data_2011567
_journal_name_full  'Acta Crystallographica, Section C'
_journal_year  2000
_journal_volume  56
_journal_page_first  1298
_journal_page_last  1299
_publ_section_title
;
 Dichlorobis[2-(o-tolyliminiomethyl)phenolato-O]zinc(II)
;
loop_
_publ_author_name
  '\"Ulk\"u, Din\,cer'
  'Ar\?ic\?i, Cengiz'
  'Tahir, M. Nawaz'
  'Atakol, Orhan'
_chemical_formula_moiety  'C28 H26 Cl2 N2 O2 Zn'
_chemical_formula_sum  'C28 H26 Cl2 N2 O2 Zn'
_chemical_formula_iupac  '[ZnCl2 (C14 H13 NO )2 ]'
_chemical_formula_weight  558.808
_symmetry_cell_setting  monoclinic
_symmetry_space_group_name_H-M  'C 2/c'
_symmetry_space_group_name_Hall  '-C 2yc'
loop_
_symmetry_equiv_pos_as_xyz
  'x,y,z'
  '-x,y,-z+1/2'
  '-x,-y,-z'
  'x,-y,z+1/2'
  'x+1/2,y+1/2,z'
  '-x+1/2,-y+1/2,-z'
  '-x+1/2,y+1/2,-z+1/2'
  'x+1/2,-y+1/2,z+1/2'
_cell_length_a  16.0495(11)
_cell_length_b  10.5240(13)
_cell_length_c  15.6324(12)
_cell_angle_alpha  90.00
_cell_angle_beta  104.232(2)
_cell_angle_gamma  90.00
_cell_volume  2559.4(4)
_cell_formula_units_Z  4
_cell_measurement_temperature  295
_exptl_crystal_density_diffrn  1.450
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_calc_flag
_atom_site_calc_attached_atom
_atom_site_type_symbol
  Zn  .500  .07524(4)  .250  .04190(10)
  Ueq . . Zn
  Cl  .61546(4)  .19710(7)  .25456(4)  .0574(2) Ueq . . Cl
  O1  .53260(10)
  -.0419(2)  .35170(10)
  .0458(4) Ueq . . O
  N1  .65480(10)
  -.0923(2)  .49080(10)
  .0388(5) Ueq . . N
  C1  .47910(10)
  -.1045(2)  .3873(2)  .0407(6) Ueq . . C
  C2  .3926(2)  -.1265(3)  .3432(2)  .0522(6) Ueq . . C
  C3  .3382(2)  -.1893(3)  .3840(2)  .0584(8) Ueq . . C
  C4  .3658(2)  -.2329(3)  .4703(2)  .0543(6) Ueq . . C
  C5  .44950(10)
  -.2158(2)  .5149(2)  .0457(6) Ueq . . C
  C6  .50790(10)
  -.1532(2)  .47470(10)
  .0375(6) Ueq . . C
  C7  .59510(10)
  -.1435(2)  .52250(10)
  .0394(6) Ueq . . C
  C8  .74390(10)
  -.0838(2)  .5332(2)  .0416(6) Ueq . . C
  C9  .7724(2)  -.0957(3)  .6239(2)  .0579(8) Ueq . . C
  C10  .8592(2)  -.0893(3)  .6633(2)  .0703(10) Ueq . . C
  C11  .9167(2)  -.0678(3)  .6126(2)  .0693(10) Ueq . . C
  C12  .8877(2)  -.0553(3)  .5231(2)  .0575(8) Ueq . . C
  C13  .8013(2)  -.0633(2)  .4806(2)  .0452(6) Ueq . . C
  C14  .7709(2)  -.0503(3)  .3819(2)  .0626(8) Ueq . . C
  H1  .637  -.057  .433  .0507 Uiso . . H
  H2  .372  -.098  .284  .0684 Uiso . . H
  H3  .280  -.203  .353  .0760 Uiso . . H
  H4  .327  -.275  .498  .0722 Uiso . . H
  H5  .469  -.246  .574  .0608 Uiso . . H
  H7  .611  -.176  .581  .0519 Uiso . . H
