data_2012590
_journal_name_full  'Acta Crystallographica, Section C'
_journal_year  2002
_journal_volume  58
_journal_page_first  m147
_journal_page_last  m149
_publ_section_title
;
Bis(8-quinolinolato-N,O)platinum(II) and its synthetic intermediate,
8-hydroxyquinolinium dichloro(8-quinolinolato-N,O)platinate(II) tetrahydrate
;
loop_
_publ_author_name
  'Kato, Masako'
  'Ogawa, Yuki'
  'Kozakai, Mikiko'
  'Sugimoto, Yukihiro'
_chemical_formula_moiety  'C18 H12 N2 O2 Pt'
_chemical_formula_sum  'C18 H12 N2 O2 Pt'
_chemical_formula_iupac  '[Pt (C9 H6 N O)2]'
_chemical_formula_weight  483.39
_symmetry_cell_setting  monoclinic
_symmetry_space_group_name_H-M  'P 21/n'
loop_
_symmetry_equiv_pos_as_xyz
  x,y,z
  1/2-x,1/2+y,1/2-z
  -x,-y,-z
  1/2+x,1/2-y,1/2+z
_cell_length_a  11.349(2)
_cell_length_b  4.704(2)
_cell_length_c  13.7310(10)
_cell_angle_alpha  90
_cell_angle_beta  106.430(10)
_cell_angle_gamma  90
_cell_volume  703.0(3)
_cell_formula_units_Z  2
_cell_measurement_temperature  294.2
_exptl_crystal_density_diffrn  2.283
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Pt1  .0000  .0000  .0000  .02828(9) Uani d S 1.00 . . Pt
  O1  -.1716(3)  .1457(7)  -.0629(2)  .0351(7) Uani d . 1.00 . . O
  N1  -.0042(3)  .2755(8)  .1092(3)  .0303(8) Uani d . 1.00 . . N
  C1  .0835(4)  .3380(10)
  .1928(3)  .0350(10)
  Uani d . 1.00 . . C
  C2  .0646(4)  .5360(10)
  .2631(3)  .0430(10)
  Uani d . 1.00 . . C
  C3  -.0448(4)  .6720(10)
  .2469(3)  .0400(10)
  Uani d . 1.00 . . C
  C4  -.1410(4)  .6150(10)
  .1570(3)  .0330(10)
  Uani d . 1.00 . . C
  C5  -.2580(4)  .7420(10)
  .1312(4)  .0410(10)
  Uani d . 1.00 . . C
  C6  -.3420(4)  .6680(10)
  .0424(4)  .0430(10)
  Uani d . 1.00 . . C
  C7  -.3170(4)  .4650(10)
  -.0246(4)  .0410(10)
  Uani d . 1.00 . . C
  C8  -.2039(4)  .3350(10)
  -.0036(3)  .0316(10) Uani d . 1.00 . . C
  C9  -.1157(4)  .4122(9)  .0897(3)  .0293(10) Uani d . 1.00 . . C
  H1  .1620  .2457  .2057  .0349 Uiso calc . 1.00 . . H
  H2  .1303  .5832  .3239  .0427 Uiso calc . 1.00 . . H
  H3  -.0603  .8029  .2965  .0397 Uiso calc . 1.00 . . H
  H4  -.2772  .8820  .1769  .0412 Uiso calc . 1.00 . . H
  H5  -.4212  .7566  .0246  .0428 Uiso calc . 1.00 . . H
  H6  -.3794  .4211  -.0863  .0408 Uiso calc . 1.00 . . H
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Pt1  .02730(10)
  .02680(10)
  .03090(10)
  .00010(10)
  .00834(8)  .0000(2)
  O1  .0270(10)
  .037(2)  .038(2)  .001(2)  .0020(10)
  -.003(2)
  N1  .030(2)  .028(2)  .033(2)  .001(2)  .0090(10)
  .003(2)
  C1  .031(2)  .034(3)  .039(2)  .004(2)  .008(2)  .002(2)
  C2  .042(2)  .047(4)  .037(2)  -.007(3)  .008(2)  -.008(2)
  C3  .047(3)  .037(3)  .036(2)  -.003(2)  .013(2)  -.010(2)
  C4  .038(2)  .030(2)  .035(2)  -.002(2)  .016(2)  .002(2)
  C5  .043(3)  .040(3)  .046(3)  .002(2)  .022(2)  -.001(2)
  C6  .034(2)  .044(3)  .051(3)  .012(2)  .014(2)  .006(3)
  C7  .033(2)  .039(3)  .046(2)  -.003(2)  .005(2)  .000(2)
  C8  .031(2)  .029(2)  .037(2)  .000(2)  .013(2)  .002(2)
  C9  .035(2)  .025(2)  .031(2)  -.002(2)  .014(2)  .007(2)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Pt1 O1 . . 2.014(3) yes
  Pt1 N1 . . 1.992(4) yes
  O1 C8 . . 1.325(6) no
  N1 C1 . . 1.322(5) no
  N1 C9 . . 1.377(6) no
  C1 C2 . . 1.401(7) no
  C1 H1 . .  .961 no
  C2 C3 . . 1.359(7) no
  C2 H2 . .  .974 no
  C3 C4 . . 1.423(6) no
  C3 H3 . .  .971 no
  C4 C5 . . 1.408(6) no
  C4 C9 . . 1.413(7) no
  C5 C6 . . 1.363(6) no
  C5 H4 . .  .977 no
  C6 C7 . . 1.407(8) no
  C6 H5 . .  .959 no
  C7 C8 . . 1.379(6) no
  C7 H6 . .  .961 no
  C8 C9 . . 1.432(5) no