#------------------------------------------------------------------------------ #$Date: 2011-09-16 18:46:08 +0300 (Fri, 16 Sep 2011) $ #$Revision: 26025 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2015305.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2015305_Fobs loop_ _publ_author_name 'Lu, Li-Ping' 'Yao, Shu-Qin' 'Zhu, Miao-Li' _publ_section_title ; cis-Diaqua[(E)-2-(2-oxidobenzylideneamino-\k^2^N,O)benzoato-\kO]copper(II): tubes built from O---H···O hydrogen-bonding, \p--\p and C---H···\p interactions ; _journal_coeditor_code GD3011 _journal_issue 5 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first m220 _journal_page_last m222 _journal_volume 62 _journal_year 2006 _space_group_IT_number 148 _symmetry_space_group_name_Hall '-R 3' _symmetry_space_group_name_H-M 'R -3 :H' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 120.000 _cell_length_a 46.26300 _cell_length_b 46.2630 _cell_length_c 7.2030 _exptl_crystal_F_000 6228.00 _reflns_d_resolution_high 0.7709 _[local]_cod_data_source_file gd3011Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' ysq2-s R = 0.07 ' _shelx_refln_list_code 4 _shelx_f_calc_maximum 1110.29 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz x,y,z -y,x-y,z -x+y,-x,z -x,-y,-z y,-x+y,-z x-y,x,-z 1/3+x,2/3+y,2/3+z 1/3-y,2/3+x-y,2/3+z 1/3-x+y,2/3-x,2/3+z 1/3-x,2/3-y,2/3-z 1/3+y,2/3-x+y,2/3-z 1/3+x-y,2/3+x,2/3-z 2/3+x,1/3+y,1/3+z 2/3-y,1/3+x-y,1/3+z 2/3-x+y,1/3-x,1/3+z 2/3-x,1/3-y,1/3-z 2/3+y,1/3-x+y,1/3-z 2/3+x-y,1/3+x,1/3-z loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status _refln_sint/lambda 0 3 0 783145.56 705551.50 10570.15 o 0.03744 -2 4 0 132409.44 79330.91 700.46 o 0.04323 -1 5 0 47137.30 91340.67 5035.53 o 0.05719 0 6 0 93.08 3394.13 480.66 o 0.07488 -5 7 0 90198.63 78828.58 1769.10 o 0.07794 -2 7 0 935.68 741.15 265.83 o 0.07794 -7 8 0 296.14 70.12 262.12 o 0.09422 -4 8 0 286.42 162.71 195.82 o 0.08646 -1 8 0 131916.30 156322.02 3326.71 o 0.09422 -6 9 0 760164.19 821244.44 14963.14 o 0.09905 -3 9 0 216418.13 241470.59 5555.44 o 0.09905 0 9 0 206931.56 211923.88 4449.87 o 0.11232 -8 10 0 8368.40 5863.25 495.86 o 0.11438 -5 10 0 96963.88 92567.18 3225.99 o 0.10808 -2 10 0 64981.82 81341.65 2290.08 o 0.11438 -10 11 0 40257.91 58249.30 2465.59 o 0.13148 -7 11 0 8138.12 6900.25 507.72 o 0.12035 -4 11 0 2129.94 1656.73 288.35 o 0.12035 -1 11 0 36047.90 42561.10 2194.96 o 0.13148 -9 12 0 108.84 925.79 540.47 o 0.13499 -6 12 0 14457.82 22024.76 1352.24 o 0.12969 -3 12 0 6488.92 8987.20 993.88 o 0.13499 0 12 0 157067.86 171412.28 4597.34 o 0.14976 -11 13 0 228226.89 227577.13 4235.88 o 0.15131 -8 13 0 3144.99 2093.71 408.82 o 0.14174 -5 13 0 203466.81 225665.31 5289.73 o 0.14174 -2 13 0 11187.03 7862.12 474.08 o 0.15131 -13 14 0 85235.28 86518.68 2039.46 o 0.16882 