#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/01/46/2014699.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2014699_Fobs loop_ _publ_author_name 'Esterhuysen, Catharine' 'Bredenkamp, Martin W.' 'Lloyd, Gareth O.' _publ_section_title ; Resolution of (S,S)-4-(2,2,4-trimethylchroman-4-yl)phenyl camphanate and its 4-chromanyl epimer by crystallization ; _journal_issue 1 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first o32 _journal_page_last o34 _journal_volume 61 _journal_year 2005 _space_group_IT_number 19 _symmetry_space_group_name_Hall 'P 2ac 2ab' _symmetry_space_group_name_H-M 'P 21 21 21' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 7.3983 _cell_length_b 8.4130 _cell_length_c 38.6280 _exptl_crystal_F_000 960.00 _reflns_d_resolution_high 0.8107 _[local]_cod_data_source_file hj1032Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' xm in P2(1)2(1)2(1)' _shelx_refln_list_code 4 _shelx_f_calc_maximum 176.19 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' 'x+1/2, -y+1/2, -z' '-x, y+1/2, -z+1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 1799.17 1943.84 55.68 o 4 0 0 413.73 416.99 16.46 o 6 0 0 374.89 412.53 47.48 o 8 0 0 79.61 56.85 26.65 o 1 1 0 9179.64 9151.04 219.36 o 2 1 0 2262.53 2237.29 49.49 o 3 1 0 181.35 186.27 6.61 o 4 1 0 8164.05 8768.13 174.37 o 5 1 0 856.72 875.20 38.16 o 6 1 0 623.98 602.59 21.60 o 7 1 0 254.12 279.04 24.07 o 8 1 0 1.06 -11.87 16.73 o 9 1 0 213.96 232.17 28.32 o 0 2 0 17054.21 17661.46 830.41 o 1 2 0 48.04 42.10 5.15 o 2 2 0 842.72 808.90 36.06 o 3 2 0 353.52 362.17 11.32 o 4 2 0 267.29 281.92 10.01 o 5 2 0 39.72 33.77 6.21 o 6 2 0 182.05 182.15 14.50 o 7 2 0 10.95 30.72 12.00 o 8 2 0 15.62 0.98 17.29 o 1 3 0 5370.73 6201.96 209.02 o 2 3 0 2272.91 2309.02 58.41 o 3 3 0 15.81 34.73 7.63 o 4 3 0 12.22 15.32 6.37 o 5 3 0 36.56 46.69 10.46 o 6 3 0 66.90 55.71 11.43 o 7 3 0 0.14 -4.88 11.63 o 8 3 0 58.07 44.83 20.09 o 0 4 0 14403.28 15630.43 737.82 o 1 4 0 321.00 308.45 16.68 o 2 4 0 256.96 269.63 13.22 o 3 4 0 79.69 78.81 7.35 o 4 4 0 49.89 43.98 7.85 o 5 4 0 195.67 191.15 14.30 o 6 4 0 7.90 -9.77 9.77 o 7 4 0 56.48 65.10 14.92 o 8 4 0 0.48 6.90 19.38 o 1 5 0 435.12 446.95 22.74 o 2 5 0 2.22 1.43 7.79 o 3 5 0 41.96 42.43 13.64 o 4 5 0 263.28 246.53 12.94 o 5 5 0 909.01 866.69 33.87 o 6 5 0 158.60 180.46 17.07 o 7 5 0 219.43 258.72 21.60 o 0 6 0 483.04 487.17 36.19 o 1 6 0 177.42 214.04 16.58 o 2 6 0 599.38 576.53 28.96 o 3 6 0 91.82 108.89 14.28 o 4 6 0 101.54 100.35 15.47 o 5 6 0 0.29 10.86 14.38 o 6 6 0 73.74 80.22 18.82 o 7 6 0 4.77 -17.20 20.25 o 1 7 0 157.85 139.80 16.17 o 2 7 0 11.17 3.54 18.83 o 3 7 0 11.08 -8.14 12.26 o 4 7 0 72.36 55.19 17.35 o 5 7 0 584.95 671.53 55.45 o 6 7 0 22.65 6.90 21.88 o 0 8 0 1453.48 1301.19 78.77 o 1 8 0 829.67 829.31 40.77 o 2 8 0 84.58 69.77 16.64 o 3 8 0 67.22 19.70 14.68 o 4 8 0 70.24 50.74 20.11 o 5 8 0 28.79 32.59 20.36 o 1 9 0 1023.48 927.44 48.96 o 2 9 0 40.15 44.58 