data_2012610
_journal_name_full  'Acta Crystallographica, Section C'
_journal_year  2002
_journal_volume  58
_journal_page_first  m228
_journal_page_last  m229
_publ_section_title
;
Bis(3,5-dimethylpyrazole-\kN^2^)silver(I) nitrate
;
loop_
_publ_author_name
  'Mohamed, Ahmed A.'
  'Fackler, John P. Jr'
_chemical_formula_moiety  'C10 H16 Ag N4 1+, N1 O3 1-'
_chemical_formula_sum  'C10 H16 Ag N5 O3'
_chemical_formula_iupac  '[Ag (C5 H7 N2)2] (N O3)'
_chemical_formula_weight  362.15
_symmetry_cell_setting  triclinic
_symmetry_space_group_name_H-M  'P -1'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x, -y, -z'
_cell_length_a  10.0300(10)
_cell_length_b  11.3360(10)
_cell_length_c  13.656(2)
_cell_angle_alpha  90.99(2)
_cell_angle_beta  109.47(2)
_cell_angle_gamma  101.01(3)
_cell_volume  1431.4(3)
_cell_formula_units_Z  4
_cell_measurement_temperature  213(2)
_exptl_crystal_density_diffrn  1.680
_diffrn_ambient_temperature  293(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Ag1 1.13535(4) 1.11512(3) 1.37322(3) 0.04379(13) Uani d . 1 . . Ag
  Ag2 0.63916(4) 0.63958(3) 0.88521(3) 0.03984(13) Uani d . 1 . . Ag
  N1 1.0365(4) 1.2331(3) 1.1675(3) 0.0347(9) Uani d . 1 . . N
  H1D 0.9995 1.1620 1.1360 0.042 Uiso calc R 1 . . H
  N2 1.1037(4) 1.2546(3) 1.2720(3) 0.0354(9) Uani d . 1 . . N
  N3 1.1544(4) 0.9791(3) 1.4786(3) 0.0360(9) Uani d . 1 . . N
  N4 1.2254(4) 1.0088(3) 1.5825(3) 0.0344(9) Uani d . 1 . . N
  H4A 1.2754 1.0795 1.6088 0.041 Uiso calc R 1 . . H
  N5 0.6696(4) 0.8963(3) 0.8080(3) 0.0343(9) Uani d . 1 . . N
  H5D 0.7234 0.9255 0.8702 0.041 Uiso calc R 1 . . H
  N6 0.6055(4) 0.7774(3) 0.7813(3) 0.0344(9) Uani d . 1 . . N
  N7 0.6555(4) 0.4905(3) 0.9781(3) 0.0308(8) Uani d . 1 . . N
  N8 0.5927(4) 0.3762(3) 0.9345(3) 0.0321(9) Uani d . 1 . . N
  H8B 0.5543 0.3570 0.8684 0.039 Uiso calc R 1 . . H
  N9 0.8795(4) 0.9419(3) 1.0669(3) 0.0369(9) Uani d . 1 . . N
  N10 0.4473(5) 0.2894(3) 0.6684(3) 0.0448(11) Uani d . 1 . . N
  C1 0.9633(5) 1.3317(4) 1.0038(4) 0.0431(12) Uani d . 1 . . C
  H1A 0.9323 1.2495 0.9740 0.065 Uiso calc R 1 . . H
  H1B 1.0308 1.3750 0.9745 0.065 Uiso calc R 1 . . H
  H1C 0.8810 1.3687 0.9889 0.065 Uiso calc R 1 . . H
  C2 1.0339(5) 1.3344(3) 1.1184(4) 0.0345(10) Uani d . 1 . . C
  C3 1.1050(5) 1.4272(4) 1.1957(4) 0.0393(12) Uani d . 1 . . C
  H3A 1.1226 1.5092 1.1867 0.047 Uiso calc R 1 . . H
  C4 1.1453(5) 1.3747(4) 1.2893(4) 0.0378(11) Uani d . 1 . . C
  C5 1.2211(6) 1.4338(4) 1.3974(4) 0.0595(15) Uani d . 1 . . C
  H5A 1.2601 1.3758 1.4429 0.089 Uiso calc R 1 . . H
  H5B 1.1538 1.4649 1.4214 0.089 Uiso calc R 1 . . H