  H9  .732  -.110  .659  .0773 Uiso . . H
  H10  .879  -.098  .725  .0925 Uiso . . H
  H11  .976  -.062  .640  .0887 Uiso . . H
  H12  .928  -.041  .489  .0773 Uiso . . H
  H141  .717  -.009  .367  .0823 Uiso . . H
  H142  .812  -.002  .361  .0823 Uiso . . H
  H143  .766  -.132  .356  .0823 Uiso . . H
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
_atom_site_aniso_type_symbol
  Zn  .0322(2)  .0573(2)  .0347(2) 0  .00510(10)
  0 Zn
  Cl  .0425(3)  .0744(4)  .0540(3)  -.0146(3)  .0094(2)  -.0044(3) Cl
  O1  .0325(7)  .0634(9)  .0392(7)  -.0025(7)  .0042(6)  .0071(7) O
  N1  .0276(8)  .0460(10)
  .0400(9)  .0015(7)  .0031(7)  .0005(8) N
  C1  .0340(10)
  .0420(10)
  .0440(10)
  -.0002(9)  .0057(9)  -.0060(9) C
  C2  .0370(10)
  .0630(10)
  .0490(10)
  -.0050(10)
  -.0040(10)
  -.0010(10)
  C
  C3  .0310(10)
  .0570(10)
  .080(2)  -.0090(10) .0000(10)
  -.0050(10)
  C
  C4  .0380(10)
  .0520(10)
  .0750(10)
  -.0070(10)
  .0180(10)
  .0020(10)
  C
  C5  .0390(10)
  .0440(10)
  .0550(10)
  -.0010(10)
  .0135(9)  .0020(10)
  C
  C6  .0302(9)  .0400(10)
  .0410(10)
  .0016(9)  .0063(8)  -.0033(9) C
  C7  .0350(10)
  .0420(10)
  .0390(10)
  .0031(9)  .0049(8)  .0009(9) C
  C8  .0287(9)  .0410(10)
  .0510(10)
  .0030(9)  .0019(9)  -.0020(10)
  C
  C9  .0370(10)
  .079(2)  .0530(10)
  .0020(10)
  .0020(10)
  -.0020(10)
  C
  C10  .0440(10)
  .096(2)  .059(2)  .0010(10)
  -.0100(10)
  -.005(2) C
  C11  .0310(10)
  .078(2)  .087(2)  .0010(10)
  -.0080(10)
  .001(2) C
  C12  .0310(10)
  .0560(10)
  .084(2)  .0000(10)
  .0110(10)
  .0090(10)
  C
  C13  .0340(10)
  .0390(10)
  .0610(10)
  .0009(9)  .0089(9)  .0030(10)
  C
  C14  .0440(10)
  .084(2)  .0620(10)
  .0000(10)
  .0170(10)
  .0100(10)
  C
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Zn Cl . . 2.2401(7) yes
  Zn O1 . . 1.977(2) yes
  O1 C1 . . 1.311(3) yes
  N1 C7 . . 1.299(3) yes
  N1 C8 . . 1.423(3) yes
  N1 H1 . .  .95 no
  C1 C2 . . 1.409(3) no
  C1 C6 . . 1.426(3) no
  C2 C3 . . 1.371(4) no
  C2 H2 . .  .95 no
  C3 C4 . . 1.390(4) no
  C3 H3 . .  .95 no
  C4 C5 . . 1.364(3) no
  C4 H4 . .  .95 no
  C5 C6 . . 1.414(3) no
  C5 H5 . .  .95 no
  C6 C7 . . 1.418(3) no
  C7 H7 . .  .95 no
  C8 C9 . . 1.384(4) no
  C8 C13 . . 1.395(4) no
  C9 C10 . . 1.379(4) no
  C9 H9 . .  .95 no
  C10 C11 . . 1.375(5) no
  C10 H10 . .  .95 no
  C11 C12 . . 1.368(5) no
  C11 H11 . .  .95 no
  C12 C13 . . 1.384(3) no
  C12 H12 . .  .95 no
  C13 C14 . . 1.506(4) no
  C14 H141 . .  .95 no
  C14 H142 . .  .95 no
  C14 H143 . .  .95 no