18.95 o 3 9 0 17.73 36.81 27.10 o 4 9 0 16.50 4.23 20.06 o 0 10 0 266.26 289.00 42.19 o 1 10 0 2.27 -6.03 20.86 o 2 10 0 100.02 154.63 27.98 o 1 0 1 1240.46 1204.08 27.18 o 2 0 1 3274.67 3200.07 63.99 o 3 0 1 12890.20 13860.17 273.41 o 4 0 1 101.02 75.64 5.35 o 5 0 1 16.72 5.18 6.06 o 6 0 1 18.20 25.47 8.34 o 7 0 1 0.86 -8.12 12.73 o 8 0 1 0.05 8.64 16.87 o 9 0 1 13.17 26.70 20.51 o 0 1 1 4152.31 4141.61 138.26 o 1 1 1 31042.02 31961.74 576.28 o 2 1 1 1142.12 1110.87 19.09 o 3 1 1 926.95 900.00 14.22 o 4 1 1 261.55 292.03 6.93 o 5 1 1 707.11 682.68 13.70 o 6 1 1 21.10 11.41 5.88 o 7 1 1 6.92 10.78 8.81 o 8 1 1 183.13 230.24 18.18 o 9 1 1 248.42 264.09 20.68 o 0 2 1 5869.52 5931.52 198.70 o 1 2 1 495.81 496.01 11.84 o 2 2 1 2467.17 2378.35 44.79 o 3 2 1 54.09 62.40 5.60 o 4 2 1 113.16 122.68 6.01 o 5 2 1 77.36 77.69 5.42 o 6 2 1 723.43 687.58 19.94 o 7 2 1 615.38 586.29 19.42 o 8 2 1 125.80 113.38 15.33 o 0 3 1 268.02 264.77 14.18 o 1 3 1 2227.87 2257.06 50.23 o 2 3 1 4427.72 4642.98 93.31 o 3 3 1 30.93 29.48 4.51 o 4 3 1 871.86 890.38 18.66 o 5 3 1 205.64 215.86 7.91 o 6 3 1 718.41 763.27 25.88 o 7 3 1 286.08 274.59 15.07 o 8 3 1 40.48 57.97 14.45 o 0 4 1 11075.99 11810.94 395.53 o 1 4 1 1038.92 1078.66 29.39 o 2 4 1 750.43 742.25 19.75 o 3 4 1 354.29 343.23 9.57 o 4 4 1 35.55 44.49 6.66 o 5 4 1 450.67 492.36 17.25 o 6 4 1 99.98 119.53 12.31 o 7 4 1 39.34 36.87 9.68 o 8 4 1 144.47 114.16 14.56 o 0 5 1 805.78 739.02 31.81 o 1 5 1 1678.05 1678.73 44.19 o 2 5 1 22.96 30.37 9.01 o 3 5 1 8.65 0.86 5.50 o 4 5 1 61.56 71.67 6.65 o 5 5 1 289.21 284.43 12.99 o 6 5 1 49.23 82.80 10.94 o 7 5 1 59.76 43.25 10.99 o 0 6 1 80.61 64.02 11.60 o 1 6 1 341.59 358.74 19.88 o 2 6 1 284.94 305.17 15.57 o 3 6 1 34.53 15.31 7.77 o 4 6 1 345.48 344.12 14.98 o 5 6 1 143.08 144.06 13.56 o 6 6 1 256.33 277.74 17.81 o 7 6 1 13.79 20.13 14.02 o 0 7 1 1520.82 1411.69 57.07 o 1 7 1 39.58 49.18 9.16 o 2 7 1 20.19 34.40 11.49 o 3 7 1 304.34 281.10 15.55 o 4 7 1 33.67 21.68 20.05 o 5 7 1 6.77 -10.35 11.09 o 6 7 1 28.59 46.82 14.55 o 0 8 1 1343.93 1310.06 55.96 o 1 8 1 93.83 93.57 12.20 o 2 8 1 126.41 124.22 13.12 o 3 8 1 14.54 0.40 10.48 o 4 8 1 51.06 43.42 15.77 o 5 8 1 43.38 60.02 16.41 o 0 9 1 0.22 2.34 16.30 o 1 9 1 8.03 12.36 12.32 o 2 9 1 6.08 9.61 20.30 o 3 9 1 0.77 16.04 17.94 o 4 9 1 49.75 61.03 16.22 o 0 10 1 159.97 159.07 25.85 o 1 10 1 17.49 5.17 14.65 o 2 10 1 36.06 59.29 15.61 o 1 0 2 1703.02 1645.69 40.79 o 2 0 2 13253.67 13755.59 270.91 o 3 0 2 70.07 84.04 7.18 o 4 0 2 27.68 32.57 4.19 o 5 0 2 194.90 194.59 10.78 o 6 0 2 46.32 76.31 9.81 o 7 0 2 153.71 184.91 24.95 o 8 0 2 310.66 290.55 27.10 o 9 0 2 0.07 -14.51 18.79 o 0 1 2 7215.85 7289.14 174.09 o 1 1 2 2787.85 2866.34 49.24 o 2 1 2 863.99 878.79 16.57 o 3 1 2 63.21 72.65 4.59 o 4 1 2 449.33 509.31 10.08 o 5 1 2 150.26 153.50 8.10 o 6 1 2 611.15 578.68 16.11 o 7 1 2 218.76 269.17 19.58 o 8 1 2 10.87 8.22 12.27 o 9 1 2 20.69 32.60 14.87 o 0 2 2 1820.19 