  H5C 1.2982 1.4988 1.3975 0.089 Uiso calc R 1 . . H
  C6 0.9983(6) 0.7969(4) 1.3669(4) 0.0533(14) Uani d . 1 . . C
  H6A 0.9880 0.8529 1.3143 0.080 Uiso calc R 1 . . H
  H6B 0.9047 0.7611 1.3692 0.080 Uiso calc R 1 . . H
  H6C 1.0428 0.7350 1.3507 0.080 Uiso calc R 1 . . H
  C7 1.0908(5) 0.8621(3) 1.4707(4) 0.0342(10) Uani d . 1 . . C
  C8 1.1223(5) 0.8199(3) 1.5690(4) 0.0357(11) Uani d . 1 . . C
  H8A 1.0911 0.7422 1.5845 0.043 Uiso calc R 1 . . H
  C9 1.2088(5) 0.9157(3) 1.6391(3) 0.0339(10) Uani d . 1 . . C
  C10 1.2773(5) 0.9259(4) 1.7547(4) 0.0475(12) Uani d . 1 . . C
  H10A 1.2827 1.0058 1.7822 0.071 Uiso calc R 1 . . H
  H10B 1.3730 0.9102 1.7729 0.071 Uiso calc R 1 . . H
  H10C 1.2204 0.8683 1.7834 0.071 Uiso calc R 1 . . H
  C11 0.4445(6) 0.6525(4) 0.6212(4) 0.0555(14) Uani d . 1 . . C
  H11A 0.4780 0.5874 0.6594 0.083 Uiso calc R 1 . . H
  H11B 0.4536 0.6465 0.5536 0.083 Uiso calc R 1 . . H
  H11C 0.3450 0.6482 0.6134 0.083 Uiso calc R 1 . . H
  C12 0.5330(5) 0.7697(4) 0.6788(4) 0.0365(11) Uani d . 1 . . C
  C13 0.5519(5) 0.8837(4) 0.6418(4) 0.0429(12) Uani d . 1 . . C
  H13A 0.5129 0.9026 0.5734 0.051 Uiso calc R 1 . . H
  C14 0.6394(5) 0.9622(3) 0.7262(4) 0.0347(10) Uani d . 1 . . C
  C15 0.6953(5) 1.0954(4) 0.7378(4) 0.0481(13) Uani d . 1 . . C
  H15A 0.7970 1.1133 0.7771 0.072 Uiso calc R 1 . . H
  H15B 0.6454 1.1341 0.7736 0.072 Uiso calc R 1 . . H
  H15C 0.6795 1.1245 0.6701 0.072 Uiso calc R 1 . . H
  C16 0.5368(5) 0.1645(3) 0.9785(4) 0.0451(13) Uani d . 1 . . C
  H16A 0.4720 0.1515 0.9076 0.068 Uiso calc R 1 . . H
  H16B 0.4853 0.1341 1.0238 0.068 Uiso calc R 1 . . H
  H16C 0.6142 0.1230 0.9861 0.068 Uiso calc R 1 . . H
  C17 0.5975(5) 0.2966(3) 1.0065(3) 0.0316(10) Uani d . 1 . . C
  C18 0.6648(5) 0.3622(3) 1.1019(4) 0.0336(10) Uani d . 1 . . C
  H18A 0.6837 0.3325 1.1671 0.040 Uiso calc R 1 . . H
  C19 0.6992(4) 0.4824(3) 1.0811(3) 0.0307(10) Uani d . 1 . . C
  C20 0.7729(5) 0.5900(4) 1.1576(4) 0.0451(12) Uani d . 1 . . C
  H20A 0.7756 0.6615 1.1211 0.068 Uiso calc R 1 . . H
  H20B 0.8698 0.5826 1.1964 0.068 Uiso calc R 1 . . H
  H20C 0.7207 0.5951 1.2045 0.068 Uiso calc R 1 . . H
  O1 0.8255(4) 0.8369(3) 1.0302(3) 0.0665(12) Uani d . 1 . . O
  O2 0.9716(4) 0.9676(3) 1.1554(3) 0.0578(10) Uani d . 1 . . O
  O3 0.8419(4) 1.0251(3) 1.0123(3) 0.0540(10) Uani d . 1 . . O
  O4 0.4103(5) 0.2569(4) 0.5752(3) 0.0844(14) Uani d . 1 . . O
  O5 0.5410(5) 0.3810(3) 0.7099(3) 0.0757(13) Uani d . 1 . . O
  O6 0.3939(4) 0.2258(3) 0.7247(3) 0.0588(10) Uani d . 1 . . O
