data_2013883
_journal_name_full  'Acta Crystallographica, Section C'
_journal_year  2004
_journal_volume  60
_journal_page_first  m63
_journal_page_last  m64
_publ_section_title
;
catena-Poly[bis[(2,2-bipyridine-\k^2^N,N')cobalt(II)]-\m-1,2,4,5-
benzenetetracarboxylato-\k^4^O^1^:O^2^:O^3^:O^4^]
;
loop_
_publ_author_name
  'Xiao, Hong-Ping'
  'Li, Xin-Hua'
  'Yuan, Ji-Xin'
  'Hu, Mao-Lin'
_chemical_formula_moiety  'C30 H18 Cu2 N4 O8'
_chemical_formula_sum  'C15 H9 Cu N2 O4'
_chemical_formula_iupac  '[Cu2 (C10 H2 O8) (C10 H8 N2)2]'
_chemical_formula_weight  689.56
_symmetry_cell_setting  'monoclinic'
_symmetry_space_group_name_H-M  'P 21/n'
_symmetry_space_group_name_Hall  '-P 2yn'
loop_
_symmetry_equiv_pos_as_xyz
  'x, y, z'
  '-x+1/2, y+1/2, -z+1/2'
  '-x, -y, -z'
  'x-1/2, -y-1/2, z-1/2'
_cell_length_a  7.2794(7)
_cell_length_b  12.5009(12)
_cell_length_c  14.4436(14)
_cell_angle_alpha  90
_cell_angle_beta  104.021(2)
_cell_angle_gamma  90
_cell_volume  1275.2(2)
_cell_formula_units_Z  2
_cell_measurement_temperature  273(2)
_exptl_crystal_density_diffrn  1.796
_diffrn_ambient_temperature  273(2)
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
  Cu1 0.12671(5) 0.51437(3) 0.28264(2) 0.02411(15) Uani d . 1 . . Cu
  O1 -0.4480(3) 0.5500(2) -0.24253(15) 0.0426(6) Uani d . 1 . . O
  O2 -0.2239(3) 0.43644(19) -0.17381(14) 0.0330(5) Uani d . 1 . . O
  O3 -0.0839(3) 0.44152(18) 0.19560(14) 0.0324(5) Uani d . 1 . . O
  O4 -0.1984(3) 0.59946(19) 0.22122(15) 0.0382(5) Uani d . 1 . . O
  N1 0.1225(3) 0.4282(2) 0.39770(16) 0.0238(5) Uani d . 1 . . N
  N2 0.2687(3) 0.6143(2) 0.38029(16) 0.0242(5) Uani d . 1 . . N
  C1 0.0426(4) 0.3322(3) 0.3988(2) 0.0306(7) Uani d . 1 . . C
  H1 -0.0242 0.3022 0.3416 0.037 Uiso calc R 1 . . H
  C2 0.0567(4) 0.2764(3) 0.4827(2) 0.0339(7) Uani d . 1 . . C
  H2 0.0002 0.2096 0.4819 0.041 Uiso calc R 1 . . H
  C3 0.1547(4) 0.3203(3) 0.5674(2) 0.0325(7) Uani d . 1 . . C
  H3 0.1661 0.2834 0.6244 0.039 Uiso calc R 1 . . H
  C4 0.2364(4) 0.4200(2) 0.5671(2) 0.0270(6) Uani d . 1 . . C
  H4 0.3016 0.4517 0.6238 0.032 Uiso calc R 1 . . H
  C5 0.2193(4) 0.4722(2) 0.4807(2) 0.0223(6) Uani d . 1 . . C
  C6 0.2981(4) 0.5794(2) 0.47109(18) 0.0214(6) Uani d . 1 . . C
  C7 0.3906(4) 0.6431(2) 0.5471(2) 0.0281(7) Uani d . 1 . . C
  H7 0.4128 0.6180 0.6094 0.034 Uiso calc R 1 . . H
  C8 0.4487(4) 0.7443(3) 0.5284(2) 0.0344(7) Uani d . 1 . . C
  H8 0.5097 0.7885 0.5782 0.041 Uiso calc R 1 . . H
  C9 0.4154(5) 0.7792(3) 0.4349(2) 0.0363(7) Uani d . 1 . . C
  H9 0.4526 0.8473 0.4211 0.044 Uiso calc R 1 . . H
  C10 0.3270(4) 0.7120(3) 0.3631(2) 0.0328(7) Uani d . 1 . . C
  H10 0.3069 0.7351 0.3003 0.039 Uiso calc R 1 . . H
  C11 -0.2089(4) 0.5153(2) 0.17650(19) 0.0233(6) Uani d . 1 . . C
  C12 -0.3650(4) 0.5008(2) 0.08769(19) 0.0189(6) Uani d . 1 . . C