1732.63 60.22 o 1 2 2 5603.79 5681.56 111.39 o 2 2 2 1821.65 1697.62 30.62 o 3 2 2 131.70 138.41 6.19 o 4 2 2 771.98 756.29 14.26 o 5 2 2 221.42 234.03 9.03 o 6 2 2 283.68 285.58 11.13 o 7 2 2 30.90 26.04 8.47 o 8 2 2 50.18 43.24 13.52 o 0 3 2 3278.32 3178.20 109.20 o 1 3 2 866.01 863.14 21.27 o 2 3 2 3382.11 3684.90 73.95 o 3 3 2 276.82 243.08 12.57 o 4 3 2 180.32 171.17 6.36 o 5 3 2 379.42 377.19 13.82 o 6 3 2 161.39 138.84 13.48 o 7 3 2 141.86 141.05 11.26 o 8 3 2 13.17 18.08 11.61 o 0 4 2 1767.69 1687.01 61.42 o 1 4 2 139.68 170.56 8.77 o 2 4 2 1050.08 1108.12 29.27 o 3 4 2 325.61 332.34 11.01 o 4 4 2 79.00 73.16 5.69 o 5 4 2 73.32 73.28 7.90 o 6 4 2 43.71 41.44 8.17 o 7 4 2 33.38 33.68 9.67 o 8 4 2 58.63 42.51 13.17 o 0 5 2 636.17 595.36 27.44 o 1 5 2 619.86 635.56 20.22 o 2 5 2 65.44 89.90 9.91 o 3 5 2 196.70 189.83 9.73 o 4 5 2 271.11 302.00 13.47 o 5 5 2 193.48 202.32 11.38 o 6 5 2 69.24 63.07 10.73 o 7 5 2 49.25 37.49 10.75 o 0 6 2 255.34 208.34 16.47 o 1 6 2 1299.18 1192.88 53.63 o 2 6 2 37.92 25.50 7.37 o 3 6 2 202.92 198.75 16.37 o 4 6 2 168.22 172.45 11.59 o 5 6 2 286.82 277.37 16.72 o 6 6 2 174.74 185.50 16.01 o 7 6 2 92.26 97.15 17.69 o 0 7 2 411.87 401.54 24.82 o 1 7 2 1598.41 1586.00 44.52 o 2 7 2 23.24 41.75 9.36 o 3 7 2 733.13 713.53 25.51 o 4 7 2 59.57 64.65 11.99 o 5 7 2 230.91 250.58 18.00 o 6 7 2 56.73 80.59 15.27 o 0 8 2 576.28 648.29 35.49 o 1 8 2 584.26 602.59 23.87 o 2 8 2 73.17 59.86 11.56 o 3 8 2 28.14 41.40 13.45 o 4 8 2 42.35 40.34 15.18 o 5 8 2 21.44 38.35 14.58 o 0 9 2 275.10 237.00 24.71 o 1 9 2 310.57 351.28 26.14 o 2 9 2 127.94 124.09 15.18 o 3 9 2 14.14 12.08 13.07 o 4 9 2 145.09 139.05 20.64 o 0 10 2 116.00 141.96 25.61 o 1 10 2 32.23 38.69 15.96 o 2 10 2 5.99 37.07 18.12 o 1 0 3 5359.76 5082.73 109.47 o 2 0 3 3319.90 3448.32 75.73 o 3 0 3 734.79 714.29 18.35 o 4 0 3 5582.91 5667.18 113.56 o 5 0 3 85.85 93.53 10.38 o 6 0 3 7.78 11.46 7.59 o 7 0 3 1.18 -5.24 10.63 o 8 0 3 180.73 237.67 25.81 o 9 0 3 100.53 105.24 23.92 o 0 1 3 5880.32 5487.18 117.69 o 1 1 3 1970.18 1938.90 31.91 o 2 1 3 598.08 594.13 11.34 o 3 1 3 3308.53 3390.37 52.99 o 4 1 3 1165.99 1099.15 18.31 o 5 1 3 505.71 480.55 11.48 o 6 1 3 0.61 3.82 5.75 o 7 1 3 14.68 13.65 8.72 o 8 1 3 161.66 192.07 17.23 o 9 1 3 70.06 101.25 16.76 o 0 2 3 920.71 801.80 48.85 o 1 2 3 8763.42 8709.46 170.01 o 2 2 3 1685.43 1606.65 29.15 o 3 2 3 582.24 629.84 13.44 o 4 2 3 387.22 396.97 9.10 o 5 2 3 153.73 149.82 6.40 o 6 2 3 426.32 413.56 13.40 o 7 2 3 151.83 155.99 12.51 o 8 2 3 14.85 20.54 13.05 o 0 3 3 1134.04 1078.65 40.19 o 1 3 3 410.99 423.37 12.57 o 2 3 3 746.96 770.24 17.97 o 3 3 3 335.57 339.71 10.04 o 4 3 3 138.18 126.92 6.07 o 5 3 3 667.22 646.86 16.71 o 6 3 3 1034.72 1017.28 29.72 o 7 3 3 89.90 68.44 12.15 o 8 3 3 2.70 5.93 11.51 o 0 4 3 1274.88 1305.67 54.10 o 1 4 3 423.03 437.33 14.89 o 2 4 3 963.16 1006.66 25.14 o 3 4 3 582.87 615.73 15.11 o 4 4 3 399.65 386.54 11.91 o 5 4 3 58.79 65.70 