data_2011793 _journal_name_full 'Acta Crystallographica, Section C' _journal_year 2001 _journal_volume 57 _journal_page_first 228 _journal_page_last 229 _publ_section_title ; Synthesis and crystal structure of Li~2~Sn(OH)~6~ ; loop_ _publ_author_name 'Yang, Shoufeng' 'Zavalij, Peter Y.' 'Whittingham, M. Stanley' _chemical_name_common 'Lithium tin hydroxide' _chemical_formula_sum 'H6 Li2 O6 Sn' _chemical_formula_structural 'Li2 Sn (O H)6' _chemical_formula_iupac 'Li2 Sn (O H)6' _chemical_formula_weight 234.62 _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M 'P 21/n' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' _cell_length_a 5.1640(6) _cell_length_b 5.4013(7) _cell_length_c 9.2982(11) _cell_angle_alpha 90 _cell_angle_beta 96.596(2) _cell_angle_gamma 90 _cell_volume 257.63(5) _cell_formula_units_Z 2 _cell_measurement_temperature 293(2) _exptl_crystal_density_diffrn 3.024 _diffrn_ambient_temperature 293(2) loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_calc_flag _atom_site_refinement_flags _atom_site_occupancy _atom_site_disorder_assembly _atom_site_disorder_group _atom_site_type_symbol Sn 0 1/2 1/2 .00939(13) Uani d S 1 . . Sn O1 .2180(4) 0.6013(4) 0.3381(2) .0141(4) Uani d . 1 . . O O2 .2822(4) 0.2304(4) 0.5395(2) .0152(4) Uani d . 1 . . O O3 .2221(4) 0.7324(3) 0.6360(2) .0146(4) Uani d . 1 . . O Li .0964(9) 0.7626(9) 0.1589(5) .0192(10) Uani d . 1 . . Li H1 .318(7) 0.659(7) 0.367(4) .024(11) Uiso d . 1 . . H H2 .246(6) 0.122(6) 0.547(4) .011(10) Uiso d . 1 . . H H3 .183(6) 0.747(6) 0.707(4) .026(10) Uiso d . 1 . . H loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Sn .00971(17) .00941(17) .00917(17) .00009(8) .00158(9) .00036(8) O1 .0136(10) .0166(11) .0124(9) -.0030(9) .0024(8) .0012(8) O2 .0162(10) .0087(10) .0208(11) .0009(8) .0023(8) .0023(9) O3 .0164(10) .0165(10) .0114(10) -.0036(7) .0035(7) -.0036(8) Li .014(2) .023(2) .021(2) -.0016(19) .0027(18) .002(2) loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag Sn O3 . 2.0388(19) yes Sn O3 3_566 2.0388(19) n Sn O1 . 2.055(2) yes Sn O1 3_566 2.055(2) n Sn O2 . 2.063(2) yes Sn O2 3_566 2.063(2) n O1 Li . 1.920(5) ? O1 Li 2_545 2.064(5) ? O2 Li 2_545 2.023(5) ? O3 Li 4_676 1.921(5) ? Li O1 . 1.920(5) yes Li O3 4_575 1.921(5) yes Li O2 2 2.023(5) yes Li O1 2 2.064(5) yes