.9700 . ? C41 H41B 0.9700 . ? C41 C42 1.503(9) . ? C42 H42A 0.9700 . ? C42 H42B 0.9700 . ? C43 H43A 0.9700 . ? C43 H43B 0.9700 . ? C43 C44 1.510(5) . ? C44 H44A 0.9700 . ? C44 H44B 0.9700 . ? C45 H45A 0.9700 . ? C45 H45B 0.9700 . ? C45 C46 1.496(6) . ? C46 H46A 0.9700 . ? C46 H46B 0.9700 . ? C47 H47A 0.9700 . ? C47 H47B 0.9700 . ? C47 C48 1.513(8) . ? C48 H48A 0.9700 . ? C48 H48B 0.9700 . ? C49 H49A 0.9700 . ? C49 H49B 0.9700 . ? C49 C50 1.502(6) . ? C50 H50A 0.9700 . ? C50 H50B 0.9700 . ? C51 H51A 0.9700 . ? C51 H51B 0.9700 . ? C51 C52 1.484(8) . ? C52 H52A 0.9700 . ? C52 H52B 0.9700 . ? C53 H53A 0.9700 . ? C53 H53B 0.9700 . ? C53 C54 1.497(11) . ? C54 H54A 0.9700 . ? C54 H54B 0.9700 . ? C55 C56 1.396(5) . ? C55 C62 1.419(5) . ? C56 C57 1.510(6) . ? C56 C58 1.400(5) . ? C57 H57A 0.9600 . ? C57 H57B 0.9600 . ? C57 H57C 0.9600 . ? C58 H58 0.9300 . ? C58 C59 1.381(6) . ? C59 C60 1.516(6) . ? C59 C61 1.393(6) . ? C60 H60A 0.9600 . ? C60 H60B 0.9600 . ? C60 H60C 0.9600 . ? C61 H61 0.9300 . ? C61 C62 1.391(5) . ? C62 C63 1.500(6) . ? C63 H63A 0.9600 . ? C63 H63B 0.9600 . ? C63 H63C 0.9600 . ? C64 C65 1.416(5) . ? C64 C71 1.411(5) . ? C65 C66 1.504(5) . ? C65 C67 1.396(6) . ? C66 H66A 0.9600 . ? C66 H66B 0.9600 . ? C66 H66C 0.9600 . ? C67 H67 0.9300 . ? C67 C68 1.396(6) . ? C68 C69 1.513(6) . ? C68 C70 1.392(6) . ? C69 H69A 0.9600 . ? C69 H69B 0.9600 . ? C69 H69C 0.9600 . ? C70 H70 0.9300 . ? C70 C71 1.398(6) . ? C71 C72 1.506(5) . ? C72 H72A 0.9600 . ? C72 H72B 0.9600 . ? C72 H72C 0.9600 . ? C73 C74 1.409(6) . ? C73 C80 1.409(6) . ? C74 C75 1.515(6) . ? C74 C76 1.401(6) . ? C75 H75A 0.9600 . ? C75 H75B 0.9600 . ? C75 H75C 0.9600 . ? C76 H76 0.9300 . ? C76 C77 1.394(6) . ? C77 C78 1.511(6) . ? C77 C79 1.384(6) . ? C78 H78A 0.9600 . ? C78 H78B 0.9600 . ? C78 H78C 0.9600 . ? C79 H79 0.9300 . ? C79 C80 1.404(5) . ? C80 C81 1.502(6) . ? C81 H81A 0.9600 . ? C81 H81B 0.9600 . ? C81 H81C 0.9600 . ? C82 C83 1.410(5) . ? C82 C89 1.412(5) . ? C83 C84 1.510(5) . ? C83 C85 1.401(5) . ? C84 H84A 0.9600 . ? C84 H84B 0.9600 . ? C84 H84C 0.9600 . ? C85 H85 0.9300 . ? C85 C86 1.399(6) . ? C86 C87 1.511(6) . ? C86 C88 1.389(6) . ? C87 H87A 0.9600 . ? C87 H87B 0.9600 . ? C87 H87C 0.9600 . ? C88 H88 0.9300 . ? C88 C89 