7.02 o 6 4 3 366.81 343.55 14.08 o 7 4 3 43.36 48.41 10.02 o 8 4 3 28.59 27.81 12.96 o 0 5 3 395.48 374.35 20.17 o 1 5 3 310.99 283.41 12.24 o 2 5 3 18.38 41.64 10.85 o 3 5 3 177.88 174.80 8.77 o 4 5 3 21.56 20.20 6.40 o 5 5 3 143.61 154.31 13.88 o 6 5 3 540.08 569.48 27.61 o 7 5 3 277.16 277.49 15.71 o 0 6 3 1188.06 1045.99 92.90 o 1 6 3 128.55 130.87 9.89 o 2 6 3 243.95 258.25 12.98 o 3 6 3 148.82 160.94 11.37 o 4 6 3 211.49 220.85 14.61 o 5 6 3 143.62 149.14 13.86 o 6 6 3 103.88 99.07 12.48 o 7 6 3 30.30 19.79 14.17 o 0 7 3 702.65 661.85 32.89 o 1 7 3 788.90 791.48 26.39 o 2 7 3 222.87 217.78 13.75 o 3 7 3 29.47 18.55 9.33 o 4 7 3 60.24 58.54 12.00 o 5 7 3 92.82 79.53 14.04 o 6 7 3 93.62 85.62 15.90 o 0 8 3 747.12 805.94 39.90 o 1 8 3 203.66 191.40 14.54 o 2 8 3 353.86 380.27 19.14 o 3 8 3 106.60 131.49 27.55 o 4 8 3 19.37 29.35 15.24 o 5 8 3 16.94 8.63 13.61 o 0 9 3 6.85 -2.32 21.78 o 1 9 3 98.09 120.11 15.21 o 2 9 3 70.18 104.21 14.92 o 3 9 3 32.13 19.35 13.66 o 4 9 3 72.23 121.79 19.86 o 0 10 3 8.00 13.34 21.78 o 1 10 3 126.51 139.96 17.82 o 2 10 3 95.46 116.91 18.37 o 1 0 4 18403.52 18784.86 449.14 o 2 0 4 929.55 841.95 20.20 o 3 0 4 2522.62 2624.06 58.89 o 4 0 4 4928.88 5372.53 131.28 o 5 0 4 1272.48 1303.90 32.45 o 6 0 4 1011.48 1005.93 68.88 o 7 0 4 78.28 85.18 13.90 o 8 0 4 8.43 20.07 18.02 o 9 0 4 5.41 -5.95 32.71 o 0 1 4 5002.67 4805.81 114.99 o 1 1 4 10799.31 10977.50 175.46 o 2 1 4 2649.17 2627.85 43.35 o 3 1 4 2131.55 2164.91 36.44 o 4 1 4 360.05 355.84 7.99 o 5 1 4 168.12 163.92 6.78 o 6 1 4 354.08 367.12 15.25 o 7 1 4 77.31 81.90 10.59 o 8 1 4 48.60 74.13 14.09 o 9 1 4 36.79 10.92 14.02 o 0 2 4 22.92 15.06 4.77 o 1 2 4 1455.36 1389.72 26.79 o 2 2 4 2080.36 2096.97 35.19 o 3 2 4 147.53 173.38 7.85 o 4 2 4 204.35 209.76 7.16 o 5 2 4 1004.72 968.47 22.16 o 6 2 4 108.33 127.14 11.24 o 7 2 4 62.86 60.07 10.29 o 8 2 4 7.50 20.16 12.88 o 0 3 4 2374.47 2116.08 74.19 o 1 3 4 3212.82 3335.01 72.91 o 2 3 4 637.77 633.80 14.50 o 3 3 4 1787.53 1970.29 33.96 o 4 3 4 1185.50 1243.50 24.38 o 5 3 4 211.28 244.24 8.95 o 6 3 4 638.95 597.73 17.08 o 7 3 4 29.40 53.57 9.50 o 8 3 4 98.83 111.85 13.98 o 0 4 4 519.76 500.77 22.89 o 1 4 4 446.21 469.12 20.79 o 2 4 4 979.12 1073.30 26.64 o 3 4 4 286.73 311.12 10.70 o 4 4 4 928.84 910.92 19.48 o 5 4 4 221.45 232.10 10.02 o 6 4 4 288.94 273.55 12.80 o 7 4 4 27.66 33.08 9.65 o 8 4 4 38.63 49.74 13.39 o 0 5 4 0.54 3.27 7.43 o 1 5 4 622.32 591.53 26.12 o 2 5 4 31.62 31.99 6.42 o 3 5 4 116.82 130.99 8.02 o 4 5 4 33.84 32.70 6.76 o 5 5 4 7.62 18.06 6.90 o 6 5 4 117.13 110.94 11.73 o 7 5 4 52.90 56.25 11.28 o 0 6 4 2433.46 2417.14 88.34 o 1 6 4 1089.26 1103.08 48.43 o 2 6 4 17.98 22.60 7.33 o 3 6 4 183.32 175.24 10.11 o 4 6 4 261.89 252.91 15.79 o 5 6 4 146.15 179.05 14.77 o 6 6 4 165.22 188.55 16.34 o 7 6 4 42.61 54.08 14.90 o 0 7 4 3112.81 3158.12 114.43 o 1 7 4 288.92 272.23 14.76 o 2 7 4 21.32 18.92 8.76 o 3 7 4 61.15 77.26 9.75 o 4 7 4 308.01 