#------------------------------------------------------------------------------
#$Date: 2015-02-25 15:01:53 +0200 (Wed, 25 Feb 2015) $
#$Revision: 132410 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/01/05/2010569.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2010569
loop_
_publ_author_name
'Amedjkouh, Mohamed'
'Grimaldi, Jacques'
'Reboul, Jean-Pierre'
'Siri, Didier'
_publ_section_title
;Diethyl
 [(2<i>RS</i>,5<i>RS</i>)-5-isopropyl-2,3,3-trimethylpyrrolidin-2-yl]phosphonate
;
_journal_data_validation_number  IUC9900188
_journal_issue                   1
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              e31
_journal_page_last               e32
_journal_volume                  56
_journal_year                    2000
_chemical_formula_sum            'C14 H30 N O3 P'
_chemical_formula_weight         291.37
_chemical_name_systematic        ?
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_type_scat_source           International_Tables_for_Xray_Crystallography
_cell_angle_alpha                90
_cell_angle_beta                 96.47(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.552(3)
_cell_length_b                   11.853(7)
_cell_length_c                   15.615(4)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    294
_cell_measurement_theta_max      16
_cell_measurement_theta_min      10
_cell_volume                     1756.7(13)
_computing_cell_refinement       'CAD-4 Software'
_computing_data_collection       'CAD-4 Software (Enraf-Nonius, 1989)'
_computing_data_reduction        'BEGIN SDP (Frenz, 1985)'
_computing_publication_material  'CIF VAX MolEN (Fair, 1990)'
_computing_structure_refinement  'LSFM SDP (Frenz, 1985)'
_computing_structure_solution    'MULTAN80 (Main et al., 1980)'
_diffrn_ambient_temperature      294
_diffrn_measurement_device       'Enraf-Nonius CAD-4'
_diffrn_measurement_method       \q/2\q
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .030
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            3018
_diffrn_reflns_theta_max         24.70
_diffrn_reflns_theta_min         2.16
_diffrn_standards_decay_%        -9.64
_diffrn_standards_interval_time  60
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    .162
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.10
_exptl_crystal_density_meas      1.11(2)
_exptl_crystal_density_method    flotation
_exptl_crystal_description       prism
_exptl_crystal_F_000             640
_exptl_crystal_size_max          .50
_exptl_crystal_size_mid          .40
_exptl_crystal_size_min          .30
_refine_diff_density_max         .37
_refine_diff_density_min         -.20
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.167
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     173
_refine_ls_number_reflns         1861
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          .107
_refine_ls_R_factor_gt           .049
_refine_ls_shift/su_max          .003
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      'w = 4Fo^2^/[\s^2^(Fo^2^) + 0.0025Fo^4^]'
_refine_ls_wR_factor_ref         .069
_reflns_number_gt                1861
_reflns_number_total             2744
_reflns_threshold_expression     I>3\s(I)
_[local]_cod_data_source_file    qa0197.cif
_[local]_cod_data_source_block   I
_[local]_cod_cif_authors_sg_H-M  'P 21/n'
_[local]_cod_chemical_formula_sum_orig 'C14 H30 N1 O3 P1'
_cod_original_cell_volume        1757(2)
_cod_database_code               2010569
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x+1/2, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_calc_flag
P .88259(9) .11005(7) .83161(5) .0500(2) Uani ?
O1 1.0475(2) .1212(2) .85320(10) .0657(7) Uani ?
O2 .8394(2) .0554(2) .91700(10) .0685(7) Uani ?
O3 .8077(2) .2156(2) .8097(2) .0648(7) Uani ?
N .7149(2) -.0366(2) .7492(2) .0496(7) Uani ?
C1 1.1089(4) .1940(4) .9214(3) .0820(10) Uani ?
C2 .8640(3) -.0011(2) .7501(2) .0481(8) Uani ?
C3 .8749(3) .0415(3) .6561(2) .0533(9) Uani ?
C4 .7266(3) .0885(3) .6322(2) .0545(9) Uani ?
C5 .6292(3) .0080(3) .6722(2) .0488(8) Uani ?
C6 1.2599(4) .2126(4) .9098(3) .104(2) Uani ?
C7 .6958(5) .0674(4) .9410(3) .0940(10) Uani ?
C8 .6995(6) .1201(5) 1.0244(3) .120(2) Uani ?
C9 .9628(4) -.0979(3) .7811(2) .0670(10) Uani ?
C10 .9907(4) .1298(4) .6483(2) .0730(10) Uani ?
C11 .8983(4) -.0583(4) .5970(3) .0820(10) Uani ?
C12 .4930(3) .0621(3) .6952(2) .0600(10) Uani ?
C13 .4058(4) -.0214(4) .7407(3) .0830(10) Uani ?
C14 .4080(4) .1110(4) .6149(3) .100(2) Uani ?