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o 0.39067 -9 35 1 11173.74 11664.67 1406.48 o 0.39895 -6 35 1 40755.27 42001.55 2417.54 o 0.41049 -3 35 1 34921.99 34795.68 2524.66 o 0.42503 0 35 1 14290.88 14734.57 2103.21 o 0.44227 3 35 1 29988.52 29904.79 2929.90 o 0.46191 6 35 1 14979.41 12905.99 2148.47 o 0.48365 9 35 1 6369.47 8399.36 2392.85 o 0.50723 12 35 1 2305.76 3628.13 1813.84 o 0.53240 15 35 1 1810.05 4370.20 1975.38 o 0.55894 18 35 1 2841.26 3694.12 2123.99 o 0.58667 -53 36 1 174.66 2137.30 2047.63 o 0.58906 -50 36 1 1690.36 3805.06 1966.55 o 0.56186 -47 36 1 3215.10 6476.63 2163.22 o 0.53589 -44 36 1 6092.21 3121.27 2618.72 o 0.51136 -41 36 1 76.11 24.70 1390.70 o 0.48846 -38 36 1 2312.29 1586.35 1325.33 o 0.46744 -35 36 1 9149.11 4595.90 2115.64 o 0.44857 -32 36 1 6326.78 5513.47 1354.68 o 0.43212 -29 36 1 25950.77 25213.37 2130.37 o 0.41839 -26 36 1 35408.18 34075.80 2744.68 o 0.40764 -23 36 1 23351.75 20655.71 1746.79 o 0.40012 -20 36 1 2443.99 1185.89 1203.08 o 0.39601 -17 36 1 22794.83 22192.64 1680.58 o 0.39542 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2336.02 o 0.53502 4 42 1 4833.19 4067.42 2335.89 o 0.55516 7 42 1 873.07 10.29 2242.60 o 0.57704 -49 43 1 1710.10 5804.83 4465.11 o 0.58187 -46 43 1 35157.07 38564.33 5496.28 o 0.56061 -43 43 1 150.72 15.57 1793.96 o 0.54110 -40 43 1 2877.28 3535.84 1844.33 o 0.52355 -37 43 1 1859.72 1386.19 1579.47 o 0.50815 -34 43 1 108.01 2496.53 1702.90 o 0.49511 -31 43 1 46675.14 43215.38 5955.15 o 0.48462 -28 43 1 3593.45 3018.29 1690.75 o 0.47684 -25 43 1 1422.33 2980.58 1573.19 o 0.47192 -22 43 1 2983.68 5605.53 1533.03 o 0.46993 -19 43 1 1052.36 2753.43 1312.12 o 0.47092 -16 43 1 5787.09 4505.63 1466.93 o 0.47488 -13 43 1 11417.90 15195.26 2668.95 o 0.48171 -10 43 1 7986.40 9197.06 2245.01 o 0.49132 -7 43 1 3736.17 6331.46 2060.86 o 0.50353 -4 43 1 3.13 5.55 1435.63 o 0.51816 -1 43 1 60620.38 62731.29 7747.42 o 0.53502 2 43 1 10088.23 12206.94 3914.10 o 0.55390 5 43 1 2602.89 4717.69 2272.87 o 0.57460 -48 44 1 4076.54 6940.69 3350.40 o 0.57986 -45 44 1 231.15 19.46 2016.70 o 0.55977 -42 44 1 20.22 4215.03 1875.31 o 0.54153 -39 44 1 3360.65 1781.16 1598.04 o 0.52533 -36 44 1 7713.64 10579.53 2244.86 o 0.51136 -33 44 1 187.61 2013.90 1558.13 o 0.49980 -30 44 1 13087.26 14815.66 2624.54 o 0.49084 -27 44 1 1448.55 5179.81 2190.98 o 0.48462 -24 44 1 33225.59 30647.84 3560.89 o 0.48123 -21 44 1 168.60 5.47 1560.10 o 0.48074 -18 44 1 4785.36 7143.95 1524.54 o 0.48317 -15 44 1 1129.01 811.44 1284.20 o 0.48846 -12 44 1 739.76 575.81 1196.15 o 0.49652 -9 44 1 2626.73 4732.81 1850.65 o 0.50723 -6 44 1 3473.11 6398.99 2102.79 o 0.52041 -3 44 1 3115.02 7702.92 2531.44 o 0.53589 0 44 1 12483.03 12428.85 2796.19 o 0.55348 3 44 1 11787.31 13435.19 3045.50 o 0.57297 6 44 1 908.62 3787.30 3375.79 o 0.59419 -47 45 