331.16 25.30 o 5 7 4 148.30 149.16 15.42 o 6 7 4 44.39 45.69 14.85 o 0 8 4 609.96 570.11 32.47 o 1 8 4 91.91 128.12 13.05 o 2 8 4 47.35 41.09 11.36 o 3 8 4 60.62 39.64 12.15 o 4 8 4 201.47 196.32 20.39 o 5 8 4 1.24 3.11 13.51 o 0 9 4 195.10 183.07 23.57 o 1 9 4 158.34 188.92 31.68 o 2 9 4 113.78 95.46 16.80 o 3 9 4 61.75 67.28 14.82 o 4 9 4 61.08 42.33 18.11 o 0 10 4 1.77 23.03 21.41 o 1 10 4 42.17 69.44 18.96 o 2 10 4 26.71 24.55 15.56 o 1 0 5 1049.94 975.71 22.03 o 2 0 5 228.82 212.83 7.18 o 3 0 5 2265.35 2344.24 52.98 o 4 0 5 1266.11 1341.11 32.40 o 5 0 5 51.61 50.60 6.38 o 6 0 5 193.63 211.50 15.10 o 7 0 5 292.46 282.58 19.07 o 8 0 5 61.91 52.81 34.65 o 9 0 5 8.14 -13.10 19.67 o 0 1 5 2348.27 2222.29 54.03 o 1 1 5 1829.10 1731.03 27.14 o 2 1 5 1903.49 1875.83 31.47 o 3 1 5 3098.70 3223.95 53.34 o 4 1 5 702.03 689.29 12.57 o 5 1 5 112.84 115.73 5.48 o 6 1 5 968.58 968.71 23.06 o 7 1 5 357.90 326.54 14.41 o 8 1 5 118.96 126.93 17.90 o 9 1 5 60.97 96.50 16.40 o 0 2 5 15609.45 15860.90 339.30 o 1 2 5 3055.93 2920.15 54.06 o 2 2 5 844.56 821.67 15.24 o 3 2 5 223.58 219.35 6.76 o 4 2 5 34.18 40.23 4.09 o 5 2 5 160.15 179.38 8.60 o 6 2 5 226.60 223.75 10.15 o 7 2 5 195.97 193.61 13.45 o 8 2 5 103.66 111.98 25.14 o 0 3 5 1266.15 1261.12 50.59 o 1 3 5 1931.43 1946.04 40.16 o 2 3 5 244.48 274.22 8.26 o 3 3 5 2709.74 2905.23 48.80 o 4 3 5 93.61 101.63 5.89 o 5 3 5 133.77 142.25 7.25 o 6 3 5 1108.75 1051.69 23.30 o 7 3 5 52.93 61.98 12.28 o 8 3 5 42.24 39.73 12.31 o 0 4 5 2813.95 2895.73 101.14 o 1 4 5 37.23 68.19 8.97 o 2 4 5 2317.76 2507.49 56.57 o 3 4 5 1226.53 1235.55 28.56 o 4 4 5 170.97 181.73 9.27 o 5 4 5 173.45 167.06 8.89 o 6 4 5 778.41 794.72 22.86 o 7 4 5 7.57 7.91 9.17 o 8 4 5 35.88 25.71 13.58 o 0 5 5 48.11 35.37 9.39 o 1 5 5 120.42 128.43 8.73 o 2 5 5 332.03 322.97 12.23 o 3 5 5 348.82 383.14 12.78 o 4 5 5 226.75 232.04 13.67 o 5 5 5 256.28 273.60 13.79 o 6 5 5 11.90 20.80 8.69 o 7 5 5 193.86 203.90 14.95 o 0 6 5 226.46 197.60 16.19 o 1 6 5 151.97 153.43 10.59 o 2 6 5 546.82 568.73 20.28 o 3 6 5 16.12 5.06 6.38 o 4 6 5 171.67 152.10 11.31 o 5 6 5 252.12 272.88 14.46 o 6 6 5 13.60 9.91 11.98 o 7 6 5 81.48 109.56 16.33 o 0 7 5 54.57 64.86 16.44 o 1 7 5 230.87 264.38 16.71 o 2 7 5 567.19 563.57 28.51 o 3 7 5 46.21 63.53 10.98 o 4 7 5 243.62 238.31 16.94 o 5 7 5 163.24 165.84 18.46 o 6 7 5 42.98 52.73 14.91 o 0 8 5 21.70 10.61 16.96 o 1 8 5 182.69 194.19 14.59 o 2 8 5 811.02 780.93 28.13 o 3 8 5 90.86 87.01 13.70 o 4 8 5 131.14 131.85 15.92 o 5 8 5 88.61 88.90 18.19 o 0 9 5 11.44 27.37 17.54 o 1 9 5 19.87 17.35 12.65 o 2 9 5 72.97 64.89 14.77 o 3 9 5 22.03 43.82 14.43 o 4 9 5 11.63 19.21 17.46 o 0 10 5 148.66 131.37 25.09 o 1 10 5 84.06 78.29 14.99 o 2 10 5 31.01 35.52 16.07 o 0 0 6 92.96 88.72 6.03 o 1 0 6 1653.59 1611.13 35.62 o 2 0 6 2093.14 2180.26 48.74 o 3 0 6 348.06 342.86 11.01 o 4 0 6 746.20 675.74 22.67 o 5 0 6 17.67 25.54 6.09 o 6 0 6 6.45 20.68 12.79 o 7 0 6 386.37 