1.398(6) . ? C89 C90 1.516(6) . ? C90 H90A 0.9600 . ? C90 H90B 0.9600 . ? C90 H90C 0.9600 . ? C91 H91A 0.9700 . ? C91 H91B 0.9700 . ? C91 C92 1.513(8) . ? C92 H92A 0.9700 . ? C92 H92B 0.9700 . ? C93 H93 0.9300 . ? C93 H93A 0.9300 . ? C93 C94 1.390(13) . ? C93 C94' 1.37(4) . ? C94 H94A 0.9700 . ? C94 H94B 0.9700 . ? C94' H94C 0.9700 . ? C94' H94D 0.9700 . ? C95 H95 0.9300 . ? C95 C96 1.370(11) . ? C95 C101 1.433(13) . ? C96 H96 0.9300 . ? C96 C97 1.430(12) . ? C97 H97 0.9300 . ? C97 C98 1.366(12) . ? C98 H98 0.9300 . ? C98 C99 1.367(11) . ? C99 C100 1.463(12) . ? C99 C101 1.361(11) . ? C100 H10G 0.9600 . ? C100 H10H 0.9600 . ? C100 H10I 0.9600 . ? C101 H101 0.9300 . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag Zn1 C55 C56 C57 -10.4(5) . . . . ? Zn1 C55 C56 C58 168.7(3) . . . . ? Zn1 C55 C62 C61 -170.0(3) . . . . ? Zn1 C55 C62 C63 7.3(5) . . . . ? Zn2 C64 C65 C66 -4.5(5) . . . . ? Zn2 C64 C65 C67 175.8(3) . . . . ? Zn2 C64 C71 C70 -176.3(3) . . . . ? Zn2 C64 C71 C72 2.9(5) . . . . ? Zn3 C73 C74 C75 -0.3(6) . . . . ? Zn3 C73 C74 C76 -178.1(3) . . . . ? Zn3 C73 C80 C79 177.9(3) . . . . ? Zn3 C73 C80 C81 -0.2(5) . . . . ? Zn4 C82 C83 C84 3.7(5) . . . . ? Zn4 C82 C83 C85 -176.8(3) . . . . ? Zn4 C82 C89 C88 177.8(3) . . . . ? Zn4 C82 C89 C90 -1.5(5) . . . . ? K1 O1 C2 C1 -31.9(7) . . . . ? K1 O1 C3 C4 55.0(6) . . . . ? K1 O2 C4 C3 42.7(6) . . . . ? K1 O2 C5 C6 -56.9(5) . . . . ? K1 O3 C8 C7 -53.6(5) . . . . ? K1 O3 C9 C10 48.4(4) . . . . ? K1 O4 C10 C9 47.5(4) . . . . ? K1 O4 C11 C12 -48.1(4) . . . . ? K1 O5 C14 C13 -46.0(4) . . . . ? K1 O5 C15 C16 37.1(4) . . . . ? K1 O6 C16 C15 59.9(3) . . . . ? K1 O6 C17 C18 -52.8(4) . . . . ? K1 N1 C1 C2 -51.0(5) . . . . ? K1 N1 C7 C8 -40.1(5) . . . . ? K1 N1 C13 C14 -46.6(4) . . . . ? K1 N2 C6 C5 -29.6(5) . . . . ? K1 N2 C12 C11 -47.3(4) . . . . ? K1 N2 C18 C17 -45.8(4) . . . . ? K2 O7 C26 C25 52.4(4) . . . . ? K2 O7 C27 C28 -49.1(4) . . . . ? K2 O8 C28 C27 -46.5(4) . . . . ? K2 O8 C29 C30 45.8(4) . . . . ? K2 O9 C20 C19 48.0(5) . . . . ? K2 O9 C21 C22 -47.6(4) . . . . ? K2 O10 C22 C21 -48.8(4) . . . . ? K2 O10 C23 C24 49.6(4) . . . . ? K2 O11 C32 C31 55.2(4) . . . . ? K2 O11 C33 C34 -38.9(4) . . . . ? K2 O12 C34 C33 -54.4(4) . . . . ? K2 O12 C35 C36 