1 705.04 16.15 1975.93 o 0.57865 -44 45 1 555.59 549.04 2236.79 o 0.55977 -41 45 1 30225.30 22995.25 3310.11 o 0.54282 -38 45 1 14324.50 14115.56 2741.29 o 0.52799 -35 45 1 28593.83 22864.05 3527.92 o 0.51545 -32 45 1 74136.86 67815.20 12783.79 o 0.50538 -29 45 1 60897.84 59596.82 6259.60 o 0.49793 -26 45 1 3801.45 4188.01 2543.34 o 0.49322 -23 45 1 11727.23 8361.43 2252.04 o 0.49132 -20 45 1 11759.98 14623.97 3065.43 o 0.49227 -17 45 1 1810.62 2213.65 1399.27 o 0.49605 -14 45 1 14492.59 16154.56 3763.98 o 0.50260 -11 45 1 637.38 1343.60 1574.59 o 0.51181 -8 45 1 674.68 1237.44 1650.62 o 0.52355 -5 45 1 774.00 1722.87 1723.75 o 0.53763 -2 45 1 7847.00 8650.74 2694.36 o 0.55390 1 45 1 3314.70 5669.13 3844.01 o 0.57216 4 45 1 9.36 745.80 1756.39 o 0.59222 -46 46 1 4115.36 4348.81 2551.53 o 0.57825 -43 46 1 1910.78 4415.51 1848.48 o 0.56061 -40 46 1 29292.63 23551.74 4181.75 o 0.54497 -37 46 1 27259.34 29205.62 3611.44 o 0.53152 -34 46 1 16472.50 10063.90 2640.86 o 0.52041 -31 46 1 12162.44 13996.89 3486.53 o 0.51181 -28 46 1 29092.45 22347.98 4074.07 o 0.50584 -25 46 1 7734.64 5958.81 2156.69 o 0.50260 -22 46 1 1883.50 2194.85 1698.95 o 0.50214 -19 46 1 19.69 585.00 1690.72 o 0.50446 -16 46 1 40054.42 42926.04 3645.72 o 0.50952 -13 46 1 32175.60 32997.01 4827.20 o 0.51726 -10 46 1 1643.67 1994.26 1746.41 o 0.52755 -7 46 1 915.04 3444.49 1943.09 o 0.54024 -4 46 1 9646.62 13149.18 2778.44 o 0.55516 -1 46 1 2286.50 2964.74 1812.88 o 0.57216 2 46 1 54.13 4163.47 4152.39 o 0.59104 -45 47 1 1453.19 5366.12 2483.57 o 0.57865 -42 47 1 1126.02 2543.74 1815.50 o 0.56227 -39 47 1 3082.59 4697.41 1986.57 o 0.54796 -36 47 1 2074.87 2775.97 1699.29 o 0.53589 -33 47 1 9910.31 6174.87 2704.61 o 0.52622 -30 47 1 18445.96 21116.96 4077.26 o 0.51906 -27 47 1 9529.60 4859.34 2214.94 o 0.51454 -24 47 1 766.21 535.61 1653.13 o 0.51272 -21 47 1 30140.52 31466.55 4343.10 o 0.51363 -18 47 1 36162.64 38353.38 4289.40 o 0.51726 -15 47 1 199.00 1235.75 1390.65 o 0.52355 -12 47 1 1581.95 539.81 1536.46 o 0.53240 -9 47 1 10540.42 10462.37 2536.83 o 0.54368 -6 47 1 2496.73 1639.87 1829.71 o 0.55726 -3 47 1 609.25 3747.92 1907.26 o 0.57297 0 47 1 8459.42 6648.68 2390.88 o 0.59064 -44 48 1 301.55 213.58 2346.71 o 0.57986 -41 48 1 386.08 5528.33 1970.87 o 0.56476 -38 48 1 26086.17 22772.09 3405.15 o 0.55179 -35 48 1 908.37 254.87 1983.20 o 0.54110 -32 48 1 19221.79 18980.66 3793.24 o 0.53283 -29 48 1 3916.31 4043.25 2396.53 o 0.52710 -26 48 1 5138.96 3286.65 2391.91 o 0.52399 -23 48 1 36443.86 35071.64 3957.90 o 0.52355 -20 48 1 446.31 444.52 1567.84 o 0.52577 -17 48 1 335.60 2840.31 1777.86 o 0.53064 -14 48 1 275.48 866.56 1988.00 o 0.53807 -11 48 1 557.83 1953.34 1818.52 o 0.54796 -8 48 1 674.61 2202.89 1824.30 o 0.56019 -5 48 1 5512.01 8414.04 2400.06 o 0.57460 -2 48 1 3432.97 2212.29 