390.06 22.26 o 8 0 6 120.45 103.17 21.24 o 9 0 6 3.51 12.40 20.02 o 0 1 6 260.94 249.24 8.53 o 1 1 6 3576.17 3435.30 55.59 o 2 1 6 101.13 93.30 4.57 o 3 1 6 56.04 50.66 3.67 o 4 1 6 680.45 718.84 12.95 o 5 1 6 157.31 157.37 6.64 o 6 1 6 720.39 704.36 21.04 o 7 1 6 46.20 46.16 9.05 o 8 1 6 157.64 167.98 16.72 o 9 1 6 173.89 207.85 21.21 o 0 2 6 6.36 2.36 3.84 o 1 2 6 2504.60 2496.51 43.55 o 2 2 6 2997.07 3069.24 50.57 o 3 2 6 341.52 355.33 8.49 o 4 2 6 235.34 232.36 7.08 o 5 2 6 2274.89 2207.31 41.46 o 6 2 6 243.11 220.89 14.17 o 7 2 6 233.23 266.66 15.10 o 8 2 6 27.18 20.48 11.82 o 0 3 6 694.46 710.37 54.29 o 1 3 6 1185.72 1224.95 24.60 o 2 3 6 1569.23 1588.19 31.23 o 3 3 6 621.94 611.22 12.81 o 4 3 6 1182.64 1140.81 24.62 o 5 3 6 27.55 27.63 5.37 o 6 3 6 311.61 311.40 11.26 o 7 3 6 133.33 115.55 11.90 o 8 3 6 0.64 12.04 11.64 o 0 4 6 750.55 841.90 60.40 o 1 4 6 529.25 542.76 18.97 o 2 4 6 509.30 530.24 14.42 o 3 4 6 1760.16 1744.41 36.08 o 4 4 6 139.51 122.62 8.30 o 5 4 6 1116.61 1094.18 29.90 o 6 4 6 19.19 21.16 7.35 o 7 4 6 139.32 142.17 11.99 o 8 4 6 12.75 15.10 12.92 o 0 5 6 1006.15 930.37 38.13 o 1 5 6 49.39 57.19 10.88 o 2 5 6 1.92 0.27 4.83 o 3 5 6 229.90 214.24 9.60 o 4 5 6 388.00 393.39 21.50 o 5 5 6 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15.69 o 1 8 8 25.47 38.11 10.24 o 2 8 8 88.38 72.22 12.91 o 3 8 8 106.06 106.89 19.15 o 4 8 8 47.43 57.89 14.13 o 5 8 8 83.71 80.34 18.48 o 0 9 8 0.01 -13.44 13.94 o 1 9 8 29.17 31.11 12.05 o 2 9 8 77.40 77.17 15.52 o 3 9 8 21.63 34.66 15.13 o 4 9 8 3.70 10.27 15.15 o 0 10 8 180.59 156.33 21.91 o 1 10 8 12.16 1.78 14.22 o 1 0 9 11432.32 11364.42 244.00 o 2 0 9 4042.04 4039.82 98.74 o 3 0 9 224.56 219.96 8.39 o 4 0 9 722.05 807.67 21.42 o 5 0 9 88.18 81.34 8.82 o 6 0 9 73.51 96.65 13.11 o 7 0 9 170.50 216.74 21.06 o 8 0 9 0.01 9.76 14.52 o 0 1 9 2.07 7.28 4.26 o 1 1 9 1161.55 1137.69 17.75 o 2 1 9 2494.38 2546.42 40.27 o 3 1 9 650.43 635.56 13.72 o 4 1 9 21.24 29.70 3.75 o 5 1 9 415.58 401.79 10.58 o 6 1 9 124.67 121.74 10.39 o 7 1 9 305.79 291.98 18.46 o 8 1 9 23.15 21.50 11.62 o 0 2 9 167.22 189.19 13.14 o 1 2 9 151.72 173.77 5.24 o 2 2 9 303.94 318.33 10.23 o 3 2 9 600.71 577.91 13.09 o 4 2 9 658.12 676.06 15.21 o 5 2 9 79.05 77.54 7.38 o 6 2 9 1137.85 1123.92 26.39 o 7 2 9 564.80 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244.31 13.91 o 2 7 9 58.22 61.25 9.37 o 3 7 9 58.70 51.15 11.08 o 4 7 9 80.35 96.47 12.00 o 5 7 9 75.87 65.20 12.23 o 6 7 9 124.21 133.70 19.77 o 0 8 9 0.06 9.99 12.71 o 1 8 9 170.32 176.89 12.34 o 2 8 9 264.79 298.21 18.41 o 3 8 9 334.19 307.04 34.17 o 4 8 9 156.04 143.23 16.32 o 5 8 9 68.10 51.86 17.70 o 0 9 9 0.96 -13.66 13.66 o 1 9 9 87.72 73.27 12.15 o 2 9 9 73.04 76.38 14.04 o 3 9 9 156.04 158.20 18.08 o 4 9 9 82.44 114.25 29.05 o 0 10 9 108.71 119.61 21.36 o 1 10 9 49.41 56.13 15.36 o 0 0 10 4078.40 3904.24 133.41 o 1 0 10 71.18 70.37 5.11 o 2 0 10 49.51 53.66 5.74 o 3 0 10 3617.91 3856.49 