  C13 -0.3111(4) 0.4928(2) 0.00192(19) 0.0197(6) Uani d . 1 . . C
  H13 -0.1830 0.4877 0.0033 0.024 Uiso calc R 1 . . H
  C14 -0.4422(4) 0.4924(2) -0.08563(19) 0.0186(5) Uani d . 1 . . C
  C15 -0.3708(4) 0.4925(2) -0.1755(2) 0.0221(6) Uani d . 1 . . C
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
  Cu1 0.0210(2) 0.0394(3) 0.0107(2) 0.00225(14) 0.00139(14) -0.00150(13)
  O1 0.0477(14) 0.0616(16) 0.0207(11) 0.0184(12) 0.0126(10) 0.0148(11)
  O2 0.0282(11) 0.0565(14) 0.0166(10) 0.0131(10) 0.0098(8) 0.0046(9)
  O3 0.0264(11) 0.0454(13) 0.0196(10) 0.0097(10) -0.0060(8) -0.0056(9)
  O4 0.0401(13) 0.0430(13) 0.0261(12) 0.0014(11) -0.0028(9) -0.0140(10)
  N1 0.0188(11) 0.0359(14) 0.0161(11) 0.0012(10) 0.0028(9) -0.0032(10)
  N2 0.0206(12) 0.0339(14) 0.0177(12) 0.0014(10) 0.0041(9) 0.0012(10)
  C1 0.0275(15) 0.0352(17) 0.0288(16) -0.0013(13) 0.0062(13) -0.0077(13)
  C2 0.0335(17) 0.0290(16) 0.0422(19) 0.0026(13) 0.0151(14) 0.0015(14)
  C3 0.0330(17) 0.0388(18) 0.0274(16) 0.0074(14) 0.0104(13) 0.0065(13)
  C4 0.0253(15) 0.0374(17) 0.0185(14) 0.0058(13) 0.0058(11) -0.0004(12)
  C5 0.0161(13) 0.0329(16) 0.0184(14) 0.0049(11) 0.0053(11) -0.0030(11)
  C6 0.0173(13) 0.0320(16) 0.0152(13) 0.0054(11) 0.0043(10) -0.0017(11)
  C7 0.0253(15) 0.0368(17) 0.0202(14) 0.0023(12) 0.0018(12) -0.0013(12)
  C8 0.0291(16) 0.0392(18) 0.0331(17) -0.0032(13) 0.0042(13) -0.0111(14)
  C9 0.0371(18) 0.0309(17) 0.0421(19) -0.0032(14) 0.0118(15) 0.0004(14)
  C10 0.0340(17) 0.0396(18) 0.0256(16) 0.0012(14) 0.0087(13) 0.0060(13)
  C11 0.0212(14) 0.0376(17) 0.0104(13) -0.0027(12) 0.0024(11) -0.0008(11)
  C12 0.0180(13) 0.0207(14) 0.0159(13) -0.0002(10) -0.0002(11) 0.0013(10)
  C13 0.0168(13) 0.0261(15) 0.0157(14) 0.0006(11) 0.0026(11) -0.0001(10)
  C14 0.0190(13) 0.0224(14) 0.0135(13) 0.0006(10) 0.0023(10) 0.0000(10)
  C15 0.0206(14) 0.0309(15) 0.0144(14) -0.0027(11) 0.0032(11) -0.0020(11)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
  Cu1 O3 . 1.956(2) ?
  Cu1 O2 3_565 1.972(2) ?
  Cu1 N2 . 1.978(2) ?
  Cu1 N1 . 1.987(2) ?
  O1 C15 . 1.227(4) ?
  O2 C15 . 1.274(3) ?
  O2 Cu1 3_565 1.972(2) ?
  O3 C11 . 1.278(4) ?
  O4 C11 . 1.228(4) ?
  N1 C1 . 1.336(4) ?
  N1 C5 . 1.351(4) ?
  N2 C10 . 1.335(4) ?
  N2 C6 . 1.349(3) ?
  C1 C2 . 1.382(4) ?
  C1 H1 . 0.9300 ?
  C2 C3 . 1.373(4) ?
  C2 H2 . 0.9300 ?
  C3 C4 . 1.381(4) ?
  C3 H3 . 0.9300 ?
  C4 C5 . 1.387(4) ?
  C4 H4 . 0.9300 ?
  C5 C6 . 1.478(4) ?
  C6 C7 . 1.391(4) ?
  C7 C8 . 1.381(5) ?
  C7 H7 . 0.9300 ?
  C8 C9 . 1.384(5) ?
  C8 H8 . 0.9300 ?
  C9 C10 . 1.368(5) ?
  C9 H9 . 0.9300 ?
  C10 H10 . 0.9300 ?
  C11 C12 . 1.504(4) ?
  C12 C13 . 1.391(4) ?
  C12 C14 3_465 1.399(4) ?
  C13 C14 . 1.387(4) ?
  C13 H13 . 0.9300 ?
  C14 C12 3_465 1.399(4) ?
  C14 C15 . 1.511(4) ?