1907.97 o 0.59104 -43 49 1 11079.81 12059.24 2612.30 o 0.58187 -40 49 1 51.75 1338.31 1646.71 o 0.56806 -37 49 1 2288.37 5492.68 2556.92 o 0.55643 -34 49 1 486.70 636.28 2008.96 o 0.54711 -31 49 1 25813.66 17938.16 4207.50 o 0.54024 -28 49 1 37528.29 34250.42 4793.01 o 0.53589 -25 49 1 632.99 14.88 1992.19 o 0.53415 -22 49 1 11115.28 15675.14 2830.75 o 0.53502 -19 49 1 8221.26 10796.23 2562.36 o 0.53850 -16 49 1 4876.35 3916.65 2366.67 o 0.54454 -13 49 1 35143.03 34960.92 5198.80 o 0.55306 -10 49 1 4.64 938.35 1636.93 o 0.56393 -7 49 1 6031.60 3334.26 3174.08 o 0.57704 -4 49 1 19281.28 24140.08 4223.31 o 0.59222 -42 50 1 14.85 3005.45 1847.90 o 0.58468 -39 50 1 6781.85 8950.21 3290.17 o 0.57216 -36 50 1 5345.74 6712.20 4795.96 o 0.56186 -33 50 1 20665.07 24458.50 6086.12 o 0.55390 -30 50 1 15226.24 13743.73 3086.02 o 0.54839 -27 50 1 24738.29 27611.05 4768.42 o 0.54540 -24 50 1 5488.79 7897.51 2129.86 o 0.54497 -21 50 1 1870.74 6205.37 2133.84 o 0.54711 -18 50 1 13520.10 12723.32 2964.32 o 0.55179 -15 50 1 117.58 1403.61 2673.05 o 0.55894 -12 50 1 8493.28 17968.25 3724.30 o 0.56847 -9 50 1 3021.76 2870.41 2152.00 o 0.58027 -6 50 1 1023.26 3676.18 1957.42 o 0.59419 -41 51 1 229.30 2751.71 2364.00 o 0.58826 -38 51 1 2868.77 8152.53 2806.38 o 0.57704 -35 51 1 1687.57 2386.50 2465.02 o 0.56806 -32 51 1 1764.96 3286.33 3795.91 o 0.56144 -29 51 1 5.50 1104.34 2421.79 o 0.55726 -26 51 1 4063.88 6833.63 2731.97 o 0.55559 -23 51 1 1851.63 4109.39 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22 4 35684.96 35747.95 2389.61 o 0.36641 -10 22 4 3471.02 3419.68 884.99 o 0.36577 -7 22 4 1502.70 2886.96 984.84 o 0.36895 -4 22 4 45962.77 40566.34 2517.86 o 0.37585 -1 22 4 2430.50 4167.72 1264.05 o 0.38627 2 22 4 6489.52 5973.42 1499.61 o 0.39994 5 22 4 2523.74 2321.23 1177.62 o 0.41654 8 22 4 2554.11 3653.45 1335.36 o 0.43572 11 22 4 8007.50 7041.81 1820.54 o 0.45718 14 22 4 8082.95 10009.16 2003.82 o 0.48059 17 22 4 262.83 2846.85 1505.01 o 0.50570 20 22 4 313.54 967.39 1491.55 o 0.53226 -45 23 4 5187.72 7818.21 1903.94 o 0.56006 -42 23 4 4294.92 4195.51 1613.18 o 0.53270 -39 23 4 5223.78 3644.54 1701.83 o 0.50663 -36 23 4 6.77 601.23 1293.60 o 0.48205 -33 23 4 31719.56 32657.05 3254.58 o 0.45922 -30 23 4 11845.57 9644.27 1982.98 o 0.43840 -27 23 4 1639.89 2961.58 1236.10 o 0.41989 -24 23 4 5592.96 6222.54 1404.90 o 0.40401 -21 23 4 35776.64 38628.32 2405.35 o 0.39108 -18 23 4 66153.11 61132.29 2897.22 o 0.38140 -15 23 4 2451.96 2944.22 1056.46 o 0.37523 -12 23 4 30825.71 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2307.26 o 0.38079 -11 24 4 13418.30 14614.58 1563.68 o 0.38018 -8 24 4 72589.09 75802.22 3208.07 o 0.38324 -5 24 4 7612.02 8531.30 1584.70 o 0.38988 -2 24 4 6267.27 7518.95 1534.22 o 0.39994 1 24 4 612.50 1685.71 1118.13 o 0.41316 4 24 4 