85.64 o 4 0 10 19.78 26.85 5.27 o 5 0 10 112.57 110.41 9.62 o 6 0 10 226.27 217.90 16.02 o 7 0 10 321.94 303.60 30.74 o 8 0 10 204.97 233.54 21.16 o 0 1 10 278.60 295.91 12.00 o 1 1 10 1444.26 1383.11 21.30 o 2 1 10 1769.16 1726.92 28.00 o 3 1 10 1033.49 1046.04 20.56 o 4 1 10 130.22 126.83 5.79 o 5 1 10 17.43 12.33 4.65 o 6 1 10 88.77 102.12 8.90 o 7 1 10 54.75 40.29 9.16 o 8 1 10 130.93 126.02 14.25 o 0 2 10 21.43 25.87 5.60 o 1 2 10 104.53 112.48 6.50 o 2 2 10 47.42 47.82 4.09 o 3 2 10 1559.57 1643.25 30.82 o 4 2 10 356.80 351.04 9.84 o 5 2 10 94.62 82.92 6.21 o 6 2 10 169.17 159.57 9.59 o 7 2 10 361.86 314.08 18.05 o 8 2 10 57.72 69.21 13.17 o 0 3 10 953.96 941.22 23.73 o 1 3 10 565.01 590.02 13.95 o 2 3 10 156.73 177.87 6.27 o 3 3 10 640.87 601.16 13.31 o 4 3 10 23.30 19.06 4.88 o 5 3 10 572.69 547.72 14.26 o 6 3 10 74.92 81.04 8.13 o 7 3 10 118.98 122.42 11.49 o 8 3 10 51.93 49.26 13.18 o 0 4 10 33.31 30.53 9.32 o 1 4 10 1165.52 1269.95 24.73 o 2 4 10 152.78 183.10 13.09 o 3 4 10 836.62 826.67 23.30 o 4 4 10 644.74 605.23 17.33 o 5 4 10 215.74 226.69 10.35 o 6 4 10 126.69 123.37 9.68 o 7 4 10 10.14 21.06 10.67 o 8 4 10 0.21 -8.64 13.56 o 0 5 10 168.62 176.07 12.13 o 1 5 10 279.55 298.22 10.15 o 2 5 10 65.36 73.09 6.33 o 3 5 10 148.06 130.07 9.38 o 4 5 10 424.64 465.60 15.64 o 5 5 10 80.58 68.63 9.89 o 6 5 10 265.02 246.67 13.44 o 7 5 10 56.29 62.00 16.81 o 0 6 10 77.65 78.07 10.73 o 1 6 10 92.52 110.34 8.75 o 2 6 10 230.85 258.51 11.25 o 3 6 10 16.19 13.86 8.86 o 4 6 10 128.92 99.67 10.75 o 5 6 10 482.85 501.07 25.68 o 6 6 10 119.52 124.90 24.87 o 7 6 10 69.69 65.28 22.86 o 0 7 10 100.74 113.01 13.59 o 1 7 10 492.25 518.95 17.25 o 2 7 10 600.18 583.79 20.65 o 3 7 10 0.45 -4.42 10.84 o 4 7 10 457.70 464.75 20.22 o 5 7 10 2.16 12.43 10.78 o 6 7 10 42.38 82.52 19.06 o 0 8 10 370.42 390.79 22.70 o 1 8 10 187.58 193.08 12.65 o 2 8 10 123.56 108.13 12.72 o 3 8 10 24.58 47.67 14.34 o 4 8 10 5.76 20.70 13.75 o 5 8 10 121.46 93.28 24.91 o 0 9 10 347.24 377.64 50.01 o 1 9 10 29.02 45.78 15.60 o 2 9 10 29.74 25.20 14.13 o 3 9 10 24.90 43.52 15.28 o 4 9 10 31.84 48.48 15.66 o 0 10 10 2.37 -14.07 17.23 o 1 10 10 2.58 6.97 14.23 o 1 0 11 5641.22 5595.58 134.56 o 2 0 11 6.94 6.88 3.90 o 3 0 11 1774.09 2080.27 47.60 o 4 0 11 280.36 266.12 10.35 o 5 0 11 632.24 593.02 27.92 o 6 0 11 68.62 56.15 11.30 o 7 0 11 5.28 4.12 11.82 o 8 0 11 175.10 171.41 19.48 o 0 1 11 696.81 700.72 19.67 o 1 1 11 2337.21 2239.09 33.59 o 2 1 11 1658.03 1668.37 27.16 o 3 1 11 1618.96 1729.12 32.04 o 4 1 11 262.24 299.10 8.89 o 5 1 11 208.37 203.09 8.38 o 6 1 11 40.45 39.56 7.17 o 7 1 11 139.28 158.78 11.77 o 8 1 11 162.37 179.76 13.99 o 0 2 11 1165.82 1031.58 27.88 o 1 2 11 535.46 537.57 10.49 o 2 2 11 756.88 748.54 15.50 o 3 2 11 702.90 747.55 14.82 o 4 2 11 76.72 85.62 5.73 o 5 2 11 317.16 322.28 11.60 o 6 2 11 23.22 20.64 6.91 o 7 2 11 389.91 386.64 16.19 o 8 2 11 28.51 4.10 11.54 o 0 3 11 823.62 892.66 24.54 o 1 