data_2010581
_journal_name_full  'Acta Crystallographica, Section C'
_journal_year  2000
_journal_volume  56
_journal_page_first  e10
_journal_page_last  e11
_publ_section_title
;
Bis[3-(salicylideneamino-O,N)propanolato]manganese(III) perchlorate
;
loop_
_publ_author_name
  'Zhang, Cungen'
  'Wu, Dan'
  'Sun, Jie'
  'Kong, Xiangfu'
_chemical_formula_moiety  'C20 H24 Mn N2 O4 1+, Cl O4 1-'
_chemical_formula_sum  'C20 H24 Cl Mn N2 O8 '
_chemical_formula_iupac  '[Mn (C10 H12 N O2)2] Cl O4'
_chemical_formula_weight  510.81
_symmetry_cell_setting  Monoclinic
_symmetry_space_group_name_H-M  'C 2/c'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x, y, -z+1/2'
  '-x, -y, -z'
  'x, -y, z+1/2'
  'x+1/2, y+1/2, z'
  '-x+1/2, y+1/2, -z+1/2'
  '-x+1/2, -y+1/2, -z'
  'x+1/2, -y+1/2, z+1/2'
_cell_length_a  18.359(4)
_cell_length_b  6.8980(10)
_cell_length_c  18.256(4)
_cell_angle_alpha  90.00
_cell_angle_beta  110.62(2)
_cell_angle_gamma  90.00
_cell_volume  2163.8(9)
_cell_formula_units_Z  4
_cell_measurement_temperature  293(2)
_exptl_crystal_density_diffrn  1.568
_exptl_crystal_density_meas  1.57
_diffrn_ambient_temperature  293(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_calc_attached_atom
  Mn  .7500  .2500  .5000  .0289 Uani Mn
  Cl  .5000  .6087(2)  .2500  .0483 Uani Cl
  O1  .65990(10)
  .2311(3)  .52520(10)
  .0386 Uani O
  O2  .68570(10)
  .4088(3)  .38440(10)
  .0424 Uani O
  O3  .4362(2)  .7187(5)  .2511(2)  .1085 Uani O
  O4  .5251(2)  .4928(6)  .3176(2)  .1033 Uani O
  N  .7157(2)  .0120(4)  .43150(10)
  .0343 Uani N
  C1  .6288(2)  .0655(5)  .5387(2)  .0355 Uani C
  C2  .5859(2)  .0678(6)  .5888(2)  .0457 Uani C
  C3  .5525(2)  -.0984(7)  .6031(2)  .0523 Uani C
  C4  .5589(2)  -.2720(6)  .5683(2)  .0567 Uani C
  C5  .5989(2)  -.2775(5)  .5176(2)  .0499 Uani C
  C6  .6356(2)  -.1106(5)  .5028(2)  .0394 Uani C
  C7  .6711(2)  -.1191(5)  .4440(2)  .0401 Uani C
  C8  .7342(2)  -.0039(5)  .3591(2)  .0430 Uani C
  C9  .6824(2)  .1322(6)  .2973(2)  .0504 Uani C
  C10  .6999(2)  .3465(6)  .3149(2)  .0487 Uani C
  H1  .5808  .1862  .6078  .0647 Uiso H
  H2  .5266  -.0856  .6376  .0647 Uiso H
  H3  .5353  -.3799  .5767  .0647 Uiso H
  H4  .6034  -.3884  .4917  .0647 Uiso H
  H5  .6534  -.2289  .4073  .0647 Uiso H
  H6  .7241  -.1299  .3408  .0647 Uiso H
  H7  .7896  .0324  .3704  .0647 Uiso H
  H8  .6279  .1140  .2919  .0647 Uiso H
  H9  .6890  .1110  .2499  .0647 Uiso H
  H10  .6670  .4357  .2705  .0647 Uiso H
  H11  .7567  .3810  .3262  .0647 Uiso H
  H12  .6365  .4079  .3747  .0647 Uiso H
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Mn  .0320(3)  .0279(3)  .0267(3)  .0010(3)  .0101(2)  -.0038(3)
  Cl  .0452(7)  .0571(8)  .0379(6)  .0000  .0087(5)  .0000
  O1  .0380(10)
  .0370(10)
  .0430(10)
  .0040(10)
  .0169(10)  -.0030(10)
  O2  .0440(10)
  .0460(10)
  .0350(10)
  .0090(10)
  .0110(10)
  .0040(10)
  O3  .102(3)  .111(3)  .105(3)  .047(2)  .026(2)  -.024(2)
  O4  .065(2)  .154(3)  .091(2)  .013(2)  .028(2)  .072(2)
  N  .0390(10)
  .0330(10)
  .0300(10)
  .0040(10)
  .0110(10)
  -.0030(10)
  C1  .029(2)  .043(2)  .031(2)  .0010(10)
  .0060(10)
  .0030(10)
  C2  .040(2)  .058(2)  .036(2)  .006(2)  .0090(10)
  -.001(2)
  C3  .035(2)  .084(3)  .037(2)  .000(2)  .012(2)  .014(2)
  C4  .043(2)  .061(3)  .062(2)  -.007(2)  .014(2)  .022(2)
  C5  .046(2)  .040(2)  .056(2)  .002(2)  .008(2)  .003(2)
  C6  .033(2)  .039(2)  .044(2)  .0040(10)
  .0110(10)
  .005(2)
  C7  .040(2)  .031(2)  .047(2)  .0030(10)
  .011(2)  -.006(2)
  C8  .055(2)  .040(2)  .037(2)  .001(2)  .019(2)  -.0130(10)
  C9  .050(2)  .072(3)  .026(2)  .003(2)  .010(2)  -.012(2)
  C10  .049(2)  .062(2)  .034(2)  .006(2)  .014(2)  .008(2)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Mn O1 . 1.871(2) yes
  Mn O2 . 2.300(2) yes
  Mn N . 2.026(3) yes
  Cl O3 . 1.402(3) no
  Cl O4 . 1.405(3) no
  O1 C1 . 1.339(4) no
  O2 C10 . 1.447(4) no
  N C7 . 1.293(4) yes
  N C8 . 1.480(4) yes
  C1 C2 . 1.401(5) no
  C1 C6 . 1.406(4) no
  C2 C3 . 1.367(5) no
  C3 C4 . 1.379(6) no
  C4 C5 . 1.369(5) no
  C5 C6 . 1.408(5) no
  C6 C7 . 1.439(4) no
  C8 C9 . 1.518(5) no
  C9 C10 . 1.523(6) no