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Ag1 0.0531(3) 0.0446(2) 0.0421(2) 0.01650(16) 0.02301(19) 0.01914(16)
  Ag2 0.0406(2) 0.03845(19) 0.0433(3) 0.01120(15) 0.01593(18) 0.01510(16)
  N1 0.037(2) 0.0322(17) 0.033(2) 0.0043(15) 0.0118(17) 0.0027(16)
  N2 0.040(2) 0.0368(18) 0.031(2) 0.0104(15) 0.0134(17) 0.0078(16)
  N3 0.038(2) 0.0372(18) 0.030(2) 0.0061(15) 0.0085(17) 0.0041(16)
  N4 0.034(2) 0.0302(16) 0.033(2) 0.0034(14) 0.0047(17) 0.0013(16)
  N5 0.034(2) 0.0366(17) 0.031(2) 0.0072(15) 0.0086(17) 0.0029(16)
  N6 0.034(2) 0.0335(17) 0.036(2) 0.0073(15) 0.0120(17) 0.0052(16)
  N7 0.034(2) 0.0287(16) 0.030(2) 0.0054(14) 0.0120(17) 0.0012(15)
  N8 0.034(2) 0.0316(16) 0.027(2) 0.0053(14) 0.0074(16) -0.0030(15)
  N9 0.038(2) 0.0362(18) 0.036(2) 0.0047(16) 0.0140(18) -0.0028(17)
  N10 0.059(3) 0.0337(19) 0.034(3) 0.0085(18) 0.007(2) -0.0021(18)
  C1 0.043(3) 0.046(2) 0.038(3) 0.012(2) 0.009(2) 0.011(2)
  C2 0.034(3) 0.035(2) 0.038(3) 0.0118(18) 0.014(2) 0.010(2)
  C3 0.048(3) 0.030(2) 0.039(3) 0.0069(19) 0.014(2) 0.007(2)
  C4 0.037(3) 0.039(2) 0.039(3) 0.0062(19) 0.017(2) 0.003(2)
  C5 0.067(4) 0.061(3) 0.042(3) 0.004(3) 0.012(3) -0.004(3)
  C6 0.058(3) 0.051(3) 0.039(3) -0.001(2) 0.010(3) -0.008(2)
  C7 0.034(3) 0.035(2) 0.034(3) 0.0065(18) 0.013(2) 0.0015(19)
  C8 0.036(3) 0.032(2) 0.042(3) 0.0058(17) 0.016(2) 0.008(2)
  C9 0.034(3) 0.036(2) 0.033(3) 0.0112(18) 0.010(2) 0.0057(19)
  C10 0.047(3) 0.057(3) 0.036(3) 0.013(2) 0.010(2) 0.009(2)
  C11 0.058(4) 0.049(3) 0.051(4) 0.003(2) 0.013(3) -0.007(2)
  C12 0.038(3) 0.039(2) 0.035(3) 0.0118(19) 0.014(2) 0.004(2)
  C13 0.046(3) 0.051(3) 0.032(3) 0.019(2) 0.009(2) 0.011(2)
  C14 0.030(2) 0.037(2) 0.042(3) 0.0108(18) 0.016(2) 0.011(2)
  C15 0.053(3) 0.040(2) 0.057(3) 0.016(2) 0.023(3) 0.010(2)
  C16 0.052(3) 0.031(2) 0.047(3) 0.0027(19) 0.013(2) -0.003(2)
  C17 0.032(2) 0.0303(19) 0.034(3) 0.0075(17) 0.013(2) 0.0041(18)
  C18 0.036(3) 0.037(2) 0.030(3) 0.0099(18) 0.012(2) 0.0049(19)
  C19 0.030(2) 0.0330(19) 0.032(3) 0.0087(17) 0.013(2) 0.0026(18)
  C20 0.047(3) 0.039(2) 0.044(3) 0.006(2) 0.011(2) -0.007(2)
  O1 0.077(3) 0.0333(16) 0.070(3) -0.0009(16) 0.008(2) -0.0077(17)
  O2 0.060(2) 0.063(2) 0.037(2) 0.0139(17) -0.0003(18) -0.0058(17)
  O3 0.071(3) 0.0379(16) 0.044(2) 0.0144(16) 0.0070(18) 0.0064(15)
  O4 0.124(4) 0.080(3) 0.030(2) 0.001(2) 0.012(2) -0.007(2)
  O5 0.097(3) 0.0482(19) 0.060(3) -0.022(2) 0.019(2) -0.0059(18)
  O6 0.066(3) 0.0550(19) 0.060(3) 0.0025(17) 0.034(2) 0.0043(18)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Ag1 N2 . 2.119(3) y
  Ag1 N3 . 2.120(3) y
  Ag1 O2 . 3.140(3) ?