3 11 856.33 849.39 17.24 o 2 3 11 458.43 446.99 10.71 o 3 3 11 948.42 931.11 20.34 o 4 3 11 282.69 290.89 11.82 o 5 3 11 229.37 244.62 9.37 o 6 3 11 24.19 33.20 8.00 o 7 3 11 472.00 452.63 23.90 o 8 3 11 69.34 88.05 13.98 o 0 4 11 82.43 100.52 8.24 o 1 4 11 432.69 416.81 10.86 o 2 4 11 69.81 78.02 6.08 o 3 4 11 632.41 668.66 16.62 o 4 4 11 721.22 667.13 18.55 o 5 4 11 317.13 303.86 16.52 o 6 4 11 8.26 10.49 7.47 o 7 4 11 150.17 154.47 14.20 o 8 4 11 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30 86.85 94.00 20.54 o 6 2 30 76.91 81.86 14.52 o 0 3 30 688.99 708.05 29.45 o 1 3 30 414.02 399.59 12.95 o 2 3 30 108.18 110.83 9.30 o 3 3 30 511.70 551.27 31.99 o 4 3 30 184.36 147.26 15.45 o 5 3 30 5.82 -8.50 13.30 o 6 3 30 43.08 65.68 16.50 o 0 4 30 548.99 528.91 22.36 o 1 4 30 539.05 527.36 15.76 o 2 4 30 392.14 398.23 18.62 o 3 4 30 497.17 495.16 20.55 o 4 4 30 402.22 385.15 25.19 o 5 4 30 137.62 142.14 17.02 o 6 4 30 164.23 185.73 19.83 o 0 5 30 34.41 37.27 12.02 o 1 5 30 497.36 481.87 19.94 o 2 5 30 517.84 565.95 21.11 o 3 5 30 89.05 80.27 12.68 o 4 5 30 21.87 7.58 13.97 o 5 5 30 25.31 16.78 15.54 o 0 6 30 10.66 26.21 12.98 o 1 6 30 523.31 475.34 18.40 o 2 6 30 419.91 432.86 24.30 o 3 6 30 359.59 363.28 22.01 o 4 6 30 39.07 47.51 16.14 o 0 7 30 75.69 89.89 23.37 o 1 7 30 2.43 4.42 12.35 o 2 7 30 208.01 239.63 16.85 o 3 7 30 157.80 189.34 20.49 o 0 8 30 129.16 136.19 30.30 o 1 0 31 82.80 91.25 12.84 o 2 0 31 624.93 632.88 27.68 o 3 0 31 402.95 372.77 26.80 o 4 0 31 0.89 4.17 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134.61 137.34 13.75 o 2 5 38 93.02 109.59 19.13 o 3 5 38 41.33 38.88 16.59 o 0 6 38 1.73 1.02 16.62 o 1 6 38 14.59 16.15 14.13 o 1 0 39 6.36 6.49 17.85 o 2 0 39 33.75 32.25 16.08 o 3 0 39 67.65 66.75 22.58 o 4 0 39 3.25 -11.36 21.10 o 5 0 39 79.41 93.65 26.70 o 0 1 39 93.23 93.44 32.46 o 1 1 39 176.22 195.98 15.84 o 2 1 39 41.05 51.03 13.17 o 3 1 39 456.18 492.25 26.88 o 4 1 39 42.50 86.40 17.19 o 5 1 39 101.92 138.77 19.57 o 0 2 39 169.03 167.41 18.86 o 1 2 39 42.05 40.74 13.45 o 2 2 39 5.94 6.16 12.14 o 3 2 39 126.85 144.91 25.92 o 4 2 39 4.39 3.94 15.58 o 0 3 39 244.77 234.37 21.64 o 1 3 39 25.26 13.86 13.23 o 2 3 39 81.01 90.27 14.95 o 3 3 39 39.19 46.89 22.19 o 4 3 39 403.87 447.20 26.48 o 0 4 39 228.17 278.66 20.75 o 1 4 39 167.99 183.69 17.64 o 2 4 39 35.33 60.61 16.70 o 3 4 39 120.67 137.89 19.82 o 0 5 39 161.96 200.14 25.49 o 1 5 39 16.21 14.14 11.92 o 2 5 39 23.66 26.49 19.90 o 0 0 40 276.62 221.33 38.31 o 1 0 40 45.05 62.44 16.15 o 2 0 40 124.31 128.77 24.05 o 3 0 40 16.23 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45 39.64 63.93 19.25 o 0 0 46 680.68 848.10 72.84 o 1 0 46 102.75 163.36 46.70 o 2 0 46 0.06 5.82 26.86 o 0 1 46 67.12 54.91 43.05 o 1 1 46 10.96 21.32 19.30 o 2 1 46 91.20 73.60 28.41 o 0 2 46 10.77 -27.44 27.44 o 1 2 46 161.27 183.02 26.90 o 1 0 47 50.89 66.04 29.80 o 0 1 47 199.00 272.88 36.14 o 1 1 47 3.94 -19.13 19.13 o