H1 1.1022 .1584 .9765 .1011 Uiso calc
H2 1.0575 .2635 .9208 .1011 Uiso calc
H3 1.3028 .2621 .9531 .1275 Uiso calc
H4 1.3088 .1446 .9101 .1275 Uiso calc
H5 1.2641 .2497 .8544 .1275 Uiso calc
H6 .6535 -.0059 .9443 .1140 Uiso calc
H7 .6394 .1111 .8995 .1140 Uiso calc
H8 .6069 .1276 1.0393 .1477 Uiso calc
H9 .7549 .0762 1.0655 .1477 Uiso calc
H10 .7408 .1931 1.0207 .1477 Uiso calc
H11 .5966 -.0497 .6322 .0638 Uiso calc
H12 .7187 .1626 .6541 .0697 Uiso calc
H13 .7046 .0902 .5708 .0697 Uiso calc
H14 .9488 -.1179 .8383 .0828 Uiso calc
H15 .9447 -.1616 .7444 .0828 Uiso calc
H16 1.0584 -.0748 .7798 .0828 Uiso calc
H17 1.0684 .0973 .6267 .0907 Uiso calc
H18 .9531 .1894 .6107 .0907 Uiso calc
H19 1.0186 .1625 .7039 .0907 Uiso calc
H20 .8289 -.1142 .6010 .0999 Uiso calc
H21 .8944 -.0327 .5387 .0999 Uiso calc
H22 .9896 -.0903 .6132 .0999 Uiso calc
H23 .5186 .1222 .7341 .0754 Uiso calc
H24 .3209 .0156 .7547 .1036 Uiso calc
H25 .3800 -.0836 .7048 .1036 Uiso calc
H26 .4570 -.0460 .7930 .1036 Uiso calc
H27 .3234 .1440 .6304 .1256 Uiso calc
H28 .4617 .1660 .5897 .1256 Uiso calc
H29 .3838 .0517 .5744 .1256 Uiso calc
H30 .711(3) -.108(3) .752(2) .0507 Uiso ?
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
P .0492(4) .0440(4) .0561(4) .0006(4) .0022(4) .0000(4)
O1 .0500(10) .0690(10) .0760(10) -.0060(10) -.0040(10) -.0150(10)
O2 .0670(10) .082(2) .0560(10) -.0020(10) .0050(10) .0070(10)
O3 .0720(10) .0430(10) .0780(10) .0100(10) .0050(10) -.0020(10)
N .0460(10) .0420(10) .0610(10) -.0050(10) .0060(10) .0060(10)
C1 .070(2) .080(3) .091(3) -.006(2) -.011(2) -.022(2)
C2 .0400(10) .041(2) .063(2) .0020(10) .0060(10) .000(2)
C3 .048(2) .056(2) .058(2) -.004(2) .0140(10) -.003(2)
C4 .050(2) .062(2) .051(2) -.004(2) .0010(10) .007(2)
C5 .044(2) .049(2) .053(2) -.0040(10) .0030(10) .000(2)
C6 .070(3) .091(3) .144(4) -.016(2) -.021(3) -.027(3)
C7 .087(3) .127(4) .069(2) -.010(3) .012(2) .003(3)
C8 .144(4) .133(4) .086(3) -.001(4) .023(3) -.023(3)
C9 .059(2) .048(2) .092(2) .014(2) -.002(2) .000(2)
C10 .056(2) .085(2) .081(2) -.015(2) .018(2) .007(2)
C11 .079(2) .090(3) .079(2) .004(2) .024(2) -.022(2)
C12 .045(2) .065(2) .069(2) -.001(2) .003(2) .002(2)
C13 .055(2) .093(3) .107(3) -.010(2) .028(2) -.001(2)
C14 .056(2) .129(4) .112(3) .012(3) -.008(2) .033(3)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
P O1 1.579(2) yes
P O2 1.578(3) yes
P O3 1.463(2) yes
P C2 1.827(3) yes
O1 C1 1.442(5) yes
O2 C7 1.469(5) yes
N C2 1.484(4) yes
N C5 1.474(4) yes
C1 C6 1.490(6) yes
C2 C3 1.566(5) yes
C2 C9 1.529(4) yes
C3 C4 1.528(4) yes
C3 C10 1.537(5) yes
C4 C5 1.515(4) yes
C5 C12 1.528(4) yes
C7 C8 1.441(6) yes
C3 C11 1.533(5) yes
C12 C13 1.521(5) yes
C12 C14 1.529(5) yes
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
O1 P O2 101.70(10) yes
O1 P O3 115.40(10) yes
O1 P C2 103.00(10) yes
O2 P O3 112.40(10) yes
O2 P C2 106.20(10) yes
O3 P C2 116.50(10) yes
P O1 C1 121.4(2) yes
P O2 C7 121.1(2) yes
C2 N C5 110.5(2) yes
O1 C1 C6 108.5(4) yes
O2 C7 C8 110.1(4) yes
P C2 N 103.3(2) yes
P C2 C3 114.1(2) yes
P C2 C9 108.2(2) yes
N C2 C3 104.4(2) yes
N C2 C9 110.3(2) yes
C3 C2 C9 115.8(3) yes
N C5 C4 104.6(2) yes
N C5 C12 111.6(3) yes
C4 C5 C12 114.3(3) yes
C5 C4 C3 105.4(3) yes
C2 C3 C4 100.9(2) yes
C2 C3 C10 114.7(3) yes
C2 C3 C11 110.2(3) yes
C4 C3 C10 112.8(3) yes
C4 C3 C11 109.2(3) yes
C10 C3 C11 108.8(3) yes
C5 C12 C13 111.2(3) yes
C5 C12 C14 110.8(3) yes
C13 C12 C14 111.2(3) yes
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
N H30 O3 2_646 .85(4) 2.30(3) 3.078(4) 152(3) yes
_cod_database_fobs_code 2010569
_journal_paper_doi 10.1107/S0108270199016303