  Ag1 Ag2 . 8.0395(8) ?
  Ag2 N6 . 2.127(3) y
  Ag2 N7 . 2.129(3) y
  N1 C2 . 1.340(5) ?
  N1 N2 . 1.354(5) ?
  N1 H1D . 0.8600 ?
  N2 C4 . 1.337(5) ?
  N3 C7 . 1.342(5) ?
  N3 N4 . 1.361(5) ?
  N4 C9 . 1.336(5) ?
  N4 H4A . 0.8600 ?
  N5 C14 . 1.337(5) ?
  N5 N6 . 1.364(4) ?
  N5 H5D . 0.8600 ?
  N6 C12 . 1.338(5) ?
  N7 C19 . 1.337(5) ?
  N7 N8 . 1.357(4) ?
  N8 C17 . 1.343(5) ?
  N8 H8B . 0.8600 ?
  N9 O1 . 1.230(4) ?
  N9 O2 . 1.241(4) ?
  N9 O3 . 1.249(4) ?
  N10 O4 . 1.230(5) ?
  N10 O5 . 1.238(5) ?
  N10 O6 . 1.242(5) ?
  C1 C2 . 1.484(6) ?
  C1 H1A . 0.9600 ?
  C1 H1B . 0.9600 ?
  C1 H1C . 0.9600 ?
  C2 C3 . 1.379(6) ?
  C3 C4 . 1.388(6) ?
  C3 H3A . 0.9300 ?
  C4 C5 . 1.493(6) ?
  C5 H5A . 0.9600 ?
  C5 H5B . 0.9600 ?
  C5 H5C . 0.9600 ?
  C6 C7 . 1.498(6) ?
  C6 H6A . 0.9600 ?
  C6 H6B . 0.9600 ?
  C6 H6C . 0.9600 ?
  C7 C8 . 1.388(6) ?
  C8 C9 . 1.377(6) ?
  C8 H8A . 0.9300 ?
  C9 C10 . 1.489(6) ?
  C10 H10A . 0.9600 ?
  C10 H10B . 0.9600 ?
  C10 H10C . 0.9600 ?
  C11 C12 . 1.489(6) ?
  C11 H11A . 0.9600 ?
  C11 H11B . 0.9600 ?
  C11 H11C . 0.9600 ?
  C12 C13 . 1.398(6) ?
  C13 C14 . 1.372(6) ?
  C13 H13A . 0.9300 ?
  C14 C15 . 1.493(5) ?
  C15 H15A . 0.9600 ?
  C15 H15B . 0.9600 ?
  C15 H15C . 0.9600 ?
  C16 C17 . 1.495(5) ?
  C16 H16A . 0.9600 ?
  C16 H16B . 0.9600 ?
  C16 H16C . 0.9600 ?
  C17 C18 . 1.376(6) ?
  C18 C19 . 1.399(5) ?
  C18 H18A . 0.9300 ?
  C19 C20 . 1.490(6) ?
  C20 H20A . 0.9600 ?
  C20 H20B . 0.9600 ?
  C20 H20C . 0.9600 ?