30244.41 22377.68 2508.41 o 0.42924 7 24 4 43380.71 43027.69 3660.67 o 0.44789 10 24 4 11884.73 10775.23 2577.40 o 0.46878 13 24 4 1433.21 5032.69 1683.26 o 0.49165 16 24 4 10051.10 8130.44 2240.95 o 0.51622 19 24 4 3494.59 6545.39 1850.10 o 0.54226 22 24 4 56.68 321.88 1524.54 o 0.56958 -46 25 4 588.89 754.20 2067.30 o 0.56999 -43 25 4 12526.73 10735.23 2281.83 o 0.54312 -40 25 4 8459.29 10230.69 3624.52 o 0.51757 -37 25 4 280.53 1061.73 1577.24 o 0.49354 -34 25 4 16.96 0.27 1206.13 o 0.47127 -31 25 4 20353.03 18407.34 3004.54 o 0.45100 -28 25 4 6645.31 5413.95 1326.40 o 0.43303 -25 25 4 2482.25 3142.85 1585.18 o 0.41766 -22 25 4 23267.35 21714.02 2308.19 o 0.40516 -19 25 4 497.56 938.02 939.63 o 0.39583 -16 25 4 10713.90 11870.51 1695.60 o 0.38988 -13 25 4 11364.16 10835.21 1699.45 o 0.38748 -10 25 4 2195.63 2483.95 892.43 o 0.38868 -7 25 4 41020.34 37156.75 2362.25 o 0.39346 -4 25 4 15767.40 14943.62 1954.36 o 0.40169 -1 25 4 20619.60 23548.75 3215.73 o 0.41316 2 25 4 85322.66 76452.99 4458.25 o 0.42761 5 25 4 53150.13 45423.11 3636.03 o 0.44474 8 25 4 2586.10 2766.18 1438.29 o 0.46428 11 25 4 33.09 50.35 1218.96 o 0.48591 14 25 4 6248.70 9316.06 1879.99 o 0.50938 17 25 4 541.91 1806.36 1572.76 o 0.53445 20 25 4 8293.84 9439.82 2141.55 o 0.56090 23 25 4 675.22 142.23 1544.06 o 0.58854 -48 26 4 7039.80 7029.62 1918.27 o 0.58894 -45 26 4 5202.48 6650.89 1904.75 o 0.56173 -42 26 4 204.95 606.31 1352.03 o 0.53576 -39 26 4 2421.49 2876.36 1597.51 o 0.51122 -36 26 4 2459.25 3727.37 1533.23 o 0.48831 -33 26 4 63.56 1.73 1196.51 o 0.46729 -30 26 4 28660.91 25727.06 3286.62 o 0.44841 -27 26 4 14068.24 16038.01 1962.12 o 0.43195 -24 26 4 2426.84 4008.71 1211.31 o 0.41821 -21 26 4 12574.62 13930.94 1640.84 o 0.40746 -18 26 4 628.09 1930.10 1026.67 o 0.39994 -15 26 4 15457.65 13064.53 2898.60 o 0.39583 -12 26 4 21863.91 20838.00 1889.74 o 0.39524 -9 26 4 19587.75 16280.34 1670.64 o 0.39818 -6 26 4 35527.14 35882.82 3279.19 o 0.40459 -3 26 4 44160.69 42881.80 3349.22 o 0.41429 0 26 4 28964.10 30870.86 3529.91 o 0.42706 3 26 4 19735.84 20934.80 2534.83 o 0.44264 6 26 4 5335.31 10924.44 1971.94 o 0.46074 9 26 4 33415.04 32471.50 3316.66 o 0.48108 12 26 4 814.17 1138.64 1406.47 o 0.50339 15 26 4 24166.90 29279.49 3257.16 o 0.52741 18 26 4 7484.64 14769.18 2416.16 o 0.55293 21 26 4 10367.00 10157.77 2318.56 o 0.57974 -47 27 4 1614.66 4023.40 1733.14 o 0.58055 -44 27 4 6914.13 5883.58 2219.78 o 0.55419 -41 27 4 7728.94 6050.66 1816.06 o 0.52918 -38 27 4 1808.80 2997.68 1580.93 o 0.50570 -35 27 4 23129.30 25636.24 3010.39 o 0.48399 -32 27 4 31325.27 28564.88 2973.20 o 0.46428 -29 27 4 36.42 93.58 867.52 o 0.44684 -26 27 4 2149.45 3556.51 1202.14 o 0.43195 -23 27 4 1408.80 2976.10 1008.78 o 0.41989 -20 27 4 13706.45 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