43.9(4) . . . . ? K2 N3 C19 C20 44.8(5) . . . . ? K2 N3 C25 C26 43.7(4) . . . . ? K2 N3 C31 C32 39.8(4) . . . . ? K2 N4 C24 C23 43.1(4) . . . . ? K2 N4 C30 C29 46.0(4) . . . . ? K2 N4 C36 C35 47.9(4) . . . . ? K3 O13 C38 C37 53.4(4) . . . . ? K3 O13 C39 C40 -54.7(4) . . . . ? K3 O14 C40 C39 -46.1(5) . . . . ? K3 O14 C41 C42 56.2(6) . . . . ? K3 O15 C44 C43 44.2(4) . . . . ? K3 O15 C45 C46 -34.6(4) . . . . ? K3 O16 C46 C45 -59.1(4) . . . . ? K3 O16 C47 C48 56.7(6) . . . . ? K3 O17 C50 C49 56.0(4) . . . . ? K3 O17 C51 C52 -52.8(4) . . . . ? K3 O18 C52 C51 -45.7(4) . . . . ? K3 O18 C53 C54 53.9(5) . . . . ? K3 N5 C37 C38 42.9(4) . . . . ? K3 N5 C43 C44 47.4(3) . . . . ? K3 N5 C49 C50 39.6(4) . . . . ? K3 N6 C42 C41 42.9(8) . . . . ? K3 N6 C48 C47 40.2(6) . . . . ? K3 N6 C54 C53 43.6(5) . . . . ? O1 C3 C4 O2 -66.4(7) . . . . ? O2 C5 C6 N2 58.4(6) . . . . ? O3 C9 C10 O4 -63.9(4) . . . . ? O4 C11 C12 N2 67.3(5) . . . . ? O5 C15 C16 O6 -66.4(4) . . . . ? O6 C17 C18 N2 68.6(4) . . . . ? O7 C27 C28 O8 63.5(5) . . . . ? O8 C29 C30 N4 -61.9(4) . . . . ? O9 C21 C22 O10 64.5(4) . . . . ? O10 C23 C24 N4 -63.7(4) . . . . ? O11 C33 C34 O12 61.8(5) . . . . ? O12 C35 C36 N4 -63.5(4) . . . . ? O13 C39 C40 O14 68.8(5) . . . . ? O14 C41 C42 N6 -67.3(8) . . . . ? O15 C45 C46 O16 63.8(4) . . . . ? O16 C47 C48 N6 -67.3(7) . . . . ? O17 C51 C52 O18 66.7(5) . . . . ? O18 C53 C54 N6 -68.5(6) . . . . ? N1 C1 C2 O1 57.7(7) . . . . ? N1 C7 C8 O3 64.2(6) . . . . ? N1 C13 C14 O5 62.6(5) . . . . ? N3 C19 C20 O9 -63.0(6) . . . . ? N3 C25 C26 O7 -66.7(5) . . . . ? N3 C31 C32 O11 -64.8(5) . . . . ? N5 C37 C38 O13 -66.4(4) . . . . ? N5 C43 C44 O15 -63.0(4) . . . . ? N5 C49 C50 O17 -66.4(4) . . . . ? N7 C91 C92 N8 -60.9(6) . . . . ? N9 C93 C94 N10 66.6(14) . . . . ? N9 C93 C94' N10' -45(6) . . . . ? C1 N1 C7 C8 76.7(5) . . . . ? C1 N1 C13 C14 -162.5(4) . . . . ? C2 O1 C3 C4 -159.9(5) . . . . ? C3 O1 C2 C1 -172.5(5) . . . . ? C4 O2 C5 C6 172.4(5) . . . . ? C5 O2 C4 C3 173.9(5) . . . . ? C6 N2 C12 C11 -168.2(4) . . . . ? C6 N2 C18 C17 77.1(4) . . . . ? C7 N1 C1 C2 -170.3(4) . . . . ? C7 N1 C13 C14 74.1(5) . . . . ? C8 O3 C9 C10 179.9(4) . . . . ? C9 O3 C8 C7 176.7(4) . . . . ? C10 O4 C11 C12 173.9(3) . . . . ? C11 O4 C10 C9 -174.9(3) . . . . ? C12 N2 C6 C5 87.5(5) . . . . ? C12 N2 C18 C17 -162.5(3) . . . . ? C13 N1 C1 C2 65.7(6) . . . . ? C13 N1 C7 C8 -159.3(4) . . . . ? C14 O5 C15 C16 -170.2(3) . . . . ? C15 O5 C14 C13 162.2(3) . . . . ? C16 O6 C17 C18 -174.4(3) . . . . ? C17 O6 C16 C15 -174.7(3) . . . . ? C18 N2 C6 C5 -151.1(4) . . . . ? C18 N2 C12 C11 71.7(4) . . . . ? C19 N3 C25 C26 -76.1(5) . . . . ? C19 N3 C31 C32 160.1(4) . . . . ? C20 O9 C21 C22 173.4(4) . . . . ? C21 O9 C20 C19 -175.5(4) . . . . ? C22 O10 C23 C24 -175.4(3) . . . . ? C23 O10 C22 C21 175.0(3) . . . . ? C24 N4 C30 C29 165.1(3) . . . . ? C24 N4 C36 C35 -70.6(4) . . . . ? C25 N3 C19 C20 164.2(4) . . . . ? C25 N3 C31 C32 -79.4(5) . . . . ? C26 O7 C27 C28 177.3(4) . . . . ? C27 O7 C26 C25 -174.2(4) . . . . ? C28 O8 C29 C30 -175.2(3) . . . . ? C29 O8 C28 C27 173.1(4) . . . . ? C30 N4 C24 C23 -77.6(4) . . . . ? C30 N4 C36 C35 169.1(3) . . . . ? C31 N3 C19 C20 -75.9(5) . . . . ? C31 N3 C25 C26 163.7(4) . . . . ? C32 O11 C33 C34 -176.0(4) . . . . ? C33 O11 C32 C31 -166.7(4) . . . . ? C34 O12 C35 C36 177.3(3) . . . . ? C35 O12 C34 C33 169.8(3) . . . . ? C36 N4 C24 C23 161.7(3) . . . . ? C36 N4 C30 C29 -73.5(4) . . . . ? C37 N5 C43 C44 -72.8(4) . . . . ? C37 N5 C49 C50 161.5(3) . . . . ? C38 O13 C39 C40 176.4(4) . . . . ? C39 O13 C38 C37 -178.9(3) . . . . ? C40 O14 C41 C42 -171.1(5) . . . . ? C41 O14 C40 C39 -179.9(4) . . . . ? C42 N6 C48 C47 161.9(5) . . . . ? C42 N6 C54 C53 -76.0(6) . . . . ? C43 N5 C37 C38 160.4(3) . . . . ? C43 N5 C49 C50 -76.7(4) . . . . ? C44 O15 C45 C46 169.3(3) . . . . ? C45 O15 C44 C43 -159.5(3) . . . . ? C46 O16 C47 C48 177.2(5) . . . . ? C47 O16 C46 C45 176.1(4) . . . . ? C48 N6 C42 C41 -78.1(7) . . . . ? C48 N6 C54 C53 162.1(5) . . . . ? C49 N5 C37 C38 -78.4(4) . . . . ? C49 N5 C43 C44 165.9(3) . . . . ? C50 O17 C51 C52 180.0(4) . . . . ? C51 O17 C50 C49 -177.3(3) . . . . ? C52 O18 C53 C54 -171.1(4) . . . . ? C53 O18 C52 C51 179.1(4) . . . . ? C54 N6 C42 C41 160.2(7) . . . . ? C54 N6 C48 C47 -76.7(6) . . . . ? C55 C56 C58 C59 0.3(6) . . . . ? C56 C55 C62 C61 2.3(5) . . . . ? C56 C55 C62 C63 179.5(3) . . . . ? C56 C58 C59 C60 -174.6(4) . . . . ? C56 C58 C59 C61 2.6(6) . . . . ? C57 C56 C58 C59 179.4(4) . . . . ? C58 C59 C61 C62 -3.0(6) . . . . ? C59 C61 C62 C55 0.6(6) . . . . ? C59 C61 C62 C63 -176.7(4) . . . . ? C60 C59 C61 C62 174.2(4) . . . . ? C62 C55 C56 C57 178.2(4) . . . . ? C62 C55 C56 C58 -2.7(5) . . . . ? C64 C65 C67 C68 0.9(6) . . . . ? C65 C64 C71 C70 1.3(6) . . . . ? C65 C64 C71 C72 -179.5(4) . . . . ? C65 C67 C68 C69 -177.7(4) . . . . ? C65 C67 C68 C70 0.8(6) . . . . ? C66 C65 C67 C68 -178.8(4) . . . . ? C67 C68 C70 C71 -1.5(6) . . . . ? C68 C70 C71 C64 0.4(6) . . . . ? C68 C70 C71 C72 -178.8(4) . . . . ? C69 C68 C70 C71 177.1(4) . . . . ? C71 C64 C65 C66 177.8(3) . . . . ? C71 C64 C65 C67 -1.9(5) . . . . ? C73 C74 C76 C77 0.5(6) . . . . ? C74 C73 C80 C79 1.4(6) . . . . ? C74 C73 C80 C81 -176.6(4) . . . . ? C74 C76 C77 C78 -179.5(4) . . . . ? C74 C76 C77 C79 1.1(6) . . . . ? C75 C74 C76 C77 -177.5(4) . . . . ? C76 C77 C79 C80 -1.4(6) . . . . ? C77 C79 C80 C73 0.1(6) . . . . ? C77 C79 C80 C81 178.2(4) . . . . ? C78 C77 C79 C80 179.2(4) . . . . ? C80 C73 C74 C75 176.2(4) . . . . ? C80 C73 C74 C76 -1.7(6) . . . . ? C82 C83 C85 C86 -1.0(6) . . . . ? C83 C82 C89 C88 -2.4(6) . . . . ? C83 C82 C89 C90 178.3(4) . . . . ? C83 C85 C86 C87 175.7(4) . . . . ? C83 C85 C86 C88 -2.7(6) . . . . ? C84 C83 C85 C86 178.6(4) . . . . ? C85 C86 C88 C89 3.9(6) . . . . ? C86 C88 C89 C82 -1.3(6) . . . . ? C86 C88 C89 C90 178.0(4) . . . . ? C87 C86 C88 C89 -174.5(4) . . . . ? C89 C82 C83 C84 -176.1(4) . . . . ? C89 C82 C83 C85 3.5(6) . . . . ? C94 C93 C94' N10' 65(6) . . . . ? C94' C93 C94 N10 -46.1(18) . . . . ? C95 C96 C97 C98 3.1(13) . . . . ? C96 C95 C101 C99 -2.4(14) . . . . ? C96 C97 C98 C99 -1.3(14) . . . . ? C97 C98 C99 C100 -179.9(8) . . . . ? C97 C98 C99 C101 -2.4(13) . . . . ? C98 C99 C101 C95 4.2(14) . . . . ? C100 C99 C101 C95 -178.1(8) . . . . ? C101 C95 C96 C97 -1.3(13) . . . . ? loop_ _smtbx_masks_void_nr _smtbx_masks_void_average_x _smtbx_masks_void_average_y _smtbx_masks_void_average_z _smtbx_masks_void_volume _smtbx_masks_void_count_electrons _smtbx_masks_void_content 1 0.041 0.295 0.006 13.9 0.1 ? 2 -0.031 0.505 0.104 24.7 0.9 ? 3 0.031 0.495 0.896 24.7 0.6 ? 4 -0.041 0.705 -0.006 13.9 0.1 ? 5 0.469 -0.005 0.604 24.7 0.9 ? 6 0.459 0.795 0.494 13.9 0.1 ? 7 0.531 0.005 0.396 24.7 0.6 ? 8 0.541 0.205 0.506 13.9 0.1 ?